JPH0588312A - Production of sheet-shaped resin molding - Google Patents

Abstract

PURPOSE:To provide the process for production which can produce a resin molding having high accuracy with high productivity relating to the process for production of the sheet-shaped resin molding having rugged shapes on the surface. CONSTITUTION:After an active energy ray curing type resin compsn. 2 is applied on a sheet-shaped transparent base material to be transported, a roll 3 which has the inverted shape of the rugged shape on the surface and rotates at the same rotating speed as the transporting speed of the transparent base material is pressed to the active energy ray curing type resin compsn. 2 applied on the base material and is irradiated in this state with active energy ray through the transparent base material 1 on the side opposite from the coated surface, by which the resin layer is cured.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a decorative design product and a method for continuously producing a resin molded product having a precise rugged surface such as a lenticular lens.

[0002]

2. Description of the Related Art Sheets having an uneven surface are used for decoration and lenticular lenses, but it is quite difficult to form the uneven shape precisely. In particular, it is difficult to manufacture the lenticular lens used for stereoscopic photography at low cost because it requires high precision.

As shown in FIG. 8 (a), a lenticular sheet for stereoscopic photography is a transparent sheet provided with minute cylindrical continuous concavo-convex shapes. Similar to the lenticular sheet, there is a so-called fly-eye lens sheet as shown in FIG. 8B.
This is a transparent sheet having an uneven shape on the surface of which minute spherical lenses are arranged, and is used to form a three-dimensional photograph like a lenticular sheet. The stereoscopic image by the lenticular sheet is a stereoscopic image display method in which the observation direction is different in only one direction, whereas the stereoscopic image by the fly-eye lens sheet is a stereoscopic image display method in which the observation direction is different in two dimensions.

A three-dimensional photograph using a lenticular sheet and a fly-eye lens sheet will be briefly described. Here, only one direction when the lenticular sheet is used will be described, but basically the same applies to the two-dimensional case where the fly-eye lens sheet is used. FIG. 9 is a diagram for explaining the principle of stereoscopic photography. In FIG. 9A, 1
Reference numeral 1 is a lenticular sheet, which a human 13 observes. The lenticular sheet 11 is shown in FIG. 9 (b).
As shown in FIG. 5, the surface 21 on the observation side of the transparent sheet 11 has an uneven shape in which minute cylinders are arranged.
Acts as a cylindrical lens with the image forming position as.
A printing paper 23 is attached after the back surface 22.

The photographic printing paper 23 is manufactured as follows. First, an object to be represented by a three-dimensional photograph is taken with different parallax. Then, the captured image is projected toward the lenticular sheet to which the photographic printing paper 23 is attached while maintaining the parallax. The projected image is reduced on the printing paper 23 and recorded in the order of parallax. After peeling off the photographic paper and developing it, the photographic paper is attached to the original position.
As shown in, image light is output in a direction corresponding to the parallax at the time of projection.

[0006] In stereoscopic photography, a lenticular sheet having a characteristic suitable for that is used by assuming the positional relationship of an object to be projected and observing the positional relationship of the lenticular sheet. Now, as shown in FIG. 10, the imaging position of the cylinder surface 21 and the back surface 2 which is the printing paper surface.
It is assumed that there is a case where 2 do not match due to the variation in the thickness of the lenticular sheet. Then, as shown in FIG. 10, an image that should be originally recorded at one point is blurred, which causes a problem that the reproduced stereoscopic image is deteriorated. This is the same when the shape of the cylinder surface 21 changes. Therefore, the lenticular sheet for stereoscopic photography and the fly-eye lens sheet are required to have high manufacturing accuracy.

As a method for producing a sheet-shaped resin molded product having irregularities on its surface such as a lenticular sheet and a fly's eye lens sheet, a method of injection molding a molten synthetic resin, a method of contacting a resin plate with a mold is used. A press molding method or the like is used in which the uneven shape of the surface of the mold is transferred by heating and pressing this.

[0008]

However, when the lenticular sheet for stereoscopic photography and the fly-eye lens sheet are manufactured by the above method, there are various problems. The injection molding method uses an upper mold 31 and a lower mold 32 as shown in FIG.
The molten synthetic resin is injected through the injection port 33 into the hollow 34 formed by and solidified, and then the upper mold 31 and the lower mold 32 are formed.
It is a method of separating and molding. However, the injection molding method has a problem in productivity and cost because the mold wears relatively quickly, and it is difficult to mold a large size, so that it can be used only for a relatively small size.
Further, in the press molding method by heating and pressing shown in FIG. 11 (b), it takes a long time to heat and cool the resin plate and the mold, so that it is necessary to prepare a large number of molds for mass production of the resin molded product. However, in order to make a large-sized resin molded product, a large amount of equipment and the like is required. Further, as is apparent from FIG. 11B, in the case of a lenticular sheet or a fly-eye lens sheet, the shape of the mold has an acute-angled protruding portion, so that there is a problem that the mold is quickly worn by pressing. Furthermore, the lenticular sheet produced by these methods is not always satisfactory in the transferability to the mold, and the shape of the lenticular lens is deviated from the design value, and the image may be misaligned or lines may appear in the image. The image was not sharp.

Further, in order to further improve the productivity by the press molding method, as shown in FIG. 12, the concavo-convex shape of the cylinder is provided on the surface of the roll 39, and the heated resin plate is sandwiched between the opposing support roll 40. There is also a method of continuous press molding, but there is a problem that the mold is greatly damaged and the shape is not sufficiently transferred due to the above reasons. The present invention has been made in view of the above problems, and an object of the present invention is to realize a manufacturing method capable of producing a resin molded product having an uneven surface on the surface with high accuracy and good production efficiency.

[0010]

In order to solve the above-mentioned problems, the production method of the present invention comprises applying an active energy ray-curable resin composition to a sheet-like transparent substrate, and then forming a reverse mold having an uneven shape on the surface. The active energy ray is radiated while pressing the rotating roll having the. That is, the method for producing a sheet-shaped resin molded article of the present invention is a method for producing a sheet-shaped resin molded article having an uneven surface, in which an active energy ray-curable resin composition is applied to a sheet-shaped transparent substrate to be conveyed. After applying
A roll having a concavo-convex shape that is the reverse of the concavo-convex shape on the surface and rotating at the same rotation speed as the transport speed of the transparent substrate was pressed against the active energy ray-curable resin composition applied to the transparent substrate. In this state, the resin layer is cured by irradiating active energy rays from the side opposite to the surface coated with the resin composition through the transparent substrate.

[0011]

FIG. 1 is a diagram for explaining the manufacturing method of the present invention. In the figure, reference numeral 1 denotes a sheet-shaped transparent substrate, which is conveyed by a conveying unit at a constant speed. 2 is an active energy ray-curable resin composition, which is in liquid form. Reference numeral 7 is for applying the above resin composition to the surface of the transparent substrate 1 with a constant thickness. Reference numeral 3 denotes a roll having a reverse shape of an uneven surface, which rotates at a constant speed. 4 is an active energy ray irradiating means, and from the lower surface side of the transparent substrate 1,
Irradiation with active energy rays. Reference numeral 8 is a means for shielding active energy rays, which prevents the resin composition from being irradiated with active energy rays and being cured before the resin composition follows the surface shape of the roller 3.

The roll 3 is pressed against the resin composition 2 applied on the transparent substrate 1, but does not contact the transparent substrate 1. Even if they come into contact with each other, the surface of the roll 3 and the transparent substrate 1
Make sure that little force is applied to. The resin composition is in a liquid state until it is irradiated with active energy rays, and even if the surface of the roll 3 is pressed, almost no force is applied to the surface of the roll 3 and the resin composition follows the uneven shape of the surface of the roll 3. It will have a different shape. In that state, the active energy ray is irradiated and cured to form a desired uneven shape on the transparent substrate 1.

Therefore, since almost no force is applied to the surface of the roll 3, the mold is not damaged. Moreover, since the transparent substrate 1 is transported in accordance with the rotation of the roll 3, the production efficiency is good, and a very long substrate can be produced in the transportation direction. In addition, since the liquid resin composition 2 is irradiated with active energy rays and hardens when it follows the shape of the roll 3,
The transferability of the uneven shape is very good. Further, since the transparent base material 1 which has already been processed into a sheet is used, it is easy to manage the distance between the lower surface of the transparent base material 1 and the roll 3 and the sheet-shaped resin molded product has a high precision. can get.

[0014]

EXAMPLE An example of producing a lenticular sheet as shown in FIG. 2 will be described. Here, the sheet is conveyed in the direction of the cylinder, but the same applies to the case where the direction of the cylinder is perpendicular to the conveying direction. As the transparent substrate used in the present invention, a plate-shaped or film-shaped resin substrate, a glass plate or the like can be used. Above all, a resin sheet-shaped substrate having a thickness of 1000 μm or less is desirable from the viewpoint of continuous productivity of the molded product and winding and storing the molded product. Further, if necessary, an easily adhesive layer, an antistatic layer, etc. may be provided on the resin substrate.

Examples of the active energy ray-curable resin used in carrying out the present invention include a composition mainly containing a monomer / oligomer having a polymerizable group, a thermoplastic binder resin and a monomer / oligomer having a polymerizable group. It is possible to use a composition mainly composed of a photo-cationic polymerization reaction type epoxy resin composition, or a composition mainly composed of a resin having a polymerizable group bonded to the main chain or side chain of the polymer, The resin is not particularly limited to these compositions as long as it is a resin having a relatively low viscosity and curable by active energy rays.

The monomer or oligomer having a polymerizable group is not particularly limited, but has a boiling point of 100 ° C. at normal pressure.
When the molecular weight of 10,000 or less is used and ultraviolet rays are used as active energy rays, monomers and oligomers having an acryloyloxy group or a methacryloyloxy group as a polymerizable group are preferable. Examples of such a monomer or oligomer having a (meth) acryloyloxy group include a polyether acrylate or polyether methacrylate (hereinafter, "acrylate or methacrylate" is simply abbreviated as "(meth) acrylate") polyester (meth) acrylate. -Based, polyol (meth) acrylate-based, epoxy (meth) acrylate-based, amidourethane (meth) acrylate-based, urethane (meth) acrylate-based, spiroacetal (meth) acrylate-based, polybutadiene (meth) acrylate-based monomers and oligomers Can be mentioned.

The composition containing a thermoplastic binder resin and a monomer / oligomer having a polymerizable group as a main component is a composition containing the above-described monomer / oligomer having a polymerizable group and a thermoplastic resin. As the thermoplastic resin, those having high transparency are preferable, for example, polyester resin,
(Meth) acrylic resin, polystyrene, polycarbonate, polyvinyl butyral, etc. can be mentioned.

Examples of the cationic photopolymerization type epoxy resin composition include bisphenol A diglycidyl ether, novolac glycidyl ether, hexahydrophthalic acid glycidyl ester, triglycidyl isocyanurate, and 3,4 epoxycyclohexylmethylcarboxylate as resins. Examples of the photopolymerization initiator used include resins in which a diaryl iodonium compound composed of an aromatic halonium salt of Lewis acid, a triaryl sulfonium compound composed of an aromatic sulfonium salt of Lewis acid, and the like are used in combination.

Examples of the resin having a polymerizable group bonded to the main chain and side chain of the polymer include unsaturated polybasic acids having a reactive double bond and unsaturated compounds obtained by polycondensation of polyhydric alcohols. There are polyester resins and the like, specifically, maleic anhydride / phthalic anhydride / propylene glycol, maleic anhydride / isophthalic acid / propylene glycol,
Examples thereof include resins obtained from maleic acid / fumaric acid / isophthalic acid / 1,3-butanediol, maleic acid / isophthalic acid / neopentyl glycol, maleic anhydride / tetrahydrophthalic anhydride / dipropylene glycol and the like.

For the purpose of improving the refractive index, flexibility, releasing property, adhesiveness, light resistance, antistatic property, etc. of the active energy ray-curable resin composition layer, a plasticizer, a surfactant, a releasing agent Agent,
Antioxidants, ultraviolet absorbers, antistatic agents, lubricants, colorants, fillers and the like may be added to the active energy ray-curable resin composition. In order to cure the resin composition in the present invention, particle beams such as electron beams and ion beams, γ rays, X
Active energy rays such as rays, electromagnetic waves such as ultraviolet rays and visible rays are used. Above all, it is preferable to use ultraviolet rays from the viewpoints of curing speed and simplicity of equipment when the size is increased. When using ultraviolet rays as active energy rays,
The photopolymerization initiator is added in an amount of 0.01 to 20% by weight based on the total resin portion.

The photopolymerization initiator used is benzoin, benzoin isobutyl ether, benzyl dimethyl ketal, ethylphenyl glyoxylate, diethoxyacetophenone, 1,1-dichloroacetophenone, 4'-isopropyl-2-hydroxy-2. -Methyl propiophenone, 1-hydroxycyclohexyl phenyl ketone, benzophenone, benzophenone / diethanolamine, 4,4'-bisdimethylaminobenzophenone, 2-methylthioxanthone, tert-butylanthraquinone, carbonyl compounds such as benzyl, tetramethylthiuram monosulfide Sulfur compounds such as tetramethylthiuram disulfide, azo compounds such as azobisisobutylnitrile and azobis-2,4-dimethylvaleronitrile, Down benzoyl peroxide, di -t
Peroxide compounds such as ert-butyl peroxide may be mentioned. These compounds can be used alone or in combination of two or more kinds.

In the present invention, the coating method for applying the active energy ray-curable resin composition to the transparent substrate is a roll coating method, a blade coating method, a bar coating method, a spray coating method, a curtain coating method, a flow coating method,
Although the dip coating method and the like can be mentioned, it is desirable that the viscosity of the resin composition is low in consideration of workability, and therefore a solvent such as ethyl alcohol, methyl ethyl ketone, toluene, ethyl acetate, is added to the resin composition. You may mix dimethylformamide etc. and adjust to suitable coating viscosity. When blending these solvents, it is necessary to volatilize and dry the solvent after coating the resin composition.

Next, a method of bringing a roll into contact with the active energy ray-curable resin composition applied on a sheet-shaped transparent substrate will be described. Basically, it is the same as that shown in FIG. 1, and in the following figures, the numbers representing the respective parts are common. The mold for shaping the uneven shape used in the present invention is a roll having the uneven shape on the periphery. The material is not particularly limited, but examples thereof include metal, glass, ceramics, synthetic resin and the like.

In the lenticular sheet produced, not only the surface shape but also the thickness including the transparent base material has a great influence on the quality of the three-dimensional photograph, so it is important to control the thickness. In order to keep the thickness constant, it is important to keep the positional relationship between the lower surface of the transparent substrate and the roll surface at a predetermined value when the roll is brought into contact with the resin composition and cured. In the present invention, it is possible to use a transparent base material that has already been processed into a sheet shape and heat it for molding so that it has plasticity. In order to perform management, a support roll 5 that supports the lower surface of the transparent base material 1 is used as shown in FIG.

The distance between the roll 3 and the support roll 5 maintains a mechanically precise positional relationship, so that a lenticular sheet having a constant thickness can be obtained. However, in this case, since the supporting roller 5 is present, it is not possible to irradiate the active energy ray from directly below the contact portion of the roll 3, so that it is necessary to irradiate it from an oblique direction as shown in FIG. Therefore, it is desirable that the diameter of the support roll 5 is as small as possible. Note that, in FIG. 3, even after the cured resin composition is separated from the surface of the roll 3, the active energy ray is irradiated to completely cure the resin composition. Since the uneven shape is determined by curing while being in contact with the roll 3, the uneven shape is not changed by irradiation with the active energy ray after separation.

In the method shown in FIG. 3, the active energy rays can be irradiated only in the oblique direction as described above. Therefore, this is improved in the example shown in FIG. In FIG. 4, the support roll 5 is made of a material transparent to active energy rays, for example, quartz glass when the active energy rays are ultraviolet rays,
The active energy ray source 4 is provided in the support roll 5 or is guided into the support roll 5 and is irradiated from the inside of the support roll 5. This makes it possible to efficiently irradiate the portion of the roll 3 in contact with the resin composition 2 with active energy rays. Also in this case, it is necessary to provide a shield 8 to prevent the resin composition 2 from being cured before coming into contact with the roll 3.

In the example shown in FIGS. 3 and 4, the support roll 5 is used.
Was provided to control the thickness. However, the lower surface of the transparent substrate 1 may be separated from the surface of the support roll 5 by a slight amount due to vibration or the like. Therefore, in practice, it is preferable to wind the support roll 5 side even at a small angle. FIG. 5 is an example of FIG.
In this example, the support roll 5 is wound. In the examples shown in FIGS. 1 and 3 to 5, the resin composition 2 contacts the roll 3 only on the tangent line, and the contact time is short. Therefore, it is necessary to irradiate a strong actinic energy ray to cure it while it is in contact. However, when it is difficult to obtain such a strong active energy ray source, the transparent substrate 1 may be wound around the roll 3 as shown in FIG. By doing so, since the surface of the roll 3 is in contact with the resin composition 2 for a long time, the production speed can be further increased, and the transferability of the uneven shape can be further improved.

However, in FIG. 6, since the transparent substrate 1 is biased by the roll 3, the surface of the roll 3 comes into contact with the surface of the transparent substrate 1. In that case, if the urging force is not too large, the damage to the surface of the roll 3 does not cause much problem, and the tip of the uneven shape of the surface of the roll 3 contacts the surface of the transparent substrate 1. A lenticular sheet with a certain thickness can be obtained.

However, when the damage of the concave-convex mold becomes a problem due to the contact of the surface of the roll 3 with the transparent substrate 1, as shown in FIG. By providing the cylindrical portion 9 having a large diameter and winding the transparent substrate 1 around that portion, the interval is accurately maintained without contacting the mold portion. Of course, the resin composition is not applied to the portion of the transparent substrate 1 that is wrapped around the cylindrical portion 9,
No uneven shape is formed either.

Considering the transferability to a money mold and the inhibition of polymerization by oxygen, it is necessary to irradiate at least a part of the active energy ray-curable resin composition in contact with the roll through the transparent substrate with the active energy ray. is there. The above is the description of the manufacturing method of the present invention. The lenticular sheet manufactured by the above manufacturing method will be described.

In the first example, the transparent substrate has a thickness of 1
The 88-micron easy-adhesion-treated polyester film "Lumirror T93 (manufactured by Toray Industries, Inc.)" was used. The following composition containing an initiator by ultraviolet rays was used as the active energy ray-curable resin composition. 2,2 'bis (4-acryloxy-diethoxyphenyl) propane 21.0 parts by weight phenoxyethyl acrylate 9.0 parts by weight 1-hydroxycyclohexyl phenyl ketone 1.5 parts by weight Silicone surfactant SH28PA 0.1 parts by weight (Manufactured by Toray Dow Corning Silicone Co., Ltd.) Methyl ethyl ketone 4.0 parts by weight Toluene 1.0 parts by weight The resin composition was applied to the above film with a blade roll coater to volatilize the solvent, and then, as shown in FIG. The resin composition was cured by irradiating the resin composition with ultraviolet rays while pressing a roll-shaped mold having a reverse shape of the lenticular lens on the coated surface of the resin composition to obtain a lenticular lens sheet.

The thickness of the obtained lenticular lens sheet was uniform. Furthermore, when the lens shape was measured with a surface roughness measuring device (SE-30H manufactured by Kosaka Laboratory), the shape of the lenticular lens of the roll mold was accurately transferred. In the second example, 125 μm thick polyester film “Lumirror T
93 (manufactured by Toray Industries, Inc.) "was used. The following composition containing an initiator by ultraviolet rays was used as the active energy ray-curable resin composition.

2,2 ′ bis (4-acryloxy-diethoxyphenyl) propane 21.0 parts by weight 2-hydroxy-3-phenoxypropyl acrylate 9.0 parts by weight 1-hydroxycyclohexyl phenyl ketone 1.5 parts by weight Silicon-based Surfactant SH28PA 0.1 parts by weight (manufactured by Toray Dow Corning Silicone Co., Ltd.) Methyl ethyl ketone 4.0 parts by weight Toluene 1.0 parts by weight The resin composition was applied to the above film with a blade roll coater to volatilize the solvent. Then, as shown in FIG. 6, ultraviolet rays were applied while pressing a roll-shaped mold having the shape of a lenticular lens on the coated surface of the resin composition, thereby curing the resin composition to obtain a lenticular lens sheet. .. In this case, the lenticular lens sheet could be manufactured faster than in the case of the first example. The thickness of the obtained lenticular lens sheet was uniform. Furthermore, when the lens shape was measured with a surface roughness measuring device (SE-30H manufactured by Kosaka Laboratory), the shape of the lenticular lens of the roll mold was accurately transferred.

For comparison, in order to imprint a lenticular lens mold on a 125 μm thick PMMA film,
PM a flat mold with the shape of a lenticular lens
It was pressed against the MA film and pressed. Although the shape of the lenticular lens could not be transferred at room temperature by pressing, the mold of the lenticular lens could be transferred by heating the film and the mold by the flat plate pressing method. However, the lens shape of the obtained lenticular lens sheet is measured by a surface roughness measuring device (Saka
E-30H), the shape of the mold lenticular lens was not accurately transferred.

Although the manufacturing method of the present invention has been described by taking the manufacturing of the lenticular sheet as an example, it is naturally applicable not only to the lenticular sheet but also to the manufacturing of a fly's-eye lens sheet or the like having another uneven shape on the surface. Is.

[0036]

The present invention has the constitution as described in detail above, and after coating the active energy ray-curable resin composition on a transparent substrate, the coated surface is formed on a roll-shaped mold having irregularities on the surface. By using the step of irradiating active energy rays in a state of pressing the resin layer to cure the resin layer, it is possible to easily use the resin layer in a large size and continuously manufacture a resin molded product with high productivity. In addition to being able to do so, it is possible to obtain a resin molded product having very good transferability, and the effect is extremely large.

[Brief description of drawings]

FIG. 1 is a diagram illustrating steps of a method for producing a sheet-shaped resin molded product of the present invention.

FIG. 2 is a diagram showing a lenticular sheet to be manufactured in an example.

FIG. 3 is a diagram showing an example in which an opposed roll is provided for controlling the thickness.

FIG. 4 is a diagram showing an example in which an opposing roll is made transparent and active energy rays are irradiated from the inside of the opposing roll.

FIG. 5 is a diagram showing an example in which a small amount of a sheet-shaped transparent substrate is wound around a facing roll in the example of FIG. 4 to further improve the thickness control.

FIG. 6 is a diagram showing an example in which the contact time is increased by winding the roll around the roll having an uneven shape to be transferred to the surface.

FIG. 7 is a view showing an example in which guide portions are provided at both ends of the roll in order to control the thickness with high accuracy without contact between the roll surface and the transparent substrate in FIG.

FIG. 8 is a diagram showing a lenticular sheet and a fly-eye lens sheet for stereoscopic photography.

FIG. 9 is a diagram illustrating the principle of stereoscopic photography.

FIG. 10 is a diagram illustrating a shift in focal position due to a variation in thickness of a lenticular sheet and a fly-eye lens sheet.

FIG. 11 is a diagram showing a conventional method for manufacturing a sheet having an uneven surface.

FIG. 12 is a view showing a conventional example in which continuous molding is performed using a roll-shaped mold by the press molding method of FIG.

[Explanation of symbols]

 DESCRIPTION OF SYMBOLS 1 ... Transparent base material 2 ... Active energy ray curable resin composition 3 ... Roll 4 ... Active energy ray source

 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Masayuki Fujiwara 20-1 Miyukicho, Otake City, Hiroshima Prefecture Mitsubishi Rayon Co., Ltd. Central Research Laboratory

Claims (4)

[Claims] 1. A method for producing a sheet-shaped resin molded product having an uneven surface, comprising the steps of applying an active energy ray-curable resin composition to a sheet-shaped transparent substrate to be conveyed, and then applying the active energy ray-curable resin composition onto the surface. A roll having a concavo-convex shape that is the reverse of the concavo-convex shape and rotating at the same rotation speed as the transport speed of the transparent substrate was pressed against the active energy ray-curable resin composition applied to the transparent substrate. In the state, a method for producing a sheet-shaped resin molded product having an uneven shape on the surface of which the resin layer is cured by irradiating active energy rays from the side opposite to the surface coated with the resin composition through the transparent substrate. 2. The method for producing a sheet-shaped resin molded product according to claim 1, wherein the reverse mold concavo-convex shape on the roll surface is a shape in which a large number of lens-shape reverse molds are provided in a ring shape. .. 3. The sheet-shaped transparent base material having a thickness of 100.
The method for producing a sheet-shaped resin molded product according to claim 1, wherein a sheet-shaped substrate having a thickness of 0 μm or less is used. 4. The method for producing a sheet-shaped resin molded product according to claim 1, wherein the active energy rays are ultraviolet rays.