JPH0584524A - Manufacture of draw-ironed can - Google Patents

Manufacture of draw-ironed can

Info

Publication number
JPH0584524A
JPH0584524A JP3275034A JP27503491A JPH0584524A JP H0584524 A JPH0584524 A JP H0584524A JP 3275034 A JP3275034 A JP 3275034A JP 27503491 A JP27503491 A JP 27503491A JP H0584524 A JPH0584524 A JP H0584524A
Authority
JP
Japan
Prior art keywords
ironing
diameter
less
plate thickness
ratio
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP3275034A
Other languages
Japanese (ja)
Inventor
Katsumi Koyama
克己 小山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Furukawa Aluminum Co Ltd
Original Assignee
Furukawa Aluminum Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Furukawa Aluminum Co Ltd filed Critical Furukawa Aluminum Co Ltd
Priority to JP3275034A priority Critical patent/JPH0584524A/en
Publication of JPH0584524A publication Critical patent/JPH0584524A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To provide a draw-ironing method capable of reducing cracks in the draw-ironing process without damaging the surface property of a can and further shortening a movable distance of a shell body forming machine. CONSTITUTION:In a working process of an Al-alloy cylindrical draw-ironed can having a final shape of a diameter-to-height ratio >=1.8, as the ratio of the outer diameter of a blank to an initial drawn core diameter is given by >=1.6 and <=1.8, and the ratio of the core diameter at the initial drawing time to the continued redrawn core diameter is given by >=1.3 and <=1.5, two stages of drawing are carried out. In this case, the difference between the outer diameter of the core and its inner diameter in time of drawing is given by >=2.1 times and <=2.3 times to the thickness of the blank and after it is drawn, the reduction percentage of the plate thickness of the wall part on the can side in time of the initial ironing to the plate thickness of the blank is given by >=25% and <=40%, the reduction of the plate thickness of the side wall part on the followed ironed can is given by >=40% and <=50% and two stages of ironing is carried out continuously to obtain the final side wall thickness of the can.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明はビールあるいは飲料缶な
どの円筒状成形体を製造するDI缶の製造方法に関する
ものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for producing a DI can for producing a cylindrical molded body such as a beer or beverage can.

【0002】[0002]

【従来の技術】ビールあるいは飲料缶などの深い円筒状
成形体は、通常ブランキング加工と初期絞り加工を行
うカッピング工程と、その後に再絞り加工と3段のし
ごき加工を行う缶胴体加工工程により成形されている。
一方、製缶業界では生産性向上のために缶成形速度が年
々早くなっており、現在毎分300缶に達する成形機も
開発されている。
2. Description of the Related Art A deep cylindrical molded body such as a beer or a beverage can is usually formed by a blanking process and a cupping process for initial drawing, followed by a redrawing process and a three-stage ironing process for forming a body of a can. It is molded.
On the other hand, in the can manufacturing industry, the can forming speed is increasing year by year in order to improve the productivity, and a molding machine capable of reaching 300 cans per minute is now being developed.

【0003】[0003]

【発明が解決しようとする課題】ところで成形機の速度
はその出力と共に精度の維持という点から制約されてい
る。そして精度はパンチの可動距離(ストローク)が短
いほど有利であることはいうまでもない。現在缶胴体加
工機は再絞りと3段のしごき加工を連続的に行うために
600mm以上の可動距離を必要としていて、缶成形速
度の増加による生産性の向上に対する制限の1つとなっ
ている。
By the way, the speed of a molding machine is limited in terms of maintaining its output as well as its accuracy. Needless to say, the accuracy is more advantageous as the movable distance (stroke) of the punch is shorter. At present, the can body processing machine requires a movable distance of 600 mm or more in order to continuously perform redrawing and three-stage ironing, which is one of the restrictions for improving the productivity by increasing the can forming speed.

【0004】これに対する対策としてダイス間の距離を
短くするか、あるいは工程数を減らすことが考えられ
る。前者については現工程を行いつつ、次工程が始まっ
てしまい素材の成形性にとって大きな負担となる。また
後者については1工程における加工率が大きくなり破胴
を生じる。特開平2−303634号では、しごき工程
における厚みの減少率をカップ側壁の下部から上部まで
比較的一様な範囲になるよう所定範囲に制御しその後の
加工時の割れを防止する、絞りしごき缶の製造方法が開
示されている。しかしこれだけでは、しごき工程を少な
くすることはできなかった。またこの方法は絞り工具の
摩耗あるいは缶表面性状の悪化を招き、まだ満足すべき
方法とはいえなかった。
As a countermeasure against this, it is conceivable to shorten the distance between the dies or reduce the number of steps. Regarding the former, the current process is performed, but the next process begins, which imposes a heavy burden on the formability of the material. On the other hand, in the latter case, the processing rate in one process becomes large, and the crushing occurs. Japanese Unexamined Patent Publication No. 2-303634 discloses a squeezing ironing can in which the reduction rate of the thickness in the ironing process is controlled within a predetermined range from the lower part to the upper part of the cup side wall to prevent cracks during subsequent processing. Is disclosed. However, this alone cannot reduce the ironing process. Further, this method causes wear of the drawing tool or deterioration of the surface properties of the can, and is not yet a satisfactory method.

【0005】本発明の目的は、上記問題点を鑑み缶の表
面性状を損なうことなく絞りしごき工程における割れを
減少させること、さらに缶胴体成形機の可動距離を短く
できるような絞りしごき加工方法を提供することにあ
る。
In view of the above problems, an object of the present invention is to reduce a crack in a drawing and ironing process without deteriorating the surface properties of a can, and to provide a drawing and ironing method capable of shortening a movable distance of a can body forming machine. To provide.

【0006】[0006]

【課題を解決するための手段】本発明者は、絞りしごき
缶の製造における上記の従来法の欠点を克服するため鋭
意研究を重ねた結果、特に高さと直径の比が1.8以上
の最終形状となる、アルミニウム合金製の円筒状絞りし
ごき缶を製造にするに当り、絞り加工を2段で行い、各
絞り加工における加工後の中子径に対する加工前の管径
の比を所定範囲にそれぞれ収めることにより、その後の
しごき加工を2段で行って、その目的を達成することが
できることを見い出し、この知見に基づき本発明をなす
に至った。
The present inventor has conducted extensive studies to overcome the above-mentioned drawbacks of the conventional method for producing a squeezed ironing can, and as a result, in particular, a final height-diameter ratio of 1.8 or more was obtained. When manufacturing a cylindrical drawn ironing can made of aluminum alloy, which is shaped, the drawing process is performed in two steps, and the ratio of the pipe diameter before processing to the core diameter after processing in each drawing process falls within the predetermined range. It has been found that the objects can be achieved by carrying out the ironing process in two steps by accommodating each of them, and based on this knowledge, the present invention has been accomplished.

【0007】すなわち本発明は、高さと直径との比が
1.8以上の最終形状となるアルミニウム合金製の円筒
状絞りしごき缶の加工工程において、(a)初期絞り中
子径に対する打ち抜き板の外径の比を1.6以上1.8
未満とし、引き続き行う再絞り加工の中子径に対する初
期絞り時の中子径の比を1.3以上1.5未満とした絞
り加工を2段行うこと、(b)絞り加工時の中子外径と
ダイス内径の差を素材板厚の2.1倍以上、2.3倍未
満とすること、そして(c)絞り加工後、素板板厚に対
する初期しごき加工時の缶側壁部の板厚減少率を25%
以上40%未満、引き続き行うしごき加工の缶側壁部の
板厚減少率を40%以上50%未満とした2段のしごき
加工を連続的に行うことにより最終の缶側壁厚さとする
ことを特徴とする絞りしごき缶の製造方法を提供するも
のである。
That is, according to the present invention, in the processing step of a cylindrical drawn ironing can made of an aluminum alloy having a final shape in which the ratio of height to diameter is 1.8 or more, (a) the punching plate with respect to the initial drawn core diameter is used. Outer diameter ratio is 1.6 or more and 1.8
Less than 1 and the ratio of the core diameter at the time of initial drawing to the core diameter of the re-drawing process to be continuously performed is 1.3 or more and less than 1.5 in two stages, and (b) the core at the time of drawing. The difference between the outer diameter and the inner diameter of the die should be 2.1 times or more and less than 2.3 times the material plate thickness, and (c) the plate of the side wall of the can at the time of initial ironing to the plate thickness after drawing. 25% reduction in thickness
The final can side wall thickness is obtained by continuously performing a two-stage ironing process in which the plate thickness reduction rate of the can side wall part of the ironing process is 40% or more and less than 50%. A method for producing a squeezed ironing can.

【0008】本発明に用いられるアルミニウム合金は特
に制限はない。絞りしごき加工用アルミニウム合金の改
良は缶の軽量化のための高強度化とともに生産性を重視
した成形性のよい材料の開発が進められており、このよ
うなものから適宜選択して用いることができる。
The aluminum alloy used in the present invention is not particularly limited. For the improvement of aluminum alloys for drawing and ironing, the development of materials with good formability, which emphasizes productivity as well as higher strength for weight reduction of cans, is underway. it can.

【0009】本発明方法により成形されたアルミニウム
合金製の円筒状缶は図1に示される。高さ(H)と直径
(D)との比H/D≧1.8である。この円筒状缶の2
段の絞り加工の状態を図2(A)、(B)、(C)に示
す。(A)は打抜き板、(B)は初期絞り缶、(C)は
再絞り缶である。絞り加工時の総計の絞り比は最終缶の
寸法と缶底部及び缶側壁部の板厚により決定される。2
段の絞り加工の場合総計の絞り比を最大にするには1段
目の絞り比を最大に設定することが望ましい。しかしこ
の設定では材料の特性値や成形条件の変動により初回絞
り割れが多発する。上記を考慮して初期絞り中子径に対
する打ち抜き板の外径の比D0 /D1 が1.6以上1.
8未満であり、引き続き行う再絞り加工の中子径に対す
る初期絞り時の中子径の比D1 /D2が1.3以上1.
5未満である絞り加工がよい。ここでさらに初期絞り比
を1.65以上1.75未満でかつ再絞り比を1.35
以上1.4未満とすることが好ましい。これによりさら
にしごき成形性を高めるることができる。
A cylindrical can made of an aluminum alloy formed by the method of the present invention is shown in FIG. The ratio of height (H) to diameter (D) is H / D ≧ 1.8. 2 of this cylindrical can
The state of the step drawing is shown in FIGS. 2 (A), (B), and (C). (A) is a punched plate, (B) is an initial drawn can, and (C) is a redrawn can. The total drawing ratio during drawing is determined by the size of the final can and the plate thickness of the can bottom and the can side wall. Two
In the case of step drawing, it is desirable to set the first step draw ratio to the maximum in order to maximize the total draw ratio. However, with this setting, initial drawing cracks frequently occur due to changes in material characteristic values and molding conditions. Considering the above, the ratio D 0 / D 1 of the outer diameter of the punched plate to the diameter of the initial drawing core is 1.6 or more.
It is less than 8, and the ratio D 1 / D 2 of the core diameter at the time of initial drawing to the core diameter of the subsequent redrawing is 1.3 or more.
A drawing process of less than 5 is preferable. Here, the initial drawing ratio is 1.65 or more and less than 1.75 and the redrawing ratio is 1.35.
It is preferably not less than 1.4 and less than 1.4. Thereby, the ironing formability can be further enhanced.

【0010】また、絞り加工時にしごき加工と同様に素
板の板厚を減少させることが望ましいが、絞り加工時に
あまり板厚を減少させるとそのときの成形荷重が増加
し、割れや表面不良を生じるとともに絞りダイスの耐久
時間を著しく悪くする。そのため絞り加工時の中子外径
とダイス内径の差を素材板厚の2.1倍以上に抑える。
また、それが2.3倍以上では、しごき性向上の効果が
無くなる。
Further, it is desirable to reduce the plate thickness of the raw plate during the drawing process as in the case of the ironing process. However, if the plate thickness is excessively reduced during the drawing process, the forming load at that time increases and cracks and surface defects occur. As a result, the durability of the drawing die is significantly deteriorated. Therefore, the difference between the outer diameter of the core and the inner diameter of the die during drawing is suppressed to 2.1 times or more the material plate thickness.
If it is 2.3 times or more, the effect of improving the ironing property is lost.

【0011】上記のように絞り加工時の板厚の増加を抑
える場合、ダイスに加わる負担を低減させる必要があ
る。ダイスに関する条件を図3及び図4に従って説明す
ると、図3は絞り加工の状態を示す断面図、図4は図3
のダイスのRの部分の拡大図である。図中1はダイス、
2はアルミニウム合金板、3は中子である。ダイス1の
中心線を通る断面形状において肩部半径の終了部に当た
る最も小さな位置1aから30秒以上3度未満の逃げ角
αを持つ長さ(L)0.2mm以上1.5mm未満の直
線部分1bを有する絞りダイスを用いることが必要とな
る。さらに逃げ角αが1分以上1度未満であり、0.5
mm以上1.0未満の長さ(L)の直線部分とすること
によりさらに性能の向上が図れる。これら逃げ角を有す
る直線部分があることにより絞り成形体の板厚分布を均
一するとともに板厚がダイス通過後に戻るために生じる
不要な荷重増加を抑制できる。
In order to suppress the increase in plate thickness during drawing as described above, it is necessary to reduce the load applied to the die. The conditions relating to the die will be described with reference to FIGS. 3 and 4. FIG. 3 is a sectional view showing a state of drawing, and FIG.
It is an enlarged view of the R part of the die. In the figure, 1 is a die,
2 is an aluminum alloy plate and 3 is a core. A straight portion having a length (L) of 0.2 mm or more and less than 1.5 mm having a clearance angle α of 30 seconds or more and less than 3 degrees from the smallest position 1a corresponding to the end portion of the shoulder radius in the cross-sectional shape passing through the center line of the die 1. It is necessary to use a drawing die with 1b. Furthermore, the clearance angle α is 1 minute or more and less than 1 degree, and 0.5
The performance can be further improved by forming a straight line portion having a length (L) of not less than 1.0 mm and less than 1.0. The presence of the straight line portions having these clearance angles makes it possible to make the plate thickness distribution of the draw-formed product uniform and to suppress an unnecessary increase in load caused by the plate thickness returning after passing through the die.

【0012】この本発明方法による絞りしごき缶の成形
工程を図5に示す。本発明において絞り加工後、しごき
加工を行うが素板板厚に対する初期しごき加工時の缶側
壁部の板厚減少率を25%以上40%未満、引き続き行
うしごき加工の缶側壁部の板厚減少率を40%以上50
%未満とした2段のしごき加工を連続的に行うことによ
り最終の缶側壁厚さとする。ここで得られた高成形用材
料や潤滑性の高い油の開発が成されると共に成形条件を
適正化することにより2段のしごきにより3段と同等の
成形体が得られる。
FIG. 5 shows the forming process of the drawn and ironed can according to the method of the present invention. In the present invention, ironing is performed after drawing, but the plate thickness reduction rate of the can side wall part during the initial ironing process is 25% or more and less than 40% with respect to the base plate thickness, and the plate thickness reduction of the can side wall part of the subsequent ironing process is performed. 40% or more 50
The final can side wall thickness is obtained by continuously performing a two-step ironing process in which the percentage is less than%. Development of the high molding material and oil of high lubricity obtained here and development of the molding conditions to optimize molding conditions makes it possible to obtain a molded product equivalent to that of three stages by ironing in two stages.

【0013】成形工程における生産性の向上は成形速度
の増加に比例する。ここでの成形速度向上の阻害要因は
成形機の精度にある。精度を高める方法として機械の剛
性を上がるとともに可動距離を短くすることが考えられ
る。そのために現在3段のしごき加工が一般的であるが
これを上記のように絞り加工後、素板板厚に対する初期
しごき加工時の缶側壁部の板厚減少率を25%以上40
%未満、引き続き行うしごき加工の缶側壁部の板厚減少
率を40%以上50%未満とすることによりこれまで割
れを生じてしまうために実施できなかった連続した2段
のしごき加工による缶成形が可能となる。ここで初期し
ごき加工では絞り加工に起因する板厚の不均一の影響が
あるため40%以上の板厚減少率では部分的に割れを生
じる。また逆に25%未満では最終製品の板厚が決まっ
ているために次工程のしごき時の板厚減少率が限界の5
0%を越える。
The improvement in productivity in the molding process is proportional to the increase in molding speed. The impediment to improving the molding speed here is the accuracy of the molding machine. As a method of increasing accuracy, it is possible to increase the rigidity of the machine and shorten the movable distance. For this reason, currently three-stage ironing is generally used, but after drawing this as described above, the plate thickness reduction rate of the can side wall part at the time of initial ironing with respect to the base plate thickness is 25% or more 40% or more.
%, The can forming by continuous two-stage ironing that could not be performed until now because cracking occurred by setting the plate thickness reduction rate of the can side wall part of the ironing process to be continued to 40% or more and less than 50%. Is possible. Here, in the initial ironing process, there is an influence of nonuniformity of the plate thickness due to the drawing process, so that cracks partially occur at a plate thickness reduction rate of 40% or more. On the other hand, if it is less than 25%, the thickness of the final product is fixed, so the reduction rate of the thickness at the time of ironing in the next process is 5
It exceeds 0%.

【0014】[0014]

【実施例】次に本発明を実施例に基づきさらに詳細に説
明する。0.30mm板厚の表1に示す組成のAA30
04合金を用いて表2に示す条件に従い350ml容の
DI缶を作製した。この場合の割れ発生率を同時に表2
に併せて示した。表から明らかなように本発明により作
成した場合にはほとんど割れ不良が生じず、成形機に必
要な可動距離を短くできる。
EXAMPLES The present invention will be described in more detail based on examples. AA30 having a composition shown in Table 1 with a plate thickness of 0.30 mm
A DI can having a capacity of 350 ml was produced according to the conditions shown in Table 2 using 04 alloy. The crack occurrence rate in this case is also shown in Table 2.
Are also shown. As is clear from the table, in the case of the production according to the present invention, the defective crack hardly occurs and the movable distance required for the molding machine can be shortened.

【0015】[0015]

【表1】 [Table 1]

【0016】[0016]

【表2】 [Table 2]

【0017】[0017]

【発明の効果】本発明方法によるDI成形により絞りし
ごき加工時の割れの発生を抑えることができるとともに
しごき工程数を減らすことによりさらに高速度の成形が
可能である。本発明方法によれば絞りしごき缶の生産性
を著しく高めることができる。
INDUSTRIAL APPLICABILITY By the DI molding according to the method of the present invention, it is possible to suppress the occurrence of cracks during drawing and ironing, and it is possible to perform molding at a higher speed by reducing the number of ironing steps. According to the method of the present invention, the productivity of the squeezed ironing can can be remarkably increased.

【図面の簡単な説明】[Brief description of drawings]

【図1】成形した円筒状缶の斜視図である。FIG. 1 is a perspective view of a molded cylindrical can.

【図2】絞り加工した缶の斜視図である。(A)は打抜
き板、(B)は初期絞り缶、(C)は再絞り缶である。
FIG. 2 is a perspective view of a drawn can. (A) is a punched plate, (B) is an initial drawn can, and (C) is a redrawn can.

【図3】絞り加工の状態を示す断面図である。FIG. 3 is a cross-sectional view showing a state of drawing processing.

【図4】図3の絞り加工用に用いられるダイスの部分拡
大断面図である。
4 is a partially enlarged cross-sectional view of a die used for drawing in FIG.

【図5】本発明方法による絞りしごき缶の製造工程図で
ある。
FIG. 5 is a manufacturing process drawing of a squeezed ironing can according to the method of the present invention.

【符号の説明】[Explanation of symbols]

1 ダイス 2 アルミニウム合金板 3 中子 1a ダイスの内径の最小の位置 1b ダイスの直線部分 L ダイスの直線部分の長さ 1 die 2 aluminum alloy plate 3 core 1a minimum position of inner diameter of die 1b linear portion of die L length of linear portion of die

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 高さと直径との比が1.8以上の最終形
状となるアルミニウム合金製の円筒状絞りしごき缶の加
工工程において、(a)初期絞り中子径に対する打ち抜
き板の外径の比を1.6以上1.8未満とし、引き続き
行う再絞り加工の中子径に対する初期絞り時の中子径の
比を1.3以上1.5未満とした絞り加工を2段行うこ
と、(b)絞り加工時の中子外径とダイス内径の差を素
材板厚の2.1倍以上、2.3倍未満とすること、そし
て(c)絞り加工後、素板板厚に対する初期しごき加工
時の缶側壁部の板厚減少率を25%以上40%未満、引
き続き行うしごき加工の缶側壁部の板厚減少率を40%
以上50%未満とした2段のしごき加工を連続的に行う
ことにより最終の缶側壁厚さとすることを特徴とする絞
りしごき缶の製造方法。
1. In a process of processing a cylindrical drawn and ironed can made of an aluminum alloy having a final shape in which the ratio of height to diameter is 1.8 or more, (a) the outer diameter of the punched plate with respect to the initial drawn core diameter. Performing two stages of drawing with a ratio of 1.6 or more and less than 1.8, and a ratio of the core diameter at the time of initial drawing to the core diameter of redrawing that is subsequently performed is 1.3 or more and less than 1.5, (B) The difference between the outer diameter of the core and the inner diameter of the die during drawing is 2.1 times or more and less than 2.3 times the material plate thickness, and (c) after drawing, the initial thickness relative to the plate thickness. Plate thickness reduction rate of can side wall during ironing is 25% or more and less than 40%, and plate thickness reduction rate of can side wall during subsequent ironing is 40%
A method for producing a drawn and ironed can, wherein the final can side wall thickness is obtained by continuously performing a two-step ironing process in which the above is less than 50%.
【請求項2】 高さと直径との比が1.8以上の最終形
状となるアルミニウム合金製の円筒状絞りしごき缶の加
工工程において、ダイスの中心線を通る断面形状におい
て肩部半径の終了部にあたる最も内径の小さな位置から
30秒以上3度未満の逃げ角を持つ0.2mm以上1.
5mm未満の直線部分を有する絞りダイスを用いて絞り
加工を行うことを特徴とする請求項1記載の絞りしごき
缶の製造方法。
2. The end portion of the shoulder radius in the sectional shape passing through the center line of the die in the process of processing a cylindrical drawn and ironed can made of an aluminum alloy having a final shape in which the ratio of height to diameter is 1.8 or more. 0.2mm or more with a clearance angle of 30 seconds or more and less than 3 degrees from the position with the smallest inner diameter corresponding to 1.
The method for producing a drawn and ironed can according to claim 1, wherein drawing is performed using a drawing die having a straight portion of less than 5 mm.
JP3275034A 1991-09-27 1991-09-27 Manufacture of draw-ironed can Pending JPH0584524A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP3275034A JPH0584524A (en) 1991-09-27 1991-09-27 Manufacture of draw-ironed can

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3275034A JPH0584524A (en) 1991-09-27 1991-09-27 Manufacture of draw-ironed can

Publications (1)

Publication Number Publication Date
JPH0584524A true JPH0584524A (en) 1993-04-06

Family

ID=17549951

Family Applications (1)

Application Number Title Priority Date Filing Date
JP3275034A Pending JPH0584524A (en) 1991-09-27 1991-09-27 Manufacture of draw-ironed can

Country Status (1)

Country Link
JP (1) JPH0584524A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104592008A (en) * 2015-01-04 2015-05-06 安徽雪郎生物科技股份有限公司 Preparation method of DL-sodium hydrogen malate
JP2017523920A (en) * 2014-05-30 2017-08-24 アンハイザー−ブッシュ リミテッド ライアビリティ カンパニーAnheuser−Busch,Llc Two-stage ironing tool pack for forming long bottle-shaped metal containers

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017523920A (en) * 2014-05-30 2017-08-24 アンハイザー−ブッシュ リミテッド ライアビリティ カンパニーAnheuser−Busch,Llc Two-stage ironing tool pack for forming long bottle-shaped metal containers
CN104592008A (en) * 2015-01-04 2015-05-06 安徽雪郎生物科技股份有限公司 Preparation method of DL-sodium hydrogen malate

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