JPH0581287B2 - - Google Patents
Info
- Publication number
- JPH0581287B2 JPH0581287B2 JP59278469A JP27846984A JPH0581287B2 JP H0581287 B2 JPH0581287 B2 JP H0581287B2 JP 59278469 A JP59278469 A JP 59278469A JP 27846984 A JP27846984 A JP 27846984A JP H0581287 B2 JPH0581287 B2 JP H0581287B2
- Authority
- JP
- Japan
- Prior art keywords
- absorption tower
- absorbent
- tower
- supplied
- sulfuric acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000010521 absorption reaction Methods 0.000 claims description 78
- 230000002745 absorbent Effects 0.000 claims description 44
- 239000002250 absorbent Substances 0.000 claims description 44
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 42
- 239000007788 liquid Substances 0.000 claims description 32
- 230000003647 oxidation Effects 0.000 claims description 14
- 238000007254 oxidation reaction Methods 0.000 claims description 14
- 238000006477 desulfuration reaction Methods 0.000 claims description 13
- 230000023556 desulfurization Effects 0.000 claims description 13
- 239000002002 slurry Substances 0.000 claims description 13
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 12
- 239000003546 flue gas Substances 0.000 claims description 12
- 239000007789 gas Substances 0.000 claims description 11
- 239000011575 calcium Substances 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 9
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 8
- 229910052791 calcium Inorganic materials 0.000 claims description 8
- 229910052602 gypsum Inorganic materials 0.000 claims description 6
- 239000010440 gypsum Substances 0.000 claims description 6
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 12
- 101100399296 Mus musculus Lime1 gene Proteins 0.000 description 12
- 235000011941 Tilia x europaea Nutrition 0.000 description 12
- 239000004571 lime Substances 0.000 description 12
- 230000000694 effects Effects 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000001276 controlling effect Effects 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Treating Waste Gases (AREA)
- Gas Separation By Absorption (AREA)
Description
【発明の詳細な説明】
[産業上の利用分野]
本発明は、吸収塔2塔シリーズにおいて、排ガ
ス中のSOxを吸収除去し、吸収剤に石灰を使用す
る石灰石膏法排煙脱硫装置の吸収剤供給方法に関
するものである。Detailed Description of the Invention [Industrial Field of Application] The present invention is an absorption tower system for a lime-gypsum flue gas desulfurization system that uses lime as an absorbent and absorbs and removes SOx from flue gas in a series of two absorption towers. The present invention relates to a method for supplying a drug.
[従来の技術]
第2図は吸収塔を2塔備えた方式の排煙脱硫装
置の一例を示すもので、火炉等からの排ガス1が
第一吸収塔2に導かれ、続いて第二吸収塔3に導
かれた後外部に導かれるようになつており、又、
吸収剤(石灰CaCO3)スラリー4が吸収剤流量
調整弁5を介して第二吸収塔3に供給されて前記
排ガス中のSOxを下記式()により吸収分離す
る。[Prior Art] Figure 2 shows an example of a flue gas desulfurization system equipped with two absorption towers, in which exhaust gas 1 from a furnace etc. is guided to a first absorption tower 2, and then to a second absorption tower. After being led to tower 3, it is led to the outside, and
Absorbent (lime CaCO 3 ) slurry 4 is supplied to second absorption tower 3 via absorbent flow rate regulating valve 5, and SOx in the exhaust gas is absorbed and separated according to the following formula ().
CaCO3+SO2+1/2H2O
→CaSO3・1/2H2O+CO2 …()
続いて、第二吸収塔3のブリード液6は、ブリ
ード液流量調整弁7を介して第一吸収塔2に供給
されて、該第一吸収塔2内において前記()式
と同様に排ガス中のSOx分離を行う。 CaCO 3 + SO 2 + 1/2H 2 O → CaSO 3 1/2H 2 O + CO 2 ... () Subsequently, the bleed liquid 6 of the second absorption tower 3 is transferred to the first absorption tower 2 via the bleed liquid flow rate adjustment valve 7. SOx is separated from the exhaust gas in the first absorption tower 2 in the same manner as in formula () above.
上記したように排ガスを吸収分離した第1吸収
塔2ブリード液6は、空気8及び硫酸9が供給さ
れている酸化塔10に送られて反応することによ
り石膏となり、石膏分離装置11により石膏は取
り出される。 The bleed liquid 6 of the first absorption tower 2 which has absorbed and separated the exhaust gas as described above is sent to the oxidation tower 10 to which air 8 and sulfuric acid 9 are supplied and reacts to become gypsum. taken out.
酸化塔での反応は次の()式及び()式に
より石膏になる。 The reaction in the oxidation tower produces gypsum according to the following equations () and ().
CaSO3・1/2H2O+1/2O2+3/2H2O
→CaSO4・2H2O …()
CaCO3+H2SO4+H2O→CaSO4・2H2O
…()
このとき、酸化塔10に対する硫酸9の供給量
は、酸化塔10に設けたPHコントローラ12によ
り酸化塔10内部が常に一定のPHになるように自
動的に調整されている。 CaSO 3・1/2H 2 O+1/2O 2 +3/2H 2 O →CaSO 4・2H 2 O …() CaCO 3 +H 2 SO 4 +H 2 O→CaSO 4・2H 2 O
() At this time, the amount of sulfuric acid 9 supplied to the oxidation tower 10 is automatically adjusted by the PH controller 12 provided in the oxidation tower 10 so that the pH inside the oxidation tower 10 is always constant.
上記したような排煙脱硫装置における吸収剤の
供給は、従来、排ガス1中のSOx量を検出する
SOx検出計a、及び排ガス流量計bを設けて、そ
れらの検出信号により吸収剤スラリー4の必要供
給量を求めて吸収剤流量調整弁5を作動させるこ
とにより、第二吸収塔3への吸収剤スラリー4の
供給量を調整し、また第一吸収塔2に設けたPHコ
ントローラcによりブリード液流量調整弁7を作
動して第一吸収塔2内のPHが一定になるように第
一吸収塔3のブリード液6を第1吸収塔2に供給
するようにしている。 Conventionally, the supply of absorbent in the flue gas desulfurization equipment described above involves detecting the amount of SOx in the flue gas 1.
A SOx detection meter a and an exhaust gas flow meter b are provided, and by determining the required supply amount of absorbent slurry 4 based on their detection signals and operating the absorbent flow rate adjustment valve 5, absorption to the second absorption tower 3 is The supply amount of the agent slurry 4 is adjusted, and the bleed liquid flow rate adjustment valve 7 is operated by the PH controller c provided in the first absorption tower 2, so that the pH in the first absorption tower 2 is kept constant. The bleed liquid 6 from the tower 3 is supplied to the first absorption tower 2.
[発明が解決しようとする問題点]
第一吸収塔2内の吸収剤濃度が高いとSO2吸収
性能が高くなるが、吸収剤の使用量が多くなり、
その結果酸化塔10での反応式()に使用する
硫酸の量が多くなる。逆に第一吸収塔2液中の吸
収剤濃度が低いと使用する吸収剤量や、硫酸の使
用量は少なくなるがSO2吸収性能が低くなるとい
う問題がある。従つて第一吸収塔2内の吸収剤濃
度を適性に且つ一定に維持することが必要であ
る。第一吸収塔2内の吸収剤濃度を一定にするた
めには前記したように第一吸収塔2内の液のPHを
検出してそのPHが一定になるよう第二吸収塔3か
ら第一吸収塔2に供給するブリード液6の流量を
制御する方法がある。[Problems to be solved by the invention] When the absorbent concentration in the first absorption tower 2 is high, the SO 2 absorption performance increases, but the amount of absorbent used increases,
As a result, the amount of sulfuric acid used in reaction formula () in the oxidation tower 10 increases. Conversely, if the absorbent concentration in the second liquid of the first absorption tower is low, the amount of absorbent used and the amount of sulfuric acid used will be reduced, but there is a problem that the SO 2 absorption performance will be low. Therefore, it is necessary to maintain the absorbent concentration within the first absorption tower 2 at an appropriate and constant level. In order to keep the concentration of the absorbent in the first absorption tower 2 constant, as described above, the pH of the liquid in the first absorption tower 2 is detected, and in order to keep the pH constant, from the second absorption tower 3 to the first There is a method of controlling the flow rate of the bleed liquid 6 supplied to the absorption tower 2.
しかし、上記従来方式においては、第一吸収塔
2に対するブリード液6の供給を第一吸収塔2の
PH値が一定になるように制御しているため、石灰
の活性低下により制御不可能になる問題を生じ
る。即ち、第一吸収塔2において塔内未反応石灰
濃度とPHはある比例関係にあるが、排ガス1中に
はSOx以外に煤塵、塩素、ふつ素等の不純物が混
在しており、これらの不純物が石灰と反応したり
石灰の溶解を悪化させる等により、石灰の濃度と
PHの比例関係が崩れてアンバランスとなり、従つ
て第一吸収塔2のブリード液のPHが一定になるよ
うに第一吸収塔ブリード液6を第一吸収塔2に供
給する方式ではブリード液6の流量が変動するこ
とになつて、次のような問題を生じる。 酸化
塔10へ入る液中の未反応の石灰が多くなり、
硫酸9の使用量が増加して不経済となる。 However, in the above conventional method, the supply of the bleed liquid 6 to the first absorption tower 2 is
Since the pH value is controlled to be constant, the problem arises that it becomes uncontrollable due to a decrease in the activity of lime. That is, in the first absorption tower 2, there is a certain proportional relationship between the concentration of unreacted lime in the tower and the PH, but in addition to SOx, the exhaust gas 1 contains impurities such as soot dust, chlorine, and fluorine, and these impurities The concentration of lime may be lowered by reacting with lime or worsening lime dissolution.
The proportional relationship of PH collapses and becomes unbalanced. Therefore, in a system in which the first absorption tower bleed liquid 6 is supplied to the first absorption tower 2 so that the pH of the bleed liquid in the first absorption tower 2 is constant, the bleed liquid 6 is As a result, the following problems occur. Unreacted lime in the liquid entering the oxidation tower 10 increases,
The amount of sulfuric acid 9 used increases, making it uneconomical.
第二吸収塔3内の石灰濃度が薄くなつたり濃
くなつたりして安定しない。 The lime concentration in the second absorption tower 3 becomes thinner or thicker and becomes unstable.
本発明は、上記従来の問題点に着目してなした
もので、第一及び第二吸収塔内の吸収剤濃度を安
定化させて効果的な脱硫を行わせることを目的と
している。 The present invention has been made in view of the above-mentioned conventional problems, and aims to stabilize the absorbent concentration in the first and second absorption towers to perform effective desulfurization.
[問題点を解決するための手段]
本発明は、上記技術的課題を解決しようとして
なしたもので、吸収塔を2塔備え、SOxを含む排
ガスを第一吸収塔から第二吸収塔に導き、また吸
収剤スラリーを第二吸収塔から第一吸収塔に導い
て前記排ガス中のSOx分離を行つた後、第一吸収
塔のブリート液を硫酸が供給されている酸化塔に
導いて石膏を取り出す排煙脱硫装置の吸収剤供給
方法において、第一吸収塔に対し、酸化塔に供給
される硫酸の供給流量の設定値を設けて該硫酸の
供給流量が一定になるように第二吸収塔のブリー
ド液を供給し、第二吸収塔に対し、前記第一吸収
塔に供給するブリード液中のカルシウム全量に見
合つた吸収剤スラリーを供給することを特徴とす
る排煙脱硫装置の吸収剤供給方法、に係るもので
ある。[Means for Solving the Problems] The present invention was made in an attempt to solve the above-mentioned technical problems, and includes two absorption towers, in which exhaust gas containing SOx is guided from the first absorption tower to the second absorption tower. In addition, the absorbent slurry is led from the second absorption tower to the first absorption tower to separate SOx from the exhaust gas, and then the bleat liquid from the first absorption tower is led to the oxidation tower to which sulfuric acid is supplied to remove gypsum. In a method for supplying an absorbent to a flue gas desulfurization equipment to be extracted, a set value for the supply flow rate of sulfuric acid supplied to the oxidation tower is set for the first absorption tower, and the second absorption tower is set so that the supply flow rate of the sulfuric acid is constant. A bleed liquid is supplied to the second absorption tower, and an absorbent slurry corresponding to the total amount of calcium in the bleed liquid supplied to the first absorption tower is supplied to the second absorption tower. This relates to a method.
[作用]
従つて、本発明によると、第一吸収塔及び第二
吸収塔内の吸収剤濃度が良好な状態で安定化し、
効果的な排煙脱硫が可能となる。[Operation] Therefore, according to the present invention, the absorbent concentration in the first absorption tower and the second absorption tower is stabilized in a good state,
Effective flue gas desulfurization becomes possible.
[実施例]
以下本発明の実施例を図面を参照しつつ説明す
る。[Examples] Examples of the present invention will be described below with reference to the drawings.
第1図は、前記第2図の排煙脱硫装置に適用し
た本発明の吸収剤供給方法の一例を示すもので、
図中第2図と同一符号を付したものは同一物を示
している。 FIG. 1 shows an example of the absorbent supply method of the present invention applied to the flue gas desulfurization equipment shown in FIG.
In the figure, the same reference numerals as in FIG. 2 indicate the same parts.
第一吸収塔2内の石灰は活性低下を生じ、この
ために石灰の過剰分とPHとが一定の関係を保持し
なくなるため、第二吸収塔2内の吸収剤濃度は単
純にPHで表わすことができない。 The activity of the lime in the first absorption tower 2 decreases, and as a result, the excess lime content and PH no longer maintain a constant relationship, so the absorbent concentration in the second absorption tower 2 is simply expressed as PH. I can't.
しかし、反応式()は、第一吸収塔2内の液
の吸収剤(石灰CaCO3)を硫酸と反応させて石
膏を作つているので、この時使用した硫酸量が第
一吸収塔2の吸収剤量又は吸収剤濃度を表わして
いることを利用して、第一吸収塔2内の液の吸収
剤濃度を制御する。従つて第一吸収塔2に対する
第二吸収塔3のブリード液6の供給は、酸化塔1
0に供給する硫酸9の量が一定になるようにブリ
ード液流量調整弁7を調整する硫酸流量調節計1
3によつて行う。 However, in reaction formula (), gypsum is produced by reacting the liquid absorbent (lime CaCO 3 ) in the first absorption tower 2 with sulfuric acid, so the amount of sulfuric acid used at this time is The absorbent concentration of the liquid in the first absorption tower 2 is controlled by utilizing the fact that it represents the amount of absorbent or the concentration of absorbent. Therefore, the bleed liquid 6 of the second absorption tower 3 is supplied to the first absorption tower 2 from the oxidation tower 1.
A sulfuric acid flow rate controller 1 adjusts a bleed liquid flow rate adjustment valve 7 so that the amount of sulfuric acid 9 supplied to the sulfuric acid 9 becomes constant.
Perform according to 3.
又、第二吸収塔3への吸収剤スラリー4の供給
は第二吸収塔3からのブリード液中のカルシウム
Ca全量(反応済+未反応のカルシウム量)に見
合つた量の吸収剤スラリー4を供給して第二吸収
塔3内の吸収剤濃度を一定に保持するようにして
いる。即ち、第二吸収塔3に供給する吸収剤スラ
リー4及び水14の流量を検出する流量計15及
び16を設け、該流量計15,16からの流量信
号を制御装置17に入力して演算し、該制御装置
17の出力により前記第二吸収塔3内のカルシウ
ム濃度が一定になるように吸収剤流量調整弁5を
調整する。即ち、第二吸収塔3から第一吸収塔2
に供給されるブリード液6の流量を検出する流量
計18を設け、該流量計18の流量信号を前記制
御装置17に入力する。上記において、第二吸収
塔3内の吸収剤濃度は一定に保たれているので、
ブリード液6の流量を流量計18にて検出するこ
とにより第二吸収塔3から流出するカルシウム全
量を想定することができるので、この量に見合つ
た吸収剤スラリー4を供給して第二吸収塔3内の
吸収剤濃度を一定に保持するよう制御装置17に
より制御することができる。 In addition, the supply of the absorbent slurry 4 to the second absorption tower 3 is performed using calcium in the bleed liquid from the second absorption tower 3.
The absorbent slurry 4 is supplied in an amount commensurate with the total amount of Ca (reacted + unreacted calcium amount) to keep the absorbent concentration in the second absorption tower 3 constant. That is, flow meters 15 and 16 are provided to detect the flow rates of the absorbent slurry 4 and water 14 supplied to the second absorption tower 3, and the flow signals from the flow meters 15 and 16 are input to the control device 17 and calculated. According to the output of the control device 17, the absorbent flow rate regulating valve 5 is adjusted so that the calcium concentration in the second absorption tower 3 becomes constant. That is, from the second absorption tower 3 to the first absorption tower 2
A flow meter 18 is provided to detect the flow rate of the bleed liquid 6 supplied to the control device 17, and a flow signal from the flow meter 18 is input to the control device 17. In the above, since the absorbent concentration in the second absorption tower 3 is kept constant,
By detecting the flow rate of the bleed liquid 6 with the flow meter 18, it is possible to estimate the total amount of calcium flowing out from the second absorption tower 3. Therefore, absorbent slurry 4 corresponding to this amount is supplied to the second absorption tower. The absorbent concentration in the absorbent 3 can be controlled by the control device 17 to be kept constant.
上記によれば、第一吸収塔2内に対し、酸化塔
10に供給される硫酸9の量が一定になるように
ブリード液調節計13及びブリード液流量調整弁
7を介してブリード液6が供給されるようになつ
ているので、第一吸収塔2内の吸収剤濃度は良好
な状態に安定させられることになる。 According to the above, the bleed liquid 6 is supplied to the first absorption tower 2 via the bleed liquid regulator 13 and the bleed liquid flow rate adjustment valve 7 so that the amount of sulfuric acid 9 supplied to the oxidation tower 10 is constant. Since the absorbent is supplied, the absorbent concentration within the first absorption tower 2 is stabilized in a good state.
又、第二吸収塔3から第一吸収塔2に供給され
るブリード液6の流量を検出することにより、第
二吸収塔3から流出するカルシウム全量を想定
し、その量に見合つた吸収剤スラリー4を第二吸
収塔3に供給するようにしているので、第二吸収
塔3内のカルシウム濃度も一定に保持させること
ができ、よつて効果的な排煙脱硫を行うことがで
きる。また硫酸使用量を一定にすることに限定さ
れるものではなく脱硫性能により硫酸使用量の設
定値を変化して制御することも本発明に含まれる
ものである。 In addition, by detecting the flow rate of the bleed liquid 6 supplied from the second absorption tower 3 to the first absorption tower 2, the total amount of calcium flowing out from the second absorption tower 3 is estimated, and the absorbent slurry is adjusted to match that amount. 4 is supplied to the second absorption tower 3, the calcium concentration within the second absorption tower 3 can also be kept constant, and thus effective flue gas desulfurization can be performed. Further, the present invention is not limited to keeping the amount of sulfuric acid used constant, but also includes changing and controlling the set value of the amount of sulfuric acid used depending on the desulfurization performance.
[発明の効果]
上記したように、本発明の排煙脱硫装置の吸収
剤供給方法によれば、第一吸収塔及び第二吸収塔
内の吸収剤濃度を良好な状態に安定させることが
できるので、効果的な脱硫を確実に行つて信頼性
を向上させることができると共に、必要以上の無
駄な吸収剤及び硫酸等の消費を防止して運転コス
トの低減を図ることができる、等の優れた効果を
奏し得る。[Effects of the Invention] As described above, according to the absorbent supply method of the flue gas desulfurization apparatus of the present invention, the absorbent concentration in the first absorption tower and the second absorption tower can be stabilized in a good state. Therefore, it is possible to ensure effective desulfurization and improve reliability, and it is also possible to reduce operating costs by preventing unnecessary consumption of absorbent and sulfuric acid, etc. It can have a great effect.
第1図は本発明の方法を実施する装置の一例を
示す説明図、第2図は従来方式の一例を示す説明
図である。
1は排ガス、2は第一吸収塔、3は第二吸収
塔、4は吸収剤スラリー、5は吸収剤流量調整
弁、6はブリード液、7はブリード液流量調整
弁、9は硫酸、10は酸化塔、12はPHコントロ
ーラ、13はブリード液調節計、15,16は流
量計、17は制御装置、18は流量計を示す。
FIG. 1 is an explanatory diagram showing an example of an apparatus for implementing the method of the present invention, and FIG. 2 is an explanatory diagram showing an example of a conventional method. 1 is an exhaust gas, 2 is a first absorption tower, 3 is a second absorption tower, 4 is an absorbent slurry, 5 is an absorbent flow rate adjustment valve, 6 is a bleed liquid, 7 is a bleed liquid flow rate adjustment valve, 9 is sulfuric acid, 10 12 is an oxidation tower, 12 is a PH controller, 13 is a bleed liquid controller, 15 and 16 are flow meters, 17 is a control device, and 18 is a flow meter.
Claims (1)
吸収塔から第二吸収塔に導き、また吸収剤スラリ
ーを第二吸収塔から第一吸収塔に導いて前記排ガ
ス中のSOx分離を行つた後、第一吸収塔のブリー
ト液を硫酸が供給されている酸化塔に導いて石膏
を取り出す排煙脱硫装置の吸収剤供給方法におい
て、第一吸収塔に対し、酸化塔に供給される硫酸
の供給流量の設定値を設けて該硫酸の供給流量が
一定になるように第二吸収塔のブリード液を供給
し、第二吸収塔に対し、前記第一吸収塔に供給す
るブリード液中のカルシウム全量に見合つた吸収
剤スラリーを供給することを特徴とする排煙脱硫
装置の吸収剤供給方法。1 Equipped with two absorption towers, the exhaust gas containing SOx is led from the first absorption tower to the second absorption tower, and the absorbent slurry is led from the second absorption tower to the first absorption tower to separate SOx in the exhaust gas. In the absorbent supply method for flue gas desulfurization equipment, in which the bleat liquid from the first absorption tower is led to the oxidation tower to which sulfuric acid is supplied to take out the gypsum, the sulfuric acid supplied to the oxidation tower is The bleed liquid of the second absorption tower is supplied so that the supply flow rate of the sulfuric acid is constant by setting the set value of the supply flow rate of A method for supplying an absorbent to a flue gas desulfurization equipment, characterized by supplying an absorbent slurry corresponding to the total amount of calcium.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP59278469A JPS61157330A (en) | 1984-12-28 | 1984-12-28 | Method for supplying absorbent of waste gas desulfurization apparatus |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP59278469A JPS61157330A (en) | 1984-12-28 | 1984-12-28 | Method for supplying absorbent of waste gas desulfurization apparatus |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS61157330A JPS61157330A (en) | 1986-07-17 |
JPH0581287B2 true JPH0581287B2 (en) | 1993-11-12 |
Family
ID=17597760
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP59278469A Granted JPS61157330A (en) | 1984-12-28 | 1984-12-28 | Method for supplying absorbent of waste gas desulfurization apparatus |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS61157330A (en) |
-
1984
- 1984-12-28 JP JP59278469A patent/JPS61157330A/en active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS61157330A (en) | 1986-07-17 |
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