JPH0559082B2 - - Google Patents
Info
- Publication number
- JPH0559082B2 JPH0559082B2 JP57213061A JP21306182A JPH0559082B2 JP H0559082 B2 JPH0559082 B2 JP H0559082B2 JP 57213061 A JP57213061 A JP 57213061A JP 21306182 A JP21306182 A JP 21306182A JP H0559082 B2 JPH0559082 B2 JP H0559082B2
- Authority
- JP
- Japan
- Prior art keywords
- parts
- mat
- pine
- stabilizer
- premix
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003381 stabilizer Substances 0.000 claims description 16
- 239000003205 fragrance Substances 0.000 claims description 6
- 239000000049 pigment Substances 0.000 claims description 3
- 241000190070 Sarracenia purpurea Species 0.000 claims description 2
- 239000000654 additive Substances 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims description 2
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 18
- 235000011613 Pinus brutia Nutrition 0.000 description 18
- 241000018646 Pinus brutia Species 0.000 description 18
- 239000000203 mixture Substances 0.000 description 10
- 238000009472 formulation Methods 0.000 description 9
- XUDJOVURIXHNRW-UHFFFAOYSA-N 1-amino-4-anilinoanthracene-9,10-dione Chemical compound C1=2C(=O)C3=CC=CC=C3C(=O)C=2C(N)=CC=C1NC1=CC=CC=C1 XUDJOVURIXHNRW-UHFFFAOYSA-N 0.000 description 7
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 7
- 241000255925 Diptera Species 0.000 description 7
- 239000000077 insect repellent Substances 0.000 description 7
- 239000004480 active ingredient Substances 0.000 description 6
- 239000003350 kerosene Substances 0.000 description 5
- -1 2-methyl-3- (2-propynyl)-4-oxocyclopent-2 -enyl Chemical group 0.000 description 4
- 241000238631 Hexapoda Species 0.000 description 3
- CMBYOWLFQAFZCP-UHFFFAOYSA-N Hexyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCCCCC CMBYOWLFQAFZCP-UHFFFAOYSA-N 0.000 description 3
- 229940100463 hexyl laurate Drugs 0.000 description 3
- 238000005470 impregnation Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- XLOPRKKSAJMMEW-SFYZADRCSA-M (R,R)-chrysanthemate Chemical compound CC(C)=C[C@@H]1[C@@H](C([O-])=O)C1(C)C XLOPRKKSAJMMEW-SFYZADRCSA-M 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 238000007865 diluting Methods 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- OCQDPIXQTSYZJL-UHFFFAOYSA-N 1,4-bis(butylamino)anthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(NCCCC)=CC=C2NCCCC OCQDPIXQTSYZJL-UHFFFAOYSA-N 0.000 description 1
- BLFZMXOCPASACY-UHFFFAOYSA-N 1,4-bis(propan-2-ylamino)anthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(NC(C)C)=CC=C2NC(C)C BLFZMXOCPASACY-UHFFFAOYSA-N 0.000 description 1
- FBMQNRKSAWNXBT-UHFFFAOYSA-N 1,4-diaminoanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(N)=CC=C2N FBMQNRKSAWNXBT-UHFFFAOYSA-N 0.000 description 1
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 1
- DKCPKDPYUFEZCP-UHFFFAOYSA-N 2,6-di-tert-butylphenol Chemical compound CC(C)(C)C1=CC=CC(C(C)(C)C)=C1O DKCPKDPYUFEZCP-UHFFFAOYSA-N 0.000 description 1
- PFANXOISJYKQRP-UHFFFAOYSA-N 2-tert-butyl-4-[1-(5-tert-butyl-4-hydroxy-2-methylphenyl)butyl]-5-methylphenol Chemical compound C=1C(C(C)(C)C)=C(O)C=C(C)C=1C(CCC)C1=CC(C(C)(C)C)=C(O)C=C1C PFANXOISJYKQRP-UHFFFAOYSA-N 0.000 description 1
- GPNYZBKIGXGYNU-UHFFFAOYSA-N 2-tert-butyl-6-[(3-tert-butyl-5-ethyl-2-hydroxyphenyl)methyl]-4-ethylphenol Chemical compound CC(C)(C)C1=CC(CC)=CC(CC=2C(=C(C=C(CC)C=2)C(C)(C)C)O)=C1O GPNYZBKIGXGYNU-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000011094 fiberboard Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000003958 fumigation Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/18—Vapour or smoke emitting compositions with delayed or sustained release
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
- A01M13/00—Fumigators; Apparatus for distributing gases
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/34—Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Environmental Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Toxicology (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Dentistry (AREA)
- Insects & Arthropods (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Catching Or Destruction (AREA)
Description
本発明は、電気マツトに関し、さらに詳しく
は、厚さ１〜1.25mm、表面積５〜15cm2の繊維板製
のマツトに、活性成分として２−メチル−３−
（２−プロピニル）−４−オキソシクロペント−２
−エニル クリサンテメートを１マツトあたり60
〜160mg、安定剤および色素、あるいはこれらと
香料および／または添加剤からなるマツト用プレ
ミツクスが、１マツト当り80〜300mg含浸されて
いるハエ取り用高薬量電気マツトに関する。
電気蚊取器に代表されるいわゆる電気マツト
は、蚊取線香、エアゾール剤などと同様に、一般
家庭で広く用いられているが、このような電気マ
ツトは、主として蚊の駆除に用いられているに過
ぎない。
近年、畜舎、鶏舎、ゴミ処理場等では、多量の
ハエが発生し周辺家庭では、飛翔するハエの継続
的、有効な駆除方法がとくに望まれている。
本発明者らは、このような状況に鑑み、電気マ
ツト方式でのハエの駆除方法につき種々検討を加
えた結果、前述のような本発明の高薬量電気マツ
トを市販の電気蚊取用ヒーターを用いて140℃〜
180℃に加熱することにより、活性成分が充分に
揮散し、かつ長時間気中濃度を有効な範囲に維持
することができ、ハエを駆除できることを見出し
本発明を完成した。
本発明において、活性成分として用いられる２
−メチル−３−（２−プロピニル）−４−オキソシ
クロペント−２−エニル クリサンテメートとし
ては（RS）−２−メチル−３−（２−プロピニル）
−４−オキソシクロペント−２−エニル（1RS）
−シス・トランス−クリサンテメート（以下、Ｓ
−4060と記す）およびその光学または立体異性
体、あるいはその混合物である（RS）−２−メチ
ル−３−（２−プロピニル）−４−オキソシクロペ
ント−２−エニル（1R）−シス・トランス−クリ
サンテメート（以下、Ｓ−4068と記す）、(S)−２
−メチル−３−（２−プロピニル）−４−オキソシ
クロペント−２−エニル（1R）−トランス−クリ
サンテメート（以下、Ｓ−4068−ｄ−Ｔと記す）
などのプラレスリン類が挙げられ、その１マツト
当りの含浸量は60mg〜160mgである。
また、安定剤としては２，2′−メチレンビス
（６−ｔ−ブチル−４−メチルフエノール）（以
下、安定剤−と記す）、２，2′−メチレンビス
（６−ｔ−ブチル−４−エチルフエノール）（以
下、安定剤−と記す）、４，4′−メチレンビス
（２，６−ジ−ｔ−ブチルフエノール（以下、安
定剤−と記す）、４，4′−ブチリデンビス（６
−ｔ−ブチル−３−メチルフエノール）（以下、
安定剤−と記す）、４，4′−チオビス６−ｔ−
ブチル−３−メチルフエノール（以下、安定剤−
と記す）等のフエノール系酸化防止剤が挙げら
れる。
これらの活性成分および安定剤に、アリルアミ
ノアントラキノン、１，４−ジイソプロピルアミ
ノアントラキノン、１，４−ジアミノアントラキ
ノン、１，４−ジブチルアミノアントラキノン、
１−アミノ−４−アニリノアントラキノン等の色
素、あるいは、これらにマツト用の香料および／
または、低粘化と含浸を容易ならしめるために添
加剤として少量のミリスチン酸イソプロピル、パ
ルミチン酸イソプロピル、ラウリル酸ヘキシル
等、脂肪酸エステル、ケロシン等の有機溶剤を必
要に応じ添加することによりマツト用プレミツク
スを調製する。
このマツト用プレミツクスを１mm〜1.25mmの厚
さで、５cm2〜15cm2表面積を有するパルプ等の繊維
板製のマツトに含浸することにより本発明の高薬
量電気マツトを得ることができる。
この時、必要に応じ、マツト用プレミツクスを
さらに、上記のような脂肪酸エステル、ケロシン
などの有機溶剤で希釈した後、マツトに含浸させ
てもよい。
次に本発明の高薬量電気マツトにつき、その処
方例およびこれを用いての有効成分の揮散率と害
虫駆除効果を示す。
なお、以下の処方例において、部は重量部を表
わす。また、参考処方例や試験例におけるピナミ
ンフオルテとは（RS）−３−アリル−２−メチル
−４−オキソシクロペント−２−エニル（1R）−
シス・トランス−クリサンテメートを意味する。
参考処方例 １
ピナミンフオルテ80部、安定剤−10部、１−
アミノ−４−アニリノアントラキノン0.5部およ
びミリスチン酸イソプロピル9.5部からなるマツ
ト用プレミツクス150mgを厚さ1.14mm、表面積7.7
cm2のパルプ板製のマツトに含浸させることによ
り、マツトが得られる。
処方例 １
Ｓ−4068、Ｓ−4068FまたはＳ−4068−ｄ−
T40部、安定剤−5.0部、１−アミノ−４−ア
ニリノアントラキノン0.3部およびミリスチン酸
イソプロピル54.7部からなるマツト用プレミツク
ス150mgを上記と同様のマツトに含浸させること
により、夫々の本発明のマツトが得られる。
処方例 ２
処方例１のプレミツクスにおいて、安定剤−
の量を10部に、ミリスチン酸イソプロピルの量を
49.7部に変える他は処方例１と全く同様の操作を
行うことにより、夫々の本発明のマツトが得られ
る。
処方例 ３
Ｓ−4068、Ｓ−4068FまたはＳ−4068−ｄ−
T40部、安定剤7.0部、１−アミノ−４−アニ
リノアントラキノン0.3部、フラグランスRS−
7836（香料：高砂香料工業社品）5.0部およびミリ
スチン酸イソプロピル47.7部からなるマツト用プ
レミツクス200mgを上記と同様のマツトに含浸さ
せることにより、夫々の本発明のマツトが得られ
る。
処方例 ４
Ｓ−4068、Ｓ−4068FまたはＳ−4068−ｄ−
T80部、安定剤−10部、１−アミノ−４−アニ
リノアントラキノン0.3部およびパルミチン酸イ
ソプロピル9.7部からなるマツト用プレミツクス
をミリスチン酸イソプロピルで２倍に希釈した液
150mgを、上記と同様のマツトに含浸させること
により、夫々の本発明のマツトが得られる。
処方例 ５
処方例４のマツト用プレミツクスをケロシンで
1.25倍に希釈した液100mgを上記と同様のマツト
に含浸させることにより夫々の本発明のマツトが
得られる。
処方例 ６
Ｓ−4068、Ｓ−4068FまたはＳ−4068−ｄ−
T40部、クリスロンフオルテ10部、安定剤−10
部、１−アミノ−４−アニリノアントラキノン
0.5部およびラウリル酸ヘキシル39.5部からなる
マツト用プレミツクス150mgを厚さ1.14mm、表面
積7.7cm2のパルプ板製のマツトに含浸させること
により、夫々の本発明のマツトが得られる。
処方例 ７
Ｓ−4068、Ｓ−4068FまたはＳ−4068−ｄ−
T70部、Ｓ−2703F10部、安定剤−10部、１−
アミノ−４−アニリノアントラキノン0.5部およ
びミリスチン酸イソプロピル9.5部からなるマツ
ト用プレミツクスをケロシンで２倍に希釈した液
300mgを厚さ1.14mm、表面積15cm2のパルプ板製の
マツトに含浸させることにより、夫々の本発明の
マツトが得られる。
試験例 １
ピナミンフオルテおよびＳ−4068Fを各々参考
処方例１および処方例１に準じてマツト用プレミ
ツクスを調製した。次いで、各々のプレミツク
ス、またはそのケロシン希釈液を、第１表に示す
活性成分含浸量になるように、厚さ1.14mm、表面
積7.7cm2のパルプ板製のマツト（以下、マツトＡ
と記す）および厚さ2.8mm、表面積7.7cm2の市販の
マツト（以下、マツトＢと記す）に含浸させ、
各々のマツトを市販の電気蚊取用ヒーターを用い
て160℃に加熱し、揮散してくる活性成分を経時
的に、シリカゲルを充填したガラス製トラツプ装
置で捕集し、その捕集量を調査し、含浸量に対す
る揮散率を求めた。
結果を第１表に示す。
The present invention relates to an electric mat, and more particularly to a mat made of fibreboard, having a thickness of 1 to 1.25 mm and a surface area of 5 to 15 cm 2 , containing 2-methyl-3-
(2-propynyl)-4-oxocyclopent-2
-enyl chrysanthemate 60 per mat
The present invention relates to a high-dose electric mat for fly traps in which each mat is impregnated with 80 to 300 mg of a premix for mats consisting of a stabilizer and a pigment, or a fragrance and/or an additive. So-called electric mosquito repellents, typified by electric mosquito repellents, are widely used in households, as are mosquito coils, aerosols, etc., but such electric mattresses are mainly used to exterminate mosquitoes. It's nothing more than that. BACKGROUND ART In recent years, large numbers of flies have been generated in livestock barns, poultry houses, garbage disposal sites, etc., and a continuous and effective method for exterminating flying flies has been particularly desired in surrounding households. In view of this situation, the present inventors conducted various studies on a method for exterminating flies using an electric mosquito repellent method, and as a result, the present inventors decided to use the high-dose electric mosquito repellent of the present invention as described above to replace a commercially available electric mosquito repellent heater. 140℃~
The present invention was completed based on the discovery that by heating to 180°C, the active ingredient can be sufficiently volatilized and the concentration in the air can be maintained within an effective range for a long period of time, thereby exterminating flies. In the present invention, 2 used as an active ingredient
-Methyl-3-(2-propynyl)-4-oxocyclopent-2-enyl As chrysanthemate, (RS)-2-methyl-3-(2-propynyl)
-4-oxocyclopent-2-enyl (1RS)
-cis-trans-chrysanthemate (hereinafter referred to as S
-4060) and its optical or stereoisomers, or mixtures thereof (RS)-2-methyl-3-(2-propynyl)-4-oxocyclopent-2-enyl (1R)-cis/trans -Chrysanthemate (hereinafter referred to as S-4068), (S)-2
-Methyl-3-(2-propynyl)-4-oxocyclopent-2-enyl (1R)-trans-chrysanthemate (hereinafter referred to as S-4068-d-T)
Prarethrins such as these are mentioned, and the amount of impregnation per mat is 60 mg to 160 mg. In addition, as stabilizers, 2,2'-methylenebis(6-t-butyl-4-methylphenol) (hereinafter referred to as stabilizer), 2,2'-methylenebis(6-t-butyl-4-ethyl phenol) (hereinafter referred to as stabilizer), 4,4'-methylenebis(2,6-di-t-butylphenol (hereinafter referred to as stabilizer)), 4,4'-butylidenebis(6
-t-butyl-3-methylphenol) (hereinafter referred to as
stabilizer), 4,4'-thiobis6-t-
Butyl-3-methylphenol (hereinafter referred to as stabilizer)
Examples include phenolic antioxidants such as These active ingredients and stabilizers include allylaminoanthraquinone, 1,4-diisopropylaminoanthraquinone, 1,4-diaminoanthraquinone, 1,4-dibutylaminoanthraquinone,
Pigments such as 1-amino-4-anilinoanthraquinone, or fragrances and/or fragrances for pine.
Alternatively, in order to reduce viscosity and facilitate impregnation, a small amount of isopropyl myristate, isopropyl palmitate, hexyl laurate, etc., fatty acid esters, organic solvents such as kerosene, etc. can be added as necessary to make premixes for pine. Prepare. The high-dose electric mat of the present invention can be obtained by impregnating a mat made of fiberboard such as pulp with a thickness of 1 mm to 1.25 mm and a surface area of 5 cm 2 to 15 cm 2 with this mat premix. At this time, if necessary, the premix for pine may be further diluted with an organic solvent such as the above fatty acid ester or kerosene, and then impregnated into the pine. Next, examples of the formulation of the high-dose electric mat of the present invention, as well as the volatilization rate of the active ingredient and pest control effect using the same, will be shown. In addition, in the following prescription examples, parts represent parts by weight. In addition, what is pinamine forte in reference formulation examples and test examples? (RS)-3-allyl-2-methyl-4-oxocyclopent-2-enyl (1R)-
means cis-trans-chrysanthemate. Reference prescription example 1 Pinamin Fuorte 80 parts, stabilizer -10 parts, 1-
150 mg of a pine premix consisting of 0.5 parts of amino-4-anilinoanthraquinone and 9.5 parts of isopropyl myristate was applied to a thickness of 1.14 mm and a surface area of 7.7 mm.
A mat is obtained by impregnating a cm 2 pulp board mat. Prescription example 1 S-4068, S-4068F or S-4068-d-
By impregnating 150 mg of a pine premix consisting of 40 parts of T, 5.0 parts of stabilizer, 0.3 parts of 1-amino-4-anilinoanthraquinone and 54.7 parts of isopropyl myristate into the same mat as above, each of the pine of the present invention was prepared. is obtained. Formulation Example 2 In the premix of Formulation Example 1, stabilizer -
and the amount of isopropyl myristate to 10 parts.
Each of the mats of the present invention can be obtained by performing exactly the same operation as in Formulation Example 1 except that the amount is changed to 49.7 parts. Prescription example 3 S-4068, S-4068F or S-4068-d-
40 parts of T, 7.0 parts of stabilizer, 0.3 parts of 1-amino-4-anilinoanthraquinone, Fragrance RS-
Each pine of the present invention is obtained by impregnating the same pine as described above with 200 mg of a pine premix consisting of 5.0 parts of 7836 (Fragrance: Takasago International Co., Ltd.) and 47.7 parts of isopropyl myristate. Prescription example 4 S-4068, S-4068F or S-4068-d-
A solution prepared by diluting a pine premix consisting of 80 parts of T, 10 parts of stabilizer, 0.3 parts of 1-amino-4-anilinoanthraquinone, and 9.7 parts of isopropyl palmitate with isopropyl myristate.
Each mat of the present invention is obtained by impregnating 150 mg into the same mat as above. Prescription example 5 Premix for pine from Prescription example 4 with kerosene.
Each mat of the present invention can be obtained by impregnating the same mat as above with 100 mg of the solution diluted 1.25 times. Prescription example 6 S-4068, S-4068F or S-4068-d-
T40 parts, Crylonfuorte 10 parts, stabilizer -10
part, 1-amino-4-anilinoanthraquinone
Each of the inventive mats is obtained by impregnating a pulp board mat with a thickness of 1.14 mm and a surface area of 7.7 cm 2 with 150 mg of a pine premix consisting of 0.5 parts of hexyl laurate and 39.5 parts of hexyl laurate. Prescription example 7 S-4068, S-4068F or S-4068-d-
70 parts of T, 10 parts of S-2703F, 10 parts of stabilizer, 1-
A solution prepared by diluting a pine premix consisting of 0.5 parts of amino-4-anilinoanthraquinone and 9.5 parts of isopropyl myristate with kerosene.
Each mat of the invention is obtained by impregnating 300 mg into a mat made of pulp board with a thickness of 1.14 mm and a surface area of 15 cm 2 . Test Example 1 Premixes for pine were prepared using Pinamin Forte and S-4068F according to Reference Formulation Example 1 and Formulation Example 1, respectively. Next, each premix or its diluted kerosene solution was placed on a pulp board mat ( hereinafter referred to as mat
) and a commercially available pine with a thickness of 2.8 mm and a surface area of 7.7 cm 2 (hereinafter referred to as pine B),
Each pine was heated to 160℃ using a commercially available electric mosquito repellent heater, and the volatilized active ingredients were collected over time using a glass trap device filled with silica gel, and the amount collected was investigated. Then, the volatilization rate with respect to the amount of impregnation was determined. The results are shown in Table 1.
【表】
試験例 ２
参考処方例１および処方例１にて得られたピナ
ミンフオルテおよびＳ−4068Fの第２表に示す活
性成分量を含有するマツトを、各々市販の電気蚊
取用ヒーターで15分間予熱した後、あらかじめハ
エ20頭を放つてある0.34m3のガラス箱内に入れ、
継続加熱燻蒸して、ノツクダウン虫数を数えて
KT50（分）値を求めた。
20分後、全供試虫を観察用容器に集め、餌と水
を与え別室に移し、24時間後の死虫数を数えて死
虫率を求めた。
結果を第２表に示す。[Table] Test Example 2 Pinemin forte obtained in Reference Formulation Example 1 and Formulation Example 1 and S-4068F containing the active ingredient amounts shown in Table 2 were each heated for 15 minutes using a commercially available electric mosquito repellent heater. After preheating, place it in a 0.34 m 3 glass box into which 20 flies have been released.
Continuous heat fumigation and counting the number of insects
The KT50 (minutes) value was determined. After 20 minutes, all the test insects were collected in an observation container, given food and water, and moved to a separate room.After 24 hours, the number of dead insects was counted to determine the mortality rate. The results are shown in Table 2.
Claims (1)
のマツトに、活性成分して２−メチル−３−（２
−プロピニル）−４−オキソシクロペント−２−
エニル クリサンテメートを１マツトあたり60〜
160mg、安定剤および色素、あるいは、これらと
香料および／または添加剤からなるマツト用プレ
ミツクスが、１マツト当り80〜300mg含浸されて
いることを特徴とするハエ取り用高薬量電気マツ
ト。1. 2-methyl-3-( 2 -methyl-3-(2
-propynyl)-4-oxocyclopent-2-
Enyl chrysanthemate from 60 to 1 matsuto
1. A high-dose electric mat for fly traps, characterized in that each mat is impregnated with 80 to 300 mg of a premix for mats consisting of 160 mg of a stabilizer and a pigment, or these together with a fragrance and/or an additive.
Priority Applications (11)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57213061A JPS59104303A (en) | 1982-12-03 | 1982-12-03 | Electrothermally fumigating mat of high chemical content |
| AU21623/83A AU555368B2 (en) | 1982-12-03 | 1983-11-23 | Insecticidal mat for electric fumigator |
| GB08331281A GB2130883B (en) | 1982-12-03 | 1983-11-23 | Insecticidal mat for electric fumigator |
| GR73058A GR78770B (en) | 1982-12-03 | 1983-11-24 | |
| FR838318923A FR2536958B1 (en) | 1982-12-03 | 1983-11-28 | INSECTICIDE TABLECLOTH FOR ELECTRIC FUMIGATOR |
| IT23963/83A IT1167043B (en) | 1982-12-03 | 1983-11-30 | INSECTICIDE FABRIC FOR AN ELECTRIC SMOKER |
| KR1019830005729A KR840006748A (en) | 1982-12-03 | 1983-12-03 | Pest Control Electric Mat |
| PH29926A PH18837A (en) | 1982-12-03 | 1983-12-05 | Insecticidal mat for electric fumigator |
| AR302309A AR241065A1 (en) | 1982-12-03 | 1985-11-19 | "INSECTICIDE MAT FOR ELECTRIC FUMIGADOR" |
| HK971/85A HK97185A (en) | 1982-12-03 | 1985-12-05 | Insecticidal mat for electric fumigator |
| MY350/86A MY8600350A (en) | 1982-12-03 | 1986-12-30 | Insecticidal mat for electric fumigator |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57213061A JPS59104303A (en) | 1982-12-03 | 1982-12-03 | Electrothermally fumigating mat of high chemical content |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59104303A JPS59104303A (en) | 1984-06-16 |
| JPH0559082B2 true JPH0559082B2 (en) | 1993-08-30 |
Family
ID=16632876
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57213061A Granted JPS59104303A (en) | 1982-12-03 | 1982-12-03 | Electrothermally fumigating mat of high chemical content |
Country Status (11)
| Country | Link |
|---|---|
| JP (1) | JPS59104303A (en) |
| KR (1) | KR840006748A (en) |
| AR (1) | AR241065A1 (en) |
| AU (1) | AU555368B2 (en) |
| FR (1) | FR2536958B1 (en) |
| GB (1) | GB2130883B (en) |
| GR (1) | GR78770B (en) |
| HK (1) | HK97185A (en) |
| IT (1) | IT1167043B (en) |
| MY (1) | MY8600350A (en) |
| PH (1) | PH18837A (en) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0133601Y2 (en) * | 1985-03-20 | 1989-10-12 | ||
| FR2587589B1 (en) * | 1985-09-23 | 1990-05-11 | Roussel Uclaf | NEW PESTICIDE COMPOSITIONS CONTAINING (1R CIS, E) 2,2-DIMETHYL 3/2-FLUORO 3-OXO 3-METHOXY 1-PROPENYL / CYCLOPROPANE CARBOXYLATE FROM PENTAFLUORO PHENYL METHYL |
| JPS63152305A (en) * | 1986-08-15 | 1988-06-24 | Fumakiraa Kk | Insecticidal mat for vaporization by heating |
| EG18369A (en) * | 1986-08-15 | 1992-10-30 | Sumitomo Chemical Co | An insecticidal composition for electric fumigator |
| US5233787A (en) * | 1990-05-21 | 1993-08-10 | Milliken Denmark A/S | Pile mat for the elimination of vermins on pets |
| DK166937B1 (en) * | 1990-05-21 | 1993-08-09 | Milliken Denmark | MEASURES TO COMPLETE TRAFFIC OF ANIMALS |
| GB9123538D0 (en) * | 1991-11-06 | 1992-01-02 | Excel Ind Ltd | Insecticidal or insect-resistant composition and methods of manufacture thereof |
| DE69424928T2 (en) * | 1994-03-11 | 2000-11-09 | Zobele Industrie Chimiche S.P.A., Trento | Insecticidal formulation with a solid carrier |
| AU708907B2 (en) * | 1995-09-14 | 1999-08-12 | Sumitomo Chemical Company, Limited | Liquid insecticidal preparation for heat fumigation and method for killing insects by heat fumigation |
| US6074656A (en) * | 1996-11-12 | 2000-06-13 | Dainihon Jochugiku Co., Ltd. | Long-acting insecticidal mat and heat-transpiration insecticidal method using the same |
| US6551560B1 (en) * | 2000-08-31 | 2003-04-22 | S. C. Johnson & Son, Inc. | Two-stage dispensing mat |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56145201A (en) * | 1980-03-21 | 1981-11-11 | Eauitsuku Ag | Insecticidal vapor releasing body |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB749811A (en) * | 1950-09-19 | 1956-05-30 | Murphy Chemical Ltd | Improvements in fumigating devices |
| FR2054435A1 (en) * | 1969-06-02 | 1971-04-23 | Fumakilla Ltd | Control of insects by vaporisation of alleth - rin |
| LU73337A1 (en) * | 1975-09-05 | 1977-05-11 | ||
| JPS53121927A (en) * | 1977-03-29 | 1978-10-24 | Sumitomo Chem Co Ltd | Insecticidal composition for electiric mosquito-repellent device |
| US4199548A (en) * | 1977-06-10 | 1980-04-22 | Toyo Ink Manufacturing Co., Ltd. | Thermally diffusible composites |
| JPS55164603A (en) * | 1979-06-08 | 1980-12-22 | Hajime Hirobe | Mat for control of cockroach |
| IN152745B (en) * | 1980-03-21 | 1984-03-24 | Airwick Ag | |
| FR2491037B1 (en) * | 1980-09-26 | 1986-02-21 | Roussel Uclaf | PACKAGING OR COATING MATERIAL CONTAINING A PYRETHRINOID COMPOUND |
-
1982
- 1982-12-03 JP JP57213061A patent/JPS59104303A/en active Granted
-
1983
- 1983-11-23 AU AU21623/83A patent/AU555368B2/en not_active Ceased
- 1983-11-23 GB GB08331281A patent/GB2130883B/en not_active Expired
- 1983-11-24 GR GR73058A patent/GR78770B/el unknown
- 1983-11-28 FR FR838318923A patent/FR2536958B1/en not_active Expired - Fee Related
- 1983-11-30 IT IT23963/83A patent/IT1167043B/en active
- 1983-12-03 KR KR1019830005729A patent/KR840006748A/en not_active Application Discontinuation
- 1983-12-05 PH PH29926A patent/PH18837A/en unknown
-
1985
- 1985-11-19 AR AR302309A patent/AR241065A1/en active
- 1985-12-05 HK HK971/85A patent/HK97185A/en unknown
-
1986
- 1986-12-30 MY MY350/86A patent/MY8600350A/en unknown
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56145201A (en) * | 1980-03-21 | 1981-11-11 | Eauitsuku Ag | Insecticidal vapor releasing body |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS59104303A (en) | 1984-06-16 |
| FR2536958B1 (en) | 1990-01-26 |
| AR241065A2 (en) | 1991-10-31 |
| AU2162383A (en) | 1984-06-07 |
| GB2130883A (en) | 1984-06-13 |
| GR78770B (en) | 1984-10-02 |
| MY8600350A (en) | 1986-12-31 |
| HK97185A (en) | 1985-12-13 |
| GB2130883B (en) | 1985-08-14 |
| PH18837A (en) | 1985-10-10 |
| GB8331281D0 (en) | 1983-12-29 |
| IT1167043B (en) | 1987-05-06 |
| AU555368B2 (en) | 1986-09-18 |
| FR2536958A1 (en) | 1984-06-08 |
| KR840006748A (en) | 1984-12-03 |
| IT8323963A0 (en) | 1983-11-30 |
| AR241065A1 (en) | 1991-10-31 |
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