JPH0550473A - Injection mold - Google Patents

Injection mold

Info

Publication number
JPH0550473A
JPH0550473A JP21576491A JP21576491A JPH0550473A JP H0550473 A JPH0550473 A JP H0550473A JP 21576491 A JP21576491 A JP 21576491A JP 21576491 A JP21576491 A JP 21576491A JP H0550473 A JPH0550473 A JP H0550473A
Authority
JP
Japan
Prior art keywords
layer
tic
mold
tin
injection mold
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP21576491A
Other languages
Japanese (ja)
Inventor
Masami Izuhara
正己 出原
Michio Watanabe
道男 渡辺
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toshiba Corp
Original Assignee
Toshiba Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toshiba Corp filed Critical Toshiba Corp
Priority to JP21576491A priority Critical patent/JPH0550473A/en
Publication of JPH0550473A publication Critical patent/JPH0550473A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/17Component parts, details or accessories; Auxiliary operations
    • B29C45/26Moulds
    • B29C45/37Mould cavity walls, i.e. the inner surface forming the mould cavity, e.g. linings

Abstract

PURPOSE:To improve the abrasion resistance of an air vent part and to extend the life of an injection mold by laminating and applying at least two kinds of ceramics materials to the surface of the air vent part in the injection mold for molding an insulating plastic material in a gradient compounding state to form a composite film layer thereto. CONSTITUTION:In the air vent part 4 of a injection mold 1 for molding a product 3, an extremely thin Ti layer 12 is applied to a mold matrix 1 to enhance the close adhesiveness of a ceramics film and, next, for example, a TiN layer 13, a TiCN layer 14 composed of a mixture of TiN and TiC and the outermost TiC layer 15 are successively laminated to the Ti layer 12. The TiCN layer 14 is formed in a gradient compounding state so that an initial TiN mixing ratio is high and a TiC mixing ratio is gradually increased and a TiC ratio becomes about 100% finally. By this film formation, the surface hard TiC layer 15 is reduced in abrasion and also increased in toughness by the TiCN layer 14 and TiN layer 13 thereunder and, in cooperation with the close adhesiveness of the films due to the Ti layer 12, the problems such as abrasion, breakage, release or the like on the surface of the mold are solved.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、注型用金型表面へセラ
ミック薄膜の形成を行った注型用金型に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a casting mold in which a ceramic thin film is formed on the surface of the casting mold.

【0002】[0002]

【従来の技術】従来、プラスチック材料を注型する注型
金型の耐摩耗性、耐食性を向上させるためには、金型材
料自体の硬さを増加させるか、または、金型表面に硬質
被覆を行う処理がとられている。
2. Description of the Related Art Conventionally, in order to improve wear resistance and corrosion resistance of a casting mold for casting a plastic material, the hardness of the mold material itself is increased or the surface of the mold is hard coated. Processing is performed.

【0003】硬さを向上させる方法として、焼入れによ
り硬度向上を図る、あるいは硬い材料、例えば超硬質の
炭化物などがあるが、いずれも難加工材であることと、
注型時の温度変化に伴ってき裂など欠陥を生じ易い。ま
た、硬い材料を被覆する方法として、硬質クロムメッキ
や窒化法、イオン窒化法などがあるが、電気絶縁用プラ
スチック材料には、き裂防止などの目的からガラス繊維
やシリカ粒子が充填されているために、注型材料によっ
て、特にエアベントが削りとられ、拡大するなど十分の
耐摩耗性を得るまでに至っていない。ことに、このエア
ベントの拡大は、不要の部分を形成し、この不要の成形
材料を成形品から除去するとき、成形品にカケが発生す
る恐れがある。また、これを補修するのに手間がかか
る。
As a method for improving the hardness, there is a method for improving the hardness by quenching, or there is a hard material, for example, an ultra-hard carbide, but both are hard-to-machine materials.
Defects such as cracks are likely to occur due to temperature changes during casting. Further, as a method for coating a hard material, there are hard chrome plating, nitriding method, ion nitriding method, etc., but the plastic material for electrical insulation is filled with glass fiber or silica particles for the purpose of preventing cracks. For this reason, the air vent has been particularly scraped off by the casting material, and it has not yet reached sufficient wear resistance such as expansion. In particular, the expansion of the air vent forms an unnecessary portion, and when the unnecessary molding material is removed from the molded product, the molded product may be chipped. In addition, it takes time to repair this.

【0004】複雑な形状からなる電気絶縁用プラスチッ
ク注型金型においては、種々金型を分割し、しかも注型
困難な薄いものにも、プラスチック材料を過不足なく注
入し、欠陥のない所望の成形品を注型することが不可欠
である。
In the case of a plastic injection mold for electric insulation having a complicated shape, various molds are divided, and even if the mold is thin, it is possible to inject the plastic material into the thin mold without excess or deficiency. Casting molded parts is essential.

【0005】[0005]

【発明が解決しようとする課題】エアベント部を構成す
る注型金型内面は、注型材料注入時、金型内部のガス放
出と同時に、一部溶融した注型材料が高速で流出するた
めに、硬い金型面にもかかわらず、内表面は削り取ら
れ、使用回数の増加と共に摩耗拡大されることもある。
従って、注型回数の増加と共に、そのエアベンド内で固
化する注型材料の量が増加して歩留りが悪化すると共
に、成型品からこれら不要部分を除去するとき、工数は
勿論、一般的にはカケが発生し易く、これを補修するの
に手間がかかるなどの問題が生じる。この対策として、
前述したように、硬質金属メッキ、焼入れなどにより耐
摩耗性の向上を図って来たが、十分なる改善がなされて
いないのが現状である。
The inner surface of the casting mold forming the air vent portion is such that when the casting material is injected, the gas inside the die is released and at the same time, the partially molten casting material flows out at a high speed. Despite the hard mold surface, the inner surface may be scraped off, and the wear may be expanded as the number of times of use increases.
Therefore, as the number of castings increases, the amount of casting material that solidifies in the air bend increases and the yield deteriorates.When removing these unnecessary parts from the molded product, not only the number of man-hours but generally the chipping Is likely to occur, and it takes time to repair it. As a measure against this,
As described above, although the wear resistance has been improved by hard metal plating, quenching, etc., the current situation is that the wear resistance has not been sufficiently improved.

【0006】本発明はこのような点を考慮してなされた
ものであり、前記金型内エアベンド部において、金型表
面に密着性のすぐれた、かつ安定した多層構成からなる
セラミックス膜を被覆させることにより耐摩耗性にすぐ
れ、長寿命の注型用金型を提供することを目的とするも
のである。
The present invention has been made in consideration of the above points, and in the air bend portion in the mold, the surface of the mold is coated with a ceramic film having a multi-layered structure which has excellent adhesion and is stable. Thus, the object is to provide a casting mold having excellent wear resistance and long life.

【0007】[0007]

【課題を解決するための手段及び作用】絶縁用プラスチ
ック材料を射出成形する注型用金型のガス抜き用エアベ
ンド部の注型材料が接する部分に少なくとも2種以上に
傾斜機能的に複合膜層化し、エアベンド部の孔食防止及
び耐摩耗性を向上させる。
Means and Actions for Solving the Problems At least two or more functionally graded composite film layers are provided in a portion of a casting mold for injection-molding an insulating plastic material in contact with the casting material of a gas venting air bend portion. To improve pitting corrosion prevention and wear resistance of the air bend part.

【0008】[0008]

【実施例】本発明に基づく実施例を図面に基づいて説明
する。
Embodiments of the present invention will be described with reference to the drawings.

【0009】電気絶縁用プラスチック材料を注型する金
型において、図1に示すように特にエアベンド部4の金
型表面の耐摩耗性を改善する。図2において、金型の母
材11の表面にTi金属12を極く薄く成膜し、その表面に
窒化チタニウム(TiN)13を被覆し、さらにその表
面にTiNと窒化炭素(TiC)を、しかも逐次TiC
濃度が傾斜配合材料的に増加するように成膜し、最終表
面をTiC層にする。
In a mold for casting a plastic material for electrical insulation, as shown in FIG. 1, the wear resistance of the mold surface of the air bend portion 4 is particularly improved. In FIG. 2, a Ti metal 12 is formed extremely thinly on the surface of a base material 11 of a mold, titanium nitride (TiN) 13 is coated on the surface, and TiN and carbon nitride (TiC) are further coated on the surface. Moreover, sequential TiC
The TiC layer is formed on the final surface by forming a film so that the concentration is increased in the graded compound material.

【0010】ここで傾斜配合とは、例えば、A成分とB
成分をもつ材料配合において、A成分濃度を低下するに
従って、これと逆比例してB成分濃度を上昇させるよう
に、A〜Bへと略直線的に成分変化をもたらせるように
配合することをいう。
Here, the gradient composition means, for example, A component and B component.
In blending materials having components, as the concentration of the A component decreases, the concentration of the B component increases in inverse proportion to the decrease of the concentration of the A component so that the components can be changed substantially linearly from A to B. Say.

【0011】金型表面にTiを極く薄く被覆することに
より、その表面にセラミックススを被覆すると、膜の密
着性が増加する。(通常10〜20%改良)、またセラミ
ックスス膜の耐摩耗性と密着性との関係は、密着性では
TiNがTiCと比較して優れ、耐摩耗性ではTiCが
TiNと比較してすぐれている。しかもTiNは、Ti
Cと比較して膜内の靭性が大である。これらの条件によ
り、一般にショットブラストにSiO2 粉などを加え
て、セラミックスス薄膜に噴射して耐摩性試験に行った
結果では、TiC膜が耐摩耗性においてTiNよりすぐ
れているが、反面孔食性の摩耗が点在し、以後の摩耗要
因となる。一方、TiNは、膜の靭性効果により、Ti
C膜と比較して若干摩耗量が多い反面、孔食性は減少
し、比較的安定した耐摩耗形態を形成する。さらに詳細
を図面を参照して説明する。
When the surface of the die is coated with Ti very thinly and the surface of the die is coated with ceramics, the adhesion of the film is increased. (Normally 10 to 20% improvement) In addition, the relationship between wear resistance and adhesion of the ceramics film is that TiN is superior to TiC in terms of adhesion and TiC is superior to TiN in terms of wear resistance. There is. Moreover, TiN is Ti
The toughness in the film is higher than that of C. Under these conditions, generally, SiO 2 powder or the like is added to shot blast and sprayed on a ceramics thin film to perform a wear resistance test. As a result, the TiC film is superior in wear resistance to TiN, but the pitting corrosion resistance Wear is scattered and becomes a factor of subsequent wear. On the other hand, TiN has a
Although the amount of wear is slightly larger than that of the C film, the pitting corrosion property is reduced and a relatively stable wear resistant form is formed. Further details will be described with reference to the drawings.

【0012】図1にプラスチック材料注型用金型のエア
ベント部を示し、1が注型金型、2が湯口、3が注型
品、4がエアベント部である。そのエアベンド部4にセ
ラミックス薄膜を被覆したものを図2に示す。すなわ
ち、金型母材11の表面に極薄(0.05〜0.2 μm)のTi
層12を被覆し、その表面にTiN13を1〜2μm被覆
し、さらにTiN+TiC混合のTiCN層14を2〜4
μm、最表面にTiC層15を2〜3μm被覆構成したも
ので量る。なお、TiCN層は初期TiN混合比を高
く、逐次TiC混合比を増加させ、最終的にTiC比を
約100 %となるよう成膜したものである。
FIG. 1 shows an air vent portion of a plastic material casting die, wherein 1 is a casting die, 2 is a sprue, 3 is a casting product, and 4 is an air vent portion. FIG. 2 shows the air bend portion 4 coated with a ceramic thin film. That is, an extremely thin (0.05 to 0.2 μm) Ti film is formed on the surface of the mold base material 11.
Layer 12 is coated with TiN 13 having a thickness of 1-2 μm, and TiN + TiC mixed TiCN layer 14 is coated with 2-4.
The TiC layer 15 is coated on the outermost surface in a thickness of 2 to 3 μm. The TiCN layer is formed so that the initial TiN mixing ratio is high, the TiC mixing ratio is successively increased, and the TiC ratio is finally about 100%.

【0013】以上の成膜により、最も摩耗を必要とする
エアベンド部表面は、硬いTiC層が被覆したことから
抵抗性に富み、摩耗量が少なく、かつ、その下層のTi
CN層およびTiN層により膜の耐摩耗性と同時に、靭
性も増加し、膜の密着性を向上させるTi層と相まっ
て、金型表面の摩耗、欠損および剥離などの課題とされ
る問題点が解決し、金型寿命延長の大きな効果をもたら
せた。本実施例では、PVDイオンプレーティンにより
セラミックスス膜形成を行ったが、他の手法であるCV
Dやスパッタリングでも同様に行うことができる。
By the above-mentioned film formation, the surface of the air bend portion that requires the most wear is covered with a hard TiC layer, so that the surface is rich in resistance, the amount of wear is small, and the underlying Ti layer is Ti.
The CN layer and TiN layer increase the wear resistance of the film as well as the toughness, and together with the Ti layer, which improves the adhesion of the film, solve the problems such as wear, chipping and peeling of the mold surface. However, it has a great effect of extending the life of the mold. In this example, the ceramics film was formed by PVD ion plating, but other methods such as CV are used.
The same can be done with D or sputtering.

【0014】[0014]

【発明の効果】本発明によれば注型金型のエアベンド部
の耐摩耗性及び長寿命化を図ることができる。
According to the present invention, the wear resistance and the long life of the air bend portion of the casting mold can be achieved.

【図面の簡単な説明】[Brief description of drawings]

【図1】プラスチック材料を射出成形する金型への本発
明によるセラミックス薄膜を形成した金型の一実施例を
示す図である。
FIG. 1 is a diagram showing an example of a mold in which a ceramic thin film according to the present invention is formed on a mold for injection-molding a plastic material.

【図2】本発明により成膜したセラミックス各層の詳細
を示す拡出断面図である。
FIG. 2 is an enlarged sectional view showing details of each ceramic layer formed according to the present invention.

【符号の説明】[Explanation of symbols]

1…注型金型、 2…湯口、 3…注型品、 4…エアベンド。 1 ... Casting mold, 2 ... Gate, 3 ... Casting product, 4 ... Air bend.

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 絶縁用プラスチック材料を射出成形する
注型用金型のガス抜き用エアベンド部の注型材料が接す
る部分を、少くとも2種以上に傾斜配合的に複合膜層化
することを特徴とする注型用金型。
1. A composite film layer in which at least two or more portions of the degassing air bend portion of a casting mold for injection-molding an insulating plastic material, which come into contact with the casting material, are formed in a gradient composition. Characteristic casting mold.
JP21576491A 1991-08-28 1991-08-28 Injection mold Pending JPH0550473A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP21576491A JPH0550473A (en) 1991-08-28 1991-08-28 Injection mold

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP21576491A JPH0550473A (en) 1991-08-28 1991-08-28 Injection mold

Publications (1)

Publication Number Publication Date
JPH0550473A true JPH0550473A (en) 1993-03-02

Family

ID=16677845

Family Applications (1)

Application Number Title Priority Date Filing Date
JP21576491A Pending JPH0550473A (en) 1991-08-28 1991-08-28 Injection mold

Country Status (1)

Country Link
JP (1) JPH0550473A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008207219A (en) * 2007-02-27 2008-09-11 Toyo Advanced Technologies Co Ltd Pressing die
WO2012157073A1 (en) * 2011-05-17 2012-11-22 伊藤光学工業株式会社 Surface-treated mold and mold surface treatment method
CN103009697A (en) * 2012-12-18 2013-04-03 安徽天一重工股份有限公司 Self-lubricating gradient composite superhard film and preparation method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008207219A (en) * 2007-02-27 2008-09-11 Toyo Advanced Technologies Co Ltd Pressing die
US8087918B2 (en) * 2007-02-27 2012-01-03 Toyo Advanced Technologies Co., Ltd. Pressing mold and method for producing the same
WO2012157073A1 (en) * 2011-05-17 2012-11-22 伊藤光学工業株式会社 Surface-treated mold and mold surface treatment method
JPWO2012157073A1 (en) * 2011-05-17 2014-07-31 伊藤光学工業株式会社 Surface treatment mold and mold surface treatment method
JP5745623B2 (en) * 2011-05-17 2015-07-08 伊藤光学工業株式会社 Surface treatment mold and mold surface treatment method
CN103009697A (en) * 2012-12-18 2013-04-03 安徽天一重工股份有限公司 Self-lubricating gradient composite superhard film and preparation method thereof

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