JPH05317393A - Solid deodorizer for use in men's room - Google Patents

Abstract

PURPOSE:To provide a safe solid deodorant for use in the men's room which can remove bad odor for a long period, restrain propagation of miscellaneous germs and wash a pipe beneath each stool without generating strong irritating smell. CONSTITUTION:A solid deodorant for use in the men's room comprises a sulfate compound, glutaraldehyde, a polyglycol macromolecular compound and perfume and the sulfate compound is selected from zinc sulfate-7-hydrate, aluminium sulfate-14-to-18-hydrate, and hydrated ferric sulfate. The polyglycol macromolecular compound is a polyethylene glycol or a Pluronic type nonionic surface active agent. The solid deodorand is composed of 5-25wt% sulfate compound, 5-25wt% glutaraldehyde, 40-89wt% polyglycol macromolecular compound and 1-6wt% perfume.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a solid deodorant for men's toilets, and more specifically, it is installed in the lower part of the toilet bowl or the upper part of the toilet bowl of a men's toilet bowl to volatilize offensive odorous gas coming from inside the pipe under the toilet bowl. The present invention relates to a solid deodorant for men's toilets, which is capable of removing the malodor by reacting and removing the malodor, and further, the dissolved component directly acts on the source of malodor such as urinary stones adhering to the inside of the pipe under the toilet.

[0002]

2. Description of the Related Art As a method for removing the bad smell of a toilet, especially the bad smell of a toilet bowl of a men's toilet, a ball-shaped product in which naphthalene is formed together with a fragrance, that is, a method of installing naphthalene balls or an acid- or chlorine-based cleaning agent has been used. The method of washing is carried out. In addition to these, recently, it has been known to use indoor air fresheners and deodorants for toilets. However, the technology related to the deodorant to be installed on the upper part or the lower part of the bowl of the men's toilet bowl is complicated and difficult, and the research and development is not sufficiently done at present.

[0003]

However, in the case of naphthalene balls, an antibacterial agent and a masking agent are mainly contained, and only a peculiar irritating odor is strong, and it is basically difficult to remove a bad odor. In addition, the method of cleaning with an acid or chlorine-based cleaning agent has the problem that cleaning up to the inside of the pipe at the bottom of the toilet is difficult or time-consuming, and it has to be cleaned every day. There is a great possibility that it will lead to an accident, and it is very dangerous.

Further, as described above, when an indoor air freshener or deodorant is installed in the lower part of the pan of the toilet bowl of the men's toilet,
Where these are not manufactured for toilet bowls for men's toilets, the lower part of the dish is a place where urine comes into direct contact with these agents and ammonia accumulates at a high concentration, so that various bacteria propagate. Under severe environmental conditions, it is difficult to constantly expect a good deodorizing effect, and therefore it is basically difficult to remove a bad odor.

Therefore, the inventors of the present invention have conducted research with sincerity and spirit in order to solve the above problems, and as a result, volatile components in the deodorant are generated from urine stones, etc. in the lower pipe of the toilet bowl. Not only the bad odor can be removed by reacting with the bad odor, but also the liquid such as water and urine dissolves the deodorant, so the solution reacts with the source of the bad odor such as urinary stones, and the bad odor is generated. The present invention has been made on the basis of this finding that the above can be suppressed.

Therefore, the object of the present invention is to remove the bad odor generated from the men's toilet for a long period of time, to suppress the growth of various bacteria, and to clean the pipe under the toilet bowl so that it can be cleaned and has a strong irritating odor. It is to provide a solid deodorant for men's toilets that is not and safe.

[0007]

The present invention is achieved by each of the inventions (1) to (4) comprising the following constitutional requirements. (1) A solid deodorant for men's toilets comprising a sulfate compound, glutaraldehyde, a polyglycol polymer compound and a fragrance. (2) The menstrual toilet, wherein the sulfate compound according to the above-mentioned item 1 is at least one selected from zinc sulfate heptahydrate, aluminum sulfate 14 to 18 hydrate, and ferric sulfate hydrate. Deodorant for solids.

(3) The polyglycol polymer compound according to the above item (1) is at least one selected from polyethylene glycol and pluronic nonionic surfactants. Solid deodorant for men's toilets described. (4) Sulfate compound 5 to 25% by weight, glutaraldehyde 5 to 25% by weight, polyglycol polymer compound 40 to
The solid deodorant for men's toilets according to any one of claims 1 to 3, wherein the solid deodorant comprises 89% by weight and 1 to 6% by weight of the fragrance.

The present invention will be described in more detail below. The present invention is a solid deodorant for men's toilet composed of a sulfate compound, a glutaraldehyde, a polyglycol polymer compound and a fragrance. Volatile components in the agent are removed by reacting with the bad odor, and liquids such as water and urine dissolve the deodorant, so the dissolved solution reacts with the source of the bad odor such as urinary stones to prevent the generation of the bad odor. The deodorant can be suppressed, has no strong irritating odor itself, is safe, and has an excellent effect that it can be used for a long period of time.

The method for producing the solid deodorant for men's toilets of the present invention is not particularly limited, and when the components are mixed, the components may be added in any order. In the solid deodorant for men's toilet of the present invention, the sulfate compound,
It is for dissolving ammonia in water, urine, etc., and reacting and removing ammonia contained in urinary stones etc. on the inner wall of the pipe under the toilet bowl.

Specific examples of the sulfate compound used in the present invention include zinc sulfate heptahydrate and aluminum sulfate 14
.About.18 hydrate, ferric sulfate hydrate and the like are preferably used. Glutaraldehyde reacts and removes offensive odors such as generated ammonia gas, and a dissolved solution of glutaraldehyde dissolved in water, urine, etc. reacts and removes ammonia contained in urinary stones on the inner wall of pipes like sulfate compounds. .. Further, since this glutaraldehyde has a bactericidal activity, it has an action of suppressing the growth of various bacteria.

Further, the agent itself has a bactericidal property, and has a role of keeping the effect of the agent for a long period of time until it dissolves and disappears.
The polyglycol polymer compound has a role as a solidifying agent for solidifying the deodorant compound, and further, since the polyglycol polymer compound has detergency,
It dissolves in water or urine and becomes a solution that flows on the inner wall of the pipe,
The cleaning power of this liquid cleans the inner wall of the pipe.
Furthermore, since the dissolution rate of the polyglycol polymer compound can be adjusted by the difference in its molecular weight, the solubility can be controlled by combining several types of polyglycol polymer compounds, and the deodorant effect can be maintained over a long period of time. Can be made

Specific examples of the polyglycol polymer compound include polyethylene glycol having an average molecular weight of 1540 or more, CR-500 (polyglycol polymer compound,
Sanyo Chemical Industry Co., Ltd.), Pluronic type nonionic surfactants (Newpol PE-68, 78, 108, etc., Sanyo Chemical Industry Co., Ltd.) and the like. The fragrance is used as a masking agent for improving the atmosphere in the toilet, and examples thereof include those commonly used as a fragrance such as a lemon fragrance.

The component composition of the solid deodorant for men's toilets of the present invention is 5 to 25% by weight of a sulfate compound, 5 to 25% by weight of glutaraldehyde, and 40 to 40 of a polyglycol polymer compound.
It is preferably composed of 89% by weight and 1 to 6% by weight of perfume. In the component composition of the solid deodorant for men's toilet, if the sulfate compound is less than 5% by weight, the effect of reacting and removing ammonia is weak, and if it exceeds 25% by weight, solidification becomes difficult, which is not preferable.

If the amount of glutaraldehyde is less than 5% by weight,
25% by weight, which is not enough to remove the bad odors such as ammonia by reaction and to suppress the growth of various bacteria.
If it exceeds, solidification becomes difficult, which is inconvenient.

40% by weight of polyglycol polymer compound
When the amount is less than the above, solidification is difficult, and when it exceeds 89% by weight, the amount of other additives is relatively suppressed and the initial purpose is not achieved. Further, if the fragrance is less than 1% by weight, the masking effect is weak, and if it exceeds 6% by weight, the odor of the fragrance is too strong, which is not preferable for masking.

[0017]

In the present invention, the sulfate compound acts to remove the malodor by dissolving it in a liquid such as water or urine and reacting with the malodor such as ammonia contained in urinary stones on the inner wall of the pipe under the toilet bowl. Glutaraldehyde reacts with the volatilized components to remove the generated ammonia, and when it dissolves in a liquid, it reacts with the odorous substances such as ammonia contained in urinary stones on the inner wall of the pipe under the toilet bowl, like the sulfate compound. Acts to remove the bad smell. Further, since this glutaraldehyde has a bactericidal activity, it has an action of suppressing the growth of various bacteria and making it clean.

The polyglycol polymer compound has a role as a solidifying agent for solidifying the deodorant compound, and at the same time, the dissolution rate of the polyglycol polymer compound is controlled by the difference in the molecular weight thereof so that It also has the function of controlling dissolution. The fragrance is used as a masking agent for improving the atmosphere of the toilet. And the deodorant which combined such a compound has a favorable deodorizing effect.

[0019]

EXAMPLES The present invention will be described in more detail below with reference to examples, but the present invention is not limited to these examples.

Example 1 Zinc sulfate 7-hydrate 15% by weight, glutaraldehyde 12% by weight, polyethylene glycol (average molecular weight 2000
0) 50% by weight, CR-500 (polyglycol-based polymer compound, manufactured by Sanyo Kasei Co., Ltd.) 20% by weight, and 3% by weight of a lemon fragrance were mixed to prepare a solid deodorant. Using this deodorant as a test body, 100 g was set on the upper part of the eye plate of the men's toilet. Amount of ammonia gas detected by Kitagawa type detector tube (manufactured by Komei Rikagaku Co., Ltd., gas detector tube ammonia S
It was measured according to D). The unit of measurement is ppm, and the obtained results are shown in Table 1.

[0021]

[Table 1] Locations (invention) Comparison 1 2 3 4 5 6 7 After 1 week 0 0 0 0 0 0 0 0 5.3 After 2 weeks 0 0 0 0 0 0 0 7.8 3 weeks After 0.1 0 0.3 0.1 0 0 0.3 10.2

As is clear from Table 1, when the deodorant of the present invention is used, the amount of ammonia is small even after 3 weeks regardless of the place of installation, and thus it has a good deodorant effect. ..

Example 2 23% by weight of aluminum sulfate 14-18 hydrate, 17% by weight of glutaraldehyde, Newpol PE-108
47 wt% (Pluronic type nonionic surfactant, Sanyo Chemical Industry Co., Ltd.), CR-500 (polyglycol-based polymer compound, Sanyo Chemical Industry Co., Ltd.) 10 wt% and citrus flavoring agent 3 wt% Was mixed to prepare a solid deodorant. Using this deodorant as a test body, 90 g was placed under the eye dish of the men's toilet. The amount of ammonia gas was measured with a Kitagawa detector tube. The unit of measurement is ppm, and the obtained results are shown in Table 2.

[0024]

[Table 2] Locations (Invention) Comparison 1 2 3 4 5 6 7 8 1 week later 0 0 0 0 0 0 0 0 6.5 2 weeks later 0 0 0 0 0 0 0 0.1 9.7 3 weeks later 0.2 0.1 0 0 0.4 0.1 0 0.5 17.1

As is clear from Table 2, when the deodorant of the present invention is used, the amount of ammonia is small even after 3 weeks regardless of the place of installation, and thus it has a good deodorant effect. ..

[0026]

As described above, the solid deodorant for men's toilets of the present invention reacts and removes the bad odor generated from the toilet, suppresses the growth of various bacteria, and cleans the toilet bowl and the inner wall of the pipe under it. Further, the men's toilet gel deodorant of the present invention can be cleaned, can exert its effect over a long period of time, and is safe and easy to handle without generation of chlorine gas.

Claims (4)

[Claims] 1. A solid deodorant for men's toilets comprising a sulfate compound, glutaraldehyde, a polyglycol polymer compound and a fragrance. 2. A male compound characterized in that the sulfate compound according to claim 1 is at least one selected from zinc sulfate heptahydrate, aluminum sulfate 14 to 18 hydrate, and ferric sulfate hydrate. Solid deodorant for toilet. 3. The solid deodorant for men's toilet according to claim 1 or 2, wherein the polyglycol polymer compound is at least one selected from polyethylene glycol and a pluronic nonionic surfactant. Agent. 4. A composition comprising 5 to 25% by weight of a sulfate compound, 5 to 25% by weight of glutaraldehyde, 40 to 89% by weight of a polyglycol polymer compound and 1 to 6% by weight of a perfume. The solid deodorant for men's toilets according to any one of claims 1 to 3.