JPH05262617A - Make-up cosmetic - Google Patents

Abstract

PURPOSE:To provide the subject make-up cosmetic exhibiting a moisty, wet, tack-free and smooth feeling in use and excellent in durability. CONSTITUTION:This cosmetic contains a high-molecular polyethylene glycol having 500000 to 5000000 molecular weight as a moisturizer in an amount of 0.001 to 5wt.%, preferably 0.01 to 2wt.%. The above-mentioned cosmetic may contain raw materials contained in general cosmetics, e.g. various kinds of oil components, a humectant, a surfactant, a water-soluble polymer, a preservative, a chelating agent, a drug, a perfume, an antioxidant, a powder or water as necessary.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to makeup cosmetics such as foundation, eye shadow, blusher, white powder and lipstick. More specifically, molecular weight 500,000-5,00
The present invention relates to a make-up cosmetic composition in which one or two or more kinds of polyethylene glycol of 0,000 are blended to give a moist and fresh finish, a smooth feeling on use, non-greasiness, and a long-lasting makeup.

[0002]

2. Description of the Related Art Since makeup powder contains powder, it has a drawback that it is powdery after application and the skin is bulky, except for those who have oily skin. .. Conventionally, in order to solve such problems, attempts to blend a large amount of oil, glycerin, xylitol, sorbitol, various polyols such as low molecular weight polyethylene glycol, and various amino acids such as pyrrolidone carboxylic acid Attempts have been made to incorporate humectants and emollients such as higher alcohols, higher fatty acids, ester oils, lanolin.

However, when they are used, they are moist, but they are all sticky and have poor makeup lasting, so that they are not always satisfactory.

[0004]

In view of these circumstances, the inventors of the present invention have eagerly searched for a substance having an excellent moisturizing effect, a non-greasy feeling, a slippery feel, and an excellent makeup retention, and as a result, the molecular weight has been found. 500,000-5,000,00
When polyethylene glycol of 0 is used as a moisturizer in makeup cosmetics, it is surprisingly highly moisturizing, non-greasy, and has a smooth feel.
Furthermore, they have found that they have excellent makeup retention, and have completed the present invention.

[0005]

That is, the present invention is a makeup cosmetic characterized in that it contains one or more polyethylene glycol having a molecular weight of 500,000 to 5,000,000.

The structure of the present invention will be described in detail below.

The high molecular weight polyethylene glycol used in the present invention has a molecular weight of 500,000 to 5,000,000,
It can be obtained from Union Carbide Corporation (trade name: Polyox).

In the makeup cosmetic of the present invention, in order to obtain a proper moisturizing effect and a proper slippery feel, a high molecular weight polyethylene glycol having a molecular weight of 500,000 to 5,000,000 is added in an amount of 0.001 to 5% by weight based on the total amount of the cosmetic. , Preferably 0.01 to 2% by weight. 0.0
If it is less than 01% by weight, a sufficient effect cannot be obtained, and if it exceeds 5% by weight, it becomes difficult to dissolve it, and stickiness is observed even in the system of the present invention.

The makeup cosmetic composition of the present invention is used for the skin and includes all of them for the purpose of protection and makeup thereof.
If necessary, various oil components, moisturizing components, surfactants, water-soluble polymer substances (including anionic, nonionic, and cationic substances), preservatives, chelating agents, drugs, perfumes, antioxidants Raw materials such as powder, water, and the like, which are generally blended with cosmetics, can be blended.

For example, as oil, liquid paraffin,
Vaseline, paraffin wax, microcrystalline wax, ceresin, ozokerite, squalane, beeswax, carnauba wax, olive oil, lanolin, higher alcohols, fatty acids, esters of higher alcohols and fatty acids,
Widely used in cosmetics such as dimethyl polysiloxane, methylphenyl polysiloxane, dimethyl cyclopolysiloxane, diaryl polysiloxane, fatty acid modified polysiloxane, higher alcohol modified polysiloxane, silicone modified oil such as amino modified polysiloxane, silicone resin, silicone rubber, etc. Oil is used.

As the surfactant, polyoxyethylene alkyl ether, polyoxyethylene fatty acid ester, polyoxyethylene sorbitan fatty acid ester, sorbitan fatty acid ester, glycerin fatty acid ester,
Nonionic surfactants such as polyglycerin fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyoxyethylene hydrogenated castor oil, polyoxyethylene sorbitol fatty acid ester, polyoxyethylene-modified organopolysiloxane, polyoxyalkylene-modified organopolysiloxane, etc. Anionic surfactants such as silicone surfactants, fatty acid soaps such as sodium stearate and triethanolamine palmitate, and surfactants commonly used in cosmetics such as cationic surfactants and amphoteric surfactants are used. Be done.

As the water-soluble polymer, carboxymethyl cellulose, methyl cellulose, hydroxymethyl cellulose, polyvinyl alcohol, polyvinylpyrrolidone, tragacanth gum, carrageenan, locust bean gum, dextrin, dextrin fatty acid ester, carboxyvinyl polymer, xanthene gum, gelatin,
Water-soluble polymers commonly used in cosmetics such as sodium alginate, gum arabic, sodium hyaluronate, and sodium chondroitin sulfate are used.

As the moisturizer, sorbitol, xylitol, glycerin, maltitol, propylene glycol, 1,3-butylene glycol, 1,4-butylene glycol, sodium pyrrolidonecarboxylate, lactic acid, sodium lactate, low molecular weight polyethylene glycol, etc. A moisturizer commonly used for cosmetics is used.

As preservatives, preservatives commonly used in cosmetics such as alkyl paraoxybenzoate, sodium benzoate and potassium sorbate are used, and as preservatives, vitamins, crude drugs, anti-inflammatory agents, bactericides and the like are used. A drug commonly used in cosmetics is used.

As the powder, talc, kaolin, sericite, muscovite, synthetic mica, phlogopite, phlogopite, biotite, lithia mica, permiculite, magnesium carbonate, calcium carbonate, diatomaceous earth, magnesium silicate, silicic acid. Inorganic powder such as calcium, aluminum silicate, barium silicate, strontium silicate, metal tungstate, α-iron oxide, hydrated iron oxide, silica, hydroxyapatite, nylon powder, polyethylene powder, benzoguanamine powder, tetrafluoride Ethylene powder, distyrenebenzene pinhole polymer powder, organic powders such as microcrystalline cellulose, inorganic white pigments such as titanium oxide and zinc oxide, inorganic red pigments such as red iron oxide (red iron oxide) iron titanate, yellow iron oxide , Inorganic yellow pigments such as loess, mango violet, Inorganic purple pigments such as Baltic Violet, inorganic green pigments such as chromium oxide, chromium hydroxide and cobalt titanium, inorganic blue pigments such as ultramarine blue and navy blue, titanium oxide coated mica, titanium oxide coated bismuth oxychloride, bismuth oxychloride , Pearl pigments such as titanium oxide coated talc, fish scale foil, colored titanium oxide coated mica, metal powder pigments such as aluminum powder and copper powder, and hydrophobized products thereof.

As the dye, red No. 104 and red 202
No., Red 226, Red 227, Red 230, Yellow 4, Yellow 5, Yellow 202, Orange 206, Orange 2
No. 07, green No. 3, green No. 201, green No. 204, green No. 205, blue No. 1, blue No. 2, blue No. 201, etc. tar dyes, carminic acid, laccaic acid, calsamine, bradylin, crocin etc. natural dyes Rake is used.

[0017]

EXAMPLES Next, the present invention will be described in more detail by way of examples, which should not be construed as limiting the present invention. All compounding amounts are% by weight.

Example 1 O / W Emulsion Foundation Oil Phase Part Amount (1) Stearic Acid 1.5 (2) Palmitic Acid 1.5 (3) Cetyl Alcohol 1.5 (4) Dimethylpolysiloxane (6cs) 3.0 (5) Cetyl octanoate 3.0 (6) Squalane 3.0 (7) Vaseline 0.5 (8) Polyoxyethylene 2-octyldodecyl ether 1.0 (9) Diglycerin isostearate 1. 0 Powder part (10) Talc 9.9 (11) Yellow iron oxide 3.5 (12) Red iron oxide 1.5 (13) Black iron oxide 0.1 (14) Titanium dioxide 10.0 Water phase part (15 ) Kunipia G-4 (clay mineral manufactured by Kunimine Industries Co., Ltd.) 0.2 (16) Polyethylene glycol (molecular weight 500,000) 0.5 (17) 1.3-Butylene glycol 5.0 (18) Potassium hydroxide 1.0 ( 19) Methylpa Ben appropriate amount (20) ion exchange water Balance

(Manufacturing method) The water phase part was mixed at 70 ° C., the powder part was dispersed therein, and the oil phase part was further added thereto for emulsification, followed by cooling treatment to obtain an O / W type emulsion foundation. Got

Comparative Example 1 O / W Emulsion Foundation Oil Phase Part Amount (1) Stearic Acid 1.5 (2) Palmitic Acid 1.5 (3) Cetyl Alcohol 1.5 (4) Dimethylpolysiloxane (6cs) 3.0 (5) Cetyl octanoate 3.0 (6) Squalane 3.0 (7) Vaseline 0.5 (8) Polyoxyethylene 2-octyldodecyl ether 1.0 (9) Diglycerin isostearate 1. 0 Powder part (10) Talc 9.9 (11) Yellow iron oxide 3.5 (12) Red iron oxide 1.5 (13) Black iron oxide 0.1 (14) Titanium dioxide 10.0 Water phase part (15 ) Kunipia G-4 (clay mineral manufactured by Kunimine Industries Co., Ltd.) 0.2 (16) Polyethylene glycol (molecular weight 20,000) 0.5 (17) 1.3-Butylene glycol 5.0 (18) Glycerin 3.0 (19) Potassium hydroxide 1.0 (20) Methylparaben Appropriate amount (21) Ion-exchanged water Remainder

(Manufacturing method) According to Example 1.

Example 2 W / O Emulsion Foundation Oil Phase Part Blending Amount (1) Dimethylpolysiloxane 5.0 (2) Methylphenylpolysiloxane 5.0 (3) Dimethylpolysiloxane n = 20,000 5.0 (4 ) Trimethylsiloxysilicic acid 1.0 (5) Polyoxyethylene-modified organopolysiloxane 3.0 (6) Distearyldimethylammonium chloride 2.0 (7) Octylmethoxycinnamate 5.0 (8) Fragrance Suitable amount Water phase part (9) Smecton SA (synthetic clay mineral manufactured by Kunimine Industries Co., Ltd.) 3.0 (10) 1,3-butylene glycol 5.0 (11) glycerin 5.0 (12) polyethylene glycol (molecular weight 5,000,000) 0.01 (13 ) Polyethylene glycol (molecular weight 500,000) 1.0 (14) Sodium L-glutamate 2.0 (15) Ion exchange Water balance Powder part (16) Dextrin fatty acid ester treated talc 9.9 (17) Dextrin fatty acid ester treated yellow iron oxide 3.5 (18) Dextrin fatty acid ester treated red iron oxide 1.5 (19) Dextrin fatty acid ester treated black oxide Iron 0.1 (20) Dextrin fatty acid ester treated titanium dioxide 10.0

(Production Method) The oil phase part was mixed at 70 ° C., the powder part was mixed with this, and after cooling, the water phase part was added and emulsified to obtain a W / O type emulsion foundation.

Example 3 Solid W / O Emulsion Foundation Oil Phase Part Amount (1) Dimethylpolysiloxane 5.0 (2) Decamethylpentacyclosiloxane 25.0 (3) Polyoxyethylene-modified organopolysiloxane 3. 0 (4) Distearyldimethylammonium chloride 2.0 (5) Solid paraffin 4.0 (6) Microcrystalline wax 0.6 (7) Perfume proper amount Water phase part (8) Methylparaben 0.1 (9) 1, 3 -Butylene glycol 5.0 (10) Dipropylene glycol 3.0 (11) Glycerin 5.0 (12) Polyethylene glycol (molecular weight 4,000,000) 0.2 (13) Sodium L-glutamate 2.0 (14) Deionized water Remaining powder part (16) Silicone treated talc 9.9 (17) Silicone treated yellow iron oxide 3.5 (18) Silicon Red treated iron oxide 1.5 (19) Silicone treated black iron oxide 0.1 (20) Silicone treated titanium dioxide 10.0

(Manufacturing Method) The oil phase part was mixed at 80 ° C., the powder part was dispersed therein, and the water phase part was added at 80 ° C. for emulsification to obtain a W / O type solid emulsion foundation. ..

Example 4 Two-layer type lotion type foundation Aqueous phase compounding amount (1) Ethanol 10.0 (2) Propylene glycol 5.0 (3) Sorbitol 1.0 (4) Glycerin 3.0 (5) Polyethylene glycol (Molecular weight 1,000,000) 0.001 (6) Methylparaben Appropriate amount (7) Camphor 0.1 (8) Ion-exchanged water Balance powder (9) Yellow iron oxide 0.8 (10) Red iron oxide 0.3 (11) ) Black iron oxide 0.06 (12) Titanium dioxide 1.0 (13) Zinc oxide 1.0

(Production method) After dissolving the aqueous phase, the powder is wet dispersed to obtain a two-layer lotion type foundation.

Example 5 Oily Stick Foundation Oil Phase Part Amount (1) Liquid Paraffin Remainder (2) Isopropyl Palmitate 10.0 (3) Lanolin Alcohol 2.0 (4) Microcrystalline Wax 5.0 (5) Carnauba wax 1.5 (6) Candelilla wax 0.5 (7) Ethylparaben 0.8 (8) Methylphenylpolysiloxane 3.0 (9) Sorbitan sesquioleate 1.0 (10) Perfume proper amount (11) Polyethylene glycol (Molecular weight 3,000,000) 5.0 Powder part (11) Yellow iron oxide 5.8 (12) Red iron oxide 2.3 (13) Black iron oxide 0.6 (14) Titanium dioxide 15.0 (15) Kaolin 15. 0 (16) Talc 10.0

(Production Method) The oil phase part is melted at 80 ° C., the powder part is added, and the mixture is uniformly dispersed. The mixture is kneaded by a roll mill, poured into a container, cooled and solidified to obtain an oily stick foundation.

Example 6 Eye Shadow Oil Phase Part Amount (1) Squalane 4.0 (2) Cetyl Octanoate 1.0 (3) Sorbitan Sesquioleate 0.8 (4) Ethylparaben 0.5 (5) Macadamia nut oil 0.1 (6) Perfume proper amount (7) Polyethylene glycol (molecular weight 1,000,000) 3.0 Powder part (8) Talc 6.0 (9) Muscovite balance (10) Ultramarine 8.0 (11) Yellow iron oxide 3.0 (12) Black iron oxide 1.0

(Manufacturing Method) The powder part was mixed, the oil phase part was heated and melted, sprayed, mixed and pulverized, and then molded into a container to obtain an eye shadow.

Example 7 Powder Foundation Oil Phase Part Amount (1) Dimethylpolysiloxane 20cs 2.0 (2) Octyl palmitate 8.0 (3) Sorbitan sesquioleate 1.0 (4) Ethylparaben 0.5 (5) Octyl methoxycinnamate 0.1 (6) Perfume proper amount powder part (7) Polyethylene glycol (molecular weight 800,000) inclusion clay mineral 0.03 (8) Talc 10.0 (9) Muscovite 3.0 (10) Sericite Remainder (11) Nylon powder 10.0 (12) Yellow iron oxide 1.8 (13) Red iron oxide 0.8 (15) Titanium dioxide 5.0

(Manufacturing method) According to Example 6.

Example 8 Control Makeup Base Oil Phase Part Amount (1) Stearic Acid 2.0 (2) Palmitic Acid 1.0 (3) Cetostearyl Alcohol 3.0 (4) Dimethylpolysiloxane (6cs) 3. 0 (5) Cetyl octanoate 3.0 (6) Squalane 3.0 (7) Vaseline 1.0 (8) Polyoxyethylene stearyl ether 1.0 (9) Glyceryl monostearate 2.0 Powder part (10) Talc 5.0 (11) Red No. 202 0.02 (12) Red iron oxide 0.5 (13) Titanium dioxide 5.0 Water phase part (14) Sodium hexametaphosphate 0.03 (15) Kunipia G-4 ( Kunimine Industry Co., Ltd. clay mineral) 0.2 (16) Polyethylene glycol (molecular weight 500,000) 0.5 (17) 1.3-Butylene glycol 5.0 (18) Glycerin 3.0 (19) Sodium oxide 1.0 (20) Methylparaben qs (21) Ion-exchanged water balance

(Manufacturing method) According to the first embodiment.

Example 9 Lipstick Oil Phase Part Amount (1) Liquid Paraffin Remainder (2) Glyceryl Isostearate 1.0 (3) Castor Oil 40.0 (4) Carnauba Wool 2.0 (5) Solid Paraffin 7. 0 (6) Candelilla wax 0.5 (7) Ethylparaben 0.5 (8) Perfume proper amount (9) Polyethylene glycol (molecular weight 4,000,000) 0.5 (10) δ-tocopherol 0.03 Powder part (11) Red No. 202 0.5 (12) Red No. 204 2.3 (13) Orange No. 201 0.2 (14) Titanium dioxide 2.0

(Manufacturing Method) The oil phase part is melted at 80 ° C., the powder part is added, and the mixture is uniformly dispersed. The mixture is kneaded by a roll mill, poured into a container, cooled and solidified to obtain lipstick.

[0038] Examples 1 to 9 and Comparative Example 1 were used by 20 beauty technicians and evaluated. The results are shown in Table 1. The numbers in the table indicate the number of people who evaluated each as ABCDE. Evaluation A: Quite excellent evaluation D; Poor evaluation B; Excellent evaluation E; Quite poor evaluation C; Normal

[0039]

[Table 1]

[0040]

EFFECT OF THE INVENTION The makeup cosmetic composition of the present invention is moist and fresh, non-greasy, and has a smooth feeling of use.
In addition, it provides a makeup cosmetic with good makeup retention.

Claims (1)

[Claims] 1. A makeup cosmetic containing one or more polyethylene glycols having a molecular weight of 500,000 to 5,000,000.