JPH0520523Y2 - - Google Patents

Info

Publication number
JPH0520523Y2
JPH0520523Y2 JP17615087U JP17615087U JPH0520523Y2 JP H0520523 Y2 JPH0520523 Y2 JP H0520523Y2 JP 17615087 U JP17615087 U JP 17615087U JP 17615087 U JP17615087 U JP 17615087U JP H0520523 Y2 JPH0520523 Y2 JP H0520523Y2
Authority
JP
Japan
Prior art keywords
glass plate
layer
decorative
resin
manufactured
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP17615087U
Other languages
Japanese (ja)
Other versions
JPH0180418U (en
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Priority to JP17615087U priority Critical patent/JPH0520523Y2/ja
Priority to DE3838930A priority patent/DE3838930C2/en
Priority to KR1019890006194A priority patent/KR970010550B1/en
Publication of JPH0180418U publication Critical patent/JPH0180418U/ja
Priority to US07/417,077 priority patent/US5019440A/en
Priority to US08/063,681 priority patent/USRE34743E/en
Application granted granted Critical
Publication of JPH0520523Y2 publication Critical patent/JPH0520523Y2/ja
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C5/00—Processes for producing special ornamental bodies
    • B44C5/04—Ornamental plaques, e.g. decorative panels, decorative veneers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/1077—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing polyurethane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10018—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising only one glass sheet
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10165—Functional features of the laminated safety glass or glazing
    • B32B17/10247—Laminated safety glass or glazing containing decorations or patterns for aesthetic reasons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10165—Functional features of the laminated safety glass or glazing
    • B32B17/10247—Laminated safety glass or glazing containing decorations or patterns for aesthetic reasons
    • B32B17/10256—Laminated safety glass or glazing containing decorations or patterns for aesthetic reasons created by printing techniques
    • B32B17/10266—Laminated safety glass or glazing containing decorations or patterns for aesthetic reasons created by printing techniques on glass pane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C5/00—Processes for producing special ornamental bodies
    • B44C5/04—Ornamental plaques, e.g. decorative panels, decorative veneers
    • B44C5/0407—Ornamental plaques, e.g. decorative panels, decorative veneers containing glass elements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C5/00—Processes for producing special ornamental bodies
    • B44C5/04—Ornamental plaques, e.g. decorative panels, decorative veneers
    • B44C5/0446—Ornamental plaques, e.g. decorative panels, decorative veneers bearing graphical information
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44F—SPECIAL DESIGNS OR PICTURES
    • B44F1/00—Designs or pictures characterised by special or unusual light effects
    • B44F1/06—Designs or pictures characterised by special or unusual light effects produced by transmitted light, e.g. transparencies, imitations of glass paintings
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00—Coverings or linings, e.g. for walls or ceilings
    • E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
    • E04F13/14—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements stone or stone-like materials, e.g. ceramics concrete; of glass or with an outer layer of stone or stone-like materials or glass
    • E04F13/145—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements stone or stone-like materials, e.g. ceramics concrete; of glass or with an outer layer of stone or stone-like materials or glass with an outer layer of glass

Landscapes

  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Laminated Bodies (AREA)
  • Surface Treatment Of Glass (AREA)
  • Panels For Use In Building Construction (AREA)

Description

【考案の詳細な説明】 （産業上の利用分野） 本考案は、室内の壁、天井等のパネル材あるい
は室内装飾等に用いられる装飾ガラス板に関す
る。[Detailed Description of the Invention] (Industrial Application Field) The present invention relates to a decorative glass plate used for panel materials such as interior walls and ceilings or for interior decoration.

（従来の技術） 装飾ガラス板は、透明ガラス板の表面に直接シ
ルクスクリーン印刷によつて印刷層を形成したも
のや、積層ガラスを使用したものが使用されてい
る。積層ガラス使用したものとしては、例えば、
特開昭50−65584号公報に、ポリビニルブチラー
ル樹脂フイルムに転写印刷による印刷層を設けた
積層ガラス中間膜が開示されている。かかる技術
によれば、ガラス板に直接印刷した装飾ガラス板
に比べて意匠効果も優れ、また、耐性も優れた装
飾ガラス板が得られるので、装飾的価値は高いも
のである。しかしながら、この装飾ガラス板を得
るには、２枚のガラス板とポリビニルブチラール
樹脂フイルムの中間膜が必要であり、価格が高く
なるという問題点があつた。(Prior Art) Decorative glass plates include those in which a printed layer is formed directly on the surface of a transparent glass plate by silk screen printing, and those using laminated glass. Examples of laminated glass include:
JP-A-50-65584 discloses a laminated glass interlayer film in which a printed layer is provided by transfer printing on a polyvinyl butyral resin film. According to this technique, it is possible to obtain a decorative glass plate which has a superior design effect and excellent durability compared to a decorative glass plate printed directly on a glass plate, and thus has a high decorative value. However, in order to obtain this decorative glass plate, two glass plates and an interlayer film of polyvinyl butyral resin film are required, resulting in a problem that the price is high.

また、透明樹脂フイルムの片面に印刷を施した
フイルムを接着剤によりガラス板に積層する技術
も知られているが、パネル材のような半永久的な
耐性を要求されるような用途としては不十分であ
つた。すなわち、長期間に亘る環境温度や湿度の
変化により接着部が剥離してくるという欠点を有
しているのである。 Another known technique is to laminate a transparent resin film printed on one side to a glass plate using adhesive, but this is insufficient for applications that require semi-permanent durability such as panel materials. It was hot. That is, it has the disadvantage that the adhesive portion may peel off due to changes in environmental temperature and humidity over a long period of time.

（考案が解決しようとする問題点） 本考案は、グラビア印刷方式などにより得られ
る精密な印刷画像を転写することで装飾的価値の
高い装飾ガラス板を提供するものである。(Problems to be Solved by the Invention) The present invention provides a decorative glass plate with high decorative value by transferring a precise printed image obtained by a gravure printing method or the like.

また、本考案は、このような装飾ガラス板を経
済的に得ることを目的とするものである。 Moreover, the present invention aims to economically obtain such a decorative glass plate.

（問題点を解決するための手段） 本考案を図面に基づいて説明すると、本考案装
飾ガラス板は、光透過性ガラス板１１、プライマ
ー層１２、転写印刷層１３および硬化樹脂層１４
を順次形成したものである。(Means for Solving the Problems) To explain the present invention based on the drawings, the decorative glass plate of the present invention includes a light-transmitting glass plate 11, a primer layer 12, a transfer printing layer 13, and a cured resin layer 14.
were formed sequentially.

ガラス板１１は、転写印刷層１３がガラス板を
通して透視できる必要がある。ガラス板１１の厚
さは特に限定されないが、実用上は１〜10mmの厚
さのものが好ましく使用される。また、プライマ
ー層形成の前にガラス板１１を表面をシランカツ
プリング剤で表面処理しておくことが望ましい。 The glass plate 11 needs to allow the transfer printing layer 13 to be seen through the glass plate. The thickness of the glass plate 11 is not particularly limited, but in practice, a thickness of 1 to 10 mm is preferably used. Further, it is desirable that the surface of the glass plate 11 be treated with a silane coupling agent before forming the primer layer.

プライマー層１２は、転写印刷層１３がガラス
板１１に強固に接着するようにガラス板１１の表
面に、１〜100μmの塗料樹脂層を形成するもので
あつて、本考案ではポリイソシアネートとポリオ
ールとから得られる硬化性ポリウレタン樹脂塗料
が使用される。特にポリイソシアネートとしてヘ
キサメチレンジイソシアネートなどのを使用した
無黄変性ポリウレタン塗料が長期間に亘つて光線
に暴露されても黄変しないので好ましい。また、
屋外の壁などに使用される用途には耐性の優れた
樹脂フツ素樹脂系ポリオールを成分としたポリウ
レタン樹脂が好ましい。 The primer layer 12 is to form a paint resin layer of 1 to 100 μm on the surface of the glass plate 11 so that the transfer printing layer 13 firmly adheres to the glass plate 11, and in the present invention, it is made of polyisocyanate and polyol. A curable polyurethane resin coating obtained from In particular, non-yellowing polyurethane paints using hexamethylene diisocyanate or the like as the polyisocyanate are preferred because they do not yellow even when exposed to light over a long period of time. Also,
For applications such as outdoor walls, polyurethane resins containing resin fluororesin polyols with excellent resistance are preferred.

プライマー層１２も転写印刷層１３を透視でき
るようにするため光線透過性とする必要があり、
そのためにクリヤーな塗料が用いられる。 The primer layer 12 also needs to be light-transparent so that the transfer printing layer 13 can be seen through.
Clear paint is used for this purpose.

転写印刷層１３は、任意の模様などを形成した
印刷画像をプライマー層１２の表面に転写したも
のである。この転写印刷層１３は、予めポリエス
テルフイルムなどの基材にグラビア印刷方式によ
り印刷した転写シートを使用し、このシートの印
刷面をプライマー層１２表面に熱圧着することに
より形成することができる。 The transfer printing layer 13 is a layer in which a printed image with an arbitrary pattern or the like is transferred onto the surface of the primer layer 12. This transfer printing layer 13 can be formed by using a transfer sheet printed in advance on a base material such as a polyester film by a gravure printing method, and by thermocompression bonding the printed surface of this sheet to the surface of the primer layer 12.

硬化樹脂層１４は、転写印刷層１３を補強して
装飾ガラス板としての耐性を向上させるために形
成される。特に、転写印刷の画像を鮮明にするた
めに、チタンホワイト、カーボンブラツク等の顔
料によつて、隠蔽性のある塗料で形成することが
好ましい。硬化樹脂層１４の樹脂としては、プラ
イマー層１２に使用したポリウレタン塗料を使用
してもよいが、常温、あるいは低温で硬化する他
の硬化性塗料であれば他の塗料系であつても使用
可能である。硬化樹脂層１４の厚さは特に制限が
ないが、5μm以上が好ましい。 The cured resin layer 14 is formed to reinforce the transfer printing layer 13 and improve its durability as a decorative glass plate. In particular, in order to make the transfer printed image clear, it is preferable to use a coating that has a concealing property using pigments such as titanium white and carbon black. As the resin for the cured resin layer 14, the polyurethane paint used for the primer layer 12 may be used, but any other curable paint that cures at room temperature or low temperature can also be used. It is. The thickness of the cured resin layer 14 is not particularly limited, but is preferably 5 μm or more.

（実施例） 以下実施例について説明する。例中「％」は
「重量％」を表す。(Example) Examples will be described below. In the examples, "%" represents "% by weight".

実施例 １ 下記処方により表面処理剤を作成した。Example 1 A surface treatment agent was prepared using the following formulation.

シランカツプリング剤（信越化学工業(株)製
KBM−603） 0.1％ イソプロピルアルコール 99.9 厚さ10mmの板ガラスを、40℃の５％カセイソー
ダ水溶液に１分間浸漬し取り出し後、イオン交換
水を30秒間噴霧して表面に残るアルカリ液を洗い
流し、ついで80℃の熱風中で３分間乾燥させた。
しかる後に上記表面処理剤をスプレーガンにて均
一に塗布し80℃の熱風中で１分間乾燥させた。 Silane coupling agent (manufactured by Shin-Etsu Chemical Co., Ltd.)
KBM-603) 0.1% isopropyl alcohol 99.9 A plate glass with a thickness of 10 mm is immersed in a 5% caustic soda aqueous solution at 40°C for 1 minute, taken out, and then sprayed with ion-exchanged water for 30 seconds to wash away the alkaline solution remaining on the surface. It was dried in hot air at ℃ for 3 minutes.
Thereafter, the surface treatment agent was uniformly applied using a spray gun and dried in hot air at 80° C. for 1 minute.

つぎに下記処方でウレタン樹脂クリヤー塗料プ
ライマーを作成した。 Next, a urethane resin clear paint primer was prepared using the following formulation.

主 剤 アクリルポリオール（日立化成工業(株)製 ヒ
タロイド3008） 67.0％ オクチツクス錫（日本化学産業(株)製） 0.1 メチルエチルケトン 20.0 トルエン 12.9 硬化剤 ヘキサメチレシジイソシアネート（住友バイ
エルウレタン(株)製 スミジユールＮ−75）
100.0％ 主剤と硬化剤を重量比にて６対１で混合し、表
面処理を行つたガラス板にスプレーガンで均一に
80℃の熱風中で20分間乾燥させた。塗膜厚さは10
ミクロンとした、しかる後に、予めポリエステル
フイルム上に塩化ビニル酢酸ビニル共重合樹脂を
バインダーとするインキを柄付け印刷して作成し
た転写フイルムを、ガラス板に塗装した塗膜プラ
イマー層を100℃に加熱してから圧着せしめ、50
℃まで冷却してからポリエステルフイルムを剥が
してウレタン塗膜上に柄を転写した。つぎに、下
記処方のウレタン樹脂白塗料を作成した。Main agent Acrylic polyol (Hitalloid 3008, manufactured by Hitachi Chemical Co., Ltd.) 67.0% Tin octix (manufactured by Nippon Kagaku Sangyo Co., Ltd.) 0.1 Methyl ethyl ketone 20.0 Toluene 12.9 Curing agent Hexamethylene diisocyanate (manufactured by Sumitomo Bayer Urethane Co., Ltd.) Sumidyur N- 75)
100.0% Mix base material and hardening agent at a weight ratio of 6:1 and spray evenly onto a surface-treated glass plate with a spray gun.
It was dried in hot air at 80°C for 20 minutes. The coating thickness is 10
After that, a transfer film made by printing a pattern on a polyester film with an ink containing vinyl chloride vinyl acetate copolymer resin as a binder was applied to a glass plate, and the primer layer was heated to 100℃. and then crimp it, 50
After cooling to ℃, the polyester film was peeled off and the pattern was transferred onto the urethane coating. Next, a urethane resin white paint with the following formulation was prepared.

主 剤 アクリルポリオール（日立化成工業(株)製 ヒ
タロイド3008） 50.0％ チタン白顔料（石原産業(株)製 タイペークＲ−
820） 20.0 オクチツクス錫（日本化学産業(株)製） 0.1 メチルエチルケトン 10.0 トルエン 9.9 硬化剤 ヘキサメチレシジイソシアネート（住友バイ
エルウレタン(株)製 スミジユールＮ−75）
100.0％ 主剤と硬化剤を重量比にて８対１で混合し、転
写処理を行つたガラス板にスプレーガンで均一に
塗布し80℃の熱風中で30分間乾燥させた。塗膜厚
さは10ミクロンとした。このようにして柄付けを
した塗膜はガラスに強固に付着しており、碁盤目
セロハンテープ剥離試験で100／100であつた。Main agent Acrylic polyol (Hitaroid 3008 manufactured by Hitachi Chemical Co., Ltd.) 50.0% Titanium white pigment (Taipeku R- manufactured by Ishihara Sangyo Co., Ltd.)
820） 20.0 Octix tin (manufactured by Nippon Kagaku Sangyo Co., Ltd.) 0.1 Methyl ethyl ketone 10.0 Toluene 9.9 Curing agent Hexamethylene diisocyanate (Sumidyur N-75, manufactured by Sumitomo Bayer Urethane Co., Ltd.)
100.0% A base material and a curing agent were mixed at a weight ratio of 8:1, and the mixture was uniformly applied to a glass plate subjected to transfer treatment using a spray gun, and dried in hot air at 80° C. for 30 minutes. The coating film thickness was 10 microns. The paint film patterned in this way adhered firmly to the glass, and was 100/100 in a grid cellophane tape peel test.

実施例 ２ 下記処方により表面処理剤を作成した。Example 2 A surface treatment agent was prepared using the following formulation.

シランカツプリング剤（信越化学工業(株)製
KBM−603） 0.1％ イソプロピルアルコール 99.9 厚さ10mmの板ガラスを、40℃の５％カセイソー
ダ水溶液に１分間浸漬し取り出し後、イオン交換
水を30秒間噴霧して表面に残るアルカリ液を洗い
流し、ついで80℃の熱風中で３分間乾燥させた。
しかる後に上記表面処理剤を浸したガーゼでガラ
ス表面を拭いて表面処理剤を塗布し80℃で１分間
乾燥させた。 Silane coupling agent (manufactured by Shin-Etsu Chemical Co., Ltd.)
KBM-603) 0.1% isopropyl alcohol 99.9 A plate glass with a thickness of 10 mm is immersed in a 5% caustic soda aqueous solution at 40°C for 1 minute, taken out, and then sprayed with ion-exchanged water for 30 seconds to wash away the alkaline solution remaining on the surface. It was dried in hot air at ℃ for 3 minutes.
Thereafter, the surface treatment agent was applied by wiping the glass surface with gauze soaked in the above surface treatment agent and dried at 80° C. for 1 minute.

つぎに実施例１に記載したウレタン樹脂クリヤ
ー塗料（プライマー）を、表面処理ガラス板にス
プレーガンで均一に塗布し80℃の熱風中で20分間
乾燥させた。塗膜厚さは10ミクロンとした。しか
る後に、予めポリエステルフイルム上に塩化ビニ
ル酢酸ビニル共重合樹脂をバインダーとするイン
キを柄付け印刷して作成した転写フイルムを、ガ
ラス板に塗装した塗膜プライマー層を100℃に加
熱してから圧着せしめ、50℃に冷却してからポリ
エステルフイルムを剥がしてウレタン塗膜上に柄
を転写した。 Next, the urethane resin clear paint (primer) described in Example 1 was uniformly applied to the surface-treated glass plate using a spray gun and dried in hot air at 80°C for 20 minutes. The coating film thickness was 10 microns. After that, a transfer film created by printing a pattern on a polyester film with an ink containing vinyl chloride vinyl acetate copolymer resin as a binder is heated to 100℃ and then pressure bonded to the coating primer layer applied to the glass plate. After cooling to 50°C, the polyester film was peeled off and the pattern was transferred onto the urethane coating.

つぎに下記処方でウレタン樹脂黒色塗料を作成
した。 Next, a urethane resin black paint was prepared using the following recipe.

主 剤 アクリルポリオール（日立化成工業(株)製 ヒ
タロイド3008） 50.0％ カーボンブラツク顔料（三菱化成工業(株)製 カ
ーボンブラツクMA−100） 2.0 オクチツクス錫 0.1 メチルエチルケトン 25.0 トルエン 22.9 硬化剤 実施例１で使用したジイソシアネート 主剤と硬化剤を重量比にて８対１で混合し、転
写処理を行つたガラス板にスプレーガンで均一に
塗布し80℃の熱風中で30分間乾燥させた。塗膜厚
さは10ミクロンとした。このようにして柄付けを
した塗膜はガラスに強固に付着しており、碁盤目
セロハンテープ剥離試験で100／100であつた。Main agent Acrylic polyol (Hitalloid 3008 manufactured by Hitachi Chemical Co., Ltd.) 50.0% Carbon black pigment (Carbon Black MA-100 manufactured by Mitsubishi Chemical Industries, Ltd.) 2.0 Octix tin 0.1 Methyl ethyl ketone 25.0 Toluene 22.9 Curing agent Used in Example 1 A diisocyanate base agent and a curing agent were mixed at a weight ratio of 8:1, and the mixture was uniformly applied to a glass plate subjected to transfer treatment using a spray gun and dried in hot air at 80°C for 30 minutes. The coating film thickness was 10 microns. The paint film patterned in this way adhered firmly to the glass, and was 100/100 in a grid cellophane tape peel test.

（考案の効果） 本考案の装飾ガラス板は、ガラスを積層したも
のと異なり、本質的にガラス板に硬化性樹脂の層
を形成したものなので、価格を安く、軽量であ
る。(Effects of the Invention) The decorative glass plate of the present invention is different from a laminated glass plate and is essentially a glass plate with a hardening resin layer formed thereon, so it is inexpensive and lightweight.

また、装飾模様はグラビア印刷方式などにより
形成できるので装飾的価値性が高く、かつ、この
転写印刷は耐性の優れた硬化性樹脂層に挟みこま
れて固定されるので、耐性が優れ、半永久的な使
用が要求される室内外壁用のパネル材として実用
性が高いものである。 In addition, decorative patterns can be formed using gravure printing methods, so they have high decorative value, and since this transfer printing is sandwiched and fixed between highly durable hardening resin layers, it has excellent durability and is semi-permanent. It is highly practical as a panel material for indoor and outdoor walls that require extensive use.

【図面の簡単な説明】[Brief explanation of the drawing]

第１図は本考案の装飾ガラス板の断面図であ
る。数字は以下のとおりである。 １１……ガラス板、１２……プライマー層、１
３……転写印刷層、１４……硬化樹脂層。 FIG. 1 is a sectional view of the decorative glass plate of the present invention. The numbers are as follows. 11...Glass plate, 12...Primer layer, 1
3... Transfer printing layer, 14... Cured resin layer.

Claims (1)

【実用新案登録請求の範囲】 １ 光線透過性ガラス板の片面に、光線透過性ポ
リウレタン樹脂よりなるプライマー層、転写印
刷層および硬化樹脂層を順次形成した装飾ガラ
ス板。 ２ 上記ポリウレタン樹脂が無黄変性ポリウレタ
ン樹脂である実用新案登録請求の範囲第１項記
載の装飾ガラス板。 ３ 上記硬化樹脂層が着色された硬化樹脂層であ
る実用新案登録請求の範囲第１項記載の装飾ガ
ラス板。[Claims for Utility Model Registration] 1. A decorative glass plate in which a primer layer made of a light-transparent polyurethane resin, a transfer printing layer, and a cured resin layer are sequentially formed on one side of a light-transparent glass plate. 2. The decorative glass plate according to claim 1, wherein the polyurethane resin is a non-yellowing polyurethane resin. 3. The decorative glass plate according to claim 1, wherein the cured resin layer is a colored cured resin layer.
JP17615087U 1987-11-18 1987-11-18 Expired - Lifetime JPH0520523Y2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP17615087U JPH0520523Y2 (en) 1987-11-18 1987-11-18
DE3838930A DE3838930C2 (en) 1987-11-18 1988-11-17 Decorative glass plate
KR1019890006194A KR970010550B1 (en) 1987-11-18 1989-05-09 Decorative glass plate
US07/417,077 US5019440A (en) 1987-11-18 1989-10-04 Decorative plate
US08/063,681 USRE34743E (en) 1987-11-18 1993-05-20 Decorative plate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP17615087U JPH0520523Y2 (en) 1987-11-18 1987-11-18

Publications (2)

Publication Number Publication Date
JPH0180418U JPH0180418U (en) 1989-05-30
JPH0520523Y2 true JPH0520523Y2 (en) 1993-05-27

Family

ID=16008534

Family Applications (1)

Application Number Title Priority Date Filing Date
JP17615087U Expired - Lifetime JPH0520523Y2 (en) 1987-11-18 1987-11-18

Country Status (3)

Country Link
JP (1) JPH0520523Y2 (en)
KR (1) KR970010550B1 (en)
DE (1) DE3838930C2 (en)

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DE9404843U1 (en) * 1994-03-22 1995-07-27 Degussa AG, 40474 Düsseldorf Fully recyclable composite body, especially for the production of furniture panels
FR2729416B1 (en) * 1995-01-13 1997-04-25 Ronzat Sa Soc Nouv PROCESS FOR THE MANUFACTURE AND LAYING OF DECORATIVE GLASS PANELS
JPH09286039A (en) * 1996-04-22 1997-11-04 Komatsu Ltd Plate-shaped composite and its production
EP0950509A1 (en) * 1998-02-20 1999-10-20 F. XAVER LEIPOLD GMBH & CO. KG A multilayer for coating preferably a transparent substrate
EP1195243A1 (en) * 2000-10-09 2002-04-10 Frank Haag Safety glass
AU2003304273A1 (en) * 2003-07-07 2005-01-21 Susanne Hader Translucent decorative image element and process for producing the same
KR100778378B1 (en) * 2006-06-15 2007-11-29 백상오 Printed article manufactured by method for doing decalcomania on glass surface
US8119048B2 (en) 2006-09-22 2012-02-21 Nissha Printing Co., Ltd. Housing case, method for manufacturing housing case, and glass insert molding die used in same
EP2562003A3 (en) * 2007-05-27 2013-06-19 Thomas Schneider Planar element and method for the production thereof
CN102535790A (en) * 2012-03-05 2012-07-04 烟台同化防水保温工程有限公司 High-emulation elastic outer wall decoration panel and manufacturing method thereof
CN109228637A (en) * 2018-08-29 2019-01-18 芜湖长信科技股份有限公司 A kind of OGS touch screen base ink printing method

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JPS5329811A (en) * 1976-09-01 1978-03-20 Kansai Paint Co Ltd Method of transferring pictures
JPS53105521A (en) * 1977-02-28 1978-09-13 Dainippon Printing Co Ltd Production of decorative glass
JPS5669243A (en) * 1979-11-10 1981-06-10 Yamamura Glass Kk Glass vessel with decoration on surface
JPS6073899A (en) * 1983-09-30 1985-04-26 ラムダ美工株式会社 Method of transferring pattern on article with hard surface such as glass
JPS63166737A (en) * 1986-12-26 1988-07-09 Asai Glass Kk Transfer-printed decorative glass plate and production thereof

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JPS53105521A (en) * 1977-02-28 1978-09-13 Dainippon Printing Co Ltd Production of decorative glass
JPS5669243A (en) * 1979-11-10 1981-06-10 Yamamura Glass Kk Glass vessel with decoration on surface
JPS6073899A (en) * 1983-09-30 1985-04-26 ラムダ美工株式会社 Method of transferring pattern on article with hard surface such as glass
JPS63166737A (en) * 1986-12-26 1988-07-09 Asai Glass Kk Transfer-printed decorative glass plate and production thereof

Also Published As

Publication number Publication date
DE3838930C2 (en) 1997-04-24
KR970010550B1 (en) 1997-06-28
DE3838930A1 (en) 1989-06-01
JPH0180418U (en) 1989-05-30
KR900017807A (en) 1990-12-20

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