JPH05169070A - Method for reduction of heavy metal especially soitable for diagnosis of dentist - Google Patents

Method for reduction of heavy metal especially soitable for diagnosis of dentist

Info

Publication number
JPH05169070A
JPH05169070A JP4158163A JP15816392A JPH05169070A JP H05169070 A JPH05169070 A JP H05169070A JP 4158163 A JP4158163 A JP 4158163A JP 15816392 A JP15816392 A JP 15816392A JP H05169070 A JPH05169070 A JP H05169070A
Authority
JP
Japan
Prior art keywords
heavy metal
dentist
amalgam
reducing
medicine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP4158163A
Other languages
Japanese (ja)
Other versions
JPH07102352B2 (en
Inventor
Hartmut Braetsch
ハルトムート・ブレチュ
Michael Grimm
ミヒャエル・グリム
H Juergen Zimmerhackl
ハー・ユルゲン・ツィンマーハックル
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kaltenbach and Voigt GmbH
Original Assignee
Kaltenbach and Voigt GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kaltenbach and Voigt GmbH filed Critical Kaltenbach and Voigt GmbH
Publication of JPH05169070A publication Critical patent/JPH05169070A/en
Publication of JPH07102352B2 publication Critical patent/JPH07102352B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/70Treatment of water, waste water, or sewage by reduction
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D19/00Degasification of liquids
    • B01D19/02Foam dispersion or prevention
    • B01D19/04Foam dispersion or prevention by addition of chemical substances
    • B01D19/0404Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/42Treatment of water, waste water, or sewage by ion-exchange
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/58Treatment of water, waste water, or sewage by removing specified dissolved compounds
    • C02F1/62Heavy metal compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/68Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
    • C02F1/683Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water by addition of complex-forming compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/50Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/20Heavy metals or heavy metal compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/006Dental effluents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/06Controlling or monitoring parameters in water treatment pH
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/04Disinfection
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/12Prevention of foaming
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00Use of specific compounds during water treatment
    • C02F2305/04Surfactants, used as part of a formulation or alone

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Hydrology & Water Resources (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Dispersion Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Removal Of Specific Substances (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)
  • Detergent Compositions (AREA)

Abstract

PURPOSE: To provide a method for reducing the heavy metal, for example, amalgam, included in the waste water discharged from the medical examination by a dentist which obviates the formation of a soluble compd., for example, mercury ions, like a separator for the amalgam used in the case of the conventional medical examination by the dentist relating to the method for reducing the heavy metal, for example, the amalgam, described above.
CONSTITUTION: A specifically formed medicine is used at the time of mending and washing of, for example, appliances and apparatus. The pH value of the environment of this time is maintained at 9 to 13 at an alkaline level. A component for taking out the heavy metal impurity by utilizing absorbency and ion exchangeability or a component for taking out the heavy metal impurity by a chemical effect is included in the medicine for this purpose. A surfactant, sterilizer, defoaming agent, color additive and/or arom. additive may be included in the medicine.
COPYRIGHT: (C)1993,JPO

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、特に歯科医の診療で例
えば濯ぎや、器具及び装置の手入れや洗浄の際に生じる
排水中の重金属含有量を還元することを目的とし、アル
カリ性を保たれた環境中で特別の還元剤を用いることを
考慮している。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention is intended to reduce the content of heavy metals in waste water generated in dentistry, for example, during rinsing, cleaning and cleaning of instruments and devices, and keeping alkalinity. Considering the use of special reducing agents in different environments.

【0002】歯科医の診療から由来しかつ公の排水を汚
染するアマルガムすなわち水銀と他の金属との合金を分
離器によって捕捉することが、これまでに試みられてき
た。例えばアマルガムの研磨屑を捕捉するためのアマル
ガム用分離器は種々の会社によって製造され、必要な許
可を受けている。しかし、アマルガム用分離器を使用す
る際に、歯科医でない他の診療分野で使用される化学薬
品との関連で、溶性水銀化合物又は水銀イオン及び微細
分散固体水銀化合物又は水銀の生成は完全には排除され
ないので、毒性の強い物質が公の排水に入ることがあ
る。
It has been attempted in the past to capture amalgams, alloys of mercury and other metals, originating from dentist practice and polluting public drainage with separators. For example, amalgam separators for capturing amalgam debris are manufactured by various companies and have the necessary permits. However, when using amalgam separators, the formation of soluble mercury compounds or mercury ions and finely dispersed solid mercury compounds or mercury is not completely associated with chemicals used in other non-dentist practice areas. Highly toxic substances can enter the public sewage since they are not excluded.

【0003】本発明がここで関与するのは、例えば日常
の手入れの際に、要求に応じて考えられた薬剤が、吸引
装置及びスピットン領域(Speischalenbereich)並びに該
領域に後置された部分、例えば分離器に入れられて、p
H値がアルカリレベル、好ましくは9乃至13の間に保
たれることによってである。この目的のために考えられ
た重金属還元剤は、ビルダ−の他に、重金属を含有する
物質を吸収するための特異有効成分、すなわち吸収性、
イオン交換性又は化学結合をもって作用する有効成分を
含有する。該有効成分としては、例えば、チオウレイド
基を含むスチロ−ルジビニルベンゼンをベ−スにした粉
末状の陽イオン交換樹脂(例えば商品としてはレヴァタ
イトTP214)が考えられる。ベトナイトすなわち酸
性白土タイプの粘土鉱物、例えばシリトナイトという商
品は吸収作用を有すると見なされ、カルバメ−ト又はハ
ロゲン、例えば沃化カリウムは化学結合をなすと見なさ
れる。3つのすべての成分は単独で又は共に用いること
ができる。使用される薬剤は、界面活性剤、殺菌剤、消
泡剤、色添加剤及び/又は芳香添加剤を含有することは
望ましい。
[0003] The invention is concerned here with, for example, during routine care, the drug, which is considered on demand, is inhaled by the suction device and the Speischalenbereich region and the parts which are placed behind it, for example Put in separator, p
By keeping the H value at an alkaline level, preferably between 9 and 13. The heavy metal reducing agent considered for this purpose is, in addition to the builder, a specific active ingredient for absorbing a substance containing a heavy metal, that is, absorbability,
It contains active ingredients that act by ion exchange or chemical bonding. As the active ingredient, for example, a powdered cation exchange resin (for example, Levatite TP214 as a commercial product) in which styrene divinylbenzene containing a thioureido group is based is considered. Commercial products of betonite or acid clay type clay minerals, such as silitonite, are considered to have an absorbing effect, and carbamates or halogens, such as potassium iodide, are considered to form a chemical bond. All three components can be used alone or together. The agents used preferably contain surfactants, germicides, defoamers, color additives and / or fragrance additives.

【0004】消泡剤としては、一方では、(シリコンエ
マルジョン、例えば1乃至5の粘度を有するジメチルポ
リシロキサンエマルジョンをベ−スにした)即効タイプ
の薬剤が考えられ、他方では、鎖長に従って作用時間を
調節する使用された消泡剤用のマトリックスとして、例
えばポリエチレングリコ−ル又はエチレンオキシ付加物
のような遅延性の薬剤が考慮される。こうした2つのタ
イプのうちの少なくとも各々1つの代表的な薬剤が用い
られることは好ましい。薬剤中にあるビルダ−はメタケ
ン酸ナトリウム及び炭酸アリカリ、ホウ酸塩又は水酸化
物から成る。洗浄を補佐するために、非イオン界面活性
剤が用いられる。殺菌成分としては、酸素を除く酸、例
えば過酢酸、又は酸塩及び第4アンモニウム化合物が考
慮される。殺菌効果を有する両性界面活性剤及び塩素を
除く殺菌剤が適切である。重金属還元のために考えられ
た薬剤は、固体で、例えば粒質物又は粉末として、又は
液状で、溶剤としての水と共に使用される。粉末又は粒
質物状の一般的な組成は、例えば下記のごとくである。
Anti-foaming agents are, on the one hand, fast-acting agents (based on silicone emulsions, for example dimethylpolysiloxane emulsions having a viscosity of 1 to 5), and on the other hand act according to chain length. As a matrix for the antifoaming agent used for adjusting the time, delaying agents such as polyethylene glycol or ethyleneoxy adducts come into consideration. It is preferred that at least one representative drug of each of these two types is used. The builder in the drug consists of sodium metakenate and potassium carbonate, borate or hydroxide. Nonionic surfactants are used to aid in cleaning. Acids other than oxygen, such as peracetic acid, or acid salts and quaternary ammonium compounds come into consideration as germicidal components. Amphoteric surfactants having a bactericidal effect and fungicides other than chlorine are suitable. The agents envisaged for heavy metal reduction are used in solid form, for example as granules or powders, or in liquid form, with water as solvent. A general composition in the form of powder or granules is, for example, as follows.

【0005】30乃至95重量%のビルダ−及びそれぞ
れ5重量%までの界面活性剤、殺菌剤、徐々及び急速に
作用する消泡剤、色添加剤及び芳香添加剤、及び重金属
を吸収又はイオン交換によって、化学的に吸収する成
分。
30-95% by weight of builder and up to 5% by weight respectively of surfactants, bactericides, gradual and fast acting defoamers, color and fragrance additives, and heavy metal absorbing or ion exchange. A component that is chemically absorbed by.

【0006】この場合、上記百分率は非常に高い濃度を
表わしている。該濃度は製造上に問題を生ずることなく
高められるが、このことにより、診察に適した、有効な
調剤とはなるわけではない。固形の製剤に特に適した調
剤は、 メタケン酸ナトリウム 83重量% 炭酸アルカリ 3 非イオン界面活性剤 3 ジクロロイソシアネ−ト 3 粉砕されたレヴァタイトTP214 2 シリトナイト 1 沃化カリウム 2 助剤 3 薬剤及び方法の1実施例では、薬剤は歯科用器械の排水
導管に接続されたカ−トリッジに導入される。液状の重
金属還元剤は以下の構成を有する。 洗浄成分 92重量% 50%のシリトナイト分散液 2 50%のレヴァタイト分散液 4 沃化カリウム 2
In this case, the above percentages represent very high concentrations. Although the concentration can be increased without producing problems, this does not make it an effective preparation suitable for examination. Particularly suitable formulations for solid formulations are sodium metakenate 83% by weight alkali carbonate 3 nonionic surfactant 3 dichloroisocyanate 3 milled levatite TP214 2 silitonite 1 potassium iodide 2 aid 3 agents and methods In one embodiment, the drug is introduced into a cartridge connected to the drainage conduit of the dental instrument. The liquid heavy metal reducing agent has the following constitution. Cleaning component 92% by weight 50% silitonite dispersion 2 50% levitite dispersion 4 potassium iodide 2

【0007】薬剤を使用すると、重金属を吸収した成分
が、固体としてアマルガム用分離器の貯蔵容器に蓄えら
れる。更に排水を処理するために、貯蔵容器の中身に吸
収された重金属が加えられる。
When the drug is used, the component having absorbed the heavy metal is stored as a solid in the storage container of the amalgam separator. The absorbed heavy metal is added to the contents of the storage container to further treat the wastewater.

───────────────────────────────────────────────────── フロントページの続き (72)発明者 ハルトムート・ブレチュ ドイツ連邦共和国、デー − 7957 シェ ンマーホーフェン 4、アム・ゾンネンラ イン 11 (72)発明者 ミヒャエル・グリム ドイツ連邦共和国、デー − 7930 エー インゲン、ドロセルベーク 1 (72)発明者 ハー・ユルゲン・ツィンマーハックル ドイツ連邦共和国、デー − 7930 エー インゲン、アム・ランミンガー 17 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Hartmut Brech, Germany, Day -7957 Schemmerhofen 4, Am Sonnenrain 11 (72) Inventor Michael Grimm, Germany, Day 7930 Aingen , Drosselbeek 1 (72) Inventor Her Jürgen Zimmermar Kuckle, Germany-7930 Eingen, Am Ramminger 17

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 ビルダ−の他に、重金属を含有する物質
をイオン交換、吸収によって吸収するか、又は化学結合
する特異成分を含有する薬剤を、吸引装置領域及びスピ
ットン領域並びに該領域に後置された部分、例えば分離
器に導入し、pH値をアルカリレベル、好ましくは9乃
至13の間に保つこと、を特徴とする歯科医の診療の排
水中の重金属還元方法。
1. In addition to a builder, a drug containing a specific component that absorbs a substance containing a heavy metal by ion exchange or absorption, or chemically bonds, is post-applied to the suction device region, the spitton region, and the region. Method for reducing heavy metals in wastewater of dentist's practice, characterized in that it is introduced into a controlled part, for example a separator, and the pH value is kept at an alkaline level, preferably between 9 and 13.
【請求項2】 前記薬剤は界面活性剤、殺菌剤、消泡
剤、色活性剤及び/又は芳香活性剤を含有すること、を
特徴とする請求項1に記載の重金属還元方法。
2. The method for reducing heavy metals according to claim 1, wherein the agent contains a surfactant, a bactericide, a defoaming agent, a color activator and / or an aroma activator.
【請求項3】 前記薬剤中には消泡作用を有する少なく
とも2つの物質、すなわち即効タイプの物質と、それぞ
れの使用範囲に調節された特異的な作用時間を有する他
方の物質が含有されていること、を特徴とする請求項1
又は2に記載の重金属還元方法。
3. The drug contains at least two substances having a defoaming action, that is, a fast-acting substance, and the other substance having a specific action time adjusted to each usage range. Claim 1 characterized by the above.
Or the heavy metal reduction method described in 2.
【請求項4】 前記薬剤は沃土カリウムを含有するこ
と、を特徴とする請求項1乃至3のいずれか1に記載の
重金属還元方法。
4. The method for reducing heavy metals according to claim 1, wherein the chemical contains potassium iodide.
JP4158163A 1991-06-18 1992-06-17 Method of removing heavy metals in wastewater of dentist's practice Expired - Fee Related JPH07102352B2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4120068A DE4120068C2 (en) 1991-06-18 1991-06-18 Method for heavy metal reduction in the wastewater of dental practices
DE4120068:3 1991-06-18

Publications (2)

Publication Number Publication Date
JPH05169070A true JPH05169070A (en) 1993-07-09
JPH07102352B2 JPH07102352B2 (en) 1995-11-08

Family

ID=6434200

Family Applications (1)

Application Number Title Priority Date Filing Date
JP4158163A Expired - Fee Related JPH07102352B2 (en) 1991-06-18 1992-06-17 Method of removing heavy metals in wastewater of dentist's practice

Country Status (4)

Country Link
JP (1) JPH07102352B2 (en)
CH (1) CH685626A5 (en)
DE (1) DE4120068C2 (en)
IT (2) ITMI920609U1 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001030707A1 (en) * 1999-10-28 2001-05-03 Solmetex, Inc. Device and method for treating dental waste streams

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5637877A (en) * 1979-08-31 1981-04-11 Nec Corp Page control system
JPS649680U (en) * 1987-07-08 1989-01-19

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3813264A1 (en) * 1987-04-23 1988-11-10 Eck Marcel Robert Dr Med Dent Process and apparatus for purifying waste waters arising in dental treatments
DE3742063A1 (en) * 1987-12-11 1989-06-22 Varta Batterie METHOD FOR DETOXIFYING SEWAGE CONTAINING ELEMENTAL MERCURY

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5637877A (en) * 1979-08-31 1981-04-11 Nec Corp Page control system
JPS649680U (en) * 1987-07-08 1989-01-19

Also Published As

Publication number Publication date
ITMI920609V0 (en) 1992-06-16
CH685626A5 (en) 1995-08-31
JPH07102352B2 (en) 1995-11-08
IT1258999B (en) 1996-03-11
DE4120068C2 (en) 1995-06-08
ITMI920609U1 (en) 1992-12-19
ITMI921473A1 (en) 1993-12-16
DE4120068A1 (en) 1992-12-24
ITMI921473A0 (en) 1992-06-16

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