CN1271931C - Disinfection effervescence tablet, granule or powder containing chlorine with low chlorine odor and preparation method thereof - Google Patents
Disinfection effervescence tablet, granule or powder containing chlorine with low chlorine odor and preparation method thereof Download PDFInfo
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- CN1271931C CN1271931C CN 200410068135 CN200410068135A CN1271931C CN 1271931 C CN1271931 C CN 1271931C CN 200410068135 CN200410068135 CN 200410068135 CN 200410068135 A CN200410068135 A CN 200410068135A CN 1271931 C CN1271931 C CN 1271931C
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- sodium
- agent
- chlorine
- surfactant
- disinfection effervescence
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- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 title claims abstract description 69
- 239000000460 chlorine Substances 0.000 title claims abstract description 69
- 229910052801 chlorine Inorganic materials 0.000 title claims abstract description 69
- 238000004659 sterilization and disinfection Methods 0.000 title claims abstract description 64
- 239000000843 powder Substances 0.000 title claims abstract description 17
- 238000002360 preparation method Methods 0.000 title claims description 15
- 239000003826 tablet Substances 0.000 title description 13
- 239000008187 granular material Substances 0.000 title 1
- 239000002245 particle Substances 0.000 claims abstract description 30
- 239000004094 surface-active agent Substances 0.000 claims abstract description 20
- 159000000000 sodium salts Chemical class 0.000 claims abstract description 11
- 239000007788 liquid Substances 0.000 claims abstract description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 36
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 27
- 239000003795 chemical substances by application Substances 0.000 claims description 25
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 20
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 10
- 235000011152 sodium sulphate Nutrition 0.000 claims description 10
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 9
- 239000004327 boric acid Substances 0.000 claims description 9
- YRIZYWQGELRKNT-UHFFFAOYSA-N 1,3,5-trichloro-1,3,5-triazinane-2,4,6-trione Chemical compound ClN1C(=O)N(Cl)C(=O)N(Cl)C1=O YRIZYWQGELRKNT-UHFFFAOYSA-N 0.000 claims description 5
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 5
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 5
- 229950009390 symclosene Drugs 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- 239000002280 amphoteric surfactant Substances 0.000 claims description 4
- 239000003093 cationic surfactant Substances 0.000 claims description 4
- -1 dodecyl dihydroxy ethyl betain Chemical compound 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- 238000005453 pelletization Methods 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- 239000002002 slurry Substances 0.000 claims description 4
- YZRBWJKMPZVKLU-UHFFFAOYSA-N 2,2-dichloro-2-(dichloroamino)acetic acid;urea Chemical compound NC(N)=O.OC(=O)C(Cl)(Cl)N(Cl)Cl YZRBWJKMPZVKLU-UHFFFAOYSA-N 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 229910021538 borax Inorganic materials 0.000 claims description 3
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 claims description 3
- DLFDEDJIVYYWTB-UHFFFAOYSA-N dodecyl(dimethyl)azanium;bromide Chemical compound Br.CCCCCCCCCCCCN(C)C DLFDEDJIVYYWTB-UHFFFAOYSA-N 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 3
- 239000004299 sodium benzoate Substances 0.000 claims description 3
- 235000010234 sodium benzoate Nutrition 0.000 claims description 3
- 239000011684 sodium molybdate Substances 0.000 claims description 3
- 235000015393 sodium molybdate Nutrition 0.000 claims description 3
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 claims description 3
- 229960001922 sodium perborate Drugs 0.000 claims description 3
- 229940045872 sodium percarbonate Drugs 0.000 claims description 3
- 239000004328 sodium tetraborate Substances 0.000 claims description 3
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 3
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 claims description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- 239000005977 Ethylene Substances 0.000 claims description 2
- 239000002202 Polyethylene glycol Substances 0.000 claims description 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical group [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 2
- 230000031709 bromination Effects 0.000 claims description 2
- 238000005893 bromination reaction Methods 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 150000004665 fatty acids Chemical class 0.000 claims description 2
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims description 2
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 claims description 2
- FFJMLWSZNCJCSZ-UHFFFAOYSA-N n-methylmethanamine;hydrobromide Chemical compound Br.CNC FFJMLWSZNCJCSZ-UHFFFAOYSA-N 0.000 claims description 2
- 229920001223 polyethylene glycol Polymers 0.000 claims description 2
- YRWWOAFMPXPHEJ-OFBPEYICSA-K sodium L-ascorbic acid 2-phosphate Chemical compound [Na+].[Na+].[Na+].OC[C@H](O)[C@H]1OC(=O)C(OP([O-])([O-])=O)=C1[O-] YRWWOAFMPXPHEJ-OFBPEYICSA-K 0.000 claims description 2
- 229940048058 sodium ascorbyl phosphate Drugs 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 150000001805 chlorine compounds Chemical group 0.000 claims 1
- 239000000645 desinfectant Substances 0.000 abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 10
- 230000000536 complexating effect Effects 0.000 abstract description 7
- 230000000638 stimulation Effects 0.000 abstract description 4
- 238000005260 corrosion Methods 0.000 abstract description 3
- 230000007797 corrosion Effects 0.000 abstract description 3
- 229910052751 metal Inorganic materials 0.000 abstract description 3
- 239000002184 metal Substances 0.000 abstract description 3
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 230000002147 killing effect Effects 0.000 abstract description 2
- 235000019645 odor Nutrition 0.000 description 14
- 230000001954 sterilising effect Effects 0.000 description 11
- 239000000796 flavoring agent Substances 0.000 description 10
- 235000019634 flavors Nutrition 0.000 description 10
- RTKIYNMVFMVABJ-UHFFFAOYSA-L thimerosal Chemical compound [Na+].CC[Hg]SC1=CC=CC=C1C([O-])=O RTKIYNMVFMVABJ-UHFFFAOYSA-L 0.000 description 10
- 229940033663 thimerosal Drugs 0.000 description 10
- 239000000047 product Substances 0.000 description 9
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 4
- 238000007873 sieving Methods 0.000 description 4
- 239000011343 solid material Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- 241000700605 Viruses Species 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 238000009360 aquaculture Methods 0.000 description 2
- 244000144974 aquaculture Species 0.000 description 2
- 238000012258 culturing Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 description 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 1
- 241000193830 Bacillus <bacterium> Species 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 description 1
- 241000222122 Candida albicans Species 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241000238557 Decapoda Species 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- 241000725303 Human immunodeficiency virus Species 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 229940095731 candida albicans Drugs 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- RKLXDNHNLPUQRB-TVJUEJKUSA-N chembl564271 Chemical compound C([C@@H](C(=O)N[C@@H](CC(C)C)C(=O)N[C@@H](CCC(N)=O)C(=O)N[C@@H]1C(=O)N[C@@H](CC(C)C)C(=O)N[C@@H]2C(C)SC[C@H](N[C@@H](CC(N)=O)C(=O)NC(=O)[C@@H](NC2=O)CSC1C)C(=O)N[C@@H](CCCCN)C(=O)N[C@@H]([C@@H](C)CC)C(=O)NC(=C)C(=O)N[C@@H](CCCCN)C(O)=O)NC(=O)[C@H]1NC(=O)C(=C\C)/NC(=O)[C@H](CCC(N)=O)NC(=O)[C@H](CC(C)C)NC(=O)[C@H](C)NC(=O)CNC(=O)[C@@H](NC(=O)[C@@H](NC(=O)[C@H]2NC(=O)CNC(=O)[C@@H]3CCCN3C(=O)[C@@H](NC(=O)[C@H]3N[C@@H](CC(C)C)C(=O)NC(=O)C(=C)NC(=O)CC[C@H](NC(=O)[C@H](NC(=O)[C@H](CCCCN)NC(=O)[C@@H](N)CC=4C5=CC=CC=C5NC=4)CSC3)C(O)=O)C(C)SC2)C(C)C)C(C)SC1)C1=CC=CC=C1 RKLXDNHNLPUQRB-TVJUEJKUSA-N 0.000 description 1
- SURLGNKAQXKNSP-DBLYXWCISA-N chlorin Chemical compound C\1=C/2\N/C(=C\C3=N/C(=C\C=4NC(/C=C\5/C=CC/1=N/5)=CC=4)/C=C3)/CC\2 SURLGNKAQXKNSP-DBLYXWCISA-N 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
- 229910000397 disodium phosphate Inorganic materials 0.000 description 1
- 235000019800 disodium phosphate Nutrition 0.000 description 1
- 239000013051 drainage agent Substances 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000007938 effervescent tablet Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 208000006454 hepatitis Diseases 0.000 description 1
- 231100000283 hepatitis Toxicity 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000008786 sensory perception of smell Effects 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 108010082567 subtilin Proteins 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 241000712461 unidentified influenza virus Species 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 230000010148 water-pollination Effects 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
The present invention relates to an effervescent disinfectant containing chlorine with low chlorine odor, which can be an effervescent disinfection tablet containing chlorine, a particle or powder. The effervescent disinfectant containing chlorine with complexing chlorine is prepared by complexing organochlorine, surface active agent and sodium salt and can be quickly dissolved in water to prepare into a disinfection liquid containing chlorine. The present invention is a novel effervescent disinfectant containing chlorine with the advantages of little environmental pollution on air, little stimulation on the skin of a human body, low metal corrosion, strong microbe killing action and high stability.
Description
Technical field
The present invention relates to a kind of chlorine-containing disinfectant, specifically is the chloride effervescent tablet about a kind of low chlorine odor, particle or pulvis and preparation method thereof.
Background technology
Chlorine-containing disinfectant continued to use for 108 more than ten years, begin is that inorganic chlorine is main bleaching powder, floats smart powder, because such preparation is water insoluble, use after usually making supernatant, dosage is difficult to be grasped, and causes the medicament waste, after this use the liquor natrii hypochloritis, available chlorine has only 10%, and very unstable, is difficult to store and transportation.Sixties development organochlorine, dichlord isocyanurice acid, sym-closene, toluene-sodium-sulfonchloramide etc. are made into pulvis with sodium sulphate, and the effective chlorine density height can be water-soluble fully, and good stability.In the late nineteen eighties, successively developed and used chloride disinfection effervescence tablet, particle, the pulvis that the effervesce technology is made, make product meet water and in several minutes, dissolve, the thimerosal clear, in the application correct good stability of dosage, easy to use and be received by the market.Flavor is big but the disadvantage of these chlorine-containing disinfectants is chlorine, brings stimulation to human body, pollutes to air.Therefore developing a kind of chlorine-containing disinfectant of low chlorine odor, for market provides new environment-friendly type chlorine-containing disinfectant, is purpose of the present invention.
Summary of the invention
The invention provides a kind of chloride disinfection effervescence agent of low chlorine odor, it can be disinfection effervescence tablet, particle or pulvis.
Common chlorine-containing disinfectant generates hypochlorous acid owing to meet water, and small amounts of chlorine and hydrogen chloride are so just given in the environment and brought chlorine flavor, bring pollution to air.But by the complexing combination, make the chlorine molecule become " complexing chlorine " state to exist, overflow from solution to reduce the chlorine flavor, make chlorine-containing disinfection liquid more stable, the chlorine flavor of chlorine-containing disinfection liquid just can alleviate greatly like this.
For this reason, the invention provides a kind of chloride disinfection effervescence agent of low chlorine odor, it can be chloride disinfection effervescence tablet, particle or pulvis.It adopts and comprises that following proportion raw material is prepared from.
Form weight %
Organochlorine 10-75
Surfactant 3-20
Sodium salt 1-20
Effervescent agent 10-20
Citric acid 1-15
Boric acid 1-3
Sodium sulphate 1-20
Organochlorine is a disinfection sanitizer in the prescription, and it combines with the surfactant and the sodium salt complexing that play the complexing agent effect, and complexing has more been strengthened in the adding of sodium salt, makes chlorine-containing disinfectant more stable, and the chlorine flavor of chlorine-containing disinfection liquid then alleviates greatly.Effervescent agent and citric acid can make disinfectant rise at bubbly water, impel disinfectant to dissolve fast.Boric acid is lubricate, as releasing agent (preparation sterilization sheet or particle) or as drainage agent (preparation pulvis).Sodium sulphate is to use as filler.
Wherein:
Organochlorine is to be selected from sym-closene, dichlord isocyanurice acid, sodium dichloroisocyanate, toluene-sodium-sulfonchloramide or tetrachloroglycine urea.
Surfactant is to be selected from non-ionic surface active agent, anion surfactant, cationic surfactant or amphoteric surfactant.Wherein non-ionic surface active agent is to be selected from fatty alcohol-polyoxyethylene ether, alkyl acid APEO, fatty acid polyethylene glycol ester or aliphatic amine polyoxyethylene ether; Cationic surfactant is to be selected from dodecyl dimethyl ammonium bromide, two certain herbaceous plants with big flowers base dimethyl ammonium bromide or bromination ethylene two ammoniums; Anion surfactant is to be selected from dodecyl sodium sulfate or lauryl sodium sulfate; Amphoteric surfactant is to be selected from dodecyl dihydroxy ethyl betain, imidazoline amophoteric surface active agent or fluorocarbon surfactant F3.
Sodium salt is to be selected from borax, sodium ascorbyl phosphate, sodium molybdate, Sodium Benzoate or sodium cellulose glycolate.
Effervescent agent is sodium bicarbonate, SODIUM PERCARBONATE or sodium perborate.
The preparation method of the chloride disinfection effervescence agent of low chlorine odor of the present invention
With various powdery solid raw materials respectively at after 40-80 ℃ of dry 0.5-3 hour, with organochlorine, surfactant and sodium salt are evenly mixed, add effervescent agent again, citric acid, boric acid and sodium sulphate, be stirred into powder, sieve, choose the powder of 150 μ m ± 10% particle diameter, be chloride disinfection effervescence pulvis product.After in addition powder being adopted the non-slurry pelletizing machine to make particle, sieve, choose 1000-5000 μ m size particles, be chloride disinfection effervescence granular product, choose 150-1000 μ m size particles and be pressed into tablet, be chloride disinfection effervescence tablet product.
If surfactant is a liquid, then surfactant and sodium salt are blended into pastel, use atomized drying and make powder, mixed with organochlorine again, all the other steps are identical.
Chloride disinfection effervescence tablet, particle or the pulvis of the low chlorine odor that the present invention makes can very rapid dissolving in water, can be mixed with the chlorine-containing disinfection liquid of variable concentrations by difference requirements of using, and the transparent clarification of this thimerosal mixes erosion, precipitates and floating thing.Chloride disinfection effervescence tablet; particle or pulvis can contain different effective chlorine densities; disinfection effervescence pulvis for example; effective chlorine density is 10%; be that every gram pulvis contains available chlorine 100mg, disinfection effervescence particle effective chlorine density is 20%, and promptly every gram particle contains available chlorine 200mg; the disinfection effervescence tablet effective chlorine density is 50%, and every (weighing 1 gram) contains available chlorine 500mg.For example will prepare available chlorine is the 1000ml solution of 1000mg/L, can take by weighing disinfection effervescence pulvis 10 gram, and effervescence granular 5 grams, 2 of disinfection effervescence tablets drop into respectively in the 1000ml water.The article of sterilizing are immersed in the thimerosal and carry out disinfection, or with thimerosal to environment spraying, erasing sterilization, to the aquaculture pond sterilization particle of can directly splashing, utilize the gravity of particle to sink at the bottom of the pond, utilize effervescent effect to reach by progressively sterilizing at the bottom of the pond to the water surface, this disinfection way is more suitable for culturing the sterilization requirement in pond, because low chlorine odor is little to the stimulation of culturing fish and shrimp, sterilization back culture efficiency is splendid.
The thimerosal of the chloride disinfection effervescence agent preparation of low chlorine odor of the present invention when available chlorine is 100mg/L, can 100% be killed staphylococcus aureus, Gram-negative and positive bacteriums such as Escherichia coli; Available chlorine is 250ml/L, can 100% kills Candida albicans, hydrophily virus, influenza virus, AIDS virus and hepatitis viruse; Available chlorine is 1000mg/L, can 100% kills spores of bacillus subtilin.The detection of all bactericidal effects is to be undertaken by the GB15981-1995 method.Drinking water disinfection can be the disinfectant of 5-10mg/L with available chlorine, the environment object is used the thimerosal of available chlorine 100-250mg/L, hospital disinfection can increase in right amount by the sterilization requirement, the sterilization particle carries out aquaculture pond splash about one mu of the water surface of the 1m depth of water of available 200-500 gram of sterilizing, and all can obtain the good sterilization effect.
The chloride disinfection effervescence agent of low chlorine odor of the present invention has following advantage:
1. to be mixed with effective chlorine density be 2000mg/m in the chloride disinfection effervescence agent of low chlorine odor
3During thimerosal, press GB/T 16029-1995 method and detect.Chlorine flavor is not for detecting in the air, and human body almost is to can't smell chlorine flavor (people's sense of smell is 0.03mg/m to the chlorine flavor threshold values
3, be almost to can't smell chlorine flavor).And the thimerosal with same effective chlorine density of common sym-closene preparation, chlorine flavor then is 0.47-0.99mg/m
3, it substantially exceed China air standard allow chlorine from concentration value 0.1mg/m
3
2. the chloride disinfection effervescence agent of low chlorine odor is mixed with effective chlorine density when being the thimerosal of 1000mg/L, and pH value is 6.0-7.0, and the pH value of this neutral range shows that thimerosal is low to the human body skin excitant.
3. because organochlorine is the complexing combination in disinfectant, chlorine-containing disinfection liquid is reduced greatly to metal protection,, carbon steel is not had corrosion substantially stainless steel, copper, aluminium non-corrosiveness.
In sum, the chloride disinfection effervescence agent of low chlorine odor of the present invention is to have three low (low chlorine odors, the low stimulation, low corrosion) the chloride disinfection effervescence agent of feature, be a kind of have few to the air environmental pollution, human body skin is stimulated little, low, strong to the microorganism killing effect to metal erosion, the novel chlorin-containing disinfection effervescence agent that product stability is good can be satisfied the market demand of environmental type disinfectant.
Embodiment
The preparation of embodiment 1 chloride disinfection effervescence pulvis
Solid material is respectively at after 40-70 ℃ of dry 0.5-1 hour, fatty alcohol-polyoxyethylene ether 5kg and sodium molybdate 1kg are mixed into pastel, use atomized drying and make powder, evenly mixed with sym-closene 75kg again, add SODIUM PERCARBONATE 10kg again, citric acid 5kg, boric acid 1kg and sodium sulphate 3kg stir, and adopt the vibrations sieving machine to sieve, choose the powder of 150 μ m ± 10% particle diameter, be chloride disinfection effervescence pulvis product.
The preparation of embodiment 2 chloride disinfection effervescence particles
Solid material is respectively at after 40-60 ℃ of dry 0.5-2 hour; dodecyl dimethyl ammonium bromide 3kg and sodium hydrogen phosphate 10kg are mixed into pastel, use atomized drying and make powder, evenly mixed with toluene-sodium-sulfonchloramide 50kg again; add sodium perborate 15kg again; citric acid 15kg, boric acid 3kg and sodium sulphate 4kg, stirring and evenly mixing; powder adopts the non-slurry pelletizing machine to make particle; use the vibrations sieving machine and sieve, choose 1000-5000 μ m size particles, be chloride disinfection effervescence granular product.
The preparation of embodiment 3 chloride disinfection effervescence pulvis
Solid material is respectively at after 40-80 ℃ of dry 0.5-2 hour, with tetrachloroglycine urea 10kg, dodecyl dihydroxy ethyl betain 20kg and Sodium Benzoate 20kg are evenly mixed, add sodium bicarbonate 20kg again, citric acid 15kg, boric acid 1kg and sodium sulphate 14kg, stirring and evenly mixing, adopt the vibrations sieving machine to sieve, choose the powder of 150 μ m ± 10% particle diameter, be chloride disinfection effervescence pulvis product.
The preparation of embodiment 4 chloride disinfection effervescence tablets
Solid material is respectively at after 40-70 ℃ of dry 0.5-3 hour, and with sodium dichloroisocyanate 60kg, dodecyl sodium sulfate 10kg and borax 5kg are evenly mixed; add sodium bicarbonate 10kg again; citric acid 1kg, boric acid 2kg and sodium sulphate 12kg, stirring and evenly mixing; powder adopts the non-slurry pelletizing machine to make particle; use the vibrations sieving machine and sieve, choose the small pieces that 150-1000 μ m size particles is pressed into the 0.1-5 gram, also can be pressed into 20 grams, 40 grams; the sheet of 100 grams is chloride disinfection effervescence tablet product.
Claims (7)
1, a kind of chloride disinfection effervescence agent of low chlorine odor is characterized in that its employing comprises that following proportion raw material is prepared from:
Form weight %
Organochlorine 10-75
Surfactant 3-20
Sodium salt 1-20
Effervescent agent 10-20
Citric acid 1-15
Boric acid 1-3
Sodium sulphate 1-20
Described organochlorine is to be selected from sym-closene, sodium dichloroisocyanate, toluene-sodium-sulfonchloramide or tetrachloroglycine urea; Described surfactant is to be selected from non-ionic surface active agent, cationic surfactant or amphoteric surfactant; Described sodium salt is to be selected from borax, sodium ascorbyl phosphate, sodium molybdate or Sodium Benzoate.
2, chloride disinfection effervescence agent as claimed in claim 1 is characterized in that it is chloride disinfection effervescence tablet, particle or pulvis.
3, chloride disinfection effervescence agent as claimed in claim 1 is characterized in that described non-ionic surface active agent is to be selected from fatty alcohol-polyoxyethylene ether, alkyl acid APEO, fatty acid polyethylene glycol ester or aliphatic amine polyoxyethylene ether.
4, chloride disinfection effervescence agent as claimed in claim 1 is characterized in that described cationic surfactant is to be selected from dodecyl dimethyl ammonium bromide, two certain herbaceous plants with big flowers base dimethyl ammonium bromide or bromination ethylene two ammoniums.
5, chloride disinfection effervescence agent as claimed in claim 1 is characterized in that described amphoteric surfactant is to be selected from dodecyl dihydroxy ethyl betain, imidazoline amophoteric surface active agent or fluorocarbon surfactant F3.
6, chloride disinfection effervescence agent as claimed in claim 1 is characterized in that described effervescent agent is sodium bicarbonate, SODIUM PERCARBONATE or sodium perborate.
7, the preparation method of the described chloride disinfection effervescence agent of claim 1, it is characterized in that this preparation method's step is: with 40-80 ℃ after dry 0.5-3 hour respectively of various powdery solid raw material, with organochlorine, surfactant and sodium salt are mixed, add effervescent agent again, citric acid, boric acid becomes powder with sodium sulphate, sieve, choose the powder of 150 μ m ± 10% particle diameter, be chloride disinfection effervescence pulvis product, after in addition powder being adopted the non-slurry pelletizing machine to make particle, sieve, choose 1000-5000 μ m size particles, be chloride disinfection effervescence granular product, choose 150-1000 μ m size particles and be pressed into tablet, be chloride disinfection effervescence tablet product;
Surfactant is a liquid, then surfactant and sodium salt is blended into pastel, uses atomized drying and makes powder, and mixed with organochlorine again, all the other steps are identical.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410068135 CN1271931C (en) | 2004-11-12 | 2004-11-12 | Disinfection effervescence tablet, granule or powder containing chlorine with low chlorine odor and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410068135 CN1271931C (en) | 2004-11-12 | 2004-11-12 | Disinfection effervescence tablet, granule or powder containing chlorine with low chlorine odor and preparation method thereof |
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| CN1631154A CN1631154A (en) | 2005-06-29 |
| CN1271931C true CN1271931C (en) | 2006-08-30 |
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| CN 200410068135 Expired - Fee Related CN1271931C (en) | 2004-11-12 | 2004-11-12 | Disinfection effervescence tablet, granule or powder containing chlorine with low chlorine odor and preparation method thereof |
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| US8518941B2 (en) | 2010-08-19 | 2013-08-27 | American Sterilizer Company | Extreme temperature aqueous decontamination composition |
| CN102396465A (en) * | 2011-11-15 | 2012-04-04 | 山东大明消毒科技有限公司 | Trichloroiminocyanuric acid effervescent tablet and preparation method thereof |
| CN102870805A (en) * | 2012-10-20 | 2013-01-16 | 云南省农业科学院农业环境资源研究所 | Disinfector combination for unapplicable tobacco leaf digested and well-rotted residue |
| CN104430515A (en) * | 2014-11-28 | 2015-03-25 | 成都顺发消洗科技有限公司 | Novel disinfectant |
| CN105707077B (en) * | 2016-03-25 | 2019-06-18 | 江苏省农用激素工程技术研究中心有限公司 | For preventing and treating the dichloro quinolinic acid herbicidal single dose of rape field weed |
| CN106675797B (en) * | 2016-12-26 | 2019-12-06 | 李心 | Chlorine-containing composite disinfecting detergent and preparation method thereof |
| CN108849873A (en) * | 2018-04-20 | 2018-11-23 | 吴礼高 | A kind of deodorization and disinfection piece preparation method for the disinfection of infectious clinical waste |
| CN109080986A (en) * | 2018-07-10 | 2018-12-25 | 湖州燕子果业有限公司 | A kind of fruits transport packing box |
| CN111972421A (en) * | 2019-05-21 | 2020-11-24 | 山东佳洁净水处理科技有限公司 | Fragrant chlorine-containing disinfection tablet |
| CN110663695A (en) * | 2019-10-14 | 2020-01-10 | 常州市金太阳动物保健品有限公司 | Trichloroisocyanuric acid disinfectant and processing method thereof |
| CN111454780A (en) * | 2020-05-11 | 2020-07-28 | 张文琳 | Washing machine tank cleaning agent |
| CN114766509A (en) * | 2022-05-16 | 2022-07-22 | 深圳市玛斯特威科技开发有限公司 | Aviation disinfectant and preparation method thereof |
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2004
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| CN1631154A (en) | 2005-06-29 |
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