JPH05117872A - Production of composite member - Google Patents

Production of composite member

Info

Publication number
JPH05117872A
JPH05117872A JP30994291A JP30994291A JPH05117872A JP H05117872 A JPH05117872 A JP H05117872A JP 30994291 A JP30994291 A JP 30994291A JP 30994291 A JP30994291 A JP 30994291A JP H05117872 A JPH05117872 A JP H05117872A
Authority
JP
Japan
Prior art keywords
capsule
particles
composite
fitted
particle
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP30994291A
Other languages
Japanese (ja)
Inventor
Satoru Ishizuka
哲 石塚
Shinji Yamamoto
真二 山本
Nobuhiro Fujita
伸弘 藤田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzuki Motor Corp
Original Assignee
Suzuki Motor Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzuki Motor Corp filed Critical Suzuki Motor Corp
Priority to JP30994291A priority Critical patent/JPH05117872A/en
Publication of JPH05117872A publication Critical patent/JPH05117872A/en
Pending legal-status Critical Current

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  • Other Surface Treatments For Metallic Materials (AREA)

Abstract

PURPOSE:To form a composite layer with a particle on a surface by coating the surface except a required part with a capsule and impregnating the particle for composite by pressurizing. CONSTITUTION:The capsule 4a with which the surface except the specific part of the parts 4 to be treated is coated is fitted in freely attachably and detachably. Then the parts 4 to be treated is buried, for example, with the specific amount of the ceramic particle 3 having 0.01-100mum particle diameter on the under punch 2 in the press mold 1 heated at 0-1200 deg.C. The ceramic particle 3 is impregnated into the surface of the parts 4 by pressurizing to 10-10000kgf/cm<2> with the upper punch 5. The composite layer is formed on the surface except the part coated with the capsule 4a and the composite member having excellent hardness, wear resistance, heat resistance, tensile strength, fatigue strength, Young's modulus or the like is obtained.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は金属,金属間化合物,樹
脂,木材などの材料をマトリックスとして、粒子、たと
えば金属やセラミックス等の粒子を特定表面に複合化し
てなる複合部材の製造方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for producing a composite member in which particles such as metal and ceramics are compounded on a specific surface by using a material such as metal, intermetallic compound, resin and wood as a matrix.

【0002】[0002]

【従来の技術】複合材料に関し、次のような従来技術が
知られている。たとえば、SiCやCなどの繊維やウィ
スカーでプリフォームを製作し、これを金型内にセット
したあと、Al合金などの溶湯を注いで、プリフォーム
に加圧含浸させることで複合材料(FRM)とする方法
である。また、SiCやCなどの粒子を、完全溶融、ま
たは部分溶融の溶湯に添加し、これに機械的撹拌を与え
て複合材料(MMC)とするコンポキャスト法がある。
さらにSiCやCなどの粒子とAl合金等の粉末とを混
合し、静水圧々縮や熱間押出し、または焼結等によって
複合材料を製造する方法(粉末冶金法)が広くおこなわ
れている。また、SiCやCなどの粒子とAl合金等の
粉末を混合し、これに冷間や熱間で機械的撹拌を与え
て、合金粉末中にSiCやCなどの粒子を練込み、粒子
分散複合材料とする方法(メカニカルアロイング法)が
ある。
2. Description of the Related Art Regarding composite materials, the following conventional techniques are known. For example, a composite material (FRM) is manufactured by making a preform from fibers such as SiC or C or whiskers, setting it in a mold, then pouring a molten metal such as an Al alloy, and impregnating the preform with pressure. And the method. Further, there is a compocast method in which particles such as SiC and C are added to a molten metal which is completely melted or partially melted and mechanical stirring is applied to the molten metal to form a composite material (MMC).
Further, a method (powder metallurgy) for mixing composite particles such as SiC and C and powder such as Al alloy, and producing a composite material by hydrostatic pressing, hot extrusion, or sintering is widely used. In addition, particles such as SiC and C are mixed with powder such as Al alloy, and mechanical stirring is applied to this powder in cold or hot to knead particles such as SiC and C into the alloy powder to obtain a particle dispersion composite. There is a method of using as a material (mechanical alloying method).

【0003】[0003]

【発明が解決しようとする課題】本発明では、金属,金
属間化合物,樹脂,木材及び其他の材料又は部品(以
下、部材とする)の外表面の特定部に複合用の粒子たと
えばセラミックス等の粒子を侵入させてなる複合化層を
設けた部材を対象とするもので、前記コンポキャスト法
や、粉末冶金法及びメカニカルアロイング法による方法
は、材料全体に粒子等を均一に分散させる方法であり、
表面だけを複合化することはできない。さらに粉末冶金
法やメカニカルアロイング法に用いる合金粉末は高価で
あり、また完成品を得るまでの工程が多くかかる。さら
に素材製造の最終工程が押し出し加工であるため、完成
品形状が単純なものに限られてしまうという問題点があ
る。本発明は前記事情に鑑みてなされたもので、前記問
題点を解消するとともに、表層部の特定の部分だけを複
合化した複合部材の製造方法を提供することを目的とす
る。
SUMMARY OF THE INVENTION According to the present invention, metal, intermetallic compound, resin, wood and other materials or parts (hereinafter referred to as members) are provided with composite particles such as ceramics on a specific portion on the outer surface thereof. It is intended for a member provided with a composite layer formed by infiltrating particles, and the above-mentioned compocast method, powder metallurgy method and mechanical alloying method is a method of uniformly dispersing particles etc. in the entire material. Yes,
It is not possible to compound only the surface. Further, alloy powder used in powder metallurgy or mechanical alloying is expensive, and many steps are required to obtain a finished product. Further, since the final process of manufacturing the material is extrusion, the shape of the finished product is limited to a simple one. The present invention has been made in view of the above circumstances, and an object of the present invention is to solve the above problems and to provide a method for manufacturing a composite member in which only a specific portion of a surface layer portion is composited.

【0004】[0004]

【課題を解決するための手段】前記目的に添い、本発明
は部材の特定部以外の表面に着脱可能なカプセルを嵌着
しておき、所定温度にした加圧型内に収容した所定量の
複合用の粒子内に、前記部材を埋込み、これを粒子の外
側から加圧して、又は粒子中に特定部以外の表面に着脱
可能なカプセルを嵌着した部材を埋込み、これを更に筒
内に密閉し、それの外側から加圧して部材の特定部表面
のみに粒子を侵入させ、そこに粒子との複合化層を形成
することにより、前記課題を解消した。
According to the present invention, in accordance with the above object, a detachable capsule is fitted on a surface other than a specific portion of a member, and a predetermined amount of a composite is housed in a pressurizing mold heated to a predetermined temperature. The above-mentioned member is embedded in the particles for use, and this is pressed from the outside of the particle, or a member in which a removable capsule is attached to the surface other than a specific part is embedded in the particle, and this is further sealed in the cylinder. Then, the above problem was solved by applying pressure from the outside of the member to cause the particles to enter only the surface of the specific portion of the member and form a composite layer with the particles there.

【0005】以下、本発明について、図面を参照しなが
ら詳細に説明する。本発明において対象とする粒子とし
ては、セラミックス,金属などがあり、たとえばセラミ
ックスとしては、SiC、Si3 4 、SiO2 、Al
2 3 などのセラミックス粒子を用いる。またFe粒子
などを用いる。これらの粒子は粒子と短繊維の混合物や
短繊維単体を使用することもできる。マトリックスは金
属,金属間化合物,樹脂,木材及び其他の材料を用い
る。なお金属としては、たとえばAl合金,Mg合金及
び其他慣用の金属や合金を、金属間化合物としてはAl
3 Tiなどを、樹脂材料としては通常の部材に採用され
ている一般の樹脂類を、木材としては、たとえば桧材な
どを用いる。
The present invention will be described in detail below with reference to the drawings. The particles targeted in the present invention include ceramics and metals, and examples of the ceramics include SiC, Si 3 N 4 , SiO 2 and Al.
Ceramic particles such as 2 O 3 are used. Further, Fe particles or the like is used. As these particles, a mixture of particles and short fibers or a single short fiber may be used. The matrix uses metal, intermetallic compound, resin, wood and other materials. Examples of metals include Al alloys, Mg alloys and other commonly used metals and alloys, and examples of intermetallic compounds include Al.
3 Ti and the like are used, as the resin material, general resins that are used in ordinary members are used, and as the wood, for example, cypress is used.

【0006】まず、前記マトリックス製の部品、たとえ
ば金属部品について、複合化層を設ける特定部以外の表
面に金属や樹脂等で形成したカプセルを嵌着する。この
カプセルは、処理を施す部品の形状に合せて着脱できる
ように製作する。すなわち、図1〜図2に示すように処
理すべき部品の表面を覆う箱状のカプセル4aを製作
し、該カプセル4aを部品(ベーン)4に図示のように
着脱可能に嵌着する。またカプセル4aと部品4との間
に隙間がある場合は樹脂などの充填材やテープで塞ぐ。
次に、図3に示すように0〜1200℃の温度にした加
圧型1内の下パンチ2上に、たとえば前記セラミックス
粒子3を所定量収容する。この場合、セラミックス粒子
3も、後の加圧工程での前記部品4表面への侵入を容易
にするため、予め0〜1200℃の温度にしておく。ま
たセラミックス粒子は粒子径0.01〜100μmのも
のを用いて複合材としての強度を確保する。次に、加圧
型1内のセラミックス粒子3内に、カプセル4aを嵌着
した部品4を所定の温度にして埋込む。なお、この部品
4はカプセル4aを嵌着していない部分のみを予熱する
ようにしてもよい。またセラミックス粒子中に前記部品
4を埋込んでおいて、セラミックス粒子とともに同時に
加熱してもよい。次に、部品4を埋込んだ加圧型1内の
セラミックス粒子3の上方から、上パンチ5により、1
0〜10,000kgf/cm2 の圧力P1 を加え、部
品4の表面にセラミックス粒子3を侵入させる。この場
合、カプセル4aが嵌着されている部分はセラミックス
粒子3の侵入が阻止され、露出部のみの表面に複合化層
が形成される。なお、この処理は金型内のセラミックス
粒子の量を加減することによって前記部品の複数処理が
可能である。処理後はカプセル4aを部品4から取り外
し、次の部品に同様に嵌着して同様な処理を繰返せばよ
い。以上の処理は、部品の酸化を防止するため、真空ま
たは不活性ガスの雰囲気でおこなってもよい。
First, with respect to the matrix-made component, for example, a metal component, a capsule made of metal, resin or the like is fitted on the surface other than the specific portion where the composite layer is provided. This capsule is manufactured so that it can be attached and detached according to the shape of the component to be treated. That is, as shown in FIGS. 1 and 2, a box-shaped capsule 4a that covers the surface of a component to be treated is manufactured, and the capsule 4a is detachably fitted to the component (vane) 4 as shown in the drawing. If there is a gap between the capsule 4a and the component 4, it is closed with a filler such as resin or a tape.
Next, as shown in FIG. 3, for example, a predetermined amount of the ceramic particles 3 is accommodated on the lower punch 2 in the pressure die 1 which is heated to a temperature of 0 to 1200 ° C. In this case, the ceramic particles 3 are also preliminarily kept at a temperature of 0 to 1200 ° C. in order to facilitate their entry into the surface of the component 4 in the subsequent pressing step. The strength of the composite material is secured by using ceramic particles having a particle diameter of 0.01 to 100 μm. Next, the component 4 in which the capsule 4a is fitted is embedded in the ceramic particles 3 in the pressure mold 1 at a predetermined temperature. The component 4 may be preheated only at the portion where the capsule 4a is not fitted. Further, the component 4 may be embedded in the ceramic particles and heated simultaneously with the ceramic particles. Next, from above the ceramic particles 3 in the pressure mold 1 in which the component 4 is embedded, by the upper punch 5, 1
A pressure P 1 of 0 to 10,000 kgf / cm 2 is applied to inject the ceramic particles 3 into the surface of the component 4. In this case, the ceramic particles 3 are prevented from entering the portion where the capsule 4a is fitted, and the composite layer is formed only on the surface of the exposed portion. In addition, this treatment can perform a plurality of treatments of the component by adjusting the amount of ceramic particles in the mold. After the treatment, the capsule 4a may be removed from the component 4, fitted to the next component in the same manner, and the same treatment may be repeated. The above treatment may be performed in a vacuum or in an atmosphere of an inert gas in order to prevent oxidation of the parts.

【0007】次に、他の方法として、まず、後に加圧を
受ける筒中にセラミックス粒子を充填し、次いで前記カ
プセルを嵌着した前記部品をその内に埋込む。筒は内部
を減圧し、密封する。その後、この筒ごと所定の温度
(0〜1200℃)として、10〜10,000kgf
/cm2 の静水圧(CIPやHIP)を筒の外側から与
えてカプセルから露出している部品表面に複合化層を形
成する。以上の方法はロッカーアーム、スプロケットギ
ア、バルブリフター、ベーン等々及び其他各種の部材に
ついて適用することができる。なお、本発明は前記のよ
うにマトリックス部材に対する複合用の粒子にセラミッ
クス粒子を用いて説明したが、特定のマトリックス部材
に特定の物質、たとえばFe粒子などを加圧侵入させ
て、特定の複合層を形成することも可能であり、本発明
は前記実施例のみに限定されるものではない。
Next, as another method, first, ceramic particles are filled in a cylinder which is to be pressurized later, and then the component fitted with the capsule is embedded therein. The cylinder is depressurized and sealed. After that, as a predetermined temperature (0 to 1200 ° C.) for each cylinder, 10 to 10,000 kgf
Hydrostatic pressure (CIP or HIP) of / cm 2 is applied from the outside of the cylinder to form the composite layer on the surface of the component exposed from the capsule. The above method can be applied to rocker arms, sprocket gears, valve lifters, vanes, and other various members. Although the present invention has been described by using the ceramic particles as the composite particles for the matrix member as described above, a specific substance such as Fe particles is pressure-penetrated into a specific matrix member to form a specific composite layer. Can be formed, and the present invention is not limited to the above-mentioned embodiments.

【0008】[0008]

【実施例】1)ASTM A390を材料として、切削
加工によりベーンを製作した。次に、このベーンの複合
化処理を施さない部分を被覆する方形状のカプセルを、
厚さ2mmのJIS A1050の材料で製作した。こ
のカプセルをベーンに嵌着し(図1,図2参照)、これ
を350℃に予熱しておく。一方、300℃に予熱して
ある加圧型内に550℃に加熱した平均粒子径1μmの
SiC粒子を入れ、その中に前記ベーンを埋没させて、
上パンチにより100MPaの静水圧を5分間加えた。
その結果、図4に示すように表面の特定部に複合層4b
を有するベーンが製造できた。
[Examples] 1) A vane was produced by cutting using ASTM A390 as a material. Next, a rectangular capsule that covers the part of the vane that is not subjected to the composite treatment,
It was made of a JIS A1050 material having a thickness of 2 mm. The capsule is fitted in a vane (see FIGS. 1 and 2) and preheated to 350 ° C. On the other hand, SiC particles having an average particle diameter of 1 μm heated to 550 ° C. are put into a pressure mold which has been preheated to 300 ° C., and the vane is embedded therein,
A hydrostatic pressure of 100 MPa was applied by the upper punch for 5 minutes.
As a result, as shown in FIG. 4, the composite layer 4b is formed on the specific portion of the surface.
A vane having

【0009】2)JIS AC8Aを材料として、熱間
鍛造により図5に示すようなバルブリテーナー8を製造
した。これに厚さ1.5mmのJIS SPCCで製作
したカプセル8aを図6に示すように嵌着した。次に、
図7に示すようにJIS SPCC製筒9内に、平均粒
子径1μmのSiC粒子3を充填し、その中にカプセル
8aを嵌着したバルブリテーナー8を埋没させて、筒9
の内部を0.1Pa程度に減圧後、溶接密閉した。更に
これをHIP装置により全体を200℃に加熱しつつ、
100MPaの静水圧P2 を5分間加え、其後カプセル
8aを取り外した。その結果、図8に示すようにカプセ
ル8aで被覆されていなかったバルブリテーナー8の表
面に、SiC粒子が侵入した複合層8bが形成された。
なお、取り外したカプセル8aは同様な他のバルブリテ
ーナーに嵌着して同様な処理を繰返した。
2) A valve retainer 8 as shown in FIG. 5 was manufactured by hot forging using JIS AC8A as a material. A capsule 8a having a thickness of 1.5 mm and manufactured by JIS SPCC was fitted therein as shown in FIG. next,
As shown in FIG. 7, a JIS SPCC cylinder 9 is filled with SiC particles 3 having an average particle diameter of 1 μm, and a valve retainer 8 having a capsule 8a fitted therein is buried to form a cylinder 9
The inside of the container was depressurized to about 0.1 Pa and then sealed by welding. Furthermore, while heating the whole to 200 ° C with a HIP device,
Hydrostatic pressure P 2 of 100 MPa was applied for 5 minutes, and then the capsule 8a was removed. As a result, as shown in FIG. 8, on the surface of the valve retainer 8 which was not covered with the capsule 8a, a composite layer 8b into which SiC particles had invaded was formed.
The removed capsule 8a was fitted to another similar valve retainer and the same treatment was repeated.

【0010】[0010]

【発明の効果】本発明によれば、金属,金属間化合物,
樹脂,木材及び其他の部材の特定の表面に複合用の粒子
との複合化層を形成していき、複合化した部分において
は、マトリックス材料そのものよりも硬度、耐摩耗性、
耐熱性、引張強度、疲労強度、ヤング率等が優れたもの
がえられる。またカプセルを着脱して繰返して使用すれ
ばよく、方法自体も簡単であり、さらに表面だけを部分
的に複合化するのでセラミックス粒子の使用量も少なく
てすみ、したがって比較的にコストがかからない処理方
法である。
According to the present invention, a metal, an intermetallic compound,
By forming a composite layer with particles for composite on a specific surface of resin, wood and other members, in the composite part, hardness, wear resistance,
A material having excellent heat resistance, tensile strength, fatigue strength, Young's modulus, etc. can be obtained. In addition, the capsule itself can be detached and used repeatedly, the method itself is simple, and since only the surface is partially compounded, the amount of ceramic particles used is small, and therefore the treatment method is relatively inexpensive. Is.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明に係る方法で処理する部材(ベーン)に
カプセルを嵌着した状態を示す説明図である。
FIG. 1 is an explanatory view showing a state in which a capsule is fitted to a member (vane) to be treated by the method according to the present invention.

【図2】図1におけるA−A断面の説明図である。FIG. 2 is an explanatory diagram of a cross section taken along the line AA in FIG.

【図3】本発明に係る方法の実施要領の説明図である。FIG. 3 is an explanatory diagram of an implementation point of a method according to the present invention.

【図4】本発明に係る方法で処理した部材の説明図であ
る。
FIG. 4 is an explanatory view of a member treated by the method according to the present invention.

【図5】同じく本発明に係る方法を適用する他の部材
(バルブリテーナー)の説明図である。
FIG. 5 is an explanatory diagram of another member (valve retainer) to which the method according to the present invention is also applied.

【図6】図5に示す部材にカプセルを嵌着した状態の断
面説明図である。
6 is a cross-sectional explanatory view of a state in which a capsule is fitted to the member shown in FIG.

【図7】本発明に係る他の方法を図6に示す部材に対し
て実施している状態の説明図である。
FIG. 7 is an explanatory diagram showing a state in which another method according to the present invention is applied to the member shown in FIG.

【図8】図7に示す方法で処理した部材の断面説明図で
ある。
FIG. 8 is an explanatory cross-sectional view of a member processed by the method shown in FIG.

【符号の説明】[Explanation of symbols]

1 加圧型 2 下パンチ 3 セラミックス粒子 4 部品(ベーン) 4a カプセル 4b 複合層 5 上パンチ 8 バルブリテーナー 8a カプセル 8b 複合層 9 筒 1 Pressurized Type 2 Lower Punch 3 Ceramic Particles 4 Parts (Vane) 4a Capsule 4b Composite Layer 5 Upper Punch 8 Valve Retainer 8a Capsule 8b Composite Layer 9 Tube

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 部材の特定部以外の表面に着脱可能なカ
プセルを嵌着しておき、所定温度にした加圧型内に収容
した所定量の複合用の粒子内に、前記部材を埋込み、こ
れを粒子の外側から加圧して、部材の特定部表面のみに
粒子を侵入させ、そこに粒子との複合化層を形成するこ
とを特徴とする複合部材の製造方法。
1. A removable capsule is fitted on the surface of the member other than a specific portion, and the member is embedded in a predetermined amount of composite particles contained in a pressure mold heated to a predetermined temperature. Is applied from the outside of the particles to allow the particles to invade only the surface of a specific portion of the member and form a composite layer with the particles therein.
【請求項2】 複合用の粒子中に、特定部以外の表面に
着脱可能なカプセルを嵌着した部材を埋込み、更にこれ
らを筒内に密封して、全体を所定温にしつつ静水圧を加
えて、部材の特定部表面のみに複合化層を形成すること
を特徴とする複合部材の製造方法。
2. A member for which a removable capsule is fitted to the surface other than a specific portion is embedded in the particles for composite use, and these are sealed in a cylinder, and hydrostatic pressure is applied while keeping the whole at a predetermined temperature. And a composite layer is formed only on the surface of a specific portion of the member.
JP30994291A 1991-10-29 1991-10-29 Production of composite member Pending JPH05117872A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP30994291A JPH05117872A (en) 1991-10-29 1991-10-29 Production of composite member

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP30994291A JPH05117872A (en) 1991-10-29 1991-10-29 Production of composite member

Publications (1)

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JPH05117872A true JPH05117872A (en) 1993-05-14

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Family Applications (1)

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JP30994291A Pending JPH05117872A (en) 1991-10-29 1991-10-29 Production of composite member

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JP (1) JPH05117872A (en)

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