JPH0493360A - Antifungal resin composition - Google Patents
Antifungal resin compositionInfo
- Publication number
- JPH0493360A JPH0493360A JP20797490A JP20797490A JPH0493360A JP H0493360 A JPH0493360 A JP H0493360A JP 20797490 A JP20797490 A JP 20797490A JP 20797490 A JP20797490 A JP 20797490A JP H0493360 A JPH0493360 A JP H0493360A
- Authority
- JP
- Japan
- Prior art keywords
- resin
- group
- salt
- compsn
- propionate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011342 resin composition Substances 0.000 title claims description 8
- 230000000843 anti-fungal effect Effects 0.000 title abstract description 4
- 229940121375 antifungal agent Drugs 0.000 title abstract 2
- 239000011347 resin Substances 0.000 claims abstract description 22
- 229920005989 resin Polymers 0.000 claims abstract description 22
- 229920002050 silicone resin Polymers 0.000 claims abstract description 5
- 229920005992 thermoplastic resin Polymers 0.000 claims abstract description 4
- 150000001860 citric acid derivatives Chemical class 0.000 claims abstract description 3
- 230000000844 anti-bacterial effect Effects 0.000 claims description 11
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 10
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims description 5
- 239000000395 magnesium oxide Substances 0.000 claims description 5
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 5
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 5
- 239000011787 zinc oxide Substances 0.000 claims description 5
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 2
- 150000003016 phosphoric acids Chemical class 0.000 claims description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- -1 NaHCO3) Chemical class 0.000 abstract description 7
- XBDQKXXYIPTUBI-UHFFFAOYSA-N Propionic acid Chemical class CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 abstract description 3
- 229920013716 polyethylene resin Polymers 0.000 abstract description 3
- WSWCOQWTEOXDQX-MQQKCMAXSA-M (E,E)-sorbate Chemical class C\C=C\C=C\C([O-])=O WSWCOQWTEOXDQX-MQQKCMAXSA-M 0.000 abstract description 2
- 150000003839 salts Chemical class 0.000 abstract description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 abstract 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 abstract 2
- 238000013329 compounding Methods 0.000 abstract 2
- 241000233866 Fungi Species 0.000 abstract 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 abstract 1
- 150000005323 carbonate salts Chemical class 0.000 abstract 1
- 229940071120 dehydroacetate Drugs 0.000 abstract 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 abstract 1
- 235000017557 sodium bicarbonate Nutrition 0.000 abstract 1
- JXKPEJDQGNYQSM-UHFFFAOYSA-M sodium propionate Chemical compound [Na+].CCC([O-])=O JXKPEJDQGNYQSM-UHFFFAOYSA-M 0.000 abstract 1
- 229960003212 sodium propionate Drugs 0.000 abstract 1
- 235000010334 sodium propionate Nutrition 0.000 abstract 1
- 239000004324 sodium propionate Substances 0.000 abstract 1
- 239000004033 plastic Substances 0.000 description 9
- 229920003023 plastic Polymers 0.000 description 9
- 241000894006 Bacteria Species 0.000 description 8
- 239000003242 anti bacterial agent Substances 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 4
- 239000000428 dust Substances 0.000 description 4
- 235000013305 food Nutrition 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- 239000004745 nonwoven fabric Substances 0.000 description 4
- 239000012785 packaging film Substances 0.000 description 4
- 229920006280 packaging film Polymers 0.000 description 4
- 229920001296 polysiloxane Polymers 0.000 description 4
- 235000013311 vegetables Nutrition 0.000 description 4
- PZRWFKGUFWPFID-UHFFFAOYSA-N 3,9-dioctadecoxy-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound C1OP(OCCCCCCCCCCCCCCCCCC)OCC21COP(OCCCCCCCCCCCCCCCCCC)OC2 PZRWFKGUFWPFID-UHFFFAOYSA-N 0.000 description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 239000001963 growth medium Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 241000228245 Aspergillus niger Species 0.000 description 1
- BCZXFFBUYPCTSJ-UHFFFAOYSA-L Calcium propionate Chemical compound [Ca+2].CCC([O-])=O.CCC([O-])=O BCZXFFBUYPCTSJ-UHFFFAOYSA-L 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- GIATZHZBSIMOEE-UHFFFAOYSA-N P(O)(O)O.P(O)(O)O.C(C)(C)(C)C1=C(C=CC(=C1)C(C)(C)C)C(O)(C(CO)(CO)CO)C1=C(C=C(C=C1)C(C)(C)C)C(C)(C)C Chemical compound P(O)(O)O.P(O)(O)O.C(C)(C)(C)C1=C(C=CC(=C1)C(C)(C)C)C(O)(C(CO)(CO)CO)C1=C(C=C(C=C1)C(C)(C)C)C(C)(C)C GIATZHZBSIMOEE-UHFFFAOYSA-N 0.000 description 1
- RRFWWSOELBTKEK-UHFFFAOYSA-N P(O)(O)O.P(O)(O)O.C(CCCCCCCCCCCCCCCCC)C(O)(C(CO)(CO)CO)CCCCCCCCCCCCCCCCCC Chemical compound P(O)(O)O.P(O)(O)O.C(CCCCCCCCCCCCCCCCC)C(O)(C(CO)(CO)CO)CCCCCCCCCCCCCCCCCC RRFWWSOELBTKEK-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920001218 Pullulan Polymers 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 241000223259 Trichoderma Species 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 235000019402 calcium peroxide Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 210000000003 hoof Anatomy 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000002504 physiological saline solution Substances 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920001955 polyphenylene ether Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 235000019423 pullulan Nutrition 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 229940075554 sorbate Drugs 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- CFAVHELRAWFONI-UHFFFAOYSA-N tris(2,4-dibutylphenyl) phosphite Chemical compound CCCCC1=CC(CCCC)=CC=C1OP(OC=1C(=CC(CCCC)=CC=1)CCCC)OC1=CC=C(CCCC)C=C1CCCC CFAVHELRAWFONI-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
本発明は、例えば坦、ボール、ザル、シールウェア、シ
リコンバッキング、野菜収納箱のようなプラスチック製
の台所用品、プラスチック製の風呂場用品やトイレ用品
、食品包装用のフィルムとか塵袋、その他歯ブラシ、不
織布、衣類などに利用される抗菌効果を有する樹脂組成
物に関するものである。The present invention is applicable to plastic kitchen utensils such as plates, bowls, colanders, sealware, silicone backings, vegetable storage boxes, plastic bathroom utensils and toilet utensils, food packaging films and dust bags, and other toothbrushes. The present invention relates to a resin composition having an antibacterial effect that is used for nonwoven fabrics, clothing, etc.
従来より、例えば坦、ボール、ザル、シールウェア、シ
リコンバッキング、野菜収納箱のようなプラスチック製
の台所用品、プラスチック製の風呂場用品やトイレ用品
、食品包装用のフィルムとか塵袋、その他歯ブラシ、不
織布、衣類などに合成樹脂が利用されて来ていること周
知の通りである。
ところで、これらの製品において、今日、黴の発生が問
題になっている。
すなわち、生活水準の向上につれて清潔感が求められ、
上記のような製品にあっては黴が特に嫌われている。
しかしながら、上記のような製品は黴が発生し易い雰囲
気で使われることが多く、プラスチック製品と蹄も黴が
発生している。Traditionally, we have produced plastic kitchen utensils such as plates, bowls, colanders, sealware, silicone backings, vegetable storage boxes, plastic bathroom and toilet utensils, food packaging films and dust bags, toothbrushes, etc. It is well known that synthetic resins have been used for nonwoven fabrics, clothing, and the like. Incidentally, mold generation has become a problem in these products today. In other words, as living standards improve, a sense of cleanliness is required.
Mold is particularly disliked in products such as those mentioned above. However, products such as those mentioned above are often used in environments where mold is likely to grow, and plastic products and hooves are also prone to mold.
本発明の目的は、黴（細菌）が発生しにくい、すなわち
抗菌効果を有する樹脂組成物を提供することである。
上記本発明の目的は、熱加硫型のシリコン樹脂及び熱可
塑性樹脂の中から選ばれる少なくとも一種の樹脂の中に
、酸化亜鉛、酸化マグネシウム、及びプロピオン酸塩の
群の中から選ばれる少なくとも一種が混入されてなるこ
とを特徴とする抗菌効果を有する樹脂組成物によって達
成される。
尚、上記の抗菌効果を有する樹脂組成物において、樹脂
の中には、酸化亜鉛、酸化マグネシウム、及び例えばプ
ロピオン酸Ｎａやプロピオン酸Ｃａ等のプロピオン酸塩
の群の中から選ばれる少なくとも一種の他に、ＣａＯ１
例えばＮ ａ ＨＣＯｓ、Ｎａ、ＣＯ３等の炭酸塩、例
えばクエン酸Ｎａ等のクエン酸塩、ソルビン酸塩、デヒ
ドロ酢酸塩、例えばＫＨ，ＰＯ４、Ｋｚ ＨＰＯ，、Ｎ
ａＨ２ＰＯａ 、Ｎａｚ ＨＰＯａ 、サイクリックネ
オペンタンテトライルビス（オクタデシルホスファイト
）（ＣＰＴＢＯＰ）、ビス（２，４−ジ−ｔ−ブチルフ
ェニル）ペンタエリスリトール−ジ−ホスファイト（Ｂ
ＢＰＥＰ）、テトラキス（２，４−ジー１−ブチルフェ
ニル）４．４ −ビフェニレンジ−ホスファイト、トリ
ス（２，４−ジーを一ブチルフェニル）ホスファイト、
ジステアリルペンタエリスリトール−ジ−ホスファイト
等のリン酸化合物の群の中から選ばれる少なくとも一種
が混入されてなるものが好ましい。
又、これらの化合物の量は、これらの化合物の種類や用
いられる樹脂の種類によって多少の差異はあるが、酸化
亜鉛、酸化マグネシウム、及びプロピオン酸塩の群の中
から選ばれる化合物の量は約０．３〜１０％程度である
ことが好ましく、より望ましくは０．５〜３％程度であ
ることが好ましく、ス、ＣａＯ２炭酸塩、クエン酸塩、
ソルビン酸塩、デしドロ酢酸塩、リン酸化合物の群の中
から選ばれる化合物の量は約１％以下であることが好ま
しく、より望ましくは０． １〜０． ６％程度である
ことが好ましい。
以下、本発明をさらに説明する。
例えば坦、ポール、ザル、シールウェア、シリコンバッ
キング、野菜収納箱のようなプラスチック製の台所用品
、プラスチック製の風呂場用品やトイレ用品、食品包装
用のフィルムとか塵袋、その他歯ブラシ、不織布、衣類
などの製品は、例えば熱加硫型シリコン樹脂（３００〜
４００ ’Ｃで加硫）やポリエチレン樹脂（ＰＥ）、ポ
リプロピレン樹脂（ＰＰ）、ポリスチレン樹脂、ポリエ
チレンテレフタレート、ポリフェニレンエーテル、ポリ
アクリロニトリル、ポリブチレンテレフタレート、メタ
クリル酸樹脂、塩化ビニル系の樹脂といったような熱可
塑性の樹脂を用いて製造されることが多い。
ところで、これらの樹脂に抗菌効果を付与する為には、
これらの樹脂中に抗菌剤を練り込んでおけば良いと考え
られる。
しかしながら、本願発明者により、抗菌剤を樹脂粉末と
共に混合し、これを基にして所定の成型手段で所望の商
品を製造し、この商品の抗菌効果を調べた処、このもの
は期待に沿えるものではなかった。
この原因についての子細な検討が行われた結果、樹脂中
に練り込まれた筈の抗菌剤が成型時の熱により抗菌特性
が喪失されるに至ることが推定された。
そこで、このような観点から、製品の製造後において、
その表面に抗菌剤をコーティングすることが考えられた
のであるが、このものでは抗菌効果の永続性に疑問があ
った。
それ故、成型時の熱によっても抗菌特性が喪失しない抗
菌剤に研究の主眼点が置かれた。
又、更なる研究の結果、成型時などに樹脂に添加される
各種の添加剤と反応しにくいものであることも望ましい
ことが判ってきた。
かつ、樹脂中に混入された薬剤が樹脂中で均一に分散し
ており、しかも徐々に表面にブリードしてくるものであ
ることも大事であることが判ってきた。
そして、このような観点に沿っての研究開発が進められ
た結果、本発明が達成されたのである。An object of the present invention is to provide a resin composition that is less likely to generate mold (bacteria), that is, has an antibacterial effect. The object of the present invention is to provide at least one resin selected from the group of zinc oxide, magnesium oxide, and propionate in at least one resin selected from heat-curable silicone resins and thermoplastic resins. This is achieved by a resin composition having an antibacterial effect, which is characterized by being mixed with. In addition, in the resin composition having the above-mentioned antibacterial effect, the resin contains at least one other material selected from the group of zinc oxide, magnesium oxide, and propionate salts such as Na propionate and Ca propionate. , CaO1
Carbonates such as Na HCOs, Na, CO3, citrates such as Na citrate, sorbates, dehydroacetates such as KH, PO4, Kz HPO,, N
aH2POa, Naz HPOa, cyclic neopentanetetrayl bis(octadecyl phosphite) (CPTBOP), bis(2,4-di-t-butylphenyl)pentaerythritol-di-phosphite (B
BPEP), tetrakis(2,4-di-1-butylphenyl)4,4-biphenylenedi-phosphite, tris(2,4-di-butylphenyl)phosphite,
Preferably, at least one selected from the group of phosphoric acid compounds such as distearylpentaerythritol di-phosphite is mixed therein. Although the amount of these compounds varies somewhat depending on the type of these compounds and the type of resin used, the amount of the compound selected from the group of zinc oxide, magnesium oxide, and propionate is approximately It is preferably about 0.3 to 10%, more preferably about 0.5 to 3%, and contains salt, CaO2 carbonate, citrate,
Preferably, the amount of the compound selected from the group of sorbate, dedroacetate, and phosphate compounds is about 1% or less, more preferably 0. 1~0. It is preferably about 6%. The present invention will be further explained below. For example, plastic kitchen utensils such as plates, poles, colanders, sealware, silicone backings, vegetable storage boxes, plastic bathroom and toilet utensils, food packaging films and dust bags, other toothbrushes, non-woven fabrics, and clothing. For example, products such as heat-curable silicone resin (300~
Thermoplastics such as polyethylene resin (PE), polypropylene resin (PP), polystyrene resin, polyethylene terephthalate, polyphenylene ether, polyacrylonitrile, polybutylene terephthalate, methacrylic acid resin, vinyl chloride resin It is often manufactured using resin. By the way, in order to impart antibacterial effects to these resins,
It is considered that it is sufficient to knead an antibacterial agent into these resins. However, the inventor of this application mixed an antibacterial agent with resin powder, produced a desired product based on this using a prescribed molding method, and investigated the antibacterial effect of this product, and found that this product met expectations. It wasn't something. As a result of detailed investigation into the cause of this, it was concluded that the antibacterial properties of the antibacterial agent that had been kneaded into the resin were lost due to the heat during molding. Therefore, from this point of view, after manufacturing the product,
One idea was to coat the surface with an antibacterial agent, but there were doubts about the durability of the antibacterial effect. Therefore, the main focus of research was on antibacterial agents that would not lose their antibacterial properties even when heated during molding. Further, as a result of further research, it has been found that it is desirable that the resin be less likely to react with various additives added to the resin during molding. Additionally, it has been found that it is important that the drug mixed into the resin is uniformly dispersed in the resin and that it gradually bleeds to the surface. The present invention was achieved as a result of research and development based on this viewpoint.
表−１に示す薬剤（抗菌剤）を用い、これを樹脂粉末と
混合し、抗菌剤混入シートを作製した。
上記のようにして得たシートの杭機（菌）特性を調べた
ので、その結果を表−１に併せて示す。
尚、杭機（菌）特性は、生理的食塩水に黴や細菌を分散
し、この分散液を培地に塗布し、そして上記のシートを
培地の上に置き、その後培養器に入れて、黴の場合には
２８°Ｃで２週間、細菌の場合には３０°Ｃで１２時間
培養し、黴や細菌の成育具合を観察した。
使用した菌は、アスペルギルスニガー（Ａ、ｎ）トリコ
デルマビイリティ （Ｔ、ｖ）、タラトスボリウム ク
ラドスポリオイデス（Ｃ，ｃ）、オーレオバティザイム
プルランス（Ａ、ｐ）、大腸菌（Ｅ、Ｃｏ１）、黄色
ブドウ球菌（Ｓ、 ｔ）である。
尚、表１における評価は、防黴特性及び防黴特性はＡ−
Ｈの五段階の評価（Ａが最も優れている、Ｅは効果なし
）で表した。
この表−１によれば、本発明になるものは杭機（菌）特
性に優れていることが判り、このような樹脂組成物で例
えば坦、ボール、ザル、シールウェア、シリコンバッキ
ング、野菜収納箱のようなプラスチック類の台所用品、
プラスチック類の風呂場用品やトイレ用品、食品包装用
のフィルムとか塵袋、その信書ブラシ、不織布、衣類な
どが製造されれば、これらの製品には黴が発生しにくい
ことが判る。
特許出願人 株式会社 バイオ技研Using the agents (antibacterial agents) shown in Table 1, they were mixed with resin powder to produce an antibacterial agent-containing sheet. The pile machine (bacteria) characteristics of the sheet obtained as described above were investigated, and the results are also shown in Table 1. In addition, the characteristics of the pile machine (bacteria) are as follows: Disperse mold and bacteria in physiological saline, apply this dispersion to the culture medium, place the above sheet on the culture medium, and then place it in an incubator to remove the mold. In the case of bacteria, they were cultured at 28°C for 2 weeks, and in the case of bacteria, they were cultured at 30°C for 12 hours, and the growth of mold and bacteria was observed. The bacteria used were Aspergillus niger (A, n), Trichoderma abili (T, v), Thallatosborium cladosporioides (C, c), Aureobatizyme pullulans (A, p), Escherichia coli (E, Co1). ) and Staphylococcus aureus (S, t). In addition, the evaluation in Table 1 shows that the anti-fungal properties and the anti-mildew properties are A-.
H was evaluated on a five-point scale (A being the best, E being no effect). According to Table 1, it was found that the product of the present invention has excellent pile machine (bacterial) properties, and such resin compositions can be used for example in flats, bowls, colanders, sealware, silicone backings, and vegetable storage. plastic kitchen utensils such as boxes,
If plastic bathroom goods, toilet goods, food packaging films, dust bags, correspondence brushes, non-woven fabrics, clothing, etc. are manufactured, mold will not easily form on these products. Patent applicant Biogiken Co., Ltd.
Claims (2)
ら選ばれる少なくとも一種の樹脂の中に、酸化亜鉛、酸
化マグネシウム、及びプロピオン酸塩の群の中から選ば
れる少なくとも一種が混入されてなることを特徴とする
抗菌効果を有する樹脂組成物。(1) At least one resin selected from the group consisting of zinc oxide, magnesium oxide, and propionate is mixed into at least one resin selected from heat-vulcanized silicone resins and thermoplastic resins. A resin composition having an antibacterial effect.
脂組成物において、樹脂の中には、酸化亜鉛、酸化マグ
ネシウム、及びプロピオン酸塩の群の中から選ばれる少
なくとも一種と、ＣａＯ、炭酸塩、クエン酸塩、ソルビ
ン酸塩、デヒドロ酢酸塩、リン酸化合物の群の中から選
ばれる少なくとも一種とが混入されてなるもの。(2) In the resin composition having an antibacterial effect according to claim 1, the resin contains at least one member selected from the group consisting of zinc oxide, magnesium oxide, and propionate, and CaO, A substance mixed with at least one selected from the group of carbonates, citrates, sorbates, dehydroacetates, and phosphoric acid compounds.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20797490A JPH0493360A (en) | 1990-08-08 | 1990-08-08 | Antifungal resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20797490A JPH0493360A (en) | 1990-08-08 | 1990-08-08 | Antifungal resin composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0493360A true JPH0493360A (en) | 1992-03-26 |
Family
ID=16548590
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP20797490A Pending JPH0493360A (en) | 1990-08-08 | 1990-08-08 | Antifungal resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0493360A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04239058A (en) * | 1991-01-09 | 1992-08-26 | Fuji Kobunshi Kogyo Kk | Fungiproof silicone rubber composition |
| JPH0622818A (en) * | 1991-04-26 | 1994-02-01 | Johnson & Johnson Kk | Antimicrobial tooth brush |
| JPH06189869A (en) * | 1992-12-25 | 1994-07-12 | Kanebo Ltd | Spongy devil's tongue molding |
| JPH06217741A (en) * | 1992-07-27 | 1994-08-09 | Nobuhide Maeda | Container for preventing degradation of drink |
| WO2001050864A1 (en) * | 2000-01-14 | 2001-07-19 | Shiseido Co., Ltd. | Antibacterial and mildew-proofing agents and antibactieral and mildew-proofing compositions |
| US6663877B1 (en) | 1996-06-26 | 2003-12-16 | E. I. Du Pont De Nemours And Company | Antibacterial solid surface materials with restorable antibacterial effectiveness |
| JP2012031326A (en) * | 2010-08-02 | 2012-02-16 | Nippon Shokubai Co Ltd | Acrylic acid base copolymer and method for producing the same |
-
1990
- 1990-08-08 JP JP20797490A patent/JPH0493360A/en active Pending
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04239058A (en) * | 1991-01-09 | 1992-08-26 | Fuji Kobunshi Kogyo Kk | Fungiproof silicone rubber composition |
| JPH0622818A (en) * | 1991-04-26 | 1994-02-01 | Johnson & Johnson Kk | Antimicrobial tooth brush |
| JPH06217741A (en) * | 1992-07-27 | 1994-08-09 | Nobuhide Maeda | Container for preventing degradation of drink |
| JPH06189869A (en) * | 1992-12-25 | 1994-07-12 | Kanebo Ltd | Spongy devil's tongue molding |
| US6663877B1 (en) | 1996-06-26 | 2003-12-16 | E. I. Du Pont De Nemours And Company | Antibacterial solid surface materials with restorable antibacterial effectiveness |
| WO2001050864A1 (en) * | 2000-01-14 | 2001-07-19 | Shiseido Co., Ltd. | Antibacterial and mildew-proofing agents and antibactieral and mildew-proofing compositions |
| JP2001199822A (en) * | 2000-01-14 | 2001-07-24 | Shiseido Co Ltd | Antibacterial mildewproofing agent and antibacterial mildewproofing composition |
| JP2012031326A (en) * | 2010-08-02 | 2012-02-16 | Nippon Shokubai Co Ltd | Acrylic acid base copolymer and method for producing the same |
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