TW200824567A - Acaricide synthetic materials and articles made therefrom - Google Patents

Abstract

Synthetic thermoplastic polymer articles are effectively protected from infestation by mites such as house dust mites or bedmites, by incorporation of an agent selected from Propiconazole, Cyproconazole, Difenoconazole, Fludioxonil, Thiabendazole, Tebuconazole, Zinc Pyrithione, 2-n-Octyl-4-isoiazolin-3-on, 4,5-Di-chlor-N-n-octyl-isothiazolin-3-on, certain 2,4-bis(alkylamino) pyrimidines or silvers as given in claim 1, Carbendazim, 10,10'-oxy-bis -phenoxyarsene, and/or n-bytyl-1,2-benzisothiazolin-3-on and optionally an antimicrobial agent into the bulk of the resin. Final articles may be filters, bed clothes and fillings, mattresses, covers, pillowcases, upholstery fabrics and foams, textiles, and floor coverings including carpets, backing material like backing for flooring, underlays.

Description

200824567 V IX. OBJECTS OF THE INVENTION: FIELD OF THE INVENTION The present invention relates to a method for reducing damage to articles, such as household articles or clothing or industrial articles, by the use of synthetic thermoplastic resins, which contain intrusions into bulk. a first agent for specific killing of a resin, optionally a second agent for antimicrobial treatment; a method for producing such a resin, a use of the resin for imparting an acaricide property, and an acaricide agent containing the resin . • [Prior Art] Spiders that are extremely small and can be propagated in fabrics and fillers (such as pillows, bedding, etc.), carpets and filters, as long as sufficient firmness and nutrition are available. . Exceeding the mites that appear in household dust, 2 sheets and pillowcases are developed. They produce powerful allergens: one of the main causes of asthma and wet therapy; see t 1 h in the confirmation of allergens as gas known to reduce dust mites. ♦ Bacterial treatments # " Certain pesticides And/or the fungicide treatment article 'such as fiber, fabric component is included in the surface of the corresponding fiber = or the surface is treated, or the object is Φ and 14 methods need to be repeated to incorporate the snail into the object The effect of the bulk == complex process 'in the forming process. m ~ 1 V long-term continuous material needs to be mixed against the cockroach to resist the effective preparation of the appropriate formulation into the material: the effect and the good material properties of the bulk material Further results, can be 200824567 can reduce the possibility of paleontological agents on the surface ιΓ This reduces the risk of allergies caused by anti-micro#. For the desired results, retain the matrix of poly-δ materials (eg machine, mechanical%) Characteristics of color, surface characteristics, and stability of killing a/rain under processing conditions are important. [Summary of the Invention]

It has now been found that it will be selected from the group consisting of propiconazole, cypr〇conazole, difen〇c〇naz〇le, Fludioxonil, thiabenzene. Thiabendaz〇le, Tebuconazole, Zinc Pyrithi〇ne, 2 n-octyl-4-isothiazolin-3-one, 4,5-di-chloro-N _N-octyl isothiazoline _3• ketone, formula

Ch3

(lie), nh2 8 200824567

CH3

(lid) ‘((Acryl)) 3⁄40定和Carbendazim,! 〇, 1〇, _ 7弋又本气胂(1〇,1〇1_〇^-|;)18«^}16110乂}^861^), 正_Butyl_ 1,2-Benzene The thiazoline agent is incorporated into the polymer resin, especially

The steroid group in contact with the synthetic thermoplastic polymer material is lowered. On the surface of the article containing the acaricide of the present invention, the acaricide has a significant effect in effectively reducing or eliminating the snail population. Of course, the surface may be an outer surface, such as the surface of a sheet or fiber, or an inner surface, such as in a foam or in the surface of a hollow volume within a yarn, fabric or garment. Acaricides of interest are also elemental silver, or silver glass or silver zeolite, for example in the form of microparticles or nanoparticles, which may be used by themselves (especially microparticles), or in a suitable liquid, such as emu oil (eg poly A dispersion in methyl dioxane or white oil is used. More preferred formulations are thiabendazole, tibuconazole, piroxicam, 2_n-octyl-4-isothiazoline _3·one, 4,5-di-chloro-4-n-octyl_ Isothiazoline_3_, Hb, nc, nd 2, 4 bis (anisoleyl) (four), propyl sulphate, cyproterone, difenac. Sitting and arrogant; especially silk, saliva, sputum, zinc sulphate, lib, nc, Ed 2,4_bis (anisoleyl) ^, propiconazole, cyprodinil Oxazole, difenconazole, and fludioin. Preferred formulations are also elemental silver or silver glass or silver stagnation. The best preparation of thiabendazole (IUPAC name: 2-(1,% thiazole_4_yl)_丨H_ 9 200824567

A compound with 4: v ... ^ ^ by stupid imidazole) can obtain a particularly good surname by adding more (second) anti-fruit, j: 鲈Du α) antimicrobial agent. From the formula (1) (iv) of the antimicrobial compound -

rX

(I)

Where η is 〇 or preferably 1,

Ri and R2 are hydrogen or a chlorine group, I is a hydroxyl group or preferably hydrogen, R4, R5 and r6 are hydrogen or a gas group, R7 is a trans group, and x is a direct bond, -NHCONH-, -CH2- or preferably. Yes; and / or silver or silver complex or salt. Preferred examples of the antimicrobial component include 2-phenylphenol, 2,4,4'-tri A=r 虱hydroxy-diphenyl ether, 4,4,-dichloro-2-hydroxy-diphenyl ether, 2 , 2'-methylene-bis-(4-chlorine), 4-(2-tris-butyl-5-methylphenoxy)-indole, 3-(4-chlorophenyl-M-( 3,4-Dichloro-phenyl)-urea, 2,4,6-trichlorophenol, A§C1, AgN〇3, Ag2s〇4, silver-zeolite, silver-glass, silver-wrong acid salt, dispersion Silver in white oil. More preferably 2,4,4,-trichloro-2, hydroxy-diphenyl ether, 4,4, monochloro-2-hydroxy-diphenyl ether, 2,2,- Amidino-bis-(4-chloro-phenol), 3-(4-chlorophenyl)4-(3,4-dioxaphenyl)-urea, AgC1, silver-zeolite, silver-glass, silver - 200824567 steric acid salt, silver dispersed in white oil; especially 2,4,4,-trichloro-2, thiol-monoether (one gas;; / (Triclosan)), silver-zeolite, silver Glass, silver-acid salt, silver dispersed in white oil. The silver-containing zeolite may be those described in U.S. Patent Nos. 4,775,585, 4,911,898, 4,911,899 and 6,071,542, the disclosures of The contents are incorporated herein by reference. The zeolite is usually an aluminosilicate having a three-dimensionally grown skeleton structure, usually represented by χΜ2/η〇·Al2〇3 · ySi〇2 · zH2〇, written as 丨2〇3 as a basis, where M represents an ion-exchangeable metal ion, often a unit price or The ion of the divalent metal; n corresponds to the valence of the metal; X is the coefficient of the metal oxide; y is the coefficient of cerium oxide; and Z is the number of water for crystallization. The zeolite of the invention has at least square meters / gram specific surface area. A single compound or a mixture of each component may be used. For example, a combination of a phenolic antibacterial agent and a silver component as mentioned above may provide more pots. Of course, one may be added. Or a plurality of more components selected from the group consisting of zinc oxide, copper and copper compounds. Silver usually comprises colloidal silver, silver nitrate, silver sulfate, silver chloride, silver composites, metal-containing zeolites and surface-modified metal-containing zeolites. In the material of the present invention (i.e., the article containing the synthetic polymer resin, and the polymer resin itself), the first agent and the second agent, if present, are preferably from 〇5/2 ( ) to 2_ 5 ratio is accepted Especially from the ratio of "to 10:1. · The total amount of the agent - especially the amount of the first and second doses, if any," from the weight of the final material, often from 0.01% to 10% 11 in the range of 200824567 'especially 0.02% to 5%. In the following:: Under the condition of the use, the weight of the final material is 0.22. /... 〇, the sword or the total amount of the first and second doses A material (i.e., an article containing a synthetic polymer resin containing the present invention: (10)", or a material for producing such articles, for example, = 'usually contains about H0. % by weight, often 1% to 1% by weight, = ... 〇〇% by weight of the killer resin. The two or two of the agent contained in the resin are judged by the low-denier two-second resin used in the final article or on the surface thereof for a good anti-caries effect. In the case of a resin, the content of the agent in the polymer resin is generally higher than that of the second, and the article contains a high amount of the agent content in the acaricide resin or the resin (4) (IV). The structure is based on the agent of the present invention and the polymerization containing the same. Resin, which has good long-term toxicological characteristics 'and more in the polymer substrate: coloring agent... good compatibility, polymer tree can be processed in it, such as rotomoulding, spinning Before, etc., first (4)) the plastic tree is used in the month. The agent can resist the harsh addition of wood, such as temperature, for example, a temperature exceeding 20 ° C. The present invention also relates to a preparation of a smoldering agent. The method of the material, which is more than two, into the first agent as defined above, if necessary, there are two more: the bacteria (9) two), and the preparation as defined above, visible S: with: more resistance Bactericide' reduces the heart k in bulk synthetic polymers, for example in the production of snails The period 'is added as a melt additive 12 200824567. [Embodiment] Examples of polymers, especially synthetic polymers which can be filled with the scum agent of the present invention are: ", 2, i monoolefins and diolefins Polymers such as polypropylene, polyisobutylene, polybutene, poly-4-methylpentamene, polyvinylcyclohexane, polyisoprene; poly:diene' and polymers of cyclic olefins For example, cyclopentene or norbornene, polyethylene (which may be crosslinked as desired), such as high density polyethylene (HDPE), two density and high molecular weight polyethylene (HDPE-HMW), high density and ultra high molecular weight. Polyethylene (HDPE-UHMW), medium density poly: ^ (MDPE), low density polyethylene (LDpE), linear low density polyethylene (LLDPE), (VLDPE) and (ULDPE). Polyolefins, ie polymers of monoolefins, as exemplified in the previous paragraphs, Che Yijia's polyethylene and polypropylene can be prepared by different methods, in particular the following: a) Free radical polymerization (usually At high pressures and elevated temperatures). b) Catalytic polymerization using a catalyst which typically contains one or more metals belonging to the Wb, Vb, VIb or vm family of the Periodic Table. These metals typically have one or more ligands, typically oxides, complexes, alcoholates, esters, ethers, amines, alkyls, alkenyls and/or aryls, which may be π- or σ- Coordinating. These metal composites may be in free form or be entangled on a substrate, typically on activated magnesium chloride, titanium hydride, oxygen or oxidized hair. These catalysts are soluble or insoluble in the polymerization medium. The catalyst itself may be used in the polymerization, or more activations may be used. 13 200824567 'typically metal alkyls, metal hydrides, alkyl halides, alkyl metal oxides or metal alkoxides Alkyloxanes, which are elements of the ia, na, and/or 羾 family of the periodic table. The activator can be conveniently modified with more ester, ether, amine or oxime ether groups. These catalyst systems are often referred to as philHps, Standard

Indiana, Ziegler (-Natta), TNZ (DuPont), metallocene or single site catalyst (SSC).

In 1) a mixture of intermediate length 1 and its extract, such as a mixture of polypropylene and polyisobutylene, polypropylene with polyethylene (pp/HDPE, pp/LDpE), and a mixture of different types of polyethylene (eg LDpE) /HDpE). 3. Copolymers of monoolefins and diolefins with each other or with other vinyl monomers, such as ethylene/propylene copolymers, linear low density polyethylene (LLDp and its combination with low density polyethylene (LDPE), propylene, butyl Small olefin copolymer, propylene/isobutylene copolymer, ethylene/butyl copolymer, ethylene/hexene copolymer, ethylene/methylpentene copolymer, ethylene/heptene copolymer, ethylene/octene', w Ethylene/vinyl hexyl alcohol copolymer, ethylene/cycloaliphatic copolymer (such as ethylene/norbornium oxime COC), ethylene (tetra) hydrocarbon copolymer, wherein the olefin is made by real estate; propylene/butyl Diene copolymer, isobutylene/doprene copolymer, ethylene, vinyl cyclohexene copolymer, ethylene/acrylic acid ruthenium co-polymer, ethylene/methacrylic acid-based copolymer, ethylene/acetic acid Ethylene (tetra) copolymer or ethylene/propionic acid copolymer, and its salts (ionomer), with = B: with propylene and dilute, such as hexamethylene, dicyclopentanyl or ethylene Bismuth dilute 70 copolymer; and the mixing of such copolymers with each other and with the polymers mentioned in U above 'eg polypropylene/ethylene propylene copolymer, 14 200824567 LDPE/ethylene vinyl acetate I copolymer (EVA), LDPE/ethylene-acrylic acid copolymer (EAA), LLDPE/EVA, LLDPE/EAA, and alternative or random Polyalkylene/carbon monoxide copolymers, and mixtures thereof with other polymers, such as polyamines. 4. Hydrocarbon resins (for example, including hydrogenated modifications thereof (e.g., tackifiers), and polyalkylenes and a mixture of starches. The homopolymers and copolymers from 1) to 4) may have any stereostructure, including syndiotactic, isotactic, semi-isotactic or atactic; Atactic polymers are preferred. Also included are stereoblock polymers. 5. Polystyrene, poly(p-nonylstyrene), poly(cardamomethylstyrene). 6. Aromatic homopolymers and copolymers derived from vinyl aromatic monomers, including all isomers of styrene, α-mercaptostyrene, vinyl toluene, especially p-vinyltoluene, ethyl All isomers of styrene, propyl styrene, vinyl diphenyl, vinyl naphthalene and vinyl anthracene, and mixtures thereof. The homopolymers and copolymers may have any stereostructure, including syndiotactic, isotactic, semi-isotactic or atactic; wherein atactic polymers are preferred. Also included are stereoblock polymers. 6a· comprising the aforementioned vinyl aromatic monomer and selected from the group consisting of ethylene, propylene, diene, nitrile, acid, maleic anhydride, maleimide, vinyl acetate and vinyl chloride or acrylic acid derivatives, And copolymers of comonomers thereof, such as styrene/butadiene, styrene/acrylonitrile, styrene/ethylene (copolymer), styrene/alkyl methacrylate, styrene/butadiene Alkene / alkyl acrylate, stupid ethylene / butadiene / alkyl methacrylate, styrene / maleic anhydride, styrene / acrylonitrile / methyl acrylate; high impact strength 15 200824567 mixture, such as polyacrylic acid Binary copolymer; and block copolymer of styrene copolymer of styrene and other polymers, diene polymer or block copolymer of acetamidine/propylene/diurene, #笨乙烯/丁丁稀/styrene , phenethyl, pentadiene / styrene, styrene / ethylene / butene / styrene "styrene / ethylene styrene / styrene. 6b. Hydrogenated aromatic polymers derived from the hydrogenation of polymers mentioned under 6), in particular polycyclohexylethylene (PCHE) prepared by hydrogenating atactic polystyrene, often referred to as poly Ethylene ring house (pvcH). 6c. Deuterated aromatic polymers from the hydrogenation of polymers mentioned under 6a). The homopolymers and copolymers can have any stereostructure, including syndiotactic, isotactic, semi-isotactic or atactic; wherein atactic polymers are preferred. Also included are stereoblock polymers. 7_Graft copolymer of vinyl aromatic monomer, such as styrene or cardiomethylstyrene, such as phenylethylene on polybutadiene, polybutadiene-styrene or polybutadiene - styrene on acrylonitrile copolymer; stupid ethylene and acrylonitrile (or methacrylonitrile) on polybutadiene; styrene, acrylonitrile and methyl methacrylate on polybutanin; Benzene and cis-butadiene, dianlic anhydride on polybutadiene; styrene, acrylonitrile and maleic anhydride or maleimide on ruthenium polybutadiene; on polybutadiene Styrene and acrylic acid or alkyl methacrylate on styrene and maleimide-imine' polybutadiene; styrene and acrylonitrile on ethylene/propylene/diene terpolymer; Styrene and acrylonitrile on polyalkyl acrylates or polyalkyl methacrylates; styrene and acrylonitrile on acrylate/butadiene copolymers, and 16 200824567 A mixture of copolymers listed below, such as a copolymer mixture known as abs, MBS, ASA or AES polymers. 8. Polymers containing i, such as polychloroprene, chlorinated rubber, chlorinated and brominated copolymers of isobutylene-isoprene (butyl rubber), chlorinated or chlorinated polyethylene, a copolymer of ethylene and vinyl chloride, an epichlorohydrin, and a copolymer of an ethylenic compound, such as polyvinyl chloride (PVC), polyvinylidene chloride, polyvinyl fluoride, poly Vinylidene fluoride, and copolymers thereof, such as vinyl chloride/vinylidene chloride, vinyl chloride/vinyl acetate or vinylidene chloride/vinyl acetate copolymer. 9. Polymers derived from α,β-unsaturated acids, and derivatives thereof, such as polyacrylates and polymethacrylates; polymethyl methacrylate, polypropylene fc fe and polyacrylonitrile, Butyl acrylate increases toughness. 10. Copolymers of monomers mentioned below under 9) or with other unsaturated monomers, such as acrylonitrile/butadiene copolymers, acrylonitrile/alkyl acrylate copolymers, acrylonitrile/alkoxy acrylates Alkyl ester or acrylonitrile/halogenated ethylene copolymer or acrylonitrile/alkyl methacrylate/butadiene terpolymer. Π·A polymer derived from an unsaturated alcohol and an amine, or a mercapto derivative or acetal thereof such as polyvinyl alcohol, vinyl acetate, polyvinyl polystearate, polybenzoic acid B — 'polybutene Ethylene glycol g|, polyvinyl ketal, polyallyl phthalate or polymaleic acid acrylic acid S; and its copolymer with the olefin mentioned in 1) above. Homopolymers and copolymers of 12.% ether, such as polyalkylene glycols, polyethylene oxide, polypropylene oxide or copolymers thereof with diglycidyl ether. 13. Polyacetal ' such as polyoxymethylene and ethylene oxide as comonomer. 17 200824567 Those water formaldehydes, polycondensates modified with thermoplastic polyurethane, acrylate $ mbs. 14. Polyphenylenes and polyphenylene sulfides, and mixtures of polyphenylene ethers with styrene polymers or polyamines. 15. Polyamines derived from polyethers, polyesters or polybutylenes which are terminally hydroxyl groups, and polyisocyanates which are aliphatic or aromatic at the other end, and their precursors. 16. Polyamines and copolyamines derived from diamines and di(iv) and/or derived from aminic acid or the corresponding indoleamine (PA), such as polyamine 4, polyamine 6, polydecylamine 6/6, 6/1〇, 6/9, 6/12, 4/6, 12/12, polydecylamine 11, polydecylamine 12, aromatic polycondensation starting from m-xylylenediamine and adipic acid Indoleamine; *Ife 'prepared from hexamethylenediamine and isophthalic acid or/and terephthalic acid with or without a modifier, such as poly-w·methyl/, fluorene For dioxin or poly-m-xylylenediamine: 3C has a description of the amine and polyolefin 'olefin copolymer, ionomer or chemically bonded or grafted elastomer Segment copolymer; or with polyether, for example with polyethyl-alcohol, polyacrylic acid

- Pre- or tetra-decyl diol; and polyamine or copolyamine modified with EPDM "BS; and poly & amines (RIM polyamine system) condensed during processing. Amines, polyamines, quinones, polyetherimine, polyesterimine, polycarbazide, and polybenzimidazole. 18·Derived from two-branched $- and diols and/or a polyester derived from a hydroxycarboxylic acid or a corresponding lactone, and Example 4 J is obtained by using ethylene glycol dicarboxylate (PET), polybutylene terephthalate, and t-claw-1. 4-Dimethylenecyclohexaneterephthalic acid 18 200824567 Ester, polyalkylene naphthalene dicarboxylate (PAN) and polyhydroxybenzoate, polylactic acid (PLA), and derived from the terminal hydroxyl group Block copolyetheresters of polyethers; also polyesters modified with polycarbonate or MBS. 19. Natural polymeric materials such as leather, cellulose, rubber, gelatin and their chemically modified homogeneous derivatives, such as cellulose acetate, cellulose propionate and cellulose butyrate, or cellulose ethers such as methyl Cellulose; and rosin and its derivatives. 20. A blend of the above polymers (composite polymer), such as PP/EPDM, poly-amine/EPDM or ABS, PVC/EVA, PVC/ABS, PVC/MBS, PC/ABS, PBTP/ABS, PC/ASA, PC/PBT, PVC/CPE, PVC/Acrylate, POM/Thermoplastic PUR, PC/Thermoplastic PUR, POM/Acrylate, POM/MBS, PPO/HIPS, PPO/PA6.6 and Copolymer PA/ HDPE, PA/PP, PA/PPO, PBT/PC/ABS or PBT/PET/PC. Preferred substrates are polyethylene (PE) such as LDPE or HDPE; polypropylene (PP; homo or copolymer); ethylene vinyl acetate (EVA); polyester, such as polyethylene terephthalate (PET), PET-G, polylactic acid (PLA), poly(trimethylene terephthalate) (PTT); polyol; polyoxymethylene (POM); thermoplastic polyolefin (TPO); polyurethane (PUR); thermoplastic polyurethane (TPU); polyvinyl chloride; polyamine (PA), such as PA6 or PA6.6; or a corresponding blend. The best is PP, PE, PET, PA, PUR, PLA, PTT. The substrate is often in the form of fibers, fabrics, nonwovens, foams. Materials, especially polymeric substrates, may also already incorporate one or more of the following known additives therein: 19 200824567 i. Anti-gasification 1_· 1 · One base of the base is also 'for example 2,6-two -Third-butyl _4_methyl age, 2-di-di-butyl_4,6-di-methyl sulphate, 2,6-di-t-butyl-4-ethyl sulphate, 2 ,6-一_苐三_butyl-4-正_butyl, 2,6-di-third-butyl-4_isobutyl, 2,6-dicyclopentyl-4·indenyl, ; 2-(α-fluorenylcyclohexyl)-4,6-monomethylphenol, 2,6-di-octadecyl-4-methylphenol, 2,4,6-tricyclohexylphenol, 2.6 - Di-t-butyl- 4-methoxymethylphenol, nonylphenol, which is linear or branched in a side chain, such as 2,6-di-mercapto-4-methylphenol, 2,4 - Dimercapto-6-( 1,-methylundecane-1,yl)phenol, 2,4-dimethylmethylheptadecane,yl)phenol, 2,4-didecyl_6_ (1,-decyltridecyl)phenol, and mixtures thereof. 1^·alkylthio 1, such as 2,4-dioctylthiodecyl third-butylphenol, 2,4-dioctylthioindolyl-6-methylphenol, 2,4-dioctylsulfide Base group _6_ethyl phenol, 2,6-di-dodecylthio decyl _4_nonyl phenol. _ and ;): complete brewing, such as 2,6-di-t-butyl-butyl-4-indolyl-, 2,5-di-tertiary-butyl hydrogen, 2,5 _二_三_Pentyl hydrogen moth, 2.6- diphenyl _4_ octadecyloxy oxime, 2,6-di-third-butyl oxo, 2,5_ di-third-butyl _4_hydroxybacteria, 3,5_di-t-butyl- 4-hydroxy bactericidal _, 3,5-di-third-butyl _4_ phenyl stearate, double (3,5·di-first, butyl-phenyl) adipic acid vinegar. For example, alpha-fertility enzyme, geranium, sputum, δ·tocopherol, and mixtures thereof (vitamin oxime). Diphenyl, for example, 2,2,-thiobis(6_Third-buty K f), 2'2'-thiobis(4_octyl), 4,4,_thiobis(tetra) Butyl·3·methyl sulphate), 4,4, thiobis...Third butyl-2-methyl age), 20 200824567 4,4'-thiobis (3,6-di- Di-pentylphenol), 4,4'-bis(2,6-dimercapto-4-phenyl)disulfide. 1.6. Alkylene nonylphenols, such as 2,2'-fluorenylene bis(6-tri-butyl-4-nonylphenol), 2,2'-methylene double (6-third·butyl) Base-4·ethylphenol), 2,2,-methylenebis[4-methyl-6-(α-methyld-hexane)-age], 2,2'-methylenebis(4- Methyl-6-cyclohexylphenol), 2,2'-fluorenylene bis(6-mercapto-4-nonylphenol), 2,2,-methylenebis(4,6-di-third -butylphenol), 2,2'-ethylenebis(4,6-di-tertiary-butylphenol), 2,2'-ethylenebis(6-tris-butyl-4- Isobutylphenol), 2,2,_methylenebis[6-(α-曱benzyl)-4-nonylphenol], 2,2,-methylenebis[6-(α-dioxin Benzyl)-4-nonylphenol], 4,4'-methylenebis(2,6-di-tertiary-butylphenol), 4,4, methylenebis(6-third-butyl Base 2_nonylphenol), 1,1_bis(5-tris-butyl-4-hydroxy-2-tolyl)butane, 2,6-bis(3-tri-butyl-5 -mercapto-2-hydroxy-benzyl)-4-nonylphenol, hydrazine, ι,3-tris(5-tris-butyl-4-hydroxy-2-indolylphenyl)butane, 1,1 - bis(5-tert-butyl-4-hydroxy-2-tolyl)-3-n-dodecyldecylbutane, ethylene glycol bis[3,3-bis(3,_ Tris-butyl-4, hydroxyphenyl)butyrate], bis(3-tris-butyl-4-hydroxy-5-methyl-phenyl)bis-cyclopentadiene, bis[2-( 3 into the third -butyl 2, _ hydroxy-5, 曱 benzyl) -6 - tert-butyl -4- phenyl phenyl terephthalate, 1, 1 _ _ (3 , 5-dimethyl-2-hydroxyphenyl) butyl, 2,2-bis(3,5-di-t-butyl-4-hydroxyphenyl)propane, 2,2,-bis-( 5-tert-butyl-4.hydroxy-2-pyrenephenyl)_4_n-dodecyldecylbutane, 1,1,5,5-tetrakis(5-tri-butyl-4- Hydroxy-2-tolyl)pentane. υ.Ο·?Ν·and S-Benzyl hydrazine, examples '3,5,3,5,tetra-tert-butyl-4,4-one perbenzyl dibenzyl _, octagonal 4--4-yl-3,5-dibenzylbenzyl decyl acetate, tridecyl-4-hydroxy-3,5-di-tris-butylbenzyl decyl Ethene 21 200824567 acid ester, tris(3) ,5-di-t-butyl-4-hydroxybenzyl)amine, bis(4-tris-butyl-3-hydroxy-2,6-dimethylbenzyl)dithioterephthalic acid Ester, bis(3,5·di-t-butyl-4-hydroxybenzyl) sulfide, isooctyl-3,5·di-t-butyl-4-hydroxybenzyl-tert-acetate. 1.8. Hydroxybenzylated malonate, such as di-octadecyl-2,2-bis(3,5-di-tri-butyl-2-hydroxybenzyl)malonate, - octadecyl-2-(3-second-butyl-4-yl-5-nonyl)malonic acid S, di-dodecyl-Weiethyl-2,2-bis (3, 5-di-t-butyl-4-hydroxyl hydroxy)malonic acid S, bis[4-(1,1,3,3-tetradecyl)phenyl]-2,2-dual ( 3,5·di-t-butyl-4-hydroxybenzyl)malonic acid g. 1.9. An aromatic hydroxybenzyl compound, such as 1,3,5-tris(3,5-di-t-butyl-4-hydroxybenzyl)-2,4,6-tridecylbenzene, 1, 4_bis(3,5-di-t-butyl-4-hydroxybenzyl)-2,3,5,6-tetramethylbenzene, 2,4,6·tris (3,5-di- The third-butyl-4-benzyl group is condensed. 1.10. Three-till compounds, such as 2,4-bis(octyl)-6-(3,5-di-tris-butyl-4-hydroxyanilino)-1,3,5-three tillage, 2- Octyl-4,6-bis(3,5-di-tris-butyl-4-hydroxyanilino)-1,3,5-trimorphine, 2-octyl-4,6-bis (3,5 - Di-di-di-butyl-4-light phenoxy)-1,3,5-di- 1,1,4,6-tri-(3,5-di-second-butyl-4 -Phenylphenoxy)-1,2,3-dimorph, 1,3,5-tris(3,5-di-tris-butyl-4-hydroxybenzyl)isocyanurate, 1 ,3,5-tris(4-tris-butyl-3-hydroxy-2,6-dibenzyl)isocyanurate, 2,4,6-tris(3,5-di-third -butyl 4-hydroxyphenethyl)-l,3,5-trimorphine, 1,3,5-tris(3,5-di-t-butyl-4-hydroxy-phenylpropanyl )-Hexahydro-l,3,5-trimorphine, 1,3,5-tris(3,5-dicyclohexyl-4-hydroxybenzyl)isocyanurate. 22 200824567 1.11 ·Benzyl 'such as dimercapto-2,5-di-t-butyl-4-hydroxybenzylphosphonate, diethyl, 3,5-di-third-butyl_4_ Hydroxybenzylphosphonate, di-octadecyl-3,5-di-tertiary-butyl-4-hydroxybenzylphosphonate, di-octadecyl-5-second-butyl- A calcium salt of 4-hydroxy-3-methylbenzylphosphonate, a monoethyl ester of 3,5-di-t-butyl-4-butyl-4-pyridylphosphonic acid. 1 · 12·酉胜脱基 ('eg 4-a fund auranilide, 4-pyridylstearylamine, N-(3,s di-t-butyl-4-hydroxyphenyl)amine Lysine

Li3_P-(U-二二复三-丁某-4-hydroxyphenyl)propionic acid and mono- or polyhydric alcohol drum JOL, for example with methanol, ethanol, n-octanol, iso-octanol, stearyl alcohol 1,6-hexanediol, l59_decanediol, ethylene glycol, propylene glycol, neopentyl glycol, thiodiglycol, diethylene glycol, triethylene glycol, pentaerythritol, tris(hydroxyethyl) isocyanide Uric acid ester, N, N, bis(hydroxyethyl) oxazinamide, 3-thioundecyl alcohol, thiopentadecanol, trimethyl hexane diol, triterpene propane, 4-hydroxyindole _卜石舞_2,6,7-三腭二环[2·2·2]octane. . 4--4-hydroxy-3-indolyl phenyl)propionic acid with mono- or polyterpene alcohol, for example with methanol, ethanol, n-octanol, iso-octanol, decaol, 1,6-hexane Alcohol, hydrazine, decanediol, ethylene glycol, hydrazine, 2-propylene glycol, neopentyl glycol, thiodiglycol, diethylene glycol, triethylene glycol, pentaerythritol, tris(hydroxyethyl)isocyanuric acid Ester, N, N,-bis(hydroxyethyl) oxazinamide, 3-thioxanol, = thiopentadecanol, tridecyl hexanediol, trimethyl methacrylate, and hydroxymethyl phosphorus , 2,6,7·three hired bicyclo[2·2·2]octane; 3,9-bis[2_{3_(3_third·butyl_4_罗工基5-tolyl)propanoid Oxydiethyl dimethyl]-2,4,8, ι〇_tetra[5·5]·undecane. 23 200824567 New and single- or polyol ι i, decanediol: ethylene glycol, ethanol, octanol, stearyl alcohol, 1,6-hexanediol, monoglycol, 1,2, propanediol, Neopentyl glycol, thiodiglycol, I, triethylene glycol, ^ bis (ethyl) oxalate, 3 meth) isocyanuric acid (tetra), N, N, ? 妒 _ 叁 叁 decane Alcohol, 3-thiapentadecanol, trimethicone I-methanol propane, 4, mercapto·14-2,6,7-three-occupied bicyclo[2.2·2] Ιι16·.3 - Acid and mono- or polyhydric alcohol 'for example with chymase, 7 π 士 ^ f ^ ethanol, octanol, stearyl alcohol, 1,6-hexanediol, 1,9-nonanediol, B - '丙-propanol, neopentyl glycol, thiodiglycol, --tj N bis|1 and containing aryl alcohol, pentaerythritol, tris(hydroxyethyl)isocyanurate, N,N, again Ethyl) grass drunk face, 2 a ^ January female 3_喽 undecyl alcohol, 3 · thiopentadecanol, tridecyl alcohol monosterol propane, 'hydroxyl decyl_1 _ phosphorus_2,6 , 7_ three hired two rings [2 2 octane. ·』盖-4 -经笨基)丙 -- :_/^. <±y ) ry «=ι又 _ Receive, 1 夕 如 N, N, etc. - S - knot - ^

Length 1, _di-dibutyl-4-hydroxyphenylpropanyl) hexamethylenediamine N'N-bis(3,5-di-tris-butylhydroxyphenylpropenyl) Sanya Mercaptodiamine, N,N,-bis(3,5-di-tris-butyl-4-ylhydroxyphenylpropanyl)anthracene, N,N,_double [2_(3_[3, 5_2_3rd-butyl butyl phenyl] propanyloxy) ethyl] oxazamide (Naugard 8χι^, supplied by Unir〇yal). IJ^·anti-ascorbic acid (^Synthesis C) agent, such as N, N'-di-isopropyl-p-phenylenediamine, N, N, di-second-butyl-p-phenylene Amine, N, N, bis(1,4-dimethylpentyl)·p-phenylenediamine, N,N,-bis(1-ethyl_3_indolyl)-p-phenylenediamine, N, N,- biguanide 24 200824567 methylheptyl)-p-phenylenediamine, N,N,-dicyclohexyl-p-phenylenediamine, N,N'-diphenyl-p-phenylenediamine, N, N,-biguanidinyl)-p-phenylenediamine, isopropyl-N,-phenyl-p-phenylenediamine, N-(l,3-dimethylbutylphenyl-p-phenylenediamine , N-(l-fluorenyl)-N,-phenyl-p-phenylenediamine, cyclohexyl, phenyl-p-phenylenediamine, 4-(p-toluidinesulfonyl)diphenylamine, N,N,di-fluorenyl-N,N,-di-second-butyl-p-phenylenediamine, diphenylamine, N-allyldiphenylamine, 4-isopropoxydiphenylamine, N- Phenyl-1-naphthylamine, N-(4-tris-octylphenyl-1,naphthylamine, N-phenyl-2-naphthylamine, octylated diphenylamine, for example, pair, pair, di- Tri-octyldiphenylamine, 4-n-butylaminophenol, 4-butylaminophenol, 4-guanamine base, 4 - dodecylamine 5, 4 - 18 ^Amino bis, 4-(4-oxophenyl)amine, 2,6-di-t-butyl-4-dimethylaminononyl phenol, 2,4'-diaminodiphenyl fluorene Alkane, 4,4,-diaminodiphenylmethane, N,N,N,,N'-tetramethyl-4,4'-diaminodiphenylnonane, bis[(2-methylphenyl) Amino]ethane, 1,2-bis(anilino)propane, (o-tolyl)difluorene, bis[4_(1,3,-monomethyl)phenyl]amine, third- Octylated phenyl-phenyl-naphthylamine, a mixture of mono- and mono-compounded tri-butyl/tri-octyldiphenylamine, mono- and di-alkylated decyldiphenylamine Mixture, a mixture of mono- and dialkylated dodecyldiphenylamine, a mixture of mono- and dialkylated isopropyl/isohexyldiphenylamine, the third and the mono-alkylation a mixture of butyl diphenylamine, 2,3 _ dihydro-3,3-dimercapto-4 Η-Μ-stupyl thiophene, phenothiazine, mono- and dialkylated second-butyl/different a mixture of octylphenothiazine, a mixture of mono- and dialkylated di-octylphenoxazines, allylic phenothiazine, ν, ν, ν, Ν, _ tetraphenyl- 1,4-diaminobutyl Rare. 25 200824567 U · 2 (2 base) left ugly three saliva, such as 2_(2'· warp-5, a stupyl) benzotriazole, 2-(3,,5, di-third - Butyl-2, hydroxyphenyl)benzotriazole, 2-(5-second-butyl-2'-hydroxyphenyl)benzotriazole, 2·(2,_hydroxy, (1,1) , 3,3-tetramethylbutyl)phenyl)benzotriazole, 2_(3,5, bis-tert-butyl-2-hydroxyphenyl)-5-chlorobenzotriazole, 2- (3,-Third-tert-Butyl-2,-hydroxyl-methylphenyl)-5-chlorobenzotriazole, 2_(3,_second-butyl, third-butyl-2, hydroxybenzene Benzodiazole, 2-(2'-hydroxy-4,-octyloxyphenyl)benzotriazole, 2_(3',5'-di-tris-pentyl-2, hydroxyphenyl Benzotriazole, 2_(3,5,bis0, cardiomethyl)-2 hydroxyphenyl)benzotriazole, 2_(3,-third-butyl-2, hydroxy-5 '_(2-octyloxycarbonylethyl)phenyl)_5-chlorobenzotriazole, 2_(3, 3,5-di-(2-ethylhexyloxy)weiethyl]_2, phenyl )_5_Chlorobenzotriazine, di(a, 3, 3, 3-butylhydroxy-5,-(2_曱-oxycarbonylethyl)phenyl)-5-chlorobenzone sit: 2_(3 third- Base group ·5, (2-methoxyindolyl) stupyl) benzotrizene, 2-(3,_t-butyl-2-,-ylamino-5Μ2-octyloxy Phenyl)benzotrisole, 2_(3,_third_butyl-5,_[2_(2-ethylhexyloxy)ethylidene]-2'-phenyl)benzotrisole, 2_(3,_12 院基·2,_经基·5,_tolyl) 笨三三, 2-(3,·三-butyl 々,-经基_5,-(2- Isooctyloxydiphenyl benzotrisole, 2'2'-methylenebis[4_(m3·tetramethylbutyl)-6-benzotriazol-2-ylphenol] — slope,, 』 L3 _Di-di-butyl-5,-(2-methoxycarbonylethyl bromide-2,-p-phenyl)_2Η_benzotrisole and acetyl sulphate exchange product; [R-Ch2CH2- COO_CH2CHH2_, where r = 3, third butyl _4, _ Rorikyl - 5, -2H benzotriene - mei cage farmer. Jujube opens the main base 2, 2-[2,_trans-base·3,_(α,α-dimethyl d,1,3,3-tetramethylbutyl, sen-dimethyl phenyl) phenyl] Benzotriazine. 26 200824567 H. 2-Phenylbenzophenone, for example 4-carbyl, 4-methoxy, 4-oxomethoxy, 4-methoxy, 4-dodecyloxy, 4-benzyloxy, 4,2,,4,_trihydroxy and 2,-hydroxy-4,4'-dimethoxyl derivatives. U disubstituted and unsubstituted i formic acid |, such as salicylic acid anal tert-butyl phenyl ester, phenyl salicylate, octyl phenyl salicylate, benzoyl resorcinol, Bis(4-tert-butylbenzylidene) resorcinol, benzhydryl resorcinol, 3,5-di-t-butyl-4-butylbenzoic acid 2,4 -di-t-butylphenyl ester, cetyl 3,5,di-tert-butyl-4-hydroxybenzoate, 3,5-di-tertiary-butyl-4-hydroxybenzene Octadecyl citrate, 3,5-di-t-butyr-4-hydroxybenzoic acid 2-methyl-4,6-di-t-butylbenzene. H_.. Acrylic vinegar', such as ethyl cyano U-diphenyl acrylate, 0-cyano-no, bis-isophenyl diphenyl acrylate, hydrazine; 曱 曱 carbonyl carbonyl cinnamate, Methyl cyano _/5_decyl-p-methoxycinnamate, cyano _ cold-methyl-p-methoxy cinnamate butyl ester, α-methoxycarbonyl _ p-methoxy cinnamic acid bismuth Nickel complexes of esters and oxime-((--oxycarbonylcarbonylcyanovinyl fluorenyl dihydro oxime. • Nickel, such as 2,2'-thiobispung tetrabutyl) phenol], such as 1: 1 or 1:2 complex with or without additional ligands such as n-butylamine, triethanolamine or N-cyclohexyldiethanolamine, nickel dibutyldithiocarbamate, monoalkyl esters, for example Nickel salt of ketone ester or ethyl ester of 4-hydroxyl-3,5-di-third-tert-butylphosphonic acid, ketone oxime, for example, nickel of 2_transalkyl- 4· phenylundecyl ketone oxime Complex '丨_phenyl_4_laurel ____hydroxyl. ratio. Sitting nickel complex with or without additional ligands. For example, bis(2,2,6,6-tetradecyl-4-hexahydropyridyl) 癸27 200824567 diester, bis(2,2,6,6-tetradecyl-4-hexahydropyridyl) Succinate, bis(1,2,2,6,6-pentamethyl-4-hexahydropyridinyl)sebacate, bis(1-octyloxy-2.2.6.6-tetramethyl-4- Hexahydropyridyl) sebacate, bis(1,2,2,6,6-pentamethyl-4-hexanitro-11 sigma) n-butyl- 3,5-di-second-butyl a condensate of benzyl-4-pyrroladate, 1-(2-hydroxyethyl)-2,2,6,6-tetramethyl-4-hydroxyhexahydropyridine and succinic acid, N,N '-Bis(2,2,6,6-tetramethyl-4-hexahydropyridinyl)hexamethylenediamine and 4-third-octylamino-2,6-diox-1,3, 5-three-till linear or cyclic condensate, tris(2,2,6,6-tetradecyl-4-hexahydropyridinyl)phosphinic acid, tetrakis (2,2,6,6- Tetramethyl-4-hexapyridine)-1,2,3,4-butane tetracarboxylate, 1,1,-(1,2-ethanediyl)-bis(3,3,5, 5-tetramethylhexalinone), 4·benzimidyl-2,2,6,6-tetramethylhexahydropyridine, 4-stearyloxy-2,2,6,6- Tetrakisylhexahydropyridine, bis(1,2,2,6,6-pentamethylhexahydropyridinyl)-2-n-butyl-2 -(2-hydroxy-3,5-di-tris-butylidene)malonate, 3-n-octyl-7,7,9,9-tetramethyl-1,3,8-triterpenoid [4.5] decane-2,4-dione, bis(1-octyloxy-2,2,6,6-tetramethylhexahydropyridinyl)sebacate, bis(1-octyloxy- 2.2.6.6- Tetramethylhexahydropyridyl) succinate, hydrazine, Ν'-bis(2,2,6,6-tetramethyl-4-hexahydropyridinyl)hexamethylenediamine and 4 a linear or cyclic condensate of morpholinyl-2,6-dichloro-1,3,5-trimorphine, 2-chloro-4,6·bis(4-n-butylamino-2.2.6.6- Condensate of tetramethylhexahydropyridyl)·1,3,5-triazine and 1,2-bis(3-aminopropylamino)ethane, 2-gas-4,6-di-(4) -n-butylamino-1,2,2,6,6-pentamethylhexahydropyridyl)-1,3,5-triphthyl and 1,2-bis(3-aminopropylamino)B Alkane condensate, 8-ethylidene-3-dodecyl-7,7,9,9-tetradecyl-1,3,8-tris-spiro[4·5]decane-2,4 -dione, 3-dodecyl_1·(2,2,6,6-tetramethyl 4-hexahydropyridyl)pyridinium-2,5-dione, 3-dodecyl- 1·(1,2,2,6,6- 28 200824567 pentamethyl-4-hexahydropyridylpolypyrrolidine-2,5-dione, 4-hexadecyloxy- and 4-stearyl Oxygen A mixture of 2,2,6,6-tetramethylpiperidine six Yun pyridine, N, N '· bis (2,2,6,6-tetramethyl-4 ° hexahydro-ratio. a condensate of hexamethylene monoamine and cyclohexylamine-2,6-dichloro-1,3,5-three tillage, hydrazine, 2-bis(3-aminopropylamino)ethane and Condensate of 2,4,6-trichloro_1,3,5-sanming 1 and aminobutyl-2,2,6,6-tetramethylhexahydropyridine (CAS registration number [136504-96-6] ]); 丨, 6-hexanediamine and 2,4,6-trichloro-1,3,5-three tillage and hydrazine, hydrazine-:butylamine and 'butylamino _ 2,2,6,6 a condensate of tetramethylhexahydropyridine (CAS Registry Number [192268-64·7]); N-(2,2,6,6-tetramethyl-4-hexahydropyridinyl)-positive-tweldium Alkyl amber imine,! ^-(1,2,2,6,6-pentamethyl-4-hexahydropyridinyl)-n-dodecylsuccinate, 2-111:): complete _7, 7,9,9-tetradecyl-1-employed_3,8_diphthoquinone_ 4-oxo-spiro[4,5]decane, 7,7,9,9-tetramethyl-2- Reaction product of cycloundecyl_1___3,8-dioxin-4-oxospiro-[4,5]decane and cyclop-chloropropane, 1,1-double (1,2,2 ,6,6·pentamethylhexahydropyridyloxycarbonyl)-2-(4-methoxyphenyl)ethene, N,N,-bis-indenyl-N,N,·bis (2,2, 6,6_tetradecyl-4-hexachloropyridinyl)hexamethylenediamine, 4-decyloxymethylenemalonic acid and 1,2,2,6,6-pentamethyl_4 Diester of hydroxylahydropyridine, poly[methylpropyl-3-oxy.4_(2,2,6,6-tetramethyl-4-hexahydroacridinyl)]nonane, butenene Diacid anhydride _^ olefin copolymer with 2,2,6,6-tetradecyl-4-aminohexahydropyridine or 1,2,2,6,^pentamethyl-4-amine hexahydropurine reaction product. The hindered amine may also be one of the compounds described in British Patent No. A_2 3〇1 1〇6, such as components ^), Ib), I_c), bd), Ie), κ), bg)' ) 'b 1), hj), Ik) or 1-1), especially the light stabilizers ι· 29 200824567 la-2, lbl listed in pages 51 to 73 of the British patent-Ad 301 l〇6 Lcl, lc-2, ldl, ld-2, ld-3, l_e_l, 1-fl, 1-gl, lg-2 or 1-kl. The hindered amine may also be one of the compounds described in European Patent _A_〇 782 994, for example in the scope of claim 1 or 38, or in Examples 1-12 or D-1 to D- The compound described in 5.

G_.7· In the -y-original _ substituted by the alkenyl group which is lightly substituted by the yl group, for example, it is 1-(2-hydroxyl-methylpropoxyb 4_octadecyloxy) Base 2,2,6,6-tetramethylhexahydropyridine, i_(2_hydroxy-2-methylpropoxy)_4_hexadecane,yloxy-2,2,6,6-tetramethyl Reaction product of hexahydropyridine, hydrazine-oxy-4_hydroxy-2,2,6,6-tetramethylhexahydrou-pyridinium with a carbon radical derived from a third-pentanol, l (2-hydroxy- 2-Methoxyoxy)-4-hydroxy-2,2,6,6-tetramethylhexahydropyridine, hydroxy-2-methylpropoxy)_4.oxo-2,2,6,6_four Mercaptohexahydropi-pyridinium, bis(1_(2-hydroxy-2-indolyloxy)-2,2,6,6-tetradecylhexahydropyridin-4-yl)sebacate, double- (1-(2·私基_2_曱propoxy)_2,2,6,6-tetramethylhexahydropyridine·4-yl)hexadi(tetra), bis-(1-(2-)-based 2-monopropoxy)_2,2,6,6 tetramethylhexahydroacridin-4-yl)sodium succinate, bis(1_(2-hydroxy-2-methylpropoxy)>2,2 ,6,6_tetradecylhexahydroacridin-4-yl)glutarate and 2,4-dihydroxy_2·nonyloxy)-2,2,6,6-tetradecylhexahydroindole A compound of pyridine-4-yl-butylamino-4-bromo-6-(2-hydroxyethylamino) 4-trione. H enzyme I, such as 4,4,-dioctylpyridinium diphenylamine, 2,2,-diethoxyoxadiazolidine, 2,2,-dioctyloxy_5,5,_di_third _ Diclofenac diphenylamine, 2,2,-docosyloxy_5,5,_di third _butazone diphenylamine, ethoxylated 2-ethylidene diphenylamine, hydrazine, Ν, · bis(3-diaminopropyl) oxalate, 2_ethoxy_5-tert-butyl-2, acetophene diphenylamine and its with 2_B 30 200824567 -oxy a mixture of ethyl-5,4,-di-t-butazone-diphenylamine, a mixture of o- and p-nonyloxy-substituted littermate, and o- and p-ethoxy- A mixture of disubstituted grasses and distamines. Three tillages such as 2,4,6-tris(2-hydroxy-4-octyloxyphenyl)-1,3,5·sanming:, 2-(2-hydroxy-4-inocyloxyphenyl)·4, 6-bis(2,4-xylphenyl)-1,3,5-trimorphine, 2_(2,4-dihydroxyphenyl)_4,6-bis(2,4-dimethylphenyl)-1, 3,5-Sanming:, 2, deducted bis(2-hydroxypropoxyphenyl)-6_(2,4-dimethyl-phenyl)-1,3,5·three tillage, 2-(2-hydroxy- 4-octyloxyphenyl)-4,6-bis(4-methylphenyl: hydrazine, 3,5-trin, 2-(2-hydroxy-4-dodecyloxyphenyl)-4,6- Bis(2,4-dimethylphenyl)-1,3,5-trimorphine, 2-(2-hydroxy-4-tridecyloxyphenyl)_4,6-bis(2,4-dioxene) Base)-:1,3,5_three tillage, 2_[2_hydroxy_4_(2-hydroxy-3-butoxypropoxy)phenyl]-4,6-bis(2,4-didecyl) -i,3,5-three tillage, 2-[2-hydroxy-4-(2-carbazhen-3-octyloxypropoxy)phenylhydrazine, bis (2,4-dimethylhydrazine, , % trimorphine, 2_[4-(dodecyldecyl/tridecyloxy-2_hydroxypropoxy)·2-hydroxyphenyl]_ 4,6_bis(2,4-disyl)tri Pent, 2-[2·transcarbyl_4_(2•pyrudododecyloxypropoxy)phenyl]-4,6-bis(2,4-dimethylphenyl)-1,3,5- Trimorphine, 2-(2-hydroxy-4-hexyloxy) Base_4,6_diphenyl_1,3,5_sanming:, 2_(2-hydroxy-4-methoxyphenyl)_4,6-diphenyl-1,3,5-trimorphine, 2 ,4,6·Tris[2-hydroxy-4-(3-butoxy-2-hydroxypropoxy)phenyl]-1,3,5_three tillage, 2_(2.hydroxyphenyl)_ 4 -(4-methoxyphenyl)-6-phenyl-1,3,5-trimorphine, 2-{2-hydroxy-4-[3-(2-ethylhexyl-1-oxy)-2- Propyl propyloxy]phenyl}-4,6·bis(2,4-dimethylphenyl)· 1,3,5-trimium. 3. Goldhouse deactivator, such as N,N'-diphenyl Phytosamine, water yangjun, Ν'-salt yang, n, N,-double (shuiyang 醯) 肼, N, N, - bis (3,5-two-third _ 31 200824567 hydroxy hydroxy phenyl醯, 3-, 3-水杨醯 amine _ι, 2,4-triazole, bis(benzylidene) grass 醯肼, grass 醯 diphenylamine, 笨 醯 醯 醯肼 醯肼Stupid I 肼, N, N, dimethyl hexamethylene quinone dioxime, N, N, - bis (shui Yang I base) grass-based diterpenoids, N, N, - bis (salicylidene) sulfur Propyl hydrazine. Phosphonic acid esters such as triphenyl phosphite, monophenylalkyl phosphite, phenyl dialkyl phosphite, tris(phenylphenyl) phosphite, phosphorous Acid trilaurate, tris(octadecyl)phosphite, distearyl I-pentaerythritol diphosphite, tris(2,4-di-t-but-3-phenyl)phosphite, diisoindole Pentaerythritol diphosphite, bis(2,4-di-tert-butylphenyl)pentaerythritol diphosphite, bis(2,4-di-cumylphenyl)pentaerythritol diphosphite, double (2 , 6-di-t-butyl-4-methylphenyl)pentaerythritol diphosphite, diisodecyloxy pentaerythritol di ternary acid ester, bis(2,4-di-tertiary-butyl-6-曱Phenyl) pentaerythritol diphosphite, bis(2,4,6-tris(tris-butylidene)pentaerythritol diphosphite, tristea sorbitan saponin, four (2) , 4-di-tert-butylphenyl) 4,4-diphenylene diphosphinate, 6-oxenyloxy-2,4,8,10-tetra-tertiary-butyl-12H- Dibenzo[d,g]-i,3,2-dioxaphosphocene, bis(2,4-di-t-butyl-6-tolyl)methyl phosphite , bis(2,4-di-t-butyl-6-fluorenylphenyl)ethyl phosphite, 6-fluoro-2,4,8,10-tetra-tertiary-butyl-12- Base-dibenzo[d,g]-l 3,2-dioxaphospholium, 2,2',2"-nitrilo[;triethyltris(3,3,5,5,-tetra-tertiary-butyl-1, fluorene -diphenyl-2,2,-diyl)phosphite], 2-ethylhexyl (3,3',5,5,-tetra-tert-butyl-1,1'-diphenyl- 2,2,-diyl) squaric acid S, 5-butyl-5-ethyl-2-(2,4,6-tri-tert-butylphenoxy 32 200824567 base)·1,3 2 - 2 hired dioximirane (dioxaphosphirane). The following linoleic acid esters are particularly preferred: tris(2,4-di-tertiary-butyryl)phosphite (irgafos 168, Ciba Specialty Chemicals Inc.), tris(phenylene) Base) phosphorous acid, (ch3)3c

C(CH3)3

(A) H3C — CH

P — F (ch3)3c

c (ch3)3 (ch3)3c (ch3)3c

p — 〇一CH2CH2-

(C)

N (B)

33 200824567

—Base 1, for example, N,N-dibenzylhydroxylamine, N,N-diethylhydroxylamine, N,N-dioctylhydroxylamine, N,N-dilaurylhydroxylamine, hydrazine, hydrazine-di-tetradecane Hydroxylamine, hydrazine, hydrazine-hexadecylhydroxylamine, hydrazine, hydrazine-di-octadecylhydroxylamine, hydrazine-hexadecyl-indole-octadecylhydroxylamine, hydrazine-heptadecyl octadecane Hydroxylamine, sputum derived from IL-tallowamine, hydrazine-dialkyl group via amine. , for example, Ν-knot-α-phenyl nitrone, Ν-ethyl _α-fluorenyl nitrone, Ν-octyl _α-heptyl nitrone, Ν_lauryl _α-undecyl nitrate Ketone, oxime, tetradecyl-α-tridecyl nitrone, Ν_hexadecyl...-pentadecyl nitrone, hydrazine-octadecyl heptadecyl nitrone, Ν- + six Alkyl-Q-heptadecyl sulfonium, Ν-eighteenths-α-pentadecane 颂 Ν j, Ν-heptadecane α αheptazone, anthracene octadecyl -α-hexadecyl nitrone, a nitrone derived from hydrazine derived from hydrogenated tallow amine, hydrazine dialkylhydroxylamine. An amine oxide derivative, a dimercaptodecylamine oxide, a tridecylamine oxide, a tris(dodecyl) group as disclosed in U.S. Patent Nos. 5,844,029 and 5,880,191. An amine oxide and a tris(hexadecyl)amine oxide. [Benzene oxime g and (4) p ketones, for example, in U.S. Patent No. 4,325,863; U.S. Patent No. 4,338,244; U.S. Patent No. 5,175,312; U.S. Patent No. 5,216,052; U.S. Patent No. 5,252,643; German Patent-A-4316611 , German patent _a_4316622; German patent. A · 34 200824567 43 said 6; European patent _ eight marriage 9839 or European patent _A_ read ι〇2 revealed that the difference, or 3-Γ4-0 r# one - Fly 14 (2-ethyl sulphate ethoxy)-phenyl-5,7-di-situ 笨 并 南 酉 酉 酉 5 5 5 5 5 5 5 5 5 4- 4- 4- 4- 4- (2-stearyloxyethoxy)phenyl]-benzopyran-2-one, 3,3,_bis[5,7·di-t-butyl-MM2,ylethoxy]benzene Benzo benzophenan-2-, 5,7-di-tris-butyl-3*ethoxyphenyl)benzofuran, ketone, 3, oxime oxy. , 5_diphenyl)-5,7-di-t-butylbenzopyrene-2·one, 3_(3>didecyl_4_neopentyloxyphenyl)-5,7· II. Benzyl benzofuranone, 3_(3,4. xylyl)-5,7-di-t-butyl butyl benzoindole-2-one, 3_(2,3_曱5,7_di-t-butylbenzofuran_2-|same. For example, dilauryl thiodipropionate or dihexadecyl thiodipropionate. After oxidizing HA, directly remove hydrazine, such as vinegar of β-thiodipropionic acid, such as lauryl ketone, hexadecane ketone, meat stalk or thirteen burnt vinegar, sulfhydryl benzopyrene or 2- a salt of a benzoyl benzopyrene, a zinc dibutyldithiocarbamate, a di(octadecyl) disulfide, a tetrakis(tetradecylmercapto)propionic acid vinegar. 11. A polyamine stabilized, a plug such as a copper salt mixed with an iodide and/or a phosphorus compound, and a bivalent salt. 12. ^Stable stability, such as melamine, polyvinylpyrrolidone, dicyandiamide, triallyl cyanurate, urea derivatives, anthraquinone derivatives, amines, polyamines, polyurethanes, alkali metal salts of high carbon number fatty acids And alkaline earth metal salts, such as stearic acid, stearic acid, magnesium behenate, stearic acid, sodium broad oleate and potassium palmitate, catechol catechol or zinc catechol. 35 200824567 &; for example, inorganic substances, such as talc, metal oxides, such as two or oxidized towns, preferably the acid filling of soil test metals; ε carbonate or sulfate; organicized people ^ ^ 〇咏 々 'such as mono- or poly-nonanoic acid and its salts, such as 4 - $ butyl benzoic acid, adipic acid, diphenylacetic acid, sodium succinate or benzo-sodium ' ♦ compound, such as ionic copolymer (ionomer). Particularly preferred are 1,3:2,4-substituted, 4,·- ® # 'monomethylbenzylidene) sorbitol, 1,3:2,4-di(paramethyl-indenyl) ) Sorbitol and bis(subunit) sorbitol. * 'Powders or fibers such as calcium carbonate, silicate, fiberglass, spring & asbestos, talc, kaolin, mica, barium sulfate, metal oxygen, barium hydroxide, slave black, graphite, wood flour and other natural products , synthetic fiber. , for example, plasticizers, lubricants, emulsifiers, pigments, dyes, rheology additives, catalysts, flow control agents, fluorescent Zengzhou (7) mobile and bismuth agents, crosslinking accelerators, halogen scavengers, smoke Inhibitor, flame-resistant sputum, you turn @ ^ antistatic agent, clarifying agent, such as substituted and unsubstituted yoke sorbitol benzoic _ uv absorber, such as, p-phenylene Base bis (3,1_benzoxanthyl ketone), Cyasorb 3638 (CAS #186〇〇59 4) and a blowing agent. For example, a fungicide such as 3,5-dimethyltetrachloro M, 5-2H-thiodiindole-2-thione, ditributyltin oxide, 4,5-chloro 2 n-octyl_ 4_isothiazolene _3 ketone, n-butyl benzoisoxanthene, 10,10-oxybisphenoxy fluorene, zinc 2_acridinyl mercaptan_1_oxide, etc. And algicides, such as 2-A visit 1 π 'knife L-based 4-% propylamino-6-(α,β·dimethylpropylamine S-triphthyl, 2-methylthio-4-cyclopropylamine Base · 6_ third_ butylamine + three tillage, 2_ 36 200824567 曱 thioethylamine _6_ (α,α_di-propylamino) _s_ three tillage and so on. Included in the range of from 1 to 10% by weight, these additives are included; the usual amount of these additional additives is in the range of from about 0.25 to 5% by weight. The filler may be incorporated in a higher amount, for example 1-5 〇 % by weight 〇 preferably additional additives selected from the group consisting of antioxidants, UV absorbers, hindered amines, phosphites or phosphonites, hydroxylamines, nitrones, benzofurans, 2-ketones, thio-co-agents , polyamide amine stabilizer, metal stearate, nucleating agent, filler, reinforcing agent, lubricant, emulsifier, dyeing a group of materials, pigments, fluorescent whitening agents, flame retardants, antistatic agents, and foaming agents. The acaricides of the present invention and more additives may be added to the plastic resin as needed. Internal, for example, polyolefins, respectively or mixed with each other. If desired, the individual components of the added mixture may be mixed and melted (smelted and blended) with each other prior to incorporation into the plastic material. The dry killing agent in the form of a powder, or the wet mixing in the form of a liquid or suspension, the addition of the acaricide (s) of the present invention, as needed, to the plastic material. After melting or after, the formulation (and) may be added to the formulation and more additives may be needed, or by applying the dissolved or dispersed additive to the plastic material, without subsequent solvent evaporation. In the form of the acaricide (s) of the present invention and more additives as may be required to be added to the plastic material in a concentration of from about 1 to 80:, such as 2.5 parts by weight of the carrier loaded ❶/❶ to 70%, especially > 疋5 to 50% In such operations, powders, granules, solutions, in the form of a suspension of 2008 2008 567, or a polymer in the form of a singularity may be used. Thus, the present invention encompasses the production of smoldering materials, such as fibers, fabrics, a process for foaming plastics and non-woven fabrics, wherein the first agent, if necessary, is in the range of from i to 80% by weight of the carrier, and may be impregnated into the thermoplastic polymer carrier as needed. And then the loaded carrier is incorporated into the material, both of which need to be heated. ^ ^ 'The material or the form of the 纟 纟 加 is added to the plastic resin, the 』 Addition via carrier, such as LDPE, HDPE, MDPE, PP, EVA, ABS, SAN, PS, ... 5 Acrylate, PMMA, Polyamide, Polyacetate, PVC, Latex, Styrene, Polyol, PUR, TPU , unsaturated H poly-methyl, water emulsion, etc.; especially good is ldpe, hdpe, pur 6 PA 6.6, PET, PET-G (ie ethylene glycol-modified PET), can also be polymerized Adding this month's acaricide and more additives may be needed before, during or after the action or cross-linking. The acaricide of the present invention may also be incorporated into a plastic material in a pure form or in a wax, a smoldering agent, and a more desirable two-component. And + to see more additives sprayed on the material. They can dilute their forces, or monomers or their _, make it: t (such as the above traditional addition ==. Deactivation in the polymerization catalyst During the period, it is possible to use a spray to add a spray, such as a vapor for deactivation: Beyer/Li. In the case of a spherically polymerized polydome, for example, it is possible to apply the addition of the present invention to the sprinkle. The substance is 9 虿, and may be added together with other additions of 38 200824567. ^ ^ Additives of the invention and visible to the polymer material, or mixed with each other. Prior to the inclusion of the individual components, the individual components are combined with one another to be incorporated into the polymerization, compaction or in the melt. For example, by methods known to dry cultivators, such as liquids, dispersions in powder form. Or suspension (IV), or in water or oil, the additive of the present invention: Solvents, polymers, etc. can be, for example, before or after molding, =: components and characters and damageable clouds | add this article, " see more additives, or add or add The mixture is applied to the polymer material: = agent or suspension / dispersant evaporation. mm mm valley extruder, internal mixer, etc.) processing clothing (such as ^ ^ ^ 乂 know the mixture or powder, 戍In the form of a liquid or dispersion or suspension or melt. It can be combined in a closed apparatus such as a pinch unit, such as 捏 ΓΜ# i? ^ ^ ^, which is equipped with a stirrer. It is processed in the presence of oxygen or in the kneading machine, both::: Whether it is under inert gas or not, it is not important. It can be taken in all the usual mixing 嫱4 Add 'additives or add blends to the polymer, and melt the beans in the beans, and mix them with the additives. The appropriate machine benefits are the skill and skill of the artist. Machines. 4 known. They are mainly mixers, pinches: good in the extruder, by processing Adding materials to 4 □ merge. 39 200824567 4 inch K processing machine benefits, single _ screw extruder, reverse and forward double screw cup extruder, planetary gear extruder, ring extrusion Machine or reciprocating kneader. It is also possible to use a processing machine with at least one gas removal compartment, which can use a vacuum. Eight in, for example, Handbuch der Kunststoffextrusion, Volume 1 G-rundlagen, edited by F. Hensen, w H 1989 Appropriate extruders and kneaders are described in pages 3-7 of the ISBN, 3-446-14339-4 (Extrusionsanlagen 6, ISBN 3-446-14329-7). For example, the screw length is i-60 times the screw diameter, preferably 35_48 times the screw diameter. The rotation speed of the screw is preferably 1 〇 6 rpm per minute, and the 4 inch is preferably 25-3 00 rpm. The maximum flow rate depends on the screw diameter, the rotational speed and the driving force. The process of the present invention can also be carried out by varying the variables mentioned or by using a weighing machine to deliver the dosage level at a lower level than the maximum flow. If multiple components are added, these may be pre-mixed or added individually. In particular, polymeric resins containing the inventive additives (forms)/formulations described herein can be used to produce molded, rotationally molded articles, injection molded articles, blow molded articles, films, tapes, Single yarn, fiber, non-woven fabric, foam, cross section, adhesive or putty, surface coating and the like. Accordingly, articles containing the anti-caries agent of the present invention include synthetic fibers and fabrics, including woven fabrics, non-woven fabrics and knitted fabrics, as well as mattresses and foams. Of particular interest is the application of the invention in a filter, bedding, package 200824567 including sheets, blankets, mattresses, bedspreads or pillowcases, or foam (four) materials, fabrics and floor coverings, including carpets, lining you + L 1 m 〒 〒 枓, like the effect of the lining of the floor, the bottom pad under the carpet, the paint behind the fabric. Regarding the effect of anti-cochle, the preparation or preparation according to the present invention is combined into a polymer resin, thereby making it into a storage place, and controlling the release of the agent for a long period of time. The end population is thus effectively reduced or removed on the surface of the article, in the bulk of the media, and in the fabric or pile of, for example, bedding, furniture, mattresses, clothing or blankets. The best items containing or consisting of: the anti-mite resin of the invention are fibers, foams or articles each having these, and/or foamed plastics, including fabrics and non-woven fabrics: y (four) examples explain this in more detail Invention 1 is not intended to limit this (4) in any way. It is claimed that this (4) cover specific implementation (four) and modifications, which do not violate the spirit and scope of the present invention. Unless otherwise specified, = Dong provides all the parts; room temperature indicates the level within the range of 纟20_ hunger. A) Processing conditions 1) Formulation using pp substrate: The agent was mixed with polypropylene pellets (MoplenHP side 1 = pexAG) at room temperature and squeezed at 23 (rc via a twin screw extruder) The molten polymer and the agent are discharged by the ® mold and are in the cold water stream

Cool and solidify immediately. The cured strip was loaded into a particle granulator. "IL fiber spinning process: You use Taiding M i to make continuous fiber picking, the next fiber spinning line, the food, and the reinforced polypropylene fiber: 24 (rc (four) machine temperature, 4 adjustment The speed of the spinning pump, 4 produces a fiber with a specific gravity of 4.5dPf. After 41 200824567, the fiber is woven into a machine. 2) The embodiment of the PET substrate is used: the agent (and) at 120 ° C and The polyester pellets (RT21, Trevira GmbH) were dehydrated until the residual humidity reached below 504 ooppm. Mix the medicinal agent with the pellet at a temperature of 270. The underarm is extruded through a twin-screw extruder. The molten polymer and medicament are discharged via a circular die and immediately cooled and solidified in a stream of cold water. The cured strip was loaded into a granulator.

, cut-off spinning process: before spinning, once again under 1 it will be dehydrated until the residual humidity is below 50-1 OOppm. Continuous polyester multifilament fibers were prepared using a fiber spun yarn under the following conditions y: 285 squeezing [machine broth, 4 crepe filaments. The speed of the spinning pump was adjusted to produce a fiber having a specific gravity of 4.5 dpf. The fibers are then woven into socks. 3) Example of the use of the polystyrene PA6 substrate. The formulation (the) and the polyamide globules (ultramj-4' BASF) were dehydrated at 80 ° C until the remaining humidity reached 5 〇〇 (5) So far. y "Under the 7K agent mixed with the pellet and pass through the twin-screw extruder at 260 ° C. The molten compound and the agent are discharged through a circular die, and at the moment = immediately crotch and solidified. The cured strip is loaded into the granulator. Fiber spinning process · Before spinning, re-- at 8 (TC will be small March) until the residual humidity reaches 500ppm. Use in the lower jaw = continuous spinning Line, prepare continuous polyamine polyfilament fiber: 265. " == temperature, silk. Adjust the speed of the spinning pump to produce fibers with helium. Then weave the fibers into socks. 42 200824567 ▲For their resistance瞒Performance, evaluation of the woven #本.Experimental setting: For each formulation, test the sample of 丨〇χ1 〇 centimeters in triplicate. Before inoculation with the snail, stain the sample with natural dust and make Adapt to the specific humidity. To ensure the nutritional needs of the insects, Μ = the ratio, add the genus and yeast powder in the dust / will do: the unit is placed in the bottom of the glass dish (15 cm in diameter). Then Different samples are placed in the strange temperature box, and the best end conditions are at the specific end. Week (ie suitable for house dust worms (~_Phag〇ides Pteronyssinus) species, temperature is 芄 and 75% relative humidity). For comparison, the same kind of woven _ this is prepared in the same way as the preparation without the present invention. "Reference group") and sputum culture leaf we blank") 0 After adaptation, each sample was inoculated with 5q cockroaches (25 male adults with 25 males) from the prosperous culture. After 6 weeks of incubation, the material is expected to be at least two generations from the generation of the house. Under such optimal thermohydrogenic conditions, the results achieved with the polypropylene substrate (1) are summarized in Table 1. In Table 2: The results achieved with the polyethylene terephthalate substrate (2) are summarized in Table 3, which summarizes the results achieved with the polyamide substrate (3). Samples of the same 'but without the anti-caries agent of the present invention provide further comparison. Fabric-like 丄·Anti-butter treatment applied on pp substrate 43 200824567 Effect after 2 weeks Ϋ 4 weeks later * 6 weeks later” Reference group “2-2-3” “2-2- 3" 387.7 0.2% triclosan + 0.2% thiabendazole (present invention) "0-0-1" "0-1-1" 0 0.4% triclosan + 0.4% thiabendazole (present invention) “0-0-0” “0-0-0” 0 0.5% silver-glass compound + “0-0-1” “0-0-0,, 1.3 0.2% thiabendazole (present invention) 0.22% Triclosan (comparative) "2-3-3" "0-1-1" 2.3 0.5% silver-glass compound (present invention) "2-2-2" "0-0-1" 7 0.2% thiobenzene Dazole (present invention) "1-1-2" "0-00,, 0.7 PCC blank "3-3-3" "3 each 3" 456.7 Table 2 •• Anti-螨 treatment applied to PET substrate Effect on the basis of the fabric sample 2 weeks later * 4 weeks later * 6 weeks later ** Reference group "3-3-3" "3_3-3" 411.2 0.2% triclosan + 0.2% thiabendazole (this Invention) "3-3-3" "1-1-1" 4.7 0.4% trigasta + 0.4% thiabendazole (present invention) "3-2-3" "0-0-0" 0 PCC blank “3-3-3” “3-3·3” 438.3 Plate _·· Apply anti-瞒 treatment to Effect on PA 6 substrate-based fabric samples after 2 weeks * 4 weeks later * after 6 weeks" 0.2% triclosan + 0.2% thiabendazole (present invention) "2-2-2" "0- 0_0,, 0 0.4% triclosan + 0.4% thiabendazole (present invention) "2-2-2" "0-0-0,, 0 PCC blank "3-3-3" "3-3- 3" 438.3 44 Number of 200824567: ^ y ^ m — IW sample is obtained. Give each sample three points to J. The mouth is the mother. The sample is repeated. The second is not observed. The live dust worms are not observed. A considerable number of scorpion populations are developed at 25 ° C and 75% relative. Quantitative measurement of the snail population after 6 weeks of incubation under humidity; number of live ticks in the sample (average of 3 samples). The results show that the materials of the present invention provide a unique killing effect.

[Simple diagram description] None [Main component symbol description] None 45

Claims (1)

200824567 X. Patent application scope: 1 · A method of reducing cockroaches (especially the deer kr to house dust mites or bed mites) to invade the object from the bag, the method includes Scatter The polymer resin of the bulk is incorporated into the surface of the article by a synthetic thermoplastic polymer resin containing a selected from the group consisting of Thiabendazole, metallic silver, silver- Glass, silver zeolite, Propiconazole, Cyproxazole, Cyperconazole, Tebuconazole Zinc Pyrithione, 2-n-octyl-4-isosin-3-ketone (2-n-Octyl-4-isothiazolin-3-on), 4,5-di-chloro -N-正-octyl-isocarcinoma. 4,5-Di-chlor-Nn-octyl-isothizaolin-3-on, n-butyl-1,2-benzoisoindol-3-one (n-butyl-) l,2-benzisothiazolin-3-on), 2,4-double (:): amine-based) 46 200824567 Carbendazim, 1〇, 1〇'-gas _ bis-phenoxy oxime (1〇, ι〇, - 〇xy-bis-phenoxyarsene) or a mixture thereof. 2. The method of claim 1, wherein the article is a household item or a garment or an industrial item, in particular selected from the group consisting of a filter, a bedding and a stuffing, a mattress, a bed cover, a pillowcase, a upholstery fabric, and a foam, fabric. And floor coverings, including carpets, lining materials, floor linings, and linings. 3. The method of the patent scope 帛i, wherein the polymer resin: has a molding, a film, a tape, a single, a fiber, a woven fabric, a non-woven fabric, a foamed plastic, a cross-section (profUe), an adhesive or The form of putty and surface coating. 2. The method of claim 1, wherein the resin contains d, preferably a phenolic antimicrobial compound selected from formula (I) 200824567 η is 0 or preferably, and Ri and I are hydrogen or chlorine, and the rule 3 is hydroxyl or preferably hydrogen. R4, I and the heart are hydrogen or a chloro group, R7 is a thiol group, and CH^ or preferably is a silver, silver complex and a silver salt. 5 · For example, the method of claim 4 of the patent scope of the patent, which will be the first item of the patent application, selected from the group consisting of thiabendazole, quinacazole, and pyrithione. 2- L-octyl-4·isothiazoline_3__,...·chloro*n-octyl-isothiazoline _ ^, ,^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^ The first dose of the group consisting of propranazole, dipyridazole, and fludioin is mixed with the second agent of the fourth paragraph of the patent scope of Shen Qing, especially selected from the group consisting of 2-phenylene, 2, 4 , 4 _ 二气-2'·Phenyldiphenyl^|, 4,4,-diox-2-yl-di-anthracene, 2,2'-indenylene-bis-(4-chloro-phenol , 4_(2_Terve-butyl-5-methylphenylindenyl)-phenol, 3-(4-chlorophenyl)·ι_(3,4·dichloro-phenyl)-urea, 2, 4,6-trichlorophenol, AgCl, AgN03, Ag2s〇4, silver-zeolite, silver-glass, silver-zirconate, metallic silver, such as a group of silver dispersed in white oil Or the first agent is selected from the group consisting of metallic silver, silver zeolite and silver-glass 48 200824567 group ' and mixed with peconazole and/or phenolic antimicrobial compound of formula (i), especially Free 2-stylphenol, 2,4,4,_trichloro-2,-hydroxy-diphenyl ether, 4,4'-dichloro 1-hydroxy-diphenyl ether, 2,2,-indenylene-double -(4·chloro-phenol), 4-(2_tri-butyl-5-nonylphenoxy)-phenol, 3-(4-chlorophenyl)-1-(3,4-dichloro- A group consisting of phenyl)-urea and 2,4,6-trichlorophenol. 6. If you apply for a patent scope! The method of the invention, wherein the synthetic thermoplastic polymer resin is selected from the group consisting of polyethylene, polypropylene, ethylene vinyl acetate, water saponin, such as PET or pET_G or pLA, polyol, polyformic acid, plastic polyolefin, polyamine The corresponding compound of vinegar, thermoplastic polyamine (1) ethylene ethylene, polystyrene. '*' A method for the preparation of the ancient and i-lr 1_ 蜊 杆 rod of the remedy material, which is characterized by, metal silver, silver glass, silver zeolite, acetocyanine, cyclamate: Condyl, Flandinis, Tetani Saliva, Zinc Sulfate, 2_Isothiazolin-3-one, 4,5-Di-N-N τ * %~4· 下乱-Ν-正-辛基-isothiazoline_3_ (Hb) 2,4-bis(alkylamino)pyrimidine 49 200824567 (lid) And carbendazim, 10,10 Tiandai-bis-oxyxanthene, n-butyl-1,2-benzoxanthene sin-3-one and its mixture π, Japanese infidelity The agent, if desired, is also incorporated into the bulk of the synthetic thermoplastic polymer resin, either directly into the acaricidal material or incorporated into the surface of the acaricidal material. «·If you apply for the patent scope, the 7th ice _, spear/item method, which uses heating The agent may optionally be mixed with the polymer resin in a plastic state, preferably in the form of a masterbatch or a molten additive, and then molded into a mold, a film, Tape, mono-filament, fiber, fabric, non-woven fabric, foam, cross-section, adhesive, oil &, surface coating shape. The method according to any one of the claims or the method of item 7, wherein the first agent is contained in the polymer resin in an amount of from 0.01% to 10% by weight based on the weight of the resin. If there is a second agent, the first:second dose ratio (weight·weight) from 〇_5.2〇 to 2〇····5 is included in the polymer resin. 50 200824567 , η>--In the bulk resin, the synthetic thermoplastic polymer containing the second agent as defined in item 4 of the scope of the patent application The resin is used to prepare acaricidal materials or articles. 3 Volume 11 · A mites fabric, foam, textile, carpet, film, glue π mono-silk, fiber, non-woven fabric, adhesive or putty, which is included in the bulk resin as in the scope of the patent application The agent defined in item i, and optionally a Φ synthetic thermoplastic polymer resin as defined in the fourth scope of the patent application. XI. Schema: None 51