JPH0490844A - Emulsifying composition - Google Patents
Emulsifying compositionInfo
- Publication number
- JPH0490844A JPH0490844A JP2205476A JP20547690A JPH0490844A JP H0490844 A JPH0490844 A JP H0490844A JP 2205476 A JP2205476 A JP 2205476A JP 20547690 A JP20547690 A JP 20547690A JP H0490844 A JPH0490844 A JP H0490844A
- Authority
- JP
- Japan
- Prior art keywords
- oil
- alcohol
- emulsifying
- fatty acid
- collagen peptide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 12
- 230000001804 emulsifying effect Effects 0.000 title abstract description 11
- 239000003921 oil Substances 0.000 claims abstract description 27
- 235000019198 oils Nutrition 0.000 claims abstract description 27
- 102000008186 Collagen Human genes 0.000 claims abstract description 15
- 108010035532 Collagen Proteins 0.000 claims abstract description 15
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229920001436 collagen Polymers 0.000 claims abstract description 15
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 15
- 239000000194 fatty acid Substances 0.000 claims abstract description 15
- 229930195729 fatty acid Natural products 0.000 claims abstract description 15
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 15
- 239000003240 coconut oil Substances 0.000 claims abstract description 14
- 235000019864 coconut oil Nutrition 0.000 claims abstract description 14
- 239000011591 potassium Substances 0.000 claims abstract description 14
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 14
- 108090000765 processed proteins & peptides Proteins 0.000 claims abstract description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000007788 liquid Substances 0.000 claims description 7
- OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical compound CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 abstract description 13
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 abstract description 12
- IWWCATWBROCMCW-UHFFFAOYSA-N batyl alcohol Natural products CCCCCCCCCCCCCCCCCCOC(O)CO IWWCATWBROCMCW-UHFFFAOYSA-N 0.000 abstract description 6
- 229960000735 docosanol Drugs 0.000 abstract description 6
- 239000003995 emulsifying agent Substances 0.000 abstract description 3
- 235000021302 avocado oil Nutrition 0.000 abstract description 2
- 239000008163 avocado oil Substances 0.000 abstract description 2
- 229940056211 paraffin Drugs 0.000 abstract 1
- 239000012188 paraffin wax Substances 0.000 abstract 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 12
- 239000000839 emulsion Substances 0.000 description 12
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 10
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N dodecahydrosqualene Natural products CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 9
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 6
- 239000002736 nonionic surfactant Substances 0.000 description 6
- 239000003205 fragrance Substances 0.000 description 5
- 235000011187 glycerol Nutrition 0.000 description 5
- 229940057995 liquid paraffin Drugs 0.000 description 5
- 239000003755 preservative agent Substances 0.000 description 5
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 4
- 229920002125 Sokalan® Polymers 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 4
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 4
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 4
- 235000011118 potassium hydroxide Nutrition 0.000 description 4
- 230000002335 preservative effect Effects 0.000 description 4
- 239000008213 purified water Substances 0.000 description 4
- 229940032094 squalane Drugs 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical group O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 229940058015 1,3-butylene glycol Drugs 0.000 description 3
- RZRNAYUHWVFMIP-GDCKJWNLSA-N 3-oleoyl-sn-glycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@H](O)CO RZRNAYUHWVFMIP-GDCKJWNLSA-N 0.000 description 3
- 235000019437 butane-1,3-diol Nutrition 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- BJRNKVDFDLYUGJ-RMPHRYRLSA-N hydroquinone O-beta-D-glucopyranoside Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1OC1=CC=C(O)C=C1 BJRNKVDFDLYUGJ-RMPHRYRLSA-N 0.000 description 3
- 229940119170 jojoba wax Drugs 0.000 description 3
- -1 liquid paraffin Chemical class 0.000 description 3
- 229940055577 oleyl alcohol Drugs 0.000 description 3
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- MPDGHEJMBKOTSU-YKLVYJNSSA-N 18beta-glycyrrhetic acid Chemical compound C([C@H]1C2=CC(=O)[C@H]34)[C@@](C)(C(O)=O)CC[C@]1(C)CC[C@@]2(C)[C@]4(C)CC[C@@H]1[C@]3(C)CC[C@H](O)C1(C)C MPDGHEJMBKOTSU-YKLVYJNSSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 239000010495 camellia oil Substances 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- XOJVVFBFDXDTEG-UHFFFAOYSA-N pristane Chemical compound CC(C)CCCC(C)CCCC(C)CCCC(C)C XOJVVFBFDXDTEG-UHFFFAOYSA-N 0.000 description 2
- YYGNTYWPHWGJRM-UHFFFAOYSA-N (6E,10E,14E,18E)-2,6,10,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaene Chemical compound CC(C)=CCCC(C)=CCCC(C)=CCCC=C(C)CCC=C(C)CCC=C(C)C YYGNTYWPHWGJRM-UHFFFAOYSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- 239000000263 2,3-dihydroxypropyl (Z)-octadec-9-enoate Substances 0.000 description 1
- LEACJMVNYZDSKR-UHFFFAOYSA-N 2-octyldodecan-1-ol Chemical compound CCCCCCCCCCC(CO)CCCCCCCC LEACJMVNYZDSKR-UHFFFAOYSA-N 0.000 description 1
- BGRXBNZMPMGLQI-UHFFFAOYSA-N 2-octyldodecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCC(CCCCCCCC)CCCCCCCCCC BGRXBNZMPMGLQI-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 235000002568 Capsicum frutescens Nutrition 0.000 description 1
- 102000002322 Egg Proteins Human genes 0.000 description 1
- 108010000912 Egg Proteins Proteins 0.000 description 1
- MPDGHEJMBKOTSU-UHFFFAOYSA-N Glycyrrhetinsaeure Natural products C12C(=O)C=C3C4CC(C)(C(O)=O)CCC4(C)CCC3(C)C1(C)CCC1C2(C)CCC(O)C1(C)C MPDGHEJMBKOTSU-UHFFFAOYSA-N 0.000 description 1
- CMBYOWLFQAFZCP-UHFFFAOYSA-N Hexyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCCCCC CMBYOWLFQAFZCP-UHFFFAOYSA-N 0.000 description 1
- 235000018330 Macadamia integrifolia Nutrition 0.000 description 1
- 240000000912 Macadamia tetraphylla Species 0.000 description 1
- 235000003800 Macadamia tetraphylla Nutrition 0.000 description 1
- 241000772415 Neovison vison Species 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 235000019483 Peanut oil Nutrition 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- 235000019774 Rice Bran oil Nutrition 0.000 description 1
- 235000019485 Safflower oil Nutrition 0.000 description 1
- BHEOSNUKNHRBNM-UHFFFAOYSA-N Tetramethylsqualene Natural products CC(=C)C(C)CCC(=C)C(C)CCC(C)=CCCC=C(C)CCC(C)C(=C)CCC(C)C(C)=C BHEOSNUKNHRBNM-UHFFFAOYSA-N 0.000 description 1
- 235000006732 Torreya nucifera Nutrition 0.000 description 1
- 244000111306 Torreya nucifera Species 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- BTFJIXJJCSYFAL-UHFFFAOYSA-N arachidyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCO BTFJIXJJCSYFAL-UHFFFAOYSA-N 0.000 description 1
- 229960000271 arbutin Drugs 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- SASYSVUEVMOWPL-NXVVXOECSA-N decyl oleate Chemical compound CCCCCCCCCCOC(=O)CCCCCCC\C=C/CCCCCCCC SASYSVUEVMOWPL-NXVVXOECSA-N 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 235000013345 egg yolk Nutrition 0.000 description 1
- 210000002969 egg yolk Anatomy 0.000 description 1
- 229960003720 enoxolone Drugs 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- GQXQIRNPJBUEGY-UHFFFAOYSA-N hexadecan-7-yl 2,2-dimethyloctanoate Chemical compound CCCCCCCCCC(CCCCCC)OC(=O)C(C)(C)CCCCCC GQXQIRNPJBUEGY-UHFFFAOYSA-N 0.000 description 1
- 229940100463 hexyl laurate Drugs 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 229940074358 magnesium ascorbate Drugs 0.000 description 1
- AIOKQVJVNPDJKA-ZZMNMWMASA-L magnesium;(2r)-2-[(1s)-1,2-dihydroxyethyl]-4-hydroxy-5-oxo-2h-furan-3-olate Chemical compound [Mg+2].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] AIOKQVJVNPDJKA-ZZMNMWMASA-L 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- RZRNAYUHWVFMIP-UHFFFAOYSA-N monoelaidin Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-UHFFFAOYSA-N 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000010466 nut oil Substances 0.000 description 1
- 229940073665 octyldodecyl myristate Drugs 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- BARWIPMJPCRCTP-UHFFFAOYSA-N oleic acid oleyl ester Natural products CCCCCCCCC=CCCCCCCCCOC(=O)CCCCCCCC=CCCCCCCCC BARWIPMJPCRCTP-UHFFFAOYSA-N 0.000 description 1
- BARWIPMJPCRCTP-CLFAGFIQSA-N oleyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCCOC(=O)CCCCCCC\C=C/CCCCCCCC BARWIPMJPCRCTP-CLFAGFIQSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- BJRNKVDFDLYUGJ-UHFFFAOYSA-N p-hydroxyphenyl beta-D-alloside Natural products OC1C(O)C(O)C(CO)OC1OC1=CC=C(O)C=C1 BJRNKVDFDLYUGJ-UHFFFAOYSA-N 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229940093430 polyethylene glycol 1500 Drugs 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000008165 rice bran oil Substances 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 229940031439 squalene Drugs 0.000 description 1
- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- VLPFTAMPNXLGLX-UHFFFAOYSA-N trioctanoin Chemical compound CCCCCCCC(=O)OCC(OC(=O)CCCCCCC)COC(=O)CCCCCCC VLPFTAMPNXLGLX-UHFFFAOYSA-N 0.000 description 1
- 239000002383 tung oil Substances 0.000 description 1
- 239000010497 wheat germ oil Substances 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Colloid Chemistry (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は、ヤシ油脂肪酸コラーゲンペプチドカリウムと
、液状油分と、高級アルコールとを含有することを特徴
とする安定性、使用性に優れた乳化組成物に関する。[Detailed Description of the Invention] [Industrial Application Field] The present invention provides an emulsion with excellent stability and ease of use, which is characterized by containing coconut oil fatty acid collagen peptide potassium, liquid oil, and higher alcohol. Regarding the composition.
［従来の技術］
従来から、Ｏ／Ｗ型の乳化組成物を得るために、非イオ
ン界面活性剤を単独で、あるいは石鹸と非イオン界面活
性剤を併用で乳化剤として用いてきた。しかしながら、
十分な乳化力を得るためには、これら乳化剤を多量に配
合する必要があり、これが原因で系にべたつきが生じた
り、安全性の面で好ましくないといった問題点があった
。[Prior Art] Conventionally, in order to obtain O/W type emulsified compositions, nonionic surfactants have been used alone or in combination with soap and nonionic surfactants as emulsifiers. however,
In order to obtain sufficient emulsifying power, it is necessary to incorporate a large amount of these emulsifiers, which causes problems such as stickiness in the system and unfavorable safety issues.
ヤシ油脂肪酸コラーゲンペプチドカリウムは、少量で優
れた乳化力を有するために、他の非イオン界面活性剤を
用いた系に比べて使用性面のべたつきのなき、安定性、
安全性面で優れている等の利点があり、従来からこれを
用いる試みがなきれている。Coconut oil fatty acid collagen peptide potassium has excellent emulsifying power in a small amount, so compared to systems using other nonionic surfactants, it is non-sticky, stable, and easy to use.
It has advantages such as being superior in terms of safety, and so far there have been no attempts to use it.
［発明が解決しようとする課題］
しかしながら、ヤシ油脂肪酸コラーゲンペプチドカリウ
ムを用いた系は、上記した利点を有するものの、他の非
イオン界面活性剤を用いた系に比べると、肌へのなじみ
が悪く、又コクがなく水っぽいといった欠点があった。[Problems to be Solved by the Invention] However, although the system using coconut oil fatty acid collagen peptide potassium has the above-mentioned advantages, it is less compatible with the skin than systems using other nonionic surfactants. It was bad, and it also had the drawbacks of being lackluster and watery.
本発明者は上記欠点について鋭意検討した結果、高級ア
ルコールを用いたならば、なじみが良く、コクの有る使
用性が得られることを見出して本発明を完成するに至っ
た。As a result of intensive study on the above-mentioned drawbacks, the inventors of the present invention have found that the use of higher alcohols provides good familiarity and richness in use, leading to the completion of the present invention.
［課題を解決するための手段］
すなわち本発明は、ヤシ油脂肪酸コラーゲンベブチドカ
リウムと、液状油分と、高級アルコールとを含有するこ
とを特徴とする乳化組成物に関する。[Means for Solving the Problems] That is, the present invention relates to an emulsified composition characterized by containing potassium coconut oil fatty acid collagen bebutide, a liquid oil component, and a higher alcohol.
以下、本発明の構成について詳述する。Hereinafter, the configuration of the present invention will be explained in detail.
本発明で用いられるヤシ油脂肪酸コラーゲンペプチドカ
リウムは、コラーゲンを加水分解して得られたポリペブ
タイトをアシル化し、中和したものであり、市販品とし
ては、ブロモイスＥＣＰ（酸相化成社製）、ラメポンＳ
（Ｃｈｅｍｉｓｈｅ Ｆａｂｒｉｋ Ｇｒｕｎａｎ
ＧＭＢＨ社製）等が挙げられる。The coconut oil fatty acid collagen peptide potassium used in the present invention is obtained by acylating and neutralizing polypebutite obtained by hydrolyzing collagen, and commercially available products include Bromois ECP (manufactured by Acid Co., Ltd.) and Ramepon. S
(Chemishe Fabrik Grunan
(manufactured by GMBH), etc.
本発明で用いられるヤシ油脂肪酸コラーゲンペプチドカ
リウムの配合量は、特に限定されないが乳化組成物全量
中、０．３重量％以下が好ましい。０６３重量％を超え
ると特異臭が強くなり好ましくない。The amount of coconut oil fatty acid collagen peptide potassium used in the present invention is not particularly limited, but is preferably 0.3% by weight or less based on the total amount of the emulsified composition. If it exceeds 0.063% by weight, the specific odor becomes strong, which is not preferable.
本発明で用いられる高級アルコールとしては、ベヘニル
アルコール、バチルアルコール、ステアリルアルコール
、セチルアルコール等が挙げられ、これらの中でもベヘ
ニルアルコール、バチルアルコールが好ましく、特にベ
ヘニルアルコールとバチルアルコールとをベヘニルアル
コール：バチルアルコール＝１：２〜１：１の比で用い
ると、効果の面で特に好ましい。Examples of the higher alcohol used in the present invention include behenyl alcohol, batyl alcohol, stearyl alcohol, cetyl alcohol, etc. Among these, behenyl alcohol and batyl alcohol are preferred, and in particular, behenyl alcohol and batyl alcohol are mixed in a ratio of behenyl alcohol: batyl alcohol = 1:2. A ratio of 1:1 to 1:1 is particularly preferred in terms of effectiveness.
本発明で用いられる高級アルコールの配合量は、油分量
に対して１７３〜１７１５倍量であり、好ましくは、１
７５〜１７１０倍量である。１７３倍量を超えると効果
はきはと増加せず、結晶析出等の可能性がある。また１
７１５倍量未満では、効果がさほど期待できない。The amount of higher alcohol used in the present invention is 173 to 1715 times the amount of oil, preferably 1
It is 75 to 1710 times the amount. If the amount exceeds 173 times, the effect will not increase significantly and crystal precipitation may occur. Also 1
If the amount is less than 715 times, the effect cannot be expected to be so great.
本発明に用いられる液状油分としては、アボガド油、ツ
バキ油、タードル油、マカデミアナツツ油、トウ上０コ
シ油、ミンク油、オリーブ油、ナタネ油、卵黄油、ゴマ
油、パーシック油、小麦胚芽油、サザンカ油、ヒマシ油
、アマニ油、サフラワー油、綿実油、エノ油、大豆油、
落花生油、茶実油、カヤ油、コメヌカ油、シナキリ油、
日本キリ油、ホホバ油、胚芽油、トリグリセリン、トリ
オクタン酸グリセリン、トリイソパルミチン酸グリセリ
ン等の液状油分、流動パラフィン、スクワレン、スクワ
ラン、プリスタン等の炭化水素、オレイン酸、トール油
、イソステアリン酸等の高級アルコール脂肪酸、ラウリ
ルアルコール、オレイルアルコール、インステアリルア
ルコール、オクチルドデカノール等の高級アルコール、
メチルポリシロキサン、メチルフェニルポリシロキサン
、メチルハイドロジエンポリシロキサン、デカメチルポ
リシロキサン等のシリコーン、ミリスチン酸イソプロピ
ル、バルミチン酸イソプロピル、ラウリン酸ヘキシル、
オレイン酸オレイル、オレイン酸デシルミリスチン酸オ
クチルドデシル、ジメチルオクタン酸へキシルデシル、
フタル酸ジエチル°、フタル酸ジブチル等のエステル類
等が挙げられる。The liquid oils used in the present invention include avocado oil, camellia oil, tardle oil, macadamia nut oil, chili oil, mink oil, olive oil, rapeseed oil, egg yolk oil, sesame oil, persic oil, wheat germ oil, and sasanica oil. oil, castor oil, linseed oil, safflower oil, cottonseed oil, eno oil, soybean oil,
Peanut oil, tea seed oil, kaya oil, rice bran oil, shinakiri oil,
Liquid oils such as Japanese tung oil, jojoba oil, germ oil, triglycerin, glyceryl trioctanoate, glycerin triisopalmitate, hydrocarbons such as liquid paraffin, squalene, squalane, pristane, oleic acid, tall oil, isostearic acid, etc. Higher alcohols such as fatty acids, lauryl alcohol, oleyl alcohol, instearyl alcohol, octyldodecanol,
Silicones such as methylpolysiloxane, methylphenylpolysiloxane, methylhydrogenpolysiloxane, decamethylpolysiloxane, isopropyl myristate, isopropyl valmitate, hexyl laurate,
oleyl oleate, decyl oleate, octyldodecyl myristate, hexyldecyl dimethyloctanoate,
Examples include esters such as diethyl phthalate and dibutyl phthalate.
本発明で用いられる液状油分の配合量は、ヤシ油脂肪酸
コラーゲンペプチドカリウムに対して好ましくは、２０
０倍量以下であり、さらに好ましくは１５０倍量以下で
ある。２００倍量を超えると乳化安定性が悪くなり好ま
しくない。The amount of liquid oil used in the present invention is preferably 20% based on coconut oil fatty acid collagen peptide potassium.
The amount is 0 times or less, and more preferably 150 times or less. If the amount exceeds 200 times, emulsion stability deteriorates, which is not preferable.
本発明の乳化組成物には、上記の必須成分の他に液状油
分、固型油分、防腐剤、色材、粉末、酸化防止剤、香料
、紫外線吸収剤、薬剤、アルコール、保湿剤、高分子等
を加えることかできる。In addition to the above-mentioned essential ingredients, the emulsified composition of the present invention contains liquid oil, solid oil, preservatives, colorants, powders, antioxidants, fragrances, ultraviolet absorbers, drugs, alcohol, humectants, and polymers. etc. can be added.
［発明の効果１
本発明の乳化組成物は、従来の非イオン界面活性剤を用
いた乳化系と比べて、優れた乳化力をもち、べたつきが
少なく、また、従来のヤシ油脂肪酸コラーゲンペプチド
カリウム乳化系と比べて、コクが有り、肌へのなじみが
良いものである。[Effects of the Invention 1] The emulsifying composition of the present invention has superior emulsifying power and less stickiness compared to conventional emulsifying systems using nonionic surfactants, and also has less stickiness than conventional coconut oil fatty acid collagen peptide potassium. Compared to emulsified products, it has a richer texture and blends better into the skin.
［実施例］
次に実施例により、本発明の効果について説明する。本
発明はこれらに限定されるものではない。[Example] Next, the effects of the present invention will be explained with reference to Examples. The present invention is not limited to these.
配合量は重量％である。The blending amount is in weight%.
比較例１ 乳 液
（１）スクワラン
（２）流動パラフィン
（３）ホホバ油
（４）ポリオキシエチレン（２０モル）オレイルアルコ
ールエーテル
（５）グルセリルモノオレエート
（６）防腐剤
適量
（７）香 料 適量（８）グ
リセリン １０（９） １ 、
３−ブチレングリコール ２（１０）カルボ
キシビニルポリマー
（カーボボール ９４１ ） ０．２（１１
）苛性カリ ０．０８（１２
）精製水 残余製 法
（１２）に（８）〜（１０）を添加し、撹拌溶解後７０
℃に加熱する。それに７０℃において加熱溶解した（１
）〜（７）を加え乳化後、（１１）を加えて中和する。Comparative Example 1 Emulsion (1) Squalane (2) Liquid paraffin (3) Jojoba oil (4) Polyoxyethylene (20 mol) Oleyl alcohol ether (5) Glyceryl monooleate (6) Appropriate amount of preservative (7) Fragrance Adequate amount (8) Glycerin 10 (9) 1,
3-Butylene glycol 2(10) carboxyvinyl polymer (Carbobol 941) 0.2(11
) Caustic potash 0.08 (12
) Purified water Residue production method (8) to (10) were added to method (12), and after stirring and dissolving, 70
Heat to ℃. It was heated and dissolved at 70℃ (1
) to (7) are added to emulsify, and then (11) is added to neutralize.
その後、８Ｍ処理し、熱交換して乳液を得た。Thereafter, it was treated with 8M and subjected to heat exchange to obtain a milky lotion.
実施例１ 乳 液
（１スクワラン
（２流動パラフイン
（３ホホバ油
（４ステアリルアルコール
（５バチルアルコール
（６防腐剤
０．３
０．３
適量
（７）香 料 適量（８）グ
リセリン １０（９）ヤシ油脂
肪酸コラーゲン
ペプチドカリウム ０．２（１０） １
、３−ブチレングリコール ２（１１）カ
ルボキシビニルポリマー
（カーボボール９４１ ） ０．２（１２
）苛性カリ ０．８（１３
）精製水 残余製法
（１）〜（７）を６０℃で加熱溶解し油相パーツを得る
。Example 1 Emulsion (1) squalane (2) liquid paraffin (3) jojoba oil (4) stearyl alcohol (5) butyl alcohol (6) preservative 0.3 0.3 appropriate amount (7) fragrance appropriate amount (8) glycerin 10 (9) coconut Oil fatty acid collagen peptide potassium 0.2 (10) 1
, 3-butylene glycol 2(11) carboxyvinyl polymer (Carbobol 941) 0.2(12
) Caustic potash 0.8 (13
) Purified water The remaining production methods (1) to (7) are heated and dissolved at 60°C to obtain an oil phase part.
（８）と（９）を６０℃で加熱混合後、８Ｍ処理しなか
ら油相パーツを添加しゲルパーツを得る。After heating and mixing (8) and (9) at 60° C., the oil phase parts are added after 8M treatment to obtain gel parts.
（１３）に（１０）、（１１）を添加し撹拌溶解後、（
１２）およびゲルパーツを添加し、８Ｍ処理し乳液を得
た。Add (10) and (11) to (13), stir and dissolve, then (
12) and gel parts were added and treated with 8M to obtain an emulsion.
実施例２ 乳 液
（１）スクワラン
（２）流動パラフィン
（３）示示バ油
］
（４）ベヘニルアルコール ０．３（５
）バチルアルコール ０．８（６）防
腐剤 適量（７）香 料
適量（８）グリセリン
１゜（９）ヤシ油脂肪酸コラーゲ
ン
ペプチドカリウム ０．２（１０） １
、３−ブチレングリコール ２（１１）カ
ルボキシビニルポリマー
（力−ポボール９４１ ） ０．２（１２
）苛性カリ ０．０８（１
３）精製水 残余製 法
（１）〜（７）を６０℃において加熱溶解し油相パーツ
を得る。（８）と（９）を混合し６０℃に加熱後、８Ｍ
処理しなから油相パーツを添加し、ゲルパーツを得る。Example 2 Emulsion (1) Squalane (2) Liquid paraffin (3) Shower oil] (4) Behenyl alcohol 0.3 (5
) Bacyl alcohol 0.8 (6) Preservative appropriate amount (7) Fragrance
Appropriate amount (8) Glycerin
1゜(9) Coconut oil fatty acid collagen peptide potassium 0.2(10) 1
, 3-butylene glycol 2(11) carboxyvinyl polymer (force-pobol 941) 0.2(12
) Caustic potash 0.08 (1
3) Purified water Residue production Methods (1) to (7) are heated and dissolved at 60°C to obtain an oil phase part. After mixing (8) and (9) and heating to 60℃, 8M
Before treatment, oil phase parts are added to obtain gel parts.
（１３）に（１０）、（１１）を添加し撹拌溶解後、（
１２）およびゲルパーツを添加し、８Ｍ処理し乳液を得
た。Add (10) and (11) to (13), stir and dissolve, then (
12) and gel parts were added and treated with 8M to obtain an emulsion.
比較例１、実施例１〜２の使用性を専門パネル２０名で
判定した。また乳化安定性についてはそれぞれ０℃、Ｒ
Ｔ、３７℃、５０℃で１力月放置後、肉眼で判定した。The usability of Comparative Example 1 and Examples 1 to 2 was evaluated by a panel of 20 experts. Regarding emulsion stability, 0°C and R
T, after being left at 37°C and 50°C for 1 month, judgment was made with the naked eye.
０：非常に安定 ○：安定 △：やや分離 ×：かなり分離 結果を表−１に示す。0: very stable ○：Stable △: Slightly separated ×: Quite separated The results are shown in Table-1.
（以下余白）
表−１から明らかなように、実施例１．２は、乳化安定
性に優れ、しかも比較例１の他の非イオン界面活性剤の
系に比べてべとつきが少なく、コクが有り、なじみの良
いことがわかる。(Left below) As is clear from Table 1, Example 1.2 has excellent emulsion stability, and is less sticky and richer than Comparative Example 1, which uses other nonionic surfactants. , it can be seen that the familiarity is good.
実施例３ 乳 液
（１）流動パラフィン
（２）メチルポリシロキサン
（３）オレイルアルコール
（４）２−ヒドロキシ−４−メトキシ
ベンゾフェノン
（５）グリチルレチン酸
（６）酢酸ｄｉ−α−ミーα−トコフ
ェロールヘニルアルコール
（８）バチルアルコール
（９）防腐剤
（１０）香 料
（１１）グリセリン
（１２）ヤシ油脂肪酸コラーゲン
ペプチドカリウム
（１３）ポリエチレングリコール１５００（１４）アル
ブチン
（１５）アスコルビン酸
リン酸マグネシウム
（１６）カルボキシビニルポリマー
（カーボボール９４１）
０．１
０．１
０．１
０．２
０．４
適量
適量
０．３
０．１
０．３
（１７）苛性カリ
（１８）精製水
製法は、実施例１と同様
０．１５
残余
実施例３で得られた乳液は、乳化安定性に優れ、べたつ
きがなく、コクがあり、肌へのなじみに優れるものであ
った。Example 3 Emulsion (1) Liquid paraffin (2) Methylpolysiloxane (3) Oleyl alcohol (4) 2-hydroxy-4-methoxybenzophenone (5) Glycyrrhetinic acid (6) Di-α-Meα-tocopherolhenyl acetate Alcohol (8) Batyl alcohol (9) Preservative (10) Fragrance (11) Glycerin (12) Coconut oil fatty acid collagen peptide potassium (13) Polyethylene glycol 1500 (14) Arbutin (15) Magnesium ascorbate phosphate (16) Carboxyvinyl polymer (Carboball 941) 0.1 0.1 0.1 0.2 0.4 Appropriate amount Appropriate amount 0.3 0.1 0.3 (17) Caustic potash (18) Purified water production method is as in Example 1. Same as 0.15 Residue The emulsion obtained in Example 3 had excellent emulsion stability, was not sticky, had a rich body, and was excellent in blending into the skin.
Claims (1)
状油分と、高級アルコールとを含有することを特徴とす
る乳化組成物。(1) An emulsified composition characterized by containing coconut oil fatty acid collagen peptide potassium, liquid oil, and higher alcohol.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2205476A JP2963505B2 (en) | 1990-08-02 | 1990-08-02 | Emulsion composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2205476A JP2963505B2 (en) | 1990-08-02 | 1990-08-02 | Emulsion composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0490844A true JPH0490844A (en) | 1992-03-24 |
| JP2963505B2 JP2963505B2 (en) | 1999-10-18 |
Family
ID=16507491
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2205476A Expired - Fee Related JP2963505B2 (en) | 1990-08-02 | 1990-08-02 | Emulsion composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2963505B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003078470A1 (en) * | 2002-03-15 | 2003-09-25 | Lg Household & Health Care Ltd. | Fusion peptide grafted with tat peptide to human type-i collagen derived peptide, its preparation method, and cosmetic composition for anti-aging comprising the same |
| JP2009023952A (en) * | 2007-07-20 | 2009-02-05 | Pola Chem Ind Inc | Skin care preparation for external use |
| JP2009023947A (en) * | 2007-07-19 | 2009-02-05 | Kuraray Co Ltd | Skin care preparation for external use |
-
1990
- 1990-08-02 JP JP2205476A patent/JP2963505B2/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003078470A1 (en) * | 2002-03-15 | 2003-09-25 | Lg Household & Health Care Ltd. | Fusion peptide grafted with tat peptide to human type-i collagen derived peptide, its preparation method, and cosmetic composition for anti-aging comprising the same |
| JP2009023947A (en) * | 2007-07-19 | 2009-02-05 | Kuraray Co Ltd | Skin care preparation for external use |
| JP2009023952A (en) * | 2007-07-20 | 2009-02-05 | Pola Chem Ind Inc | Skin care preparation for external use |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2963505B2 (en) | 1999-10-18 |
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