JPS63154606A - Transparent skin cosmetic - Google Patents
Transparent skin cosmeticInfo
- Publication number
- JPS63154606A JPS63154606A JP30108386A JP30108386A JPS63154606A JP S63154606 A JPS63154606 A JP S63154606A JP 30108386 A JP30108386 A JP 30108386A JP 30108386 A JP30108386 A JP 30108386A JP S63154606 A JPS63154606 A JP S63154606A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- amount
- final composition
- water
- alkyl phosphate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 20
- 239000000203 mixture Substances 0.000 claims abstract description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000007788 liquid Substances 0.000 claims abstract description 19
- 239000012190 activator Substances 0.000 claims abstract description 17
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 16
- 239000010452 phosphate Substances 0.000 claims abstract description 16
- 239000000126 substance Substances 0.000 claims abstract description 15
- -1 alkyl phosphate Chemical compound 0.000 claims abstract description 13
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 9
- 238000002156 mixing Methods 0.000 claims abstract description 6
- 230000000694 effects Effects 0.000 abstract description 9
- 239000006071 cream Substances 0.000 abstract description 7
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 abstract description 6
- 150000001875 compounds Chemical class 0.000 abstract description 5
- 238000003756 stirring Methods 0.000 abstract description 5
- 229940057995 liquid paraffin Drugs 0.000 abstract description 3
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 abstract description 3
- 229940032094 squalane Drugs 0.000 abstract description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 abstract description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 abstract description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 abstract description 2
- 239000005642 Oleic acid Substances 0.000 abstract description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 abstract description 2
- 125000003342 alkenyl group Chemical group 0.000 abstract description 2
- 125000000217 alkyl group Chemical group 0.000 abstract description 2
- 125000000129 anionic group Chemical group 0.000 abstract description 2
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 abstract description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 abstract description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 abstract description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract description 2
- 229960002969 oleic acid Drugs 0.000 abstract 1
- 238000003860 storage Methods 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 8
- 239000000839 emulsion Substances 0.000 description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- 238000009472 formulation Methods 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 5
- 235000011613 Pinus brutia Nutrition 0.000 description 5
- 241000018646 Pinus brutia Species 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 235000019198 oils Nutrition 0.000 description 5
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- BGRXBNZMPMGLQI-UHFFFAOYSA-N 2-octyldodecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCC(CCCCCCCC)CCCCCCCCCC BGRXBNZMPMGLQI-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 229940073665 octyldodecyl myristate Drugs 0.000 description 2
- 239000004006 olive oil Substances 0.000 description 2
- 235000008390 olive oil Nutrition 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 229910052708 sodium Chemical group 0.000 description 2
- 239000011734 sodium Chemical group 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- LADGBHLMCUINGV-UHFFFAOYSA-N tricaprin Chemical compound CCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCC)COC(=O)CCCCCCCCC LADGBHLMCUINGV-UHFFFAOYSA-N 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 1
- DGSZGZSCHSQXFV-UHFFFAOYSA-N 2,3-bis(2-ethylhexanoyloxy)propyl 2-ethylhexanoate Chemical compound CCCCC(CC)C(=O)OCC(OC(=O)C(CC)CCCC)COC(=O)C(CC)CCCC DGSZGZSCHSQXFV-UHFFFAOYSA-N 0.000 description 1
- LEACJMVNYZDSKR-UHFFFAOYSA-N 2-octyldodecan-1-ol Chemical compound CCCCCCCCCCC(CO)CCCCCCCC LEACJMVNYZDSKR-UHFFFAOYSA-N 0.000 description 1
- HBTAOSGHCXUEKI-UHFFFAOYSA-N 4-chloro-n,n-dimethyl-3-nitrobenzenesulfonamide Chemical compound CN(C)S(=O)(=O)C1=CC=C(Cl)C([N+]([O-])=O)=C1 HBTAOSGHCXUEKI-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 244000180278 Copernicia prunifera Species 0.000 description 1
- 235000010919 Copernicia prunifera Nutrition 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- UNXHWFMMPAWVPI-QWWZWVQMSA-N D-threitol Chemical compound OC[C@@H](O)[C@H](O)CO UNXHWFMMPAWVPI-QWWZWVQMSA-N 0.000 description 1
- UNXHWFMMPAWVPI-UHFFFAOYSA-N Erythritol Natural products OCC(O)C(O)CO UNXHWFMMPAWVPI-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- SQUHHTBVTRBESD-UHFFFAOYSA-N Hexa-Ac-myo-Inositol Natural products CC(=O)OC1C(OC(C)=O)C(OC(C)=O)C(OC(C)=O)C(OC(C)=O)C1OC(C)=O SQUHHTBVTRBESD-UHFFFAOYSA-N 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical group 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- BTFJIXJJCSYFAL-UHFFFAOYSA-N arachidyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCO BTFJIXJJCSYFAL-UHFFFAOYSA-N 0.000 description 1
- POJOORKDYOPQLS-UHFFFAOYSA-L barium(2+) 5-chloro-2-[(2-hydroxynaphthalen-1-yl)diazenyl]-4-methylbenzenesulfonate Chemical compound [Ba+2].C1=C(Cl)C(C)=CC(N=NC=2C3=CC=CC=C3C=CC=2O)=C1S([O-])(=O)=O.C1=C(Cl)C(C)=CC(N=NC=2C3=CC=CC=C3C=CC=2O)=C1S([O-])(=O)=O POJOORKDYOPQLS-UHFFFAOYSA-L 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 1
- 239000004204 candelilla wax Substances 0.000 description 1
- 235000013868 candelilla wax Nutrition 0.000 description 1
- 229940073532 candelilla wax Drugs 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 229940105990 diglycerin Drugs 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- 229940031578 diisopropyl adipate Drugs 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 210000000245 forearm Anatomy 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 229960002737 fructose Drugs 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- CDAISMWEOUEBRE-GPIVLXJGSA-N inositol Chemical compound O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@H](O)[C@@H]1O CDAISMWEOUEBRE-GPIVLXJGSA-N 0.000 description 1
- 229960000367 inositol Drugs 0.000 description 1
- 229940119170 jojoba wax Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 239000000845 maltitol Substances 0.000 description 1
- VQHSOMBJVWLPSR-WUJBLJFYSA-N maltitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-WUJBLJFYSA-N 0.000 description 1
- 235000010449 maltitol Nutrition 0.000 description 1
- 229940035436 maltitol Drugs 0.000 description 1
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 1
- 239000004530 micro-emulsion Substances 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 229940059574 pentaerithrityl Drugs 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- CDAISMWEOUEBRE-UHFFFAOYSA-N scyllo-inosotol Natural products OC1C(O)C(O)C(O)C(O)C1O CDAISMWEOUEBRE-UHFFFAOYSA-N 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- QAEVVAMQWJMMGX-UHFFFAOYSA-M sodium;didodecyl phosphate Chemical compound [Na+].CCCCCCCCCCCCOP([O-])(=O)OCCCCCCCCCCCC QAEVVAMQWJMMGX-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 229960002920 sorbitol Drugs 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- OHRVKCZTBPSUIK-UHFFFAOYSA-N tridodecyl phosphate Chemical compound CCCCCCCCCCCCOP(=O)(OCCCCCCCCCCCC)OCCCCCCCCCCCC OHRVKCZTBPSUIK-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/55—Phosphorus compounds
- A61K8/556—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/26—Optical properties
- A61K2800/262—Transparent; Translucent
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、液状油性物質を多量含有しており、しかも外
観が透明な皮膚化粧料）こ関する。更に詳しくは、安全
性が高く、保存安定性（経日安定性）に優れ、かつ感触
、外観（透明性）、クレンジング効果、水洗性等の良好
な、液状油性物質を多量含有する透明皮膚化粧料に関す
る。DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) The present invention relates to skin cosmetics containing a large amount of liquid oily substances and having a transparent appearance. More specifically, transparent skin makeup containing a large amount of liquid oily substance is highly safe, has excellent storage stability (stable over time), and has good feel, appearance (transparency), cleansing effect, washability, etc. Regarding fees.
（従来技術）
従来、化粧料等に用いられている油性物質を含有する透
明化粧料には、一般にマイクロエマルジ璽ンがあるが、
界面活性剤を多量に使用する為、皮膚に刺激を与えると
いう問題があった。その為、使用する界面活性剤の量を
減少させる研究がなされ、第１段階として親水性非イオ
ン界面活性剤を水溶性洛媒中に添加し、次にこれに油相
を添加して水浴性洛媒中油型エマルジヲンを調製し、第
２段として該エマルジ百ンに水を添加せしめて、親水性
非イオン界面活性剤のみでしかも従来の乳化系に比較し
て半量以下で安定な水中油型エマルジ−ンを得る方法が
提案された（特公昭５７−２９２１８）。(Prior art) Transparent cosmetics containing oily substances conventionally used in cosmetics etc. generally include microemulsion seals.
Since a large amount of surfactant is used, there is a problem that it irritates the skin. Therefore, research has been conducted to reduce the amount of surfactant used, and the first step is to add a hydrophilic nonionic surfactant to a water-soluble liquid medium, and then add an oil phase to this to make it water-soluble. An oil-in-water type emulsion is prepared, and water is added to the emulsion in the second stage to create a stable oil-in-water type emulsion using only a hydrophilic nonionic surfactant and using less than half the amount of a conventional emulsion system. A method for obtaining emulsions was proposed (Japanese Patent Publication No. 57-29218).
（発明が解決しようとする問題点）
しかしながらこの方法で得らｎｔこエマルジョンでは、
乳化安定性が十分とはいえず、また油相／水相比の高い
エマルシロンが得にくいなどの問題がある。(Problem to be solved by the invention) However, in the emulsion obtained by this method,
There are problems such as the emulsion stability is not sufficient and it is difficult to obtain an emulsilone with a high oil phase/aqueous phase ratio.
（問題点を解決するための手段〉
本発明者は、前記従来技術の問題点を改良すべく鋭意研
究を重ねた結果、アルキルリン酸エステル系活性剤と多
量の液状油性物質との混合物を、多価アルコールと水と
の混合物に添加混合する場合は、容易に安全性が高く、
保存安定性（経口安定性）に優れ、かつ感触、外観（透
明性）、クレンジング効果、水洗性等の良好な透明皮膚
化粧料が得られることを見出し、本発明を完成した。(Means for Solving the Problems) As a result of extensive research to improve the problems of the prior art, the present inventor has developed a mixture of an alkyl phosphate ester activator and a large amount of liquid oily substance. When added to a mixture of polyhydric alcohol and water, it is easy to use and is highly safe.
The present invention was completed based on the discovery that a transparent skin cosmetic with excellent storage stability (oral stability) and good feel, appearance (transparency), cleansing effect, washability, etc. can be obtained.
すなわち、本発明は、アルキルリン酸エステル系非イオ
ン活性剤および／またはアルキルリン酸エステル系アニ
オン活性剤と４０〜９０重量％（重量％は最終組成物の
重量基準）の液状油性物質との混合物を、水の重量１こ
対して４倍量以上でかつ最終組成物の重量に対して５〜
５９重ｔ％の多価アルコールと水との混合物に、添加、
混合してなる、透明皮膚化粧料である。That is, the present invention provides a mixture of an alkyl phosphate nonionic activator and/or an alkyl phosphate ester anionic activator and 40 to 90% by weight (weight % is based on the weight of the final composition) of a liquid oily substance. in an amount of at least 4 times the weight of water and 5 to 5 times the weight of the final composition.
Adding to a mixture of 59% by weight polyhydric alcohol and water,
It is a transparent skin cosmetic made by mixing.
本発明で使用される前記のアルキルリン酸エステル系非
イオン活性剤としては、下記の式（１）で表わされる化
合物が好ましく、また前記のアルキルリン酸エステル系
アニオン活性剤としては下記の式（２）および式（３）
で表わされる化合物が好ましい。The alkyl phosphate nonionic activator used in the present invention is preferably a compound represented by the following formula (1), and the alkyl phosphate anion activator is preferably a compound represented by the following formula (1). 2) and equation (3)
Compounds represented by are preferred.
？９
Ｒ４＋〇−助力０−五−ＯＸ
・・・・・・（３）
（上記の各式中で、Ｒ１、Ｒ２，Ｒ８はエチレン基また
はプロピレン基を示し、Ｒ４，Ｒ５，Ｒ６は炭素数８〜
２２の直鎖または分校アルキル基またはアルケニル基を
示し、ｊ７．ｍ、ｎは０〜３０の整数を示し、Ｍはカリ
ウムまたはナトリウム、Ｘは水素原子またはカリウム、
ナトリウムである。）
ナルキルリン酸エステル系非イオン活性剤および／また
はアルキルリン酸エステル系アニオン活性□剤の使用量
（配合危）は、最終組成物の重量に対して０．５〜ｌＯ
重ｔ％である。０．５重量％よりも少な′いと保存安定
性が低下する傾向があり、１０重量％よりも多くなると
透明度が低下する傾向がある。? 9 R4+〇-Help 0-5-OX (3) (In each of the above formulas, R1, R2, R8 represent an ethylene group or a propylene group, and R4, R5, R6 have a carbon number of 8 ~
22 straight chain or branched alkyl or alkenyl group, j7. m and n represent integers of 0 to 30, M is potassium or sodium, X is a hydrogen atom or potassium,
It is sodium. ) The amount of the nalkyl phosphate nonionic activator and/or the alkyl phosphate ester anionic activator used (compounding hazard) is 0.5 to 1O based on the weight of the final composition.
The weight is t%. If it is less than 0.5% by weight, storage stability tends to decrease, and if it exceeds 10% by weight, transparency tends to decrease.
本発明で使用される多価アルコールとしては、例えば、
エチレングリコール、プロピレングリコール、１，８−
ブチレンゲリコール、ジプロピレングリコール、グリセ
リン、ジグリセリン・トリグリセリン・テトラグリセリ
ン等のポリグリセリン。Examples of the polyhydric alcohol used in the present invention include:
Ethylene glycol, propylene glycol, 1,8-
Polyglycerin such as butylene gelicol, dipropylene glycol, glycerin, diglycerin, triglycerin, tetraglycerin, etc.
グルコース、マルトース、マルチトール、蔗糖。Glucose, maltose, maltitol, sucrose.
フラクトース、キシリトール、イノシトール、ペンタエ
リスリトール、ソルビトール、マルトトリオール、スレ
イトール、澱粉分解糖、澱粉分解糖還元アルコール等が
挙げられ、これらを一種又は二種以上組合せて用いるも
のである。Examples include fructose, xylitol, inositol, pentaerythritol, sorbitol, maltotriol, threitol, starch-degrading sugar, starch-degrading sugar-reduced alcohol, and these may be used singly or in combination of two or more.
多価アルコールの使用量は、水の重量に対して４倍量以
上（好ましくは４〜１１８倍量）で、かつ最終組成物の
重量に対して５〜５９重量％である。多価アルコールの
使用量が水の重量に対して４倍量未満では透明度が不充
分であり、そして、最終組成物の重量に対して５重量１
％未満では保存安定性が低下しやす（、また５９重量％
よりも多くなると感触、クレンジング効果が低下しやす
い。The amount of polyhydric alcohol used is 4 times or more (preferably 4 to 118 times) the weight of water, and 5 to 59% by weight based on the weight of the final composition. If the amount of polyhydric alcohol used is less than 4 times the weight of water, the transparency will be insufficient;
If it is less than 59% by weight, storage stability tends to decrease (and if it is less than 59% by weight)
If the amount is more than that, the feel and cleansing effect tend to deteriorate.
本発明に使用される液状油性物質は、常温下で液状を呈
する公知の化粧料用液状油性物質でありで、液状の高級
脂肪族炭化水素類、動植物性油脂類、４級アルコール、
高級脂肪酸１合成エステル油、グリコール高級脂肪酸エ
ステル、シリコン油等である。例えば、流動パラフィン
、スクワラン。The liquid oily substance used in the present invention is a known liquid oily substance for cosmetics that is liquid at room temperature, and includes liquid higher aliphatic hydrocarbons, animal and vegetable oils, quaternary alcohols,
These include higher fatty acid 1 synthetic ester oil, glycol higher fatty acid ester, silicone oil, etc. For example, liquid paraffin, squalane.
オリーブ油、ヒマシ油、ホホバ油、オクチルドデカノー
ル６、オクチルドデシルミリステート、ジイソプロピル
アジペート、２−エチルヘキサン酸トリグリセリド、カ
プリン酸トリグリセリド、オレイルアルコール、オレイ
ン酸等を挙げることができる。これらの液状油性物質は
、一種又は二種以上組合せて用いるものである。液状油
性物質の使用量は、最終組成物の重量に対して４０〜９
０重量％使用される。４０重量％より少ない場合は、感
触、クレンジング効果がわるくなりやすく、また９０重
量％を超えると保存安定性が低下しやすい。Examples include olive oil, castor oil, jojoba oil, octyl dodecanol 6, octyl dodecyl myristate, diisopropyl adipate, 2-ethylhexanoic acid triglyceride, capric acid triglyceride, oleyl alcohol, and oleic acid. These liquid oily substances may be used singly or in combination. The amount of liquid oily substance used is 40-9% based on the weight of the final composition.
0% by weight used. When it is less than 40% by weight, the feel and cleansing effect tend to deteriorate, and when it exceeds 90% by weight, storage stability tends to decrease.
また、水の量は本発明の最終組成物の透明度に応じて適
宜選択しつるが、通常０．５〜１５％範囲が好ましい。Further, the amount of water is appropriately selected depending on the transparency of the final composition of the present invention, but it is usually preferably in the range of 0.5 to 15%.
本発明の透明皮膚化粧料には、前記成分の他（こ必要に
応じて、香料２着色剤、防腐剤、金属イオン封鎖剤、皮
膚栄養剤、感触調整剤、ＰＨ調整剤、液状以外の油性物
質、上記以外の非イオン活性剤やアニオン活性剤、両性
活性剤等を上記効果を阻害しない範囲内で配合すること
ができる。In addition to the above-mentioned ingredients, the transparent skin cosmetic of the present invention may include fragrances, coloring agents, preservatives, sequestrants, skin nutrients, feel regulators, PH regulators, oil-based substances other than liquid Substances, nonionic activators, anionic activators, amphoteric activators, etc. other than those mentioned above can be blended within a range that does not impede the above effects.
本発明の透明皮膚化粧料は、例えばアルキルリン酸エス
テル系非イオン活性剤および／まｆこはアルキルリン酸
エステル系アニオン活性剤と液状油性物質を適温（例え
ば８０’Ｃ）下で混合して均一に溶解した後、この混和
物を、多価アルコールと水との混和物（例えば８０°Ｃ
）の中に、適当な混合機（例えばラボミキサー）で撹拌
しながら徐々に添加して均一に混合すると乳化（または
可溶化）して透明度の極めて高いかつ粘稠液体またはゲ
ル状物のかたちで生成し、次にこれを適温（約８０”Ｃ
）まで冷却して収得さｎる。The transparent skin cosmetic of the present invention can be produced by mixing, for example, an alkyl phosphate nonionic active agent and/or an alkyl phosphate anion active agent and a liquid oily substance at an appropriate temperature (for example, 80'C). After homogeneous dissolution, the mixture is heated to a mixture of polyhydric alcohol and water (e.g. 80°C
) into the liquid while stirring with a suitable mixer (for example, a lab mixer) and mix uniformly, it emulsifies (or solubilizes) into an extremely transparent and viscous liquid or gel. This is then heated to an appropriate temperature (approximately 80”C).
) and harvested.
本発明の透明皮膚化粧料は、ゲル状又は粘稠液体であっ
て、洗い流し可能な例えば透明ゲル状クレンジング及び
透明マツサージクリーム、透明ナリシングオイル、透明
ナリシングクリーム等として極めて有用である。The transparent skin cosmetic of the present invention is in the form of a gel or viscous liquid, and is extremely useful as a washable transparent gel cleanser, transparent pine surge cream, transparent nourishing oil, transparent nourishing cream, etc.
（実施例）
次に実施例を挙げて本発明を説明するが、本発明はこれ
らにより限定されるものではない。実施例に示す部とは
、重量部を意味する。(Example) Next, the present invention will be explained with reference to Examples, but the present invention is not limited thereto. Parts shown in Examples mean parts by weight.
実施例１１比較例１，２
実施例１は第１表に基づく処方で、■、■を約８０℃に
て均一に俗解する（溶液Ａ）。また■。Example 11 Comparative Examples 1 and 2 Example 1 is a formulation based on Table 1, and ① and ② are uniformly mixed at about 80°C (solution A). Also ■.
■を約８０℃にて均一に俗解する（浴液Ｂ）。次に溶液
Ｂに溶液Ａを徐々に加えラボミキサーで撹拌混合した後
、８０℃まで冷却して本発明の透明クレンジングクリー
ムを調製した。(2) is uniformly heated to about 80°C (bath solution B). Next, solution A was gradually added to solution B, mixed with stirring using a lab mixer, and then cooled to 80° C. to prepare a transparent cleansing cream of the present invention.
比較例１は第１表に基づく処方で、■の代わりに■を使
用する以外は実施例１と同様の方法で調製した。Comparative Example 1 was prepared in the same manner as in Example 1 except that ■ was used in place of ■ using the formulation shown in Table 1.
比較例２は第１表に基づく処方で、■、■を約８０℃に
て均一に溶解する（溶液Ａ）。溶液Ａに、予め約８０°
Ｃに加熱混合した■を徐々に加えラボミキサーで撹拌混
合した後、更に■を加えラボミキサーで撹拌混合し、こ
れを３０°Ｃまで冷却して調製した。Comparative Example 2 uses a formulation based on Table 1, and dissolves (1) and (2) uniformly at about 80°C (solution A). Solution A should be heated at approximately 80° in advance.
After heating and mixing ■ to C was gradually added and mixed with stirring using a lab mixer, ■ was further added and mixed with stirring using a lab mixer, and the mixture was cooled to 30°C to prepare.
皮膚化粧料の保存安定性は４０℃の恒温槽内で２ケ月間
保存後の外観状態より判定した。また透明性は肉眼によ
って判定した。The storage stability of the skin cosmetics was determined from the appearance after storage for 2 months in a constant temperature bath at 40°C. Transparency was also determined visually.
実施例１では保存安定性、透明性ともに極めて良好であ
ったが、比較例１では透明性はやや良好であったが保存
安定性は不良（分離）であった。In Example 1, the storage stability and transparency were both extremely good, while in Comparative Example 1, the transparency was somewhat good, but the storage stability was poor (separation).
また、比較例２は調製直後に分離を起した。Moreover, in Comparative Example 2, separation occurred immediately after preparation.
実施例２〜４、比較Ｎ８
実施例２〜比較例８は第２表に基づく処方で、実施例１
に準じて調製した。表中のクレンジング効果は次の方法
にて調べた。Examples 2 to 4, Comparative N8 Examples 2 to Comparative Example 8 are formulations based on Table 2, and Example 1
Prepared according to. The cleansing effects in the table were examined using the following method.
二酸化チタン５．０％、赤色２０４号０．６％、橙色２
０４号５．０％、キャンデリラロウ９．８％、赤色２２
８号０．２％、固形パラフィン８．０％、ミツロウ５．
０％、カルナウバロウ５．θ％、ラノリン１１．０％、
ヒマシ油４４．８％、イソプロピルミリステート１０％
からなる口紅を油性汚れとして、これを前腕用側部にＩ
ＣＭ２の広さに塗布した後、試料１ｆを塗布し、８０
秒間マツサージを行なった後、流水で洗い流し、口紅の
取れ易さを調べた。Titanium dioxide 5.0%, Red No. 204 0.6%, Orange 2
No. 04 5.0%, Candelilla wax 9.8%, Red 22
No. 8 0.2%, solid paraffin 8.0%, beeswax 5.
0%, carnauba wax5. θ%, lanolin 11.0%,
Castor oil 44.8%, isopropyl myristate 10%
Apply lipstick to the side of your forearm as an oil stain.
After coating the area of CM2, sample 1f was applied and 80
After performing pine surge for a second, the lipstick was rinsed with running water and the ease with which the lipstick was removed was examined.
また、水洗性は、試料０．８１を手の甲に塗布し、その
部分に一定水ｊｌ （１００ｍｌ／秒）ノ流水を５秒間
あてて、残存した試料の量をもって評価した。Furthermore, water washability was evaluated by applying sample 0.81 to the back of the hand, applying a constant stream of water (100 ml/sec) to that area for 5 seconds, and evaluating the amount of sample remaining.
感触は試料のとれ及び塗布時の伸びについて評価した。The feel of the sample was evaluated in terms of removal of the sample and elongation during application.
実施例２〜４ではクレンジング効果、水洗性。In Examples 2 to 4, the cleansing effect and washability were evaluated.
感触ともに極めて良好であったが、比較例８では水洗性
は良好であったものの、クレンジング効果はやや不良、
感触は不良であった。The feel was extremely good, but in Comparative Example 8, although the washability was good, the cleansing effect was somewhat poor.
The feel was poor.
実施例５（透明ナリシングクリーム）
下記に基づく処方で、実施例１に準じて透明ナリシング
クリームを調製した。Example 5 (Transparent Nourishing Cream) A transparent nourishing cream was prepared according to Example 1 with the following formulation.
■ジラウリルリン酸ナトリウム １部■トリラ
ウリルリン酸 ＩＩ！■ミリスチン
酸オクチルドデシル ２０部■オリーブ油
８５部■スクワラン
２０部■純水
８部■グリセリン ２０部得
られたナリシングクリームは透明性も保存安定性も感触
も極めて良好であった。■Sodium dilauryl phosphate 1 part ■Trilauryl phosphate II! ■Octyldodecyl myristate 20 parts ■Olive oil
Part 85 ■ Squalane
20 parts ■Pure water
8 parts ■ Glycerin 20 parts The obtained nourishing cream had extremely good transparency, storage stability, and feel.
実施例６（透明な温感マツサージ化粧料）下記に基づく
処方で、乳化温度を室温とする以外は実施例１に準じて
透明な温感−マツサージ化粧料を調製した。Example 6 (Transparent warm-sensing pine surge cosmetic) A transparent warm-sensing pine surge cosmetic was prepared according to Example 1, except that the emulsification temperature was set to room temperature, using the following formulation.
■カプリン酸トリグリセリド １０部■流動パ
ラフィン ６１部■純水
１部■グリセリン
２５部得られた透明な温感マツサージ化粧料
は、透明性、保存安定性、感触、水洗性が何ｎも極めて
良好であり、そして適度良好な温感を肌に与えた。■Capric acid triglyceride 10 parts ■Liquid paraffin 61 parts ■Pure water
1 part ■ Glycerin
The 25 parts of the obtained transparent warm-sensing pine surge cosmetic had extremely good transparency, storage stability, feel, and washability, and gave a moderately good warm feeling to the skin.
手 続 補 正 書 （自発） 昭和６２年７月２日Supplementary manuscript (spontaneous) July 2, 1986
Claims (3)
／またはアルキルリン酸エステル系アニオン活性剤と４
０〜９０重量％（重量％は最終組成物の重量基準）の液
状油性物質との混合物を、水の重量に対して４倍量以上
でかつ最終組成物の重量に対して５〜５９重量％の多価
アルコールと水との混合物に、添加、混合してなる、透
明皮膚化粧料。(1) An alkyl phosphate nonionic activator and/or an alkyl phosphate ester anionic activator and 4
0 to 90% by weight (wt% is based on the weight of the final composition) of a mixture with a liquid oily substance in an amount not less than 4 times the weight of water and 5 to 59% by weight relative to the weight of the final composition. A transparent skin cosmetic made by adding and mixing a polyhydric alcohol with water.
量％配合される、特許請求の範囲第（１）項記載の透明
皮膚化粧料。(2) The transparent skin cosmetic according to claim (1), wherein water is blended in an amount of 0.5 to 15% by weight based on the weight of the final composition.
／またはアルキルリン酸エステル系アニオン活性剤が、
最終組成物の重量に対して０．５〜１０重量％配合され
る、特許請求の範囲第（１）項記載の透明皮膚化粧料。(3) The alkyl phosphate nonionic activator and/or the alkyl phosphate anionic activator,
The transparent skin cosmetic according to claim 1, which is blended in an amount of 0.5 to 10% by weight based on the weight of the final composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61301083A JPH0778009B2 (en) | 1986-12-16 | 1986-12-16 | Transparent skin cosmetics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61301083A JPH0778009B2 (en) | 1986-12-16 | 1986-12-16 | Transparent skin cosmetics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63154606A true JPS63154606A (en) | 1988-06-27 |
| JPH0778009B2 JPH0778009B2 (en) | 1995-08-23 |
Family
ID=17892659
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61301083A Expired - Fee Related JPH0778009B2 (en) | 1986-12-16 | 1986-12-16 | Transparent skin cosmetics |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0778009B2 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01102012A (en) * | 1987-10-14 | 1989-04-19 | Shiseido Co Ltd | Cosmetic |
| JPH0331208A (en) * | 1989-06-22 | 1991-02-12 | Unilever Nv | Cosmetic compound |
| JPH0892059A (en) * | 1994-09-20 | 1996-04-09 | Shiseido Co Ltd | Transparent face lotion |
| EP0965328A1 (en) * | 1997-01-29 | 1999-12-22 | Kao Corporation | Cosmetic |
| JP2008081426A (en) * | 2006-09-27 | 2008-04-10 | Kao Corp | Liquid bathing agent |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63122775A (en) * | 1986-11-12 | 1988-05-26 | Kao Corp | Oil gelatinizing agent |
| JPS63225312A (en) * | 1986-10-02 | 1988-09-20 | Kao Corp | Transparent or semitransparent jelly-like cosmetic |
-
1986
- 1986-12-16 JP JP61301083A patent/JPH0778009B2/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63225312A (en) * | 1986-10-02 | 1988-09-20 | Kao Corp | Transparent or semitransparent jelly-like cosmetic |
| JPS63122775A (en) * | 1986-11-12 | 1988-05-26 | Kao Corp | Oil gelatinizing agent |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01102012A (en) * | 1987-10-14 | 1989-04-19 | Shiseido Co Ltd | Cosmetic |
| JPH0696493B2 (en) * | 1987-10-14 | 1994-11-30 | 株式会社資生堂 | Cosmetics |
| JPH0331208A (en) * | 1989-06-22 | 1991-02-12 | Unilever Nv | Cosmetic compound |
| JPH0892059A (en) * | 1994-09-20 | 1996-04-09 | Shiseido Co Ltd | Transparent face lotion |
| EP0965328A1 (en) * | 1997-01-29 | 1999-12-22 | Kao Corporation | Cosmetic |
| EP0965328A4 (en) * | 1997-01-29 | 2006-09-06 | Kao Corp | Cosmetic |
| JP2008081426A (en) * | 2006-09-27 | 2008-04-10 | Kao Corp | Liquid bathing agent |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0778009B2 (en) | 1995-08-23 |
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| JPS62225240A (en) | Oil-in-polyhydric alcohol type emulsion composition |
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