JPH0479961A - Deodorant - Google Patents

Deodorant

Info

Publication number
JPH0479961A
JPH0479961A JP2195487A JP19548790A JPH0479961A JP H0479961 A JPH0479961 A JP H0479961A JP 2195487 A JP2195487 A JP 2195487A JP 19548790 A JP19548790 A JP 19548790A JP H0479961 A JPH0479961 A JP H0479961A
Authority
JP
Japan
Prior art keywords
rosin
deodorizing
oil
mixture
citrus
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2195487A
Other languages
Japanese (ja)
Inventor
Takeo Inoue
井上 健夫
Tokuhiro Sakui
佐久井 徳広
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
San Ei Kagaku Co Ltd
Sanei Kagaku Kogyo KK
Original Assignee
San Ei Kagaku Co Ltd
Sanei Kagaku Kogyo KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by San Ei Kagaku Co Ltd, Sanei Kagaku Kogyo KK filed Critical San Ei Kagaku Co Ltd
Priority to JP2195487A priority Critical patent/JPH0479961A/en
Publication of JPH0479961A publication Critical patent/JPH0479961A/en
Pending legal-status Critical Current

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  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

PURPOSE:To obtain a deodorant of high safety for use over a wide range from domestic to industrical purpose etc. as well as the manufacturing method thereof by using a mixture of limonen and rosin as the deodorizing components thereof. CONSTITUTION:An aromatic deodorant containing a mixture of limonen of citrus terpene or citrus essential oil with rosin as its deodorizing components or containing the same mixture emulsified by means of addition of a surfactant. The rosin is selected from three kinds: sum rosin, wood rosin and tall oil rosin. The limonen mentioned here includes d-limonen, l-limonen and dipentene. As the citrus essential oil containing limonen, orange oil, Chinese citrus oil, lemon oil, lime oil and others are mentioned.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は一般家庭の臭気、産業界で発生する臭気その他
の臭気に有効でかつ安全であることを特徴とする消臭剤
及びその製造方法に関するものである。
[Detailed Description of the Invention] [Industrial Field of Application] The present invention provides a deodorizer that is effective and safe against household odors, industrial odors, and other odors, and a method for producing the same. It is related to.

〔従来の技術〕[Conventional technology]

近年、衣食住のレベルが急速に上がるにつれて、生活環
境に対する意識が高くなって来ている。公害等調整委員
会が発表した「昭和六十三年度公害苦情件数調査結果報
告書」によると悪臭公害件数は11,782件にものぼ
っている。公害苦情件数の中で臭気苦情は、騒音苦情に
次いで多く、その解決は急務となっている。
In recent years, as the level of food, clothing, and shelter has increased rapidly, people have become more conscious of the living environment. According to the ``FY 1988 Pollution Complaint Survey Results Report'' released by the Pollution Coordination Committee, the number of cases of odor pollution has reached 11,782. Among the number of pollution complaints, odor complaints are second only to noise complaints, and there is an urgent need to resolve them.

トイレ、生ごみ等の家庭内の悪臭、工場、塵芥処理工場
、下水処理場、家畜舎等の産業上の悪臭の消臭方法とし
ては、感覚的消臭法、化学的消臭法、物理的消臭法、生
物的消臭法に大別される。
Methods for deodorizing household odors such as toilets and garbage, industrial odors such as factories, garbage processing plants, sewage treatment plants, and livestock pens include sensory deodorization methods, chemical deodorization methods, and physical deodorization methods. It is broadly divided into deodorization method and biological deodorization method.

この内、感覚的消臭法または化学的消臭法として、リモ
ネン、あるいは、植物の花、葉、幹、根などから得られ
るリモネンを含む植物精油を用いる方法が従来よシ知ら
れている。リモネンを含む植物精油としては、オレンジ
油、夏ミカン油、レモン油、ライム油等がある。リモネ
ンあるいは、これらの精油は、エアゾール型消臭剤、ゲ
ル状消臭剤等の形状で用いられているが、感覚的消臭法
のみに頼ると、香料の匂いが強すぎる欠点がある。
Among these methods, a method using limonene or a plant essential oil containing limonene obtained from flowers, leaves, stems, roots, etc. of plants is conventionally known as a sensory deodorization method or a chemical deodorization method. Plant essential oils containing limonene include orange oil, summer tangerine oil, lemon oil, and lime oil. Limonene or these essential oils are used in the form of aerosol type deodorants, gel deodorants, etc. However, relying only on sensory deodorization methods has the disadvantage that the fragrance smell is too strong.

またその化学的消臭作用をとってみても効果のある悪臭
の種類が限られる欠点がある。即ち、リモネン、あるい
は前記精油に硫化水素、メチルメルカプタンなどの硫黄
系悪臭に対し、中和効果や吸収効果があることは知られ
ているが、たとえばトリメチルアミン等のアミン類には
効果が弱い。
Moreover, even when looking at its chemical deodorizing effect, it has the disadvantage that the types of bad odors that it is effective against are limited. That is, it is known that limonene or the above-mentioned essential oils have a neutralizing effect and an absorbing effect on sulfur-based malodors such as hydrogen sulfide and methyl mercaptan, but they have a weak effect on amines such as trimethylamine.

一方、ロジンの消臭剤としての有用性は、特公昭56−
30025などによって知られているが、ロジンのみで
は種々の悪臭に充分に対応できない。
On the other hand, the usefulness of rosin as a deodorant was
30025, etc., but rosin alone cannot sufficiently deal with various bad odors.

例エバ、トリメチルアミンとメチルメルカプタンに対す
る消臭効果を調べると後者については顕著な消臭作用が
認められない。
For example, when the deodorizing effect on trimethylamine and methyl mercaptan was investigated, no significant deodorizing effect was observed for the latter.

〔発明が解決しようとする課題〕[Problem to be solved by the invention]

本発明は、上記の消臭剤が有する問題点を解決したもの
であり、一般家庭及び産業用等、広い範囲に使用できる
安全性の高い消臭脱臭剤、及びその製造法に関するもの
である。
The present invention solves the problems of the above-mentioned deodorants, and relates to a highly safe deodorant and deodorizer that can be used in a wide range of applications, such as general household and industrial use, and a method for producing the same.

〔課題を解決するだめの手段〕[Failure to solve the problem]

かかる課題を解決するために鋭意研究を重ねた結果、消
臭成分としてリモネンまたは柑橘系テルペンまたは柑橘
系精油とロジンとの混合物を含有する芳香消臭脱臭剤、
あるいは、リモネンまたは柑橘系テルペンまたは柑橘系
精油とロジンとの混合物に界面活性剤を加え乳化したも
のを含有する芳香消臭脱臭剤を発明するに至った。ここ
で言うロジンとはガムロジン、ウッドロジン、)−/J
’ltlロジンの三種類のロジンのことを意味する。ま
た、ここで言うリモネンとはd−リモネン、l−リモネ
ン及びジペンテンを含む。リモネンを含む柑橘系精油と
しては、オレンジ油、夏ミカン油、レモン油、ライム油
、その他が挙げられる。また、これらの精油から、蒸留
その他の手段によシ得たテルペンを用いてもよい。これ
らは、単独でも、2種以上の混合物として使用してもよ
い。
As a result of intensive research to solve these problems, we have developed an aromatic deodorizing agent containing limonene, citrus terpene, or a mixture of citrus essential oil and rosin as a deodorizing ingredient.
Alternatively, the inventors have invented an aromatic deodorizing deodorizer containing a mixture of limonene, citrus terpene, or citrus essential oil, and rosin, which is emulsified by adding a surfactant. The rosin mentioned here is gum rosin, wood rosin, )-/J
'ltl rosin refers to three types of rosin. Moreover, the limonene mentioned here includes d-limonene, l-limonene, and dipentene. Examples of citrus essential oils containing limonene include orange oil, summer tangerine oil, lemon oil, lime oil, and others. Additionally, terpenes obtained from these essential oils by distillation or other means may be used. These may be used alone or as a mixture of two or more.

本発明においては、ロジン1部に対し、リモネンまたは
リモネンを含む柑橘系精油または柑橘系テルペンを等量
販上、好ましくは2〜20部配合して、そのまま使用し
てもよいし、あるいは使用上の便宜を図るため、例えば
メタノール、エタノ−μ等の溶剤と混合して用いてもよ
い。また、このものは、このまま用いるほか、任意の形
に製剤化してもよい。トイレ、生ゴミ等の家庭内の悪臭
、工場、塵芥処理場、下水処理場、家畜舎等の産・業界
での悪臭に対しては、そのまま噴霧して使用することが
できる。
In the present invention, limonene, a citrus essential oil containing limonene, or a citrus terpene may be added to 1 part of rosin in equal amounts, preferably 2 to 20 parts, and used as is, or may be used as is. For convenience, it may be used in combination with a solvent such as methanol or ethanol. Moreover, this product may be used as it is or may be formulated into any form. It can be used as is for spraying against bad odors in the home such as from toilets and garbage, and against bad odors in industries such as factories, garbage treatment plants, sewage treatment plants, livestock sheds, etc.

また、界面活性剤を用いることによシ水溶性液状消臭剤
としても使用することができる。即ち、ロジン1部に対
し、リモネンまたはリモネンを含む柑橘系精油または柑
橘系テルペンを少なくとも等量、好ましくは2〜20部
、界面活性剤を0,1〜20部、好ましくは0. 1〜
10部配合したものに水を1部以上、好ましくは5〜1
00部加え乳化することによって目的の消臭剤を得る。
Furthermore, by using a surfactant, it can also be used as a water-soluble liquid deodorant. That is, to 1 part of rosin, at least an equal amount of limonene or a citrus essential oil containing limonene or a citrus terpene, preferably 2 to 20 parts, and 0.1 to 20 parts of a surfactant, preferably 0. 1~
Add 1 part or more of water to 10 parts, preferably 5 to 1 part.
00 parts and emulsification to obtain the desired deodorant.

用いる界面活性剤については特に制限はない。この水溶
性液状消臭剤もこのまま使用してもよいし、任意の形に
製剤化してもよい。例えば、トイレ、生ゴミ等の家庭内
の悪臭、工場、塵芥処理場、下水処理場、家畜舎等の産
業界の悪臭に、そのまま散布するか、あるいは噴霧して
使用することができる。
There are no particular restrictions on the surfactant used. This water-soluble liquid deodorant may be used as is, or may be formulated into any form. For example, it can be applied directly or sprayed on bad odors in homes such as toilets and garbage, and in industrial areas such as factories, garbage treatment plants, sewage treatment plants, and livestock sheds.

また、この消臭剤を噴霧乾燥して、粉末品として使用す
ることもできる。
Moreover, this deodorant can also be spray-dried and used as a powder product.

以下、実施例を挙げ、詳細に説明する。Hereinafter, examples will be given and explained in detail.

実施例及び比較例 リモネン、柑橘系テルペン、柑橘系精油、ロジン、界面
活性剤、エタノール、グリセリン、イオン交換水を用い
て、表1に示す様な配合にて、消臭脱臭剤を調整した。
Examples and Comparative Examples Deodorizing and deodorizing agents were prepared using limonene, citrus terpenes, citrus essential oils, rosin, surfactants, ethanol, glycerin, and ion-exchanged water in the formulations shown in Table 1.

これらの消臭脱臭剤について、 以下実験例を挙げ、 その効果について証明2す る。Regarding these deodorants, Below are some experimental examples. Proof of its effectiveness 2 Ru.

第 表 実験例1 実施例1.2.3及び比較例1の消臭脱臭剤について、
トリメチルアミンに対する消臭効果をガスクロマトグラ
フィーを用いて調べた。
Table Experimental Example 1 Regarding the deodorizing and deodorizing agents of Example 1.2.3 and Comparative Example 1,
The deodorizing effect on trimethylamine was investigated using gas chromatography.

11000ppのトリメチルアミン1 mlに対し消臭
剤5 mlを50 wlのダブ/I/栓付きのバイアル
瓶に入れf130°Cで攪拌した。1分後、3分後、1
0分後のヘッドスペースのガス0.5 zlをガスクロ
マトグラフィーに注入し、得られたガスクロマトダラム
のピーク面積よシ悪臭成分の残存率を求めた。
5 ml of deodorant was added to 1 ml of 11,000 pp trimethylamine in a 50 wl vial with a Dove/I/stopper, and the mixture was stirred at 130°C. 1 minute later, 3 minutes later, 1
After 0 minutes, 0.5 zl of gas in the headspace was injected into the gas chromatograph, and the residual rate of malodorous components was determined from the peak area of the obtained gas chromatograph.

残存率は消臭剤を用いない場合を100として計算した
The residual rate was calculated with the case where no deodorant was used as 100.

ガスクロマトグラフィー条件 (o Iumm  :  (hromoaorb  l
 Q3(olumm  temp、  :  140℃
lnj、  を筐rp、  :  280°CCarr
ier  gas  :  HeFIOW  rate
  :  5Q ml /min第  2 表 上記結果から、本発明品は実施例1〜3のいずれも、ト
リメチルアミンに対してすぐれた消臭効果を持つことが
証明された。
Gas chromatography conditions (o Iumm: (hromoaorb l
Q3(olum temp, : 140℃
lnj, rp, : 280°CCarr
ier gas: HeFIOW rate
: 5Q ml/min Table 2 From the above results, it was proven that all of the products of the present invention in Examples 1 to 3 had an excellent deodorizing effect on trimethylamine.

実験例2 実施例1.2.3及び比較例2の消臭脱臭剤についてメ
チルメルカプタンに対する消臭効果を検知管を用いて調
べた。
Experimental Example 2 The deodorizing effects of the deodorants of Examples 1.2.3 and Comparative Example 2 on methyl mercaptan were investigated using a detection tube.

50xlのバイア /V瓶中に、1500ppmのメチ
ルメルカプタン0,5厘!及び消臭剤を2.0 ml加
え混合する。密栓後20分後にヘッドスペース中のメチ
ルメルカプタン濃度を検知管((株)ガヌテック製扁7
1)を用いて測定する。消臭効果は、消臭剤を用いない
時の数値を100として残存率(%)で表した。結果を
第3表に示す。
0.5 liters of 1500ppm methyl mercaptan in a 50xl Via/V bottle! Add and mix 2.0 ml of deodorant. 20 minutes after sealing, the concentration of methyl mercaptan in the headspace was measured using a detection tube (Ban 7 manufactured by Ganutec Co., Ltd.).
1). The deodorizing effect was expressed as a residual rate (%), with the value when no deodorant was used as 100. The results are shown in Table 3.

第  3  表 上記結果から、本発明品は実施例1〜3のいずれもメチ
ルメルカプタンに対するすぐれた消臭効果を持つことが
証明された。
From the above results in Table 3, it was proven that all of the products of the present invention in Examples 1 to 3 had an excellent deodorizing effect on methyl mercaptan.

実験例3 100g/容のビーカーに水20g/を入れ、ハイライ
ト(日本たばこ産業株制)1本の吸殻を入れ20分間攪
拌する。タバコはフィルターの付は根から20まで喫煙
する。実施例4または比較例3の消臭脱臭剤をタバコ吸
殻の入ったビーカーにスプレーしく1回のスプレー量、
約0.1 ? )その消臭効果を10名のパネラ−によ
って以下の5段階で官能評価した。なお評価5は消臭剤
を使用しない時の点数である。結果を第4表に示す。
Experimental Example 3 Put 20 g of water into a 100 g beaker, add one cigarette butt of Highlight (Japan Tobacco Inc.), and stir for 20 minutes. Smoking cigarettes with filters from the root to 20. The deodorizing agent of Example 4 or Comparative Example 3 was sprayed into a beaker containing cigarette butts in a single spray amount,
Approximately 0.1? ) The deodorizing effect was sensory evaluated by 10 panelists on the following 5 scales. Note that the rating of 5 is the score when no deodorant is used. The results are shown in Table 4.

評価 5:効果なし  4:やや効果あシ3:効果あシ
  2:かなシ効果あり 1:非常に効果あり 第  4  表 上記結果から本発明品は、タバコ吸殻具に対し高い消臭
効果を持つことが証明された。
Evaluation 5: No effect 4: Slightly effective 3: Effective 2: Slightly effective 1: Very effective Table 4 From the above results, the product of the present invention has a high deodorizing effect on cigarette butts. This has been proven.

〔発明の効果〕〔Effect of the invention〕

上記の実施例、実験例で明らかなように、本発明はリモ
ネンまたは柑橘系精油または柑橘系ンテルベンと、ロジ
ンとの混合物を消臭成分として含む効果の高い消臭脱臭
剤に係わるものであり、一般家庭及び産業界での悪臭防
止に広い範囲で、また、種々の使用形態で対応できるも
のである。
As is clear from the above Examples and Experimental Examples, the present invention relates to a highly effective deodorizing agent containing a mixture of limonene, citrus essential oil, or citrus terbenes, and rosin as a deodorizing component. It can be used in a wide range of ways to prevent bad odors in general households and in industry, and can be used in various ways.

Claims (1)

【特許請求の範囲】 1、リモネンとロジンとの混合物を消臭成分として含む
消臭脱臭剤。 2、リモネンとロジンを消臭成分として含む混合物に界
面活性剤を加え、乳化することを特徴とする消臭脱臭剤
。 3、柑橘系テルペンとロジンとの混合物を消臭成分とし
て含む消臭脱臭剤。 4、柑橘系テルペンとロジンを消臭成分として含む混合
物に界面活性剤を加え、乳化することを特徴とする消臭
脱臭剤。 5、柑橘系テルペンがオレンジテルペン、夏ミカンテル
ペン、レモンテルペン、ライムテルペンであるところの
、特許請求の範囲第3項及び第4項記載の消臭脱臭剤。 6、柑橘系精油とロジンとの混合物を消臭成分として含
む消臭脱臭剤。 7、柑橘系精油とロジンを消臭成分として含む混合物に
界面活性剤を加え、乳化することを特徴とする消臭脱臭
剤。 8、柑橘系精油がオレンジ油、夏ミカン油、レモン油、
ライム油であるところの、特許請求の範囲第6項及び第
7記載の消臭脱臭剤。
[Claims] 1. A deodorizing agent containing a mixture of limonene and rosin as a deodorizing component. 2. A deodorizing agent characterized by adding a surfactant to a mixture containing limonene and rosin as deodorizing ingredients and emulsifying the mixture. 3. A deodorizing agent containing a mixture of citrus terpenes and rosin as a deodorizing ingredient. 4. A deodorizing agent characterized by adding a surfactant to a mixture containing citrus terpenes and rosin as deodorizing ingredients and emulsifying the mixture. 5. The deodorizing agent according to claims 3 and 4, wherein the citrus terpene is orange terpene, summer tangerine terpene, lemon terpene, or lime terpene. 6. A deodorizing agent containing a mixture of citrus essential oil and rosin as a deodorizing ingredient. 7. A deodorizing agent characterized by adding a surfactant to a mixture containing citrus essential oil and rosin as deodorizing ingredients and emulsifying the mixture. 8. Citrus essential oils include orange oil, summer tangerine oil, lemon oil,
The deodorizing and deodorizing agent according to claims 6 and 7, which is lime oil.
JP2195487A 1990-07-23 1990-07-23 Deodorant Pending JPH0479961A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2195487A JPH0479961A (en) 1990-07-23 1990-07-23 Deodorant

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2195487A JPH0479961A (en) 1990-07-23 1990-07-23 Deodorant

Publications (1)

Publication Number Publication Date
JPH0479961A true JPH0479961A (en) 1992-03-13

Family

ID=16341907

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2195487A Pending JPH0479961A (en) 1990-07-23 1990-07-23 Deodorant

Country Status (1)

Country Link
JP (1) JPH0479961A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH067121A (en) * 1992-05-18 1994-01-18 Murakami Shokuhin Kk Method for masking odor due to heat-steamed fish-paste cake packed in casing
US5549839A (en) * 1995-04-21 1996-08-27 Chandler; William C. Industrial solvent based on a processed citrus oil for cleaning up petroleum waste products
KR100564127B1 (en) * 1996-05-31 2006-06-28 미쓰비시 가가쿠 후즈 가부시키가이샤 Controlled Release Compositions Containing Volatile Compounds
JP2017006653A (en) * 2015-06-17 2017-01-12 花王株式会社 Odor depressant for polysulfide compound

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH067121A (en) * 1992-05-18 1994-01-18 Murakami Shokuhin Kk Method for masking odor due to heat-steamed fish-paste cake packed in casing
US5549839A (en) * 1995-04-21 1996-08-27 Chandler; William C. Industrial solvent based on a processed citrus oil for cleaning up petroleum waste products
KR100564127B1 (en) * 1996-05-31 2006-06-28 미쓰비시 가가쿠 후즈 가부시키가이샤 Controlled Release Compositions Containing Volatile Compounds
JP2017006653A (en) * 2015-06-17 2017-01-12 花王株式会社 Odor depressant for polysulfide compound
US10619027B2 (en) 2015-06-17 2020-04-14 Kao Corporation Agent for suppressing odors of polysulfide compounds

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