JPH027666B2 - - Google Patents
Info
- Publication number
- JPH027666B2 JPH027666B2 JP58196938A JP19693883A JPH027666B2 JP H027666 B2 JPH027666 B2 JP H027666B2 JP 58196938 A JP58196938 A JP 58196938A JP 19693883 A JP19693883 A JP 19693883A JP H027666 B2 JPH027666 B2 JP H027666B2
- Authority
- JP
- Japan
- Prior art keywords
- terpene
- deodorizing
- odor
- cyclic hydrocarbon
- deodorizing effect
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000007788 liquid Substances 0.000 claims description 30
- 239000002781 deodorant agent Substances 0.000 claims description 28
- HULBECQFWZPEBI-ONNFQVAWSA-N octyl (e)-but-2-enoate Chemical compound CCCCCCCCOC(=O)\C=C\C HULBECQFWZPEBI-ONNFQVAWSA-N 0.000 claims description 25
- 235000007586 terpenes Nutrition 0.000 claims description 25
- 150000003505 terpenes Chemical class 0.000 claims description 17
- -1 glycol monoalkyl ether Chemical class 0.000 claims description 16
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 15
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 7
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 7
- 239000002904 solvent Substances 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 239000000341 volatile oil Substances 0.000 claims description 5
- 239000004480 active ingredient Substances 0.000 claims description 4
- 235000001510 limonene Nutrition 0.000 claims description 4
- 150000002628 limonene derivativess Chemical class 0.000 claims description 2
- 230000001877 deodorizing effect Effects 0.000 description 49
- 235000019645 odor Nutrition 0.000 description 32
- 230000000873 masking effect Effects 0.000 description 16
- 239000000203 mixture Substances 0.000 description 14
- 239000000126 substance Substances 0.000 description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 239000003205 fragrance Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- UAHWPYUMFXYFJY-UHFFFAOYSA-N beta-myrcene Chemical compound CC(C)=CCCC(=C)C=C UAHWPYUMFXYFJY-UHFFFAOYSA-N 0.000 description 4
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethanethiol Chemical compound CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 4
- FAMPSKZZVDUYOS-UHFFFAOYSA-N 2,6,6,9-tetramethylcycloundeca-1,4,8-triene Chemical compound CC1=CCC(C)(C)C=CCC(C)=CCC1 FAMPSKZZVDUYOS-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 244000144972 livestock Species 0.000 description 3
- 244000144977 poultry Species 0.000 description 3
- GRWFGVWFFZKLTI-IUCAKERBSA-N (-)-α-pinene Chemical compound CC1=CC[C@@H]2C(C)(C)[C@H]1C2 GRWFGVWFFZKLTI-IUCAKERBSA-N 0.000 description 2
- JSNRRGGBADWTMC-UHFFFAOYSA-N (6E)-7,11-dimethyl-3-methylene-1,6,10-dodecatriene Chemical compound CC(C)=CCCC(C)=CCCC(=C)C=C JSNRRGGBADWTMC-UHFFFAOYSA-N 0.000 description 2
- PWTNRNHDJZLBCD-UHFFFAOYSA-N 2-(2-pentoxyethoxy)ethanol Chemical compound CCCCCOCCOCCO PWTNRNHDJZLBCD-UHFFFAOYSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- MOYAFQVGZZPNRA-UHFFFAOYSA-N Terpinolene Chemical compound CC(C)=C1CCC(C)=CC1 MOYAFQVGZZPNRA-UHFFFAOYSA-N 0.000 description 2
- XCPQUQHBVVXMRQ-UHFFFAOYSA-N alpha-Fenchene Natural products C1CC2C(=C)CC1C2(C)C XCPQUQHBVVXMRQ-UHFFFAOYSA-N 0.000 description 2
- VYBREYKSZAROCT-UHFFFAOYSA-N alpha-myrcene Natural products CC(=C)CCCC(=C)C=C VYBREYKSZAROCT-UHFFFAOYSA-N 0.000 description 2
- MTHSVFCYNBDYFN-UHFFFAOYSA-N anhydrous diethylene glycol Natural products OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- CRPUJAZIXJMDBK-UHFFFAOYSA-N camphene Chemical compound C1CC2C(=C)C(C)(C)C1C2 CRPUJAZIXJMDBK-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 239000010800 human waste Substances 0.000 description 2
- 229940087305 limonene Drugs 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- 230000009965 odorless effect Effects 0.000 description 2
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- NDVASEGYNIMXJL-UHFFFAOYSA-N sabinene Chemical compound C=C1CCC2(C(C)C)C1C2 NDVASEGYNIMXJL-UHFFFAOYSA-N 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 239000011550 stock solution Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 2
- YHQGMYUVUMAZJR-UHFFFAOYSA-N α-terpinene Chemical compound CC(C)C1=CC=C(C)CC1 YHQGMYUVUMAZJR-UHFFFAOYSA-N 0.000 description 2
- NPNUFJAVOOONJE-ZIAGYGMSSA-N β-(E)-Caryophyllene Chemical compound C1CC(C)=CCCC(=C)[C@H]2CC(C)(C)[C@@H]21 NPNUFJAVOOONJE-ZIAGYGMSSA-N 0.000 description 2
- OPFTUNCRGUEPRZ-UHFFFAOYSA-N (+)-beta-Elemen Natural products CC(=C)C1CCC(C)(C=C)C(C(C)=C)C1 OPFTUNCRGUEPRZ-UHFFFAOYSA-N 0.000 description 1
- NDVASEGYNIMXJL-NXEZZACHSA-N (+)-sabinene Natural products C=C1CC[C@@]2(C(C)C)[C@@H]1C2 NDVASEGYNIMXJL-NXEZZACHSA-N 0.000 description 1
- WTARULDDTDQWMU-RKDXNWHRSA-N (+)-β-pinene Chemical compound C1[C@H]2C(C)(C)[C@@H]1CCC2=C WTARULDDTDQWMU-RKDXNWHRSA-N 0.000 description 1
- WTARULDDTDQWMU-IUCAKERBSA-N (-)-Nopinene Natural products C1[C@@H]2C(C)(C)[C@H]1CCC2=C WTARULDDTDQWMU-IUCAKERBSA-N 0.000 description 1
- OPFTUNCRGUEPRZ-QLFBSQMISA-N (-)-beta-elemene Chemical compound CC(=C)[C@@H]1CC[C@@](C)(C=C)[C@H](C(C)=C)C1 OPFTUNCRGUEPRZ-QLFBSQMISA-N 0.000 description 1
- CXENHBSYCFFKJS-UHFFFAOYSA-N (3E,6E)-3,7,11-Trimethyl-1,3,6,10-dodecatetraene Natural products CC(C)=CCCC(C)=CCC=C(C)C=C CXENHBSYCFFKJS-UHFFFAOYSA-N 0.000 description 1
- GZMAAYIALGURDQ-UHFFFAOYSA-N 2-(2-hexoxyethoxy)ethanol Chemical compound CCCCCCOCCOCCO GZMAAYIALGURDQ-UHFFFAOYSA-N 0.000 description 1
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 1
- DJCYDDALXPHSHR-UHFFFAOYSA-N 2-(2-propoxyethoxy)ethanol Chemical compound CCCOCCOCCO DJCYDDALXPHSHR-UHFFFAOYSA-N 0.000 description 1
- NVEQFIOZRFFVFW-UHFFFAOYSA-N 9-epi-beta-caryophyllene oxide Natural products C=C1CCC2OC2(C)CCC2C(C)(C)CC21 NVEQFIOZRFFVFW-UHFFFAOYSA-N 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 235000019501 Lemon oil Nutrition 0.000 description 1
- WSTYNZDAOAEEKG-UHFFFAOYSA-N Mayol Natural products CC1=C(O)C(=O)C=C2C(CCC3(C4CC(C(CC4(CCC33C)C)=O)C)C)(C)C3=CC=C21 WSTYNZDAOAEEKG-UHFFFAOYSA-N 0.000 description 1
- PXRCIOIWVGAZEP-UHFFFAOYSA-N Primaeres Camphenhydrat Natural products C1CC2C(O)(C)C(C)(C)C1C2 PXRCIOIWVGAZEP-UHFFFAOYSA-N 0.000 description 1
- WTARULDDTDQWMU-UHFFFAOYSA-N Pseudopinene Natural products C1C2C(C)(C)C1CCC2=C WTARULDDTDQWMU-UHFFFAOYSA-N 0.000 description 1
- MVNCAPSFBDBCGF-UHFFFAOYSA-N alpha-pinene Natural products CC1=CCC23C1CC2C3(C)C MVNCAPSFBDBCGF-UHFFFAOYSA-N 0.000 description 1
- KQAZVFVOEIRWHN-UHFFFAOYSA-N alpha-thujene Natural products CC1=CCC2(C(C)C)C1C2 KQAZVFVOEIRWHN-UHFFFAOYSA-N 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 229960001950 benzethonium chloride Drugs 0.000 description 1
- UREZNYTWGJKWBI-UHFFFAOYSA-M benzethonium chloride Chemical compound [Cl-].C1=CC(C(C)(C)CC(C)(C)C)=CC=C1OCCOCC[N+](C)(C)CC1=CC=CC=C1 UREZNYTWGJKWBI-UHFFFAOYSA-M 0.000 description 1
- NPNUFJAVOOONJE-UHFFFAOYSA-N beta-cariophyllene Natural products C1CC(C)=CCCC(=C)C2CC(C)(C)C21 NPNUFJAVOOONJE-UHFFFAOYSA-N 0.000 description 1
- 229930006722 beta-pinene Natural products 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 229930006739 camphene Natural products 0.000 description 1
- ZYPYEBYNXWUCEA-UHFFFAOYSA-N camphenilone Natural products C1CC2C(=O)C(C)(C)C1C2 ZYPYEBYNXWUCEA-UHFFFAOYSA-N 0.000 description 1
- 229930006737 car-3-ene Natural products 0.000 description 1
- 229930007796 carene Natural products 0.000 description 1
- BQOFWKZOCNGFEC-UHFFFAOYSA-N carene Chemical compound C1C(C)=CCC2C(C)(C)C12 BQOFWKZOCNGFEC-UHFFFAOYSA-N 0.000 description 1
- 229940117948 caryophyllene Drugs 0.000 description 1
- NPNUFJAVOOONJE-UONOGXRCSA-N caryophyllene Natural products C1CC(C)=CCCC(=C)[C@@H]2CC(C)(C)[C@@H]21 NPNUFJAVOOONJE-UONOGXRCSA-N 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 description 1
- 229940075557 diethylene glycol monoethyl ether Drugs 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 229930009668 farnesene Natural products 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000013355 food flavoring agent Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- LCWMKIHBLJLORW-UHFFFAOYSA-N gamma-carene Natural products C1CC(=C)CC2C(C)(C)C21 LCWMKIHBLJLORW-UHFFFAOYSA-N 0.000 description 1
- BXWQUXUDAGDUOS-UHFFFAOYSA-N gamma-humulene Natural products CC1=CCCC(C)(C)C=CC(=C)CCC1 BXWQUXUDAGDUOS-UHFFFAOYSA-N 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- QBNFBHXQESNSNP-UHFFFAOYSA-N humulene Natural products CC1=CC=CC(C)(C)CC=C(/C)CCC1 QBNFBHXQESNSNP-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 210000001621 ilium bone Anatomy 0.000 description 1
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 description 1
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000010501 lemon oil Substances 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000010813 municipal solid waste Substances 0.000 description 1
- 150000007823 ocimene derivatives Chemical class 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- CFJYNSNXFXLKNS-UHFFFAOYSA-N p-menthane Chemical compound CC(C)C1CCC(C)CC1 CFJYNSNXFXLKNS-UHFFFAOYSA-N 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000003348 petrochemical agent Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- GRWFGVWFFZKLTI-UHFFFAOYSA-N rac-alpha-Pinene Natural products CC1=CCC2C(C)(C)C1C2 GRWFGVWFFZKLTI-UHFFFAOYSA-N 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 229930006696 sabinene Natural products 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- XJPBRODHZKDRCB-UHFFFAOYSA-N trans-alpha-ocimene Natural products CC(=C)CCC=C(C)C=C XJPBRODHZKDRCB-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Description
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The present invention provides an excellent deodorizing effect with a reduced amount of use, even though the deodorant itself does not have an unpleasant odor and does not have a strong gradient due to the masking effect unlike so-called masking deodorants. It exhibits an odor effect and exhibits excellent deodorizing effect sustainability, and also,
It can exhibit an improved deodorizing effect on a wide range of complex odor targets such as sulfur-containing, nitrogen-containing, and oxygen-containing odor targets, and also does not have a strong gradient like masking deodorants. It has excellent applicability and can be applied advantageously to a wide range of locations and targets with bad odors.
Therefore, if desired, any aromatic ingredients may also be included.
The present invention relates to a deodorizing liquid agent which also has the advantage that it can be further contained without causing any unfavorable change in its fragrance. More specifically, (a) octyl crotonate and (b) a terpene-based cyclic hydrocarbon compound of the present invention are combined into (a): (b)
=1: It relates to a deodorizing liquid containing octyl crotonate as an active ingredient in an amount ratio of about 2 to about 20 (weight ratio). Conventionally, there have been chemical deodorants (reactive deodorants) that exert a deodorizing effect by chemically reacting with malodorous components, or chemical deodorants that do not exhibit a chemical deodorizing effect by themselves but have a strong odor effect. Masking deodorants that exhibit deodorizing effects through masking effects are known, and various proposals have been made. However, as a chemical deodorant, even if the deodorizing component is theoretically capable of reacting with malodorous components, in reality, the desired reaction does not take place sufficiently, resulting in a practically satisfactory deodorizing effect. It is common that chemical deodorants cannot be obtained or that there are restrictions on the target odor that shows their reactivity, and furthermore, there are disadvantages such as the fact that chemical deodorants themselves have bad or unpleasant odors.On the other hand, masking deodorants has a strong gradient derived from its masking effect, and when used in an amount that can exert a sufficient masking deodorizing effect, there are significant restrictions on where it can be applied, and it must be used in an amount that avoids this. However, there is usually a problem in which a satisfactory masking effect cannot be achieved. Although it is possible to use these two types of deodorizing ingredients in combination, it is difficult to avoid defects in either or both of them.
The reality is that satisfactory results cannot be obtained. The present inventors have conducted research to develop a deodorizing liquid that can solve the above-mentioned technical problems. As a result, the combination of the known compound octyl crotonate, which has a rather strong burnt-like odor that is unpleasant by itself, and a terpene-based hydrocarbon compound, particularly preferably a terpene-based cyclic hydrocarbon compound, can reduce the unpleasantness of octyl crotonate. It is odorless, and the combination agent itself does not exhibit unpleasant odors or the strong gradient characteristic of so-called masking deodorants, and despite this, it has an excellent deodorizing effect on a wide range of offensive odors. We have discovered that it is a unique deodorant liquid that exhibits excellent deodorizing effect and long-lasting deodorizing effect. Furthermore, the above-mentioned unique deodorizing effect achieved by the combination of the octyl crotonate and a terpene-based hydrocarbon compound, particularly preferably a terpene-based cyclic hydrocarbon compound, changes depending on the proportion of their combination. : It has been discovered that the weight ratio of terpene hydrocarbon compounds, particularly terpene cyclic hydrocarbon compounds, is preferably in the range of 1:2 to about 20. Therefore, according to the research of the present inventors, (a) octyl crotonate and (b) a terpene-based cyclic hydrocarbon compound are mixed at a ratio of (a):(b)=1:about 2 to about 20 (weight ratio ), the deodorant liquid containing octyl crotonate as an active ingredient not only has an unpleasant odor but also has the strong masking characteristic of masking deodorants. Although it has no odor, it exhibits an excellent deodorizing effect with a reduced amount of use, and has excellent deodorizing effect sustainability. It has an improved deodorizing effect on targets with bad odors, and it does not have a strong masking odor like masking deodorants, so it can be applied in a wide range of places and can be applied advantageously to targets with bad odors. It is possible to provide a deodorizing liquid agent that has the following properties and also has the advantage of being able to further contain any aromatic component, if desired, without causing any unfavorable change in the aroma. I understood. Although it is still not clear what kind of deodorizing action mechanism causes the above-mentioned unexpected deodorizing effect of the combination of ingredients (a) and (b), the results of many comparative tests were later shown in examples. As shown in both figures, it has been found that it is difficult to obtain the unique deodorant effect of the present invention when each of these components is used alone or in amounts different from the above-mentioned proportions. Accordingly, it is an object of the present invention to provide improved deodorants containing octyl crotonate. The above objects and many other objects and advantages of the present invention will become more apparent from the following description. The deodorizing liquid of the present invention contains (a) as an essential active ingredient;
Contains a combination of octyl crotonate and (b) terpene hydrocarbons, particularly terpene cyclic hydrocarbon compounds, and contains these two essential components (a): (b)
=1: Contained in an amount ratio of about 2 to about 20 (weight ratio). By satisfying the combination conditions of (a) and (b) above and their quantity ratio conditions,
The rather strong unpleasant burnt-like odor of octyl crotonate itself was markedly reduced, and the gradient of the (ro)terpene-based cyclic hydrocarbon compound was also reduced. Although there are differences depending on the type and amount of compounds, as a deodorant liquid itself consisting of a combination of (a) and (b),
It has a faint and mild fragrance, but it does not have any unpleasant odor or the strong gradient characteristic of masking deodorants, but it exhibits an excellent deodorizing effect with a reduced amount of usage. Furthermore, the deodorizing effect exhibits excellent durability. In the deodorizing liquid agent of the present invention, in addition to the combination of (a) and (b) above, the ratio of the amounts of (a) to (b) above is also important. If the proportion of the hydrocarbon compound is too small, not only will the deodorizing liquid have an unpleasant odor derived from (a) octyl crotonate, but there will also be a tendency for the deodorizing effect to be substantially reduced; Furthermore, if the proportion of the terpene-based cyclic hydrocarbon compound is too large outside the above-mentioned proportion range, the deodorizing effect will deteriorate. Therefore, in the present invention, the amounts and ratios of the above (a) and (b) are appropriately selected. Examples of the above (b) terpene-based cyclic hydrocarbon compounds include α-pinene, β-pinene, limonene, p-
Preferred examples include menthane, α-terpinene, terpinolene, sabinene, carene, camphene, pizzaborene, humulene, elemene, and caryophyllene. These can be used alone or in combination. Further, these terpene-based cyclic hydrocarbon compounds may be isolated from natural essential oils or synthesized, and furthermore, they can be used in the form of natural essential oils containing a high content. Among the above-mentioned terpene-based cyclic hydrocarbon compounds, it is more preferable to use at least one compound selected from the group consisting of pinenes, limonenes, and essential oils containing them. Further, in the present invention, an acyclic terpene hydrocarbon compound can be used in combination with the above-mentioned (b) terpene hydrocarbon compound. Preferred examples of such other hydrocarbon compounds include myrcene, dihydromircene, farnesene, and ocimene. These are not limited to one type, but multiple types can be used. The amount of these used can be selected as appropriate, but an example of the amount used is about 5 to about 20% by weight based on the (ro)terpene cyclic hydrocarbon compound. The octyl crotonate-containing deodorant liquid of the present invention is
It may further contain a suitable solvent. Examples of such solvents include dialkylene glycol monoalkyl ether, alkylene glycol monoalkyl ether, dialkylene glycol, and alkylene glycol. These can be used alone or in combination. Among the above-mentioned exemplified solvents, use of dialkylene glycol monoalkyl ether is more preferable.
Specific examples of such solvent dialkylene glycol monoalkyl ethers include diethylene glycol monoalkyl ethers such as diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monopropyl ether, diethylene glycol monobutyl ether, diethylene glycol pentyl ether, diethylene glycol monohexyl ether, etc. can be preferably exemplified. These can be used alone or in combination. Among the above examples, diethylene glycol monobutyl ether and diethylene glycol monopentyl ether are more preferably used. In the present invention, when using the above-mentioned solvent, the amount to be used can be selected as appropriate, but for example, the amount (by weight) is about 1 to about 5 times the total amount (by weight) of (a) and (b). For example, the usage amount may be as follows. The octyl crotonate-containing deodorant liquid of the present invention is
Other additives may also be included, such as sterilizing and/or preservatives, perfumes and other flavoring agents. Examples of such additives include alkylene glycols such as triethylene glycol, propylene glycol, hexylene glycol, etc.; bersalkonium chloride;
Benzethonium chloride, other antibacterial soaps; and various other fragrances;
These fragrances are suitable for cases in which a desired fragrance can be enjoyed at the same time as an indoor deodorizing effect, if desired. In this case, since the deodorant liquid of the present invention does not itself have a strong gradient like a masking deodorant, it has the advantage of being able to contain any aromatic component without causing any undesirable changes in its aroma. be. The octyl crotonate-containing deodorant liquid of the present invention is
(a) Octyl crotonate and (b) terpene-based cyclic hydrocarbon compound, (a): (b) = 1: about 2 to about 20 (weight ratio)
If desired, it can be prepared by mixing with other components and/or other additives as described above. The deodorizing liquid of the present invention may be prepared at any concentration, and the stock solution composition may be prepared as a concentrated solution.
It can be diluted appropriately before use,
Alternatively, a stock solution composition can be prepared from the beginning with a concentration suitable for each source to be deodorized. Therefore, the total amount of (a) octyl crotonate and (b) terpene-based cyclic hydrocarbon compound in the composition can be varied. 1:9
A range of ~1:0.1 is most often used,
The ratio is preferably about 1:3 to about 1:0.2. Of course, it can be changed as appropriate depending on the type of malodor of the object to be treated, the concentration at the time of application, etc., and it is also possible to form a concentrated liquid that exceeds the above range. Normally, the source of malodor is rarely a single odor, and the actual source of malodor is usually a complex and diverse system of complex malodor-producing compounds, such as adsorption of a single malodorous compound or chemical It is well known that it is not possible to argue based only on target capture. Even for a single malodor that is thought to have been effectively captured through chemical analysis, panel tests often yield unsatisfactory results. Measuring the amount of adsorption or chemical capture alone
Predicting its deodorizing effect is impossible even for the most outstanding experts in the same technical field. The deodorizing liquid of the present invention exhibits excellent deodorizing effects against a wide range of complex malodor targets, and as shown later in Examples and Comparative Examples, the present invention has been shown to be effective against a single malodor source. On the other hand, the use of octyl crotonate and terpene-based cyclic hydrocarbon compounds alone showed a deodorizing effect that was not expected, and furthermore, it showed a significantly superior deodorizing effect against the combined odor of these odor sources. It can be seen that this shows that Specific examples of malodor sources suitable for use with the deodorizing liquid of the present invention include processing factories for fish iliac bones, cow bones, fluff, etc., fertilizer and feed factories, food processing factories, leather factories, various livestock and poultry factories, etc. Feed farms and human waste treatment plants, human waste, sewage, and garbage treatment plants for cities, homes, factories, etc.
Sources of malodors include sulfur-containing compounds, nitrogen-containing compounds, and/or oxygen-containing compounds in factories for plastics, rubber, pulp, oils and fats, petrochemicals, and the like. It can also be used to deodorize rooms such as homes and cars, livestock and poultry, and livestock and poultry houses. The deodorizing liquid composition of the present invention may be directly removed or added to the source of the bad odor, or the vapor phase bad odor may be deodorized by passing through the liquid composition, or alternatively, it may be deodorized by passing it through the liquid composition. A packed bed impregnated with a carrier can be used in various forms such as granules, gels, pellets, and powders, depending on the purpose of passing gaseous odor or other purposes. The present invention will be explained in more detail with reference to comparative examples and examples below. Examples 1 to 4 The malodor source solutions used in Examples and Comparative Examples are shown below. (A) 0.06% ammonia aqueous solution (B) Hydrogen sulfide saturated aqueous solution: water = 1:170 (C) 0.001% trimethylamine aqueous solution (D) 0.01% pyridine aqueous solution (E) 0.003% ethyl mercaptan aqueous solution The following evaluation method was used. 20 g of each malodor source solution was placed in a 100 c.c. glass pin, 0.4 cc (2%) of the deodorizing liquid composition was added, and the deodorizing effect after 3 hours was evaluated by a panel. The members of the panel are as follows.
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ã€ããŠäžèšãšåæ§ã«è¡ãè¡šâïŒã®çµæãåŸãã[Table] The evaluation is based on the following grades, and the arithmetic mean of the total of all panelists for the grade according to the above evaluation divided by the number of panelists (the second decimal place is rounded to 50
) to determine the average grade. Grade 5 Strong odor. 4 Strong odor. 3 Bad odor that is easily felt. 2. Weak odor. 1 Very faint odor. 0 Virtually odorless. Therefore, regarding the malodor source, Example 1 is octyl crotonate + myrcene (1:2), and Example 2 is octyl crotonate + lyonene (1:2).
15), as Example 3, octyl crotonate + α-
Diethylene glycol monobutyl ether was added to each of pinene (1:20) and octyl crotonate + lemon oil (1:10) as Example 4.The total amount of octyl crotonate and the above terpene-based cyclic hydrocarbon compounds (including natural essential oils) A deodorizing liquid composition (10% ethanol solution) was prepared by adding twice the weight of the deodorizing liquid composition (10% ethanol solution), and after adding it to the above malodor source, a sensory evaluation was conducted by a panel, and the results shown in Table 1 were obtained. In addition, as comparative examples, the same procedure as above was carried out for the cases where the amount of octyl crotonate was increased, and the amount of limonene was increased, and the results shown in Table 1 were obtained.
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ãã[Table] From the results in Table 1 above, it can be seen that the combined use of octyl crotonate and terpene hydrocarbon compound in the composition of the present invention exhibits an outstanding synergistic deodorizing effect that is not expected from their sole use. . Example 5 Two types of deodorant liquid compositions of the present invention were prepared according to the following formulations.
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100éš[Table] The above deodorizing liquid composition was used as the odor source (A), (B), (C), (D).
A panel test was conducted on the deodorizing effect after 3 hours of adding and mixing 2% to (E) and (E). Table the results.
Shown in 2. Example 6 In order to test the deodorizing effect on composite malodor sources, a 2% aqueous solution of the composite malodor source with the following composition was prepared, 2% of the deodorizing liquid α of Example 5 was added, and after the deodorizing operation, We conducted an odor panel test. The results are shown in Table-2. Complex malodor source Sibet 40 parts (wt) Skirt 1% (DPG) 2 Indole 10% (DPG) 2 N-Valeric acid 1% (H 2 O) 1 Ammonia water (28%) 7 Ethyl mercaptan 1% (ethanol)
0.5 Surfactant 47.5 100 parts
Claims (1)
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ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æ¶è液å€ã ïŒ è©²æ¶è液å€ãã溶åªãžã¢ã«ãã¬ã³ã°ãªã³ãŒã«
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ã®ç¯å²ç¬¬ïŒé èšèŒã®æ¶è液å€ã[Claims] 1 (a) octyl crotonate and (b) a terpene-based cyclic hydrocarbon compound in an amount ratio of (a):(b)=1:about 2 to about 20 (weight ratio), A deodorant liquid containing octyl crotonate as an active ingredient. 2. The deodorizer according to claim 1, wherein the (b) terpene-based cyclic hydrocarbon compound is at least one compound selected from the group consisting of pinenes, limonenes, and essential oils containing them. Liquid agent. 3. The deodorant liquid according to claim 1, further comprising a solvent dialkylene glycol monoalkyl ether.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP58196938A JPS6088558A (en) | 1983-10-22 | 1983-10-22 | Octyl clotonate-containing liquid deodorant |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP58196938A JPS6088558A (en) | 1983-10-22 | 1983-10-22 | Octyl clotonate-containing liquid deodorant |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS6088558A JPS6088558A (en) | 1985-05-18 |
JPH027666B2 true JPH027666B2 (en) | 1990-02-20 |
Family
ID=16366147
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP58196938A Granted JPS6088558A (en) | 1983-10-22 | 1983-10-22 | Octyl clotonate-containing liquid deodorant |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6088558A (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2615697B2 (en) * | 1987-11-13 | 1997-06-04 | æ¥ç£ååŠå·¥æ¥æ ªåŒäŒç€Ÿ | Sanitary composition |
US4983578A (en) * | 1989-04-18 | 1991-01-08 | The Drackett Company | Air freshener composition and device |
JP4520682B2 (en) * | 1999-12-13 | 2010-08-11 | ã·ã ã©ã€ãºã»ã²ãŒã«ã·ã€ããã»ãããã»ãã·ãŠã¬ã³ã¯ãã«ã»ãããã³ã°ã»ãŠã³ãã»ã³ã³ãããŒã»ã³ãã³ãžããã»ã²ãŒã«ã·ã€ãã | Odor neutralizer |
JP2005350354A (en) * | 2003-09-09 | 2005-12-22 | Kao Corp | Composition for deodorizing hircismus, and skin cosmetic and deodorant for fiber containing the same |
-
1983
- 1983-10-22 JP JP58196938A patent/JPS6088558A/en active Granted
Also Published As
Publication number | Publication date |
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JPS6088558A (en) | 1985-05-18 |
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