JPH0469086B2 - - Google Patents
Info
- Publication number
- JPH0469086B2 JPH0469086B2 JP58139306A JP13930683A JPH0469086B2 JP H0469086 B2 JPH0469086 B2 JP H0469086B2 JP 58139306 A JP58139306 A JP 58139306A JP 13930683 A JP13930683 A JP 13930683A JP H0469086 B2 JPH0469086 B2 JP H0469086B2
- Authority
- JP
- Japan
- Prior art keywords
- reaction
- hydrocarbyl
- chloride
- hydrazine
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 91
- 238000000034 method Methods 0.000 claims description 66
- -1 alkali metal amide Chemical class 0.000 claims description 57
- QDHHCQZDFGDHMP-UHFFFAOYSA-N Chloramine Chemical compound ClN QDHHCQZDFGDHMP-UHFFFAOYSA-N 0.000 claims description 50
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 30
- 230000008569 process Effects 0.000 claims description 26
- 239000000047 product Substances 0.000 claims description 26
- 229910052783 alkali metal Inorganic materials 0.000 claims description 25
- 229910052784 alkaline earth metal Chemical group 0.000 claims description 20
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 16
- 239000012320 chlorinating reagent Substances 0.000 claims description 16
- 239000000460 chlorine Substances 0.000 claims description 16
- 150000002429 hydrazines Chemical class 0.000 claims description 15
- 229910021529 ammonia Inorganic materials 0.000 claims description 14
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 12
- 229910052801 chlorine Inorganic materials 0.000 claims description 12
- BIVUUOPIAYRCAP-UHFFFAOYSA-N aminoazanium;chloride Chemical group Cl.NN BIVUUOPIAYRCAP-UHFFFAOYSA-N 0.000 claims description 11
- 150000001875 compounds Chemical class 0.000 claims description 11
- NHYCGSASNAIGLD-UHFFFAOYSA-N Chlorine monoxide Chemical compound Cl[O] NHYCGSASNAIGLD-UHFFFAOYSA-N 0.000 claims description 10
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 10
- 239000011780 sodium chloride Substances 0.000 claims description 8
- 239000001257 hydrogen Substances 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 claims description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- 150000001340 alkali metals Chemical group 0.000 claims description 5
- 150000001342 alkaline earth metals Chemical group 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 5
- 229910052708 sodium Inorganic materials 0.000 claims description 5
- 239000012467 final product Substances 0.000 claims description 2
- UUEVFMOUBSLVJW-UHFFFAOYSA-N oxo-[[1-[2-[2-[2-[4-(oxoazaniumylmethylidene)pyridin-1-yl]ethoxy]ethoxy]ethyl]pyridin-4-ylidene]methyl]azanium;dibromide Chemical compound [Br-].[Br-].C1=CC(=C[NH+]=O)C=CN1CCOCCOCCN1C=CC(=C[NH+]=O)C=C1 UUEVFMOUBSLVJW-UHFFFAOYSA-N 0.000 claims description 2
- 238000005868 electrolysis reaction Methods 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 description 70
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 26
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 20
- 238000004519 manufacturing process Methods 0.000 description 17
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 15
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 14
- 239000011541 reaction mixture Substances 0.000 description 13
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 239000006227 byproduct Substances 0.000 description 12
- 238000004821 distillation Methods 0.000 description 12
- 239000007789 gas Substances 0.000 description 12
- 239000000203 mixture Substances 0.000 description 11
- 239000000243 solution Substances 0.000 description 11
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 10
- QXJIABOUHLYVHP-UHFFFAOYSA-N n-chloromethanamine Chemical compound CNCl QXJIABOUHLYVHP-UHFFFAOYSA-N 0.000 description 10
- 239000003350 kerosene Substances 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 8
- ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 description 7
- 239000005708 Sodium hypochlorite Substances 0.000 description 7
- ZWQQOWRPOOUUBX-UHFFFAOYSA-M amino(tripropyl)azanium;chloride Chemical compound [Cl-].CCC[N+](N)(CCC)CCC ZWQQOWRPOOUUBX-UHFFFAOYSA-M 0.000 description 7
- 238000002474 experimental method Methods 0.000 description 7
- MAGVJLLHDZWQFM-UHFFFAOYSA-N n-chloro-n-methylmethanamine Chemical class CN(C)Cl MAGVJLLHDZWQFM-UHFFFAOYSA-N 0.000 description 7
- 150000003512 tertiary amines Chemical class 0.000 description 7
- 150000001412 amines Chemical class 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 6
- 239000011521 glass Substances 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 6
- YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical compound CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 description 6
- RHUYHJGZWVXEHW-UHFFFAOYSA-N 1,1-Dimethyhydrazine Chemical compound CN(C)N RHUYHJGZWVXEHW-UHFFFAOYSA-N 0.000 description 5
- 235000019270 ammonium chloride Nutrition 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 239000012429 reaction media Substances 0.000 description 5
- 238000011084 recovery Methods 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 239000004202 carbamide Substances 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- RBHJBMIOOPYDBQ-UHFFFAOYSA-N carbon dioxide;propan-2-one Chemical compound O=C=O.CC(C)=O RBHJBMIOOPYDBQ-UHFFFAOYSA-N 0.000 description 4
- 239000000543 intermediate Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- YJHURHDFGHUDOH-UHFFFAOYSA-M methylamino(tripropyl)azanium;chloride Chemical compound [Cl-].CCC[N+](CCC)(CCC)NC YJHURHDFGHUDOH-UHFFFAOYSA-M 0.000 description 4
- HDZGCSFEDULWCS-UHFFFAOYSA-N monomethylhydrazine Chemical compound CNN HDZGCSFEDULWCS-UHFFFAOYSA-N 0.000 description 4
- UMFJAHHVKNCGLG-UHFFFAOYSA-N n-Nitrosodimethylamine Chemical compound CN(C)N=O UMFJAHHVKNCGLG-UHFFFAOYSA-N 0.000 description 4
- 239000000376 reactant Substances 0.000 description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical group OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 239000012431 aqueous reaction media Substances 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 238000010960 commercial process Methods 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- ODZPKZBBUMBTMG-UHFFFAOYSA-N sodium amide Chemical compound [NH2-].[Na+] ODZPKZBBUMBTMG-UHFFFAOYSA-N 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- WGQKYBSKWIADBV-UHFFFAOYSA-N benzylamine Chemical compound NCC1=CC=CC=C1 WGQKYBSKWIADBV-UHFFFAOYSA-N 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 238000012937 correction Methods 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- RCJVRSBWZCNNQT-UHFFFAOYSA-N dichloridooxygen Chemical compound ClOCl RCJVRSBWZCNNQT-UHFFFAOYSA-N 0.000 description 2
- HYRAOUPGDTZOHU-UHFFFAOYSA-M dimethylamino(tripropyl)azanium;chloride Chemical compound [Cl-].CCC[N+](CCC)(CCC)N(C)C HYRAOUPGDTZOHU-UHFFFAOYSA-M 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 238000007710 freezing Methods 0.000 description 2
- 230000008014 freezing Effects 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- AFRJJFRNGGLMDW-UHFFFAOYSA-N lithium amide Chemical compound [Li+].[NH2-] AFRJJFRNGGLMDW-UHFFFAOYSA-N 0.000 description 2
- 150000003141 primary amines Chemical class 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000007086 side reaction Methods 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- UDICJQVCGWPLHM-UHFFFAOYSA-N (cyclohexylamino)-diethylazanium chloride Chemical compound [Cl-].CC[NH+](CC)NC1CCCCC1 UDICJQVCGWPLHM-UHFFFAOYSA-N 0.000 description 1
- DIIIISSCIXVANO-UHFFFAOYSA-N 1,2-Dimethylhydrazine Chemical compound CNNC DIIIISSCIXVANO-UHFFFAOYSA-N 0.000 description 1
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000004604 Blowing Agent Substances 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910019093 NaOCl Inorganic materials 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- PFLUPZGCTVGDLV-UHFFFAOYSA-N acetone azine Chemical compound CC(C)=NN=C(C)C PFLUPZGCTVGDLV-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- UCUVACIREVSBKI-UHFFFAOYSA-M amino(triheptyl)azanium;chloride Chemical compound [Cl-].CCCCCCC[N+](N)(CCCCCCC)CCCCCCC UCUVACIREVSBKI-UHFFFAOYSA-M 0.000 description 1
- CCYDPLVSRAWIFX-UHFFFAOYSA-M amino(trimethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)N CCYDPLVSRAWIFX-UHFFFAOYSA-M 0.000 description 1
- RZAVVUOSUROQON-UHFFFAOYSA-M amino-dimethyl-(4-methylphenyl)azanium;chloride Chemical compound [Cl-].CC1=CC=C([N+](C)(C)N)C=C1 RZAVVUOSUROQON-UHFFFAOYSA-M 0.000 description 1
- CUABPFMJBCBPIQ-UHFFFAOYSA-M amino-dimethyl-phenylazanium;chloride Chemical compound [Cl-].C[N+](C)(N)C1=CC=CC=C1 CUABPFMJBCBPIQ-UHFFFAOYSA-M 0.000 description 1
- 125000001204 arachidyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 125000002511 behenyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- RAJISUUPOAJLEQ-UHFFFAOYSA-N chloromethanamine Chemical compound NCCl RAJISUUPOAJLEQ-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000010959 commercial synthesis reaction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 125000001995 cyclobutyl group Chemical group [H]C1([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000000640 cyclooctyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])C1([H])[H] 0.000 description 1
- 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000001739 density measurement Methods 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- XYVQUXLXRYPSSX-UHFFFAOYSA-N diazocyclopropane Chemical compound [N-]=[N+]=C1CC1 XYVQUXLXRYPSSX-UHFFFAOYSA-N 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000004508 fractional distillation Methods 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 125000000755 henicosyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical group 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 125000002463 lignoceryl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 150000004682 monohydrates Chemical class 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 150000004005 nitrosamines Chemical class 0.000 description 1
- 230000009935 nitrosation Effects 0.000 description 1
- 238000007034 nitrosation reaction Methods 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002460 pentacosyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- HKOOXMFOFWEVGF-UHFFFAOYSA-N phenylhydrazine Chemical compound NNC1=CC=CC=C1 HKOOXMFOFWEVGF-UHFFFAOYSA-N 0.000 description 1
- 229940067157 phenylhydrazine Drugs 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 125000005270 trialkylamine group Chemical group 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
- 125000002469 tricosyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
ãçºæã®è©³çŽ°ãªèª¬æã
æ¬çºæã¯ãããã©ãžã³ããã³çš®ã
ã®ãããã«ã«
ãã«çœ®æããã©ãžã³ã®æ¹è¯ããã補é æ³ã«é¢ã
ãã
ãã«çœ®æããã©ãžã³ã®æ¹è¯ããã補é æ³ã«é¢ã
ãã
ããã©ãžã³ãã¢ã«ãã«çœ®æããã©ãžã³ãç¹ã«é
察称ãžã¡ãã«ããã©ãžã³ïŒVDMHïŒãããã³ããš
ãã«çœ®æããã©ãžã³ã¯ãåºãç¯å²ã®çšéãããšã
ã°ã補å€ãçæã蟲æ¥çšè£œåãçºç ²å€ã®è£œé çšäž
éäœãªã©ãæããéèŠãªåçšååç©ã§ããã
察称ãžã¡ãã«ããã©ãžã³ïŒVDMHïŒãããã³ããš
ãã«çœ®æããã©ãžã³ã¯ãåºãç¯å²ã®çšéãããšã
ã°ã補å€ãçæã蟲æ¥çšè£œåãçºç ²å€ã®è£œé çšäž
éäœãªã©ãæããéèŠãªåçšååç©ã§ããã
ããæ°ã®æ¹æ³ã¯ãåŸæ¥ãããã©ãžã³ããã³ãã®
èªå°äœã®è£œé ã«çšããããŠãããããšãã°ãã©ã
ã·ãïŒRaschigïŒæ³ã¯ã氎溶液äžã®ã¯ãã©ãã³ã
ãã³ã¢ã³ã¢ãã¢ããã®ããã©ãžã³ã®åæ¥çåæã§
ãããåãã次äºå¡©çŽ é žãããªãŠã ãéå°éã®ã¢
ã³ã¢ãã¢ãšåå¿ãããŠã¯ãã©ãã³ãçæãããæ°Ž
é žåãããªãŠã ãå¯çç©ãšããŠçæããã次ã
ã§ãã¯ãã©ãã³ãã¢ã³ã¢ãã¢ãšåå¿ãããŠããã©
ãžã³ãçæããããã®æ¹æ³ã®ç¬¬ïŒæ®µéã«ãããŠã
ã¯ãã©ãã³ã¯æ¥éã«åœ¢æãããããããªããã第
ïŒæ®µéã«ãããŠãã¯ãã©ãã³ãšã¢ã³ã¢ãã¢ãšã®å
å¿ã¯é ããå®çµã«ç±ãå¿ èŠãšãããããã©ãžã³ç
æç©ã®åœ¢æé床ã¯ã枩床ãšãšãã«å¢å€§ãããå¯å
å¿ãšããŠãããã©ãžã³ã¯åºçºã¯ãã©ãã³ãšåå¿ã
ãŠå¡©åã¢ã³ã¢ããŠã ããã³çªçŽ ã圢æããããã®
æãŸãããªãå¯åå¿ã«ããæãŸãããªãã»ã©ã«é«
ãé床ã®ããã©ãžã³ã®å解ãåé¿ããããã«ãã
ã®æ¹æ³ã¯é«æž©ïŒçŽ130âïŒã«ãããŠãã€å€§éå°é
ïŒ20ïŒïŒã30ïŒïŒïŒã®ã¢ã³ã¢ãã¢ãçšããŠå®æœã
ãŠãããã©ãžã³çæç©ãšã¯ãã©ãã³åå¿æåãšã®
åå¿ãæå°ãšããªããŠã¯ãªããªããææã®ããã©
ãžã³çæç©ã¯æçµã®åå¿æ··åç©äžã«æ¯èŒçäœãæ¿
床ïŒäžè¬ã«ïŒïŒ ãïŒïŒ ïŒã§çæããããããŠãã®
åå¿æ··åç©ã¯ããªãã®æ°Žãå«æããããããã®æ··
åç©ããã®ç¡æ°Žããã©ãžã³ã®ååã¯ããªãã®ã³ã¹
ããèŠããã
èªå°äœã®è£œé ã«çšããããŠãããããšãã°ãã©ã
ã·ãïŒRaschigïŒæ³ã¯ã氎溶液äžã®ã¯ãã©ãã³ã
ãã³ã¢ã³ã¢ãã¢ããã®ããã©ãžã³ã®åæ¥çåæã§
ãããåãã次äºå¡©çŽ é žãããªãŠã ãéå°éã®ã¢
ã³ã¢ãã¢ãšåå¿ãããŠã¯ãã©ãã³ãçæãããæ°Ž
é žåãããªãŠã ãå¯çç©ãšããŠçæããã次ã
ã§ãã¯ãã©ãã³ãã¢ã³ã¢ãã¢ãšåå¿ãããŠããã©
ãžã³ãçæããããã®æ¹æ³ã®ç¬¬ïŒæ®µéã«ãããŠã
ã¯ãã©ãã³ã¯æ¥éã«åœ¢æãããããããªããã第
ïŒæ®µéã«ãããŠãã¯ãã©ãã³ãšã¢ã³ã¢ãã¢ãšã®å
å¿ã¯é ããå®çµã«ç±ãå¿ èŠãšãããããã©ãžã³ç
æç©ã®åœ¢æé床ã¯ã枩床ãšãšãã«å¢å€§ãããå¯å
å¿ãšããŠãããã©ãžã³ã¯åºçºã¯ãã©ãã³ãšåå¿ã
ãŠå¡©åã¢ã³ã¢ããŠã ããã³çªçŽ ã圢æããããã®
æãŸãããªãå¯åå¿ã«ããæãŸãããªãã»ã©ã«é«
ãé床ã®ããã©ãžã³ã®å解ãåé¿ããããã«ãã
ã®æ¹æ³ã¯é«æž©ïŒçŽ130âïŒã«ãããŠãã€å€§éå°é
ïŒ20ïŒïŒã30ïŒïŒïŒã®ã¢ã³ã¢ãã¢ãçšããŠå®æœã
ãŠãããã©ãžã³çæç©ãšã¯ãã©ãã³åå¿æåãšã®
åå¿ãæå°ãšããªããŠã¯ãªããªããææã®ããã©
ãžã³çæç©ã¯æçµã®åå¿æ··åç©äžã«æ¯èŒçäœãæ¿
床ïŒäžè¬ã«ïŒïŒ ãïŒïŒ ïŒã§çæããããããŠãã®
åå¿æ··åç©ã¯ããªãã®æ°Žãå«æããããããã®æ··
åç©ããã®ç¡æ°Žããã©ãžã³ã®ååã¯ããªãã®ã³ã¹
ããèŠããã
ãªãªã³ïŒOlinïŒæ³ïŒKobe et ol.ïŒAdvanced
in Petroleum Chemistry and RefiningïŒVol.2.
Intersience Pub.Inc.New YorkïŒN.Y.ïŒ1959ïŒ
Chapter ïŒïŒã¯ãç¡æ°Žã¢ã³ã¢ãã¢ãçšããã©ã
ã·ãæ³ã®ä¿®æ£æ³ã§ãããã¢ã³ã¢ãã¢ã¯å å§äžã«æ°Ž
æ§ã¯ãã©ãã³æº¶æ¶²äžã«æ³šå ¥ããããåžéã®ãã
ã«ãåå¿æ··åç©ã®æž©åºŠã¯çŽ130âã«äžæãããã
ã¯ã¢ã³ã¢ãã¢ãšã¯ãã©ãã³ãšã®åå¿ã«æé©ãªæž©åºŠ
ã§ãããããããªãããè¿œå ã®ç±ãå€éšã®çææº
ããäŸçµŠããŠãåå¿ãå®çµããã€æ¯èŒçå°ããæ¿
床ã®ããã©ãžã³ãããªã倧ããäœç©ã®ã¢ã³ã¢ãã¢
ããåŒãç¶ãèžçå·¥çšã«ãããŠåé¢ããªããŠã¯ãª
ããªãããã以äžã®ãšãã«ã®ãŒããå¡©åãããªãŠ
ã ããã³æ°Žé žåãããªãŠã ã®å¯çç©ã®é€å»ããã³
ããã©ãžã³ã®ååã«å¿ èŠãšãããã©ãã·ãæ³ã«ã
ããããã«ãããã©ãžã³ã¯äžæ°Žåç©ãšããŠååã
ãããçŽç²ãªç¡æ°Žçæç©ãåŸãããã«ãå®è³ªçãª
è¿œå ã®ãšãã«ã®ãŒãååŠçã«çµåããæ°Žãè¿œãåº
ãããã«å¿ èŠãšãããã
in Petroleum Chemistry and RefiningïŒVol.2.
Intersience Pub.Inc.New YorkïŒN.Y.ïŒ1959ïŒ
Chapter ïŒïŒã¯ãç¡æ°Žã¢ã³ã¢ãã¢ãçšããã©ã
ã·ãæ³ã®ä¿®æ£æ³ã§ãããã¢ã³ã¢ãã¢ã¯å å§äžã«æ°Ž
æ§ã¯ãã©ãã³æº¶æ¶²äžã«æ³šå ¥ããããåžéã®ãã
ã«ãåå¿æ··åç©ã®æž©åºŠã¯çŽ130âã«äžæãããã
ã¯ã¢ã³ã¢ãã¢ãšã¯ãã©ãã³ãšã®åå¿ã«æé©ãªæž©åºŠ
ã§ãããããããªãããè¿œå ã®ç±ãå€éšã®çææº
ããäŸçµŠããŠãåå¿ãå®çµããã€æ¯èŒçå°ããæ¿
床ã®ããã©ãžã³ãããªã倧ããäœç©ã®ã¢ã³ã¢ãã¢
ããåŒãç¶ãèžçå·¥çšã«ãããŠåé¢ããªããŠã¯ãª
ããªãããã以äžã®ãšãã«ã®ãŒããå¡©åãããªãŠ
ã ããã³æ°Žé žåãããªãŠã ã®å¯çç©ã®é€å»ããã³
ããã©ãžã³ã®ååã«å¿ èŠãšãããã©ãã·ãæ³ã«ã
ããããã«ãããã©ãžã³ã¯äžæ°Žåç©ãšããŠååã
ãããçŽç²ãªç¡æ°Žçæç©ãåŸãããã«ãå®è³ªçãª
è¿œå ã®ãšãã«ã®ãŒãååŠçã«çµåããæ°Žãè¿œãåº
ãããã«å¿ èŠãšãããã
ã·ãšã¹ã¿ã³ãïŒSchestakoffïŒæ³ã¯ãå°¿çŽ ã次
äºå¡©çŽ é žãããªãŠã ã§å解ããŠããã©ãžã³ãçæ
ãããããšã«åºã¥ãããã®åå¿ã¯ã¢ããããã®ç¬¬
äžã¢ãã³ã補é ãããããã³ïŒHoffmanïŒæ³ã«
é¡äŒŒããããã®æ¹æ³ã«ãããŠãå°¿çŽ ããã³æ°Žé žå
ãããªãŠã ã®å·æ°Žæº¶æ¶²ãã次äºå¡©çŽ é žãããªãŠã
ã®å·æ°Žæº¶æ¶²ã«å ãããåå¿ç±ã¯æž©åºŠã100âã«äž
æããããã®æž©åºŠã«ãããŠåå¿ã¯æ¯èŒçé«ãé床
ã§èµ·ããã倧éã®æ°Žèžæ°ãå°¿çŽ æº¶æ¶²ïŒ43ïŒ ã®æº¶
液ïŒã®èª¿è£œã«äœ¿çšããŠã溶液ã®å€§ããåžç±ãè£å
ããªããŠã¯ãªããªããçæç©ã¯ãåè¿°ã®åæ¥çæ¹
æ³ã«ãããŠãããªãäœãæ¿åºŠïŒçŽïŒïŒ ïŒã®ããã©
ãžã³âæ°Žåç©ã§ãããæ¿çž®ãæ°Žåç©ã®è»¢åããã³
æçµããã©ãžã³çæç©ã®åå¥ã«è¿œå ã®ãšãã«ã®ãŒ
ãå¿ èŠãšãããé床ã®éã®ã¢ã«ã«ãªããã³ã¢ã«ã«
ãªå¡©ãå¯çç©ãšããŠçæãïŒå¯çç©å¯Ÿãã®ããã«
補é ãããN2H4ã®éèŠæ¯çŽ12ïŒïŒïŒããããã¯
ãã®æ¹æ³ã«ãããŠå䜿çšäžå¯èœã§ããã
äºå¡©çŽ é žãããªãŠã ã§å解ããŠããã©ãžã³ãçæ
ãããããšã«åºã¥ãããã®åå¿ã¯ã¢ããããã®ç¬¬
äžã¢ãã³ã補é ãããããã³ïŒHoffmanïŒæ³ã«
é¡äŒŒããããã®æ¹æ³ã«ãããŠãå°¿çŽ ããã³æ°Žé žå
ãããªãŠã ã®å·æ°Žæº¶æ¶²ãã次äºå¡©çŽ é žãããªãŠã
ã®å·æ°Žæº¶æ¶²ã«å ãããåå¿ç±ã¯æž©åºŠã100âã«äž
æããããã®æž©åºŠã«ãããŠåå¿ã¯æ¯èŒçé«ãé床
ã§èµ·ããã倧éã®æ°Žèžæ°ãå°¿çŽ æº¶æ¶²ïŒ43ïŒ ã®æº¶
液ïŒã®èª¿è£œã«äœ¿çšããŠã溶液ã®å€§ããåžç±ãè£å
ããªããŠã¯ãªããªããçæç©ã¯ãåè¿°ã®åæ¥çæ¹
æ³ã«ãããŠãããªãäœãæ¿åºŠïŒçŽïŒïŒ ïŒã®ããã©
ãžã³âæ°Žåç©ã§ãããæ¿çž®ãæ°Žåç©ã®è»¢åããã³
æçµããã©ãžã³çæç©ã®åå¥ã«è¿œå ã®ãšãã«ã®ãŒ
ãå¿ èŠãšãããé床ã®éã®ã¢ã«ã«ãªããã³ã¢ã«ã«
ãªå¡©ãå¯çç©ãšããŠçæãïŒå¯çç©å¯Ÿãã®ããã«
補é ãããN2H4ã®éèŠæ¯çŽ12ïŒïŒïŒããããã¯
ãã®æ¹æ³ã«ãããŠå䜿çšäžå¯èœã§ããã
ãã«ã°ããŠïŒBergbauïŒãŸãã¯ãã€ãšã«
ïŒBeyerïŒã®æ¹æ³ã¯ãããã«ä»ã®ããã©ãžã³ã®å
æ¥ç補é æ³ã§ããããã«ã¯ããŠæ³ã®ãšãã«ã®ãŒèŠ
æ±ã¯ãåè¿°ã®åæ¥çæ¹æ³ã«ãããããã«å€§ãããª
ãããã®æ¹æ³ã«ãããŠãã¢ã³ã¢ãã¢ãå¡©çŽ ãšã±ã
ã³ã®ååšäžã«åå¿ãããŠãäžéäœã®ãžã¢ãŸã·ã¯ã
ãããã³ãŸãã¯ã±ã¿ãžã³ãçæããã次ãã§ãã
ã®äžéäœãå æ°Žå解ããŠããã©ãžã³æ°Žåç©ãçæ
ããåŸè ãææã®ç¡æ°Žçæç©ã«è»¢åãããããã©
ãžã³ã®ååã®ãšãã«ã®ãŒèŠæ±éã¯ãåè¿°ã®åæ¥ç
æ¹æ³ãšã»ãŒåãã§ãããç¡æ°Žåå¿æ··åç©ããã®å
åãå å«ããã
ïŒBeyerïŒã®æ¹æ³ã¯ãããã«ä»ã®ããã©ãžã³ã®å
æ¥ç補é æ³ã§ããããã«ã¯ããŠæ³ã®ãšãã«ã®ãŒèŠ
æ±ã¯ãåè¿°ã®åæ¥çæ¹æ³ã«ãããããã«å€§ãããª
ãããã®æ¹æ³ã«ãããŠãã¢ã³ã¢ãã¢ãå¡©çŽ ãšã±ã
ã³ã®ååšäžã«åå¿ãããŠãäžéäœã®ãžã¢ãŸã·ã¯ã
ãããã³ãŸãã¯ã±ã¿ãžã³ãçæããã次ãã§ãã
ã®äžéäœãå æ°Žå解ããŠããã©ãžã³æ°Žåç©ãçæ
ããåŸè ãææã®ç¡æ°Žçæç©ã«è»¢åãããããã©
ãžã³ã®ååã®ãšãã«ã®ãŒèŠæ±éã¯ãåè¿°ã®åæ¥ç
æ¹æ³ãšã»ãŒåãã§ãããç¡æ°Žåå¿æ··åç©ããã®å
åãå å«ããã
ããããŠãã»ãšãã©ã®ããç¥ãããåºãå®æœã
ããŠããããã©ãžã³ã®è£œé æ³ã¯ãããã©ãžã³ã®æ°Ž
åç©ãçæããç¡æ°Žçæç©ã®ååã«å®è³ªçãªãšã
ã«ã®ãŒãå¿ èŠãšããã
ããŠããããã©ãžã³ã®è£œé æ³ã¯ãããã©ãžã³ã®æ°Ž
åç©ãçæããç¡æ°Žçæç©ã®ååã«å®è³ªçãªãšã
ã«ã®ãŒãå¿ èŠãšããã
ãšãã«ã®ãŒã®ã³ã¹ãã絶ããäžæããŠããããš
ãèŠããšãæå®ã®åå¿ãå®çµããããã«å¿ èŠãšã
ãç±ååŠçèŠä»¶ã«ããããšãã«ã®ãŒã®éå°äœ¿çšã
æå°ãšããããšã¯ããããŠéèŠã§ããããããªã
ååŠçæ¹æ³ã«ãããå šãšãã«ã®ãŒèŠæ±éãèæ ®ã
ããšãããåæããã³è£å©çååŠç©è³ªã®è£œé ã«èŠ
ãããšãã«ã®ãŒããèæ ®ããªããŠã¯ãªããªããã
ãããŠãããã©ãžã³ã®å Žåã«ãããŠãNH3ã
Cl2ãNaOClãå°¿çŽ ãNaOHãªã©ãæäŸãããã
ã®ãšãã«ã®ãŒã®èŠæ±éã¯ãæçµçæç©ãã€ããã
ãã«èŠãããšãã«ã®ãŒã®æ倱ãŸãã¯ç²åŸã®çšåºŠã
決å®ããããã§éèŠãªå åã§ãããåæ§ã«ãå¯ç
ç©å¯Ÿææã®æçµçæç©ã®ééæ¯ã¯ãããæ¹æ³ã®å š
äœã®å¹çã«ãããŠä»ã®éèŠãªå åãšããŠè©äŸ¡ããª
ããŠã¯ãªããªããããã«ç §ããŠèãããšãããã©
ãžã³ã補é ããåè¿°ã®å è¡æè¡ã®æ¹æ³ã¯ãããšã«
ããã©ãžã³æ°Žåç©ã®åœ¢ææã«58kcalïŒã¢ã«ã®çæ
ç©ããã©ãžã³ãç³»ãã倱ãªããããšèãããšã決
å®çã«éå¹ççã§ããã
ãèŠããšãæå®ã®åå¿ãå®çµããããã«å¿ èŠãšã
ãç±ååŠçèŠä»¶ã«ããããšãã«ã®ãŒã®éå°äœ¿çšã
æå°ãšããããšã¯ããããŠéèŠã§ããããããªã
ååŠçæ¹æ³ã«ãããå šãšãã«ã®ãŒèŠæ±éãèæ ®ã
ããšãããåæããã³è£å©çååŠç©è³ªã®è£œé ã«èŠ
ãããšãã«ã®ãŒããèæ ®ããªããŠã¯ãªããªããã
ãããŠãããã©ãžã³ã®å Žåã«ãããŠãNH3ã
Cl2ãNaOClãå°¿çŽ ãNaOHãªã©ãæäŸãããã
ã®ãšãã«ã®ãŒã®èŠæ±éã¯ãæçµçæç©ãã€ããã
ãã«èŠãããšãã«ã®ãŒã®æ倱ãŸãã¯ç²åŸã®çšåºŠã
決å®ããããã§éèŠãªå åã§ãããåæ§ã«ãå¯ç
ç©å¯Ÿææã®æçµçæç©ã®ééæ¯ã¯ãããæ¹æ³ã®å š
äœã®å¹çã«ãããŠä»ã®éèŠãªå åãšããŠè©äŸ¡ããª
ããŠã¯ãªããªããããã«ç §ããŠèãããšãããã©
ãžã³ã補é ããåè¿°ã®å è¡æè¡ã®æ¹æ³ã¯ãããšã«
ããã©ãžã³æ°Žåç©ã®åœ¢ææã«58kcalïŒã¢ã«ã®çæ
ç©ããã©ãžã³ãç³»ãã倱ãªããããšèãããšã決
å®çã«éå¹ççã§ããã
UDHMã®åæ¥ç補é ã«çŸåšçšããããŠããæ¹
æ³ã¯ããžã¡ãã«ã¢ãã³ã®ç¡«é žå¡©ãäºç¡é žãããªãŠ
ã ã§ããããœåããŠãžã¡ãã«ããããœã¢ãã³ãç
æãããããéå ããŠææçæç©ã«ããããšãã
ãªããããã©ãžã³æ³ã«é¢ããŠäžã«è¿°ã¹ãæ¬ ç¹ã®å€
ãã«æ©ãŸãããããšã«å ããŠããã®æ¹æ³ã«ãããŠ
äžéäœãšããŠçæããããžã¡ãã«ããããœã¢ãã³
ã¯æ¢ç¥ã®çºçç©è³ªã§ããããããŠãã®æ¹æ³ãå®æœ
ããŠãã人å¡ã®ã¿ãªãããç°å¢ããåæ§ã«æœåšç
ãªå±éºã«ãããããã®æœåšçå±éºã®ããããªããŠ
ãã€ã·ãšãã«ã»ã»ã€ããã€ã»ã¢ã³ãã»ãã«ã¹ã»ã¢
ãããã¹ãã¬ã€ã·ãšã³ïŒOccupational Saftey
and Health AdministrationïŒïŒOSHAïŒã¯ãã
ãããœã¢ãã³ã䜿çšããããã¯è£œé ããã補é ã
èŠå¶ããå³æ ŒãªèŠåãæœè¡ããã
æ³ã¯ããžã¡ãã«ã¢ãã³ã®ç¡«é žå¡©ãäºç¡é žãããªãŠ
ã ã§ããããœåããŠãžã¡ãã«ããããœã¢ãã³ãç
æãããããéå ããŠææçæç©ã«ããããšãã
ãªããããã©ãžã³æ³ã«é¢ããŠäžã«è¿°ã¹ãæ¬ ç¹ã®å€
ãã«æ©ãŸãããããšã«å ããŠããã®æ¹æ³ã«ãããŠ
äžéäœãšããŠçæããããžã¡ãã«ããããœã¢ãã³
ã¯æ¢ç¥ã®çºçç©è³ªã§ããããããŠãã®æ¹æ³ãå®æœ
ããŠãã人å¡ã®ã¿ãªãããç°å¢ããåæ§ã«æœåšç
ãªå±éºã«ãããããã®æœåšçå±éºã®ããããªããŠ
ãã€ã·ãšãã«ã»ã»ã€ããã€ã»ã¢ã³ãã»ãã«ã¹ã»ã¢
ãããã¹ãã¬ã€ã·ãšã³ïŒOccupational Saftey
and Health AdministrationïŒïŒOSHAïŒã¯ãã
ãããœã¢ãã³ã䜿çšããããã¯è£œé ããã補é ã
èŠå¶ããå³æ ŒãªèŠåãæœè¡ããã
å
è¡æè¡ã«åºæãªæ¬ ç¹ããã³å±éºã®å€ãã¯ãæ¬
çºæè ã®ç±³åœç¹èš±ç¬¬4286108å·ã«èšèŒãããæ¹æ³
ã«ãã€ãŠå æãããããã®æ¹æ³ã¯ã第äžããã©ãž
ããŠã ãã©ã€ãããã¢ã«ã«ãªéå±ã¢ãããã¢ã«ã«
ãªåé¡éå±ã¢ããããããã«ã«ãã«çœ®æã¢ã«ã«ãª
éå±ã¢ãããŸãã¯ãããã«ã«ãã«çœ®æã¢ã«ã«ãªå
é¡éå±ã¢ããããæã矀ããéžã°ããååç©ãšã
éæ°Žæ§äžæŽ»æ§æ äœã®ååšäžã«ãåå¿ãããããšã«
ãããããã©ãžã³ããã³ãããã«ã«ãã«çœ®æãã
ã©ãžã³ã補é ããã
çºæè ã®ç±³åœç¹èš±ç¬¬4286108å·ã«èšèŒãããæ¹æ³
ã«ãã€ãŠå æãããããã®æ¹æ³ã¯ã第äžããã©ãž
ããŠã ãã©ã€ãããã¢ã«ã«ãªéå±ã¢ãããã¢ã«ã«
ãªåé¡éå±ã¢ããããããã«ã«ãã«çœ®æã¢ã«ã«ãª
éå±ã¢ãããŸãã¯ãããã«ã«ãã«çœ®æã¢ã«ã«ãªå
é¡éå±ã¢ããããæã矀ããéžã°ããååç©ãšã
éæ°Žæ§äžæŽ»æ§æ äœã®ååšäžã«ãåå¿ãããããšã«
ãããããã©ãžã³ããã³ãããã«ã«ãã«çœ®æãã
ã©ãžã³ã補é ããã
ç±³åœç¹èš±ç¬¬4286108å·ã®æ¹æ³ã«ãã第äžããã©
ãžããŠã ãã©ã€ãã®è£œé ã«ãããŠäœ¿çšããåå¿æ
åã®ïŒçš®ã¯ãã¢ã³ã¢ãã¢ã¬ã¹ãå¡©çŽ ãšåå¿ããã
ããšã«ãã€ãŠè£œé ãããã¯ãã©ãã³ã§ããããã®
åå¿ã®å¯çç©ã¯å¡©åã¢ã³ã¢ããŠã ã§ãããããã¯
åå¿æåã®äŸçµŠã©ã€ã³ãè©°ãŸãããåŸåãããã
ãããŠäžè¬ã«ãã®æ¹æ³ã®æäœã劚害ããã
ãžããŠã ãã©ã€ãã®è£œé ã«ãããŠäœ¿çšããåå¿æ
åã®ïŒçš®ã¯ãã¢ã³ã¢ãã¢ã¬ã¹ãå¡©çŽ ãšåå¿ããã
ããšã«ãã€ãŠè£œé ãããã¯ãã©ãã³ã§ããããã®
åå¿ã®å¯çç©ã¯å¡©åã¢ã³ã¢ããŠã ã§ãããããã¯
åå¿æåã®äŸçµŠã©ã€ã³ãè©°ãŸãããåŸåãããã
ãããŠäžè¬ã«ãã®æ¹æ³ã®æäœã劚害ããã
æ¬çºæã«ããã°ãã¢ã«ã«ãªéå±ã¢ãããã¢ã«ã«
ãªåé¡éå±ã¢ããããããã«ã«ãã«çœ®æã¢ã«ã«ãª
éå±ã¢ããåã¯ãããã«ã«ãã«çœ®æã¢ã«ã«ãªåé¡
éå±ã¢ããããå¡©çŽ åå€ãšåå¿ãããŠãå¡©åã¢ã³
ã¢ããŠã ãåæã«çæãããªãã§ãã¯ãã©ãã³ãŸ
ãã¯ãããã«ã«ãã«çœ®æã¯ãã©ãã³ãçæããã
ãã®ããã«çæããã¯ãã©ãã³ã第äžã¢ãã³ãšå
å¿çæãããŠç¬¬äžããã©ãžããŠã ã¯ãã©ã€ããç
æããããããŠç¬¬äžããã©ãžããŠã ã¯ãã©ã€ãã
ã¢ã«ã«ãªéå±ã¢ãããã¢ã«ã«ãªåé¡éå±ã¢ããã
ãããã«ã«ãã«çœ®æã¢ã«ã«ãªéå±ã¢ãããŸãã¯ã
ããã«ã«ãã«çœ®æã¢ã«ã«ãªåé¡éå±ã¢ãããšãå®
質çã«ç¡æ°Žã®æ¡ä»¶äžã«ãåå¿ãããŠãææçæç©
ãçæãããããšãããªããç¡æ°Žããã©ãžã³ãã
ã³ãã®ããã©ã«ã«ãã«çœ®æèªå°äœã補é ããæ¹è¯
ãããæ¹æ³ãæäŸãããã
ãªåé¡éå±ã¢ããããããã«ã«ãã«çœ®æã¢ã«ã«ãª
éå±ã¢ããåã¯ãããã«ã«ãã«çœ®æã¢ã«ã«ãªåé¡
éå±ã¢ããããå¡©çŽ åå€ãšåå¿ãããŠãå¡©åã¢ã³
ã¢ããŠã ãåæã«çæãããªãã§ãã¯ãã©ãã³ãŸ
ãã¯ãããã«ã«ãã«çœ®æã¯ãã©ãã³ãçæããã
ãã®ããã«çæããã¯ãã©ãã³ã第äžã¢ãã³ãšå
å¿çæãããŠç¬¬äžããã©ãžããŠã ã¯ãã©ã€ããç
æããããããŠç¬¬äžããã©ãžããŠã ã¯ãã©ã€ãã
ã¢ã«ã«ãªéå±ã¢ãããã¢ã«ã«ãªåé¡éå±ã¢ããã
ãããã«ã«ãã«çœ®æã¢ã«ã«ãªéå±ã¢ãããŸãã¯ã
ããã«ã«ãã«çœ®æã¢ã«ã«ãªåé¡éå±ã¢ãããšãå®
質çã«ç¡æ°Žã®æ¡ä»¶äžã«ãåå¿ãããŠãææçæç©
ãçæãããããšãããªããç¡æ°Žããã©ãžã³ãã
ã³ãã®ããã©ã«ã«ãã«çœ®æèªå°äœã補é ããæ¹è¯
ãããæ¹æ³ãæäŸãããã
ããã§äœ¿çšããããããã«ã«ãã«ããšããèª
ã¯ã芪ã®çåæ°ŽçŽ ããæ°ŽçŽ ååãé€å»ããŠåŸãã
ãïŒäŸ¡ã®æ®åºãæå³ããããããã«ã«ãã«åºã®ä»£
è¡šäŸã¯ãïŒã25ã®ççŽ ååãæããã¢ã«ãã«ãã
ãšãã°ãã¡ãã«ããšãã«ããããã«ãããã«ãã
ã³ãã«ããªãã·ã«ããããã«ããªã¯ãã«ããã
ã«ããŠã³ãã·ã«ããã·ã«ãããã·ã«ãªã¯ã¿ãã·ã«
ãããã·ã«ããšã€ã³ã·ã«ããã³ãšã€ã³ã·ã«ããã³
ã·ã«ãããªã³ã·ã«ãããã©ã³ã·ã«ããã³ã¿ã³ã·ã«
ããã³ãããã®ç°æ§äœïŒïŒã25åã®ççŽ ååã®ã¢
ãªãŒã«ãããšãã°ãããšãã«ãããªã«ããã·ãª
ã«ããããã«ããããšãã«ãããã©ããšãã«ãª
ã©ïŒïŒã25åã®ççŽ ååã®ã¢ã©ã«ãã«ãããšã
ã°ããã³ãžã«ãããšããã«ãããšã³ãããã«ãã
ãšã³ããã«ãããšã³ããã·ã«ãããããªã¯ãã«ãª
ã©ïŒïŒãïŒåã®ççŽ ååã®ã·ã¯ãã¢ã«ãã«ãããš
ãã°ãã·ã¯ããããã«ãã·ã¯ãããã«ãã·ã¯ãã
ãã·ã«ãã·ã¯ããããã«ãã·ã¯ããªã¯ãã«ãªã©ã§
ããã
ã¯ã芪ã®çåæ°ŽçŽ ããæ°ŽçŽ ååãé€å»ããŠåŸãã
ãïŒäŸ¡ã®æ®åºãæå³ããããããã«ã«ãã«åºã®ä»£
è¡šäŸã¯ãïŒã25ã®ççŽ ååãæããã¢ã«ãã«ãã
ãšãã°ãã¡ãã«ããšãã«ããããã«ãããã«ãã
ã³ãã«ããªãã·ã«ããããã«ããªã¯ãã«ããã
ã«ããŠã³ãã·ã«ããã·ã«ãããã·ã«ãªã¯ã¿ãã·ã«
ãããã·ã«ããšã€ã³ã·ã«ããã³ãšã€ã³ã·ã«ããã³
ã·ã«ãããªã³ã·ã«ãããã©ã³ã·ã«ããã³ã¿ã³ã·ã«
ããã³ãããã®ç°æ§äœïŒïŒã25åã®ççŽ ååã®ã¢
ãªãŒã«ãããšãã°ãããšãã«ãããªã«ããã·ãª
ã«ããããã«ããããšãã«ãããã©ããšãã«ãª
ã©ïŒïŒã25åã®ççŽ ååã®ã¢ã©ã«ãã«ãããšã
ã°ããã³ãžã«ãããšããã«ãããšã³ãããã«ãã
ãšã³ããã«ãããšã³ããã·ã«ãããããªã¯ãã«ãª
ã©ïŒïŒãïŒåã®ççŽ ååã®ã·ã¯ãã¢ã«ãã«ãããš
ãã°ãã·ã¯ããããã«ãã·ã¯ãããã«ãã·ã¯ãã
ãã·ã«ãã·ã¯ããããã«ãã·ã¯ããªã¯ãã«ãªã©ã§
ããã
ããã§äœ¿çšãããã¢ã«ã«ãªéå±ããšããèªã¯ã
ãªããŠã ããããªãŠã ãã«ãªãŠã ãã«ããžãŠã ã
ãã³ã»ã·ãŠã ãå å«ããããšãæå³ããã
ãªããŠã ããããªãŠã ãã«ãªãŠã ãã«ããžãŠã ã
ãã³ã»ã·ãŠã ãå å«ããããšãæå³ããã
ããã§äœ¿çšãããã¢ã«ã«ãªåé¡éå±ããšããèª
ã¯ããã°ãã·ãŠã ãã«ã«ã·ãŠã ãããªãŠã ããã³
ã¹ããã³ããŠã ãå å«ããããšãæå³ããã
ã¯ããã°ãã·ãŠã ãã«ã«ã·ãŠã ãããªãŠã ããã³
ã¹ããã³ããŠã ãå å«ããããšãæå³ããã
ããã§äœ¿çšãããéæ°Žæ§ã®åå¿åªè³ªããšããèª
ã¯ãåå¿ã®ææéçšã«æªåœ±é¿ãåãŒãããã€å®è³ª
çã«æ°Žãå«æããªããããã§çšããåå¿æåã®ã
ãã®æ¶²äœã®æº¶åªãããã¯æ¶²äœãŸãã¯åºäœã®æ äœã
æå³ããããšãæå³ããããå®è³ªçã«æ°Žãå«æã
ãªãããšã¯ãïŒééïŒ ããå°ãªãã奜ãŸããã¯
0.1ïŒ ããå°ãªãæ°Žãå«æããããšãæå³ããã
ãã®ãããªæ äœã®äŸã¯ã也ç¥ããã±ãã·ã³ïŒå¥œãŸ
ããã¯äœãã€ãªãŠå«éã§ãããã€æ°ãããèžçã
ããã®ïŒãããªã¢ã«ãã«ã¢ãã³ãããšãã°ããªã
ããã«ã¢ãã³ããã³ããªããã«ã¢ãã³ãåå¡©åç
çŽ ãã¢ã«ãã«ãšãŒãã«ãããã³ãããã®æ··åç©ã§
ããããã®æ¹æ³ã®åå·¥çšã«ãããåå¿åªè³ªãšããŠ
ã±ãã·ã³ã䜿çšãããšãããã©ãžã³ãŸãã¯ããã
ã«ã«ãã«çœ®æããã©ãžã³ã®åçã¯èããå¢å ãã
ããšãããã€ãã
ã¯ãåå¿ã®ææéçšã«æªåœ±é¿ãåãŒãããã€å®è³ª
çã«æ°Žãå«æããªããããã§çšããåå¿æåã®ã
ãã®æ¶²äœã®æº¶åªãããã¯æ¶²äœãŸãã¯åºäœã®æ äœã
æå³ããããšãæå³ããããå®è³ªçã«æ°Žãå«æã
ãªãããšã¯ãïŒééïŒ ããå°ãªãã奜ãŸããã¯
0.1ïŒ ããå°ãªãæ°Žãå«æããããšãæå³ããã
ãã®ãããªæ äœã®äŸã¯ã也ç¥ããã±ãã·ã³ïŒå¥œãŸ
ããã¯äœãã€ãªãŠå«éã§ãããã€æ°ãããèžçã
ããã®ïŒãããªã¢ã«ãã«ã¢ãã³ãããšãã°ããªã
ããã«ã¢ãã³ããã³ããªããã«ã¢ãã³ãåå¡©åç
çŽ ãã¢ã«ãã«ãšãŒãã«ãããã³ãããã®æ··åç©ã§
ããããã®æ¹æ³ã®åå·¥çšã«ãããåå¿åªè³ªãšããŠ
ã±ãã·ã³ã䜿çšãããšãããã©ãžã³ãŸãã¯ããã
ã«ã«ãã«çœ®æããã©ãžã³ã®åçã¯èããå¢å ãã
ããšãããã€ãã
æ¬çºæã®å¥œãŸããå®æœæ
æ§ã«ãããŠãéåžžã«å¥œ
éœåãªç±ååŠãæãããç¡æ°Žããã©ãžã³ã®è£œé æ³
ãæäŸãããããã®å¥œãŸããæ¹æ³ã«ãããŠã¯ãå¡©
çŽ ãã¢ã«ã«ãªéå±ã¢ãããããšãã°ãœãŒããããŸ
ãã¯ãªããŠã ã¢ãããšåå¿ãããŠãã¯ãã©ãã³ã
ãã³å¯Ÿå¿ããã¢ã«ã«ãªéå±å¡©ã補é ããããã®ã
ãã«è£œé ãããã¯ãã©ãã³ã¯ã第äžã¢ãã³ãšåå¿
ããŠç¬¬äžããã©ãžããŠã ã¯ãã©ã€ãã圢æããã
ãã¯ãé 次ã«ãã¢ã«ã«ãªéå±ã¢ãããšåå¿ããŠç¡
æ°Žããã©ãžã³ãçæããã
éœåãªç±ååŠãæãããç¡æ°Žããã©ãžã³ã®è£œé æ³
ãæäŸãããããã®å¥œãŸããæ¹æ³ã«ãããŠã¯ãå¡©
çŽ ãã¢ã«ã«ãªéå±ã¢ãããããšãã°ãœãŒããããŸ
ãã¯ãªããŠã ã¢ãããšåå¿ãããŠãã¯ãã©ãã³ã
ãã³å¯Ÿå¿ããã¢ã«ã«ãªéå±å¡©ã補é ããããã®ã
ãã«è£œé ãããã¯ãã©ãã³ã¯ã第äžã¢ãã³ãšåå¿
ããŠç¬¬äžããã©ãžããŠã ã¯ãã©ã€ãã圢æããã
ãã¯ãé 次ã«ãã¢ã«ã«ãªéå±ã¢ãããšåå¿ããŠç¡
æ°Žããã©ãžã³ãçæããã
ãã®å¥œãŸããå®æœæ
æ§ã®å¯çç©ã®ãã¹ãŠã¯ã䟿
å©ã«ååããããšãã§ãããåæ¥çã«æçšãªç©è³ª
ã§ããããããã®ç©è³ªã®å€§éšåã¯ãå埪ç°ãã
ãŠããã®æ¹æ³ã®ããå·¥çšã«ãããåºçºç©è³ªãšããŠ
çšãããããããã¯åèšåºçºç©è³ªã®åæãšããŠåœ¹
ç«ãããããšãã§ããã
å©ã«ååããããšãã§ãããåæ¥çã«æçšãªç©è³ª
ã§ããããããã®ç©è³ªã®å€§éšåã¯ãå埪ç°ãã
ãŠããã®æ¹æ³ã®ããå·¥çšã«ãããåºçºç©è³ªãšããŠ
çšãããããããã¯åèšåºçºç©è³ªã®åæãšããŠåœ¹
ç«ãããããšãã§ããã
以åŸã®è©³çŽ°ãªèª¬æããæãããªããã«ãç±³åœç¹
蚱第4286108å·ã«å å«ãããæ¬çºæã®åãã®çºæ
ã®å©ç¹ã¯ãã¹ãŠãæãããããªãã¡ããã®æ¹æ³ã¯
ç¹æ®åãããè£ çœ®ãå¿ èŠãšãããåå¿æåã®ã³ã¹
ãã¯æäœãšããããããŠææçæç©ã¯æšæºã®åå
æè¡ãçšããŠå®¹æã«åŸããããããã«ç¡æ°Žã®ãã
ã©ãžã³ããã³ãããã«ã«ãã«çœ®æããã©ãžã³ã¯å
å¿æ··åç©äžã«æ¯èŒçé«ãæ¿åºŠïŒ25ã50ïŒ çšåºŠïŒã§
åŸãããšãã§ãããæ¬çºæã®æ¹æ³ã®ä»ã®æ確ãªå©
ç¹ã¯ããã®æ¹æ³ã®å¹çããæäœã劚害ããããšã
ããã¢ãã³å¡©é žå¡©ãåæã«çæããªããšããããš
ã§ããã
蚱第4286108å·ã«å å«ãããæ¬çºæã®åãã®çºæ
ã®å©ç¹ã¯ãã¹ãŠãæãããããªãã¡ããã®æ¹æ³ã¯
ç¹æ®åãããè£ çœ®ãå¿ èŠãšãããåå¿æåã®ã³ã¹
ãã¯æäœãšããããããŠææçæç©ã¯æšæºã®åå
æè¡ãçšããŠå®¹æã«åŸããããããã«ç¡æ°Žã®ãã
ã©ãžã³ããã³ãããã«ã«ãã«çœ®æããã©ãžã³ã¯å
å¿æ··åç©äžã«æ¯èŒçé«ãæ¿åºŠïŒ25ã50ïŒ çšåºŠïŒã§
åŸãããšãã§ãããæ¬çºæã®æ¹æ³ã®ä»ã®æ確ãªå©
ç¹ã¯ããã®æ¹æ³ã®å¹çããæäœã劚害ããããšã
ããã¢ãã³å¡©é žå¡©ãåæã«çæããªããšããããš
ã§ããã
æ¬çºæã®ä»ã®é¡èãªå©ç¹ã¯ããããã«ã«ãã«çœ®
æããã©ãžã³ãããšã«UDMHã®è£œé ã®æ¯èŒçå®
å šãªæé ãæäŸããããšããããšã§ããããã®ã
ããªçæç©ã®è£œé ã«çŸåšçšããããŠããæ¹æ³ãšç°
ãªããæ¬çºæã®æ¹æ³ã¯ãäœæ¥å¡ãç°å¢ã«å¯ŸããŠã»
ãšãã©ãããã¯ãŸã€ããæ害ã§ãªãæ¡ä»¶ã®ããš
ã§ãå®æœãããã
æããã©ãžã³ãããšã«UDMHã®è£œé ã®æ¯èŒçå®
å šãªæé ãæäŸããããšããããšã§ããããã®ã
ããªçæç©ã®è£œé ã«çŸåšçšããããŠããæ¹æ³ãšç°
ãªããæ¬çºæã®æ¹æ³ã¯ãäœæ¥å¡ãç°å¢ã«å¯ŸããŠã»
ãšãã©ãããã¯ãŸã€ããæ害ã§ãªãæ¡ä»¶ã®ããš
ã§ãå®æœãããã
æ¬çºæã®æ¹æ³ã¯ã次ã®äžè¬çåå¿å³ã«åŸã€ãŠå®
æœããïŒ åŒäžïŒžã¯æ°ŽçŽ ãã¢ã«ã«ãªéå±ãŸãã¯ã¢ã«ã«ãªå
é¡éå±ãè¡šãããR1ããã³R2ã¯åäžã§ãããã
ããã¯ç°ãªãããã€æ°ŽçŽ ãŸãã¯ãããã«ã«ãã«åº
ãè¡šãããã¯å¡©çŽ åå€ã®æ®åºãè¡šãããR3ã
R4ããã³R5ã¯åäžã§ããããããã¯ç°ãªããã
ã€ãããã«ã«ãã«åºãè¡šãããã¯ã¢ã«ã«ãªéå±
ãŸãã¯ã¢ã«ã«ãªåé¡éå±ãè¡šããããããŠR6ã
ãã³R7ã¯åäžã§ããããããã¯ç°ãªãããã€æ°Ž
çŽ ãŸãã¯ãããã«ã«ãã«åºãè¡šããã
æœããïŒ åŒäžïŒžã¯æ°ŽçŽ ãã¢ã«ã«ãªéå±ãŸãã¯ã¢ã«ã«ãªå
é¡éå±ãè¡šãããR1ããã³R2ã¯åäžã§ãããã
ããã¯ç°ãªãããã€æ°ŽçŽ ãŸãã¯ãããã«ã«ãã«åº
ãè¡šãããã¯å¡©çŽ åå€ã®æ®åºãè¡šãããR3ã
R4ããã³R5ã¯åäžã§ããããããã¯ç°ãªããã
ã€ãããã«ã«ãã«åºãè¡šãããã¯ã¢ã«ã«ãªéå±
ãŸãã¯ã¢ã«ã«ãªåé¡éå±ãè¡šããããããŠR6ã
ãã³R7ã¯åäžã§ããããããã¯ç°ãªãããã€æ°Ž
çŽ ãŸãã¯ãããã«ã«ãã«åºãè¡šããã
ã¯ãã©ãã³ã圢æããåå¿ïŒåå¿ïŒ¡ïŒãå®æœã
ããšããåŒã®ååç©ãããšãã°ãã¢ã«ã«ãªéå±
ã¢ããåã¯ã¢ã«ã«ãªåé¡éå±ã¢ãããåŒã®å¡©çŽ
åå€ãšåå¿ããããåŒã®åå¿æåã¯ããç¥ãã
ãŠããããŸããã®è£œé æ³ãããç¥ãããŠãããã
ã®åå¿ã«ãããŠäœ¿çšããå¡©çŽ åå€ã¯ãå¡©çŽ ã次äº
å¡©çŽ é žããã³å¡©çŽ ã¢ããªãã·ãããéžã°ãããåŸ
è ã®ïŒçš®ã®å¡©çŽ åå€ã¯ãã¢ã«ã«ãªéå±æ¬¡äºå¡©çŽ é ž
å¡©ãŸãã¯ã¢ã«ã«ãªåé¡éå±æ¬¡äºå¡©çŽ ç£å¡©ãã䟿å©
ã«è£œé ãããããã®è£œé ã®è©³çŽ°ã¯ãåŸã®å®æœäŸã«
èšèŒãããŠãããå¡©åã¢ã³ã¢ããŠã ãåæã«çæ
ãããªãã§ããããã«ã«ãã«çœ®æã¯ããã¢ãã³ã
補é ãããšãã®ãããïŒçš®ã®å¡©çŽ åå€ã®äœ¿çšã¯ã
æ¬çºæã®ãšãã«ææãªãã€é©æ°çãªé¢ã§ãããšè
ããããã
ããšããåŒã®ååç©ãããšãã°ãã¢ã«ã«ãªéå±
ã¢ããåã¯ã¢ã«ã«ãªåé¡éå±ã¢ãããåŒã®å¡©çŽ
åå€ãšåå¿ããããåŒã®åå¿æåã¯ããç¥ãã
ãŠããããŸããã®è£œé æ³ãããç¥ãããŠãããã
ã®åå¿ã«ãããŠäœ¿çšããå¡©çŽ åå€ã¯ãå¡©çŽ ã次äº
å¡©çŽ é žããã³å¡©çŽ ã¢ããªãã·ãããéžã°ãããåŸ
è ã®ïŒçš®ã®å¡©çŽ åå€ã¯ãã¢ã«ã«ãªéå±æ¬¡äºå¡©çŽ é ž
å¡©ãŸãã¯ã¢ã«ã«ãªåé¡éå±æ¬¡äºå¡©çŽ ç£å¡©ãã䟿å©
ã«è£œé ãããããã®è£œé ã®è©³çŽ°ã¯ãåŸã®å®æœäŸã«
èšèŒãããŠãããå¡©åã¢ã³ã¢ããŠã ãåæã«çæ
ãããªãã§ããããã«ã«ãã«çœ®æã¯ããã¢ãã³ã
補é ãããšãã®ãããïŒçš®ã®å¡©çŽ åå€ã®äœ¿çšã¯ã
æ¬çºæã®ãšãã«ææãªãã€é©æ°çãªé¢ã§ãããšè
ããããã
ã¢ãã³å¡©é
žå¡©ãããšãã°ãå¡©åã¢ã³ã¢ããŠã ã
åæã«çæãããã¯ãã©ãã³ã圢æããåå¿ãã
ãšãã°ãå¡©çŽ ãšã¢ã³ã¢ãã¢ãšã®åå¿ã¯æ¬çºæã®ç¯
å²ã«å«ãŸããªãããšã¯ãæ¬çºæã®æ¹æ³ã®ç°¡åãªèª¬
æããç解ãããã§ããããäžè¬ã«ãå¡©çŽ ããã®
æ¹æ³ã«ãããŠå¡©çŽ åå€ãšããŠäœ¿çšãããšããåŒ
ã®ååç©ãšããŠã¢ã«ã«ãªéå±ã¢ãããŸãã¯ã¢ã«ã«
ãªåé¡éå±ã¢ããã䜿çšããŠãã¢ãã³å¡©é žå¡©ã®å
æçæãé²æ¢ããããšãæãŸããã
åæã«çæãããã¯ãã©ãã³ã圢æããåå¿ãã
ãšãã°ãå¡©çŽ ãšã¢ã³ã¢ãã¢ãšã®åå¿ã¯æ¬çºæã®ç¯
å²ã«å«ãŸããªãããšã¯ãæ¬çºæã®æ¹æ³ã®ç°¡åãªèª¬
æããç解ãããã§ããããäžè¬ã«ãå¡©çŽ ããã®
æ¹æ³ã«ãããŠå¡©çŽ åå€ãšããŠäœ¿çšãããšããåŒ
ã®ååç©ãšããŠã¢ã«ã«ãªéå±ã¢ãããŸãã¯ã¢ã«ã«
ãªåé¡éå±ã¢ããã䜿çšããŠãã¢ãã³å¡©é žå¡©ã®å
æçæãé²æ¢ããããšãæãŸããã
次äºå¡©çŽ é
žãŸãã¯å¡©çŽ ãšã¢ããŒããã³ãžãŒãã
ãã«ã«ãã«çœ®æã¢ãã³ãšã®åå¿ã¯ã察å¿ããã¢ã
âããã³ãžâãããã«ã«ãã«çœ®æã¯ãã©ãã³ãã
ãããåçã§çæããããããã®åãå¡©çŽ åå€ãš
ãããã«ã«ãã«çœ®æã¢ã«ã«ãªéå±ã¢ãããŸãã¯ã
ããã«ã«ãã«çœ®æã¢ã«ã«ãªåé¡éå±ã¢ãããšã®å
å¿ã¯ãå¯Ÿç §çã«ããããã«ã«ãã«çœ®æã¯ãã©ãã³
ã補é ããæå¹ãªæ¹æ³ã§ã¯ãªãããã®çç±ã¯ãäž»
ãšããŠããããã«ã«ãã«çœ®æã¢ã«ã«ãªéå±ã¢ãã
ããã³ãããã«ã«ãã«çœ®æã¢ã«ã«ãªåé¡éå±ã¢ã
ããåŸãããšãå°é£ãããšããããšã«ããããã
ãã€ãŠã次äºå¡©çŽ é žãŸãã¯å¡©çŽ ã¢ããªãã·ããã
ãããã«ã«ãã«çœ®æã¯ãã©ãã³ãæããšãããã
ãã«ã«ãã«çœ®æã¢ãã³ãšåå¿ãããããšãæãŸã
ãã
ãã«ã«ãã«çœ®æã¢ãã³ãšã®åå¿ã¯ã察å¿ããã¢ã
âããã³ãžâãããã«ã«ãã«çœ®æã¯ãã©ãã³ãã
ãããåçã§çæããããããã®åãå¡©çŽ åå€ãš
ãããã«ã«ãã«çœ®æã¢ã«ã«ãªéå±ã¢ãããŸãã¯ã
ããã«ã«ãã«çœ®æã¢ã«ã«ãªåé¡éå±ã¢ãããšã®å
å¿ã¯ãå¯Ÿç §çã«ããããã«ã«ãã«çœ®æã¯ãã©ãã³
ã補é ããæå¹ãªæ¹æ³ã§ã¯ãªãããã®çç±ã¯ãäž»
ãšããŠããããã«ã«ãã«çœ®æã¢ã«ã«ãªéå±ã¢ãã
ããã³ãããã«ã«ãã«çœ®æã¢ã«ã«ãªåé¡éå±ã¢ã
ããåŸãããšãå°é£ãããšããããšã«ããããã
ãã€ãŠã次äºå¡©çŽ é žãŸãã¯å¡©çŽ ã¢ããªãã·ããã
ãããã«ã«ãã«çœ®æã¯ãã©ãã³ãæããšãããã
ãã«ã«ãã«çœ®æã¢ãã³ãšåå¿ãããããšãæãŸã
ãã
ã¯ãã©ãã³åå¿ã«ãããŠçšããåŒããã³ã®
åå¿æåã®æ¯çã¯ãèšççã§ãªããåºãç¯å²å ã§
å€åãããåå¿ã®çè«éã¯ãïŒã¢ã«ã®åŒã®åå
ç©ããã³ïŒã¢ã«ã®åŒã®ååç©ã§ãããåå¿æ··å
ç©äžã®ãããã«ã¢ã«éå°ã®åŒã®å¡©çŽ åå€ã®ååš
ã¯ãæå©ã§ãããã
åå¿æåã®æ¯çã¯ãèšççã§ãªããåºãç¯å²å ã§
å€åãããåå¿ã®çè«éã¯ãïŒã¢ã«ã®åŒã®åå
ç©ããã³ïŒã¢ã«ã®åŒã®ååç©ã§ãããåå¿æ··å
ç©äžã®ãããã«ã¢ã«éå°ã®åŒã®å¡©çŽ åå€ã®ååš
ã¯ãæå©ã§ãããã
ã¯ãã©ãã³åå¿ã¯ã奜ãŸããã¯äžæŽ»æ§ã®éæ°Žæ§
åå¿åªè³ªäžã§å®æœãããåå¿åªè³ªå¯Ÿåå¿æåã®çž
察çæ¯çã¯ãèšççã§ã¯ãªããäžè¬ã«ãåå¿åªè³ª
ã®æ¯çã¯ãåŒããã³ã®åå¿æåã®çŽ25ãçŽ
500ééïŒ ã§ããã奜ãŸããã¯ãåå¿åªè³ªã¯çæ
ç©ã®ã¯ãã©ãã³ããã³ãåŒãç¶ãå·¥çšã«ãããŠã¯
ãã©ãã³ãšåå¿ãããã¹ã第äžã¢ãã³ãšæ··åæ§ã§
ããããæ°Žãšäžæ··åæ§ã§ãããããã«ããçæç©
ã®ã¯ãã©ãã³ãåå¿ã®å¯çç©ãšçæããããç¥ã
ãªãæ°Žãã容æã«åé¢ããããã€æ¬¡ã®å·¥çšãããª
ãã¡ã第äžããã©ãžããŠã ã¯ãã©ã€ãã®è£œé ã«ã
ããŠããã以äžåŠçããªãã§äœ¿çšã§ããããã«ã
ãã
åå¿åªè³ªäžã§å®æœãããåå¿åªè³ªå¯Ÿåå¿æåã®çž
察çæ¯çã¯ãèšççã§ã¯ãªããäžè¬ã«ãåå¿åªè³ª
ã®æ¯çã¯ãåŒããã³ã®åå¿æåã®çŽ25ãçŽ
500ééïŒ ã§ããã奜ãŸããã¯ãåå¿åªè³ªã¯çæ
ç©ã®ã¯ãã©ãã³ããã³ãåŒãç¶ãå·¥çšã«ãããŠã¯
ãã©ãã³ãšåå¿ãããã¹ã第äžã¢ãã³ãšæ··åæ§ã§
ããããæ°Žãšäžæ··åæ§ã§ãããããã«ããçæç©
ã®ã¯ãã©ãã³ãåå¿ã®å¯çç©ãšçæããããç¥ã
ãªãæ°Žãã容æã«åé¢ããããã€æ¬¡ã®å·¥çšãããª
ãã¡ã第äžããã©ãžããŠã ã¯ãã©ã€ãã®è£œé ã«ã
ããŠããã以äžåŠçããªãã§äœ¿çšã§ããããã«ã
ãã
ã¯ãã©ãã³ãçæããåå¿ã¯ãåºã枩床ç¯å²ã
ããšãã°ãâ10âã150âãã«ããããã€å€§æ°å§ã
æžå§ãŸãã¯éå§ã«ãããŠå®æœã§ããããã®åå¿ã¯
宀枩ããã³å€§æ°å§ã«ãããŠæã䟿å©ã«å®æœãã
ããåå¿ãå®çµãããšããå§åãäœäžããŠæªåå¿
ã®çºæ®æ§ç©è³ªãåå¿åšããé€å»ããã
ããšãã°ãâ10âã150âãã«ããããã€å€§æ°å§ã
æžå§ãŸãã¯éå§ã«ãããŠå®æœã§ããããã®åå¿ã¯
宀枩ããã³å€§æ°å§ã«ãããŠæã䟿å©ã«å®æœãã
ããåå¿ãå®çµãããšããå§åãäœäžããŠæªåå¿
ã®çºæ®æ§ç©è³ªãåå¿åšããé€å»ããã
åå¿ç©ã®æ·»å ã®é åºã¯èšççã§ãªããæºè¶³ãã¹
ãçµæã¯ãéæ°Žæ§ã®äžæŽ»æ§åå¿åªè³ªãå«æããå
å¿åšãžåŒã®ååç©ãå ¥ãããã®åŸå¡©çŽ åå€ãå
ããããšã«ãã€ãŠãåŸãããã
ãçµæã¯ãéæ°Žæ§ã®äžæŽ»æ§åå¿åªè³ªãå«æããå
å¿åšãžåŒã®ååç©ãå ¥ãããã®åŸå¡©çŽ åå€ãå
ããããšã«ãã€ãŠãåŸãããã
äžè¬ã«ããã®åå¿ã¯30ã60å以å
ã«å®çµããã
ãã¡ãããçšããåå¿æåã®éã¯åå¿æéã«åœ±é¿
ãåãŒããåå¿ã®é²è¡ã¯ãæ®éã®åæåšå ·ãçšã
ãŠãåå¿æåã®æ¶å€±ããã³ã¯ãã©ãã³ïŒåŒïŒã®
åºçŸãå®éããããšã«ãã€ãŠç£èŠã§ãããåå¿ã
å®çµãããšããã¯ãã©ãã³ãæ°ŽãŸãã¯æ°Žæ··åæ§å¯
çç©ãããæ®éã®æè¡ãããšãã°ãèžçããã«ã³
ããŒã·ãšã³ãåçµã«ãããããã¯æ²æ®¿å€ã®äœ¿çšã«
ãããåé¢ããããšãã§ããã
ãã¡ãããçšããåå¿æåã®éã¯åå¿æéã«åœ±é¿
ãåãŒããåå¿ã®é²è¡ã¯ãæ®éã®åæåšå ·ãçšã
ãŠãåå¿æåã®æ¶å€±ããã³ã¯ãã©ãã³ïŒåŒïŒã®
åºçŸãå®éããããšã«ãã€ãŠç£èŠã§ãããåå¿ã
å®çµãããšããã¯ãã©ãã³ãæ°ŽãŸãã¯æ°Žæ··åæ§å¯
çç©ãããæ®éã®æè¡ãããšãã°ãèžçããã«ã³
ããŒã·ãšã³ãåçµã«ãããããã¯æ²æ®¿å€ã®äœ¿çšã«
ãããåé¢ããããšãã§ããã
ãã®ããã«ããŠè£œé ããã¯ãã©ãã³ããåŒã®
第äžã¢ãã³ãšãSisler et alïŒInorganic
SynthesesïŒVol.V.91ã95ããŒãžã®æé ã«åŸãã
åå¿ãããŠåŒã®ç¬¬äžããã©ãžããŠã ã¯ãã©ã€ã
ãçæãããïŒåå¿ïŒ¢ïŒããã®åå¿ã«ãããŠãã¯
ãã©ãã³ããããã«éå°éã®ç¬¬äžã¢ãã³ãããšã
ã°ãããªã¡ãã«ã¢ãã³ãããªãšãã«ã¢ãã³ãŸãã¯
ããªãããã«ã¢ãã³äžã«ãçŽâ20âãâ40âã®æž©
床ã«ãããŠå°å ¥ãããåå¿æåãäžç·ã«æ··åãã
ã«ã€ããŠã第äžããã©ãžããŠã ã¯ãã©ã€ããçµæ¶
åãå§ãããåå¿ã¯çŽ30ã60å以å ã«å®çµããã
次ãã§ãåå¿æ··åç©ã宀枩ã«å æž©ããé©åœãªæº¶åª
ïŒããšãã°ãã±ãã·ã³ïŒã§æŽæµããŠæ®çãã第äž
ã¢ãã³ãé€å»ããéãã也ç¥ããã第äžããã©
ãžããŠã å¡©ã®åçã¯å®éçã§ããããããŠãã®å
å¿å³ã®æåã®ïŒå·¥çšã®å šåçã¯ãåŒã®ååç©ã®
éã«åºã¥ããŠãçŽ65ïŒ ä»¥äžã§ããã
第äžã¢ãã³ãšãSisler et alïŒInorganic
SynthesesïŒVol.V.91ã95ããŒãžã®æé ã«åŸãã
åå¿ãããŠåŒã®ç¬¬äžããã©ãžããŠã ã¯ãã©ã€ã
ãçæãããïŒåå¿ïŒ¢ïŒããã®åå¿ã«ãããŠãã¯
ãã©ãã³ããããã«éå°éã®ç¬¬äžã¢ãã³ãããšã
ã°ãããªã¡ãã«ã¢ãã³ãããªãšãã«ã¢ãã³ãŸãã¯
ããªãããã«ã¢ãã³äžã«ãçŽâ20âãâ40âã®æž©
床ã«ãããŠå°å ¥ãããåå¿æåãäžç·ã«æ··åãã
ã«ã€ããŠã第äžããã©ãžããŠã ã¯ãã©ã€ããçµæ¶
åãå§ãããåå¿ã¯çŽ30ã60å以å ã«å®çµããã
次ãã§ãåå¿æ··åç©ã宀枩ã«å æž©ããé©åœãªæº¶åª
ïŒããšãã°ãã±ãã·ã³ïŒã§æŽæµããŠæ®çãã第äž
ã¢ãã³ãé€å»ããéãã也ç¥ããã第äžããã©
ãžããŠã å¡©ã®åçã¯å®éçã§ããããããŠãã®å
å¿å³ã®æåã®ïŒå·¥çšã®å šåçã¯ãåŒã®ååç©ã®
éã«åºã¥ããŠãçŽ65ïŒ ä»¥äžã§ããã
第äžããã©ãžããŠã ã¯ãã©ã€ããããšãã°ãã
ãªã¡ãã«ããã©ãžããŠã ã¯ãã©ã€ããããªããã
ã«ããã©ãžããŠã ã¯ãã©ã€ããããªâïœâããã
ã«ããã©ãžããŠã ã¯ãã©ã€ãããžã¡ãã«ããšãã«
ããã©ãžããŠã ã¯ãã©ã€ãããžã¡ãã«âïœâããª
ã«ããã©ãžããŠã ã¯ãã©ã€ããã·ã¯ãããã·ã«ãž
ãšãã«ããã©ãžããŠã ã¯ãã©ã€ããããªãããã«
ã¢ãã¡ãã«ããã©ãžããŠã ã¯ãã©ã€ããããã³ã
ãªãããã«ãžã¡ãã«ããã©ãžããŠã ã¯ãã©ã€ã
ã¯ãSisler et alã®æé ãçšããŠå®¹æã«è£œé ãã
ãã
ãªã¡ãã«ããã©ãžããŠã ã¯ãã©ã€ããããªããã
ã«ããã©ãžããŠã ã¯ãã©ã€ããããªâïœâããã
ã«ããã©ãžããŠã ã¯ãã©ã€ãããžã¡ãã«ããšãã«
ããã©ãžããŠã ã¯ãã©ã€ãããžã¡ãã«âïœâããª
ã«ããã©ãžããŠã ã¯ãã©ã€ããã·ã¯ãããã·ã«ãž
ãšãã«ããã©ãžããŠã ã¯ãã©ã€ããããªãããã«
ã¢ãã¡ãã«ããã©ãžããŠã ã¯ãã©ã€ããããã³ã
ãªãããã«ãžã¡ãã«ããã©ãžããŠã ã¯ãã©ã€ã
ã¯ãSisler et alã®æé ãçšããŠå®¹æã«è£œé ãã
ãã
ã¯ãã©ãã³ããã³ç¬¬äžããã©ãžããŠã å¡©ã圢æ
ããåå¿ã¯ãå ±éã®åå¿åšå ã§æ®µéçã«ãŸãã¯å
æã«å®æœã§ããã
ããåå¿ã¯ãå ±éã®åå¿åšå ã§æ®µéçã«ãŸãã¯å
æã«å®æœã§ããã
ãã®ããã«ããŠè£œé ãã第äžããã©ãžããŠã ã¯
ãã©ã€ãããã¢ã«ã«ãªéå±ã¢ãããã¢ã«ã«ãªåé¡
éå±ã¢ããããããã«ã«ãã«çœ®æã¢ã«ã«ãªéå±ã¢
ãããŸãã¯ãããã«ã«ãã«çœ®æã¢ã«ã«ãªåé¡éå±
ã¢ãããšãéæ°Žæ§åå¿åªè³ªã®ååšäžã«ãåå¿ãã
ãŠãç¡æ°Žããã©ãžã³ãŸãã¯ãããã«ã«ãã«çœ®æã
ãã©ãžã³ã補é ããåå¿ïŒåå¿ïŒ£ïŒã¯ãæ¬çºæè
ã®åè¿°ã®ç±³åœç¹èš±åºé¡ç¬¬4286108å·äžã«è©³è¿°ãã
ãŠããã
ãã©ã€ãããã¢ã«ã«ãªéå±ã¢ãããã¢ã«ã«ãªåé¡
éå±ã¢ããããããã«ã«ãã«çœ®æã¢ã«ã«ãªéå±ã¢
ãããŸãã¯ãããã«ã«ãã«çœ®æã¢ã«ã«ãªåé¡éå±
ã¢ãããšãéæ°Žæ§åå¿åªè³ªã®ååšäžã«ãåå¿ãã
ãŠãç¡æ°Žããã©ãžã³ãŸãã¯ãããã«ã«ãã«çœ®æã
ãã©ãžã³ã補é ããåå¿ïŒåå¿ïŒ£ïŒã¯ãæ¬çºæè
ã®åè¿°ã®ç±³åœç¹èš±åºé¡ç¬¬4286108å·äžã«è©³è¿°ãã
ãŠããã
å¿
èŠã«å¿ããŠããããã«ã«ãã«çœ®æããã©ãžã³
é¡ã®æ··åç©ãããšãã°ãã¢ãã¡ãã«ããã©ãžã³ãš
ãžã¡ãã«ããã©ãžã³ãšã®æ··åç©ããæ®éã®åå¿ã«
ãããŠè£œé ãããããŠããç¥ãããæè¡ãããšã
ã°ãåçã«ããåé¢ã§ãããããã¯ã次ã®ããã«
ããŠéæã§ãããããªãã¡ãã¢ãâããã³ãžâã¡
ãã«ã¢ãã³ã®æ··åç©ãå¡©çŽ åããŠã¢ãâããã³ãž
âã¡ãã«ã¯ãã©ãã³ã®æ··åç©ã圢æãããã®åŸã
ã®æ··åç©ã第äžã¢ãã³ããã³ãã¢ã«ã«ãªéå±ã¢ã
ããã¢ã«ã«ãªåé¡éå±ã¢ããããããã«ã«ãã«çœ®
æã¢ã«ã«ãªéå±ã¢ããããŸãã¯ãããã«ã«ãã«çœ®
æã¢ã«ã«ãªåé¡éå±ã¢ãããšãé 次ã«ãåå¿ãã
ãŠãææã®çæç©ã®æ··åç©ãçæããã
é¡ã®æ··åç©ãããšãã°ãã¢ãã¡ãã«ããã©ãžã³ãš
ãžã¡ãã«ããã©ãžã³ãšã®æ··åç©ããæ®éã®åå¿ã«
ãããŠè£œé ãããããŠããç¥ãããæè¡ãããšã
ã°ãåçã«ããåé¢ã§ãããããã¯ã次ã®ããã«
ããŠéæã§ãããããªãã¡ãã¢ãâããã³ãžâã¡
ãã«ã¢ãã³ã®æ··åç©ãå¡©çŽ åããŠã¢ãâããã³ãž
âã¡ãã«ã¯ãã©ãã³ã®æ··åç©ã圢æãããã®åŸã
ã®æ··åç©ã第äžã¢ãã³ããã³ãã¢ã«ã«ãªéå±ã¢ã
ããã¢ã«ã«ãªåé¡éå±ã¢ããããããã«ã«ãã«çœ®
æã¢ã«ã«ãªéå±ã¢ããããŸãã¯ãããã«ã«ãã«çœ®
æã¢ã«ã«ãªåé¡éå±ã¢ãããšãé 次ã«ãåå¿ãã
ãŠãææã®çæç©ã®æ··åç©ãçæããã
æ¬çºæã®æ¹æ³ã¯ããããåŒã§ããããã¯ã奜ãŸ
ããã¯é£ç¶çã«å®æœã§ããã
ããã¯é£ç¶çã«å®æœã§ããã
次ã®å®æœäŸã«ãããæ¬çºæã説æããã
 ã¯ãã©ãã³ã®è£œé
å®æœäŸ ïŒ
1000ml容ã®æ°Žãžã€ã±ããä»ãäžžåºã®åå¿åšãžã
滎äžæŒæããã³æ¥ç¶ç®¡ã«ããèžçã®ããäžæ¹ã«ã»
ããããå¹çå·åŽåšãåãä»ãããå·åŽåšããã
ã©ã€ã¢ã€ã¹âã¢ã»ãã³æµŽäžã§â78âã«å·åŽããã
500ml容ã®äžžåºååšãžåãä»ããïŒå®éšå®€èŠæš¡ã§
ã®ãã®æ¹æ³ã®å®æœã«äŸ¿å©ã§ããããã«ïŒãååšãã
ãã©ããããã³ããã¡ãŒã¿ãŒãä»ããŠãåå¿åšå
ãã»ãŒ25ãã«ã®å§åã«ç¶æã§ããæ°ŽåžåŒåšãžæ¥ç¶
ãããã»ãŒïŒâã®æ°Žãäžå®æž©åºŠã®åäœè£ 眮ããå·
åŽåšãžçµãŠåŸªç°ãããã
滎äžæŒæããã³æ¥ç¶ç®¡ã«ããèžçã®ããäžæ¹ã«ã»
ããããå¹çå·åŽåšãåãä»ãããå·åŽåšããã
ã©ã€ã¢ã€ã¹âã¢ã»ãã³æµŽäžã§â78âã«å·åŽããã
500ml容ã®äžžåºååšãžåãä»ããïŒå®éšå®€èŠæš¡ã§
ã®ãã®æ¹æ³ã®å®æœã«äŸ¿å©ã§ããããã«ïŒãååšãã
ãã©ããããã³ããã¡ãŒã¿ãŒãä»ããŠãåå¿åšå
ãã»ãŒ25ãã«ã®å§åã«ç¶æã§ããæ°ŽåžåŒåšãžæ¥ç¶
ãããã»ãŒïŒâã®æ°Žãäžå®æž©åºŠã®åäœè£ 眮ããå·
åŽåšãžçµãŠåŸªç°ãããã
200mlã®ãšãã«ãšãŒãã«ãååšã«å
¥ããâ78âå·
åŽãããã»ãŒ325ïœã®æ°·ã0.48ã¢ã«ã®ã¢ãã¡ãã«
ã¢ãã³ïŒ37.2ïœã®ã¢ãã¡ãã«ã¢ãã³ã®40ïŒ æ°Žæº¶
液ãAldrich Chemical Co.ããå ¥æããïŒããã
ã³0.49ã¢ã«ã®æ¬¡äºå¡©çŽ é žãããªãŠã ïŒ375mlã®
1.325ã¢ã«ã®æ¬¡äºå¡©é žãããªãŠã 溶液ãKuemical
Co.ããå ¥æããïŒããã·ã€ã±ããä»ãåå¿åšãž
å ¥ããçã¢ã«éã®åå¿æåãæºåãããåå¿åšã
éããå§åãçŽã¡ã«25ãã«ã«äœäžãããåæã®æ°
äœã®çºçãæ¢ããšããã«ãåå¿åšã®ãžã€ã±ããå
ã埪ç°ããæ°Žã®æž©åºŠã40ã45âã«å¢å ãããã¡ã
ã«ã¯ãã©ãã³ã¯èžçååšå ã«ã»ãŒïŒæéåéãã
ãã次ãã§ååšãåé¢ãããšãŒãã«æº¶æ¶²ãã也ç¥
å€ãšããŠç¡æ°Žç¡«é žãããªã ãå«æããå¥ã®ãã©ã¹
ã³å ãžãã«ã³ãããã
åŽãããã»ãŒ325ïœã®æ°·ã0.48ã¢ã«ã®ã¢ãã¡ãã«
ã¢ãã³ïŒ37.2ïœã®ã¢ãã¡ãã«ã¢ãã³ã®40ïŒ æ°Žæº¶
液ãAldrich Chemical Co.ããå ¥æããïŒããã
ã³0.49ã¢ã«ã®æ¬¡äºå¡©çŽ é žãããªãŠã ïŒ375mlã®
1.325ã¢ã«ã®æ¬¡äºå¡©é žãããªãŠã 溶液ãKuemical
Co.ããå ¥æããïŒããã·ã€ã±ããä»ãåå¿åšãž
å ¥ããçã¢ã«éã®åå¿æåãæºåãããåå¿åšã
éããå§åãçŽã¡ã«25ãã«ã«äœäžãããåæã®æ°
äœã®çºçãæ¢ããšããã«ãåå¿åšã®ãžã€ã±ããå
ã埪ç°ããæ°Žã®æž©åºŠã40ã45âã«å¢å ãããã¡ã
ã«ã¯ãã©ãã³ã¯èžçååšå ã«ã»ãŒïŒæéåéãã
ãã次ãã§ååšãåé¢ãããšãŒãã«æº¶æ¶²ãã也ç¥
å€ãšããŠç¡æ°Žç¡«é žãããªã ãå«æããå¥ã®ãã©ã¹
ã³å ãžãã«ã³ãããã
çæç©ãã¡ãã«ã¯ãã©ãã³ã®èžçã«ãããŠãã
ãªãã®éã®æ°Žãåæã«èžçãããååšå ãžæ°·ãšã
ãŠçŸããããã»ãŒ70mlã®ãšãŒãã«ååšå ã«æ®çã
ãæ°·ãžå ãããããå®å šã«æº¶èããŠããŸããŸã§å
æž©ããããã¹ãŠã®æ°·ã溶èããåŸããšãŒãã«å±€ã
åãããç¡æ°Žç¡«é žãããªãŠã ã§ä¹Ÿç¥ãããã¡ãã«
ã¯ãã©ãã³ã®åçã¯ã68.7ïŒ ã§ãã€ãã
ãªãã®éã®æ°Žãåæã«èžçãããååšå ãžæ°·ãšã
ãŠçŸããããã»ãŒ70mlã®ãšãŒãã«ååšå ã«æ®çã
ãæ°·ãžå ãããããå®å šã«æº¶èããŠããŸããŸã§å
æž©ããããã¹ãŠã®æ°·ã溶èããåŸããšãŒãã«å±€ã
åãããç¡æ°Žç¡«é žãããªãŠã ã§ä¹Ÿç¥ãããã¡ãã«
ã¯ãã©ãã³ã®åçã¯ã68.7ïŒ ã§ãã€ãã
ãã®åå¿ã®åçããªãã³ã«ä»¥äžã®å®æœäŸïŒãïŒ
ã®åå¿ã®åçã¯ãåŒãç¶ãåå¿å·¥çšïŒåå¿ïŒ¢ïŒã«
ãããŠçæããã第äžããã©ãžããŠã å¡©ã®éãè
æ ®ããŠã決å®ãããåçã®æ±ºå®ã¯ãæç®ãå ±åã
ãå Žåã®ããã«ãã¯ãã©ãã³ã第äžããã©ãžããŠ
ã å¡©ãžå®éçã«è»¢åããããšä»®å®ãããã¯ãã©ã
ã³ã®éããã®ããã«æ±ºå®ããããšãåçã¯ã¯ãã©
ãã³ã®åœ¢æã«äœ¿çšããã¢ãã³åå¿æåã®éã«åºã¥
ããã
ã®åå¿ã®åçã¯ãåŒãç¶ãåå¿å·¥çšïŒåå¿ïŒ¢ïŒã«
ãããŠçæããã第äžããã©ãžããŠã å¡©ã®éãè
æ ®ããŠã決å®ãããåçã®æ±ºå®ã¯ãæç®ãå ±åã
ãå Žåã®ããã«ãã¯ãã©ãã³ã第äžããã©ãžããŠ
ã å¡©ãžå®éçã«è»¢åããããšä»®å®ãããã¯ãã©ã
ã³ã®éããã®ããã«æ±ºå®ããããšãåçã¯ã¯ãã©
ãã³ã®åœ¢æã«äœ¿çšããã¢ãã³åå¿æåã®éã«åºã¥
ããã
å®æœäŸ ïŒ
å®æœäŸïŒã®æé ãå埩ããããã¢ãã¡ãã«ã¢ã
ã³ã®ä»£ããã«ã0.48ã¢ã«ã®ãžã¡ãã«ã¢ãã³ïŒ54.0
ïœã®ãžã¡ãã«ã¢ãã³ã®40ïŒ ã®æ°Žæº¶æ¶²ãAldrich
Chemical Co.ããå ¥æããïŒãçšããŠããžã¡ã
ã«ã¯ãã©ãã³ã補é ããã
ã³ã®ä»£ããã«ã0.48ã¢ã«ã®ãžã¡ãã«ã¢ãã³ïŒ54.0
ïœã®ãžã¡ãã«ã¢ãã³ã®40ïŒ ã®æ°Žæº¶æ¶²ãAldrich
Chemical Co.ããå ¥æããïŒãçšããŠããžã¡ã
ã«ã¯ãã©ãã³ã補é ããã
å®æœäŸ ïŒ
100ml容ã®äžéŠåå¿åšãžãå¹çæ©æ¢°çæ¹æåšã
è¡šé¢äžã¬ã¹å ¥å£ç®¡ãèžçèžæ°æž©åºŠèšãããã³èžç
ã®ããäžæ¹ã«ã»ãããã20cmã®ã¬ã©ã¹å·åŽåšãå
ãä»ããããã®å·åŽåšãç空ã¢ããã¿ãŒãžæ¥ç¶
ãããããŠãã®ã¢ããã¿ãŒããçŽåã«ãæ²¹å 填泡
ç«åšãç¡«é žãå«æãã液äœãã©ããã第ïŒæ²¹å å¡«
泡ç«åšãããã³æåŸã«ãã©ã€ã¢ã€ã¹âã¢ã»ãã³æ²¹
ã§â78âã«å·åŽããã¬ã©ã¹ãã©ãããžæ¥ç¶ããã
ãã®ã¢ããã¿ãŒããã©ã€ã¢ã€ã¹âã¢ã»ãã³æµŽäžã§
å·åŽããå容ãã©ã¹ã³ãžåãä»ããã
è¡šé¢äžã¬ã¹å ¥å£ç®¡ãèžçèžæ°æž©åºŠèšãããã³èžç
ã®ããäžæ¹ã«ã»ãããã20cmã®ã¬ã©ã¹å·åŽåšãå
ãä»ããããã®å·åŽåšãç空ã¢ããã¿ãŒãžæ¥ç¶
ãããããŠãã®ã¢ããã¿ãŒããçŽåã«ãæ²¹å 填泡
ç«åšãç¡«é žãå«æãã液äœãã©ããã第ïŒæ²¹å å¡«
泡ç«åšãããã³æåŸã«ãã©ã€ã¢ã€ã¹âã¢ã»ãã³æ²¹
ã§â78âã«å·åŽããã¬ã©ã¹ãã©ãããžæ¥ç¶ããã
ãã®ã¢ããã¿ãŒããã©ã€ã¢ã€ã¹âã¢ã»ãã³æµŽäžã§
å·åŽããå容ãã©ã¹ã³ãžåãä»ããã
50mlã®ã±ãã·ã³äžã®10ïœã®æ¬¡äºå¡©çŽ é
žã«ã«ã·ãŠ
ã ããæ§æãããã¹ã©ãªãŒããåå¿ãã©ã¹ã³ãžå ¥
ãããçªçŽ ã¬ã¹ã®æµãäžã«é£è¡ãããã¢ãã¡ãã«
ã¢ãã³ïŒ0.1ã¢ã«ïŒããã¡ã¿ããŒã«ãå«æããæŽ
æµã³ãäžãžãã®æŽæµã³ãã®åºã®ã¬ã¹åæ£ç®¡ãçµãŠ
éå ¥ãããããŠã¬ã¹å ¥äžç®¡ãçµãŠããããŸããã
ãåå¿åšäžãžäŸçµŠããã
ã ããæ§æãããã¹ã©ãªãŒããåå¿ãã©ã¹ã³ãžå ¥
ãããçªçŽ ã¬ã¹ã®æµãäžã«é£è¡ãããã¢ãã¡ãã«
ã¢ãã³ïŒ0.1ã¢ã«ïŒããã¡ã¿ããŒã«ãå«æããæŽ
æµã³ãäžãžãã®æŽæµã³ãã®åºã®ã¬ã¹åæ£ç®¡ãçµãŠ
éå ¥ãããããŠã¬ã¹å ¥äžç®¡ãçµãŠããããŸããã
ãåå¿åšäžãžäŸçµŠããã
åå¿æ··åç©ãçŽ135âã«å ç±ãããããŠçæç©
ã®ã¡ãã«ã¯ãã©ãã³ã¯ååšãžèžçããã
ã®ã¡ãã«ã¯ãã©ãã³ã¯ååšãžèžçããã
ãã®åå¿ã®ããã«ïŒåã®å®éšãå®æœããèšèŒã
ãåå¿æž©åºŠã«ãããŠæ¬¡ã®åçãåŸãïŒ27.1ïŒ ïŒ50
âïŒïŒ49.2ïŒ ïŒ72âïŒïŒ78.2ïŒ ïŒ117âïŒã絶察枩床
ãåçïŒïŒ ïŒã®é¢æ°ãšããŠãããããããããŠã
ãŒã¿ã®çŽç·æå°èªä¹æ³ã®åæãå®æœãã0.991ã®
è£æ£ä¿æ°ãåŸãããçåŒïŒåçïŒ ïŒïŒ0.674ïŒïŒæž©
床ãïŒâ188.7ãããããã®é¢æ°ã¯ããããŠçŽç·ã§
ããããšã瀺ããããããããŠãåå¿æž©åºŠã135
âããé«ããããšãåçã¯ããã«å¢å ããã§ãã
ãã
ãåå¿æž©åºŠã«ãããŠæ¬¡ã®åçãåŸãïŒ27.1ïŒ ïŒ50
âïŒïŒ49.2ïŒ ïŒ72âïŒïŒ78.2ïŒ ïŒ117âïŒã絶察枩床
ãåçïŒïŒ ïŒã®é¢æ°ãšããŠãããããããããŠã
ãŒã¿ã®çŽç·æå°èªä¹æ³ã®åæãå®æœãã0.991ã®
è£æ£ä¿æ°ãåŸãããçåŒïŒåçïŒ ïŒïŒ0.674ïŒïŒæž©
床ãïŒâ188.7ãããããã®é¢æ°ã¯ããããŠçŽç·ã§
ããããšã瀺ããããããããŠãåå¿æž©åºŠã135
âããé«ããããšãåçã¯ããã«å¢å ããã§ãã
ãã
å®æœäŸ ïŒ
å®æœäŸïŒã®æé ãå埩ããããã¢ãã¡ãã«ã¢ã
ã³ã®ä»£ããã«ãžã¡ãã«ã¢ãã³ïŒ0.1ã¢ã«ïŒã䜿çš
ããŠããžã¡ãã«ã¯ãã©ãã³ã補é ããã
ã³ã®ä»£ããã«ãžã¡ãã«ã¢ãã³ïŒ0.1ã¢ã«ïŒã䜿çš
ããŠããžã¡ãã«ã¯ãã©ãã³ã補é ããã
ãã®åå¿ã®ããã«ïŒåã®å®éšãå®æœããèšèŒã
ã枩床ã«ãããŠæ¬¡ã®åçãåŸãïŒ28.3ïŒ ïŒ52
âïŒïŒ49.8ïŒ ïŒ72âïŒïŒ79ïŒ ïŒ117âïŒã絶察枩床ã
åçïŒïŒ ïŒã®é¢æ°ãšããŠãããããããããŠçŽç·
æå°èªä¹æ³ã®åæãå®æœããè£æ£ä¿æ°ãåŸãã
ãçåŒïŒåçïŒ ïŒïŒ0.674ïŒïŒæž©åºŠãïŒâ188.7ããã
ãã®é¢æ°ã¯åã³ããããŠçŽç·ã§ããã
ã枩床ã«ãããŠæ¬¡ã®åçãåŸãïŒ28.3ïŒ ïŒ52
âïŒïŒ49.8ïŒ ïŒ72âïŒïŒ79ïŒ ïŒ117âïŒã絶察枩床ã
åçïŒïŒ ïŒã®é¢æ°ãšããŠãããããããããŠçŽç·
æå°èªä¹æ³ã®åæãå®æœããè£æ£ä¿æ°ãåŸãã
ãçåŒïŒåçïŒ ïŒïŒ0.674ïŒïŒæž©åºŠãïŒâ188.7ããã
ãã®é¢æ°ã¯åã³ããããŠçŽç·ã§ããã
ããããããã®åå¿ã®æž©åºŠãäžæãããšãåç
ãå¢å ããããšãæåŸ ãããã
ãå¢å ããããšãæåŸ ãããã
å®æœäŸïŒããã³ïŒã®å¡©çŽ åå€ã¯æ¬¡äºå¡©çŽ é
žã«ã«
ã·ãŠã èªäœã§ãªãã次äºå¡©çŽ é žã«ã«ã·ãŠã ãšã¡ã¿
ããŒã«ãšã®åå¿ã«ããçæãã次äºå¡©çŽ é žã§ã
ããããã¯æŽæµã³ãäžãééãããšããã¢ãã³ã«
ããåžåããããããæå³ã«ãããŠã次äºå¡©çŽ é ž
ã«ã«ã·ãŠã ã¯ã¡ã¿ããŒã«ã«ããã掻æ§åãããã
ãã®åå¿ã«å¿ èŠãªå¡©çŽ åå€ã解æŸããããã®åå¿
ã®å¯çç©ã¯ã«ã«ã·ãŠã ã¡ãã©ãŒãã§ããã次äºå¡©
çŽ é žã¯ã¢ãã¡ãã«ã¢ãã³ãŸãã¯ãžã¡ãã«ã¢ãã³ã
å¡©çŽ åããå Žåã«å¿ããŠã察å¿ããã¯ãã©ãã³ã
ãã³æ°Žã圢æããããã®ããã«ããŠåœ¢æããæ°Ž
ã¯ãåå¿æ··åç©ããã次äºå¡©çŽ é žã«ã«ã·ãŠã ãšç¬
éçã«åå¿ããŠæ°Žé žåã«ã«ã·ãŠã ã圢æããããš
ã«ãã€ãŠå¹æçã«é€å»ããããã®æ°Žé žåã«ã«ã·ãŠ
ã ã¯åå¿æ··åç©ãã容æã«é€å»ãããããã®ãã
ã«ããŠãå®è³ªçã«ç¡æ°Žã®çœ®æã¯ãã©ãã³ããæ¬çº
æã«åŸããã以äžã®åå¿ã®ããã«åŸããããä»ã®
äœçŽã¢ã«ã³ãŒã«ãŸãã¯æ°Žããã¡ã¿ããŒã«ã®ä»£ãã
ã«æŽæµã³ãäžã§äœ¿çšããŠåæ§ãªçµæãåŸãããšã
ã§ããã
ã·ãŠã èªäœã§ãªãã次äºå¡©çŽ é žã«ã«ã·ãŠã ãšã¡ã¿
ããŒã«ãšã®åå¿ã«ããçæãã次äºå¡©çŽ é žã§ã
ããããã¯æŽæµã³ãäžãééãããšããã¢ãã³ã«
ããåžåããããããæå³ã«ãããŠã次äºå¡©çŽ é ž
ã«ã«ã·ãŠã ã¯ã¡ã¿ããŒã«ã«ããã掻æ§åãããã
ãã®åå¿ã«å¿ èŠãªå¡©çŽ åå€ã解æŸããããã®åå¿
ã®å¯çç©ã¯ã«ã«ã·ãŠã ã¡ãã©ãŒãã§ããã次äºå¡©
çŽ é žã¯ã¢ãã¡ãã«ã¢ãã³ãŸãã¯ãžã¡ãã«ã¢ãã³ã
å¡©çŽ åããå Žåã«å¿ããŠã察å¿ããã¯ãã©ãã³ã
ãã³æ°Žã圢æããããã®ããã«ããŠåœ¢æããæ°Ž
ã¯ãåå¿æ··åç©ããã次äºå¡©çŽ é žã«ã«ã·ãŠã ãšç¬
éçã«åå¿ããŠæ°Žé žåã«ã«ã·ãŠã ã圢æããããš
ã«ãã€ãŠå¹æçã«é€å»ããããã®æ°Žé žåã«ã«ã·ãŠ
ã ã¯åå¿æ··åç©ãã容æã«é€å»ãããããã®ãã
ã«ããŠãå®è³ªçã«ç¡æ°Žã®çœ®æã¯ãã©ãã³ããæ¬çº
æã«åŸããã以äžã®åå¿ã®ããã«åŸããããä»ã®
äœçŽã¢ã«ã³ãŒã«ãŸãã¯æ°Žããã¡ã¿ããŒã«ã®ä»£ãã
ã«æŽæµã³ãäžã§äœ¿çšããŠåæ§ãªçµæãåŸãããšã
ã§ããã
å®æœäŸ ïŒ
次äºå¡©çŽ é
žã«ã«ã·ãŠã ãšã¢ãã¡ãã«ã¢ãã³ãšã
çŽæ¥åå¿ãããããšã«ãããããªãã¡ã次äºå¡©çŽ
é žã«ã«ã·ãŠã ãäœçŽã¢ã«ã³ãŒã«ãŸãã¯æ°Žã§äºååŠ
çããªãã§ãã¡ãã«ã¯ãã©ãã³ã補é ããè©Šã¿ã
ãããïŒâã25âãŸãã¯50âã®åå¿æž©åºŠã«ãã
ãŠãã¡ãã«ã¯ãã©ãã³ã¯æ€åºãããªãã€ãã
çŽæ¥åå¿ãããããšã«ãããããªãã¡ã次äºå¡©çŽ
é žã«ã«ã·ãŠã ãäœçŽã¢ã«ã³ãŒã«ãŸãã¯æ°Žã§äºååŠ
çããªãã§ãã¡ãã«ã¯ãã©ãã³ã補é ããè©Šã¿ã
ãããïŒâã25âãŸãã¯50âã®åå¿æž©åºŠã«ãã
ãŠãã¡ãã«ã¯ãã©ãã³ã¯æ€åºãããªãã€ãã
å®æœäŸïŒãïŒããã³ïŒããäžç·ã«èæ
®ãããšã
å¡©çŽ åå€ãšããŠæ¬¡äºå¡©çŽ é žã圢æããããã®äºé
å¡©çŽ é žã«ã«ã·ãŠã ã®äºååŠçã®å®çšæ§ã蚌æãã
ãã
å¡©çŽ åå€ãšããŠæ¬¡äºå¡©çŽ é žã圢æããããã®äºé
å¡©çŽ é žã«ã«ã·ãŠã ã®äºååŠçã®å®çšæ§ã蚌æãã
ãã
å®æœäŸ ïŒ
éæµå·åŽåšããã³ïŒå¯Ÿã®ã¬ã¹å
¥å£ç®¡ãåããäžž
åºåå¿åšã«ã次äºå¡©çŽ é žãããªãŠã ã®15ïŒ æ°Žæº¶æ¶²
ã®100mlãäŸçµŠãããå·åŽåšãåå¡©åççŽ ãå«æ
ãã圢管ãžæ¥ç¶ããããã®ïŒŽåœ¢ç®¡ã¯ãå¹çã¬ã¹
åæ£ç®¡ãåºéšã«æããïŒïœã®ã¬ã©ã¹å¡ãžæ¥ç¶ã
ããã±ãã·ã³äžã®ã¢ãã¡ãã«ã¢ãã³ã®10ïŒ æ··åç©
ããã®ã¬ã©ã¹å¡ãžå ¥ãããã®ã¬ã©ã¹å¡ãçæç©ã®
ã¯ãã©ãã³ãåéããããã«ååšãžæ¥ç¶ããã
åºåå¿åšã«ã次äºå¡©çŽ é žãããªãŠã ã®15ïŒ æ°Žæº¶æ¶²
ã®100mlãäŸçµŠãããå·åŽåšãåå¡©åççŽ ãå«æ
ãã圢管ãžæ¥ç¶ããããã®ïŒŽåœ¢ç®¡ã¯ãå¹çã¬ã¹
åæ£ç®¡ãåºéšã«æããïŒïœã®ã¬ã©ã¹å¡ãžæ¥ç¶ã
ããã±ãã·ã³äžã®ã¢ãã¡ãã«ã¢ãã³ã®10ïŒ æ··åç©
ããã®ã¬ã©ã¹å¡ãžå ¥ãããã®ã¬ã©ã¹å¡ãçæç©ã®
ã¯ãã©ãã³ãåéããããã«ååšãžæ¥ç¶ããã
äºé
žåççŽ ãšçªçŽ ããã¬ã¹å
¥å£ç®¡ãéããŠäžžåº
åå¿åšãžå¥ã ã«å°å ¥ãããäºé žåççŽ ã¯æ¬¡äºå¡©çŽ
é žãããªãŠã ãšåå¿ããŠãå¡©çŽ åå€ãšããŠCl2O
ã圢æãããCl2Oã圢管å ã®åå¡©åççŽ ã«ã
ãè£è¶³ãã次ãã§ã¬ã¹åæ£ç®¡ã«ééãããã¬ã©ã¹
å¡å ã®ã±ãã·ã³äžã®ã¢ãã¡ãã«ã¢ãã³ã®æº¶æ¶²äžã«
å ¥ãããå¡å šäœãå ç±ç®¡ã§ãããã溶液ã®æž©åºŠã
ãããã«äžãããæž©ããã¡ãã«ã¯ãã©ãã³ã¯å¡ã®
äžéšãéããŠçºçããååšå ã«éãããã¡ãã«ã¯
ãã©ãã³ã¯37.2ïŒ ã§ãã€ãã
åå¿åšãžå¥ã ã«å°å ¥ãããäºé žåççŽ ã¯æ¬¡äºå¡©çŽ
é žãããªãŠã ãšåå¿ããŠãå¡©çŽ åå€ãšããŠCl2O
ã圢æãããCl2Oã圢管å ã®åå¡©åççŽ ã«ã
ãè£è¶³ãã次ãã§ã¬ã¹åæ£ç®¡ã«ééãããã¬ã©ã¹
å¡å ã®ã±ãã·ã³äžã®ã¢ãã¡ãã«ã¢ãã³ã®æº¶æ¶²äžã«
å ¥ãããå¡å šäœãå ç±ç®¡ã§ãããã溶液ã®æž©åºŠã
ãããã«äžãããæž©ããã¡ãã«ã¯ãã©ãã³ã¯å¡ã®
äžéšãéããŠçºçããååšå ã«éãããã¡ãã«ã¯
ãã©ãã³ã¯37.2ïŒ ã§ãã€ãã
å®æœäŸ ïŒ
å®æœäŸïŒã®æé ãå埩ããããã¢ãã¡ãã«ã¢ã
ãã®ä»£ããã«ãžã¡ãã«ã¢ãã³ã䜿çšããããšã«ã
ãããžã¡ãã«ã¯ãã©ãã³ã補é ããããžã¡ãã«ã¯
ãã©ãã³ã®åçã¯ã36.6ïŒ ã§ãã€ãã
ãã®ä»£ããã«ãžã¡ãã«ã¢ãã³ã䜿çšããããšã«ã
ãããžã¡ãã«ã¯ãã©ãã³ã補é ããããžã¡ãã«ã¯
ãã©ãã³ã®åçã¯ã36.6ïŒ ã§ãã€ãã
å®æœäŸïŒããã³ïŒã«ããã第äžããã³ç¬¬äºã¢ã
ã³ã®å¡©çŽ åã¯å¯Ÿå¿ããã¯ãã©ãã³ãæ°Žã§äžç·ã«ç
æããããæ°Žã¯åå¿æ··åç©ãããååšãååã«äœ
ã枩床ã«ç¶æããŠãæ°Žãéããããã«ã€ããŠãã
ããåçµããããšã«ããã容æã«é€å»ããã次ã
ã§ææçæç©ãåé¢ãããå¥æ³ãšããŠãææçæ
ç©ã¯ããããšæ··åæ§ã§ããããäžã®å®æœäŸïŒã«ã
ããããã«ãæ°Žãšäžæ··åæ§ã§ãã溶åªäžã«ãéã
ãããšãã§ããããããã®å Žåã«ãããŠããå®è³ª
çã«ç¡æ°Žã®çœ®æã¯ãã©ãã³ã¯ãæ¬çºæã«ãããã®
åŸã®åå¿ã®ããã«åŸãããã
ã³ã®å¡©çŽ åã¯å¯Ÿå¿ããã¯ãã©ãã³ãæ°Žã§äžç·ã«ç
æããããæ°Žã¯åå¿æ··åç©ãããååšãååã«äœ
ã枩床ã«ç¶æããŠãæ°Žãéããããã«ã€ããŠãã
ããåçµããããšã«ããã容æã«é€å»ããã次ã
ã§ææçæç©ãåé¢ãããå¥æ³ãšããŠãææçæ
ç©ã¯ããããšæ··åæ§ã§ããããäžã®å®æœäŸïŒã«ã
ããããã«ãæ°Žãšäžæ··åæ§ã§ãã溶åªäžã«ãéã
ãããšãã§ããããããã®å Žåã«ãããŠããå®è³ª
çã«ç¡æ°Žã®çœ®æã¯ãã©ãã³ã¯ãæ¬çºæã«ãããã®
åŸã®åå¿ã®ããã«åŸãããã
å®æœäŸ ïŒ
äžã®å®æœäŸïŒã®æé ã«åŸããã¢ã³ã¢ãã¢ïŒ0.1
ã¢ã«ïŒãšå¡©çŽ ã¢ããªãã·ããšãåå¿ãããããšã«
ãããã¯ãã©ãã³ClNH2ã補é ãããåå¿æž©åºŠ
ã¯53âã§ãã€ããã¯ãã©ãã³ã®åçã¯ã27.2ïŒ ã§
ãã€ãã
ã¢ã«ïŒãšå¡©çŽ ã¢ããªãã·ããšãåå¿ãããããšã«
ãããã¯ãã©ãã³ClNH2ã補é ãããåå¿æž©åºŠ
ã¯53âã§ãã€ããã¯ãã©ãã³ã®åçã¯ã27.2ïŒ ã§
ãã€ãã
 第äžããã©ãžããŠã ã¯ãã©ã€ãã®è£œé
ïŒ æ®µéç補é
å®æœäŸ ïŒ
100mlã®ä¹Ÿç¥ãšãã«ãšãŒãã«äžã®57mlã®ããªã
ããã«ã¢ãã³ã®å·æº¶æ¶²ããå®æœäŸïŒã«ãããŠè£œé
ãããšãã«ãšãŒãã«äžã®ã¡ãã«ã¯ãã©ãã³ã®æº¶æ¶²
ãå ããã
ããã«ã¢ãã³ã®å·æº¶æ¶²ããå®æœäŸïŒã«ãããŠè£œé
ãããšãã«ãšãŒãã«äžã®ã¡ãã«ã¯ãã©ãã³ã®æº¶æ¶²
ãå ããã
ãã®æ··åç©ãã第äžããã©ãžããŠã å¡©ã®çµæ¶å
ãå®çµããããã«èŠãããŸã§ãçŽâ20âã«ç¶æã
ãã次ãã§ããšãŒãã«ã®äœç©ãå®è³ªçã«æžå°ã
ãŠããã以äžã®çµæ¶åãä¿é²ãããéããã³æž
å§ä¹Ÿç¥åŸã也ç¥ããªãããã«ã¢ãã¡ãã«ããã©ãž
ããŠã ã¯ãã©ã€ãã®åçã¯ãã¡ãã«ã¯ãã©ãã³ã
補é ããããã«äœ¿çšããã¢ãã¡ãã«ã¢ãã³ã®éã«
åºã¥ããŠãã»ãŒ68.7ïŒ ïŒ15åã®å®éšã®å¹³åãšããŠ
決å®ããïŒã§ãã€ãã
ãå®çµããããã«èŠãããŸã§ãçŽâ20âã«ç¶æã
ãã次ãã§ããšãŒãã«ã®äœç©ãå®è³ªçã«æžå°ã
ãŠããã以äžã®çµæ¶åãä¿é²ãããéããã³æž
å§ä¹Ÿç¥åŸã也ç¥ããªãããã«ã¢ãã¡ãã«ããã©ãž
ããŠã ã¯ãã©ã€ãã®åçã¯ãã¡ãã«ã¯ãã©ãã³ã
補é ããããã«äœ¿çšããã¢ãã¡ãã«ã¢ãã³ã®éã«
åºã¥ããŠãã»ãŒ68.7ïŒ ïŒ15åã®å®éšã®å¹³åãšããŠ
決å®ããïŒã§ãã€ãã
å®æœäŸ 10
å®æœäŸïŒã®æé ãå埩ããããã¯ããã¡ãã«ã¢
ãã³ã®ä»£ããã«å®æœäŸïŒã«ãããŠè£œé ãããžã¡ã
ã«ã¯ãã©ãã³ã䜿çšããŠãïŒïŒïŒïŒïŒâããªãã
ãã«ãžã¡ãã«ããã©ãžããŠã ã¯ãã©ã€ãã補é ã
ããïŒïŒïŒïŒïŒâããªãããã«ã¡ãã«ããã©ãžã
ãŠã ã¯ãã©ã€ãã®åçã¯ããžã¡ãã«ã¯ãã©ãã³ã®
補é ã«äœ¿çšãããžã¡ãã«ã¢ãã³ã®éã«åºã¥ããŠ
65.8ïŒ ïŒ16åã®å®éšã®å¹³åãšããŠæ±ºå®ããïŒã§ã
ã€ãã
ãã³ã®ä»£ããã«å®æœäŸïŒã«ãããŠè£œé ãããžã¡ã
ã«ã¯ãã©ãã³ã䜿çšããŠãïŒïŒïŒïŒïŒâããªãã
ãã«ãžã¡ãã«ããã©ãžããŠã ã¯ãã©ã€ãã補é ã
ããïŒïŒïŒïŒïŒâããªãããã«ã¡ãã«ããã©ãžã
ãŠã ã¯ãã©ã€ãã®åçã¯ããžã¡ãã«ã¯ãã©ãã³ã®
補é ã«äœ¿çšãããžã¡ãã«ã¢ãã³ã®éã«åºã¥ããŠ
65.8ïŒ ïŒ16åã®å®éšã®å¹³åãšããŠæ±ºå®ããïŒã§ã
ã€ãã
ïŒ ã¯ãã©ãã³ãçšããåæ補é
å®æœäŸ 11
ã¬ã¹åæ£ç®¡ãåºéšã«æããã¬ã¹æŽæµã³ãã«ã
100mlã«ã±ãã·ã³ã0.1ã¢ã«ã®ãœãŒãããïŒ4.0ïœïŒ
ããã³0.1ã¢ã«ã®ããªãããã«ã¢ãã³ïŒ14.4ïœïŒ
ãäŸçµŠãããçªçŽ ã§åžéãã0.1ã¢ã«ã®éã®å¡©çŽ
ã¬ã¹ïŒ7.1ïœïŒããåå¿æ··åç©äžã«åæ£ç®¡ããå°
å ¥ãããåå¿ãïŒâã«ãããŠ30ã40åéå®æœã
ãããã®åŸãåå¿æ··åç©ã®æž©åºŠã宀枩ã«ããåå¿
åšå ã®å§åãæžå°ããŠæ®çºæ§ç©è³ªãé€å»ãããå€
å°ã®å¡©åãããªãŠã ãå«åããããªãããã«ãã
ã©ãžããŠã ã¯ãã©ã€ãã®åéã¯ãåæ§ã«ããã
14.8ïœã§ãã€ãã
100mlã«ã±ãã·ã³ã0.1ã¢ã«ã®ãœãŒãããïŒ4.0ïœïŒ
ããã³0.1ã¢ã«ã®ããªãããã«ã¢ãã³ïŒ14.4ïœïŒ
ãäŸçµŠãããçªçŽ ã§åžéãã0.1ã¢ã«ã®éã®å¡©çŽ
ã¬ã¹ïŒ7.1ïœïŒããåå¿æ··åç©äžã«åæ£ç®¡ããå°
å ¥ãããåå¿ãïŒâã«ãããŠ30ã40åéå®æœã
ãããã®åŸãåå¿æ··åç©ã®æž©åºŠã宀枩ã«ããåå¿
åšå ã®å§åãæžå°ããŠæ®çºæ§ç©è³ªãé€å»ãããå€
å°ã®å¡©åãããªãŠã ãå«åããããªãããã«ãã
ã©ãžããŠã ã¯ãã©ã€ãã®åéã¯ãåæ§ã«ããã
14.8ïœã§ãã€ãã
 ç¡æ°Žããã©ãžã³ã®è£œé
å®æœäŸ 12
å®æœäŸ11ã«ãããŠè£œé ããããªãããã«ããã©
ãžããŠã ã¯ãã©ã€ããããœãŒãã¢ãããšåå¿ãã
ãŠç¡æ°Žããã©ãžã³ã補é ããã
ãžããŠã ã¯ãã©ã€ããããœãŒãã¢ãããšåå¿ãã
ãŠç¡æ°Žããã©ãžã³ã補é ããã
100ml容ã®äžéŠåå¿åšã«ãå¹çæ©æ¢°çæ¹æåšã
滎äžæŒæãè¡šé¢äžã¬ã¹å ¥å£ç®¡ãèžçèžæ°æž©åºŠèšã
ããã³èžçã®ããäžæ¹ã«ã»ãããã20cmã®ã¬ã©ã¹
å·å»åšãè£ åãããå·åŽåšããçŽåã«ãæ²¹å 泡ç«
åšãç¡«é žãå«æãã液äœãã©ããã第ïŒæ²¹å 填泡
ç«åšãããã³æåŸã«ãã©ã€ã¢ã€ã¹âã¢ã»ãã³æµŽã§
â78âã«å·åŽããã¬ã¹ãã©ãããžæ¥ç¶ããã
滎äžæŒæãè¡šé¢äžã¬ã¹å ¥å£ç®¡ãèžçèžæ°æž©åºŠèšã
ããã³èžçã®ããäžæ¹ã«ã»ãããã20cmã®ã¬ã©ã¹
å·å»åšãè£ åãããå·åŽåšããçŽåã«ãæ²¹å 泡ç«
åšãç¡«é žãå«æãã液äœãã©ããã第ïŒæ²¹å 填泡
ç«åšãããã³æåŸã«ãã©ã€ã¢ã€ã¹âã¢ã»ãã³æµŽã§
â78âã«å·åŽããã¬ã¹ãã©ãããžæ¥ç¶ããã
ãããªãŠã éå±ãšéæµãããããšã«ãã也ç¥ã
ãã50mlã®ã±ãã·ã³ïŒFisher Scientific Co.ïŒã
ããã³0.1ã¢ã«ã®ãœãŒãã¢ããïŒFisher
Scientific Co.ïŒããäžéŠåå¿åšå ã§150âã«çªçŽ
ã¬ã¹ã®ãã ãããªæµãã®ããšã«å ç±ãããã¢ã³ã¢
ãã¢ããã以äžçºçããªããªããŸã§ãå ç±ãç¶ã
ããã»ãŒ0.1ã¢ã«ã®ä¹Ÿç¥ïŒïŒïŒïŒïŒâããªããã
ã«ããã©ãžããŠã ã¯ãã©ã€ããã20mlã®ä¹Ÿç¥ã±ã
ã·ã³äžã§ã¹ã©ãªãŒåãã滎äžæŒæã«å ¥ããã
ãã50mlã®ã±ãã·ã³ïŒFisher Scientific Co.ïŒã
ããã³0.1ã¢ã«ã®ãœãŒãã¢ããïŒFisher
Scientific Co.ïŒããäžéŠåå¿åšå ã§150âã«çªçŽ
ã¬ã¹ã®ãã ãããªæµãã®ããšã«å ç±ãããã¢ã³ã¢
ãã¢ããã以äžçºçããªããªããŸã§ãå ç±ãç¶ã
ããã»ãŒ0.1ã¢ã«ã®ä¹Ÿç¥ïŒïŒïŒïŒïŒâããªããã
ã«ããã©ãžããŠã ã¯ãã©ã€ããã20mlã®ä¹Ÿç¥ã±ã
ã·ã³äžã§ã¹ã©ãªãŒåãã滎äžæŒæã«å ¥ããã
ãã®å¡©ã®ã¹ã©ãªãŒãäžéŠåå¿åšãž10åéãããŠ
å ãããçœè²èžæ°ãèªãããããããŠèžæ°ã®æž©åºŠ
ã¯å¡©ã®æ·»å ã®éã«ã»ãŒ100âã«å¢å ãããã»ãŒïŒ
ååŸãçœè²èžæ°ã®åœ¢æã¯æ¢ãã ãåå¿åšã®æž©åºŠã
ã»ãŒ165âã«äžããèžçãã»ãŒ30åéé²è¡ãããã
å ãããçœè²èžæ°ãèªãããããããŠèžæ°ã®æž©åºŠ
ã¯å¡©ã®æ·»å ã®éã«ã»ãŒ100âã«å¢å ãããã»ãŒïŒ
ååŸãçœè²èžæ°ã®åœ¢æã¯æ¢ãã ãåå¿åšã®æž©åºŠã
ã»ãŒ165âã«äžããèžçãã»ãŒ30åéé²è¡ãããã
èžçåŸãéããçåãåçå¡ã«ããèžçããçŽ
ç²ãªç¡æ°Žããã©ãžã³ãåŸããããç¡æ°Žããã©ãžã³
ã®åçã¯ãã¯ãã©ãã³ã®åœ¢æã«çšãããœãŒãã¢ã
ãã®åæéã«åºã¥ããŠ39.6ïŒ ïŒïŒåã®å®éšã®å¹³å
ãšããŠæ±ºå®ããïŒã§ãã€ãã
ç²ãªç¡æ°Žããã©ãžã³ãåŸããããç¡æ°Žããã©ãžã³
ã®åçã¯ãã¯ãã©ãã³ã®åœ¢æã«çšãããœãŒãã¢ã
ãã®åæéã«åºã¥ããŠ39.6ïŒ ïŒïŒåã®å®éšã®å¹³å
ãšããŠæ±ºå®ããïŒã§ãã€ãã
å®æœäŸ 13
å®æœäŸ12ã®æé ãå埩ããããïŒïŒïŒïŒïŒâã
ãªãããã«ããã©ãžããŠã ã¯ãã©ã€ãã®ä»£ããã«
ïŒïŒïŒïŒïŒâããªãããã«ã¡ãã«ããã©ãžããŠã
ã¯ãã©ã€ãïŒå®æœäŸïŒã«ãããããã«ããŠè£œé ã
ãïŒã䜿çšããŠãã¢ãã¡ãã«ããã©ãžã³ã補é ã
ããã¢ãã¡ãã«ããã©ãžã³ã®åçã¯ãã¯ãã©ãã³
ã®åœ¢æã«äœ¿çšããã¢ãã³ã®éã«åºã¥ããŠ53.2ïŒ
ïŒ15åã®å®éšã®å¹³ååçãšããŠæ±ºå®ããïŒã§ãã€
ãã
ãªãããã«ããã©ãžããŠã ã¯ãã©ã€ãã®ä»£ããã«
ïŒïŒïŒïŒïŒâããªãããã«ã¡ãã«ããã©ãžããŠã
ã¯ãã©ã€ãïŒå®æœäŸïŒã«ãããããã«ããŠè£œé ã
ãïŒã䜿çšããŠãã¢ãã¡ãã«ããã©ãžã³ã補é ã
ããã¢ãã¡ãã«ããã©ãžã³ã®åçã¯ãã¯ãã©ãã³
ã®åœ¢æã«äœ¿çšããã¢ãã³ã®éã«åºã¥ããŠ53.2ïŒ
ïŒ15åã®å®éšã®å¹³ååçãšããŠæ±ºå®ããïŒã§ãã€
ãã
å®æœäŸ 14
å®æœäŸ12ã®æé ã«åŸãããïŒïŒïŒïŒïŒâããªã
ããã«ããã©ãžããŠã ã¯ãã©ã€ãã®ä»£ããã«ïŒïŒ
ïŒïŒïŒâããªãããã«ãžã¡ãã«ããã©ãžããŠã ã¯
ãã©ã€ãïŒå®æœäŸ10ã«ãããããã«ããŠè£œé ã
ãïŒã䜿çšããŠãUDMHã補é ãããUDMHã®
åçã¯ãã¯ãã©ãã³ã®åœ¢æã«çšããã¢ãã³ã®éã«
åºã¥ããŠ56.9ïŒ ïŒ16åã®å®éšã®å¹³åãšããŠæ±ºå®ã
ãïŒã§ãã€ãã
ããã«ããã©ãžããŠã ã¯ãã©ã€ãã®ä»£ããã«ïŒïŒ
ïŒïŒïŒâããªãããã«ãžã¡ãã«ããã©ãžããŠã ã¯
ãã©ã€ãïŒå®æœäŸ10ã«ãããããã«ããŠè£œé ã
ãïŒã䜿çšããŠãUDMHã補é ãããUDMHã®
åçã¯ãã¯ãã©ãã³ã®åœ¢æã«çšããã¢ãã³ã®éã«
åºã¥ããŠ56.9ïŒ ïŒ16åã®å®éšã®å¹³åãšããŠæ±ºå®ã
ãïŒã§ãã€ãã
å®æœäŸ12ã14ã«ãããŠè£œé ããããã©ãžã³ãã
ã³ãããã«ã«ãã³çœ®æããã©ãžã³ã¯ç¡æ°Žçæç©ãš
ããŠå®¹æã«ååãããèžçã¯å è¡æè¡ã®æ¹æ³ã«ã
ããŠèŠæ±ããããããããªãå°ãªãã€ãã
ã³ãããã«ã«ãã³çœ®æããã©ãžã³ã¯ç¡æ°Žçæç©ãš
ããŠå®¹æã«ååãããèžçã¯å è¡æè¡ã®æ¹æ³ã«ã
ããŠèŠæ±ããããããããªãå°ãªãã€ãã
å®æœäŸ11ã12ããã³13ã«ãããŠè£œé ãããçæ
ç©ã¯ã沞ç¹ããã³å¯åºŠã®æž¬å®ã«ããåå®ãã枬å®
å€ã¯ç¡æ°Žããã©ãžã³ïŒb.p.113.8âïŒd.1.004ïŒãã¡
ãã«ããã©ãžã³ïŒb.p.87.5âïŒd.0.874ïŒãããã³
UDMHïŒb.p.63.9âïŒd.0.791ïŒãã«å¯æ¥ã«è¿äŒŒã
ãã
ç©ã¯ã沞ç¹ããã³å¯åºŠã®æž¬å®ã«ããåå®ãã枬å®
å€ã¯ç¡æ°Žããã©ãžã³ïŒb.p.113.8âïŒd.1.004ïŒãã¡
ãã«ããã©ãžã³ïŒb.p.87.5âïŒd.0.874ïŒãããã³
UDMHïŒb.p.63.9âïŒd.0.791ïŒãã«å¯æ¥ã«è¿äŒŒã
ãã
å®æœäŸ11ããã³12ã«èšèŒããç¡æ°Žããã©ãžã³ã
補é ããæé ã¯ãå¯çç©ãšããŠå¡©åãããªãŠã ã
ãã³ããªãããã«ã¢ãã³ãçæãããããªããã
ã«ã¢ãã³ã¯ã»ãšãã©å®éçã«ååããããããŠç¬¬
äžããã©ãžããŠã ã¯ãã©ã€ãã®åå¿ã«äŸ¿å©ã«å埪
ç°ãããŠåºçºç©è³ªã補é ããããšãã§ãããå¡©å
ãããªãŠã ã¯é»è§£ããŠããããªãŠã ãããã¯ã¢ã³
ã¢ãã¢ãšåå¿ãããŠãœãŒããããçæããããšã
ã§ããïŒå¯çç©ãšããŠ0.5ã¢ã«ã®æ°ŽçŽ ã¯çºçãã
ããã¯ååå¯èœã§ããïŒãšãå¡©çŽ ãããã¯ã¯ãã©
ãã³ã圢æããåå¿ã«äœ¿çšã§ããããšãçæãã
ããšãã§ããããã®ããã«ããŠé²è¡ãããããšã«
ããããã®æ¹æ³ã®ææ¥ã³ã¹ããææã«æžå°ã§ã
ããäºå®ãã¢ã«ã«ãªéå±ã¢ããã¯ããã®æ¹æ³ã«ã
ããŠé£ç¶çã«åçãããã®ã§ãå€å°ãè³æ¬çæ¯åº
ãšèŠãããšãã§ãããåè¿°ã®ããã«ããã®æ¹æ³ã¯
ãœãŒãã¢ãããŸãã¯ãªããŠã ã¢ãããçšããŠäŸ¿å©
ã«å®æœã§ããã
補é ããæé ã¯ãå¯çç©ãšããŠå¡©åãããªãŠã ã
ãã³ããªãããã«ã¢ãã³ãçæãããããªããã
ã«ã¢ãã³ã¯ã»ãšãã©å®éçã«ååããããããŠç¬¬
äžããã©ãžããŠã ã¯ãã©ã€ãã®åå¿ã«äŸ¿å©ã«å埪
ç°ãããŠåºçºç©è³ªã補é ããããšãã§ãããå¡©å
ãããªãŠã ã¯é»è§£ããŠããããªãŠã ãããã¯ã¢ã³
ã¢ãã¢ãšåå¿ãããŠãœãŒããããçæããããšã
ã§ããïŒå¯çç©ãšããŠ0.5ã¢ã«ã®æ°ŽçŽ ã¯çºçãã
ããã¯ååå¯èœã§ããïŒãšãå¡©çŽ ãããã¯ã¯ãã©
ãã³ã圢æããåå¿ã«äœ¿çšã§ããããšãçæãã
ããšãã§ããããã®ããã«ããŠé²è¡ãããããšã«
ããããã®æ¹æ³ã®ææ¥ã³ã¹ããææã«æžå°ã§ã
ããäºå®ãã¢ã«ã«ãªéå±ã¢ããã¯ããã®æ¹æ³ã«ã
ããŠé£ç¶çã«åçãããã®ã§ãå€å°ãè³æ¬çæ¯åº
ãšèŠãããšãã§ãããåè¿°ã®ããã«ããã®æ¹æ³ã¯
ãœãŒãã¢ãããŸãã¯ãªããŠã ã¢ãããçšããŠäŸ¿å©
ã«å®æœã§ããã
ããã«ãæ¬çºæã«ããç¡æ°Žããã©ãžã³ã®å
šäœã®
補é æ³ã¯ãæã奜éœåãªç±ãã©ã³ã¹ãæããçŽ
5.0Ã106kcalïŒæ¥ïŒå€ã¯1000KgïŒæ¥ã®ç¡æ°Žããã©
ãžã³ã®ä»®å®ãã補é ã«åºã¥ãïŒïŒäžã®åå¿ç±ã®è¡š
ã«ç€ºãããããã«ïŒãçæãããããããã»ã¹æ°Ž
èžæ°ã®çºçã«äœ¿çšã§ããã
補é æ³ã¯ãæã奜éœåãªç±ãã©ã³ã¹ãæããçŽ
5.0Ã106kcalïŒæ¥ïŒå€ã¯1000KgïŒæ¥ã®ç¡æ°Žããã©
ãžã³ã®ä»®å®ãã補é ã«åºã¥ãïŒïŒäžã®åå¿ç±ã®è¡š
ã«ç€ºãããããã«ïŒãçæãããããããã»ã¹æ°Ž
èžæ°ã®çºçã«äœ¿çšã§ããã
åå¿ç±
2NaïŒ2NH3â2NaNH2ïŒH2
1187500kcalïŒæ¥
Cl2ïŒNaNH2âNaClïŒClNH2
1317188 ã
ClNH2ïŒR3NâR3NClNH2
531250 ã
R3NClNH2ïŒNH2ïŒNaNH2
âR3NïŒNaClïŒN2H4
2045312 ã
æ°Žæ±ã®ç¡æ°Žããã©ãžã³ã®æº¶è§£ç±ã¯ãN2H4ã»
H2Oã®çºç±åå¿ã®çµæã§ããããã¡ããããã
ãªãŠã ãšå¡©çŽ ã®çæã«èŠããé»æ°ãšãã«ã®ãŒã®ã
ã®æ¹æ³ã®å šå¹çã®æ±ºå®ã«ãããŠèæ ®ããªããŠã¯ãª
ããªããããã®èŠæ±éã¯ã¢ã«ã«ãªéå±ã¢ããã®åœ¢
æäžã«çºçããæ°ŽçŽ ã®ççŒããã®åŸããããšãã«
ã®ãŒã«ããè£åããããã
H2Oã®çºç±åå¿ã®çµæã§ããããã¡ããããã
ãªãŠã ãšå¡©çŽ ã®çæã«èŠããé»æ°ãšãã«ã®ãŒã®ã
ã®æ¹æ³ã®å šå¹çã®æ±ºå®ã«ãããŠèæ ®ããªããŠã¯ãª
ããªããããã®èŠæ±éã¯ã¢ã«ã«ãªéå±ã¢ããã®åœ¢
æäžã«çºçããæ°ŽçŽ ã®ççŒããã®åŸããããšãã«
ã®ãŒã«ããè£åããããã
ãããã«ã«ãã«çœ®æããã©ãžã³ã®è£œé ã«é¢ãã
äžã®å®æœäŸã¯ã¢ã«ãã«çœ®æããã©ãžã³ã®è£œé ã«å
ããããŠããããåãäžè¬æ³ã«åŸãã¢ãªãŒã«âã
ã¢ã©ã«ãã«âããã³ã·ã¯ãã¢ã«ãã«â眮æããã©
ãžã³ã補é ã§ãããããšãã°ãã¢ããªã³ããã³ãž
ã«ã¢ãã³ãŸãã¯ã·ã¯ãããã·ã«ã¢ãã³ããæ¬çºæ
è ã®ç±³åœç¹èš±ç¬¬4286108å·ã«èšèŒãããŠãããã
ã«ã補é ããé©åœãªç¬¬äžããã©ãžããŠã å¡©ãšåå¿
ãããŠã察å¿ãããããã«ã«ãã«çœ®æçæç©ãã
ãªãã¡ãããšãã«ããã©ãžã³ãªã©ã補é ããããš
ãã§ããã
äžã®å®æœäŸã¯ã¢ã«ãã«çœ®æããã©ãžã³ã®è£œé ã«å
ããããŠããããåãäžè¬æ³ã«åŸãã¢ãªãŒã«âã
ã¢ã©ã«ãã«âããã³ã·ã¯ãã¢ã«ãã«â眮æããã©
ãžã³ã補é ã§ãããããšãã°ãã¢ããªã³ããã³ãž
ã«ã¢ãã³ãŸãã¯ã·ã¯ãããã·ã«ã¢ãã³ããæ¬çºæ
è ã®ç±³åœç¹èš±ç¬¬4286108å·ã«èšèŒãããŠãããã
ã«ã補é ããé©åœãªç¬¬äžããã©ãžããŠã å¡©ãšåå¿
ãããŠã察å¿ãããããã«ã«ãã«çœ®æçæç©ãã
ãªãã¡ãããšãã«ããã©ãžã³ãªã©ã補é ããããš
ãã§ããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ (a) åŒïŒïŒžâNR1R2ïŒåŒäžãã¯ã¢ã«ã«ãªé
å±åã¯ã¢ã«ã«ãªåé¡éå±ã§ãããR1åã³R2ã¯ã
åäžã§ãã€ãŠãç°ãªã€ãŠããŠããããæ°ŽçŽ åã³
ãããã«ã«ãã«åºããéžã°ããïŒã®ååç©ãå¡©
çŽ åå€ãšåå¿ãããŠãåŒïŒClâNR1R2ïŒåŒäžã
R1åã³R2ã¯äžã«å®çŸ©ããéãã§ããïŒã®ã¯ã
ã©ãã³ããå¡©åã¢ã³ã¢ããŠã ãåæã«çæãã
ãªãã§çæããïŒ (b) åèšã¯ãã©ãã³ãåŒïŒNR3R4R5ïŒåŒäžãR3ã
R4åã³R5ã¯ãåäžã§ãã€ãŠãç°ãªã€ãŠããŠã
ããããããã«ã«ãã«åºãè¡šãïŒã®ç¬¬ïŒã¢ãã³
ãšåå¿ãããŠåŒïŒNR1R2NR3R4R5ClïŒåŒäžã
R1ãR2ãR3ãR4åã³R5ã¯äžã«å®çŸ©ããéãã§
ããïŒã®ç¬¬ïŒããã©ãžããŠã ã¯ãã©ã€ããçæ
ããïŒãã㊠(c) åèšç¬¬ïŒããã©ãžããŠã ã¯ãã©ã€ãããåŒïŒ
ANR6R7ïŒåŒäžãã¯ã¢ã«ã«ãªéå±åã¯ã¢ã«ã«
ãªåé¡éå±ãè¡šããR6åã³R7ã¯ãåäžã§ãã€
ãŠãç°ãªã€ãŠããŠããããæ°ŽçŽ åã³ãããã«ã«
ãã«åºããéžã°ããïŒã®ååç©ãšå®è³ªçã«ç¡æ°Ž
æ¡ä»¶äžã§åå¿ãããŠææã®çæç©ãçæãã
ãïŒ å·¥çšãå«ããç¡æ°Žããã©ãžã³åã³ãããã«ã«ãã«
眮æããã©ãžã³ã®è£œé æ³ã ïŒ åèšå¡©çŽ åå€ã¯ãå¡©çŽ ã次äºå¡©çŽ é žåã³å¡©çŽ
ã¢ããªãã·ãããæã矀ããéžã°ããç¹èš±è«æ±ã®
ç¯å²ç¬¬ïŒé èšèŒã®æ¹æ³ã ïŒ å¡©çŽ ããã¢ã«ã«ãªéå±ã¢ãããšåå¿ãããŠã¯
ãã©ãã³ãçæããããããŠæçµçæç©ã¯ç¡æ°Žã
ãã©ãžã³ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æ¹
æ³ã ïŒ (a) å¡©åãããªãŠã ãé»æ°å解ããŠãããªãŠ
ã ãšå¡©çŽ ãçæããïŒ (b) åèšé»è§£ããçãããããªãŠã ãã¢ã³ã¢ãã¢
ãšåå¿ãããŠãœãŒãã¢ãããçæããïŒ (c) å·¥çš(b)ã«ãããŠçæãããœãŒãã¢ããã®ã»ãŒ
ååãåèšé»è§£ããè«ããå¡©çŽ ãšåå¿ãããŠã¯
ãã©ãã³ãšå¡©åãããªãŠã ãçæããïŒ (d) åèšã¯ãã©ãã³ã第ïŒãããã«ã«ãã«ã¢ãã³
ãšåå¿ãããŠç¬¬ïŒãããã«ã«ãã«ããã©ãžããŠ
ã ã¯ãã©ã€ããçæããïŒãã㊠(e) åèšç¬¬ïŒãããã«ã«ãã«ããã©ãžããŠã ã¯ã
ã©ã€ããå·¥çš(b)ã«ãããŠçæãããœãŒãã¢ãã
ã®æ®éãšç¡æ°Žæ¡ä»¶äžã«åå¿ãããŠã第ïŒããã
ã«ã«ãã«ã¢ãã³ãå¡©åãããªãŠã åã³ç¡æ°Žãã
ã©ãžã³ãçæãããïŒ å·¥çšãå«ãç¡æ°Žããã©ãžã³ã®è£œé æ³ã
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13930683A JPS6033205A (ja) | 1983-07-29 | 1983-07-29 | ããã©ãžã³é¡ã®æ¹è¯ããã補é æ³ |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13930683A JPS6033205A (ja) | 1983-07-29 | 1983-07-29 | ããã©ãžã³é¡ã®æ¹è¯ããã補é æ³ |
Related Child Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4126387A Division JPH0749407B2 (ja) | 1992-05-19 | 1992-05-19 | ãããã«ã«ãã«çœ®æã¯ãã©ãã³ã®è£œé æ¹æ³ |
| JP12638392A Division JPH06316404A (ja) | 1992-05-19 | 1992-05-19 | ã¯ãã©ãã³ã®è£œé æ¹æ³ |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6033205A JPS6033205A (ja) | 1985-02-20 |
| JPH0469086B2 true JPH0469086B2 (ja) | 1992-11-05 |
Family
ID=15242217
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP13930683A Granted JPS6033205A (ja) | 1983-07-29 | 1983-07-29 | ããã©ãžã³é¡ã®æ¹è¯ããã補é æ³ |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6033205A (ja) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3682105B2 (ja) * | 1995-12-28 | 2005-08-10 | æ¥æ¬ãã¡ãŒãã¹å·¥æ¥æ ªåŒäŒç€Ÿ | è±èã·ã¹ãã |
| FR2864078B1 (fr) * | 2003-12-17 | 2006-02-10 | Isochem Sa | Procede de synthese en continu de monoalkyl hydrazines a groupe alkyle fonctionnalise |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5688809A (en) * | 1979-10-17 | 1981-07-18 | Osborg Hans | Method of preparing hydrazine |
-
1983
- 1983-07-29 JP JP13930683A patent/JPS6033205A/ja active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5688809A (en) * | 1979-10-17 | 1981-07-18 | Osborg Hans | Method of preparing hydrazine |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6033205A (ja) | 1985-02-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4260561A (en) | Process for the preparation of carbonyl difluorides | |
| US3848064A (en) | Production of sulfur tetrafluoride from sulfur chlorides and fluorine | |
| EP0372635B1 (en) | Method of preparing dialkyl and diallyl dicarbonates | |
| US4267346A (en) | Process for the preparation of 1,2,4-triazole | |
| US4912268A (en) | Process for manufacture of fluoroaromatics | |
| US4789539A (en) | Process for the preparation of chloramine | |
| JPH0469086B2 (ja) | ||
| US4013758A (en) | Process for preparing hydrazines | |
| US4508695A (en) | Process for preparing hydrazines | |
| US4677227A (en) | Process for preparing hydrazines | |
| JPS5829296B2 (ja) | ã¢ãã¡ãã«ããã©ãžã³ã®è£œé æ¹æ³ | |
| EP0027645B1 (en) | Process for preparing hydrazines | |
| JPH06316404A (ja) | ã¯ãã©ãã³ã®è£œé æ¹æ³ | |
| EP0134259B1 (en) | Improved process for preparing hydrazines | |
| KR20080016944A (ko) | í ë¡ê²í ì§ìì í©ì±ë°©ë² | |
| JPH0749407B2 (ja) | ãããã«ã«ãã«çœ®æã¯ãã©ãã³ã®è£œé æ¹æ³ | |
| CA1218216A (en) | Process for preparing hydrazines | |
| AU2003288184A1 (en) | Process for the preparation of 2,6-dihalo-para-trifluoromethylaniline | |
| US3687626A (en) | Process for the production of sulfuryl fluoride | |
| US2399361A (en) | Manufacture of cyanogen | |
| KR100473333B1 (ko) | ìì륌 ì¶ë°ë¬Œì§ë¡ ì¬ì©íë íìŽëëŒì¡°ë칎볞ì믞ëìì ì¡°ë°©ë² ë° ì ì¡°ì¥ì¹ | |
| US4118570A (en) | Process for producing sodium dichloroisocyanurate | |
| US3168568A (en) | Process for producing unsymmetrical dimethylhydrazine | |
| KR101090539B1 (ko) | ìíŽë¡ìí¬-íëëŒì§ì ìììíŽëŠ ì ë첎 ë°í€í ë¡ìíŽë¡ìí¬-íëëŒì§ì ìììíŽëŠ ì ë첎ìí©ì±ë°©ë² | |
| RU2178384C1 (ru) | СпПÑПб пПлÑÑÐµÐœÐžÑ ÑÑПÑОЎПв азПÑа |