JPH0460008B2 - - Google Patents
Info
- Publication number
- JPH0460008B2 JPH0460008B2 JP2077484A JP2077484A JPH0460008B2 JP H0460008 B2 JPH0460008 B2 JP H0460008B2 JP 2077484 A JP2077484 A JP 2077484A JP 2077484 A JP2077484 A JP 2077484A JP H0460008 B2 JPH0460008 B2 JP H0460008B2
- Authority
- JP
- Japan
- Prior art keywords
- resin
- scrim cloth
- prepreg
- sheet
- roll
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004744 fabric Substances 0.000 claims description 34
- 229920005989 resin Polymers 0.000 claims description 21
- 239000011347 resin Substances 0.000 claims description 21
- 239000012783 reinforcing fiber Substances 0.000 claims description 19
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 description 17
- 239000000835 fiber Substances 0.000 description 8
- 238000010030 laminating Methods 0.000 description 6
- 238000003825 pressing Methods 0.000 description 5
- 229920000049 Carbon (fiber) Polymers 0.000 description 4
- 239000004917 carbon fiber Substances 0.000 description 4
- 229920001296 polysiloxane Polymers 0.000 description 4
- 239000003365 glass fiber Substances 0.000 description 3
- 239000011247 coating layer Substances 0.000 description 2
- 239000006082 mold release agent Substances 0.000 description 2
- 239000000123 paper Substances 0.000 description 2
- -1 polyethylene Polymers 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000007259 addition reaction Methods 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229920003235 aromatic polyamide Polymers 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 210000004177 elastic tissue Anatomy 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000011086 glassine Substances 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 239000009719 polyimide resin Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/40—Shaping or impregnating by compression not applied
- B29C70/50—Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC]
- B29C70/504—Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC] using rollers or pressure bands
- B29C70/506—Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC] using rollers or pressure bands and impregnating by melting a solid material, e.g. sheet, powder, fibres
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Composite Materials (AREA)
- Mechanical Engineering (AREA)
- Reinforced Plastic Materials (AREA)
Description
【発明の詳細な説明】
〔発明の技術分野〕
本発明はスクリムクロスを貼り合せたプリプレ
グの製造方法に関する。DETAILED DESCRIPTION OF THE INVENTION [Technical Field of the Invention] The present invention relates to a method for manufacturing a prepreg bonded with scrim cloth.
従来、スクリムクロス貼り合せプリプレグの製
造に際しては、第1図に示すように、補強繊維1
をロール2から互いに並行かつシート状に供給
し、一方、下側樹脂担持シート3をロール4から
供給して補強繊維1の下面に下側樹脂担持シート
3の樹脂面をまず重ね合せる。
Conventionally, when manufacturing scrim cloth bonded prepreg, as shown in Figure 1, reinforcing fibers 1
are fed parallel to each other in sheet form from rolls 2, and on the other hand, a lower resin-carrying sheet 3 is fed from roll 4, so that the resin surface of the lower resin-carrying sheet 3 is first superimposed on the lower surface of the reinforcing fibers 1.
次いで、上側樹脂担持シート5をロール6から
供給して、補強繊維1の上面に上側樹脂担持シー
ト5の樹脂面を重ね合せ、得られた重ね合せ体7
を加熱ロール8,8に供給し、加熱、加圧して樹
脂を補強繊維1に転移、含浸して一方向性のプリ
プレグ9を製造し、このプリプレグ9から前記上
側樹脂担持シート5を構成するシート5′を剥離
してロール10に巻取り、このシート5′が剥離
された面に、ロール14のスクリムクロス11を
重ね合せ、しかる後にスクリムクロス貼り合せロ
ール12,13で加熱、押圧していた。 Next, the upper resin-supporting sheet 5 is supplied from the roll 6, and the resin surface of the upper resin-supporting sheet 5 is superimposed on the upper surface of the reinforcing fibers 1, resulting in a superimposed body 7.
is supplied to heating rolls 8, 8, heated and pressurized to transfer and impregnate the reinforcing fibers 1 with resin to produce a unidirectional prepreg 9, and from this prepreg 9, a sheet forming the upper resin supporting sheet 5 is produced. The sheet 5' was peeled off and wound onto a roll 10, and the scrim cloth 11 of the roll 14 was superimposed on the surface from which this sheet 5' was peeled, and then heated and pressed with scrim cloth laminating rolls 12 and 13. .
しかして、かかる従来の製造方法においては、
スクリムクロス貼り合せロール12,13のう
ち、上側ロール12は単に押圧するだけで、下側
ロール13でのみ加熱するだけであつた。 However, in such conventional manufacturing methods,
Of the scrim cloth bonding rolls 12 and 13, the upper roll 12 was merely pressed, and only the lower roll 13 was heated.
即ち、スクリムクロスを貼り合せる側とは反対
側から加熱するので、下側樹脂担持シートのシー
トを介して加熱することになり、加熱効率が低下
したり、プリプレグの厚さ方向に温度むらを生ず
る欠点があつた。 That is, since heating is performed from the side opposite to the side to which the scrim cloth is bonded, heating is performed through the lower resin support sheet, which reduces heating efficiency and causes temperature unevenness in the thickness direction of the prepreg. There were flaws.
本発明の目的は、少なくともスクリムクロスを
重ね合せた側から加熱して、スクリムクロス貼り
合せ時の加熱効率を高めると共に、加熱時の温度
むらの発生を防止することにある。
An object of the present invention is to heat at least the side where the scrim cloths are stacked together to increase the heating efficiency when bonding the scrim cloths together, and to prevent the occurrence of temperature unevenness during heating.
上記目的を達成する本発明は、互いに平行かつ
シート状に配列した補強繊維の両面に、それぞ
れ、かつ少なくとも一方が樹脂担持シートである
シートを重ね合せ、その重ね合せ体を加熱、加圧
して樹脂を補強繊維に転移、含浸するプリプレグ
の製造方法において、得られたプリプレグからい
ずれか一方の前記シートを剥離し、その剥離した
面にスクリムクロスを重ね合せた後、その重ね合
せ体を少なくともスクリムクロス側から加熱しな
がら加圧して、前記プリプレグとスクリムクロス
を貼り合せることを特徴とするものである。
The present invention achieves the above object by superimposing sheets on both sides of reinforcing fibers arranged parallel to each other in a sheet shape, and at least one of which is a resin-supporting sheet. In the method for producing prepreg in which reinforcing fibers are transferred and impregnated, one of the sheets is peeled off from the obtained prepreg, a scrim cloth is superimposed on the peeled surface, and the superimposed body is covered with at least a scrim cloth. The method is characterized in that the prepreg and scrim cloth are bonded together by applying pressure while heating from the side.
本発明においては、前記第1図と同様、まず補
強繊維1に下側樹脂担持シート3の樹脂面を重ね
合せ、次いで上側樹脂担持シート5の樹脂面を重
ね合せて重ね合せ体7を得る。このとき、上下二
枚の樹脂担持シートのうちのいずれか一方を、樹
脂を担持していないシートとしてもよい。 In the present invention, as in FIG. 1, first, the resin surface of the lower resin-carrying sheet 3 is superimposed on the reinforcing fibers 1, and then the resin surface of the upper resin-carrying sheet 5 is superimposed on the reinforcing fibers 1 to obtain a superimposed body 7. At this time, either one of the upper and lower resin supporting sheets may be a sheet that does not support resin.
得られた重ね合せ体7を加熱ロール8,8で加
熱、加圧して樹脂を補強繊維1に転移、含浸させ
て、一方向性のプリプレグ9を製造する。 The obtained stacked body 7 is heated and pressurized with heating rolls 8, 8 to transfer and impregnate the reinforcing fibers 1 with resin, thereby producing a unidirectional prepreg 9.
この一方向性のプリプレグ9は、0.02〜1mm、
好ましくは0.03〜0.5mmの厚さを有し、30〜80重
量%、好ましくは50〜70重量%の補強繊維を含ん
でいる。 This unidirectional prepreg 9 has a thickness of 0.02 to 1 mm,
It preferably has a thickness of 0.03 to 0.5 mm and contains 30 to 80% by weight, preferably 50 to 70% by weight of reinforcing fibers.
ここで、本発明において使用される補強繊維
は、炭素繊維、ガラス繊維、例えばポリアラミド
繊維等の有機高弾性繊維、シリコンカーバイド繊
維、アルミナ繊維、ボロン繊維等の高強度高弾性
繊維であり、通常ではストランドの形態で使用さ
れる。 Here, the reinforcing fibers used in the present invention are carbon fibers, glass fibers, organic high-modulus fibers such as polyaramid fibers, high-strength and high-modulus fibers such as silicon carbide fibers, alumina fibers, and boron fibers. Used in the form of strands.
かかる補強繊維は、ただ一種ものを使用しても
良いし、例えば炭素繊維とガラス繊維、炭素繊維
と有機高弾性繊維のように、二種類以上の繊維
を、幅方向に交互に種類を変えて規則的に、又は
不規則に並べて使用しても良い。 Such reinforcing fibers may be of one type, or two or more types of fibers may be used, alternating in the width direction, such as carbon fibers and glass fibers, or carbon fibers and organic high-modulus fibers. They may be used in regular or irregular arrangement.
又、上側および下側樹脂担持シートのベースと
なるシートは、厚さ0.05〜0.2mm程度のクラフト
紙、ロール紙、グラシン紙等の片面又は両面に、
クレー、澱粉、ポリエチレン、ポリビニルアルコ
ール等に目止剤の塗布層を設け、更にその各塗布
層の上にシリコーン系、又は非シリコーン系の離
型剤、好ましくはポリジメチルシロキサンとポリ
ジメチルハイドロジエンシロキサンとの縮合反応
型、又は付加反応型シリコーンからなる離型剤を
塗布したものである。 The base sheets for the upper and lower resin-supporting sheets are made of kraft paper, roll paper, glassine paper, etc. with a thickness of about 0.05 to 0.2 mm, and are coated on one or both sides.
A coating layer of a sealant is provided on clay, starch, polyethylene, polyvinyl alcohol, etc., and a silicone-based or non-silicone mold release agent, preferably polydimethylsiloxane and polydimethylhydrodienesiloxane, is further applied on each coating layer. A mold release agent made of condensation reaction type silicone or addition reaction type silicone is coated.
樹脂担持シートに担持する樹脂は、エポキシ樹
脂、不飽和ポリエステル樹脂、フエノール樹脂、
ポリイミド樹脂等の熱硬化性樹脂である。 The resins supported on the resin support sheet include epoxy resin, unsaturated polyester resin, phenol resin,
It is a thermosetting resin such as polyimide resin.
これらの樹脂は、B−ステージ(半硬化状)の
状態にある。 These resins are in a B-stage (semi-cured) state.
樹脂の担持量は、最終的に得られるプリプレグ
の樹脂含有量が20〜70重量%、好ましくは30〜50
重量%になるように調整される。なお、シートへ
の樹脂の担持は、塗布により行うのが好ましい。 The amount of resin supported is such that the resin content of the final prepreg is 20 to 70% by weight, preferably 30 to 50% by weight.
Adjusted to % by weight. Note that the resin is preferably supported on the sheet by coating.
上記シートは、いわゆる離型紙としても作用
し、一方向性プリプレグにあつてその補強繊維の
配列が乱れるのを防止すると共に、プリプレグを
吸湿から保護している。 The sheet also functions as a so-called release paper, preventing the reinforcing fibers of the unidirectional prepreg from becoming disordered, and protecting the prepreg from moisture absorption.
加熱ロールは補強繊維のストランドの押し広げ
と、それに対する樹脂の含浸を行うもので、80〜
180℃、好ましくは90〜150℃に加熱される。 The heating roll is used to spread the reinforcing fiber strands and impregnate them with resin.
Heated to 180°C, preferably 90-150°C.
又、加圧力は線圧として1cm当り数キログラム
である。 Moreover, the pressing force is several kilograms per 1 cm as a linear pressure.
次に本発明においては、前記プリプレグ9か
ら、例えば上側樹脂担持シート5を構成するシー
ト5′が剥離され、ロール10に巻き取られ、次
いでシート5′が剥離された面に、ロール14か
ら供給されたスクリムクロス11を重ね合せる。 Next, in the present invention, the sheet 5' constituting the upper resin-carrying sheet 5, for example, is peeled off from the prepreg 9, wound onto the roll 10, and then fed from the roll 14 onto the surface from which the sheet 5' has been peeled off. The scrim cloths 11 that have been made are placed one on top of the other.
しかる後に、重ね合せ体をスクリムクロス貼り
合せロール12,13に供給して加熱、押圧し、
スクリムクロス貼り合せプリプレグ9′を得る。 After that, the stacked body is supplied to the scrim cloth bonding rolls 12 and 13, heated and pressed,
A scrim cloth bonded prepreg 9' is obtained.
ここで本発明においては、対をなすスクリムク
ロス貼り合せロール12,13のうち、少なくと
も上側のロール12で加熱する。 Here, in the present invention, heating is performed by at least the upper roll 12 of the pair of scrim cloth bonding rolls 12 and 13.
或いは、上側のロール12と共に下側のロール
13で加熱しても良い。又、スクリムクロス貼り
合せロールは、複数対とすることができ、この場
合にも上側のロールが少なくとも、それぞれ加熱
に用いられる。 Alternatively, the heating may be performed using the lower roll 13 together with the upper roll 12. Further, a plurality of pairs of scrim cloth bonding rolls may be used, and in this case as well, at least the upper roll is used for heating.
或いは又、第2図に示すように、スクリムクロ
ス11を予熱ロール15〜19で予熱した後に、
プリプレグ9のシートが剥離された面に重ね合
せ、二対のスクリムクロス貼り合せロール12,
13,12′,13′の上側ロール12,12′で
加熱、押圧して貼り合せることもできる。 Alternatively, as shown in FIG. 2, after preheating the scrim cloth 11 with preheating rolls 15 to 19,
The sheet of prepreg 9 is superimposed on the peeled surface, and two pairs of scrim cloth laminating rolls 12 are placed.
They can also be bonded together by heating and pressing with the upper rolls 12, 12' of 13, 12', 13'.
このように、予熱ロールで予熱した後にスクリ
ムクロスを貼り合せることにより、スクリムクロ
ス貼り合せロールにおける加熱をより容易にする
ことができる。 In this way, by laminating the scrim cloth after preheating with the preheating roll, it is possible to more easily heat the scrim cloth with the scrim cloth laminating roll.
スクリムクロス貼り合せロールで加熱、押圧し
た後に、得られたスクリムクロス貼り合せプリプ
レグはロール20に巻取られる。 After heating and pressing with a scrim cloth bonding roll, the obtained scrim cloth bonded prepreg is wound onto a roll 20.
なお、上記説明においては、上側樹脂担持シー
トを構成するシートを剥離する場合について述べ
たが、本発明はこれに限定されるものではなく、
下側樹脂担持シートを構成するシートを剥離して
も良く、この場合には対をなすスクリムクロス貼
り合せロールのうち、下側のロールで少なくとも
加熱される。 In addition, in the above description, the case where the sheet constituting the upper resin-supporting sheet is peeled off is described, but the present invention is not limited to this.
The sheet constituting the lower resin-carrying sheet may be peeled off, and in this case, it is heated at least by the lower roll of the pair of scrim cloth laminating rolls.
スクリムクロスは、上記補強繊維を平織、又は
朱子織したものであり、炭素繊維や有機高弾性繊
維からなるものである場合には、厚さ0.02〜0.15
mm、好ましくは0.02〜0.05mm、目付10〜90g/
m2、好ましくは20〜60g/m2であり、ガラス繊維
からなるものである場合には、厚さ0.01〜0.1mm、
好ましくは0.02〜0.05mm、目付10〜80g/m2であ
る。 The scrim cloth is made by plain weaving or satin weaving the above-mentioned reinforcing fibers, and if it is made of carbon fiber or organic high elastic fiber, the thickness is 0.02 to 0.15.
mm, preferably 0.02-0.05mm, weight 10-90g/
m 2 , preferably 20 to 60 g/m 2 , and in the case of glass fiber, the thickness is 0.01 to 0.1 mm,
Preferably it is 0.02 to 0.05 mm and the area weight is 10 to 80 g/m 2 .
かかるスクリムクロスは、一方向性プリプレグ
に幅方向強度を与える共と、補強繊維の配列状態
が乱れるのを防止する機能を有する。 Such scrim cloth has the function of imparting strength in the width direction to the unidirectional prepreg and preventing the alignment of reinforcing fibers from becoming disordered.
又、スクリムクロス貼り合せロールは、加熱温
度50〜130℃、好ましくは70〜120℃であり加圧力
は線圧として数Kg程度/cmである。 Further, the heating temperature of the scrim cloth laminating roll is 50 to 130°C, preferably 70 to 120°C, and the pressing force is about several kg/cm in linear pressure.
以上述べたように、本発明によれば、スクリム
クロスを重ね合せた後の、プリプレグをスクリム
クロスの側から加熱し、押圧するので、貼り合せ
るべきスクリムクロスが直ちに加熱されて少ない
熱量でスクリムクロスを貼り合せることができ、
熱効率を高めることができる。
As described above, according to the present invention, after the scrim cloths are stacked together, the prepreg is heated and pressed from the scrim cloth side, so the scrim cloths to be bonded are immediately heated, and the scrim cloths can be covered with a small amount of heat. can be pasted together,
Thermal efficiency can be increased.
又、スクリムクロスの側から直接加熱されるの
で、従来のように反対側からの加熱に比較して、
プリプレグの厚さ方向に温度差を生ずることが少
なくなり、スクリムクロス貼り合せむらの発生を
防止することができる。 Also, since the scrim cloth is heated directly from the side, compared to conventional heating from the opposite side,
Temperature differences in the thickness direction of the prepreg are less likely to occur, and uneven bonding of the scrim cloth can be prevented from occurring.
第1図は従来のスクリムクロス貼り合せプリプ
レグの製造方法を示す工程図、第2図は本発明の
実施例を示すその要部側面概要図である。
1…補強繊維、3…下側樹脂担持シート、5…
上側樹脂担持シート、5′…シート、8…加熱ロ
ール、11…スクリムクロス、12,12′13,
13′…スクリムクロス貼り合せロール。
FIG. 1 is a process diagram showing a conventional method for manufacturing a scrim cloth bonded prepreg, and FIG. 2 is a schematic side view of the main parts showing an embodiment of the present invention. 1... Reinforcing fiber, 3... Lower resin support sheet, 5...
Upper resin support sheet, 5'... Sheet, 8... Heating roll, 11... Scrim cloth, 12, 12'13,
13'...Scrim cloth pasting roll.
Claims (1)
の両面に、それぞれ、かつ少なくとも一方が樹脂
担持シートであるシートを重ね合せ、その重ね合
せ体を加熱、加圧して樹脂を補強繊維に転移、含
浸するプリプレグの製造方法において、得られた
プリプレグから、いずれか一方の前記シートを剥
離し、その剥離面にスクリムクロスを重ね合せた
後、その重ね合せ体を少なくともスクリムクロス
側から加熱しながら加圧して前記プリプレグとス
クリムクロスを貼り合せることを特徴とするスク
リムクロス貼り合せプリプレグの製造方法。1 Layer sheets on both sides of the reinforcing fibers arranged parallel to each other in a sheet shape, and at least one of them is a resin-supporting sheet, and heat and pressurize the stacked body to transfer and impregnate the reinforcing fibers with resin. In the prepreg manufacturing method, one of the sheets is peeled off from the obtained prepreg, a scrim cloth is superimposed on the peeled surface, and the superimposed body is heated and pressed at least from the scrim cloth side. A method for manufacturing a scrim cloth bonded prepreg, which comprises bonding the prepreg and scrim cloth.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2077484A JPS60165212A (en) | 1984-02-09 | 1984-02-09 | Manufacture of scrim cloth laminated prepreg |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2077484A JPS60165212A (en) | 1984-02-09 | 1984-02-09 | Manufacture of scrim cloth laminated prepreg |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS60165212A JPS60165212A (en) | 1985-08-28 |
JPH0460008B2 true JPH0460008B2 (en) | 1992-09-24 |
Family
ID=12036502
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2077484A Granted JPS60165212A (en) | 1984-02-09 | 1984-02-09 | Manufacture of scrim cloth laminated prepreg |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS60165212A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4723270B2 (en) * | 2005-03-25 | 2011-07-13 | 東邦テナックス株式会社 | Method for forming container using flame retardant hybrid composite material |
-
1984
- 1984-02-09 JP JP2077484A patent/JPS60165212A/en active Granted
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4723270B2 (en) * | 2005-03-25 | 2011-07-13 | 東邦テナックス株式会社 | Method for forming container using flame retardant hybrid composite material |
Also Published As
Publication number | Publication date |
---|---|
JPS60165212A (en) | 1985-08-28 |
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