JPH0333485B2 - - Google Patents

Info

Publication number
JPH0333485B2
JPH0333485B2 JP57226989A JP22698982A JPH0333485B2 JP H0333485 B2 JPH0333485 B2 JP H0333485B2 JP 57226989 A JP57226989 A JP 57226989A JP 22698982 A JP22698982 A JP 22698982A JP H0333485 B2 JPH0333485 B2 JP H0333485B2
Authority
JP
Japan
Prior art keywords
sheet
resin
reinforcing fibers
tape
prepreg
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP57226989A
Other languages
Japanese (ja)
Other versions
JPS59120420A (en
Inventor
Hajime Kobayashi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toray Industries Inc
Original Assignee
Toray Industries Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toray Industries Inc filed Critical Toray Industries Inc
Priority to JP57226989A priority Critical patent/JPS59120420A/en
Publication of JPS59120420A publication Critical patent/JPS59120420A/en
Publication of JPH0333485B2 publication Critical patent/JPH0333485B2/ja
Granted legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/40Shaping or impregnating by compression not applied
    • B29C70/50Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC]
    • B29C70/504Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC] using rollers or pressure bands
    • B29C70/506Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC] using rollers or pressure bands and impregnating by melting a solid material, e.g. sheet, powder, fibres

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Composite Materials (AREA)
  • Mechanical Engineering (AREA)
  • Reinforced Plastic Materials (AREA)
  • Moulding By Coating Moulds (AREA)

Description

【発明の詳細な説明】 本発明はテープ状プリプレグの製造方法に関
し、さらに詳しくは、繊維強化プラスチツクを成
型する場合に使用するテープ状プリプレグの製造
方法に関する。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for producing a tape-like prepreg, and more particularly to a method for producing a tape-like prepreg used in molding fiber-reinforced plastics.

テープ状プリプレグは、繊維強化プラスチツク
(以下、FRPという)を成型する場合の成型素材
となるもので、たとえば管状体を成型する場合に
フイラメントワインデイング様に使われたり、プ
リプレグの自動積層機による平板の成型や、曲率
のある部分にプリプレグをレイアツプするような
場合に使用されている。
Tape-shaped prepreg is used as a molding material when molding fiber-reinforced plastics (hereinafter referred to as FRP).For example, it is used for filament winding when molding tubular bodies, or it is used as a flat plate using an automatic prepreg laminating machine. It is used for molding and laying up prepreg on curved parts.

そのようなテープ状プリプレグを製造する方法
としては、従来、特開昭52−66577号公報に記載
されているようなものが知られている。すなわ
ち、この方法は、B−ステージ状態の熱硬化性樹
脂を塗布したシートの上に、互に分離された平行
なストリツプの形で補強繊維を配列し、その上に
別のシートを重ね合わせ、加圧加熱して補強繊維
に樹脂を含浸した後いずれか一方のシートを取り
除き、その上から粘性のあるシートを重ね合わ
せ、次いでそれを剥ぎ取つて各ストリツプ間にあ
る余分な樹脂を付着除去し、もつてテープ状のプ
リプレグを製造するものである。
As a method for manufacturing such a tape-like prepreg, the method described in Japanese Patent Application Laid-Open No. 52-66577 is known. That is, this method involves arranging reinforcing fibers in the form of mutually separated parallel strips on a sheet coated with a thermosetting resin in a B-stage state, and then superimposing another sheet on top of the reinforcing fibers in the form of parallel strips separated from each other. After applying pressure and heating to impregnate the reinforcing fibers with resin, one of the sheets is removed, a viscous sheet is placed on top of it, and then it is peeled off to remove the excess resin between each strip. , to produce tape-shaped prepreg.

しかしながら、上記従来の方法は、粘性シート
を剥ぎ取る際に補強繊維の配列が乱れるばかり
か、ストリツプ間の余分の樹脂のみならず、補強
繊維に含浸されている樹脂の一部をも除去されて
しまい、樹脂含有量の一様なプリプレグが得られ
ないという欠点があつた。また、ストリツプの端
面においては、ストリツプ間の樹脂が完全に除去
されず、この部分が樹脂過多になることもある。
さらに、上記従来の方法は、加圧加熱する場合
に、各ストリツプの補強繊維の拡がりが不安定
で、補強繊維がストリツプ間に食み出したり、配
列が乱れてしまうという欠点もあつた。
However, in the conventional method described above, not only does the arrangement of the reinforcing fibers become disordered when the viscous sheet is peeled off, but also not only the excess resin between the strips but also a part of the resin impregnated in the reinforcing fibers is removed. However, there was a drawback that a prepreg with a uniform resin content could not be obtained. Furthermore, on the end faces of the strips, the resin between the strips may not be completely removed, resulting in excess resin in these areas.
Furthermore, the above-mentioned conventional method has the disadvantage that when pressurized and heated, the reinforcing fibers in each strip spread out unstablely, and the reinforcing fibers may protrude between the strips or be disarranged.

本発明の目的は、従来の方法の上記欠点を解決
し、補強繊維の配列が乱れたり、樹脂の含有量が
不均一になるのを防止することができ、均質なテ
ープ状プリプレグを得ることができる方法を提供
するにある。
The purpose of the present invention is to solve the above-mentioned drawbacks of the conventional methods, to prevent the arrangement of reinforcing fibers from being disordered and the resin content from becoming non-uniform, and to obtain a homogeneous tape-like prepreg. We are here to provide you with a possible method.

上記目的を達成するための本発明は、B−ステ
ージ状態(たとえば、「プラスチツク工業辞典」、
第107頁、1973年9月25日、株式会社工業調査会
刊)の熱硬化性樹脂を担持したシート上に、補強
繊維を互に並行かつシート状に引き揃えるととも
に、補強繊維の引揃え方向に沿つて、かつ任意の
間隔でスペーサを介在させる工程と、前記補強繊
維の上に、B−ステージ状態の熱硬化性樹脂を担
持した、または担持していないシートを重ね合わ
せ、加圧加熱して補強繊維に前記樹脂を含浸する
工程と、いずれか一方の前記シートを取り除く工
程と、前記スペーサを取り除く工程と、樹脂含浸
補強繊維を担持したシートをスペーサが介在して
いた部分でスリツトして巻き取るか、または樹脂
含浸補強繊維をシート上から剥ぎ取つて巻き取る
工程とを有するテープ状プリプレグの製造方法を
特徴とするものである。
To achieve the above object, the present invention provides a B-stage state (e.g. "Plastic Industry Dictionary",
P. 107, September 25, 1973, Published by Kogyo Kenkyukai Co., Ltd.) Reinforcing fibers are aligned parallel to each other in a sheet shape on a sheet supporting a thermosetting resin, and the reinforcing fibers are aligned in the direction of alignment. A step of interposing spacers at arbitrary intervals along the reinforcing fibers, and a sheet carrying or not carrying a thermosetting resin in a B-stage state is superimposed on the reinforcing fibers and heated under pressure. a step of impregnating the reinforcing fibers with the resin; a step of removing one of the sheets; a step of removing the spacer; and slitting the sheet supporting the resin-impregnated reinforcing fibers at the portion where the spacer was interposed. The present invention is characterized by a method for manufacturing a tape-like prepreg, which comprises a step of winding up the sheet or peeling off resin-impregnated reinforcing fibers from a sheet and winding it up.

本発明の方法をさらに詳細に説明するに、第1
図は本発明の一実施例に係る方法を実施している
様子を示す概略側面図であり、第2図および第3
図はそれぞれ上記第1図のA矢視図、B矢視図で
ある。
To explain the method of the present invention in more detail, the first
The figure is a schematic side view showing a state in which a method according to an embodiment of the present invention is carried out, and FIGS.
The figures are a view in the direction of the A arrow and a view in the direction of the B arrow in FIG. 1, respectively.

第1図において、コータ1によつてB−ステー
ジ状態の熱硬化性樹脂を塗布した帯状シート2を
連続的に走行させながら、その上に、多数のボビ
ン(第1図の例では3個)から繰り出した補強繊
維3,4,5をその繊維軸がシート2の走行方向
になるように互に並行かつシート状に引き揃え
る。このとき、補強繊維3,4,5の引揃え方向
に沿つて、かつ任意の間隔で複数本(第1図の例
では2本)のひも状スペーサ6,7を介在させ
る。この工程により、第2図に示すように、シー
ト2上に引き揃えられた補強繊維3,4,5がス
ペーサ6,7によつて隔てられて、3個の補強繊
維群8,9,10が形成されることになる。
In FIG. 1, while a belt-shaped sheet 2 coated with thermosetting resin in a B-stage state is continuously run by a coater 1, a large number of bobbins (three in the example of FIG. 1) are placed on top of the belt-shaped sheet 2. The reinforcing fibers 3, 4, and 5 fed out from the reinforcing fibers 3, 4, and 5 are aligned in parallel with each other and in a sheet shape so that their fiber axes are in the running direction of the sheet 2. At this time, a plurality of (two in the example of FIG. 1) string-like spacers 6, 7 are interposed at arbitrary intervals along the direction in which the reinforcing fibers 3, 4, 5 are aligned. Through this step, as shown in FIG. 2, the reinforcing fibers 3, 4, and 5 aligned on the sheet 2 are separated by spacers 6 and 7, and are divided into three reinforcing fiber groups 8, 9, and 10. will be formed.

上記工程において、シートに塗布する熱硬化性
樹脂は、エポキシ樹脂、不飽和ポリエステル樹
脂、ポリイミド樹脂、フエノール樹脂のようなも
ので、塗布層の厚みは、後述するもうひとつのシ
ート12に塗布される樹脂と合わせて、テープ状
プリプレグの状態における樹脂の含有量が20〜70
重量%、好ましくは20〜60重量%になるように調
整される。また、シートとしては離型紙を用いる
のが好ましい。そのような離型紙は、たとえば、
厚み0.05〜0.2mm程度のクラフト紙、ロール紙、
グラシン紙などの紙の両面に、クレー、澱粉、ポ
リエチレン、ポリビニルアルコールなどの目止め
剤の塗布層を設け、さらにその各塗布層の上にシ
リコーン系または非シリコーン系の離型剤、好ま
しくはポリジメチルシロキサンとポリジメチルハ
イドロジエンシロキサンとの縮合反応型または付
加反応型シリコーンからなる離型剤を塗布したも
のである。さらに、補強繊維は、たとえば、炭素
繊維、ガラス繊維、有機高弾性繊維(たとえば、
ポリアラミド繊維)、シリコンカーバイド繊維、
ボロン繊維、アルミナ繊維などの高強度、高弾性
繊維である。もつとも、このような補強繊維は、
ただ1種類のものを使用する必要は必ずしもな
く、各補強繊維群間で異なる補強繊維を使用して
もよいし、また同じ補強繊維群の中で、異なる補
強繊維を、規則性をもつて、または不規則に並べ
るなどして混用してもよい。また、スペーサは、
ひも状のものであるのが好ましく、紙や合成樹脂
のひもや、ナイロンなどの合成繊維のモノフイラ
メントなどを使用することができる。
In the above process, the thermosetting resin applied to the sheet is epoxy resin, unsaturated polyester resin, polyimide resin, phenol resin, etc., and the thickness of the applied layer is the same as that applied to another sheet 12, which will be described later. Together with the resin, the resin content in the tape-like prepreg is 20 to 70%.
It is adjusted to % by weight, preferably 20 to 60% by weight. Moreover, it is preferable to use release paper as the sheet. Such release paper is, for example,
Kraft paper, roll paper with a thickness of about 0.05 to 0.2 mm,
A coating layer of a filler such as clay, starch, polyethylene, or polyvinyl alcohol is provided on both sides of paper such as glassine paper, and a silicone or non-silicone mold release agent, preferably polyester, is applied on each coating layer. A mold release agent made of condensation reaction type silicone or addition reaction type silicone of dimethylsiloxane and polydimethylhydrodiene siloxane is coated. Furthermore, the reinforcing fibers may be, for example, carbon fibers, glass fibers, organic high modulus fibers (e.g.
polyaramid fiber), silicon carbide fiber,
High-strength, high-elasticity fibers such as boron fibers and alumina fibers. However, such reinforcing fibers are
It is not necessarily necessary to use only one type of reinforcing fiber, and different reinforcing fibers may be used between each reinforcing fiber group, or different reinforcing fibers may be used with regularity within the same reinforcing fiber group. Alternatively, they may be mixed by arranging them irregularly. In addition, the spacer
It is preferably in the form of a string, and strings made of paper or synthetic resin, monofilament made of synthetic fibers such as nylon, etc. can be used.

次に、補強繊維3,4,5の上に、コータ11
によつてB−ステージ状態の熱硬化性樹脂を塗布
した、上記シート2と全く同様の帯状シート12
を重ね合わせ、加熱したプレスロール13に通し
て補強繊維3,4,5を押し拡げるとともにシー
ト2,12に塗布された樹脂の含浸を行う。この
ときの加熱温度は80〜180℃、好ましくは90〜150
℃であり、また加圧力は、線圧として1cm当り数
キログラム程度でよい。
Next, the coater 11
A belt-shaped sheet 12 completely similar to the sheet 2 described above, coated with a thermosetting resin in a B-stage state by
The reinforcing fibers 3, 4, and 5 are pressed and spread through a heated press roll 13 and impregnated with the resin applied to the sheets 2 and 12. The heating temperature at this time is 80-180℃, preferably 90-150℃
℃, and the applied pressure may be about several kilograms per cm in terms of linear pressure.

上記工程において、シート12に塗布する樹脂
は、シート2に塗布したものと同じものを使用す
る。もつとも、シート12に樹脂を塗布すること
は必ずしも必要でなく、上述した離型紙のみを使
用することであつてもよい。
In the above process, the resin applied to the sheet 12 is the same as that applied to the sheet 2. However, it is not necessarily necessary to apply resin to the sheet 12, and only the above-mentioned release paper may be used.

次に、シート12を引き剥がして取り除く。こ
の場合、シート12を残し、シート2を取り除い
てもよい。
Next, the sheet 12 is peeled off and removed. In this case, sheet 12 may remain and sheet 2 may be removed.

次に、シート2上からスペーサ6,7を剥ぎ取
る。すると、第3図に示すように、シート2上
に、上述した3個の補強繊維群8,9,10に対
応して3個の樹脂含浸補強繊維群、つまり互に分
離された3個のテープ状プリプレグ14,15,
16が得られる。
Next, the spacers 6 and 7 are peeled off from the top of the sheet 2. Then, as shown in FIG. 3, three groups of resin-impregnated reinforcing fibers are placed on the sheet 2, corresponding to the three groups of reinforcing fibers 8, 9, and 10, that is, three groups of reinforcing fibers separated from each other. Tape-shaped prepreg 14, 15,
16 is obtained.

次に、スリツタ17により、上記シート2をス
ペーサ6,7が介在していた部分、つまり第3図
における点線に沿つてスリツトし、シート付テー
プ状プリプレグとしてそれぞれ別々に巻き取る。
この場合、シート2の両耳部を同時にスリツトし
て除去してもよい。また、シート2をスリツトす
ることなく、そのシート2上から3本のテープ状
プリプレグ14,15,16を剥ぎ取り、そのま
ま、または別に用意したテープ状の離型紙に載せ
換えて巻き取るようにしてもよい。また、離型紙
やエンボス加工した合成樹脂フイルムなどのシー
トを重ね合わせながら巻き取つてもよい。
Next, the sheet 2 is slit by the slitter 17 along the portion where the spacers 6 and 7 were interposed, that is, along the dotted line in FIG. 3, and each is wound up separately as a tape-like prepreg with a sheet.
In this case, both ears of the sheet 2 may be removed by slitting them at the same time. In addition, without slitting the sheet 2, the three tape-like prepregs 14, 15, and 16 are peeled off from the sheet 2, and the tape-like prepregs 14, 15, and 16 are peeled off as they are, or they are replaced with a separately prepared tape-like release paper and rolled up. Good too. Alternatively, sheets such as release paper or embossed synthetic resin film may be rolled up while being overlapped.

上記方法において、シート2および12に塗布
する樹脂をA−ステージ状態のものとし、そのA
−ステージ状態の樹脂を加圧加熱により押し拡
げ、樹脂含浸を行う工程において、またはその工
程とは別個に設けた加熱工程においてB−ステー
ジ化することも、理論的には可能である。しかし
ながら、そのようにすると、シート上への樹脂担
持が極めて困難になるばかりか、加熱加圧工程に
極めて長時間を要することにより、製造コストが
極端に高くなる。
In the above method, the resin applied to the sheets 2 and 12 is in an A-stage state, and the A-stage resin is applied to the sheets 2 and 12.
- It is also theoretically possible to B-stage the resin in the step of expanding the staged resin by pressure heating and impregnating it with the resin, or in a heating step provided separately from that step. However, in this case, not only is it extremely difficult to support the resin on the sheet, but also the heating and pressing process takes an extremely long time, resulting in extremely high manufacturing costs.

以上説明したように、本発明の方法は、B−ス
テージ状態の熱硬化性樹脂を担持したシート上
に、補強繊維の互に並行かつシート状に引き揃え
るとともに、その補強繊維の引揃え方向に沿つ
て、かつ任意の間隔でスペーサを介在させ、補強
繊維の押拡げ、樹脂含浸を行つた後に上記スペー
サを取り除くものであるからして、スペーサが上
記押拡げ、含浸工程における補強繊維の配列の乱
れを防止するばかりか、樹脂の含浸を均一に行う
ことができて、樹脂含有量のむらが極めて少ない
均質なテープ状プリプレグを得ることができる。
また、上述した従来の方法のように、粘着シート
で樹脂を付着除去することもないから、樹脂不足
を生ずるようなこともない。
As explained above, the method of the present invention involves aligning reinforcing fibers parallel to each other in a sheet-like manner on a sheet carrying a thermosetting resin in a B-stage state, and also aligning reinforcing fibers in the alignment direction of the reinforcing fibers. Spacers are interposed along the line and at arbitrary intervals, and the spacers are removed after the reinforcing fibers are expanded and impregnated with resin. Not only can disturbances be prevented, but also resin impregnation can be performed uniformly, and a homogeneous tape-like prepreg with extremely little unevenness in resin content can be obtained.
Furthermore, unlike the conventional method described above, resin is not attached and removed using an adhesive sheet, so there is no possibility of resin shortage.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は、本発明の一実施例に係る方法を実施
している様子を示す概略側面図、第2図および第
3図は、それぞれ上記第1図のA矢視図、B矢視
図である。 1,11:コータ、2,12:シート、3,
4,5:補強繊維、6,7:スペーサ、8,9,
10:補強繊維群、13:プレスロール、14,
15,16:テープ状プリプレグ、17:スリツ
タ、18,19,20:シート付テープ状プリプ
レグ。
FIG. 1 is a schematic side view showing how a method according to an embodiment of the present invention is carried out, and FIGS. 2 and 3 are views taken in the direction of arrow A and arrow B of FIG. 1, respectively. It is. 1, 11: coater, 2, 12: sheet, 3,
4, 5: reinforcing fiber, 6, 7: spacer, 8, 9,
10: reinforcing fiber group, 13: press roll, 14,
15, 16: Tape-shaped prepreg, 17: Slitter, 18, 19, 20: Tape-shaped prepreg with sheet.

Claims (1)

【特許請求の範囲】[Claims] 1 B−ステージ状態の熱硬化性樹脂を担持した
シート上に、補強繊維を互に並行かつシート状に
引き揃えるとともに、補強繊維の引揃え方向に沿
つて、かつ任意の間隔でスペーサを介在させる工
程と、前記補強繊維の上に、B−ステージ状態の
熱硬化性樹脂を担持した、または担持していない
シートを重ね合わせ、加圧加熱して補強繊維に前
記樹脂を含浸する工程と、いずれか一方の前記シ
ートを取り除く工程と、前記スペーサを取り除く
工程と、樹脂含浸補強繊維を担持したシートをス
ペーサが介在していた部分でスリツトして巻き取
るか、または樹脂含浸補強繊維をシート上から剥
ぎ取つて巻き取る工程とを有することを特徴とす
るテープ状プリプレグの製造方法。
1. On the sheet supporting the thermosetting resin in the B-stage state, reinforcing fibers are arranged parallel to each other in a sheet shape, and spacers are interposed at arbitrary intervals along the direction in which the reinforcing fibers are arranged. a step of superimposing a sheet carrying or not carrying a thermosetting resin in a B-stage state on the reinforcing fibers and impregnating the reinforcing fibers with the resin by heating under pressure; a step of removing one of the sheets; a step of removing the spacer; and slitting and winding the sheet carrying the resin-impregnated reinforcing fibers at the part where the spacer was present, or rolling the resin-impregnated reinforcing fibers from above the sheet. A method for manufacturing a tape-shaped prepreg, comprising the steps of peeling off and winding up.
JP57226989A 1982-12-27 1982-12-27 Manufacture of prepreg in form of tape Granted JPS59120420A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP57226989A JPS59120420A (en) 1982-12-27 1982-12-27 Manufacture of prepreg in form of tape

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP57226989A JPS59120420A (en) 1982-12-27 1982-12-27 Manufacture of prepreg in form of tape

Publications (2)

Publication Number Publication Date
JPS59120420A JPS59120420A (en) 1984-07-12
JPH0333485B2 true JPH0333485B2 (en) 1991-05-17

Family

ID=16853758

Family Applications (1)

Application Number Title Priority Date Filing Date
JP57226989A Granted JPS59120420A (en) 1982-12-27 1982-12-27 Manufacture of prepreg in form of tape

Country Status (1)

Country Link
JP (1) JPS59120420A (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61108756A (en) * 1984-10-30 1986-05-27 日精株式会社 Material comprising high tensile fiber
US4836016A (en) * 1985-08-10 1989-06-06 Toyota Jidosha Kabushiki Kaisha Method and apparatus for detecting abnormal state in pulse train generating sensor
JPH07115352B2 (en) * 1990-01-23 1995-12-13 東レ株式会社 Prepreg manufacturing method
FR2703699B1 (en) * 1993-04-08 1995-05-05 Rossignol Sa Method for producing a fibrous web pre-impregnated with a thermosetting resin and fibrous web thus obtained.
JP5607504B2 (en) * 2010-11-11 2014-10-15 新日本工機株式会社 Prepreg tape and tape control information setting method
JP2014121796A (en) * 2012-12-20 2014-07-03 Sanyu Rec Co Ltd Roll of prepreg, production method of the same, and production device of the same

Also Published As

Publication number Publication date
JPS59120420A (en) 1984-07-12

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