JPH044986A - Manufacture of nickel and stainless steel clad material - Google Patents
Manufacture of nickel and stainless steel clad materialInfo
- Publication number
- JPH044986A JPH044986A JP10472390A JP10472390A JPH044986A JP H044986 A JPH044986 A JP H044986A JP 10472390 A JP10472390 A JP 10472390A JP 10472390 A JP10472390 A JP 10472390A JP H044986 A JPH044986 A JP H044986A
- Authority
- JP
- Japan
- Prior art keywords
- sheet
- stainless steel
- heat treatment
- rolling
- joining
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910001220 stainless steel Inorganic materials 0.000 title claims abstract description 27
- 239000010935 stainless steel Substances 0.000 title claims abstract description 27
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 17
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims description 48
- 239000000463 material Substances 0.000 title claims description 28
- 229910052759 nickel Inorganic materials 0.000 title claims description 13
- 238000010438 heat treatment Methods 0.000 claims abstract description 40
- 238000005097 cold rolling Methods 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims description 9
- 238000005096 rolling process Methods 0.000 abstract description 36
- 238000005304 joining Methods 0.000 abstract description 11
- 230000001680 brushing effect Effects 0.000 abstract description 10
- 238000005238 degreasing Methods 0.000 abstract description 3
- 229910000831 Steel Inorganic materials 0.000 abstract 2
- 239000010959 steel Substances 0.000 abstract 2
- 238000005253 cladding Methods 0.000 description 11
- 229910000963 austenitic stainless steel Inorganic materials 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- 238000001953 recrystallisation Methods 0.000 description 4
- 238000010586 diagram Methods 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000010924 continuous production Methods 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 238000005098 hot rolling Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000007542 hardness measurement Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000005482 strain hardening Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 230000002747 voluntary effect Effects 0.000 description 1
Landscapes
- Heat Treatment Of Sheet Steel (AREA)
- Pressure Welding/Diffusion-Bonding (AREA)
- Laminated Bodies (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、ニッケル・ステンレス鋼クラッド材の製造方
法に関する。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to a method for manufacturing nickel stainless steel cladding.
（従来の技術）
従来、例えば、燃料電池用セパレート材であるニッケル
・ステンレス鋼クランド材は、溶接組み立て→熱間圧延
耐冷間圧延のシートストリップ方式で製造しているが、
かかる従来法ではＮｉ面からの酸素吸収による圧延後の
表面に疵の発生という品質上の問題および多大な費用と
期間を要し、コスト的に問題がある。また、冷間圧延接
合は接合に大きな圧延荷重圧下率を必要とし、形状不良
発生等の品質の問題、広幅材が製造不可との問題がある
。(Prior art) Conventionally, for example, nickel stainless steel crund material, which is a separate material for fuel cells, has been manufactured by a sheet strip method of welding assembly → hot rolling and cold rolling.
In this conventional method, there is a quality problem in that defects occur on the surface after rolling due to oxygen absorption from the Ni surface, and a large amount of cost and time is required, resulting in cost problems. In addition, cold rolling joining requires a large rolling load reduction rate for joining, which causes quality problems such as occurrence of shape defects, and the problem that wide materials cannot be manufactured.
特に、今日のようにニッケル・ステンレス鋼クランド材
の需要が拡大している状況下では、輻１０００ｍｍ以上
の広幅材を製造可能とするなど何らかの改善策が求めら
れている。Particularly in today's situation where the demand for nickel and stainless steel crund materials is increasing, some improvement measures are required, such as making it possible to manufacture wide materials with a radius of 1000 mm or more.
（発明が解決しようとする課題）
かくして、本発明の第一の目的は、簡便な手段でニッケ
ルシートの接合強度の改善を図ることのできるニッケル
・ステンレス鋼クラッド材の製造方法を提供することで
ある。(Problem to be Solved by the Invention) Thus, the first object of the present invention is to provide a method for manufacturing a nickel-stainless steel clad material that can improve the bonding strength of nickel sheets by a simple means. be.
本発明の別の目的は、少ない圧延荷重でもって十分な接
合強度を確保でき、もって広幅のクラッド材の製造を可
能とするニッケル・ステンレス鋼クラッド材の製造方法
を提供することである。Another object of the present invention is to provide a method for manufacturing a nickel stainless steel cladding material that can ensure sufficient bonding strength with a small rolling load, thereby making it possible to manufacture a wide cladding material.
ＣＦｊｌＭを解決するための手段）
そこで、本発明者らは、ががる目的達成のための手段を
種々検討したところ、次のような知見を得た。Means for Solving CFjlM) Therefore, the present inventors investigated various means for achieving the object of the present invention and obtained the following findings.
■予め４００℃以下の加熱および脱脂によって活性化し
た接合界面をブラッシングすると少ない圧延荷重でも接
合が強化される。■ Brushing the joint interface activated by heating below 400°C and degreasing in advance will strengthen the joint even with a small rolling load.
■ソノようにして用意されたブラッシング面を５０〜４
００℃以下に加熱することによって接合面が活性化され
、少ない圧延荷重でも接合が強化される。■50~4 brushing surfaces prepared in a similar manner.
By heating to 00° C. or lower, the joint surfaces are activated, and the joint is strengthened even with a small rolling load.
■ニッケルシートとして９００ ℃以上で焼鈍した純Ｎ
ｉシートを使用すると、例えば従来４０％以上の圧下率
で１２０トン以上の圧延荷重での熱間圧延が必要であっ
たのが、より少ない圧延荷重でもって同等の接合性が確
保される。■Pure N annealed at 900℃ or higher as a nickel sheet
When the i-sheet is used, for example, whereas conventionally hot rolling was required at a rolling reduction of 40% or more and a rolling load of 120 tons or more, equivalent bonding properties can be secured with a lower rolling load.
ここに、本発明の要旨とするところは、Ｎｉシートとス
テンレス鋼シートとの少なくとも一方の接合面を４００
℃以下に加熱してブラッシングを行ってから両者を貼り
合わせ、５０〜４００ ℃の温度で温間圧延接合を行い
、次いで後熱処理を行ってから冷間圧延および仕上げ熱
処理を行うことを特徴とするニッケル・ステンレス鋼ク
ランド材の製造方法である。Here, the gist of the present invention is that the joint surface of at least one of the Ni sheet and the stainless steel sheet is
It is characterized by heating to below ℃ and brushing, then bonding them together, performing warm rolling bonding at a temperature of 50 to 400 ℃, then performing post-heat treatment, and then cold rolling and finishing heat treatment. This is a method for manufacturing nickel stainless steel crund material.
本発明の好適態様によれば、前記Ｎ１シートとして予め
９００℃以上に加熱して焼鈍したＮｉシートを使用する
ことにより、ステンレス鋼シートへの接着強度が一層改
善され、より少ない圧延荷重でもって接合が可能となる
ことから、より広幅のクラッド材の製造が可能となる。According to a preferred embodiment of the present invention, by using a Ni sheet that has been previously heated and annealed to 900° C. or higher as the N1 sheet, the adhesive strength to the stainless steel sheet is further improved, and the bonding can be performed with less rolling load. This makes it possible to manufacture wider cladding materials.
なお、上記ステンレス鋼は特に制限されないが、好まし
くはオーステナイト系ステンレス鋼である。Note that the stainless steel is not particularly limited, but preferably is an austenitic stainless steel.
本発明にかかる製造方法は、いわゆる溶接組み立て法に
よりクラッド組立材を形成し、これを温間圧延しても、
あるいは連続シートとして二・ンケルシートおよびステ
ンレス鋼シートをイ共給しながら連続温間圧延によって
クラッド化を行うようにしてもよい。In the manufacturing method according to the present invention, even if a clad assembly material is formed by a so-called welding assembly method and then warm rolled,
Alternatively, cladding may be performed by continuous warm rolling while co-feeding a two-layer sheet and a stainless steel sheet as continuous sheets.
（作用）
次に、本発明を添付図面を参照しながらさらに具体的に
説明する。(Operation) Next, the present invention will be described in more detail with reference to the accompanying drawings.
第１図は、本発明にかかる製造方法を実施する連続製造
ラインを説明する略式１程図であり、図中、巻戻された
純Ｎｉシート１０とステンレス鋼シート１２とは誘導加
熱装置１４．１６によってそれぞれ５０〜４００℃に加
熱される。加熱された各シートは温間圧延されるに先立
ってブラッシング処理を受ける。このときのブラシ装置
２０．２０は、表面の活性化を図るとともに表面硬化層
の形成を図るものであって、その限りにおいて特定のブ
ラシ装置に限定はされないが、具体的にはワイヤブラシ
、プラスチックブラシなどが包含される０本発明の場合
、ブラッシング条件それ自体には特に制限ないが、接合
界面を活性化するとともに表面硬化層を生成させるため
には少なくとも純Ｎｉ、ステンレス鋼のブラッシング前
の硬さの１．１倍以上の条件を満足するものであること
が望ましい。FIG. 1 is a schematic diagram illustrating a continuous production line for carrying out the production method according to the present invention. 16 to 50 to 400°C, respectively. Each heated sheet is brushed prior to being warm rolled. The brush devices 20 and 20 at this time are intended to activate the surface and form a hardened surface layer, and are not limited to a specific brush device to that extent, but specifically include wire brushes, plastic brushes, etc. In the case of the present invention, which includes brushes, etc., there are no particular restrictions on the brushing conditions per se, but in order to activate the bonding interface and generate a surface hardening layer, at least pure Ni and hardened stainless steel should be used before brushing. It is desirable that the condition of 1.1 times or more of the diameter be satisfied.
温間プラシングによって接合表面が活性化された純Ｎｉ
シート１０およびステンレス鋼シート１４は、温間圧延
工程２２に送られる。このときの温間圧延条件は、５０
〜４００℃、好ましくは１００〜３５０℃の加熱下で圧
下率４０％以上で行えば、特に限定されない。本発明に
よれば、圧延荷重を従来の場合と比較してかなり小さく
することができ、そのため従来は不可能と考えられてき
た輻７００〜１０００ｍｍという広幅のクラッド板の製
造が可能となる。Pure Ni with bonding surface activated by warm plating
Sheet 10 and stainless steel sheet 14 are sent to a warm rolling process 22. The warm rolling conditions at this time were 50
There is no particular limitation as long as the heating is carried out at a temperature of ~400°C, preferably 100~350°C, and a rolling reduction of 40% or more. According to the present invention, the rolling load can be significantly reduced compared to the conventional case, and therefore it becomes possible to manufacture a wide clad plate with a radius of 700 to 1000 mm, which was previously thought to be impossible.
本発明の好適態様によれば、純Ｎｉシートとして９００
°Ｃ以上で焼鈍した材料を使用する場合、本発明者らの
実験によれば、Ｎｉシートの接合強度はかなり改善され
るため、温間接合後そのまま巻取工程２４で巻取ること
ができる。従来はこのように巻取るときにＮｉシートの
剥離が生じることがあった。According to a preferred embodiment of the present invention, as a pure Ni sheet, 900
According to experiments conducted by the present inventors, when using a material annealed at a temperature of 0.degree. C. or higher, the bonding strength of the Ni sheet is considerably improved, so that the material can be wound up in the winding step 24 as it is after warm bonding. Conventionally, during winding in this manner, the Ni sheet sometimes peeled off.
もちろん、温間圧延後、連続して後熱処理工程２６に送
り後熱処理を行い、次いで冷間圧延工程２８および仕上
げ熱処理工程３０を経てクラッド材を製造してもよいが
、ニッケル・ステンレス鋼クランド材のように余り大量
に生産されない品種の場合には温間圧延後、−旦コイル
にしてストックできるということは実用上はかなり有利
である。Of course, after warm rolling, the cladding material may be manufactured by continuously sending it to the post-heat treatment step 26 and then passing through the cold-rolling step 28 and the final heat treatment step 30, but the nickel stainless steel crund material In the case of products such as those that are not produced in large quantities, it is practically advantageous to be able to stock them as coils after warm rolling.
この後熱処理は純Ｎｊの再結晶化による延性回復を目的
に行い、７５０°ＣＸＩ分以上、好ましくば９００゛Ｃ
で１分以上、より好ましくはオーステナイト系ステンレ
ス鋼の再結晶温度である１０５０°ＣＸＩ分以上の条件
で行えばよく、それによって接合強度は一層改善される
。After this, heat treatment is performed for the purpose of restoring ductility by recrystallization of pure Nj, and is performed at a temperature of 750°C or more, preferably 900°C.
The bonding can be carried out for at least 1 minute, more preferably for at least 1050° CXI minutes, which is the recrystallization temperature of austenitic stainless steel, thereby further improving the bonding strength.
冷間圧延は従来法に準して行えばよく、本発明にあって
は特に制限されない。代表的冷間圧延条件としては圧下
率５０％以上を挙げることができる。Cold rolling may be performed according to conventional methods, and is not particularly limited in the present invention. Typical cold rolling conditions include a rolling reduction of 50% or more.
仕上げ熱処理は、冷間加工に際して導入された歪みを除
去するために行われるもので、これも従来技術に準して
行えばよい、仕上げ熱処理の代表的処理条件は、オース
テナイト系ステンレス鋼の仕上焼鈍温度１０５０°ＣＸ
２分以上である。Finish heat treatment is performed to remove distortion introduced during cold working, and can be performed according to conventional technology. Typical processing conditions for finish heat treatment are finish annealing of austenitic stainless steel. Temperature 1050°C
It is more than 2 minutes.
かくして、本発明によれば、比較的少ない圧延荷重であ
っても十分な接合強度が確保できることから７００〜１
０００ｍｍという広幅材のクラッド材が製造可能となる
。Thus, according to the present invention, sufficient bonding strength can be ensured even with a relatively small rolling load.
It is now possible to manufacture cladding materials with a wide width of 0.000mm.
次に、本発明をその実施例によってさらに具体的に説明
するが、それは本発明の例示であってそれによって本発
明が不当に制限されるものではな実施例
本例では表面研磨、脱脂→温間ブラッシング→温間圧延
接合→後熱処理→冷間圧延→仕上げ熱処理の各工程を経
てＮｉシート／ステンレス鋼シート／Ｎｉシートの３層
の場合のクラッド化を実施した。Next, the present invention will be explained in more detail with reference to Examples, but these are merely illustrative examples of the present invention and should not unduly limit the present invention. Examples In this example, surface polishing, degreasing → heating Cladding in the case of three layers of Ni sheet/stainless steel sheet/Ni sheet was performed through the following steps: inter-brushing → warm rolling joining → post heat treatment → cold rolling → final heat treatment.
Ｎｉシートは９００℃以上で焼鈍した板厚１１１−の純
Ｎｉ板、ステンレス鋼シートは厚さ３鵬−のオーステナ
イト系ステンレス鋼板を用いた。The Ni sheet used was a pure Ni plate annealed at 900° C. or higher and had a thickness of 111 mm, and the stainless steel sheet used a 3 mm thick austenitic stainless steel plate.
Ｎｉシートおよびステンレス鋼シートを６００番研磨紙
で研磨してからシンナーで脱脂処理し、約２００“Ｃに
加熱してからワイヤブラシを使って両シートの各接合面
に温間ブラッシングを行った。ブラッシング前はほとん
ど平坦面であったが、温間ブラッシング後のステンレス
鋼シートの表面粗さを第２図にグラフで示す。The Ni sheet and the stainless steel sheet were polished with No. 600 abrasive paper, degreased with thinner, heated to about 200"C, and warm brushed on each joint surface of both sheets using a wire brush. Although the surface was almost flat before brushing, the surface roughness of the stainless steel sheet after warm brushing is shown graphically in FIG.
これらからＮｉ／ステンレス鋼／Ｎｉの三層構造のクラ
ッド組立体を得、本例では１００〜５００°Ｃに加熱し
てから、温間圧延接合を行った。このときの加熱は温間
圧延時の所要温度を確保するためであって、連続製造ラ
インの場合には温間ブラッシングの熱をそのま＼利用す
るだけでもよい。A clad assembly having a three-layer structure of Ni/stainless steel/Ni was obtained from these, and in this example, it was heated to 100 to 500°C and then warm rolled and joined. The heating at this time is to ensure the required temperature during warm rolling, and in the case of a continuous production line, it is sufficient to simply utilize the heat from warm brushing.
温間圧延接合後、後熱処理として６００〜１３００°Ｃ
に加熱した。After warm rolling joining, 600-1300°C as post heat treatment
heated to.
冷間圧延は圧下率９０％で行い、次いで１０５０°Ｃ×
２分間の仕上げ熱処理を行った。Cold rolling was performed at a reduction rate of 90%, and then at 1050°C
A finishing heat treatment was performed for 2 minutes.
結果を第３図ないし第６図にまとめて示す。The results are summarized in Figures 3 to 6.
第３図は、温間圧延に際しての加熱温度と圧下率との関
係を示すグラフである。FIG. 3 is a graph showing the relationship between heating temperature and rolling reduction during warm rolling.
温間圧延の際の温度が４００“Ｃ以下であれば、４０％
以上の圧下率で十分な接合が可能となることがわかる。40% if the temperature during warm rolling is 400"C or less
It can be seen that sufficient bonding is possible with the above rolling reduction ratio.
なお、４００゛Ｃ超に加熱すると接合面の酸化が著しく
なって接合不能となる。It should be noted that if heated above 400°C, the oxidation of the bonding surface becomes significant and bonding becomes impossible.
なお、十分な接合がなされているか否かは、ＪＩＳＧ
０６０１の剪断強さ試験ならびに剥離試験によって決定
する。In addition, whether or not there is sufficient bonding is determined according to JISG
Determined by 0601 shear strength test and peel test.
第４図は、純Ｎｉシートとして高温焼鈍材を使用する場
合（１１００“Ｃ焼鈍材）とそうでない場合（７５０°
Ｃ焼鈍材）とについて、温間圧延における圧下率と圧延
荷重に対しての接合性の評価をまとめて示すグラフであ
る。Figure 4 shows the case where a high temperature annealed material is used as the pure Ni sheet (1100"C annealed material) and the case where it is not (750°
FIG. 2 is a graph summarizing the evaluation of bondability against the rolling reduction rate and rolling load in warm rolling for C annealed material). FIG.
グラフに示す結果からも明らかなように、いずれの場合
も４０％以上の圧下率で十分な接合が得られるが、高温
焼鈍材の場合、同じ４０％以上の圧下率であっても８０
トンとより少ない圧延荷重で十分な接合性が得られるこ
とが分かる。As is clear from the results shown in the graph, sufficient bonding can be obtained with a rolling reduction of 40% or more in any case, but in the case of high-temperature annealed materials, even with the same rolling reduction of 40% or more, 80%
It can be seen that sufficient bonding performance can be obtained with a rolling load as low as 1 ton.
第５図は、後熱処理条件と圧縮剪断強度との関係を示す
グラフである。FIG. 5 is a graph showing the relationship between post-heat treatment conditions and compressive shear strength.
Ｎｉの再結晶温度である７５０°Ｃ以上の温度に１分間
以上加熱する後熱処理でＪＩＳ Ｇ ０６０１の規格で
ある２０ｋｇｆ／ｍｓ”以上の剪断強度が確保されるこ
とが分かる。好ましくは９００℃で１分以上である。It can be seen that a shear strength of 20 kgf/ms" or higher, which is the standard of JIS G 0601, can be secured by post-heat treatment at a temperature of 750° C., which is the recrystallization temperature of Ni, for 1 minute or more. Preferably at 900° C. It is more than 1 minute.
第６図は、同じく後熱処理温度と剥離強度との関係を示
すグラフである。特に、９００℃以上の加熱によって強
接合強度が確保されることが分かる。FIG. 6 is a graph similarly showing the relationship between post-heat treatment temperature and peel strength. In particular, it can be seen that strong bonding strength is ensured by heating at 900° C. or higher.
このように、好ましくは９００℃×１分間以上の後熱処
理条件によって剪断強度および剥離強度は著しく向上し
、剪断強度はＪＩＳ規格を満足する。As described above, the shear strength and peel strength are significantly improved by preferably post-heat treatment conditions of 900° C. for 1 minute or more, and the shear strength satisfies the JIS standard.
ただし、後熱処理時間と剪断強度との相関は認められな
い、また高温・長時間熱処理で逆に剥離性は低下する。However, there is no correlation between post-heat treatment time and shear strength, and releasability decreases with high-temperature and long-term heat treatment.
第７図（ａ）および（ｂ）にはそれぞれ温間接合後、お
よび９００°Ｃ後熱処理後のＮｉ−ステンレス鋼接合面
の顕微鏡金属組織写真を示す。後熱処理によってほぼ完
全な接合が達成されていることが分かる。FIGS. 7(a) and 7(b) show microscopic metallographic photographs of the Ni-stainless steel joint surface after warm bonding and after post-900°C heat treatment, respectively. It can be seen that almost perfect bonding was achieved by post-heat treatment.
断面ミクロ組織、硬さ測定結果および温間接合後、９０
０°Ｃ後熱処理後の剥離面平面観察から、後熱処理の接
合性改善効果はＮｉの再結晶による延性回復に基づくも
のと考えられる。Cross-sectional microstructure, hardness measurement results, and after warm bonding, 90
From the plane observation of the peeled surface after the 0°C post-heat treatment, it is thought that the bondability improvement effect of the post-heat treatment is based on the recovery of ductility due to recrystallization of Ni.
圧下率９０％の冷間圧延後、仕上げ熱処理を１０５０°
Ｃ×２分間行って得られたクラッド材は厚さ０．３１で
あった。After cold rolling with a rolling reduction of 90%, finish heat treatment is performed at 1050°.
The cladding material obtained by carrying out C×2 minutes had a thickness of 0.31.
（発明の効果）
以上詳述したように、本発明によれば、従来Ｎｉシート
との接合強度の点で十分でなかったニッケル・ステンレ
ス鋼クラッド材が、効率的にかつ安価な製造工程で製造
できるのであって、従来のように本発明にかかるクラッ
ド材は燃料電池用セパレート材としてばかりでな（ボタ
ン電池を始めとする電子、電気部品材料としても利用で
き、その実用的な意義は大きい。(Effects of the Invention) As detailed above, according to the present invention, the nickel stainless steel cladding material, which conventionally had insufficient bonding strength with the Ni sheet, can be manufactured using an efficient and inexpensive manufacturing process. Therefore, the cladding material according to the present invention can be used not only as a separate material for fuel cells as in the past (it can also be used as a material for electronic and electrical parts such as button batteries, and has great practical significance.
第１図は、本発明にかかる製造方法を示す工程図：
第２図は、温間ブラッシングによる表面の粗面状況の説
明図：
第３図ないし第６図は、実施例の結果をまとめて示すグ
ラフ：および
第７図（ａ）および第７図〜）は、それぞれ温間接合後
、および９００°Ｃ後熱処理後のＮｉ−ステンレス鋼接
合面の顕微鏡金属組織写真である。
出願人 日本ステンレス株式会社
代理人 弁理士 広 瀬 章 −（外１名）第
図
第
第
図
第
ｔｌＬ黙Ｉｊ！Ｌ理註’Ｃ）
槽熱処理１度（’Ｃ）
手続補正書
（自発）
平成２年５月２４日
第
図
２、発明の名称
ニッケル・ステンレス鋼クラッド材の製造方法４、代
理
人
９００’Ｃイ春ヒ黙メル工ゴ表Ｘ７００５、補正の対象
明細書の発明の詳細な説明の欄および添付図面６、補正
の内容
（１）明細書第１１頁５行目、「・・・分かる。」とあ
る記載に次の記載をつづける。
ｒ第７図（ａ）において右側に白く見えるのが未再結晶
Ｎｉで゛あり、第７図（ｂ）において中央部に白く見え
るのが再結晶Ｎｉである。ｊ
（２）添付図面の第７［Ｊ（ａ）、（ｂ）を別紙の通り
補正する。
以上
第７図
（ａ）
五聞璋澄俊ｘ３０００
（ｂ）
ｑｏｏ ”ｃ皮恕疋哩＾／θｍFigure 1 is a process diagram showing the manufacturing method according to the present invention; Figure 2 is an explanatory diagram of the roughness of the surface due to warm brushing; Figures 3 to 6 summarize the results of the examples. The graphs shown and FIGS. 7(a) and 7-) are microscopic metallographic photographs of the Ni-stainless steel joint surface after warm joining and after 900°C post-heat treatment, respectively. Applicant Nippon Stainless Co., Ltd. Agent Patent Attorney Akira Hirose - (1 other person) L Note'C) Tank heat treatment 1 degree ('C) Procedural amendment (voluntary) May 24, 1990 Figure 2 Title of invention Method for manufacturing nickel stainless steel clad material 4 Agent 900'C Iharu Hi Mokumergo Table X7005, Detailed Description of the Invention column of the specification to be amended and attached drawing 6, Contents of the amendment (1) Page 11, line 5 of the specification, "...I understand." A certain statement is followed by the following statement. In FIG. 7(a), what appears white on the right side is unrecrystallized Ni, and in FIG. 7(b), what appears white in the center is recrystallized Ni. j (2) No. 7 [J(a) and (b) of the attached drawings are amended as shown in the attached sheet. Above is Figure 7 (a) Gomon Shocho Shun x 3000 (b) qoo ”c skin 恕疋哩＾/θm
Claims (2)
一方の接合面を４００℃以下に加熱してブラッシングを
行ってから両者を貼り合わせ、５０〜４００℃の温度で
温間圧延接合を行い、次いで後熱処理を行ってから冷間
圧延および仕上げ熱処理を行うことを特徴とするニッケ
ル・ステンレス鋼クラッド材の製造方法。(1) At least one joint surface of the Ni sheet and the stainless steel sheet is heated to 400°C or less and brushed, then the two are bonded together, warm rolled and joined at a temperature of 50 to 400°C, and then A method for producing a nickel stainless steel clad material, characterized by performing heat treatment, followed by cold rolling and finishing heat treatment.
鈍したＮｉシートを使用する請求項１記載の方法。(2) The method according to claim 1, wherein a Ni sheet that has been previously heated and annealed at 900° C. or higher is used as the Ni sheet.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10472390A JPH044986A (en) | 1990-04-20 | 1990-04-20 | Manufacture of nickel and stainless steel clad material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10472390A JPH044986A (en) | 1990-04-20 | 1990-04-20 | Manufacture of nickel and stainless steel clad material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH044986A true JPH044986A (en) | 1992-01-09 |
Family
ID=14388416
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10472390A Pending JPH044986A (en) | 1990-04-20 | 1990-04-20 | Manufacture of nickel and stainless steel clad material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH044986A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH071649A (en) * | 1993-06-01 | 1995-01-06 | Nippon Metal Ind Co Ltd | Nickel-clad panel excellent in appearance and corrosion resistance, and production thereof |
| US8877796B2 (en) | 2009-11-12 | 2014-11-04 | The Regents Of The University Of Michigan | Spiro-oxindole MDM2 antagonists |
| US8901117B2 (en) | 2005-02-22 | 2014-12-02 | The Regents Of The University Of Michigan | Small molecule inhibitors of MDM2 and the uses thereof |
| CN105690910A (en) * | 2016-01-15 | 2016-06-22 | 宝山钢铁股份有限公司 | 9Ni steel and stainless steel composite steel plate for LNG storage tank and movable vessel and manufacturing method of composite steel plate |
| CN113151664A (en) * | 2021-03-31 | 2021-07-23 | 甘肃酒钢集团宏兴钢铁股份有限公司 | Mixed heating method for industrial high-purity nickel plate blank and stainless steel |
-
1990
- 1990-04-20 JP JP10472390A patent/JPH044986A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH071649A (en) * | 1993-06-01 | 1995-01-06 | Nippon Metal Ind Co Ltd | Nickel-clad panel excellent in appearance and corrosion resistance, and production thereof |
| US8901117B2 (en) | 2005-02-22 | 2014-12-02 | The Regents Of The University Of Michigan | Small molecule inhibitors of MDM2 and the uses thereof |
| US8877796B2 (en) | 2009-11-12 | 2014-11-04 | The Regents Of The University Of Michigan | Spiro-oxindole MDM2 antagonists |
| CN105690910A (en) * | 2016-01-15 | 2016-06-22 | 宝山钢铁股份有限公司 | 9Ni steel and stainless steel composite steel plate for LNG storage tank and movable vessel and manufacturing method of composite steel plate |
| CN113151664A (en) * | 2021-03-31 | 2021-07-23 | 甘肃酒钢集团宏兴钢铁股份有限公司 | Mixed heating method for industrial high-purity nickel plate blank and stainless steel |
| CN113151664B (en) * | 2021-03-31 | 2023-02-28 | 甘肃酒钢集团宏兴钢铁股份有限公司 | Mixed heating method for industrial high-purity nickel plate blank and stainless steel |
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