JPH04370276A - Moisture-permeable water-proof fabric and its production - Google Patents
Moisture-permeable water-proof fabric and its productionInfo
- Publication number
- JPH04370276A JPH04370276A JP3168640A JP16864091A JPH04370276A JP H04370276 A JPH04370276 A JP H04370276A JP 3168640 A JP3168640 A JP 3168640A JP 16864091 A JP16864091 A JP 16864091A JP H04370276 A JPH04370276 A JP H04370276A
- Authority
- JP
- Japan
- Prior art keywords
- moisture
- urethane
- temperature
- transition temperature
- polymer film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 79
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims abstract description 76
- 229920006254 polymer film Polymers 0.000 claims abstract description 45
- 230000009477 glass transition Effects 0.000 claims abstract description 43
- 229920000642 polymer Polymers 0.000 claims abstract description 42
- 239000000835 fiber Substances 0.000 claims description 21
- 239000011247 coating layer Substances 0.000 claims description 4
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 abstract description 24
- 238000000034 method Methods 0.000 abstract description 20
- 210000004243 sweat Anatomy 0.000 abstract description 13
- 230000035699 permeability Effects 0.000 abstract description 11
- 229920002635 polyurethane Polymers 0.000 abstract description 4
- 239000004814 polyurethane Substances 0.000 abstract description 4
- 239000012298 atmosphere Substances 0.000 abstract description 2
- 229920002994 synthetic fiber Polymers 0.000 abstract description 2
- 239000012209 synthetic fiber Substances 0.000 abstract description 2
- 239000004753 textile Substances 0.000 abstract 3
- 230000001419 dependent effect Effects 0.000 abstract 1
- 230000000704 physical effect Effects 0.000 abstract 1
- 229920006264 polyurethane film Polymers 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
- 230000007423 decrease Effects 0.000 description 11
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
- 150000003673 urethanes Chemical class 0.000 description 7
- 239000000853 adhesive Substances 0.000 description 6
- 230000001070 adhesive effect Effects 0.000 description 6
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- -1 polytetramethylene Polymers 0.000 description 5
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 229940106691 bisphenol a Drugs 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 239000012466 permeate Substances 0.000 description 3
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 229920003043 Cellulose fiber Polymers 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- 239000001273 butane Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 125000005442 diisocyanate group Chemical group 0.000 description 2
- 150000002009 diols Chemical class 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- 238000010030 laminating Methods 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 229920000431 shape-memory polymer Polymers 0.000 description 2
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
- CVFRFSNPBJUQMG-UHFFFAOYSA-N 2,3-bis(2-hydroxyethyl)benzene-1,4-diol Chemical compound OCCC1=C(O)C=CC(O)=C1CCO CVFRFSNPBJUQMG-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- 239000004970 Chain extender Substances 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 229940113088 dimethylacetamide Drugs 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 238000007646 gravure printing Methods 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- 230000002706 hydrostatic effect Effects 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920002620 polyvinyl fluoride Polymers 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 239000004627 regenerated cellulose Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920006268 silicone film Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
【０００１】0001
【産業上の利用分野】本発明は、外気温度によって透湿
量（水蒸気透過量）の変化する透湿性防水布帛及びその
製造方法に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a moisture permeable waterproof fabric whose moisture permeability (water vapor permeation amount) changes depending on the outside temperature, and a method for manufacturing the same.
【０００２】0002
【従来の技術】透湿性防水布帛は、水蒸気は透過させる
けれども水は透過させないものであり、スポーツ用衣料
やレインコートの生地として好適なものである。つまり
、外部からの雨水等は透過させないけれども、身体から
発生する汗は外部へ放出し、身体が雨水等で濡れるのを
防止すると共に身体の蒸れを防止できるからである。
従来より、このような透湿性防水布帛として、各種のタ
イプの布帛が使用されている。例えば、繊維布帛上に、
ウレタン系高分子フィルムを積層した透湿性防水布帛が
知られている。この透湿性防水布帛は、ウレタン系高分
子フィルムの存在によって水を透過させず、且つこのフ
ィルムを構成しているウレタン系高分子鎖間の間隙の存
在によって水蒸気を透過させるというものである。そし
て、この透湿性防水布帛は、外気温度が変化しても、そ
の透湿量は一定であった。BACKGROUND OF THE INVENTION Moisture-permeable waterproof fabrics are permeable to water vapor but not water, and are suitable as fabrics for sports clothing and raincoats. In other words, although rainwater etc. from the outside are not permeated, sweat generated from the body is released to the outside, preventing the body from getting wet with rainwater etc. and preventing the body from getting stuffy. Conventionally, various types of fabrics have been used as such moisture-permeable waterproof fabrics. For example, on a fiber fabric,
BACKGROUND ART A moisture permeable waterproof fabric laminated with a urethane polymer film is known. This moisture-permeable waterproof fabric does not allow water to pass through due to the presence of the urethane-based polymer film, and allows water vapor to pass through due to the presence of gaps between the urethane-based polymer chains that make up the film. This moisture-permeable waterproof fabric had a constant amount of moisture permeation even when the outside temperature changed.
【０００３】しかしながら、前記したような透湿量が一
定である透湿性防水布帛は、それを衣料用生地として使
用した場合、身体にとって次のような欠点が生じる。即
ち、外気温度が高いときは、身体からの発汗量が多くな
るのであるから、透湿量も多くならなければ、身体が蒸
れるという欠点を生じる。逆に、外気温度が低いときは
、身体からの発汗量が少なくなるのであるから、透湿量
も少なくならなければ、身体が冷えるという欠点を生じ
る。[0003] However, when the above-mentioned moisture-permeable waterproof fabric, which has a constant amount of moisture permeation, is used as a clothing fabric, the following disadvantages arise for the body. That is, when the outside temperature is high, the amount of sweat from the body increases, so unless the amount of moisture permeable increases, the body will become stuffy. Conversely, when the outside temperature is low, the amount of perspiration from the body decreases, so unless the amount of moisture permeable decreases, the body will become cold.
【０００４】0004
【発明が解決しようとする課題】そこで、本発明者等は
、外気温度の変化によって、透湿性防水布帛の透湿量を
変化させることについて、種々研究を行なった。その結
果、ウレタン系高分子フィルムには、次のような性質が
あることが判明した。即ち、ガラス転移温度を境として
透湿量が著しく変化することが判明したのである。本発
明は、ウレタン系高分子フィルムのこの性質を利用して
なされたものであり、透湿性防水布帛の材料として、あ
る一定のガラス転移温度を持つウレタン系高分子フィル
ムを使用することにより、外気温度が高くなれば透湿量
が多くなり、外気温度が低くなれば透湿量が少なくなる
ようにして、外気温度に拘らず、身体を快適な環境にお
こうとするものである。[Problems to be Solved by the Invention] Therefore, the present inventors conducted various studies on changing the amount of moisture permeation of a moisture-permeable waterproof fabric depending on changes in outside air temperature. As a result, it was found that the urethane polymer film has the following properties. In other words, it has been found that the amount of moisture permeation changes significantly after the glass transition temperature. The present invention was made by taking advantage of this property of urethane-based polymer film, and by using urethane-based polymer film with a certain glass transition temperature as a material for a moisture-permeable waterproof fabric, it is possible to The higher the temperature, the more moisture permeates, and the lower the outside temperature, the less moisture permeates, thereby keeping the body in a comfortable environment regardless of the outside temperature.
【０００５】[0005]
【課題を解決するための手段】即ち、本発明は、繊維布
帛の少なくとも片面にウレタン系高分子フィルムが積層
されてなり、該ウレタン系高分子フィルムのガラス転移
温度は０〜６０℃の範囲内であり、且つ該ポリウレタン
系高分子の重量平均分子量は１５０００以上であること
を特徴とする透湿性防水布帛及びその製造方法に関する
ものである。[Means for Solving the Problems] That is, in the present invention, a urethane polymer film is laminated on at least one side of a fiber fabric, and the glass transition temperature of the urethane polymer film is within the range of 0 to 60°C. The present invention relates to a moisture permeable waterproof fabric and a method for producing the same, characterized in that the polyurethane polymer has a weight average molecular weight of 15,000 or more.
【０００６】本発明に係る透湿性防水布帛は、繊維布帛
の少なくとも片面にウレタン系高分子フィルムが積層さ
れてなるものである。本発明で使用するウレタン系高分
子フィルムの最大の特徴は、ガラス転移温度が０〜６０
℃の範囲内にあることである。従来より使用されている
ウレタン系高分子フィルムは、そのガラス転移温度が−
２０〜−６０℃程度であり、この点で本発明で使用する
ウレタン系高分子フィルムと決定的に相違する。ここで
、ガラス転移温度を０〜６０℃の範囲内とした理由は、
外気の温度が概ねこの範囲内で変化するからである。従
って、ウレタン系高分子フィルムのガラス転移温度は、
外気の一般的な温度範囲である１０〜４０℃であるのが
好ましい。The moisture-permeable waterproof fabric according to the present invention is made of a fiber fabric with a urethane polymer film laminated on at least one side thereof. The greatest feature of the urethane polymer film used in the present invention is that the glass transition temperature is 0 to 60.
It must be within the range of ℃. The glass transition temperature of the urethane polymer film used conventionally is -
The temperature is about 20 to -60°C, and in this point it is decisively different from the urethane polymer film used in the present invention. Here, the reason why the glass transition temperature was set within the range of 0 to 60°C is as follows.
This is because the temperature of the outside air generally changes within this range. Therefore, the glass transition temperature of the urethane polymer film is
Preferably, the temperature range is 10 to 40°C, which is the general temperature range of outside air.
【０００７】例えば、本発明で使用するウレタン系高分
子フィルムのガラス転移温度を２０℃に設定したとする
と、外気の温度が２０℃未満になると透湿量が少なくな
り、外気の温度が２０℃以上になると透湿量が多くなる
。
このウレタン系高分子フィルムを使用した透湿性防水布
帛は、それを衣料用生地に用いた場合、外気の温度が２
０℃以上になると身体からの汗が外部へ放出され、逆に
外気の温度が２０℃未満になると身体からの汗は外部へ
放出されにくくなる。従って、身体にとって非常に快適
である。これに対し、従来のウレタン系高分子フィルム
を使用した透湿性防水布帛は、そのガラス転移温度が−
２０℃以下であるため、外気の温度（一般的に０℃以上
）がガラス転移温度以下になることはない。従って、透
湿性防水布帛の透湿量は一定であり、外気の温度に拘ら
ず、身体からの汗を外部へ放出する量も一定になる。従
って、身体が蒸れたり或いは身体にとって寒く感じると
いうことが生じるのである。なお、本発明において、ウ
レタン系高分子フィルムのガラス転移温度は、以下の方
法によって測定されるものである。即ち、ＤＳＣ法（差
動走査計熱量計）により、昇温速度２０℃／ｍｉｎで且
つ窒素ガス雰囲気で、測定されるものである。For example, if the glass transition temperature of the urethane polymer film used in the present invention is set at 20°C, when the temperature of the outside air becomes less than 20°C, the amount of moisture permeable decreases, and the temperature of the outside air decreases to 20°C. If the temperature exceeds that amount, the amount of moisture permeable will increase. This moisture-permeable waterproof fabric using a urethane-based polymer film can be used for clothing when the temperature of the outside air is 2.
When the temperature of the outside air exceeds 0°C, sweat from the body is released to the outside, and conversely, when the temperature of the outside air falls below 20°C, it becomes difficult for sweat from the body to be released to the outside. Therefore, it is very comfortable for the body. In contrast, the glass transition temperature of conventional moisture-permeable waterproof fabrics using urethane-based polymer films is -
Since the temperature is 20° C. or lower, the temperature of the outside air (generally 0° C. or higher) does not fall below the glass transition temperature. Therefore, the amount of moisture permeable through the moisture-permeable waterproof fabric is constant, and the amount of sweat released from the body to the outside is also constant regardless of the temperature of the outside air. Therefore, the body may feel stuffy or cold. In the present invention, the glass transition temperature of the urethane polymer film is measured by the following method. That is, it is measured by the DSC method (differential scanning calorimeter) at a temperature increase rate of 20° C./min and in a nitrogen gas atmosphere.
【０００８】また、本発明で使用するウレタン系高分子
の重量平均分子量は、１５０００以上である。ウレタン
系高分子の重量平均分子量が１５０００未満になると、
ウレタン系高分子フィルムの強度が低下し、破断しやす
くなったり或いは亀裂が生じたりする。従って、得られ
る透湿性防水布帛の防水性が低下し、好ましくない。な
お、ウレタン系高分子の重量平均分子量は、以下の方法
によって測定する。即ち、ウレタン系高分子のジメチル
ホルムアミド溶液を試料とし、キャリア溶剤にはジメチ
ルホルムアミドを用い、検出器には屈折計を使用して、
ゲルパーメーションクロマトグラフ法（ＧＰＣ法）によ
り、測定されるものである。[0008] Furthermore, the weight average molecular weight of the urethane polymer used in the present invention is 15,000 or more. When the weight average molecular weight of the urethane polymer is less than 15,000,
The strength of the urethane polymer film decreases, making it more likely to break or cracking. Therefore, the waterproofness of the resulting moisture-permeable waterproof fabric decreases, which is not preferable. Note that the weight average molecular weight of the urethane polymer is measured by the following method. That is, a dimethylformamide solution of a urethane polymer is used as a sample, dimethylformamide is used as a carrier solvent, and a refractometer is used as a detector.
It is measured by gel permeation chromatography (GPC method).
【０００９】本発明で使用するウレタン系高分子は、例
えば以下の如き方法で製造することができる。即ち、Ｏ
ＣＮＲ１ＮＣＯで表わされるジイソシアネートと、ＨＯ
Ｒ２ＯＨで表わされるジオールとを共重合させてウレタ
ンプレポリマーを得、このウレタンプレポリマーをＨＯ
Ｒ３ＯＨで表わされる鎖成長剤と反応させて、ウレタン
系高分子を得ることができる。このようにして得られた
ウレタン系高分子は、一般的に、ＯＣＮ（Ｒ１ＮＨＣＯ
ＯＲ２ＯＣＯＮＨ）ｍＲ１ＮＨＣＯＯＲ３ＯＣＯＮＨ（
Ｒ１ＮＨＣＯＯＲ２ＯＣＯＮＨ）ｎＲ１ＮＣＯ［但し、
ｍ及びｎは正の整数を表わし、特に１〜１６である。］
で表わされる。このウレタン系高分子のガラス転移温度
は、Ｒ１，Ｒ２，Ｒ３の剛直性，分子量，分子容，極性
等によって決まり、更にｍ及びｎの数等によって決まる
。従って、本発明においては、ウレタン系高分子のガラ
ス転移温度が所望の値を取るように、これらを決定する
のである。一般的に、Ｒ２，Ｒ３の分子量が大きくなる
ほどガラス転移温度が降下し、またＲ１，Ｒ２，Ｒ３の
剛直性が増すほど上昇する。The urethane polymer used in the present invention can be produced, for example, by the following method. That is, O
Diisocyanate represented by CNR1NCO and HO
A urethane prepolymer is obtained by copolymerizing with a diol represented by R2OH, and this urethane prepolymer is
A urethane-based polymer can be obtained by reacting with a chain growth agent represented by R3OH. The urethane polymer thus obtained is generally OCN (R1NHCO
OR2OCONH)mR1NHCOOR3OCONH(
R1NHCOOR2OCONH) nR1NCO [However,
m and n represent positive integers, especially from 1 to 16. ]
It is expressed as The glass transition temperature of this urethane-based polymer is determined by the rigidity, molecular weight, molecular volume, polarity, etc. of R1, R2, R3, and further determined by the numbers of m and n. Therefore, in the present invention, these are determined so that the glass transition temperature of the urethane polymer takes a desired value. Generally, the glass transition temperature decreases as the molecular weight of R2 and R3 increases, and increases as the rigidity of R1, R2 and R3 increases.
【００１０】ジイソシアネートの具体例としては、２，
４−トルエンジイソシアネート、４，４’−ジフェニル
メタンジイソシアネート、カンボジイミド変性の４，４
’−ジフェニルメタンジイソシアネート、ヘキサメチレ
ンジイソシアネート等を使用することができる。また、
ジオールの具体例としては、ポリプロピレングリコール
、１，４−ブタングリコールアジペート、ポリテトラメ
チレングリコール、ビスフェノール−Ａ＋プロピレンオ
キサイド等を使用することができる。また、鎖延長剤の
具体例としては、エチレングリコール、１，４−ブタン
グリコール、ビス（２−ハイドロキシエチル）ハイドロ
キノン、ビスフェノール−Ａ＋エチレンオキサイド、ビ
スフェノール−Ａ＋プロピレンオキサイド等を使用する
ことができる。Specific examples of diisocyanates include 2,
4-Toluene diisocyanate, 4,4'-diphenylmethane diisocyanate, cambodiimide-modified 4,4
'-diphenylmethane diisocyanate, hexamethylene diisocyanate, etc. can be used. Also,
Specific examples of the diol include polypropylene glycol, 1,4-butane glycol adipate, polytetramethylene glycol, bisphenol-A+propylene oxide, and the like. Further, as specific examples of the chain extender, ethylene glycol, 1,4-butane glycol, bis(2-hydroxyethyl)hydroquinone, bisphenol-A+ethylene oxide, bisphenol-A+propylene oxide, etc. can be used.
【００１１】ポリウレタン系高分子フィルムが積層され
る繊維布帛としては、木綿，麻等の天然セルロース繊維
、羊毛，絹等の天然タンパク質繊維、レーヨン，アセテ
ート等の再生セルロース繊維、ポリエステル，ポリアミ
ド，ポリアクリロニトリル等の合成繊維等の繊維、又は
これらの繊維の二種以上の混用よりなる織物，編物，不
織布等が用いられる。The fiber fabric on which the polyurethane polymer film is laminated includes natural cellulose fibers such as cotton and hemp, natural protein fibers such as wool and silk, regenerated cellulose fibers such as rayon and acetate, polyester, polyamide, and polyacrylonitrile. Fibers such as synthetic fibers, etc., or woven fabrics, knitted fabrics, non-woven fabrics, etc. made of a mixture of two or more of these fibers are used.
【００１２】本発明に係る透湿性防水布帛の製造方法と
しては、以下に示す二つの方法が好ましい。第一には、
繊維布帛の少なくとも片面に、ウレタン系高分子溶液を
均一に塗布して塗布層を形成した後、該塗布層を乾燥し
てウレタン系高分子フィルムを生成させる方法である。
ウレタン系高分子溶液としては、ウレタン系高分子を溶
剤に溶解させた溶剤溶液、又はウレタン系高分子を水溶
液中に懸濁させた水系エマルジョンを使用することがで
きる。溶剤溶液を調整する場合には、ジメチルホルムア
ルデヒド，ジメチルアセトアミド，ジメチルスルホキシ
ド，メチルエチルケトン，２−ブタノン等の有機溶剤を
溶媒として、粘度２０００〜５００００ｃｐｓとするの
が、好ましい。
粘度が２０００ｃｐｓ未満であると、繊維布帛表面に塗
布しても、フィルムを形成しにくくなり、防水性を付与
しにくくなる傾向が生じる。また、粘度が５００００ｃ
ｐｓを超えると、溶剤溶液の流動性が低下し、厚さの均
一なフィルムを形成しにくくなる傾向が生じる。ウレタ
ン系高分子溶液を繊維布帛表面に塗布するには、ナイフ
コーターやバーコーター等の従来公知のコーティング設
備を利用すればよい。また、ウレタン系高分子溶液とし
て水系エマルジョンを使用する場合には、前記のコーテ
ィング設備の他に、グラビア捺染機，ロータリー捺染機
を利用することもできる。また、繊維布帛表面にウレタ
ン系高分子溶液を塗布する前に、予め繊維布帛表面をポ
リフッ化ビニル樹脂等で加工しておくのが、好ましい。
これは、繊維布帛表面へのウレタン系高分子溶液の塗布
を均一にでき、したがって生成するフィルムが均一にな
りやすく、更に得られる透湿性防水布帛の風合がソフト
になりやすいからである。また、同様の理由で、予め繊
維布帛をカレンダー処理して、その表面を平坦にしてお
くことも、好ましい。[0012] The following two methods are preferred as methods for producing the moisture-permeable waterproof fabric according to the present invention. Firstly,
This is a method in which a urethane polymer solution is uniformly applied to at least one side of a fiber fabric to form a coating layer, and then the coating layer is dried to produce a urethane polymer film. As the urethane-based polymer solution, a solvent solution in which a urethane-based polymer is dissolved in a solvent, or an aqueous emulsion in which a urethane-based polymer is suspended in an aqueous solution can be used. When preparing a solvent solution, it is preferable to use an organic solvent such as dimethyl formaldehyde, dimethyl acetamide, dimethyl sulfoxide, methyl ethyl ketone, 2-butanone, etc. as a solvent and adjust the viscosity to 2,000 to 50,000 cps. If the viscosity is less than 2000 cps, it will be difficult to form a film even when applied to the surface of a fiber fabric, and it will tend to be difficult to provide waterproof properties. Also, the viscosity is 50000c
If it exceeds ps, the fluidity of the solvent solution decreases, and it tends to become difficult to form a film with a uniform thickness. In order to apply the urethane-based polymer solution to the surface of the fiber fabric, conventionally known coating equipment such as a knife coater or a bar coater may be used. Furthermore, when a water-based emulsion is used as the urethane-based polymer solution, a gravure printing machine or a rotary printing machine can also be used in addition to the above-mentioned coating equipment. Further, it is preferable that the surface of the fiber cloth is previously treated with a polyvinyl fluoride resin or the like before applying the urethane polymer solution to the surface of the fiber cloth. This is because the urethane-based polymer solution can be uniformly applied to the surface of the fiber fabric, so the resulting film tends to be uniform, and the resulting moisture-permeable waterproof fabric tends to have a soft feel. For the same reason, it is also preferable to previously calender the fiber fabric to flatten its surface.
【００１３】第二の方法としては、予めウレタン系高分
子フィルムと繊維布帛とを準備しておき、両者を貼合す
る方法である。ウレタン系高分子フィルムを製造する方
法としては、ウレタン系高分子を融点以上で熱溶融して
巾広のスリットから押し出し成形する方法や、ウレタン
系高分子溶液を離型紙上に均一に塗布し乾燥する方法等
が挙げられる。ウレタン系高分子フィルムと繊維布帛と
を貼合する方法としては、繊維布帛表面又はウレタン系
高分子フィルム表面に、ポリウレタン系接着剤やポリア
クリル系接着剤等の接着剤を施しておき、この接着剤に
よって両者を貼合すればよい。また、熱溶融したウレタ
ン系高分子を押し出し成形してフィルムを形成しながら
、未だフィルムが軟化状態のときに繊維布帛と積層し、
フィルムの粘着力で両者を貼合してもよい（いわゆる押
し出しラミネート法）。The second method is to prepare a urethane polymer film and a fiber fabric in advance and bond them together. Methods for producing urethane-based polymer films include methods of melting urethane-based polymers above their melting point and extruding them through a wide slit, or applying a urethane-based polymer solution uniformly onto release paper and drying it. Examples include a method to do so. A method for laminating a urethane polymer film and a fiber fabric is to apply an adhesive such as a polyurethane adhesive or a polyacrylic adhesive to the surface of the fiber fabric or the urethane polymer film, and then apply this adhesive. The two may be bonded together using an agent. In addition, while forming a film by extrusion molding a hot molten urethane polymer, while the film is still in a softened state, it is laminated with a fiber fabric,
The two may be bonded together using the adhesive strength of the film (so-called extrusion lamination method).
【００１４】以上のようにして得られる本発明に係る透
湿性防水布帛は、一般的に、ガラス転移温度を境にして
透湿量が３〜５倍程度変化するものである。即ち、ウレ
タン系高分子フィルムのガラス転移温度以上における透
湿量は、ウレタン系高分子フィルムのガラス転移温度未
満における透湿量の約３〜５倍程度になるのである。そ
して、本発明に係る透湿性防水布帛は、ウレタン系高分
子フィルムのガラス転移温度が室温程度に設定されてい
るので、外気の温度変化によって透湿量が変化するので
ある。また、本発明に係る透湿性防水布帛は、ウレタン
系高分子フィルムよりなる層が存在するため、一般的に
、耐水圧が１０００ｍｍＨｇ程度以上であり、防水性に
優れたものである。従って、本発明に係る透湿性防水布
帛は、ウポーツウェアーの他に、レインコート，手術着
，作業服等に好適に使用しうるものである。[0014] The moisture permeable waterproof fabric according to the present invention obtained as described above generally has a moisture permeability that changes by about 3 to 5 times after reaching the glass transition temperature. That is, the amount of moisture permeable at temperatures above the glass transition temperature of the urethane-based polymer film is approximately 3 to 5 times the amount of moisture permeable at temperatures below the glass transition temperature of the urethane-based polymer film. In the moisture-permeable waterproof fabric according to the present invention, the glass transition temperature of the urethane-based polymer film is set to about room temperature, so the amount of moisture permeation changes with changes in the temperature of the outside air. Further, since the moisture-permeable waterproof fabric according to the present invention includes a layer made of a urethane-based polymer film, it generally has a water pressure resistance of about 1000 mmHg or more, and has excellent waterproof properties. Therefore, the moisture-permeable waterproof fabric according to the present invention can be suitably used for raincoats, surgical gowns, work clothes, etc. in addition to sportswear.
【００１５】[0015]
【実施例】次に、本発明を実施例によって、さらに具体
的に説明する。なお、実施例中における布帛の性能評価
は、下記の方法で行なった。
（１）透湿性
ＪＩＳ Ｌ−１０９９（Ａ−１法）により、所定の温度
で透湿量を測定した。単位は、水蒸気圧差を１ａｔｍと
した時の透湿量とした。
（２）耐水性
ＪＩＳ Ｌ−１０９２（イ）静水圧法により、耐水度を
測定した。EXAMPLES Next, the present invention will be explained in more detail by way of examples. In addition, performance evaluation of the fabric in Examples was performed by the following method. (1) Moisture permeability The amount of moisture permeable was measured at a predetermined temperature according to JIS L-1099 (Method A-1). The unit was the amount of moisture permeation when the water vapor pressure difference was 1 atm. (2) Water resistance The water resistance was measured according to JIS L-1092 (a) hydrostatic pressure method.
【００１６】実施例１
まず、ウレタン系高分子が溶解されているジメチルホル
ムアミド溶液（三菱重工業株式会社製形状記憶ポリマー
、商品名「ダイアリティ」溶液タイプＭＳ２５００）を
準備した。このウレタン系高分子は、ジメチルホルムア
ミド中で重合されたものであり、その濃度は３０重量％
であり、２５℃における粘度は９５０００ｃｐｓであっ
た。また、ウレタン系高分子のガラス転移温度は２５℃
であり、その重量平均分子量は、２５０００であった。
このジメチルホルムアミド溶液を、同量の１，１，１−
トリクロロエタンで希釈して、粘度９０００ｃｐｓのウ
レタン系高分子溶液を得た。Example 1 First, a dimethylformamide solution (shape memory polymer manufactured by Mitsubishi Heavy Industries, Ltd., trade name "Diality" solution type MS2500) in which a urethane polymer was dissolved was prepared. This urethane-based polymer was polymerized in dimethylformamide, and its concentration was 30% by weight.
The viscosity at 25° C. was 95,000 cps. In addition, the glass transition temperature of urethane polymer is 25℃
and its weight average molecular weight was 25,000. This dimethylformamide solution was added to the same amount of 1,1,1-
It was diluted with trichloroethane to obtain a urethane-based polymer solution with a viscosity of 9000 cps.
【００１７】次に、フッ素系撥水剤（アサヒガードＡＧ
−４３３、濃度３％）で撥水加工したナイロンタフタ（
７５ｄ／４８ｆ／３、１２０×８５）に、ナイフコータ
ーでウレタン系高分子溶液を厚さ０．１ｍｍとなるよう
にコーティングし、乾燥した。以上のようにして得られ
た透湿性防水布帛は、ナイロンタフタにウレタン系高分
子フィルムが積層されてなるものであり、ウレタン系高
分子フィルムのガラス転移温度は２５℃であった。また
、この透湿性防水布帛の各温度における透湿量及び耐水
度を表１に示した。Next, fluorine-based water repellent (Asahi Guard AG
-433, concentration 3%) nylon taffeta (concentration 3%)
75d/48f/3, 120×85) was coated with a urethane polymer solution to a thickness of 0.1 mm using a knife coater and dried. The moisture permeable waterproof fabric obtained as described above was made by laminating a urethane polymer film on nylon taffeta, and the glass transition temperature of the urethane polymer film was 25°C. Further, Table 1 shows the moisture permeability and water resistance of this moisture permeable waterproof fabric at each temperature.
【表１】[Table 1]
【００１８】比較例１
ガラス転移温度−４０℃で、重量平均分子量３００００
のウレタン系高分子を使用する以外は、実施例１と同様
の方法で透湿性防水布帛を得た。この透湿性防水布帛中
のウレタン系高分子フィルムのガラス転移温度は、−４
０℃であった。この透湿性防水布帛の各温度における透
湿量及び耐水度を表１に示した。Comparative Example 1 Glass transition temperature -40°C, weight average molecular weight 30,000
A moisture-permeable waterproof fabric was obtained in the same manner as in Example 1, except that the urethane-based polymer was used. The glass transition temperature of the urethane polymer film in this moisture-permeable waterproof fabric is -4
It was 0°C. Table 1 shows the moisture permeability and water resistance of this moisture permeable waterproof fabric at each temperature.
【００１９】実施例２
ウレタン系高分子が溶解されているジメチルホルムアミ
ド溶液（三菱重工業株式会社製形状記憶ポリマー、商品
名「ダイアリティ」溶液タイプＭＳ２０００）を準備し
た。このウレタン系高分子は、ジメチルホルムアミド中
で重合されたものであり、その濃度は４５重量％であり
、２５℃における粘度は９５０００ｃｐｓであった。ま
た、ウレタン系高分子のガラス転移温度は２０℃であり
、その重量平均分子量は、２５０００であった。このウ
レタン系高分子溶液を、シリコーンフィルムをコートし
た離型紙上に塗布し、乾燥して厚さ１５μｍのウレタン
系高分子フィルムを形成した。このウレタン系高分子フ
ィルムを、木綿１００％のスムース生地（４０番手、３
０ｉｎｃｈ、２４Ｇ）にウレタン系接着剤を介して積層
し、両者を貼合した。このようにして得られた透湿性防
水布帛中のウレタン系高分子フィルムのガラス転移温度
は、２０℃であった。そして、この透湿性防水布帛の各
温度における透湿量及び耐水度を表２に示した。Example 2 A dimethylformamide solution (shape memory polymer manufactured by Mitsubishi Heavy Industries, Ltd., trade name "Diality" solution type MS2000) in which a urethane polymer was dissolved was prepared. This urethane-based polymer was polymerized in dimethylformamide, had a concentration of 45% by weight, and a viscosity of 95,000 cps at 25°C. Further, the glass transition temperature of the urethane polymer was 20°C, and the weight average molecular weight was 25,000. This urethane-based polymer solution was applied onto a release paper coated with a silicone film and dried to form a urethane-based polymer film with a thickness of 15 μm. This urethane polymer film is coated with 100% cotton smooth fabric (40 count, 3
0 inch, 24G) via a urethane adhesive, and the two were bonded together. The glass transition temperature of the urethane-based polymer film in the moisture-permeable waterproof fabric thus obtained was 20°C. The moisture permeability and water resistance of this moisture permeable waterproof fabric at each temperature are shown in Table 2.
【表２】[Table 2]
【００２０】比較例２
ガラス転移温度−４０℃で、重量平均分子量３００００
のウレタン系高分子を使用する以外は、実施例２と同様
の方法で透湿性防水布帛を得た。この透湿性防水布帛中
のウレタン系高分子フィルムのガラス転移温度は、−４
０℃であった。この透湿性防水布帛の各温度における透
湿量及び耐水度を表２に示した。Comparative Example 2 Glass transition temperature -40°C, weight average molecular weight 30,000
A moisture-permeable waterproof fabric was obtained in the same manner as in Example 2, except that the urethane-based polymer was used. The glass transition temperature of the urethane polymer film in this moisture-permeable waterproof fabric is -4
It was 0°C. Table 2 shows the moisture permeability and water resistance of this moisture permeable waterproof fabric at each temperature.
【００２１】実施例３
イソシアネート成分として４，４−ジフェニルメタンジ
イソシアネート（三菱化成株式会社製、商品名「ダウイ
ソシアネート１２５Ｍ」）を、ポリオール成分としてポ
リプロピレングリコール（三洋化成工業株式会社製、商
品名「ＰＰ−１０００」）を、鎖延長剤として１，４−
ブタンジオール（三菱化成株式会社製）を使用して、ガ
ラス転移温度２５℃、重量平均分子量２５０００のウレ
タン系高分子を得た。このウレタン系高分子を溶融状態
とし、スリット巾０．２ｍｍのスリットダイより押し出
しながら、ポリエステルトリコット上に積層して、両者
を貼合した。以上のようにして得られた透湿性防水布帛
は、ウレタン系高分子フィルムの厚さが７μｍであり、
ガラス転移温度は２５℃であった。そして、この透湿性
防水布帛の各温度における透湿量及び耐水度を表３に示
した。Example 3 4,4-diphenylmethane diisocyanate (manufactured by Mitsubishi Kasei Corporation, trade name "Dow Isocyanate 125M") was used as the isocyanate component, and polypropylene glycol (manufactured by Sanyo Chemical Industries, Ltd., trade name "PP-") was used as the polyol component. 1,4-
Using butanediol (manufactured by Mitsubishi Kasei Corporation), a urethane polymer having a glass transition temperature of 25° C. and a weight average molecular weight of 25,000 was obtained. This urethane-based polymer was melted and extruded through a slit die with a slit width of 0.2 mm, and laminated on polyester tricot to bond the two together. The moisture-permeable waterproof fabric obtained as described above has a urethane polymer film having a thickness of 7 μm,
The glass transition temperature was 25°C. The moisture permeability and water resistance of this moisture permeable waterproof fabric at each temperature are shown in Table 3.
【表３】[Table 3]
【００２２】比較例３
ガラス転移温度−２５℃のポリエチレンを使用する以外
は、実施例３と同様の方法で透湿性防水布帛を得た。こ
の透湿性防水布帛中のポリエチレンフィルムのガラス転
移温度は、−２５℃であった。この透湿性防水布帛の各
温度における透湿量及び耐水度を表３に示した。Comparative Example 3 A moisture-permeable waterproof fabric was obtained in the same manner as in Example 3, except that polyethylene having a glass transition temperature of -25°C was used. The glass transition temperature of the polyethylene film in this moisture-permeable waterproof fabric was -25°C. Table 3 shows the moisture permeability and water resistance of this moisture permeable waterproof fabric at each temperature.
【００２３】以上の実施例からも明かなとおり、実施例
に係る透湿性防水布帛は、ガラス転移温度が室温程度の
ウレタン系高分子フィルムを備えているので、室温がガ
ラス転移温度未満になると透湿量が低下し、室温がガラ
ス転移温度以上になると透湿量が増大する。従って、外
気温度が上がると、透湿性防水布帛の透湿量が増大し、
身体から発生する汗を良好に外部に放出し、逆に外気温
度が下がると、透湿量が低下し身体からの汗を外部に放
出しにくくなる。依って、実施例に係る透湿性防水布帛
を衣料用の生地として使用すれば、外気温度の高低によ
らず、身体を快適な環境におくことができる。これに対
し、比較例に係る透湿性防水布帛は、外気温度の高低に
拘らず、透湿量がほぼ一定であるため、外気温度の高低
によって、身体が蒸れたり或いは冷えたりすることにな
る。As is clear from the above examples, the moisture-permeable waterproof fabric according to the example includes a urethane-based polymer film whose glass transition temperature is around room temperature, so it becomes transparent when the room temperature falls below the glass transition temperature. When the amount of moisture decreases and the room temperature becomes higher than the glass transition temperature, the amount of moisture permeable increases. Therefore, when the outside temperature rises, the amount of moisture permeable through the moisture-permeable waterproof fabric increases,
Sweat generated from the body is effectively released to the outside, and conversely, when the outside temperature drops, the amount of moisture permeable decreases, making it difficult to release sweat from the body to the outside. Therefore, if the moisture-permeable waterproof fabric according to the embodiment is used as a fabric for clothing, the body can be kept in a comfortable environment regardless of the outside temperature. On the other hand, the moisture permeable waterproof fabric according to the comparative example has a substantially constant amount of moisture permeation regardless of the outside air temperature, so the body becomes stuffy or cold depending on the outside air temperature.
【００２４】[0024]
【作用】本発明に係る透湿性防水布帛を構成するウレタ
ン系高分子フィルムは、前記したようにガラス転移温度
を室温程度に設定したものである。そして、ガラス転移
温度を境として、その透湿量が著しく変化する。この透
湿量が変化する理由は、定かではないが、以下のように
考えられる。即ち、一般に高分子のガラス転移温度は、
高分子鎖中の一定長のセグメントの液体状運動の始点に
相当する。従って、ガラス転移温度以上では高分子鎖の
自由体積が、急激に増大する。自由体積が増大するとい
うことは、高分子鎖間における間隙が増大するというこ
とである。依って、この間隙を水分子が透過しやすくな
り、透湿量が増大するものと考えられるのである。[Function] The urethane polymer film constituting the moisture-permeable waterproof fabric according to the present invention has a glass transition temperature set to about room temperature, as described above. The amount of moisture permeable changes significantly after reaching the glass transition temperature. Although the reason for this change in the amount of moisture permeation is not clear, it is thought to be as follows. That is, in general, the glass transition temperature of a polymer is
It corresponds to the starting point of liquid-like motion of a segment of a certain length in a polymer chain. Therefore, the free volume of polymer chains increases rapidly above the glass transition temperature. An increase in free volume means an increase in the gaps between polymer chains. Therefore, it is thought that water molecules can easily permeate through these gaps, increasing the amount of moisture permeation.
【００２５】[0025]
【発明の効果】以上述べたように、本発明に係る透湿性
防水布帛は、ガラス転移温度が室温付近に設定されたウ
レタン系高分子フィルムを備えているため、ガラス転移
温度未満では透湿量が少なく、ガラス転移温度以上では
透湿量が著しく増大する。従って、本発明に係る透湿性
防水布帛を使用して衣料を作成すれば、外気温度が高く
なって身体からの発汗が多くなると、その汗を良好に外
部に放出し、逆に外気温度が低くなって身体からの発汗
が少なくなると、汗や体温等を外部に放出しにくくなる
。依って、外気温度の高いときには身体が涼しく感じら
れ、外気温度が低いときには身体が暖かく感じられ、常
に身体にとって快適な環境を提供するという効果を奏す
るものである。また、本発明に係る透湿性防水布帛は、
ウレタン系高分子フィルムの層を備えているので、これ
を使用して衣料を作成すれば、防水性に優れた衣料を得
ることができるという効果も奏する。Effects of the Invention As described above, since the moisture permeable waterproof fabric according to the present invention is equipped with a urethane polymer film whose glass transition temperature is set around room temperature, the moisture permeability decreases below the glass transition temperature. The amount of moisture permeable increases significantly above the glass transition temperature. Therefore, if clothing is made using the moisture permeable waterproof fabric according to the present invention, when the outside temperature increases and the body sweats a lot, the sweat will be effectively released to the outside, and conversely, when the outside temperature is low, the sweat will be released to the outside. As a result, less sweat is produced from the body, making it difficult for sweat and body heat to be released to the outside. Therefore, when the outside temperature is high, the body feels cool, and when the outside temperature is low, the body feels warm, thereby providing an effect of always providing a comfortable environment for the body. Further, the moisture permeable waterproof fabric according to the present invention is
Since it has a layer of urethane-based polymer film, it also has the effect that if clothing is made using this, clothing with excellent waterproofness can be obtained.
Claims (3)
系高分子フィルムが積層されてなり、該ウレタン系高分
子フィルムのガラス転移温度は０〜６０℃の範囲内であ
り、且つ該ポリウレタン系高分子の重量平均分子量は１
５０００以上であることを特徴とする透湿性防水布帛。Claim 1: A urethane polymer film is laminated on at least one side of a fiber fabric, the glass transition temperature of the urethane polymer film is within the range of 0 to 60°C, and Weight average molecular weight is 1
A moisture-permeable waterproof fabric characterized by having a molecular weight of 5,000 or more.
ン系高分子溶液を均一に塗布して塗布層を形成した後、
該塗布層を乾燥してウレタン系高分子フィルムを生成さ
せることを特徴とする請求項１記載の透湿性防水布帛の
製造方法。2. After uniformly applying a urethane polymer solution to at least one side of the fiber fabric to form a coating layer,
2. The method for producing a moisture-permeable waterproof fabric according to claim 1, wherein the coating layer is dried to produce a urethane-based polymer film.
帛の少なくとも片面に貼合することを特徴とする請求項
１記載の透湿性防水布帛の製造方法。3. The method for producing a moisture-permeable waterproof fabric according to claim 1, characterized in that a urethane-based polymer film is laminated on at least one side of the fiber fabric.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP03168640A JP3074335B2 (en) | 1991-06-12 | 1991-06-12 | Moisture-permeable waterproof fabric and method for producing the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP03168640A JP3074335B2 (en) | 1991-06-12 | 1991-06-12 | Moisture-permeable waterproof fabric and method for producing the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH04370276A true JPH04370276A (en) | 1992-12-22 |
| JP3074335B2 JP3074335B2 (en) | 2000-08-07 |
Family
ID=15871789
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP03168640A Expired - Fee Related JP3074335B2 (en) | 1991-06-12 | 1991-06-12 | Moisture-permeable waterproof fabric and method for producing the same |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3074335B2 (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05272061A (en) * | 1992-03-17 | 1993-10-19 | Kanebo Ltd | Cloth having moisture-permeability controllable by temperature |
| WO1994000631A1 (en) * | 1992-06-19 | 1994-01-06 | Komatsu Seiren Co., Ltd. | Moisture-permeable waterproof cloth and production thereof |
| US5692936A (en) * | 1992-06-19 | 1997-12-02 | Komatsu Seiven Co., Ltd. | Moisture-permeable waterproof fabric and process for producing the same |
| KR100315509B1 (en) * | 1995-12-01 | 2002-02-19 | 구광시 | Production of moisture-permeable waterproof cloth |
| KR100422461B1 (en) * | 1997-01-20 | 2004-07-31 | 코오롱티티에이 주식회사 | Water repellent and moisture permeable fabric having excellent environmental adaptation including improved thermal insulation at low temperature and improved moisture permeability at high temperature and its manufacturing method |
| KR100464785B1 (en) * | 1998-03-04 | 2005-04-06 | 주식회사 새 한 | Manufacturing method of dust-free medical forge by dry dot lamination processing |
| CN112626883A (en) * | 2021-01-28 | 2021-04-09 | 湘潭医卫职业技术学院 | Protective fabric for medical protective clothing and manufacturing method thereof |
| WO2022054886A1 (en) * | 2020-09-09 | 2022-03-17 | 株式会社hide kasuga 1896 | Composite linen and method for manufacturing composite linen |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5314527B2 (en) * | 2009-07-28 | 2013-10-16 | 旭化成ホームプロダクツ株式会社 | Food packaging material and rice ball packaging material |
| WO2014107878A1 (en) * | 2013-01-11 | 2014-07-17 | Dow Global Technologies Llc | Polyurethane dispersion based synthetic leathers |
-
1991
- 1991-06-12 JP JP03168640A patent/JP3074335B2/en not_active Expired - Fee Related
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05272061A (en) * | 1992-03-17 | 1993-10-19 | Kanebo Ltd | Cloth having moisture-permeability controllable by temperature |
| JP2582742B2 (en) * | 1992-03-17 | 1997-02-19 | 鐘紡株式会社 | Fabric whose moisture permeability is controlled by temperature |
| WO1994000631A1 (en) * | 1992-06-19 | 1994-01-06 | Komatsu Seiren Co., Ltd. | Moisture-permeable waterproof cloth and production thereof |
| US5692936A (en) * | 1992-06-19 | 1997-12-02 | Komatsu Seiven Co., Ltd. | Moisture-permeable waterproof fabric and process for producing the same |
| KR100315509B1 (en) * | 1995-12-01 | 2002-02-19 | 구광시 | Production of moisture-permeable waterproof cloth |
| KR100422461B1 (en) * | 1997-01-20 | 2004-07-31 | 코오롱티티에이 주식회사 | Water repellent and moisture permeable fabric having excellent environmental adaptation including improved thermal insulation at low temperature and improved moisture permeability at high temperature and its manufacturing method |
| KR100464785B1 (en) * | 1998-03-04 | 2005-04-06 | 주식회사 새 한 | Manufacturing method of dust-free medical forge by dry dot lamination processing |
| WO2022054886A1 (en) * | 2020-09-09 | 2022-03-17 | 株式会社hide kasuga 1896 | Composite linen and method for manufacturing composite linen |
| JP7085785B1 (en) * | 2020-09-09 | 2022-06-17 | 株式会社hide kasuga 1896 | Composite linen and production method of composite linen |
| CN112626883A (en) * | 2021-01-28 | 2021-04-09 | 湘潭医卫职业技术学院 | Protective fabric for medical protective clothing and manufacturing method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3074335B2 (en) | 2000-08-07 |
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