JPH04369277A - Multilayer piezoelectric actuator - Google Patents
Multilayer piezoelectric actuatorInfo
- Publication number
- JPH04369277A JPH04369277A JP3173235A JP17323591A JPH04369277A JP H04369277 A JPH04369277 A JP H04369277A JP 3173235 A JP3173235 A JP 3173235A JP 17323591 A JP17323591 A JP 17323591A JP H04369277 A JPH04369277 A JP H04369277A
- Authority
- JP
- Japan
- Prior art keywords
- electrodes
- piezoelectric actuator
- electrode
- exposed
- internal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000919 ceramic Substances 0.000 claims abstract description 27
- 239000011521 glass Substances 0.000 claims abstract description 11
- 238000009413 insulation Methods 0.000 claims description 9
- 239000011810 insulating material Substances 0.000 claims description 5
- 230000002093 peripheral effect Effects 0.000 claims description 3
- 229910001252 Pd alloy Inorganic materials 0.000 abstract description 3
- 238000005530 etching Methods 0.000 abstract description 3
- SWELZOZIOHGSPA-UHFFFAOYSA-N palladium silver Chemical compound [Pd].[Ag] SWELZOZIOHGSPA-UHFFFAOYSA-N 0.000 abstract description 3
- 229920000642 polymer Polymers 0.000 abstract description 2
- 230000003247 decreasing effect Effects 0.000 abstract 1
- 239000012212 insulator Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- 230000007423 decrease Effects 0.000 description 6
- 238000006073 displacement reaction Methods 0.000 description 5
- 238000013508 migration Methods 0.000 description 5
- 230000005012 migration Effects 0.000 description 5
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007772 electrode material Substances 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- NKZSPGSOXYXWQA-UHFFFAOYSA-N dioxido(oxo)titanium;lead(2+) Chemical compound [Pb+2].[O-][Ti]([O-])=O NKZSPGSOXYXWQA-UHFFFAOYSA-N 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- HFGPZNIAWCZYJU-UHFFFAOYSA-N lead zirconate titanate Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ti+4].[Zr+4].[Pb+2] HFGPZNIAWCZYJU-UHFFFAOYSA-N 0.000 description 1
- 229910052451 lead zirconate titanate Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Abstract
Description
【0001】0001
【産業上の利用分野】本発明は、電気エネルギーを変位
や力の機械エネルギーに変換する圧電アクチュエータに
関し、特に、複数の内部電極とセラミックスを一体焼結
した積層型圧電アクチュエータに関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a piezoelectric actuator that converts electrical energy into mechanical energy such as displacement or force, and more particularly to a laminated piezoelectric actuator in which a plurality of internal electrodes and ceramics are integrally sintered.
【0002】0002
【従来の技術】従来、精密位置決め装置や精密X−Yテ
ーブルのアクチュエータとして、ボイスコイルモータや
パルスモータ等の電磁式アクチュエータが使用されてい
たが、近年、位置決め精度、応答速度、消費電力等から
前記電磁式アクチュエータより優れている圧電アクチュ
エータが使用されつつある。圧電アクチュエータには大
別して積層型とバイモルフ型の2種類があり、積層型は
高変位精度と大発生力、バイモルフ型は発生力の値は小
さいが大変位量が得られるというそれぞれ特徴があり、
精密位置決め装置や精密X−Yテーブルのアクチュエー
タとしては積層型が多く用いられている。積層型圧電ア
クチュエータは、圧電セラミックス板と内部電極板を交
互に積層してセラミック積層体をなしている。積層型圧
電アクチュエータの変位量は圧電セラミックス板と内部
電極板の積層数と、印加される電圧の値に比例するので
、圧電セラミックス板厚を薄くし積層数を多くし、大き
な変位量で、かつ低電圧駆動化が可能なよう開発が進め
られている。また、積層型圧電アクチュエータの変位方
向と直交する圧電セラミックス板の断面積と内部電極板
の断面積とを一致する構造とすることで、内部の集中応
力を無くすことが可能であり、大発生力を得ることがで
きる。図2は積層型圧電アクチュエータの断面図を示す
が、図を参照して積層型圧電アクチュエータの構造を説
明する。一層置きに互いに対向する複数の内部電極22
a及び22bの縁部が露出した構造となっており、対向
する電極の端面は、夫々ガラス絶縁部23により外部電
極24と電気絶縁され、外部電極の外周は有機系の外装
樹脂25により覆われ、外部電極にリード線26が接続
された構造となっている。[Prior Art] Conventionally, electromagnetic actuators such as voice coil motors and pulse motors have been used as actuators for precision positioning devices and precision X-Y tables, but in recent years, electromagnetic actuators such as voice coil motors and pulse motors have Piezoelectric actuators, which are superior to the electromagnetic actuators, are being used. There are two types of piezoelectric actuators: the laminated type and the bimorph type.The laminated type has the characteristics of high displacement accuracy and large generated force, and the bimorph type has the characteristics of a small generated force value but a large amount of displacement.
Laminated type actuators are often used for precision positioning devices and precision X-Y tables. A laminated piezoelectric actuator has a ceramic laminate formed by alternately laminating piezoelectric ceramic plates and internal electrode plates. The amount of displacement of a laminated piezoelectric actuator is proportional to the number of layers of piezoelectric ceramic plates and internal electrode plates, and the value of the applied voltage. Development is underway to enable low-voltage operation. In addition, by creating a structure in which the cross-sectional area of the piezoelectric ceramic plate perpendicular to the displacement direction of the laminated piezoelectric actuator matches the cross-sectional area of the internal electrode plate, it is possible to eliminate internal concentrated stress and generate a large amount of force. can be obtained. FIG. 2 shows a cross-sectional view of the laminated piezoelectric actuator, and the structure of the laminated piezoelectric actuator will be explained with reference to the figure. A plurality of internal electrodes 22 facing each other in every other layer
The edges of the electrodes a and 22b are exposed, and the end faces of the opposing electrodes are electrically insulated from the external electrodes 24 by glass insulating parts 23, and the outer peripheries of the external electrodes are covered with an organic exterior resin 25. , a lead wire 26 is connected to the external electrode.
【0003】0003
【発明が解決しようとする課題】しかしながら、積層型
圧電アクチュエータの側面を有機系の外装樹脂で外装し
ても、積層型圧電アクチュエータ内への水分の侵入、透
過を防止することは困難であり、積層型圧電アクチュエ
ータに高湿度の環境下で直流電圧を印加し長時間使用す
ると、対向内部電極間の絶縁抵抗が低下し、甚だしくは
、短絡に至るという問題点がある。積層型圧電アクチュ
エータの高湿度環境下で直流電圧を印加して長時間使用
時の絶縁抵抗の低下の原因は、内部電極の表面露出部に
イオン性の物質や汚れが付着していることが考えられる
が、水分が有機系の外装樹脂の層を透過し、内部電極の
表面露出部に付着して、内部電極の成分として含まれる
銀をイオン化するマイグレーションが生じていることも
推定される。この時プラス極、マイナス極に於ては表面
露出内部電極プラス極:
Ag → Ag+ + e−
表面露出内部電極マイナス極:
Ag+ + e− → Ag
即ち、電極部分に於て上記反応が進行し、マイナス側の
表面露出電極部に銀が樹枝状に成長し、表面露出内部電
極のプラス極とマイナス極の電極間の実質的距離が短く
なり、内部電極間の絶縁抵抗が低下する。そこで、本発
明の技術的課題は、高湿度環境下で直流電圧を印加し長
時間使用しても、内部電極間の絶縁抵抗の低下を生ずる
ことのない構造の積層型圧電アクチュエータを提供する
ことである。[Problems to be Solved by the Invention] However, even if the side surfaces of the multilayer piezoelectric actuator are coated with an organic exterior resin, it is difficult to prevent moisture from entering or permeating the multilayer piezoelectric actuator. When a multilayer piezoelectric actuator is used for a long time with a DC voltage applied in a high humidity environment, there is a problem in that the insulation resistance between opposing internal electrodes decreases, and even short circuits occur. The reason for the decrease in insulation resistance of multilayer piezoelectric actuators when DC voltage is applied and used for long periods of time in a high humidity environment is thought to be due to the adhesion of ionic substances and dirt to the exposed surface of the internal electrodes. However, it is also presumed that migration occurs in which moisture permeates through the organic exterior resin layer and adheres to the exposed surface portion of the internal electrode, ionizing the silver contained as a component of the internal electrode. At this time, in the positive and negative electrodes, the surface-exposed internal electrode positive electrode: Ag → Ag+ + e- The surface-exposed internal electrode negative electrode: Ag+ + e- → Ag In other words, the above reaction proceeds in the electrode part, Silver grows in a dendritic manner on the surface-exposed electrode portion on the negative side, and the substantial distance between the positive and negative electrodes of the surface-exposed internal electrode becomes short, and the insulation resistance between the internal electrodes decreases. Therefore, the technical problem of the present invention is to provide a laminated piezoelectric actuator that has a structure that does not cause a decrease in insulation resistance between internal electrodes even when a DC voltage is applied and used for a long time in a high humidity environment. It is.
【0004】0004
【課題を解決するための手段】本発明は、断面形状に等
しい形状の複数の内部電極層を有する圧電セラミックス
焼結体で、前期内部電極の端部が表面に露出する周囲面
のうち、対向する二面で各々異なる内部電極上に一層置
きにガラス絶縁部により被覆され、更に該露出内部電極
とガラス絶縁部上でガラス絶縁部に覆われない一層置き
の内部電極に電気的に接続するストライプ状の外部電極
が形成された構造の積層型圧電アクチュエータにおいて
、ガラス絶縁部および外部電極が形成されていない内部
電極の端部が表面に露出する周囲面上で、外部電極を通
じてプラスの電圧が印加される内部電極部を、セラミッ
クス表面よりセラミックスの内部へ少なくとも10ミク
ロンないし200ミクロン後退させ、かつ該後退部分を
高分子有機絶縁材で充填した構造としたことを特徴とす
る積層型圧電アクチュエータである。[Means for Solving the Problems] The present invention provides a piezoelectric ceramic sintered body having a plurality of internal electrode layers having a shape equal to the cross-sectional shape. a stripe which is covered with a glass insulating part in every other layer on two different internal electrodes, and further electrically connected to the exposed internal electrode and every other internal electrode not covered with the glass insulating part on the glass insulating part; In a laminated piezoelectric actuator with a structure in which a shaped external electrode is formed, a positive voltage is applied through the external electrode on the peripheral surface where the glass insulation part and the end of the internal electrode where the external electrode is not formed are exposed to the surface. A multilayer piezoelectric actuator characterized in that an internal electrode portion is set back from the surface of the ceramic by at least 10 to 200 microns into the ceramic, and the set back portion is filled with a polymeric organic insulating material. .
【0005】[0005]
【作用】積層型圧電アクチュエータにおいて、対向する
複数の内部電極が表面に露出する部分の構造は高湿度環
境下での性能に重要な影響を与える。本発明の構造の積
層型圧電アクチュエータは、前記マイグレーション反応
がプラスの電圧が印加される電極材料のイオン化から開
始することに着目し、セラミック側面に露出する対抗内
部電極のうち、プラスの電圧が印加される電極のみを電
気化学的にエッチング処理してセラミックス表面から少
なくとも10ミクロン以上200ミクロン程後退した構
造とし、表面に露出する対向する内部電極間の沿面距離
を大きくし、しかる後に、後退して出来る空隙部を水分
の侵入防止と機械的強度確保のため、高分子絶縁材料で
充填された構造とする。積層型圧電アクチュエータに於
て、特に内部電極とセラミックスが一体焼結されたアク
チュエータでは、セラミック側面に露出する内部電極の
間隔が約百ミクロンと狭いため、有機系の外装樹脂を透
過してセラミック表面に到達した水分が、前記マイグレ
ーションを起こし、積層型圧電アクチュエータの絶縁抵
抗の低下の原因となっていたが、本発明の構造とするこ
とにより、表面に露出する対向内部電極間の沿面距離が
大きくなった分だけマイグレーションの発生を防止する
効果を向上し、高湿度環境下で直流電圧を印加し長時間
使用しても、内部電極間の絶縁抵抗の低下を生じさせる
ことのないような積層型圧電アクチュエータを提供する
ことが可能となる。なおセラミックス表面からのプラス
電極の後退させる距離は10ミクロン以上あればマイグ
レーションを防止する効果が大となるが後退させる距離
が200ミクロン以上となると樹脂の充填が充分に行わ
れず、又セラミックス部分に割れを生じる故、セラミッ
クス面からプラス電極を除去する距離は10ミクロンな
いし200ミクロンが好適である。[Operation] In a laminated piezoelectric actuator, the structure of the portion where a plurality of opposing internal electrodes are exposed on the surface has an important influence on performance in a high humidity environment. The laminated piezoelectric actuator having the structure of the present invention focuses on the fact that the migration reaction starts from ionization of the electrode material to which a positive voltage is applied, and that the internal electrode exposed to the ceramic side surface is connected to the electrode material to which a positive voltage is applied. Electrochemically etching only the electrodes to be etched to create a structure that is recessed by at least 10 microns or more and about 200 microns from the ceramic surface, increasing the creepage distance between the opposing internal electrodes exposed on the surface, and then recessing. The resulting voids are filled with polymeric insulating material to prevent moisture from entering and ensure mechanical strength. In multilayer piezoelectric actuators, especially those in which the internal electrodes and ceramics are integrally sintered, the gap between the internal electrodes exposed on the side of the ceramic is narrow, about 100 microns, so the organic exterior resin can be penetrated through the ceramic surface. The moisture that reaches the surface causes the migration, which causes a decrease in the insulation resistance of the laminated piezoelectric actuator.However, by adopting the structure of the present invention, the creepage distance between the opposing internal electrodes exposed on the surface is increased. This is a multilayer type that improves the effectiveness of preventing migration, and does not cause a drop in insulation resistance between internal electrodes even when used for long periods of time with DC voltage applied in a high humidity environment. It becomes possible to provide a piezoelectric actuator. Note that if the distance the positive electrode is retreated from the ceramic surface is 10 microns or more, it will have a great effect in preventing migration, but if the distance it is retreated is 200 microns or more, the resin will not be filled sufficiently, and the ceramic part may crack. Therefore, the distance to remove the positive electrode from the ceramic surface is preferably 10 to 200 microns.
【0006】[0006]
【実施例】以下、本発明の実施例について図面を参照し
て説明する。図1に本発明による積層型圧電アクチュエ
ータを示す。ジルコンチタン酸鉛系圧電性セラミックス
11と銀パラジウム合金の内部電極12が交互に積層し
た構造となっており、内部電極の端面は、交互にガラス
絶縁部15により対極となる外部電極13と電気的に絶
縁されている。実施例に用いた積層型圧電アクチュエー
タの寸法は、断面が5mm×5mmで長さが18mm、
内部電極間隔が115μm、内部電極積層数が150枚
である。プラスの電圧が印加される内部電極12aは、
セラミックスの表面でプラス電位を接続する外部電極を
形成した後、硝酸銀等の電解液中でプラス電位を接続す
る外部電極と別途に設けた電極の間で電気化学的にエッ
チングされる。本発明の試料ではセラミックス内部へ後
退した深さを10ミクロンとしており、該後退部へエポ
キシ系樹脂等の高分子有機絶縁材17を減圧等によって
充填し固化されている。しかる後に、リード線を半田付
けし、エポキシ系塗料で外装し積層型圧電アクチュエー
タとした。Embodiments Hereinafter, embodiments of the present invention will be described with reference to the drawings. FIG. 1 shows a laminated piezoelectric actuator according to the present invention. It has a structure in which piezoelectric ceramics 11 based on lead zirconate titanate and internal electrodes 12 made of a silver-palladium alloy are alternately laminated, and the end surfaces of the internal electrodes are electrically connected to the external electrodes 13, which are opposite electrodes, by means of glass insulating parts 15 alternately. is insulated. The dimensions of the laminated piezoelectric actuator used in the examples were 5 mm x 5 mm in cross section and 18 mm in length.
The internal electrode interval is 115 μm, and the number of internal electrode layers is 150. The internal electrode 12a to which a positive voltage is applied is
After forming an external electrode for connecting a positive potential on the surface of the ceramic, electrochemical etching is performed between the external electrode for connecting a positive potential and a separately provided electrode in an electrolytic solution such as silver nitrate. In the sample of the present invention, the depth of recess into the ceramic is 10 microns, and the recessed portion is filled with a polymeric organic insulating material 17 such as epoxy resin by reducing pressure or the like and solidified. After that, the lead wires were soldered and covered with epoxy paint to form a laminated piezoelectric actuator.
【0007】本発明の効果を確認するため、作製した試
料を恒温高湿試験槽中で、直流電圧100ボルトを印加
して、長期エージングを実施した。環境条件は、温度4
0℃に於て90%相対湿度の条件とした。試験結果を表
1に示す。比較のため、従来の製造方法で作製した試料
も同時に試験を実施した。試料数は、各100個である
。In order to confirm the effects of the present invention, the prepared samples were subjected to long-term aging in a constant temperature and high humidity test chamber by applying a DC voltage of 100 volts. The environmental conditions are temperature 4
The conditions were 0°C and 90% relative humidity. The test results are shown in Table 1. For comparison, samples manufactured using conventional manufacturing methods were also tested at the same time. The number of samples was 100 each.
【表1】
表1の結果より、明らかに本発明による積層型圧電
アクチュエータとすることにより、恒温高湿の環境下で
の長期エージングに於て従来例に比較し故障率が非常に
少なく、長寿命化が達成されていることを示す。[Table 1] From the results in Table 1, it is clear that by using the laminated piezoelectric actuator according to the present invention, the failure rate is extremely low compared to the conventional example during long-term aging in a constant temperature and high humidity environment. Indicates that longevity has been achieved.
【0008】[0008]
【発明の効果】以上説明したように、本発明によるプラ
ス側電極端面をセラミックス面より20ミクロンないし
200ミクロン程除去し、プラス側電極端面を露出せず
、しかも除去した部分に樹脂を充填した構造の積層型圧
電アクチュエータとすることにより、高湿度環境下で直
流電圧を印加し長時間使用しても、電気絶縁抵抗の低下
が生じない長寿命の積層型圧電アクチュエータを提供で
きる。As explained above, the present invention has a structure in which the positive side electrode end face is removed by approximately 20 to 200 microns from the ceramic surface, the positive side electrode end face is not exposed, and the removed portion is filled with resin. By using the laminated piezoelectric actuator as described above, it is possible to provide a long-life laminated piezoelectric actuator in which electrical insulation resistance does not decrease even when a DC voltage is applied and used for a long time in a high humidity environment.
【図1】本発明による積層型圧電アクチュエータの外観
斜視図。FIG. 1 is an external perspective view of a laminated piezoelectric actuator according to the present invention.
【図2】従来の積層型圧電アクチュエータの構造を示す
断面図。FIG. 2 is a cross-sectional view showing the structure of a conventional laminated piezoelectric actuator.
11 ジルコンチタン酸鉛系圧電性セラミックス
12 銀パラジウム合金の内部電極12a プ
ラスの電圧が印加される内部電極13 外部電極
14 外装用エポキシ樹脂
15,23 ガラス絶縁部
16 リード線
17 高分子有機絶縁材
21 圧電セラミックス
22a,22b 内部電極
24 外部電極
25 外装樹脂
26 リード線11 Zircon lead titanate piezoelectric ceramic 12 Silver-palladium alloy internal electrode 12a Internal electrode 13 to which a positive voltage is applied External electrode 14 Exterior epoxy resin 15, 23 Glass insulation part 16 Lead wire 17 Polymer organic insulating material 21 Piezoelectric ceramics 22a, 22b Internal electrode 24 External electrode 25 Exterior resin 26 Lead wire
Claims (1)
極層を有する圧電セラミックス焼結体で、前期内部電極
の端部が表面に露出する周囲面のうち、対向する二面で
各々異なる内部電極上に一層置きにガラス絶縁部により
被覆され、更に該露出内部電極とガラス絶縁部上でガラ
ス絶縁部に覆われない一層置きの内部電極に電気的に接
続するストライプ状の外部電極が形成された構造の積層
型圧電アクチュエータにおいて、ガラス絶縁部および外
部電極が形成されていない内部電極の端部が表面に露出
する周囲面上で、外部電極を通じてプラスの電圧が印加
される内部電極部を、セラミックス表面よりセラミック
スの内部へ少なくとも10ミクロンないし200ミクロ
ン後退させ、かつ該後退部分を高分子有機絶縁材で充填
した構造としたことを特徴とする積層型圧電アクチュエ
ータ。1. A piezoelectric ceramic sintered body having a plurality of internal electrode layers having the same shape as the cross-sectional shape, wherein two opposing surfaces of the peripheral surfaces where the ends of the internal electrodes are exposed have different internal electrodes. Striped external electrodes were formed on the exposed internal electrodes and electrically connected to the internal electrodes in every other layer not covered by the glass insulating parts on the exposed internal electrodes and the glass insulating parts. In the laminated piezoelectric actuator structure, the internal electrode part to which a positive voltage is applied through the external electrode is made of ceramic on the peripheral surface where the end of the internal electrode where the glass insulation part and the external electrode are not formed is exposed. A laminated piezoelectric actuator characterized by having a structure in which the ceramic is recessed from the surface by at least 10 to 200 microns, and the retracted portion is filled with a polymeric organic insulating material.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP03173235A JP3102580B2 (en) | 1991-06-17 | 1991-06-17 | Multilayer piezoelectric actuator |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP03173235A JP3102580B2 (en) | 1991-06-17 | 1991-06-17 | Multilayer piezoelectric actuator |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH04369277A true JPH04369277A (en) | 1992-12-22 |
JP3102580B2 JP3102580B2 (en) | 2000-10-23 |
Family
ID=15956661
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP03173235A Expired - Fee Related JP3102580B2 (en) | 1991-06-17 | 1991-06-17 | Multilayer piezoelectric actuator |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP3102580B2 (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011258681A (en) * | 2010-06-08 | 2011-12-22 | Nec Tokin Corp | Laminated piezoelectric actuator and manufacturing method therefor |
US8384271B2 (en) | 2009-11-16 | 2013-02-26 | Samsung Electronics Co., Ltd. | Electroactive polymer actuator and method of manufacturing the same |
EP2587563A2 (en) | 2005-10-28 | 2013-05-01 | Kyocera Corporation | Multi-layer piezoelectric element and injection apparatus using the same |
US8564181B2 (en) | 2010-12-07 | 2013-10-22 | Samsung Electronics Co., Ltd. | Electroactive polymer actuator and method of manufacturing the same |
-
1991
- 1991-06-17 JP JP03173235A patent/JP3102580B2/en not_active Expired - Fee Related
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2587563A2 (en) | 2005-10-28 | 2013-05-01 | Kyocera Corporation | Multi-layer piezoelectric element and injection apparatus using the same |
US8384271B2 (en) | 2009-11-16 | 2013-02-26 | Samsung Electronics Co., Ltd. | Electroactive polymer actuator and method of manufacturing the same |
JP2011258681A (en) * | 2010-06-08 | 2011-12-22 | Nec Tokin Corp | Laminated piezoelectric actuator and manufacturing method therefor |
US8564181B2 (en) | 2010-12-07 | 2013-10-22 | Samsung Electronics Co., Ltd. | Electroactive polymer actuator and method of manufacturing the same |
Also Published As
Publication number | Publication date |
---|---|
JP3102580B2 (en) | 2000-10-23 |
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