JPH04316546A - Repellent for land invertebrate - Google Patents
Repellent for land invertebrateInfo
- Publication number
- JPH04316546A JPH04316546A JP14886491A JP14886491A JPH04316546A JP H04316546 A JPH04316546 A JP H04316546A JP 14886491 A JP14886491 A JP 14886491A JP 14886491 A JP14886491 A JP 14886491A JP H04316546 A JPH04316546 A JP H04316546A
- Authority
- JP
- Japan
- Prior art keywords
- repellent
- mixture
- base material
- sheet
- repellent material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000002940 repellent Effects 0.000 title claims abstract description 97
- 239000005871 repellent Substances 0.000 title claims abstract description 97
- 239000000463 material Substances 0.000 claims abstract description 74
- 239000000203 mixture Substances 0.000 claims abstract description 45
- 229920005989 resin Polymers 0.000 claims abstract description 21
- 239000011347 resin Substances 0.000 claims abstract description 21
- 239000007788 liquid Substances 0.000 claims abstract description 20
- 229920003002 synthetic resin Polymers 0.000 claims abstract description 15
- 239000000057 synthetic resin Substances 0.000 claims abstract description 15
- JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000007787 solid Substances 0.000 claims abstract description 6
- 229920003051 synthetic elastomer Polymers 0.000 claims abstract description 6
- 239000005061 synthetic rubber Substances 0.000 claims abstract description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 45
- 239000002904 solvent Substances 0.000 claims description 9
- 239000004745 nonwoven fabric Substances 0.000 claims description 5
- -1 phosphate ester Chemical class 0.000 claims description 5
- 239000002759 woven fabric Substances 0.000 claims description 5
- 229910019142 PO4 Inorganic materials 0.000 claims description 4
- 239000010452 phosphate Substances 0.000 claims description 4
- 231100000419 toxicity Toxicity 0.000 abstract description 8
- 230000001988 toxicity Effects 0.000 abstract description 8
- 150000003014 phosphoric acid esters Chemical class 0.000 abstract description 4
- 230000000740 bleeding effect Effects 0.000 abstract description 3
- 230000001846 repelling effect Effects 0.000 abstract description 3
- 238000004090 dissolution Methods 0.000 abstract 1
- 230000001747 exhibiting effect Effects 0.000 abstract 1
- 241000237858 Gastropoda Species 0.000 description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 12
- 241000196324 Embryophyta Species 0.000 description 10
- 230000000694 effects Effects 0.000 description 10
- 239000002250 absorbent Substances 0.000 description 9
- 230000002745 absorbent Effects 0.000 description 7
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 229940079593 drug Drugs 0.000 description 5
- 239000003814 drug Substances 0.000 description 5
- 238000000465 moulding Methods 0.000 description 5
- 239000003973 paint Substances 0.000 description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 4
- 235000013399 edible fruits Nutrition 0.000 description 4
- 229910052698 phosphorus Inorganic materials 0.000 description 4
- 239000011574 phosphorus Substances 0.000 description 4
- 239000013055 pulp slurry Substances 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 3
- 239000010893 paper waste Substances 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- NFACJZMKEDPNKN-UHFFFAOYSA-N trichlorfon Chemical compound COP(=O)(OC)C(O)C(Cl)(Cl)Cl NFACJZMKEDPNKN-UHFFFAOYSA-N 0.000 description 3
- 239000005956 Metaldehyde Substances 0.000 description 2
- ISRUGXGCCGIOQO-UHFFFAOYSA-N Rhoden Chemical compound CNC(=O)OC1=CC=CC=C1OC(C)C ISRUGXGCCGIOQO-UHFFFAOYSA-N 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 239000005667 attractant Substances 0.000 description 2
- 229940112021 centrally acting muscle relaxants carbamic acid ester Drugs 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- JSKZWIGBDHYSGI-UCSXVCBISA-L disodium;(6r,7r)-7-[[(2e)-2-(2-amino-1,3-thiazol-4-yl)-2-[1-[2-(3,4-dihydroxybenzoyl)hydrazinyl]-2-methyl-1-oxopropan-2-yl]oxyiminoacetyl]amino]-3-[(2-carboxylato-5-methyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-yl)sulfanylmethyl]-8-oxo-5-thia-1-azabicyclo[4.2. Chemical compound [Na+].[Na+].N([C@H]1[C@@H]2N(C1=O)C(=C(CS2)CSC1=CC(=NC2=NC(=NN21)C([O-])=O)C)C([O-])=O)C(=O)C(\C=1N=C(N)SC=1)=N\OC(C)(C)C(=O)NNC(=O)C1=CC=C(O)C(O)=C1 JSKZWIGBDHYSGI-UCSXVCBISA-L 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- GKKDCARASOJPNG-UHFFFAOYSA-N metaldehyde Chemical compound CC1OC(C)OC(C)OC(C)O1 GKKDCARASOJPNG-UHFFFAOYSA-N 0.000 description 2
- 239000012046 mixed solvent Substances 0.000 description 2
- 239000002362 mulch Substances 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- 230000002459 sustained effect Effects 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 244000020190 Azalea indica Species 0.000 description 1
- 235000002498 Azalea indica Nutrition 0.000 description 1
- 240000007124 Brassica oleracea Species 0.000 description 1
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 description 1
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 description 1
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 1
- 241001672694 Citrus reticulata Species 0.000 description 1
- 244000000626 Daucus carota Species 0.000 description 1
- 235000002767 Daucus carota Nutrition 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- VEMKTZHHVJILDY-UXHICEINSA-N bioresmethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-UXHICEINSA-N 0.000 description 1
- CVXBEEMKQHEXEN-UHFFFAOYSA-N carbaryl Chemical compound C1=CC=C2C(OC(=O)NC)=CC=CC2=C1 CVXBEEMKQHEXEN-UHFFFAOYSA-N 0.000 description 1
- 230000031902 chemoattractant activity Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 230000000816 effect on animals Effects 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- NPERTKSDHFSDLC-UHFFFAOYSA-N ethenol;prop-2-enoic acid Chemical compound OC=C.OC(=O)C=C NPERTKSDHFSDLC-UHFFFAOYSA-N 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000002147 killing effect Effects 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000003415 peat Substances 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000004382 potting Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 230000002522 swelling effect Effects 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【０００１】0001
【産業上の利用分野】この発明は、植物の葉や花及び果
実などを食べるナメクジやカタツムリなどの陸生無脊椎
動物から、前記植物を保護するために使用する陸生無脊
椎動物の忌避材に関する。FIELD OF THE INVENTION This invention relates to a repellent material for terrestrial invertebrates used to protect plants from terrestrial invertebrates such as slugs and snails that eat the leaves, flowers, and fruits of plants.
【０００２】0002
【従来の技術】従来、ナメクジやカタツムリなどの陸性
無脊椎動物の誘殺剤としてのメタアルデヒドを有効成分
とした顆粒タイプ又は有機リン剤及び合成ピレスロイド
を主成分とするスプレータイプのものが、既に市販され
ている。[Prior Art] Conventionally, granule-type products containing metaldehyde as an active ingredient or spray-type products containing organic phosphorus agents and synthetic pyrethroids as main ingredients have already been used as attractants for terrestrial invertebrates such as slugs and snails. It is commercially available.
【０００３】0003
【発明が解決しようとする課題】ところで、前記誘殺剤
の有効成分であるメタアルデヒドは、水溶性であること
から持続効果に乏しく、また、スプレータイプのものに
は固着剤となるバインダーが含まれていないため持続性
がなく、特にナメクジなどがよく現われる雨上りには、
雨水により洗い流されてしまって、良好な殺傷効果が得
られない問題があった。[Problems to be Solved by the Invention] By the way, metaldehyde, which is the active ingredient in the above-mentioned attractant, is water-soluble and therefore has poor long-lasting effects, and spray-type products do not contain a binder that acts as a fixing agent. It is not sustainable, especially after rain, when slugs and the like often appear.
There was a problem in that it was washed away by rainwater, making it impossible to obtain a good killing effect.
【０００４】本発明は、以上の如き問題を解決するため
に、ナメクジなどの陸生無脊椎動物に対して有効な接触
毒性を有する有機リン酸エステル及びその誘導体又はカ
ルバミド酸エステル及びその誘導体から成る忌避薬剤を
合成樹脂またはゴムから成る基材の組成物に混合して混
合物を形成し、該混合物から前記忌避薬剤を徐々にブリ
ード又は溶出させることにより、長期に亙って優れた忌
避効果を持続できる陸生無脊椎動物の忌避材を提供する
ことを目的としている。[0004] In order to solve the above problems, the present invention provides a repellent comprising an organic phosphate ester and its derivatives or a carbamic acid ester and its derivative, which has effective contact toxicity against terrestrial invertebrates such as slugs. An excellent repellent effect can be maintained over a long period of time by mixing a drug with a base composition made of synthetic resin or rubber to form a mixture, and gradually bleeding or eluting the repellent drug from the mixture. The purpose is to provide a repellent for terrestrial invertebrates.
【０００５】[0005]
【課題を解決するための手段】上記目的を達成するため
に、本発明は、主成分が合成樹脂、ゴムまたはパルプか
ら成る基材１の組成物に、接触毒性を有する有機リン酸
エステル及びその誘導体又はカルバミド酸エステル及び
その誘導体から成る忌避薬剤２を混合して、固形又は液
状の混合物を形成したものである。[Means for Solving the Problems] In order to achieve the above object, the present invention provides a base material 1 composition whose main component is synthetic resin, rubber or pulp, and which includes an organic phosphate ester having contact toxicity and an organic phosphate ester thereof. A solid or liquid mixture is formed by mixing a repellent agent 2 consisting of a derivative or a carbamic acid ester and its derivative.
【０００６】前記混合物には、該混合物から前記忌避薬
剤２を徐々に長期に亙ってより安定良くブリード又は、
溶出させるため高吸水性樹脂３を混合することが効果的
である。[0006] The repellent agent 2 can be gradually and stably bled from the mixture over a long period of time, or
It is effective to mix super absorbent resin 3 for elution.
【０００７】また、前記混合物を固形として用いる場合
、該混合物を使用する対象物に応じて、シート状に成形
したり、或いは栽培用の容器又は栽培台を載置可能な大
きさのブロック形状に成形して用いる。尚、前記混合物
をシート状に成形する場合には、その片面に合成樹脂シ
ートを貼着するのが好ましい。[0007] When the mixture is used as a solid, it may be formed into a sheet shape or into a block shape large enough to hold a cultivation container or cultivation stand, depending on the object for which the mixture is used. Shape and use. In addition, when forming the said mixture into a sheet shape, it is preferable to stick a synthetic resin sheet to one side.
【０００８】又基材１として揮発性を有する溶剤を含む
液状合成樹脂を用いることにより、混合物を液状のまゝ
対象物やその周囲に塗布又は散布して使用可能であり、
また、この液状混合物を織布や不織布に含浸させて用い
てもよい。[0008] Furthermore, by using a liquid synthetic resin containing a volatile solvent as the base material 1, it is possible to use the mixture in liquid form by applying or spraying it on the object or its surroundings.
Further, this liquid mixture may be used by impregnating a woven fabric or a nonwoven fabric.
【０００９】[0009]
【作用】しかして、前記基材１と前記忌避薬剤２との混
合物で成形された忌避材は、初期段階では該忌避材の外
表面に付着する前記忌避薬剤２が、ナメクジなどの陸生
無脊椎動物に対して忌避作用を及ぼし、また散水や降雨
などにより前記忌避薬剤２が洗い流されることがあって
も前記基材１内に混入された忌避薬剤２が、前記忌避材
の外表面へ経時的に徐々にブリードまたは溶出され、こ
のブリードまたは溶出された忌避薬剤２が陸生無脊椎動
物に忌避作用を及ぼすのであり、従って陸生無脊椎動物
に対する忌避作用は、長期に亙って持続されるのである
。[Function] Therefore, in the initial stage of the repellent material formed from the mixture of the base material 1 and the repellent agent 2, the repellent agent 2 attached to the outer surface of the repellent material is used to protect against terrestrial invertebrates such as slugs. It has a repellent effect on animals, and even if the repellent agent 2 is washed away by water spraying or rainfall, the repellent agent 2 mixed into the base material 1 is transferred to the outer surface of the repellent material over time. The repellent agent 2 is gradually bled or eluted, and this bleed or eluted repellent agent 2 exerts a repellent effect on terrestrial invertebrates, and therefore the repellent effect on terrestrial invertebrates is sustained over a long period of time. .
【００１０】また、前記基材１と前記忌避薬剤２との混
合物に、前述した高吸水性樹脂３を混合した場合には、
この高吸水性樹脂３が散水や降雨時などの水分を吸水し
たとき、その体積が大きく膨潤されることから、前記忌
避材の表面に多数の細かい亀裂が発生するのであり、従
って、該各亀裂から前記基材１に混入された前記忌避薬
剤２が、外表面に徐々にブリード又は溶出され、またブ
リード又は溶出された一部の忌避薬剤２は前記高吸水性
樹脂３に吸収保持され、該高吸水性樹脂３の体積減少に
伴い再度ブリード又は溶出されることゝなって、前記忌
避薬剤２による忌避効果が長期に亙つてより安定的に持
続されるのである。[0010] Furthermore, when the above-mentioned super absorbent resin 3 is mixed into the mixture of the base material 1 and the repellent agent 2,
When this super-absorbent resin 3 absorbs water from water spraying or rain, its volume swells to a large extent, resulting in a large number of fine cracks on the surface of the repellent material. The repellent agent 2 mixed into the base material 1 is gradually bled or eluted to the outer surface, and some of the repellent agent 2 that has been bled or eluted is absorbed and retained by the superabsorbent resin 3. As the volume of the superabsorbent resin 3 decreases, it bleeds or elutes again, and the repellent effect of the repellent agent 2 is maintained more stably over a long period of time.
【００１１】[0011]
【実施例】以下本発明に係る陸生無脊椎動物の忌避材を
、図１に示した実施例に基づいて説明する。EXAMPLES The terrestrial invertebrate repellent material according to the present invention will be explained below based on the example shown in FIG.
【００１２】図１において、１は主成分が合成樹脂又は
ゴムから成る基材であり、２はこの基材１の組成物に混
合する忌避薬剤であって、図１の実施例では、前記基材
１の組成物に忌避薬剤２を混合した混合物をシート状に
成形したものである。尚、前記基材１は忌避薬剤２の担
体として該忌避薬剤２を経時的に徐々にブリード又は溶
出させるために使用するものであって、前記基材１に採
用する合成樹脂として例えば塩化ビニール樹脂、ポリプ
ロピレン樹脂、ポリエチレン樹脂、ウレタン樹脂又はポ
リアミド樹脂などを使用し、ゴムとしては例えばブタヂ
エンゴム、ポリイソプロピレンゴムなどを使用し、パル
プとしては例えばレーヨン紙の原料などを使用するので
ある。In FIG. 1, 1 is a base material whose main component is synthetic resin or rubber, and 2 is a repellent agent to be mixed with the composition of this base material 1. In the embodiment shown in FIG. A mixture obtained by mixing the composition of material 1 and repellent agent 2 is molded into a sheet shape. The base material 1 is used as a carrier for the repellent agent 2 to gradually bleed or elute the repellent agent 2 over time, and the synthetic resin used for the base material 1 is, for example, vinyl chloride resin. , polypropylene resin, polyethylene resin, urethane resin, or polyamide resin, the rubber used is butadiene rubber, polyisopropylene rubber, etc., and the pulp used is, for example, a raw material for rayon paper.
【００１３】また、前記忌避薬剤２としては、接触毒性
を有する有機リン酸エステル及びその誘導体（有機リン
剤）、カルバミド酸エステル及びその誘導体（カーバメ
ート系薬剤）を用いる。[0013] As the repellent agent 2, organic phosphoric acid esters and their derivatives (organic phosphorus agents) and carbamic acid esters and their derivatives (carbamate drugs), which have contact toxicity, are used.
【００１４】具体的には、有機リン剤としては、例えば
日本特殊農薬製造（株）製のディプテレックス（ジメチ
ルー２，２，２‐トリクロル‐１‐ヒドロキシエチルホ
スホネート）などを使用し、カーバメート系薬剤として
は、例えば日産化学（株）製のナック（１‐ナフチル‐
Ｎ‐メチルカーバメート）、サンケイ化学（株）製のサ
ンサイド（２‐イソプロポキシフェニル‐Ｎメチルカー
バメート）などを使用する。Specifically, as an organic phosphorus agent, for example, Dipterex (dimethyl-2,2,2-trichloro-1-hydroxyethylphosphonate) manufactured by Japan Tokushu Nohyaku Seizo Co., Ltd. is used, and as a carbamate type agent, For example, NAC (1-naphthyl-
N-methyl carbamate), Sancide (2-isopropoxyphenyl-N-methyl carbamate) manufactured by Sankei Chemical Co., Ltd., etc. are used.
【００１５】以上説明した各種忌避薬剤２は、使用する
前記基材１の成形加工条件（特に成形加工温度）で変質
しないものを、選択使用するのである。The various repellent agents 2 described above are selected from those that do not change in quality under the molding conditions (particularly the molding temperature) of the base material 1 used.
【００１６】また前記基材１には、以上の如き忌避薬剤
２と共に高吸水性樹脂３を混合して、該高吸水性樹脂３
の水分吸収に伴う膨潤作用で、前記基材１の表面に亀裂
を発生させ、この亀裂から前記基材１に混入された前記
忌避薬剤２を徐々に溶出させるかまたはブリードを調整
させることにより、忌避効果を長期にわたってより安定
的に持続させることが可能である。以上のことを目的と
して添加される前記高吸水性樹脂３としては、例えば、
三洋化成工業（株）製のサンウエットＩＭ‐１０００Ｍ
ＰＳ、日本合成化学工業（株）製のＧＰ‐１、日本触媒
化学工業（株）のアクアリックＣＡＷ、住友化学工業（
株）製のスミカゲルＰ‐１０２０、及びクラレイソプレ
ンケミカル（株）製のＫＥゲル２０１ＫＦ２などを用い
る。[0016] Also, a super absorbent resin 3 is mixed with the above-mentioned repellent agent 2 in the base material 1.
By generating cracks on the surface of the base material 1 due to the swelling effect accompanying water absorption, and gradually eluting the repellent agent 2 mixed into the base material 1 from the cracks or adjusting the bleed, It is possible to maintain the repellent effect more stably over a long period of time. As the super absorbent resin 3 added for the above purpose, for example,
Sunwet IM-1000M manufactured by Sanyo Chemical Industries, Ltd.
PS, GP-1 manufactured by Nippon Gosei Kagaku Kogyo Co., Ltd., Aqualic CAW manufactured by Nippon Shokubai Chemical Co., Ltd., Sumitomo Chemical Co., Ltd.
Sumikagel P-1020 manufactured by Co., Ltd. and KE Gel 201KF2 manufactured by Clarei Soprene Chemical Co., Ltd. are used.
【００１７】尚、図１に示したように基材１の組成物に
、忌避薬剤２と高吸水性樹脂３とを混合する他、図２に
示したように前記基材１の組成物に、忌避薬剤２のみを
混合してもよい。In addition to mixing the repellent agent 2 and super absorbent resin 3 into the composition of the base material 1 as shown in FIG. 1, as shown in FIG. , only the repellent agent 2 may be mixed.
【００１８】しかして、本発明忌避材は以上説明した基
材１の組成物に、忌避薬剤２のみ又は忌避薬剤２と高吸
水性樹脂３とを混合して、図１〜４に示すごとくシート
状に成形したり、或いは図９に示したように植物栽培用
の容器又は図５，６に示したように植物栽培台を載置可
能な所定以上の大きさから成るブロック状の立方体に成
形するか、又は、液状として用いるのである。[0018]The repellent material of the present invention is prepared by mixing only the repellent agent 2 or the repellent agent 2 and the superabsorbent resin 3 in the composition of the base material 1 described above, and forming a sheet as shown in FIGS. 1 to 4. Or, as shown in Figure 9, it can be molded into a block-shaped cube of a specified size or larger on which a plant cultivation container or a plant cultivation stand can be placed, as shown in Figures 5 and 6. Alternatively, it can be used in liquid form.
【００１９】使用法としては、シート状に成形する場合
には、図１，２に示すごとく薄肉状のシートに加工した
ものをそのまゝ用いるか又はその片面に主として合成樹
脂から成る保持シートを貼着して用いるのであって、こ
の薄肉シート状の忌避材Ｓを適宜大きさに切り取り、植
物の根の囲りや植木鉢等の下に敷いて用いたり、或いは
農業用マルチシートとして、野菜などを被覆する如く用
いたり、さらに、前記シート状に形成した忌避材Ｓを約
１０ｃｍ幅の細幅テープ状に裁断し、みかんなどの果樹
の幹に直接巻付けて陸生無脊椎動物の忌避材Ｓとして使
用するのである。この他、図３に示した如く、シート状
としたものを小片５に裁断し、これら小片５を薄肉のフ
ィルム４の一側面に融着手段又は接着手段などで飛び模
様状に一体に突設し、これら各小片５により忌避効果を
発揮させるように構成してもよいし、さらには、図４に
示した如く、混合物をシート状に成し、このシート状物
の一側面に、不織布から成る防水性に優れたベース部材
６を張付けて形成してもよい。尚、前記シート状に成形
する場合、その厚さは任意にできるのであり、従って、
フィルム状シートも含むものである。[0019] When molding into a sheet, as shown in Figs. 1 and 2, a thin sheet processed into a sheet may be used as is, or a holding sheet mainly made of synthetic resin may be placed on one side of the sheet. This thin sheet-like repellent material S can be cut to an appropriate size and used by placing it around plant roots or under flower pots, etc., or as an agricultural mulch sheet for vegetables, etc. It can be used as a covering, or it can be used as a repellent material S for terrestrial invertebrates by cutting the repellent material S formed into a sheet shape into a narrow tape approximately 10 cm wide and wrapping it directly around the trunk of a fruit tree such as a mandarin orange. Use it. In addition, as shown in FIG. 3, a sheet-like material is cut into small pieces 5, and these small pieces 5 are integrally protruded in a skip pattern on one side of the thin film 4 by fusing means or adhesive means. However, the structure may be such that each of these small pieces 5 exerts a repellent effect. Furthermore, as shown in FIG. 4, the mixture may be formed into a sheet, and one side of this sheet may be coated with It may be formed by attaching a base member 6 having excellent waterproof properties. In addition, when forming into the sheet shape, the thickness can be arbitrarily determined, and therefore,
It also includes film-like sheets.
【００２０】また、液状として用いる場合には、忌避箇
所に直接塗布、つまり、植木鉢やプランターなどの栽培
用容器の表面に塗布したり、図７，８に示した如く栽培
台Ｈの天板部分に塗布したり、さらには植物の幹部や、
その植物の周囲に塗布してもよいし、その他編布を含む
織布や不織布に含浸させて用いてもよい。When used in liquid form, it can be applied directly to avoidable areas, that is, applied to the surface of cultivation containers such as flower pots and planters, or applied to the top plate of the cultivation table H as shown in FIGS. 7 and 8. or even plant executives,
It may be applied around the plant, or may be used by impregnating woven fabrics including knitted fabrics or non-woven fabrics.
【００２１】実施例１
揮発性溶剤を含む液状合成樹脂１に前記した接触毒性を
有する忌避薬剤２を混合して粘性のある塗料の如き液状
に構成した。Example 1 A liquid synthetic resin 1 containing a volatile solvent was mixed with the above-mentioned repellent agent 2 having contact toxicity to form a liquid such as a viscous paint.
【００２２】前記忌避材Ｓを構成するに当っては、基材
１の主としてゼオン１０３ＥＰ（日本ゼオン製塩化ビニ
ル樹脂）２５重量部、ゼオン４００×１１０Ａ（日本ゼ
オン製特殊コーポリマー）５０重量部を用い、接触毒性
を有する有機薬剤４としてディプテレックス（日本特殊
農薬製造（株）の有機リン剤）１０重量部を、高吸水性
樹脂３としてサンウエットＩＭ‐１０００ＭＰＳ（三洋
化成工業（株）製）５重量部をメチルエチルケトン３０
０重量部、トルエン２５０重量部からなる撹拌性をもつ
混合溶剤に均一に分散させて粘性のある塗料状の忌避材
Ｓを形成した。
比較例
前記実施例１の比較例として、前記実施例１からの前記
接触毒性の有機薬剤２を除いた配合例の物、すなわち、
基材１の主成分としてゼオン１０３ＥＰ（日本ゼオン製
塩化ビニル樹脂）２５重量部、ゼオン４００×１１０Ａ
（日本ゼオン製特殊コーポリマー）５０重量部を、また
、高吸水性樹脂３としてサンウェットＩＭ‐１０００Ｍ
ＰＳ（三洋化成工業（株）製）を、メチルエチルケトン
３００重量部、トルエン２５０重量部からなる揮発性を
もつ混合溶剤に均一に分散して塗料状に形成した。In constructing the repellent material S, the base material 1 mainly contains 25 parts by weight of Zeon 103EP (vinyl chloride resin manufactured by Nippon Zeon) and 50 parts by weight of Zeon 400×110A (special copolymer manufactured by Nippon Zeon). 10 parts by weight of Dipterex (an organic phosphorus agent manufactured by Japan Tokushu Nohaku Seizo Co., Ltd.) was used as the contact-toxic organic agent 4, and Sunwet IM-1000MPS (manufactured by Sanyo Chemical Industries, Ltd.) 5 was used as the superabsorbent resin 3. 30 parts by weight of methyl ethyl ketone
A viscous paint-like repellent material S was formed by uniformly dispersing it in a stirrable mixed solvent consisting of 0 parts by weight and 250 parts by weight of toluene. Comparative Example As a comparative example of Example 1, a formulation example excluding the contact toxic organic drug 2 from Example 1, that is,
The main components of the base material 1 are 25 parts by weight of Zeon 103EP (vinyl chloride resin manufactured by Nippon Zeon) and Zeon 400 x 110A.
(Nippon Zeon special copolymer) 50 parts by weight, and as super absorbent resin 3 Sunwet IM-1000M
PS (manufactured by Sanyo Chemical Industries, Ltd.) was uniformly dispersed in a volatile mixed solvent consisting of 300 parts by weight of methyl ethyl ketone and 250 parts by weight of toluene to form a paint.
【００２３】しかして、図７，８に示すようにアルミニ
ウム製で高さ３１ｃｍ、幅２５ｃｍ、長さ９０ｃｍの栽
培台の天板部分に実施例１と比較例１の塗料を塗布し、
試験台Ｈとして、前記試験台Ｈにさつきの鉢植え３鉢を
置き、毎日２０００ｃｍの散水を７日間行ったところ、
実施例１の試験台Ｈを用いたものでは試験台Ｈ上及び鉢
付近にナメクジはいなかったが、比較例１の試験台Ｈを
用いたものでは、５匹のナメクジが見つかった。[0023] As shown in Figures 7 and 8, the paints of Example 1 and Comparative Example 1 were applied to the top plate of an aluminum cultivation table measuring 31 cm in height, 25 cm in width, and 90 cm in length.
As a test stand H, three potted Satsuki plants were placed on the test stand H and watered at a distance of 2000 cm every day for 7 days.
In the test using the test stand H of Example 1, there were no slugs on the test stand H or near the pot, but in the test using the test stand H of Comparative Example 1, five slugs were found.
【００２４】以上の試験の結果、前記実施例１の試験台
Ｈを用いた試験では、試験台Ｈに登ってはたナメクジは
０匹であったが、比較例１の試験台Ｈを用いた試験では
、試験台Ｈに登ってきたナメクジが５匹おり前記実施例
１の試験台Ｈつまり前記接触毒性を有する忌避薬剤２を
添加したものが、ナメクジに対する忌避効果に極めて優
れていることが理解できたのである。As a result of the above test, in the test using the test stand H of Example 1, no slugs climbed onto the test stand H, but when using the test stand H of Comparative Example 1, no slugs climbed onto the test stand H. In the test, there were 5 slugs that climbed onto the test stand H, and it was understood that the test stand H of Example 1, that is, the one to which the contact-toxic repellent agent 2 was added, had an extremely excellent repellent effect against slugs. It was done.
【００２５】前記実施例１の液状忌避材Ｓは、果樹の幹
に直接塗布しても良いし、また人参などの作付けに際し
て施す敷藁に、実施例１の塗料を作付けした作物の周囲
に散布してもよい。このように使用すれば、敷藁の表面
だけでなく、ナメクジが好む敷藁の内部にまで塗料が侵
入し、乾燥すれば藁一本一本の表面に忌避層を設けたこ
とになり、換言すれば作物の周囲に層状の忌避帯を設け
たことになるのである。The liquid repellent material S of Example 1 may be applied directly to the trunks of fruit trees, or the paint of Example 1 may be sprayed around the cultivated crops as mulch used for planting carrots, etc. You may. If used in this way, the paint will penetrate not only the surface of the litter but also the inside of the litter, which slugs prefer, and once it dries, it will create a repellent layer on the surface of each straw. In this way, a layered repellent zone has been created around the crop.
【００２６】また、実施例１の塗料をネット状の織布に
ディッピングするか、または不織布に塗布して使用して
もよいのである。Furthermore, the coating material of Example 1 may be used by dipping it into a net-like woven fabric or by applying it to a non-woven fabric.
【００２７】尚、使用する揮発性を有する溶剤としては
、有機溶剤に限らず、基材１を溶解し、一旦揮発した後
には基材１が水に溶解しないものであれば、例えばアク
リル樹脂をアルコールと水とで溶解分散したエマルジョ
ン等の水を混合した溶剤を用いてもよい。[0027] The volatile solvent to be used is not limited to organic solvents, but may be any solvent that dissolves the base material 1 and does not dissolve in water once it has evaporated, such as acrylic resin. A solvent mixed with water, such as an emulsion prepared by dissolving and dispersing alcohol and water, may also be used.
【００２８】実施例２
パルプ１に、前記した接触毒性を有する忌避薬剤２とを
混合して、この混合物にてその縦断面図を第９図に示し
た育苗ポット形状の忌避材Ｓを形成した。Example 2 Pulp 1 was mixed with repellent agent 2 having contact toxicity as described above, and this mixture was used to form a repellent material S in the shape of a pot for raising seedlings, the vertical cross-section of which is shown in FIG. .
【００２９】基材１としての漂白した古紙１０重量部と
９０重量部の水を叩解機にて撹拌混合しパルプスラリー
を作成する。前記パルプスラリー５重量部と前記薬剤２
としてサンサイド（サンケイ化学（株）製カーバメート
剤）の１１．１％水溶液４５重量部を混合し、抄紙機に
て水分を５０％含む湿シートを作成し、前記湿シート５
枚重ねて、パルプモールド機にて圧縮成型し、２００℃
で１５分乾燥させ、紙製で６ｃｍ角の植木鉢状の忌避材
Ｓを形成した。10 parts by weight of bleached waste paper as the base material 1 and 90 parts by weight of water are stirred and mixed in a beater to prepare a pulp slurry. 5 parts by weight of the pulp slurry and the drug 2
45 parts by weight of an 11.1% aqueous solution of Suncide (carbamate agent manufactured by Sankei Chemical Co., Ltd.) was mixed with the mixture, and a wet sheet containing 50% water was prepared using a paper machine.
Stack them together and compression mold them using a pulp molding machine at 200°C.
The material was dried for 15 minutes, and a 6 cm square flower pot-shaped repellent material S was formed from paper.
【００３０】比較例２
実施例２の比較例として実施例２の忌避材から接触毒性
を有する忌避薬剤２を除いた配合物、即ち基材１として
の漂白した古紙１０重量部と９０重量部の水を叩解機に
て撹拌混合しパルプスラリーを作成する。前記パルプス
ラリー５重量部と水４５重量部を混合し、抄紙機にて水
分を５０％含む湿シートを作成し、前記湿シートを５枚
重ねて、パルプモールド機にて圧縮成型し、２００℃で
１５分乾燥させ、紙製で６ｃｍ角の植木鉢状物を形成し
た。Comparative Example 2 As a comparative example of Example 2, a formulation was prepared in which the contact-toxic repellent agent 2 was removed from the repellent material of Example 2, that is, 10 parts by weight of bleached waste paper and 90 parts by weight of bleached waste paper as base material 1 were used. A pulp slurry is created by stirring and mixing water with a beater. 5 parts by weight of the pulp slurry and 45 parts by weight of water were mixed, a wet sheet containing 50% water was created using a paper machine, 5 sheets of the wet sheet were stacked together, compression molded using a pulp molding machine, and the mixture was heated at 200°C. The mixture was dried for 15 minutes, and a 6 cm square flower pot was formed from paper.
【００３１】前記実施例２の忌避材Ｓ及び比較例２の前
記形成体を試験体Ｈとし、実施例２及び比較例２の試験
体Ｈの各１０体に土２重量部とピートモス１重量部から
なる鉢土を充填し散水後、鉢土が半乾きとなったときに
キャベツの苗を移植した。育苗床に前記実施例２及び比
較例２の試験体Ｈを縦５列、横４列で前記実施例２及び
前記比較例２の前記試験体Ｈを５ｃｍ間隔で交互に配列
し、ナメクジ６匹を前記育苗床に放し翌日観察したとこ
ろ、比較例２の試験体Ｈに移植した苗の新芽は総て食べ
られていたが、実施例２の試験体Ｈに移植した苗の新芽
は食べられておらず、前記実施例２の忌避材Ｓがナメク
ジに対する忌避効果に極めて優れていることが理解でき
たのである。The repellent material S of Example 2 and the formed body of Comparative Example 2 were designated as test specimens H, and 2 parts by weight of soil and 1 part by weight of peat moss were added to 10 specimens each of the test specimens H of Example 2 and Comparative Example 2. After filling the pot with potting soil and watering, cabbage seedlings were transplanted when the potted soil was semi-dry. The test specimens H of Example 2 and Comparative Example 2 were arranged in 5 vertical rows and 4 horizontal rows on a nursery bed, and the test specimens H of Example 2 and Comparative Example 2 were arranged alternately at 5 cm intervals, and 6 slugs were placed on the nursery bed. When they were released into the nursery bed and observed the next day, all the sprouts of the seedlings transplanted to test body H of Comparative Example 2 were eaten, but the sprouts of the seedlings transplanted to test body H of Example 2 were not eaten. Therefore, it was understood that the repellent material S of Example 2 was extremely effective in repelling slugs.
【００３２】[0032]
【発明の効果】以上のごとく本発明は、主成分が合成樹
脂、ゴムまたはパルプから成る基材１の組成物に、接触
毒性を有する有機リン酸エステル及びその誘導体又はカ
ルバミド酸エステル及びその誘導体から成る忌避薬剤２
を混合して、固形又は液状の混合物を形成したことによ
りその使用に際し、初期段階では、固形又は液状から固
形化した前記混合物の外表面に付着する忌避薬剤２がナ
メクジなどの陸生無脊椎動物に対して忌避作用を及ぼし
、散水や降雨などにより忌避材の外表面に付着する忌避
薬剤２が洗い流されることがあっても、前記基材１内に
混入された忌避薬剤２が、忌避材の外表面へ経時的に徐
々にブリードまたは溶出され、このブリードまたは溶出
された忌避薬剤２が陸生無脊椎動物に忌避作用を長期に
亙って持続することができるのである。Effects of the Invention As described above, the present invention is characterized in that the composition of the base material 1, the main component of which is synthetic resin, rubber or pulp, is made from organic phosphoric acid esters and their derivatives or carbamic acid esters and their derivatives, which have contact toxicity. Repellent agent 2
When used, the repellent agent 2 attached to the outer surface of the solid or liquid mixture becomes a solid or liquid mixture. Even if the repellent agent 2 adhering to the outer surface of the repellent material is washed away by water spraying or rainfall, the repellent agent 2 mixed into the base material 1 may be washed away from the outer surface of the repellent material. The repellent agent 2 is gradually bled or eluted onto the surface over time, and the bleed or eluted repellent agent 2 can maintain its repellent effect on terrestrial invertebrates over a long period of time.
【００３３】また、前記混合物に高吸収水性樹脂３を混
合する場合には、この高吸水性樹脂３を混合する場合に
は、この高吸水性樹脂３が散水や降雨時などの水分を吸
水して、その体積が大きく膨潤されることから、前記忌
避材の表に多数の細かい亀裂を発生させ、この亀裂部分
から前記基材１に混入された忌避薬剤２を徐々にブリー
ドさせるかまたは溶出させることにより忌避効果を長期
に亙ってより安定的に持続させることができる。[0033] Furthermore, when the superabsorbent water-based resin 3 is mixed into the mixture, this super-absorbent resin 3 absorbs moisture from watering, rain, etc. As the volume of the repellent material swells greatly, a large number of fine cracks are generated on the surface of the repellent material, and the repellent agent 2 mixed into the base material 1 is gradually bled or eluted from the cracked portions. This allows the repellent effect to be sustained more stably over a long period of time.
【００３４】また、前記混合物をシート状或いは例えば
植物栽培用の容器や植物栽培台を載置可能な所定以上の
大きさから成るブロック状の立方体に成形することによ
りその使用範囲を拡大できると共に、用途に適したもの
を使用できる。Further, by forming the mixture into a sheet or a block-like cube having a size larger than a predetermined size on which a plant cultivation container or a plant cultivation table can be placed, the range of use thereof can be expanded. You can use whatever is appropriate for your purpose.
【００３５】また、揮発性を有する溶剤を含む液状合成
樹脂から成る基材１を用いて、混合物を液状とすること
により、該混合物を例えば直接果樹の幹に塗布して用い
たり、或いは作物の周囲に散布して用いたりすることが
できるし、さらには、この液状混合物を織布や不織布な
どに含浸させて使用することができる。[0035] Furthermore, by making the mixture into a liquid using the base material 1 made of a liquid synthetic resin containing a volatile solvent, the mixture can be applied directly to the trunk of a fruit tree, or applied to a crop. It can be used by being sprayed around the surroundings, or it can be used by impregnating woven or non-woven fabrics with this liquid mixture.
【図１】本発明に係る忌避材をシート状とした実施例を
示す断面図である。FIG. 1 is a cross-sectional view showing an example of a sheet-shaped repellent material according to the present invention.
【図２】忌避材の別の実施例を示す断面図である。FIG. 2 is a sectional view showing another example of a repellent material.
【図３】シート状混合物を小片に裁断して保持シートと
共に用いた忌避材の実施例を示す断面図である。FIG. 3 is a sectional view showing an example of a repellent material in which a sheet-like mixture is cut into small pieces and used together with a holding sheet.
【図４】シート状混合物の一側面にベース部材を張付け
た忌避材の実施例を示す断面図である。FIG. 4 is a sectional view showing an example of a repellent material in which a base member is attached to one side of a sheet-like mixture.
【図５】忌避材をブロック状とした実施例を示す断面図
である。FIG. 5 is a sectional view showing an example in which the repellent material is shaped like a block.
【図６】同忌避材の使用状態を示す説明図である。FIG. 6 is an explanatory diagram showing how the repellent material is used.
【図７】忌避材を液状とした場合における使用状態を示
す説明図である。FIG. 7 is an explanatory diagram showing the state of use when the repellent material is in liquid form.
【図８】同要部の一部拡大断面図である。FIG. 8 is a partially enlarged sectional view of the main part.
【図９】忌避材を植木鉢形状とした実施例を示す断面図
である。FIG. 9 is a sectional view showing an example in which the repellent material is shaped like a flowerpot.
１ 基材 ２ 忌避薬剤 ３ 高吸水性樹脂 1 Base material 2. Repellent agent 3. Super water absorbent resin
Claims (8)
から成る基材１の組成物に、接触毒性を有する有機リン
酸エステル及びその誘導体又はカルバミド酸エステル及
びその誘導体から成る忌避薬剤２を混合して、固形又は
液状の混合物を形成したことを特徴とする陸生無脊椎動
物の忌避材。Claim 1: A repellent agent 2 consisting of a contact-toxic organic phosphate ester and its derivatives or a carbamic acid ester and its derivatives is mixed into a base material 1 composition whose main component is synthetic resin, rubber or pulp. A repellent material for terrestrial invertebrates, characterized in that it has been formed into a solid or liquid mixture.
とを特徴とする請求項１記載の陸生無脊椎動物の忌避材
。2. The repellent material for terrestrial invertebrates according to claim 1, characterized in that a superabsorbent resin 3 is mixed in the mixture.
項１又は２記載の陸生無脊椎動物の忌避材。3. The repellent material for terrestrial invertebrates according to claim 1 or 2, wherein the mixture is formed into a sheet.
持シートを貼着したことを特徴とする請求項３記載の陸
生無脊椎動物の忌避材。4. The repellent material for terrestrial invertebrates according to claim 3, wherein a holding sheet is attached to one side of the mixture formed into a sheet.
ロック状の立方体に成形して成る請求項１又は２記載の
陸生無脊椎動物の忌避材。5. The repellent material for terrestrial invertebrates according to claim 1 or 2, wherein the mixture is formed into a block-like cube having a predetermined size or more.
状合成樹脂から成る請求項１及び２記載の陸生無脊動物
の忌避材。6. The repellent material for terrestrial invertebrates according to claims 1 and 2, wherein the base material 1 is made of a liquid synthetic resin containing a volatile solvent.
脂を主成分とする基材１を織布に含浸させている請求項
６記載の陸生無脊椎動物の忌避材。7. The repellent material for terrestrial invertebrates according to claim 6, wherein the woven fabric is impregnated with the base material 1 whose main component is a liquid synthetic resin containing a volatile solvent.
脂を主成分とする基材１を不織布に含浸させている請求
項６記載の陸生無脊椎動物の忌避材。8. The repellent material for terrestrial invertebrates according to claim 6, wherein the nonwoven fabric is impregnated with the base material 1 whose main component is a liquid synthetic resin containing a volatile solvent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3148864A JP2715191B2 (en) | 1991-06-20 | 1991-06-20 | Repellent material for terrestrial invertebrates |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3148864A JP2715191B2 (en) | 1991-06-20 | 1991-06-20 | Repellent material for terrestrial invertebrates |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63096396A Division JPS6452701A (en) | 1987-05-29 | 1988-04-19 | Repelling material for terrestrial invertebrate animal |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH04316546A true JPH04316546A (en) | 1992-11-06 |
| JP2715191B2 JP2715191B2 (en) | 1998-02-18 |
Family
ID=15462445
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3148864A Expired - Fee Related JP2715191B2 (en) | 1991-06-20 | 1991-06-20 | Repellent material for terrestrial invertebrates |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2715191B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2317827A (en) * | 1996-10-01 | 1998-04-08 | Keith Williams | Tape comprising a mollusc repellent |
| JP2002068902A (en) * | 2000-08-31 | 2002-03-08 | Fumakilla Ltd | Repellant against unpleasant insect pest living in soil and repelling method using the same |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59142264A (en) * | 1983-02-02 | 1984-08-15 | Nitto Electric Ind Co Ltd | Film-forming coating composition containing liquid active substance |
| JPS60146801A (en) * | 1983-12-12 | 1985-08-02 | ソルベイ アンド カンパニー（ソシエテ アノニム） | Molluscicide and manufacture |
| JPS6299301A (en) * | 1985-10-25 | 1987-05-08 | Matsushita Electric Works Ltd | Injurious insect repellent composition and injurious insect repellent building material |
-
1991
- 1991-06-20 JP JP3148864A patent/JP2715191B2/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59142264A (en) * | 1983-02-02 | 1984-08-15 | Nitto Electric Ind Co Ltd | Film-forming coating composition containing liquid active substance |
| JPS60146801A (en) * | 1983-12-12 | 1985-08-02 | ソルベイ アンド カンパニー（ソシエテ アノニム） | Molluscicide and manufacture |
| JPS6299301A (en) * | 1985-10-25 | 1987-05-08 | Matsushita Electric Works Ltd | Injurious insect repellent composition and injurious insect repellent building material |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2317827A (en) * | 1996-10-01 | 1998-04-08 | Keith Williams | Tape comprising a mollusc repellent |
| GB2317827B (en) * | 1996-10-01 | 2001-05-30 | Keith Williams | A tape comprising a mollusc repellent |
| JP2002068902A (en) * | 2000-08-31 | 2002-03-08 | Fumakilla Ltd | Repellant against unpleasant insect pest living in soil and repelling method using the same |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2715191B2 (en) | 1998-02-18 |
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|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |