JPH04265748A - Glass hot-stamping method and heat-insulating device used for the same method - Google Patents

Glass hot-stamping method and heat-insulating device used for the same method

Info

Publication number
JPH04265748A
JPH04265748A JP2640591A JP2640591A JPH04265748A JP H04265748 A JPH04265748 A JP H04265748A JP 2640591 A JP2640591 A JP 2640591A JP 2640591 A JP2640591 A JP 2640591A JP H04265748 A JPH04265748 A JP H04265748A
Authority
JP
Japan
Prior art keywords
glass plate
ink
glass
aluminum foil
rollers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2640591A
Other languages
Japanese (ja)
Other versions
JPH0767796B2 (en
Inventor
Takehiro Kobori
小堀 雄弘
Yasukatsu Kobori
泰克 小堀
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
KOBORI KAKOUSHIYO KK
Original Assignee
KOBORI KAKOUSHIYO KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by KOBORI KAKOUSHIYO KK filed Critical KOBORI KAKOUSHIYO KK
Priority to JP3026405A priority Critical patent/JPH0767796B2/en
Publication of JPH04265748A publication Critical patent/JPH04265748A/en
Publication of JPH0767796B2 publication Critical patent/JPH0767796B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

PURPOSE:To obviate the manufacture of a foundation, to decrease drying processes and to prevent the peeling of a foil by holding the surface temperature of a glass plate, on which screen-printing is conducted by ink for two pack, at approximately 50 deg.C and fast sticking the aluminum foil on the surface of the glass plate while oxidizing an ink surface. CONSTITUTION:A desired design is screen-printed on the surface of a glass plate 1 by ink 2 for two pack, and printed ink 2 for two pack is dried completely. The glass plate 1 after drying is brought into contact with rollers 11, 12, surface temperatures of which in a heat-insulating vessel are held at approximately 45-50 deg.C. An aluminum foil 3 is placed on the glass plate 1 under the state, the aluminum foil 3 is pushed by a silicon roller, etc., a surface temperature of which is brought to a fixed temperature and which have resiliency, and the surface of the glass plate 1 and the aluminum foil 3 are fast stuck. Accordingly, fine irregularities are formed to the surface of ink 2 adhering on the surface of the glass plate 1, and the aluminum foil 3 is deformed along the fine irregularities by heat, thus bonding the aluminum foil 3 on the glass plate 1 more firmly in cooperation with the bonding effect of ink 2.

Description

【発明の詳細な説明】[Detailed description of the invention]

【0001】0001

【産業上の利用分野】この発明は、硝子板の表面にアル
ミ箔等の金属箔をホットスタンプする硝子ホットスタン
プ方法と、この方法を実施する際に使用される保温装置
に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a glass hot stamping method for hot stamping a metal foil such as aluminum foil onto the surface of a glass plate, and a heat insulating device used when carrying out this method.

【0002】0002

【従来の技術】従来、硝子板の表面に例えばアルミ箔を
ホットスタンプする場合、以下のような方法をとってい
た。まず、硝子板の表面にアクリル系の塗料(あるいは
それに近いもの)を塗装し、一液用インクでスクリーン
印刷する。次に、印刷部分のインクを半乾き状態した後
、アルミ箔を付けた後、乾燥機で完全に乾燥させる。 これにより、インクが接着剤となり、アルミ箔を印刷部
分にホットスタンプすることができる。
2. Description of the Related Art Conventionally, when hot-stamping, for example, aluminum foil onto the surface of a glass plate, the following method has been used. First, acrylic paint (or something similar) is applied to the surface of the glass plate, and then screen printed with one-component ink. Next, after the ink on the printed area is semi-dry, aluminum foil is attached and the ink is completely dried in a dryer. This turns the ink into an adhesive that allows the aluminum foil to be hot stamped onto the printed area.

【0003】しかしながら、上記のような従来のホット
スタンプ方法では、一液用インクを使用するため、初期
工程で硝子板の表面にアクリル系の透明塗料を塗装して
、インクがのるように下地を作らなければならない。 また、二度の乾燥工程が必要となる。このように、手順
が繁雑であるにもかかわらず、接着が弱く、箔が剥がれ
やすいという問題があった。
However, in the conventional hot stamping method as described above, since a one-component ink is used, an acrylic transparent paint is applied to the surface of the glass plate in the initial process, and a base layer is prepared so that the ink can be applied. must be made. Moreover, two drying steps are required. Although the procedure is complicated, there is a problem that the adhesive is weak and the foil easily peels off.

【0004】0004

【発明が解決しようとする課題】以上述べたように、従
来の硝子ホットスタンプ方法では、下地工程、二度の乾
燥工程が必要なため、手間と時間がかかり、しかも箔が
剥がれやすいという問題があった。
[Problems to be Solved by the Invention] As stated above, the conventional glass hot stamping method requires a base step and two drying steps, which is time-consuming and labor-intensive, and also has the problem that the foil easily peels off. there were.

【0005】この発明は上記の問題を解決するためにな
されたもので、下地を作る必要がなく、乾燥工程も少な
く、しかも箔が剥がれにくい硝子ホットスタンプ方法を
提供することを目的とする。
The present invention was made to solve the above problems, and its object is to provide a glass hot stamping method that does not require the preparation of a base, requires fewer drying steps, and in which the foil is less likely to peel off.

【0006】[0006]

【課題を解決するための手段】上記目的を達成するため
にこの発明に係る硝子ホットスタンプ方法は、硝子板の
表面に二液用インクでスクリーン印刷する第1の工程と
、この第1の工程終了後に前記硝子板の表面に印刷され
た二液用インクを完全に乾燥させる第2の工程と、この
第2の工程終了後に前記硝子板の表面温度を50℃前後
に保持して前記インク表面を酸化させながら、その表面
にアルミ箔を密着させる第3の工程とを具備して構成さ
れる。
[Means for Solving the Problems] In order to achieve the above object, the glass hot stamping method according to the present invention includes a first step of screen printing on the surface of a glass plate with a two-component ink, and a first step of screen printing with a two-component ink. After completion of the process, there is a second step of completely drying the two-component ink printed on the surface of the glass plate, and after the completion of this second process, the surface temperature of the glass plate is maintained at around 50°C and the surface of the ink is and a third step of oxidizing the aluminum foil and adhering the aluminum foil to the surface of the aluminum foil.

【0007】[0007]

【作用】上記の構成による硝子ホットスタンプ方法では
、硝子板の表面に二液用インクで直接スクリーン印刷し
た後、インクを完全に乾燥させ、硝子板の表面温度を5
0℃前後に保持してインク表面を酸化させながら、その
表面にアルミ箔を密着させ、250℃の熱を加えて接着
させる。
[Operation] In the glass hot stamping method with the above configuration, after directly screen printing the surface of the glass plate with two-component ink, the ink is completely dried, and the surface temperature of the glass plate is lowered to 50%.
While maintaining the temperature around 0°C to oxidize the ink surface, aluminum foil is brought into close contact with the ink surface, and heat at 250°C is applied to bond the ink.

【0008】[0008]

【実施例】以下、図1乃至図3を参照してこの発明の一
実施例を説明する。
DESCRIPTION OF THE PREFERRED EMBODIMENTS An embodiment of the present invention will be described below with reference to FIGS. 1 to 3.

【0009】図1はこの発明に係る硝子ホットスタンプ
方法の工程を説明するためのもので、完成品の断面を示
している。図1において、1は硝子板であり、第1の工
程で硝子板1の表面に所望の図柄を二液用インク2でス
クリーン印刷する。二液用インク2は、エポキシ系の十
條加工1000タイプであって、メジウム3に対して硬
化剤1を混合したものである。
FIG. 1 is for explaining the steps of the glass hot stamping method according to the present invention, and shows a cross section of a finished product. In FIG. 1, 1 is a glass plate, and in a first step, a desired pattern is screen printed on the surface of the glass plate 1 using two-component ink 2. The two-component ink 2 is an epoxy Jujo-Kaku 1000 type, and is a mixture of 3 medium and 1 hardening agent.

【0010】第2の工程で、硝子板1の表面に印刷され
た二液用インク2を完全に乾燥させる。この工程におい
て、周囲温度を150℃前後に保持しつつ、20分程度
放置すれば、図中点線で示すように、インク2が均一な
厚さで、かつひび割れすることなく乾燥することが実験
によって確かめられた。
In the second step, the two-component ink 2 printed on the surface of the glass plate 1 is completely dried. In this process, experiments have shown that if the ambient temperature is maintained at around 150°C and left for about 20 minutes, the ink 2 dries to a uniform thickness and without cracking, as shown by the dotted line in the figure. It was confirmed.

【0011】第3の工程で、硝子板1の表面温度を50
℃前後に保持する。これによって、インク2の表面が酸
化して、図中実線で示すようにインク表面に細かな凹凸
が生じる、つまりざらつきが生じるようになる。この状
態で、硝子板1の表面にアルミ箔3を密着させ、250
℃程度の熱を加えると、アルミ箔3はインク2の表面に
できた細かな凹凸に沿って変形する。このため、アルミ
箔3は、インク2の接着効果と相俟って、より強固に硝
子板1の表面に接着されるようになる。後は自然乾燥さ
せれば終了である。尚、硝子板1の表面温度を45℃乃
至50℃に精度よく保持すると、アルミ箔3の接着度が
良好であることが実験によって確かめられた。
In the third step, the surface temperature of the glass plate 1 is increased to 50°C.
Keep around ℃. As a result, the surface of the ink 2 is oxidized, and the ink surface becomes finely uneven, that is, rough, as shown by the solid line in the figure. In this state, the aluminum foil 3 is tightly attached to the surface of the glass plate 1, and
When heat of about 0.degree. C. is applied, the aluminum foil 3 deforms along the fine irregularities formed on the surface of the ink 2. Therefore, together with the adhesive effect of the ink 2, the aluminum foil 3 becomes more firmly adhered to the surface of the glass plate 1. After that, just let it air dry and you're done. It has been confirmed through experiments that the degree of adhesion of the aluminum foil 3 is good when the surface temperature of the glass plate 1 is accurately maintained at 45° C. to 50° C.

【0012】ところで、第3の工程において、特に硝子
瓶のように上記硝子板1が円筒状の硝子容器の場合、表
面温度を45℃乃至50℃に精度良く保持することは非
常に困難である。この問題を解決するため、図2及び図
3に示すような保温装置を提供する。図2はその構造を
示し、図3はその電気系の構成を示す。尚、図2及び図
3において、同一部分には同一符号を付して示す。
By the way, in the third step, especially when the glass plate 1 is a cylindrical glass container such as a glass bottle, it is very difficult to accurately maintain the surface temperature at 45° C. to 50° C. . In order to solve this problem, a heat retention device as shown in FIGS. 2 and 3 is provided. FIG. 2 shows its structure, and FIG. 3 shows its electrical system configuration. Note that in FIGS. 2 and 3, the same parts are denoted by the same reference numerals.

【0013】11,12はそれぞれ表面がステンレスで
形成された一対のローラである。これらのローラ11,
12は内部に図3に示すヒータ13,14が内挿されて
おり、互いに長手方向に平行するように対向配置するよ
うにして、その回転軸が支持枠15に回転自在に支持さ
れる。各ローラ11,12は、詳細を図示しないが、回
転駆動装置16によってそれぞれ同一方向に同一速度で
回転される。上記ローラ11,12内のヒータ13,1
4はそれぞれ図3に示すように電力供給装置17に接続
され、当該装置17から電力供給を受ける。
Reference numerals 11 and 12 denote a pair of rollers each having a surface made of stainless steel. These rollers 11,
12 has heaters 13 and 14 shown in FIG. 3 inserted therein, and are rotatably supported by the support frame 15 with their rotating shafts facing each other so as to be parallel to each other in the longitudinal direction. The rollers 11 and 12 are rotated in the same direction and at the same speed by a rotary drive device 16, although details are not shown. Heaters 13 and 1 in the rollers 11 and 12
4 are each connected to a power supply device 17 as shown in FIG. 3, and receive power from the device 17.

【0014】各ローラ11,12の表面には、それぞれ
温度計18,19が取り付けられている。これらの温度
計18,19はそれぞれ各ローラ11,12の表面温度
を検出し、その検出温度に対応した電圧信号を出力する
もので、これらの電圧信号は図3に示すように共に上記
電力供給装置17に送られる。この電力供給装置17は
各温度計18,19からの電圧信号から対応するローラ
11,12の表面温度を識別し、識別温度が45℃乃至
50℃となるように、各ヒータ13,14への供給電力
を自動的に調節するようになっている。
Thermometers 18 and 19 are attached to the surfaces of each roller 11 and 12, respectively. These thermometers 18 and 19 detect the surface temperature of each roller 11 and 12, respectively, and output a voltage signal corresponding to the detected temperature, and these voltage signals are both connected to the above-mentioned power supply as shown in FIG. It is sent to device 17. This power supply device 17 identifies the surface temperature of the corresponding roller 11, 12 from the voltage signal from each thermometer 18, 19, and supplies power to each heater 13, 14 so that the identified temperature is 45°C to 50°C. The power supply is automatically adjusted.

【0015】上記構成の保温装置の使用方法を説明する
。まず、ローラ11,12の間に第2の工程を終了した
円筒状の硝子板(硝子容器)1を載置した後、回転駆動
装置16及び電力供給装置17の電源を投入する。する
と、回転駆動装置16の起動によりローラ11,12が
同一方向、同一速度で回転するため、硝子容器1もこれ
に沿って回転する。このとき、電力供給装置17の起動
によりヒータ13,14に電力が供給されるため、ヒー
タ13,14が発熱し、ローラ11,12の表面温度が
上昇する。各ローラ11,12の表面温度情報は温度計
18,19を通じて電力供給装置17にフィードバック
され、この装置17の電力調整機能により、ローラ18
,19の表面温度は45〜50℃に保持される。このた
め、ローラ11,12に接している硝子容器1も45〜
50℃に保持される。
[0015] A method of using the heat retaining device having the above structure will be explained. First, after placing the cylindrical glass plate (glass container) 1 that has undergone the second step between the rollers 11 and 12, the rotation drive device 16 and the power supply device 17 are turned on. Then, the rotation drive device 16 is activated and the rollers 11 and 12 rotate in the same direction and at the same speed, and the glass container 1 also rotates accordingly. At this time, power is supplied to the heaters 13 and 14 by activation of the power supply device 17, so the heaters 13 and 14 generate heat, and the surface temperature of the rollers 11 and 12 increases. The surface temperature information of each roller 11, 12 is fed back to the power supply device 17 through thermometers 18, 19, and the power adjustment function of this device 17 allows the roller 18
, 19 is maintained at 45-50°C. For this reason, the glass container 1 in contact with the rollers 11 and 12 is also
It is maintained at 50°C.

【0016】この状態で、硝子容器1の上にアルミ箔3
を乗せ、表面が250℃程度に暖められた弾力性を有す
るラバーあるいはシリコンローラ等でアルミ箔3を押し
付けることにより、硝子容器1の表面とアルミ箔3との
間の空気を逃がし、硝子容器1の表面とアルミ箔3とを
密着させる。このようにすれば、硝子容器1の表面に付
着したインク2の表面に細かな凹凸ができ、アルミ箔3
は250℃程度の熱によりその細かな凹凸に沿って変形
するため、インク2の接着効果と相俟って、より強固に
硝子容器1の表面に接着されるようになる。
In this state, aluminum foil 3 is placed on top of the glass container 1.
By pressing the aluminum foil 3 with an elastic rubber or silicone roller whose surface has been heated to about 250°C, the air between the surface of the glass container 1 and the aluminum foil 3 is released, and the glass container 1 The surface of the aluminum foil 3 is brought into close contact with the aluminum foil 3. In this way, the surface of the ink 2 adhering to the surface of the glass container 1 will have fine irregularities, and the aluminum foil 3
is deformed along its fine irregularities by heat of about 250° C., and together with the adhesive effect of the ink 2, it becomes more firmly adhered to the surface of the glass container 1.

【0017】以上のように、上記第1乃至第3の工程に
よる硝子ホットスタンプ方法は、直接硝子容器1にスク
リーン印刷可能な二液用インク2を用いるので、従来の
ように塗料による下地を作る必要がなく、また途中の乾
燥工程でも半乾き程度でよいので不溜りが少なく、しか
もインク2の表面にできた凹凸に沿ってアルミ箔3が変
形するので、相対的にインク2とアルミ箔3の接触面積
が広くなり、接着乾燥後でもアルミ箔3が剥がれにくい
という効果を得ることができる。また、図2の保温装置
を用いることにより、その作業性を向上させることがで
きる。
As described above, the glass hot stamping method according to the first to third steps uses the two-component ink 2 that can be screen printed directly on the glass container 1, so it is not necessary to prepare a base with paint as in the conventional method. There is no need for it, and the drying process only needs to be half-dry during the drying process, so there is less buildup.Furthermore, since the aluminum foil 3 deforms along the unevenness formed on the surface of the ink 2, the ink 2 and the aluminum foil 3 are relatively dry. The contact area of the aluminum foil 3 is increased, and the aluminum foil 3 is difficult to peel off even after the adhesive is dried. Furthermore, by using the heat retaining device shown in FIG. 2, the workability can be improved.

【0018】尚、この発明は、比較的印刷しやすいとさ
れるアルカリ成分の少ない硝子(例えば管瓶)に限らず
、いままで印刷不能とされていたアルカリ成分が多く含
まれる硝子(例えば自動瓶)にも実施可能である。
The present invention is applicable not only to glass with a low alkaline content that is relatively easy to print on (for example, tube bottles), but also to glass that has a high alkali content that has been considered unprintable (for example, automatic bottles). ) can also be implemented.

【0019】[0019]

【発明の効果】以上詳述したようにこの発明によれば、
下地を作る必要がなく、乾燥工程も少なく、しかも箔が
剥がれにくい硝子ホットスタンプ方法を提供することが
できる。
[Effects of the Invention] As detailed above, according to the present invention,
It is possible to provide a glass hot stamping method that does not require the preparation of a base, requires fewer drying steps, and in which the foil does not easily peel off.

【図面の簡単な説明】[Brief explanation of the drawing]

【図1】この発明の一実施例に係る硝子ホットスタンプ
方法の各工程を説明するための断面図。
FIG. 1 is a cross-sectional view for explaining each step of a glass hot stamping method according to an embodiment of the present invention.

【図2】図1の方法における第2の工程に用いる保温装
置の構造を示す斜視図。
FIG. 2 is a perspective view showing the structure of a heat retention device used in the second step in the method of FIG. 1.

【図3】図2の保温装置の電気系の構成を示すブロック
回路図。
FIG. 3 is a block circuit diagram showing the configuration of an electrical system of the heat-retaining device shown in FIG. 2;

【符号の説明】[Explanation of symbols]

1…硝子、2…二液用インク、3…アルミ箔、11,1
2…ローラ、13,14…ヒータ、15…支持枠、16
…回転駆動装置、17…電力供給装置、18,19…温
度計。
1...Glass, 2...Two-component ink, 3...Aluminum foil, 11,1
2...Roller, 13, 14...Heater, 15...Support frame, 16
...Rotary drive device, 17...Power supply device, 18, 19...Thermometer.

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】  硝子板の表面に二液用インクでスクリ
ーン印刷する第1の工程と、この第1の工程終了後に前
記硝子板の表面に印刷された二液用インクを完全に乾燥
させる第2の工程と、この第2の工程終了後に前記硝子
板の表面の温度を50℃前後に保持して前記インク表面
を酸化させながら、その表面にアルミ箔を密着させる第
3の工程とを具備する硝子ホットスタンプ方法。
1. A first step of screen printing with a two-component ink on the surface of a glass plate, and a second step of completely drying the two-component ink printed on the surface of the glass plate after the first step. After the second step, the temperature of the surface of the glass plate is maintained at around 50° C. to oxidize the surface of the ink, and a third step is to adhere aluminum foil to the surface. How to hot stamp glass.
【請求項2】  前記二液用インクは、エポキシ系十條
加工1000タイプであって、メジウム3に対して硬化
剤1を混合したものであることを特徴とする請求項1記
載の硝子ホットスタンプ方法。
2. The glass hot stamping method according to claim 1, wherein the two-component ink is an epoxy type Jujo Kakyou 1000 type in which 3 parts of medium and 1 part of hardening agent are mixed. .
【請求項3】  前記第3の構成において、前記硝子板
の表面の保持温度は45℃乃至50℃であることを特徴
とする請求項1記載の硝子ホットスタンプ方法。
3. The glass hot stamping method according to claim 1, wherein in the third configuration, the temperature at which the surface of the glass plate is maintained is 45° C. to 50° C.
【請求項4】  前記硝子板が円筒状の容器の場合にお
いて、内部にヒータが内挿され、互いに長手方向に平行
するように対向配置される一対のローラと、この一対の
ローラをそれぞれ同一方向に同一速度で回転させる回転
駆動装置と、前記一対のローラ内のヒータの電源となり
、その供給電力を調節可能な電力供給装置とを具備し、
前記円筒状の硝子容器を前記一対のローラ間に載置した
状態で回転させ、前記電力供給装置でヒータ温度を調整
して、前記硝子容器の表面温度が50℃前後となるよう
に設定する請求項1記載の硝子ホットスタンプ方法の第
3の工程に使用される保温装置。
4. In the case where the glass plate is a cylindrical container, a heater is inserted therein, and a pair of rollers are disposed facing each other so as to be parallel to each other in the longitudinal direction, and the pair of rollers are moved in the same direction. a rotational drive device that rotates the rollers at the same speed; and a power supply device that serves as a power source for the heaters in the pair of rollers and whose power supply can be adjusted;
The cylindrical glass container is placed between the pair of rollers and rotated, and the heater temperature is adjusted by the power supply device so that the surface temperature of the glass container is set at around 50°C. Item 1. A heat-retaining device used in the third step of the glass hot stamping method according to item 1.
JP3026405A 1991-02-20 1991-02-20 Glass hot stamping method and heat retaining device used therefor Expired - Fee Related JPH0767796B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP3026405A JPH0767796B2 (en) 1991-02-20 1991-02-20 Glass hot stamping method and heat retaining device used therefor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3026405A JPH0767796B2 (en) 1991-02-20 1991-02-20 Glass hot stamping method and heat retaining device used therefor

Publications (2)

Publication Number Publication Date
JPH04265748A true JPH04265748A (en) 1992-09-21
JPH0767796B2 JPH0767796B2 (en) 1995-07-26

Family

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Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3839932B2 (en) 1996-09-26 2006-11-01 キヤノン株式会社 Process cartridge, electrophotographic image forming apparatus, electrophotographic photosensitive drum and coupling

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5523222A (en) * 1978-08-05 1980-02-19 Oiles Industry Co Ltd Steel for prestressed concrete
JPS57105387A (en) * 1980-12-23 1982-06-30 Kamaya Kagaku Kogyo Kk Transferring method for brilliant metallic letter or pattern on glass surface
JPS6317075A (en) * 1986-07-09 1988-01-25 Hino Jushi:Kk Method of printing glass body to be transferred
JPH0236393A (en) * 1988-07-26 1990-02-06 Seiko Instr Inc Method of adhering glass for timepiece

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5523222A (en) * 1978-08-05 1980-02-19 Oiles Industry Co Ltd Steel for prestressed concrete
JPS57105387A (en) * 1980-12-23 1982-06-30 Kamaya Kagaku Kogyo Kk Transferring method for brilliant metallic letter or pattern on glass surface
JPS6317075A (en) * 1986-07-09 1988-01-25 Hino Jushi:Kk Method of printing glass body to be transferred
JPH0236393A (en) * 1988-07-26 1990-02-06 Seiko Instr Inc Method of adhering glass for timepiece

Also Published As

Publication number Publication date
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