JPH04196486A - Semiconductor device - Google Patents

Semiconductor device

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Publication number
JPH04196486A
JPH04196486A JP32755390A JP32755390A JPH04196486A JP H04196486 A JPH04196486 A JP H04196486A JP 32755390 A JP32755390 A JP 32755390A JP 32755390 A JP32755390 A JP 32755390A JP H04196486 A JPH04196486 A JP H04196486A
Authority
JP
Japan
Prior art keywords
film
insulating film
semiconductor device
barrier
layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP32755390A
Other languages
Japanese (ja)
Other versions
JP2848694B2 (en
Inventor
Hidemitsu Egawa
江川 秀光
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toshiba Corp
Original Assignee
Toshiba Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toshiba Corp filed Critical Toshiba Corp
Priority to JP32755390A priority Critical patent/JP2848694B2/en
Publication of JPH04196486A publication Critical patent/JPH04196486A/en
Application granted granted Critical
Publication of JP2848694B2 publication Critical patent/JP2848694B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Abstract

PURPOSE:To obtain a highly reliable adhesion between films by interposing an insulation layer which does not contain boron between an insulation film (a primary insulation film) and a barrier film. CONSTITUTION:A BPSG film 3 is deposited over a semiconductor substrate 1, and, subsequently, a nitride film 4, such as SiN film, is superimposed on the BPSG film 3. Moreover, deposited over the nitride film is a barrier film consisting of a Ti film 5 and a TiN film 7. In order to reduce a contact resistance, the barrier film is subjected to a heat treatment, so that the Ti film 5 adjacent to a diffusion layer 2 is transformed into a compound of Ti-Si. An Al based wiring film 8 is further deposited on the surface of the device, and the device coated with the wiring film under-goes a patterning to form wirings. With the insulation layer 4 that does not include boron interposed between the insulation film 3, deposited on the semiconductor substrate 1, and the double layered barrier films 5 and 7 comprising Ti and TiN, the adhesion between the films are improved.

Description

【発明の詳細な説明】 〔発明の目的〕 (産業上の利用分野) 本発明は絶縁膜とAg系配線膜との間にバリアメタルと
してのTiN膜を有する半導体装置に関する。
DETAILED DESCRIPTION OF THE INVENTION [Object of the Invention] (Industrial Application Field) The present invention relates to a semiconductor device having a TiN film as a barrier metal between an insulating film and an Ag-based wiring film.

(従来の技術) 従来の半導体装置の断面を第4図に示す。この+−導体
装置は、半導体基板1上にBPSG膜3が形成され、こ
のB P S (Jk3には、基板1上に形成された拡
散層2とのコンタクトを取るためのコンタクトホールが
開孔されている。そして、二のコンタ、クトホールが開
孔されたBPSG膜3上にTi膜5及びTfNI17か
らなるバリア膜が形成され、このバリア膜上にAll又
はAl1合金からなるAll系配線膜8が形成されてい
る。上述のバリア膜は、AlとSiが反応することによ
って生じる、Afl系配線のコンタクト部の接合突き抜
けやSi析出によるコンタクト抵抗増大等を抑制するた
めに設けられるものである。なお、T i @ 5及び
TiN膜7からなるバリア膜の形成直後には、コンタク
ト部においてSi表面の薄い酸化物のTiによる還元及
びTiとSiのシリサイプ−ジョンを促進してコンタク
ト抵抗を低減するための熱処理が行われる。この熱処理
によって拡散層2近傍のTi@はTi−8t化合物6に
嚢化する。
(Prior Art) A cross section of a conventional semiconductor device is shown in FIG. This +-conductor device has a BPSG film 3 formed on a semiconductor substrate 1, and a contact hole for making contact with a diffusion layer 2 formed on the substrate 1 is opened in this BPSG film 3. Then, a barrier film made of a Ti film 5 and TfNI 17 is formed on the BPSG film 3 in which the second contact hole is formed, and an All-based wiring film 8 made of All or Al1 alloy is formed on this barrier film. The above-mentioned barrier film is provided to suppress junction penetration of the contact portion of the Afl-based wiring and an increase in contact resistance due to Si precipitation, which are caused by the reaction between Al and Si. Immediately after forming the barrier film consisting of Ti@5 and the TiN film 7, the contact resistance is reduced by promoting the reduction of the thin oxide on the Si surface by Ti and the silicidation of Ti and Si in the contact portion. A heat treatment is performed for this purpose.By this heat treatment, Ti@ in the vicinity of the diffusion layer 2 is encapsulated into a Ti-8t compound 6.

又、図示はしていないが、A47系配線膜8形成後、こ
のAI系配線7N!8をバターニングして配線を形成し
、その後に絶縁保護膜を形成してパッド開孔を行う。
Although not shown, after the A47-based wiring film 8 is formed, this AI-based wiring 7N! 8 is patterned to form wiring, and then an insulating protective film is formed and pad holes are formed.

(発明が解決しようとする課題) このような半導体装置においては、パッド部が下地絶縁
膜3との界面近傍で剥離する、すなわち密着性不良が生
じるという問題があった。二の密着性不良′は、バリア
膜形成後の熱処理によって発生するものて、パ、ツド部
ドのTi膜5と下地絶縁膜3とが反応して脆い層が形成
されることによるものである。又、この密着性不良は下
地絶縁膜3の構成成分にも影響され、特にB(はう素)
の含有量が高い程発生し品い。
(Problems to be Solved by the Invention) Such a semiconductor device has a problem in that the pad portion peels off near the interface with the base insulating film 3, that is, poor adhesion occurs. The second problem, poor adhesion, is caused by the heat treatment after the formation of the barrier film, and is caused by the reaction between the Ti film 5 on the pad and the base insulating film 3, forming a brittle layer. . In addition, this poor adhesion is also affected by the constituent components of the base insulating film 3, especially B (boron).
The higher the content, the higher the quality.

本発明は上記問題点を考慮してなされたものであって、
密着性に対して高い信頼性を有する半導体装置を提供す
ることを目的とする。
The present invention has been made in consideration of the above problems, and includes:
An object of the present invention is to provide a semiconductor device having high reliability in terms of adhesion.

C発明の構成〕 (課題を解決するための手段) 第1の発明の半導体装置は、半導体基板上に形成された
絶縁膜と、この絶縁膜上に形成されるホウ素を含まない
絶縁膜層と、このホウ素を含まない絶縁膜層上に形成さ
れるTi及びTiNからなる2層構造のバリア膜と、こ
のバリア膜上に形成されるAg又はp、(t9金からな
るAll系配線膜とを備えていることを特徴とする。
C Structure of the Invention] (Means for Solving the Problems) The semiconductor device of the first invention includes an insulating film formed on a semiconductor substrate, an insulating film layer not containing boron formed on the insulating film, and an insulating film layer formed on the insulating film. , a two-layer barrier film made of Ti and TiN formed on this boron-free insulating film layer, and an All-based wiring film made of Ag, p, (t9 gold) formed on this barrier film. It is characterized by having

m2の発明の半導体装置は、半導体基板上に形成された
絶縁膜と、この絶縁膜に開孔されたコンタクトホールの
底部の半導体基板表面のみに形成されるTiシリサイド
層と、このTiシリサイド層及び前記絶縁膜上に形成さ
れるTiN@と、このTiN膜上に形成されるAI!又
はAl合金からなるAJ7系配系膜線膜備えていること
を特徴とする。
The semiconductor device of the invention of m2 includes an insulating film formed on a semiconductor substrate, a Ti silicide layer formed only on the surface of the semiconductor substrate at the bottom of a contact hole opened in this insulating film, and this Ti silicide layer and TiN@ formed on the insulating film and AI! formed on this TiN film! Alternatively, it is characterized by being equipped with an AJ7 system membrane wire film made of an Al alloy.

(作 用) 二のように構成された第1の発明の半導体装置によれば
、絶縁膜(下地絶縁膜)とバリア膜との間にホウ素を含
まない絶縁膜層が設けられている。
(Function) According to the semiconductor device of the first invention configured as in item 2, an insulating film layer that does not contain boron is provided between the insulating film (base insulating film) and the barrier film.

これによ゛リバリア膜の熱処理の温度にががゎらず、下
地絶縁膜とバリア膜との界面近傍での剥離する割合、す
なわち界面はがれ率をほぼ零とすることができ、密着性
に対して高い信頼性を得ることができる。
As a result, the temperature of heat treatment of the barrier film does not vary, and the peeling rate near the interface between the base insulating film and the barrier film, that is, the interface peeling rate, can be reduced to almost zero, and the adhesion is reduced. High reliability can be obtained.

上述のように構成された第2の発明の半導体装置によれ
ば、絶縁膜上にはTffiではなくてT i N@が形
成されているため、Tiシリサイド層を形成するに必要
な熱処理が行われても、絶縁膜とTiNfiとの界面の
剥離はほとんど生じない。
According to the semiconductor device of the second invention configured as described above, since TiN@ instead of Tffi is formed on the insulating film, the heat treatment necessary to form the Ti silicide layer is not performed. Even if the TiNfi film is diluted, peeling at the interface between the insulating film and the TiNfi hardly occurs.

これにより密着性に対して高い信頼性を得ることができ
る。
Thereby, high reliability in adhesion can be obtained.

(実施例) 第1の発明による半導体装置の一実施例を第1図を参照
して説明する。第1図は上記実施例の半導体装置の製造
工程断面図である。先ず半導体基板1上にBPSG膜3
を形成し、更にこのBPSG膜3の上に窒化膜、例えば
SiN膜4をCVD法を用いて形成する(第1図(a)
 参照)。
(Embodiment) An embodiment of the semiconductor device according to the first invention will be described with reference to FIG. FIG. 1 is a cross-sectional view of the manufacturing process of the semiconductor device of the above embodiment. First, a BPSG film 3 is formed on a semiconductor substrate 1.
A nitride film, for example, a SiN film 4 is further formed on this BPSG film 3 using the CVD method (see FIG. 1(a)).
reference).

その後、基板1上の拡散層2とのコンタクトを取るため
フンタクトホールを開孔する(第1図(a)参照)。
Thereafter, a hole is opened to make contact with the diffusion layer 2 on the substrate 1 (see FIG. 1(a)).

次にTi膜5及びTiN膜7からなるバリアAl!′を
形成する(第1図(b)参照)。そしてコンタクト抵抗
を低減するために約500〜800℃の温度で上記バリ
ア膜の熱処理を行って、拡散層2近傍のTi膜5をTi
−Si化合物に変える(第1図(C)参照)。その後、
A、Q采配線膜8を堆積しく第1図(C)参照)、バタ
ーニングを行って配線を形成する(図示せず)。そして
絶縁保護膜を形成後、パッド開孔を行う(図示せず)。
Next, barrier Al! made of Ti film 5 and TiN film 7! ' (see Figure 1(b)). Then, in order to reduce the contact resistance, the barrier film is heat-treated at a temperature of about 500 to 800°C, and the Ti film 5 near the diffusion layer 2 is changed to a Ti film.
-Si compound (see FIG. 1(C)). after that,
The A and Q frame wiring films 8 are deposited (see FIG. 1C) and patterned to form wiring (not shown). After forming the insulating protective film, pad holes are formed (not shown).

このようにして形成されたパッド部にワイヤ接続した後
1とこのワイヤめ剥離テストを行った結果を第3図のグ
ラフAlに示す。第3図に示すグラフの横軸はバリア膜
の熱処理温度を示し、縦軸はパッド部の、下地絶縁膜と
の界面がはがれる割合すなわち、界面はがれ率を示して
いる。本実施例の半導体装置の製造において、バリア膜
の熱処理を比較的高温(約500〜800℃)で行って
も界面はがれ率はほぼ零であることがグラフg1から分
かる。これに対して従来の半導体装置の、バリア膜の熱
処理温度に対する界面はがれ率をグラフg に示すが、
このグラフAl2から分かるように熱処理温度が高くな
るにつれて界面はがれ率も上昇していることが分かる。
After a wire was connected to the pad portion thus formed, a peel test was performed on the wire, and the results are shown in graph Al in FIG. The horizontal axis of the graph shown in FIG. 3 indicates the heat treatment temperature of the barrier film, and the vertical axis indicates the rate at which the interface between the pad portion and the underlying insulating film peels off, that is, the interface peeling rate. It can be seen from graph g1 that even when the barrier film is heat-treated at a relatively high temperature (approximately 500 to 800° C.) in manufacturing the semiconductor device of this example, the interface peeling rate is almost zero. In contrast, graph g shows the interface peeling rate versus heat treatment temperature of the barrier film in a conventional semiconductor device.
As can be seen from this graph Al2, as the heat treatment temperature increases, the interface peeling rate also increases.

したがって本実施例の半導体装置によれば界面はかり率
がほぼ零、すなわち密着性不良はほとんど生じず、信頼
性の高いものとなる。
Therefore, according to the semiconductor device of this embodiment, the interface coverage rate is almost zero, that is, almost no adhesion failure occurs, and the reliability is high.

なお、上記実施例においては゛、バリア膜とB P S
 G@3との間の絶縁膜としてSiN膜を設けたが、こ
のSiN膜の代わりにAJ7Nからなる窒化膜を設けて
も同様の効果を得ることができる。
In addition, in the above embodiment, the barrier film and the BPS
Although a SiN film is provided as an insulating film between G@3 and G@3, the same effect can be obtained by providing a nitride film made of AJ7N instead of this SiN film.

又、バリア膜とBPSG膜との間の絶縁膜として窒化膜
の代わりにポリシリコン又はシリコン化合物からなる膜
を設けても上記実施例と同様の効果を害ることができる
Further, even if a film made of polysilicon or a silicon compound is provided as an insulating film between the barrier film and the BPSG film instead of the nitride film, the same effect as in the above embodiment can be impaired.

又、窒化膜の代わりに、Bを含まない酸化膜、例えばC
VD法を用いて形成するSiO2膜を用いても、従来の
半導体装置に比べて密着性不良を改善することができる
。但し、この場合界面はがれ率はほぼ零とはならない。
Also, instead of the nitride film, an oxide film that does not contain B, such as C
Even with the use of a SiO2 film formed using the VD method, poor adhesion can be improved compared to conventional semiconductor devices. However, in this case, the interface peeling rate is not approximately zero.

なお、上記実施例においては、下地絶縁膜がBPSG膜
である場合について説明したが、BPSG膜の代わりに
酸化膜、例えばS IO2@を用いた場合でも本実施例
と同様の効果を得る二とかできる。
In the above embodiment, the case where the underlying insulating film is a BPSG film has been described, but the same effect as in this embodiment can be obtained even when an oxide film, for example, SIO2@, is used instead of the BPSG film. can.

次に、第2の発明による半導体装置の一実施例を第2図
を参照して説明する。第2図は上記実施例の半導体装置
の製造工程断面図である。この半導体装置は先ず、半導
体基板1上に例えばBPSG膜3を形成し、半導体基板
1上の拡散層2とのコンタクトを取るためのコンタクト
ホールをBPSG膜3に開孔する。その後、TiiSを
スパッタ法を用いて堆積する(第2図(a)参照)。そ
の後史にその上に例えばTiN膜(図示せず)をスパッ
タ法を用いて堆積させるか又はTiiSの表面の窒化を
行った後に、約500〜800℃の温度で熱処理を行う
Next, an embodiment of the semiconductor device according to the second invention will be described with reference to FIG. FIG. 2 is a cross-sectional view of the manufacturing process of the semiconductor device of the above embodiment. In this semiconductor device, first, for example, a BPSG film 3 is formed on a semiconductor substrate 1, and a contact hole for making contact with a diffusion layer 2 on the semiconductor substrate 1 is opened in the BPSG film 3. Thereafter, TiiS is deposited using a sputtering method (see FIG. 2(a)). Thereafter, for example, a TiN film (not shown) is deposited thereon by sputtering or the surface of the TiiS is nitrided, and then heat treatment is performed at a temperature of about 500 to 800°C.

すると、TiiSとSiの界面、すなわちTiiSと半
導体基板1の界面のみにTiとSiの化合物(TiSi
2)からなる層6が形成され、このT iS L 2層
を残してTiiS又は、TiN膜及びTiiSを選択的
にエツチング除去する(第2図(b)参照)。その後T
iN膜7を堆積した後、AIl又はAl1e:金からな
る配線膜8を形成する(第2図(C)参照)。そしてバ
ターニングを行って配線を形成した後、絶縁保護膜(図
示せず)を堆積してパッド開孔を行う(図示せず)。
Then, a compound of Ti and Si (TiSi
A layer 6 consisting of 2) is formed, and TiiS or the TiN film and TiiS are selectively etched away leaving this T iS L 2 layer (see FIG. 2(b)). Then T
After depositing the iN film 7, a wiring film 8 made of Al or Al1e:gold is formed (see FIG. 2(C)). After patterning is performed to form wiring, an insulating protective film (not shown) is deposited, and pad holes are formed (not shown).

このようにして形成された半導体装置のノくラド部にワ
イヤ接続した後、このワイヤの剥離テストを行っても、
パッド部の、下地絶縁膜3とバリアメタル7との界面近
傍で剥離する割合、すなわち界面はがれ率は、バリアメ
タル5の熱処理a度に依らずほぼ零であった。これによ
り、本実施例の半導体装置は密着性不良は生じず、信頼
性の高いものとなる。
Even if a peel test is performed on the wire after connecting the wire to the nodal part of the semiconductor device formed in this way,
The peeling rate near the interface between base insulating film 3 and barrier metal 7 in the pad portion, that is, the interface peeling rate, was almost zero regardless of the degree of heat treatment of barrier metal 5. As a result, the semiconductor device of this example does not suffer from poor adhesion and is highly reliable.

なお、本実施例の半導体装置のコンタクト抵抗を計量l
したとこる従来の半導体装置と同程度て間−題ない。
Note that the contact resistance of the semiconductor device of this example was measured by l.
There is no problem as it is on the same level as a conventional semiconductor device.

〔発明の効果〕〔Effect of the invention〕

本発明によれば密も性に対して高い(Q顕性を得ること
ができる。
According to the present invention, it is possible to obtain high (Q-sensitivity) relative to density.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は第1の発明による半導体装置の一実施例の製造
工程を示す断面図、第2図は第2の発明による半導体装
置の一実施例の製造工程を示す断面図、第3図は本発明
の詳細な説明するグラフ、第4図は従来の半導体装置の
断面図である。 1・・・半導体基板、2・・・拡散層、3・・・BPS
G膜、4・・・5iNPAl5・・・TiWIIc16
・・・TiSi2膜、7・・・TiN膜、8・・・Aj
7系配系層線層願人代理人  佐  藤  −雄 第1図
FIG. 1 is a sectional view showing the manufacturing process of an embodiment of the semiconductor device according to the first invention, FIG. 2 is a sectional view showing the manufacturing process of an embodiment of the semiconductor device according to the second invention, and FIG. A graph explaining the present invention in detail, and FIG. 4 is a cross-sectional view of a conventional semiconductor device. 1... Semiconductor substrate, 2... Diffusion layer, 3... BPS
G film, 4...5iNPAl5...TiWIIc16
...TiSi2 film, 7...TiN film, 8...Aj
7th system distribution layer applicant agent Sato -O Figure 1

Claims (1)

【特許請求の範囲】 1、半導体基板上に形成された絶縁膜と、この絶縁膜上
に形成されるホウ素を含まない絶縁膜層と、このホウ素
を含まない絶縁膜層上に形成されるTi及びTiNから
なる2層構造のバリア膜と、このバリア膜上に形成され
るAl又はAl合金からなるAl系配線膜とを備えてい
ることを特徴とする半導体装置。 2、前記ホウ素を含まない絶縁膜層は、 SiN又はAlNのいずれか一方の材料によって形成さ
れていることを特徴とする請求項1記載の半導体装置。 3、半導体基板上に形成された絶縁膜と、この絶縁膜に
開孔されたコンタクトホールの底部の半導体基板表面の
みに形成されるTiシリサイド層と、このTiシリサイ
ド層及び前記絶縁膜上に形成されるTiN膜と、このT
iN膜上に形成されるAl又はAl合金からなるAl系
配線膜とを備えていることを特徴とする半導体装置。 4、前記半導体基板上に形成される絶縁膜はBPSG膜
であることを特徴とする請求項1乃至3のいずれかに記
載の半導体装置。
[Claims] 1. An insulating film formed on a semiconductor substrate, an insulating film layer not containing boron formed on the insulating film, and a Ti insulating film layer formed on the insulating film layer not containing boron. A semiconductor device comprising: a barrier film having a two-layer structure made of TiN; and an Al-based wiring film made of Al or an Al alloy formed on the barrier film. 2. The semiconductor device according to claim 1, wherein the insulating film layer not containing boron is formed of one of SiN and AlN. 3. An insulating film formed on a semiconductor substrate, a Ti silicide layer formed only on the surface of the semiconductor substrate at the bottom of a contact hole opened in this insulating film, and a Ti silicide layer formed on this Ti silicide layer and the insulating film. TiN film and this T
A semiconductor device comprising an Al-based wiring film made of Al or an Al alloy formed on an iN film. 4. The semiconductor device according to claim 1, wherein the insulating film formed on the semiconductor substrate is a BPSG film.
JP32755390A 1990-11-28 1990-11-28 Semiconductor device Expired - Lifetime JP2848694B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP32755390A JP2848694B2 (en) 1990-11-28 1990-11-28 Semiconductor device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP32755390A JP2848694B2 (en) 1990-11-28 1990-11-28 Semiconductor device

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0660392A1 (en) * 1993-12-17 1995-06-28 STMicroelectronics, Inc. Method and interlevel dielectric structure for improved metal step coverage
US5793114A (en) * 1993-12-17 1998-08-11 Sgs-Thomson Microelectronics, Inc. Self-aligned method for forming contact with zero offset to gate
US6051864A (en) * 1993-12-17 2000-04-18 Stmicroelectronics, Inc. Memory masking for periphery salicidation of active regions
US6344411B1 (en) 1997-11-21 2002-02-05 Nec Corporation OHMIC contact plug having an improved crack free tin barrier metal in a contact hole and method of forming the same
JP2004063610A (en) * 2002-07-26 2004-02-26 Seiko Instruments Inc Manufacturing method of semiconductor device

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0660392A1 (en) * 1993-12-17 1995-06-28 STMicroelectronics, Inc. Method and interlevel dielectric structure for improved metal step coverage
US5793114A (en) * 1993-12-17 1998-08-11 Sgs-Thomson Microelectronics, Inc. Self-aligned method for forming contact with zero offset to gate
US6051864A (en) * 1993-12-17 2000-04-18 Stmicroelectronics, Inc. Memory masking for periphery salicidation of active regions
US6284584B1 (en) * 1993-12-17 2001-09-04 Stmicroelectronics, Inc. Method of masking for periphery salicidation of active regions
US6514811B2 (en) 1993-12-17 2003-02-04 Stmicroelectronics, Inc. Method for memory masking for periphery salicidation of active regions
US6812142B1 (en) 1993-12-17 2004-11-02 Stmicroelectronics, Inc. Method and interlevel dielectric structure for improved metal step coverage
US6344411B1 (en) 1997-11-21 2002-02-05 Nec Corporation OHMIC contact plug having an improved crack free tin barrier metal in a contact hole and method of forming the same
US6787913B2 (en) 1997-11-21 2004-09-07 Nec Electronics Corporation Ohmic contact plug having an improved crack free TiN barrier metal in a contact hole and method of forming the same
JP2004063610A (en) * 2002-07-26 2004-02-26 Seiko Instruments Inc Manufacturing method of semiconductor device

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