JPH04173854A - Stabilized chlorine-containing resin composition - Google Patents
Stabilized chlorine-containing resin compositionInfo
- Publication number
- JPH04173854A JPH04173854A JP30142290A JP30142290A JPH04173854A JP H04173854 A JPH04173854 A JP H04173854A JP 30142290 A JP30142290 A JP 30142290A JP 30142290 A JP30142290 A JP 30142290A JP H04173854 A JPH04173854 A JP H04173854A
- Authority
- JP
- Japan
- Prior art keywords
- acid
- perchloric acid
- treated
- containing resin
- chlorine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 title claims abstract description 27
- 239000000460 chlorine Substances 0.000 title claims abstract description 27
- 229910052801 chlorine Inorganic materials 0.000 title claims abstract description 27
- 239000011342 resin composition Substances 0.000 title claims abstract description 9
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 claims abstract description 101
- 229920005989 resin Polymers 0.000 claims abstract description 25
- 239000011347 resin Substances 0.000 claims abstract description 25
- 229910052751 metal Inorganic materials 0.000 claims abstract description 24
- 239000002184 metal Substances 0.000 claims abstract description 24
- 150000003839 salts Chemical class 0.000 claims abstract description 21
- 229910001701 hydrotalcite Inorganic materials 0.000 claims abstract description 18
- 229960001545 hydrotalcite Drugs 0.000 claims abstract description 18
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 claims abstract description 16
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000000203 mixture Substances 0.000 abstract description 29
- -1 organic acid salt Chemical class 0.000 abstract description 27
- 239000004800 polyvinyl chloride Substances 0.000 abstract description 8
- 229920000915 polyvinyl chloride Polymers 0.000 abstract description 8
- 230000000087 stabilizing effect Effects 0.000 abstract description 8
- 239000011575 calcium Substances 0.000 abstract description 5
- 239000011777 magnesium Substances 0.000 abstract description 5
- 229910052749 magnesium Inorganic materials 0.000 abstract description 5
- 239000000378 calcium silicate Substances 0.000 abstract description 4
- 229910052918 calcium silicate Inorganic materials 0.000 abstract description 4
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 abstract description 4
- 239000000391 magnesium silicate Substances 0.000 abstract description 4
- 229910052919 magnesium silicate Inorganic materials 0.000 abstract description 4
- 235000019792 magnesium silicate Nutrition 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract description 4
- 229910052791 calcium Inorganic materials 0.000 abstract description 3
- 238000013329 compounding Methods 0.000 abstract description 3
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 abstract description 3
- 229910052700 potassium Inorganic materials 0.000 abstract description 3
- 229910052708 sodium Inorganic materials 0.000 abstract description 3
- ZADYMNAVLSWLEQ-UHFFFAOYSA-N magnesium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[Mg+2].[Si+4] ZADYMNAVLSWLEQ-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 description 21
- 229920001577 copolymer Polymers 0.000 description 18
- 150000001875 compounds Chemical class 0.000 description 16
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 10
- 230000032683 aging Effects 0.000 description 8
- OOULUYZFLXDWDQ-UHFFFAOYSA-L barium perchlorate Chemical compound [Ba+2].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O OOULUYZFLXDWDQ-UHFFFAOYSA-L 0.000 description 8
- 150000004760 silicates Chemical class 0.000 description 8
- 239000011701 zinc Substances 0.000 description 8
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 7
- 239000004014 plasticizer Substances 0.000 description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 6
- 238000009472 formulation Methods 0.000 description 6
- 239000003549 soybean oil Substances 0.000 description 6
- 235000012424 soybean oil Nutrition 0.000 description 6
- 239000003381 stabilizer Substances 0.000 description 6
- 239000004593 Epoxy Substances 0.000 description 5
- 150000001735 carboxylic acids Chemical class 0.000 description 5
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 5
- 239000006260 foam Substances 0.000 description 5
- 150000007524 organic acids Chemical class 0.000 description 5
- XOUQAVYLRNOXDO-UHFFFAOYSA-N 2-tert-butyl-5-methylphenol Chemical compound CC1=CC=C(C(C)(C)C)C(O)=C1 XOUQAVYLRNOXDO-UHFFFAOYSA-N 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 4
- 239000004927 clay Substances 0.000 description 4
- 238000004040 coloring Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229910052736 halogen Inorganic materials 0.000 description 4
- 150000002367 halogens Chemical class 0.000 description 4
- 150000002989 phenols Chemical class 0.000 description 4
- 235000021317 phosphate Nutrition 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 150000005846 sugar alcohols Polymers 0.000 description 4
- 229910052725 zinc Inorganic materials 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- 229910021536 Zeolite Inorganic materials 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 229910052916 barium silicate Inorganic materials 0.000 description 3
- HMOQPOVBDRFNIU-UHFFFAOYSA-N barium(2+);dioxido(oxo)silane Chemical compound [Ba+2].[O-][Si]([O-])=O HMOQPOVBDRFNIU-UHFFFAOYSA-N 0.000 description 3
- AGXUVMPSUKZYDT-UHFFFAOYSA-L barium(2+);octadecanoate Chemical compound [Ba+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AGXUVMPSUKZYDT-UHFFFAOYSA-L 0.000 description 3
- 229940106691 bisphenol a Drugs 0.000 description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 3
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 239000000944 linseed oil Substances 0.000 description 3
- 235000021388 linseed oil Nutrition 0.000 description 3
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 3
- 150000007522 mineralic acids Chemical class 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 238000003672 processing method Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- 239000010457 zeolite Substances 0.000 description 3
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 2
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 2
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- HPEUJPJOZXNMSJ-UHFFFAOYSA-N Methyl stearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC HPEUJPJOZXNMSJ-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- UJMDYLWCYJJYMO-UHFFFAOYSA-N benzene-1,2,3-tricarboxylic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1C(O)=O UJMDYLWCYJJYMO-UHFFFAOYSA-N 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- 230000018044 dehydration Effects 0.000 description 2
- 238000006297 dehydration reaction Methods 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-MDZDMXLPSA-N elaidic acid Chemical compound CCCCCCCC\C=C\CCCCCCCC(O)=O ZQPPMHVWECSIRJ-MDZDMXLPSA-N 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- MNWFXJYAOYHMED-UHFFFAOYSA-N heptanoic acid Chemical compound CCCCCCC(O)=O MNWFXJYAOYHMED-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 2
- IXQGCWUGDFDQMF-UHFFFAOYSA-N o-Hydroxyethylbenzene Natural products CCC1=CC=CC=C1O IXQGCWUGDFDQMF-UHFFFAOYSA-N 0.000 description 2
- UTOPWMOLSKOLTQ-UHFFFAOYSA-N octacosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O UTOPWMOLSKOLTQ-UHFFFAOYSA-N 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- GJYCVCVHRSWLNY-UHFFFAOYSA-N ortho-butylphenol Natural products CCCCC1=CC=CC=C1O GJYCVCVHRSWLNY-UHFFFAOYSA-N 0.000 description 2
- CKMXAIVXVKGGFM-UHFFFAOYSA-N p-cumic acid Chemical compound CC(C)C1=CC=C(C(O)=O)C=C1 CKMXAIVXVKGGFM-UHFFFAOYSA-N 0.000 description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 2
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 2
- 229920001228 polyisocyanate Polymers 0.000 description 2
- 239000005056 polyisocyanate Substances 0.000 description 2
- 229920005862 polyol Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 150000003077 polyols Chemical class 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 229910052712 strontium Inorganic materials 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- SZHOJFHSIKHZHA-UHFFFAOYSA-N tridecanoic acid Chemical compound CCCCCCCCCCCCC(O)=O SZHOJFHSIKHZHA-UHFFFAOYSA-N 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 2
- ZDPHROOEEOARMN-UHFFFAOYSA-N undecanoic acid Chemical compound CCCCCCCCCCC(O)=O ZDPHROOEEOARMN-UHFFFAOYSA-N 0.000 description 2
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- CHJMFFKHPHCQIJ-UHFFFAOYSA-L zinc;octanoate Chemical compound [Zn+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O CHJMFFKHPHCQIJ-UHFFFAOYSA-L 0.000 description 2
- GGAUUQHSCNMCAU-ZXZARUISSA-N (2s,3r)-butane-1,2,3,4-tetracarboxylic acid Chemical compound OC(=O)C[C@H](C(O)=O)[C@H](C(O)=O)CC(O)=O GGAUUQHSCNMCAU-ZXZARUISSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- 239000001124 (E)-prop-1-ene-1,2,3-tricarboxylic acid Substances 0.000 description 1
- 229920003067 (meth)acrylic acid ester copolymer Polymers 0.000 description 1
- BPXVHIRIPLPOPT-UHFFFAOYSA-N 1,3,5-tris(2-hydroxyethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound OCCN1C(=O)N(CCO)C(=O)N(CCO)C1=O BPXVHIRIPLPOPT-UHFFFAOYSA-N 0.000 description 1
- OUPZKGBUJRBPGC-UHFFFAOYSA-N 1,3,5-tris(oxiran-2-ylmethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound O=C1N(CC2OC2)C(=O)N(CC2OC2)C(=O)N1CC1CO1 OUPZKGBUJRBPGC-UHFFFAOYSA-N 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- 229940114072 12-hydroxystearic acid Drugs 0.000 description 1
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- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- MEYFIGJKMVBYOG-UHFFFAOYSA-N hexanedioic acid;2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OC(=O)CCCCC(O)=O.OCC(CO)(CO)COCC(CO)(CO)CO.OCC(CO)(CO)COCC(CO)(CO)CO MEYFIGJKMVBYOG-UHFFFAOYSA-N 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- GVALZJMUIHGIMD-UHFFFAOYSA-H magnesium phosphate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GVALZJMUIHGIMD-UHFFFAOYSA-H 0.000 description 1
- 239000004137 magnesium phosphate Substances 0.000 description 1
- 229910000157 magnesium phosphate Inorganic materials 0.000 description 1
- 229960002261 magnesium phosphate Drugs 0.000 description 1
- 235000010994 magnesium phosphates Nutrition 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 150000004701 malic acid derivatives Chemical class 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- ZWLPBLYKEWSWPD-UHFFFAOYSA-N o-toluic acid Chemical compound CC1=CC=CC=C1C(O)=O ZWLPBLYKEWSWPD-UHFFFAOYSA-N 0.000 description 1
- UHGIMQLJWRAPLT-UHFFFAOYSA-N octadecyl dihydrogen phosphate Chemical compound CCCCCCCCCCCCCCCCCCOP(O)(O)=O UHGIMQLJWRAPLT-UHFFFAOYSA-N 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 150000002898 organic sulfur compounds Chemical class 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- MFPCPCHVMQLDJN-UHFFFAOYSA-N phenyl ditridecyl phosphite Chemical compound CCCCCCCCCCCCCOP(OCCCCCCCCCCCCC)OC1=CC=CC=C1 MFPCPCHVMQLDJN-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 1
- 229920005671 poly(vinyl chloride-propylene) Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 150000003873 salicylate salts Chemical class 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229960004274 stearic acid Drugs 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 239000012756 surface treatment agent Substances 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 235000019303 thiodipropionic acid Nutrition 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- GTZCVFVGUGFEME-UHFFFAOYSA-N trans-aconitic acid Natural products OC(=O)CC(C(O)=O)=CC(O)=O GTZCVFVGUGFEME-UHFFFAOYSA-N 0.000 description 1
- XTTGYFREQJCEML-UHFFFAOYSA-N tributyl phosphite Chemical compound CCCCOP(OCCCC)OCCCC XTTGYFREQJCEML-UHFFFAOYSA-N 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- IVIIAEVMQHEPAY-UHFFFAOYSA-N tridodecyl phosphite Chemical compound CCCCCCCCCCCCOP(OCCCCCCCCCCCC)OCCCCCCCCCCCC IVIIAEVMQHEPAY-UHFFFAOYSA-N 0.000 description 1
- 125000005591 trimellitate group Chemical group 0.000 description 1
- ILLOBGFGKYTZRO-UHFFFAOYSA-N tris(2-ethylhexyl) phosphite Chemical compound CCCCC(CC)COP(OCC(CC)CCCC)OCC(CC)CCCC ILLOBGFGKYTZRO-UHFFFAOYSA-N 0.000 description 1
- WGKLOLBTFWFKOD-UHFFFAOYSA-N tris(2-nonylphenyl) phosphite Chemical compound CCCCCCCCCC1=CC=CC=C1OP(OC=1C(=CC=CC=1)CCCCCCCCC)OC1=CC=CC=C1CCCCCCCCC WGKLOLBTFWFKOD-UHFFFAOYSA-N 0.000 description 1
- JZNDMMGBXUYFNQ-UHFFFAOYSA-N tris(dodecylsulfanyl)phosphane Chemical compound CCCCCCCCCCCCSP(SCCCCCCCCCCCC)SCCCCCCCCCCCC JZNDMMGBXUYFNQ-UHFFFAOYSA-N 0.000 description 1
- QQBLOZGVRHAYGT-UHFFFAOYSA-N tris-decyl phosphite Chemical compound CCCCCCCCCCOP(OCCCCCCCCCC)OCCCCCCCCCC QQBLOZGVRHAYGT-UHFFFAOYSA-N 0.000 description 1
- WRSPWQHUHVRNFV-UHFFFAOYSA-N tris[3,5-di(nonyl)phenyl] phosphite Chemical compound CCCCCCCCCC1=CC(CCCCCCCCC)=CC(OP(OC=2C=C(CCCCCCCCC)C=C(CCCCCCCCC)C=2)OC=2C=C(CCCCCCCCC)C=C(CCCCCCCCC)C=2)=C1 WRSPWQHUHVRNFV-UHFFFAOYSA-N 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 229940005605 valeric acid Drugs 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 150000003739 xylenols Chemical class 0.000 description 1
- 229940098697 zinc laurate Drugs 0.000 description 1
- 235000019352 zinc silicate Nutrition 0.000 description 1
- JDWKHPKWCUBDHC-UHFFFAOYSA-L zinc;2-tert-butylbenzoate Chemical compound [Zn+2].CC(C)(C)C1=CC=CC=C1C([O-])=O.CC(C)(C)C1=CC=CC=C1C([O-])=O JDWKHPKWCUBDHC-UHFFFAOYSA-L 0.000 description 1
- GPYYEEJOMCKTPR-UHFFFAOYSA-L zinc;dodecanoate Chemical compound [Zn+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O GPYYEEJOMCKTPR-UHFFFAOYSA-L 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、安定化された塩素含有樹脂組成物、詳しくは
、塩素含有樹脂に、過塩素酸の金属塩、及び過塩素酸処
理ハイドロタルサイトまたは過塩素酸処理珪酸塩を添加
してなる塩素含有樹脂組成物に関するものである。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention provides a stabilized chlorine-containing resin composition, specifically, a chlorine-containing resin containing a metal salt of perchloric acid and a perchloric acid-treated hydrotal. The present invention relates to a chlorine-containing resin composition to which silicates or perchloric acid-treated silicate are added.
〔従来の技術及び発明が解決しようとする課題〕塩素含
有樹脂は、加熱成型加工を行なう際に、主として脱塩化
水素に起因する熱分解を起こしやすく、このために加工
製品の機械的性質の劣化、色調の悪化を生じ、著しい不
利益をまねく。[Prior art and problems to be solved by the invention] Chlorine-containing resins tend to undergo thermal decomposition mainly due to dehydrochlorination when subjected to heat molding, and this causes deterioration of the mechanical properties of processed products. , resulting in deterioration of color tone and significant disadvantages.
かかる不利益を避けるために、一種または数種の熱安定
剤を該樹脂に添加し、加工工程における劣化を抑制する
必要がある。In order to avoid such disadvantages, it is necessary to add one or more heat stabilizers to the resin to suppress deterioration during processing.
従来かかる目的で各種の有機酸または無機酸の金属塩、
有機錫化合物等を数種組み合わせて使用することが行わ
れており、熱安定性の面ではほぼ満足すべき結果が得ら
れている。Conventionally, metal salts of various organic or inorganic acids,
Combinations of several types of organic tin compounds have been used, and almost satisfactory results have been obtained in terms of thermal stability.
しかしながら、これらの各種金属塩の組み合わせ、例え
ば、Cd/Ba系、Ba/Zn系、Ca/Zn系、Ba
/Ca/Zn系等を用いた場合には、着色性等の性能は
十分でなく、各種の安定化助剤、例えばエポキシ化合物
、多価アルコール類、有機燐化合物、有機硫黄化合物、
フェノール化合物、β−ジケトン化合物等の使用が提案
されているが、まだ十分とは言えず、さらに自動車内装
材のように、ポリウレタンまたはポリプロピレンを裏打
ちした場合、また鋼板のように、長期に比較的低温度の
熱がかかる場合における熱着色性は十分でなく、更に改
善する必要があった。However, combinations of these various metal salts, such as Cd/Ba system, Ba/Zn system, Ca/Zn system, Ba
/Ca/Zn type etc., performance such as colorability is not sufficient, and various stabilizing aids such as epoxy compounds, polyhydric alcohols, organic phosphorus compounds, organic sulfur compounds,
The use of phenolic compounds, β-diketone compounds, etc. has been proposed, but it is still not sufficient, and furthermore, when lined with polyurethane or polypropylene, such as in automobile interior materials, or with steel plates, the use of phenolic compounds, β-diketone compounds, etc. The thermal coloring property when low-temperature heat is applied is not sufficient, and there is a need for further improvement.
近年、無機酸金属塩のなかでも、ハロゲン酸素酸の金属
塩が、特に、着色性を改善する効果が大きいことが見出
され、上記有機酸または無機酸の金属塩、有機錫化合物
等と併用することが提案されている。例えば、特開昭5
3−13659号公報には、塩基性無機酸塩とハロゲン
酸素酸塩の併用が提案され、特開昭58−122951
号公報には、ハイドロタルサイトiとハロゲン酸素酸塩
の併用が提案され、特開昭61−34042号公報には
、ゼオライト構造を有するアルミノケイ酸塩とハロゲン
酸素酸塩の併用が提案されている。In recent years, among inorganic acid metal salts, metal salts of halogen oxyacids have been found to be particularly effective in improving coloring properties, and can be used in combination with metal salts of the above-mentioned organic or inorganic acids, organotin compounds, etc. It is proposed to do so. For example, JP-A-5
3-13659 proposes the combination of a basic inorganic acid salt and a halogen oxyacid, and JP-A-58-122951
JP-A-61-34042 proposes the combination of hydrotalcite i and halogen oxyacid, and JP-A-61-34042 proposes the combination of aluminosilicate having a zeolite structure and halogen oxyacid. .
また、過塩素酸処理したハイドロタルサイト類及び過塩
素酸処理した珪酸塩を使用することが提案されている。It has also been proposed to use perchloric acid treated hydrotalcites and perchloric acid treated silicates.
例えば、特開昭59−140261号公報には、過塩素
酸処理したハイドロタルサイトaが提案され、特開昭6
1−78874号公報及び特開昭61−113636号
公報には、過塩素酸処理した珪酸塩が提案されているが
、その安定化効果は未だ不十分であり、実用上満足し得
るものでなかった。For example, in JP-A-59-140261, hydrotalcite a treated with perchloric acid was proposed;
1-78874 and JP-A-61-113636 propose silicate treated with perchloric acid, but the stabilizing effect is still insufficient and is not practically satisfactory. Ta.
本発明者等は、上記の現状に鑑み、種々検討を重ねた結
果、塩素含有樹脂に、(イ)過塩素酸の金属塩の少なく
とも1種及び(ロ)過塩素酸処理ハイドロタルサイトま
たは過塩素酸処理珪酸塩の少なくとも1種を添加するこ
とにより、著しい安定化効果が得られることを見出し、
本発明に到達したものである。In view of the above-mentioned current situation, the present inventors have conducted various studies and found that (a) at least one metal salt of perchloric acid and (b) perchloric acid-treated hydrotalcite or perchloric acid are added to the chlorine-containing resin. It has been discovered that a significant stabilizing effect can be obtained by adding at least one type of chloric acid-treated silicate,
This has led to the present invention.
以下、本発明の塩素含有樹脂組成物について詳述する。Hereinafter, the chlorine-containing resin composition of the present invention will be explained in detail.
本発明で用いられる過塩素酸の金属塩を構成する金属成
分としては、リチウム、ナトリウム、カリウム、マグネ
シウム、カルシウム、ストロンチウム、バリウム、亜鉛
、カドミウム、鉛、アルミニウムなどが例示でき、これ
ら過塩素酸の金属塩は無水物でも含水物であってもよい
。また、ブチルジグリコール、ブチルジグリコールアジ
ペート等のアルコール系及びエステル系の溶剤に溶かし
たもの及びその脱水物でもよい。Examples of metal components constituting the metal salt of perchloric acid used in the present invention include lithium, sodium, potassium, magnesium, calcium, strontium, barium, zinc, cadmium, lead, and aluminum. The metal salt may be anhydrous or hydrated. Further, it may be dissolved in an alcohol-based or ester-based solvent such as butyl diglycol or butyl diglycol adipate, or a dehydrated product thereof.
これら過塩素酸の金属塩の添加量は、塩素含有樹脂10
0重量部に対して、0.001〜5重量部、特に0.0
1〜3重量部が好ましい。The amount of these metal salts of perchloric acid added is 10% of the chlorine-containing resin.
0 parts by weight, 0.001 to 5 parts by weight, especially 0.0 parts by weight
1 to 3 parts by weight is preferred.
本発明で用いられる過塩素酸処理ハイドロタルサイトは
、ハイドロタルサイト化合物の炭酸の一部及びすべてを
過塩素酸で置き換えた過塩素酸変性品である。上記ハイ
ドロタルサイト化合物とはマグネシウム及び/又は亜鉛
とアルミニウムとの炭酸複塩化合物であり、これらは、
天然ハイドロタルサイト及び合成ハイドロタルサイトを
含む。The perchloric acid-treated hydrotalcite used in the present invention is a perchloric acid-modified product in which part and all of the carbonic acid in the hydrotalcite compound is replaced with perchloric acid. The above hydrotalcite compound is a carbonate double salt compound of magnesium and/or zinc and aluminum, and these are
Contains natural hydrotalcite and synthetic hydrotalcite.
合成ハイドロタルサイトは次の式で表される化合物であ
り、マグネシウム及び亜鉛とアルミニウムの比率は任意
に変化させることができ、また、含まれる結晶水の量も
加熱脱水の程度によって任意に変化させることができる
。Synthetic hydrotalcite is a compound represented by the following formula, and the ratio of magnesium and zinc to aluminum can be changed arbitrarily, and the amount of crystal water contained can also be changed arbitrarily depending on the degree of heat dehydration. be able to.
Mgy+Zn、zAlx・(OH) z・(COt)x
zz・mHzO(式中、x、y、、及びy2は各々下記
式であられされる条件を満足する数を示し、mはO又は
任意の正数を示す。Mgy+Zn,zAlx・(OH)z・(COt)x
zz·mHzO (where x, y, and y2 each represent a number that satisfies the conditions expressed by the following formula, and m represents O or any positive number.
0<x≦0.5、y++Vz=1 x、0.1≦y+
<1.0≦y2<0.8)本発明で用いられる過塩素酸
処理珪酸塩としては、珪酸カルシウム、珪酸マグネシウ
ム、珪酸バリウム、珪酸亜鉛等の珪酸金属塩や各種珪酸
質粘土鉱物酸いはその処理物、例えば、カオリン、ベン
トナイト、マイカ粉、タルク、珪藻土、酸性白土、活性
白土やゼオライト等の天然或いは合成珪酸塩を過塩素酸
水溶液で処理したものが挙げられ、これらの過塩素酸処
理珪酸塩のうちでも、珪酸カルシウム、珪酸マグネシウ
ム、珪酸バリウム、カオリン、ベントナイト、タルク、
酸性白土、活性白土、ゼオライトの処理物が好ましい。0<x≦0.5, y++Vz=1 x, 0.1≦y+
<1.0≦y2<0.8) The perchloric acid-treated silicates used in the present invention include silicate metal salts such as calcium silicate, magnesium silicate, barium silicate, and zinc silicate, and various silicate clay mineral acids. Examples of treated products include natural or synthetic silicates such as kaolin, bentonite, mica powder, talc, diatomaceous earth, acid clay, activated clay, and zeolite, which are treated with an aqueous perchloric acid solution. Among silicates, calcium silicate, magnesium silicate, barium silicate, kaolin, bentonite, talc,
Acid clay, activated clay, and processed products of zeolite are preferred.
これらの過塩素酸処理ハイドロタルサイトまたは過塩素
酸処理珪酸塩は、例えば、ハイドロタルサイトまたは珪
酸塩を過塩素酸の希薄水溶液中に加えて撹拌するか、或
いは、ハイドロタルサイトまたは珪酸塩に過塩素酸の濃
厚水溶液を加えて撹拌し、その後必要に応じて、ろ過、
脱水または乾燥することによって容易に製造することが
できる。These perchloric acid-treated hydrotalcites or perchloric acid-treated silicates can be produced, for example, by adding hydrotalcite or silicates to a dilute aqueous solution of perchloric acid and stirring, or by adding hydrotalcites or silicates to a dilute aqueous solution of perchloric acid and stirring. Add a concentrated aqueous solution of perchloric acid and stir, then filter, if necessary.
It can be easily produced by dehydration or drying.
ハイドロタルサイトまたは珪酸塩と過塩素酸のモル比は
任意に設定することができるが、一般には、ハイドロタ
ルサイトまたは珪酸塩1モルに対し、過塩素酸0.1〜
2モルとなるような比率で用いることが好ましい。The molar ratio of hydrotalcite or silicate to perchloric acid can be set arbitrarily, but in general, 0.1 to 1 mol of perchloric acid to 1 mol of hydrotalcite or silicate.
It is preferable to use a ratio of 2 moles.
これら過塩素酸処理ハイドロタルサイトまたは過塩素酸
処理珪酸塩の添加量は、塩素含有樹脂100重量部に対
して、各々0.001〜5重量部、特に0.01〜3重
量部が好ましい。The amount of the perchloric acid-treated hydrotalcite or perchloric acid-treated silicate to be added is preferably 0.001 to 5 parts by weight, particularly 0.01 to 3 parts by weight, per 100 parts by weight of the chlorine-containing resin.
また、本発明で安定剤として用いられる過塩素酸の金属
塩及び過塩素酸処理ハイドロタルサイトまたは過塩素酸
処理珪酸塩は、それぞれ別個に塩素含有樹脂に配合する
こともできるが、これらを混合して用いることもでき、
この場合には、必要に応じて他の安定剤成分等も含むい
わゆる複合系安定剤として用いることもできる。In addition, the metal salt of perchloric acid, perchloric acid-treated hydrotalcite, or perchloric acid-treated silicate used as a stabilizer in the present invention can be separately blended into the chlorine-containing resin, but they can be mixed together. It can also be used as
In this case, it can also be used as a so-called composite stabilizer containing other stabilizer components as required.
本発明に用いられる塩素含有樹脂としては次のようなも
のがある。例えば、ポリ塩化ビニル、後塩素化ポリ塩化
ビニル、ポリ塩化ビニリデン、塩素化ポリエチレン、塩
素化ポリプロピレン、塩化ゴム、塩化ビニル−酢酸ビニ
ル共重合体、塩化ビニル−エチレン共重合体、塩化ビニ
ル−プロピレン共重合体、塩化ビニル−スチレン共重合
体、塩化ビニル−イソブチレン共重合体、塩化ヒニルー
塩化ビニリデン共重合体、塩化ビニル−スチレン−無水
マレイン酸三元共重合体、塩化ビニル−アルキル、シク
ロアルキル又はアリールマレイミド共重合体、塩化ビニ
ル−スチレン−アクリロニトリル共重合体、塩化ビニル
−ブタジェン共重合体、塩化ビニル−イソプレン共重合
体、塩化ビニル−塩素化プロピレン共重合体、塩化ビニ
ル−塩化ビニリデン−酢酸ビニル三元共重合体、塩化ビ
ニル−アクリル酸エステル共重合体、塩化ビニル−マレ
イン酸エステル共重合体、塩化ビニル−メタクリル酸エ
ステル共重合体、塩化ビニル−アクリロニトリル共重合
体、塩化ビニル−ウレタン共重合体等の塩素含有樹脂、
及び上記塩素含有樹脂と、ポリエチレン、ポリプロピレ
ン、ポリブテン、ポリ−3−メチルブテンなどのα−オ
レフィン重合体またはエチレン−酢酸ビニル共重合体、
エチレン−プロピレン共重合体などのポリオレフィン及
びこれらの共重合体、ポリスチレン、アクリル樹脂、ス
チレンと他の単量体(例えば無水マレイン酸、ブタジェ
ン、アクリロニトリルなど)との共重合体、アクリロニ
トリル−ブタジェン−スチレン共重合体、メタクリル酸
エステル−ブタジェン−スチレン共重合体、ポリウレタ
ンとのブレンド品などを挙げることができる。Examples of chlorine-containing resins used in the present invention include the following. For example, polyvinyl chloride, post-chlorinated polyvinyl chloride, polyvinylidene chloride, chlorinated polyethylene, chlorinated polypropylene, chlorinated rubber, vinyl chloride-vinyl acetate copolymer, vinyl chloride-ethylene copolymer, vinyl chloride-propylene copolymer, Polymer, vinyl chloride-styrene copolymer, vinyl chloride-isobutylene copolymer, vinyl chloride-vinylidene chloride copolymer, vinyl chloride-styrene-maleic anhydride terpolymer, vinyl chloride-alkyl, cycloalkyl or aryl Maleimide copolymer, vinyl chloride-styrene-acrylonitrile copolymer, vinyl chloride-butadiene copolymer, vinyl chloride-isoprene copolymer, vinyl chloride-chlorinated propylene copolymer, vinyl chloride-vinylidene chloride-vinyl acetate copolymer Original copolymer, vinyl chloride-acrylic acid ester copolymer, vinyl chloride-maleic acid ester copolymer, vinyl chloride-methacrylic acid ester copolymer, vinyl chloride-acrylonitrile copolymer, vinyl chloride-urethane copolymer chlorine-containing resins such as
and the above chlorine-containing resin and an α-olefin polymer such as polyethylene, polypropylene, polybutene, poly-3-methylbutene or an ethylene-vinyl acetate copolymer,
Polyolefins such as ethylene-propylene copolymers and their copolymers, polystyrene, acrylic resins, copolymers of styrene and other monomers (e.g. maleic anhydride, butadiene, acrylonitrile, etc.), acrylonitrile-butadiene-styrene Examples include copolymers, methacrylic acid ester-butadiene-styrene copolymers, and blends with polyurethane.
また、本発明の組成物にLi、 K、 Na、 Mg、
Sr、 Ca+Ba+ Zn、 cd、 Sn、 p
b等の金属の有機酸塩を併用することにより、安定化効
果が著しく向上する。In addition, the composition of the present invention contains Li, K, Na, Mg,
Sr, Ca+Ba+ Zn, cd, Sn, p
By using an organic acid salt of a metal such as b in combination, the stabilizing effect is significantly improved.
この有機酸塩は正塩、塩基性塩、過塩基性塩であっても
よい。This organic acid salt may be a normal salt, a basic salt, or an overbased salt.
上記有機酸塩を構成する有機酸残基としては、カルボン
酸、フェノール類、アシッドホスフェート類、アシッド
ホスファイト類等が有用である。As the organic acid residue constituting the above-mentioned organic acid salt, carboxylic acids, phenols, acid phosphates, acid phosphites, etc. are useful.
上記カルボン酸としては、例えば、酢酸、プロピオン酸
、酪酸、吉草酸、カプロン酸、エナント酸、カプリル酸
、ネオデカン酸、2−エチルヘキシル酸、ペラルゴン酸
、カプリン酸、ウンデカン酸、ラウリン酸、トリデカン
酸、ミリスチン酸、パルミチン酸、イソステアリン酸、
ステアリン酸、12−ヒドロキシステアリン酸、ベヘニ
ン酸、モンタン酸、エライジン酸、オレイン酸、リノー
ル酸、リルン酸、チオグリコール酸、メルカプトプロピ
オン酸、オクチルメルカプトプロピオン酸、安息香酸、
モノクロル安息香酸、p−第三ブチル安息香酸、ジメチ
ルヒドロキシ安息香酸、3.5−ジ第三ブチルー4−ヒ
ドロキシ安息香酸、トルイル酸、ジメチル安息香酸、エ
チル安息香酸、クミン酸、n−プロピル安息香酸、アセ
トキシ安息香酸、サリチル酸、p−第三オクチルサリチ
ル酸等のm個カルボン酸、シュウ酸、マロン酸、コハク
酸、グルタル酸、アジピン酸、ピメリン酸、スペリン酸
、アゼライン酸、セパチン酸、マレイン酸、フマール酸
、シトラコン酸、メタコン酸、イタコン酸、アコニット
酸、チオジプロピオン酸、フタル酸、イソフタル酸、テ
レフタル酸、オキシフタル酸、クロルフタル酸等の二価
のカルボン酸あるいはこれらのモノエステル又はモノア
マイド化合物、ブタントリカルボン酸、ブタンテトラカ
ルボン酸、ヘミメリット酸、トリメリット酸、メロフア
ン酸、ピロメリント酸等の三価又は四価カルボン酸のジ
又はトリエステル化合物があげられる。Examples of the carboxylic acids include acetic acid, propionic acid, butyric acid, valeric acid, caproic acid, enanthic acid, caprylic acid, neodecanoic acid, 2-ethylhexylic acid, pelargonic acid, capric acid, undecanoic acid, lauric acid, tridecanoic acid, myristic acid, palmitic acid, isostearic acid,
Stearic acid, 12-hydroxystearic acid, behenic acid, montanic acid, elaidic acid, oleic acid, linoleic acid, linoleic acid, thioglycolic acid, mercaptopropionic acid, octylmercaptopropionic acid, benzoic acid,
Monochlorobenzoic acid, p-tert-butylbenzoic acid, dimethylhydroxybenzoic acid, 3,5-di-tert-butyl-4-hydroxybenzoic acid, toluic acid, dimethylbenzoic acid, ethylbenzoic acid, cumic acid, n-propylbenzoic acid , m carboxylic acids such as acetoxybenzoic acid, salicylic acid, p-tertiary octylsalicylic acid, oxalic acid, malonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, speric acid, azelaic acid, sepacic acid, maleic acid, Divalent carboxylic acids such as fumaric acid, citraconic acid, methaconic acid, itaconic acid, aconitic acid, thiodipropionic acid, phthalic acid, isophthalic acid, terephthalic acid, oxyphthalic acid, chlorophthalic acid, or monoester or monoamide compounds thereof, Examples include di- or triester compounds of trivalent or tetravalent carboxylic acids such as butanetricarboxylic acid, butanetetracarboxylic acid, hemimellitic acid, trimellitic acid, merophanic acid, pyromellitic acid, and the like.
上記フェノール類の例としては、フェノール、クレゾー
ル、キシレノール、メチルプロピルフェノール、メチル
第三オクチルフェノール、エチルフェノール、イソプロ
ピルフェノール、第三ブチルフェノール、n−ブチルフ
ェノール、ジイソブチルフェノール、イソアミルフェノ
ール、シアミルフェノール、イソヘキシルフェノール、
オクチルフェノール、イソオクチルフェノール、2−エ
チルヘキシルフェノール、第三オクチルフェノール、ノ
ニルフェノール、ジノニルフェノール、第三ノニルフェ
ノール、デシルフェノール、ドデシルフェノール、オク
タデシルフェノール、シクロヘキシルフェノール、フェ
ニルフェノール等があげられる。Examples of the above phenols include phenol, cresol, xylenol, methylpropylphenol, methyl tert-octylphenol, ethylphenol, isopropylphenol, tert-butylphenol, n-butylphenol, diisobutylphenol, isoamylphenol, cyamylphenol, isohexylphenol. ,
Examples include octylphenol, isooctylphenol, 2-ethylhexylphenol, tertiary octylphenol, nonylphenol, dinonylphenol, tertiary nonylphenol, decylphenol, dodecylphenol, octadecylphenol, cyclohexylphenol, and phenylphenol.
上記アシッドホスフェートiの例としては、モノ/ジス
テアリルアシッドホスフェート、モノ/ジフェニルアシ
ノドホスフェート、モノ/ジノニルフェニルアシッドホ
スフェート等があげられる。Examples of the above acid phosphate i include mono/distearyl acid phosphate, mono/diphenylacinodophosphate, mono/dinonylphenyl acid phosphate, and the like.
また、上記アシッドホスファイト類の例としては、フェ
ニルアシッドホスファイト、ノニルフェニルアシンドホ
スファイト、オクチルアシッドホスファイト、ステアリ
ルアシッドホスファイト等があげられる。Examples of the acid phosphites include phenyl acid phosphite, nonylphenyl acid phosphite, octyl acid phosphite, stearyl acid phosphite, and the like.
これら有機酸の金属塩の添加量は、塩素含有樹脂100
重量部に対して、0.01〜10重量部、特に0.1〜
5重量部が好ましい。The amount of these metal salts of organic acids added is 100% of the chlorine-containing resin.
0.01 to 10 parts by weight, especially 0.1 to 10 parts by weight
5 parts by weight is preferred.
また、本発明の組成物にアルキル錫系安定剤を併用する
ことができる。Furthermore, an alkyltin stabilizer can be used in combination with the composition of the present invention.
上記アルキル錫系安定剤の例としては、モノ/ジメチル
錫、モノ/ジブチル錫、モノ/ジオクチル錫の単独及び
混合物のメルカプタイド、マレート、ラウレート等があ
げられる。Examples of the above-mentioned alkyltin stabilizers include mercaptides, malates, laurates of mono/dimethyltin, mono/dibutyltin, mono/dioctyltin, singly or as a mixture.
これらアルキル錫系安定剤の添加量は、塩素含有樹脂1
00重量部に対して、0.01〜10重量部、特に0.
1〜5重量部が好ましい。The amount of these alkyltin stabilizers added is 1
0.00 parts by weight, 0.01 to 10 parts by weight, especially 0.00 parts by weight.
1 to 5 parts by weight is preferred.
本発明の組成物に、更に有機ホスファイト化合物及び/
又はエポキシ化合物を併用することにより優れた相乗効
果を示す。The composition of the present invention further includes an organic phosphite compound and/or
Or, when used in combination with an epoxy compound, an excellent synergistic effect is exhibited.
上記有機ホスファイト化合物としては、例えば、トリフ
ェニルホスファイト、トリス(2,4−ジ第三ブチルフ
ェニル)ホスファイトへ トリス(ノニルフェニル)ホ
スファイト、トリス(ジノニルフェニル)ホスファイト
、トリス(モノ、ジ混合ノニルフェニル)ホスファイト
、ジフェニルアシッドホスファイト、2.2゛−メチレ
ンビス(4゜6−ジ第三ブチルフエニル)オクチルホス
ファイト、ジフェニルデシルホスファイト、フエニルジ
イソデシルホスファイト、トリブチルホスファイト、ト
リ(2−エチルヘキシル)ホスファイト、トリデシルホ
スファイト、トリラウリルホスファイト、ジブチルアシ
ッドホスファイト、ジラウリルアシッドホスファイト、
トリラウリルトリチオホスファイト、ビス(ネオペンチ
ルグリコール)・1.4−シクロヘキサンジメチルジホ
スファイト、ビス(2,4−ジ第三ブチルフェニル)ペ
ンタエリスリトールジホスファイト、ジステアリルペン
タエリスリトールジホスファイト、フェニル−4,4“
−イソプロピリデンジフェノール・ペンタエリスリトー
ルジホスファイト、テトラ(C22〜15混合アルキル
)−4,4’ −イソプロピリデンジフェニルジホスフ
ァイト、水素化−4,4゛−イソプロピリデンジフェノ
ールポリホスファイト、ビス(オクチルフェニル)・ビ
ス(4,4”−n−ブチリデンビス(2−第三ブチル−
5−メチルフェノール)〕 ・1,6−ヘキサンジオー
ル・ジホスファイト、テトラトリデシル・4,4゜−ブ
チリデンビス(2−第三ブチル−5−メチルフェノール
)ジホスファイト、ヘキサ(トリデシル)・1.1.3
−トリス(2−メチル−5−第三ブチル−4−ヒドロキ
シフェニル)ブタン・トリホスファイトなどがあげられ
る。Examples of the organic phosphite compounds include triphenyl phosphite, tris (2,4-di-tert-butylphenyl) phosphite, tris (nonylphenyl) phosphite, tris (dinonylphenyl) phosphite, tris (mono- , dimixed nonylphenyl) phosphite, diphenyl acid phosphite, 2.2゛-methylenebis(4゜6-ditert-butylphenyl)octyl phosphite, diphenyldecyl phosphite, phenyl diisodecyl phosphite, tributyl phosphite, tri- (2-ethylhexyl) phosphite, tridecyl phosphite, trilauryl phosphite, dibutyl acid phosphite, dilauryl acid phosphite,
Trilauryl trithiophosphite, bis(neopentyl glycol)/1,4-cyclohexane dimethyl diphosphite, bis(2,4-di-tert-butylphenyl) pentaerythritol diphosphite, distearyl pentaerythritol diphosphite, phenyl -4,4“
-isopropylidene diphenol/pentaerythritol diphosphite, tetra(C22-15 mixed alkyl)-4,4'-isopropylidene diphenyl diphosphite, hydrogenated-4,4'-isopropylidene diphenol polyphosphite, bis (octylphenyl) bis(4,4”-n-butylidenebis(2-tert-butyl-
5-methylphenol)] 1,6-hexanediol diphosphite, tetratridecyl 4,4゜-butylidenebis(2-tert-butyl-5-methylphenol) diphosphite, hexa(tridecyl) 1.1.3
-Tris(2-methyl-5-tert-butyl-4-hydroxyphenyl)butane and triphosphite.
これらの有機ホスファイト化合物の添加量は、塩素含有
樹脂100重量部に対して、0.01〜5重量部、特に
0.1〜3重量部とするのが好ましい。The amount of these organic phosphite compounds added is preferably 0.01 to 5 parts by weight, particularly 0.1 to 3 parts by weight, based on 100 parts by weight of the chlorine-containing resin.
また、上記エポキシ化合物としては、エポキシ化大豆油
、エポキシ化アマニ油、エポキシ化魚油、エポキシ化ト
ール油脂肪酸エステル、エポキシ化生脳油、エポキシ化
ヒマシ油、エポキシ化サフラワー油、エポキシ化アマニ
油脂肪酸ブチル、エポキシステアリン酸メチル、−ブチ
ル、−2−エチルヘキシルまたは−ステアリル、トリス
(エポキシプロピル)イソシアヌレート、3−(2−キ
セノキシ)−1,2−エポキシプロパン、エポキシ化ポ
リブタジェン、ビスフェノール−Aジグリシジルエーテ
ル、ビニルシクロヘキセンジエポキサイド、ジシクロペ
ンタジエンジエボキサイド、3゜4−エポキシシクロへ
キシル−6−メチルエポキシシクロヘキサンカルボキシ
レート等が挙げられる。In addition, the above-mentioned epoxy compounds include epoxidized soybean oil, epoxidized linseed oil, epoxidized fish oil, epoxidized tall oil fatty acid ester, epoxidized raw brain oil, epoxidized castor oil, epoxidized safflower oil, and epoxidized linseed oil. Butyl fatty acids, epoxy methyl stearate, -butyl, -2-ethylhexyl or -stearyl, tris(epoxypropyl) isocyanurate, 3-(2-xenoxy)-1,2-epoxypropane, epoxidized polybutadiene, bisphenol-A di Examples include glycidyl ether, vinylcyclohexene diepoxide, dicyclopentadiene dieboxide, 3°4-epoxycyclohexyl-6-methylepoxycyclohexanecarboxylate, and the like.
これらエポキシ化合物の添加量は、塩素含有樹脂100
重量部に対して、0.01〜20重量部、特に0.5〜
10重量部とするのが好ましい。The amount of these epoxy compounds added is 100% of the chlorine-containing resin.
0.01 to 20 parts by weight, especially 0.5 to 20 parts by weight
The amount is preferably 10 parts by weight.
本発明の組成物に、更に多価アルコール化合物を併用す
ることにより優れた相乗効果を示す。When the composition of the present invention is further combined with a polyhydric alcohol compound, an excellent synergistic effect is exhibited.
上記多価アルコール化合物としては、例えば、ペンタエ
リスリトール、ジペンタエリスリトール、ソルビトール
、マンニトール、ペンタエリスリトールまたはジペンタ
エリスリトールのステアリン酸ハーフエステル、ビス(
ジペンタエリスリトール)アジペート、グリセリン、ト
リス(2−ヒドロキシエチル)イソシアヌレート等が挙
げられる。Examples of the polyhydric alcohol compound include pentaerythritol, dipentaerythritol, sorbitol, mannitol, pentaerythritol or dipentaerythritol stearic acid half ester, bis(
Dipentaerythritol) adipate, glycerin, tris(2-hydroxyethyl)isocyanurate, and the like.
これら多価アルコール化合物の添加量は、塩素含有樹脂
100重量部に対して、0.1〜5重量部とするのが好
ましい。The amount of these polyhydric alcohol compounds added is preferably 0.1 to 5 parts by weight per 100 parts by weight of the chlorine-containing resin.
本発明の組成物に、更に非金属安定化助剤を併用するこ
とにより優れた相乗効果を示す。When the composition of the present invention is further combined with a nonmetallic stabilizing agent, an excellent synergistic effect is exhibited.
上記非金属安定化助剤としては、例えば、β−ジケトン
化合物として、デヒドロ酢酸、ジヘンゾイルメタン、ス
テアロイルヘンジイルメタン、含エステルβ−ジケトン
化合物等が挙げられる。Examples of the nonmetallic stabilizing aid include dehydroacetic acid, dihenzoylmethane, stearoylhendiylmethane, and ester-containing β-diketone compounds as β-diketone compounds.
これら非金属安定化助剤の添加量は、塩素含有樹脂10
0重量部に対して、0.001〜1重量部とするのが好
ましい。The amount of these nonmetallic stabilizing aids is 10% of the chlorine-containing resin.
It is preferable to set it as 0.001-1 weight part with respect to 0 weight part.
本発明の組成物には、フタル酸エステル系可塑剤、アジ
ピン酸エステル系可塑剤等のエステル系可塑剤又ポリエ
ステル系可塑剤、燐酸エステル系可塑剤、塩素系可塑剤
、その他の可塑剤等を用途に応じて適宜使用できる。The composition of the present invention may contain ester plasticizers such as phthalate plasticizers, adipate plasticizers, polyester plasticizers, phosphate plasticizers, chlorine plasticizers, and other plasticizers. It can be used as appropriate depending on the purpose.
その他、無機化合物として、合成タルサイト類、リン酸
カルシウム、リン酸マグネシウム等の併用も用途に応じ
て適宜使用可能である。In addition, as inorganic compounds, synthetic talcites, calcium phosphate, magnesium phosphate, etc. can be used in combination as appropriate depending on the purpose.
本発明の組成物に光安定剤を添加するならば、光安定性
を向上させ得るので、使用目的に応じて適宜これらを選
択し使用することが可能である。If a photostabilizer is added to the composition of the present invention, the photostability can be improved, so it is possible to appropriately select and use these depending on the purpose of use.
これらにはベンゾフェノン系、ベンゾトリアゾール系、
サリシレート系、置換アクリルニトリル系、ヒンダード
アミン系、各種の金属塩又は金属キレート、特にニッケ
ル又はクロムの塩又はキレート類等が包含される。These include benzophenone, benzotriazole,
Included are salicylates, substituted acrylonitriles, hindered amines, various metal salts or metal chelates, especially nickel or chromium salts or chelates.
更に、無毒又は低毒の塩素含有樹脂組成物を得るために
は、前記の通常用いられる有機酸金属塩のうち、無毒又
は低毒なものを選んで用いれば無毒又は低毒で且つ熱安
定性の良好な塩素含有樹脂組成物が得られる。Furthermore, in order to obtain a non-toxic or low-toxic chlorine-containing resin composition, it is possible to select and use a non-toxic or low-toxic one from among the above-mentioned commonly used organic acid metal salts. A chlorine-containing resin composition with good properties can be obtained.
その他必要に応じて、本発明の組成物には例えば架橋剤
、炭酸カルシウムまたは硫酸バリウム等の充填剤、顔料
、発泡剤、帯電防止剤、防曇剤、プレートアウト防止剤
、表面処理剤、滑剤、難燃剤、蛍光剤、防黴剤、殺菌剤
、光劣化剤、加工助剤、離型剤、抗酸化剤などを包含さ
せることができる。In addition, if necessary, the composition of the present invention may include, for example, a crosslinking agent, a filler such as calcium carbonate or barium sulfate, a pigment, a foaming agent, an antistatic agent, an antifogging agent, a plate-out inhibitor, a surface treatment agent, and a lubricant. , a flame retardant, a fluorescent agent, a fungicide, a bactericide, a photodegradant, a processing aid, a mold release agent, an antioxidant, and the like.
本発明の安定化された塩素含有樹脂組成物はあらゆる加
工方法及び用途に利用できる。The stabilized chlorine-containing resin composition of the present invention can be used in a variety of processing methods and applications.
この加工方法としては、カレンダー加工、押出加工、イ
ンジェクション加工、ブロー加工、パウダースラシュ加
工、ペースト加工、キャスティング加工、その他の加工
方法を挙げることができる。Examples of this processing method include calendar processing, extrusion processing, injection processing, blow processing, powder slush processing, paste processing, casting processing, and other processing methods.
用途としては、自動車内外装材、鋼板建材、マーキング
フィルム、硬質シート、板、パイプ、異型押出製品、ラ
ップフィルム、農業用フィルム、床材、レザー、壁紙、
ターポリン、その信金ての含塩素樹脂製品を挙げること
ができる。Applications include automobile interior and exterior materials, steel plate construction materials, marking films, hard sheets, plates, pipes, profile extrusion products, wrap films, agricultural films, flooring materials, leather, wallpaper,
Examples include tarpaulins and chlorine-containing resin products made by Shinkin Banks.
〔実施例]
次に、実施例によって本発明の組成物の安定化効果を具
体的に示す。しかしながら、本発明は次に挙げられた実
施例によって限定されるものではない。実施例1
次の配合物をロール混練し、次いでプレス加工を行い厚
さ1mのシートを作成した。このシートについて、12
0°Cで4日間熱老化後の着色性及び190°Cでの熱
安定性を測定した。[Example] Next, the stabilizing effect of the composition of the present invention will be specifically shown by Examples. However, the invention is not limited to the examples listed below. Example 1 The following formulation was roll-kneaded and then press-worked to produce a sheet with a thickness of 1 m. About this sheet, 12
The colorability after heat aging at 0°C for 4 days and the thermal stability at 190°C were measured.
その結果を下記第1表に示す。The results are shown in Table 1 below.
〈配合〉 重量部ポリ塩化
ビニル樹脂 100ジ(C9−、、)アル
キルフタレート 50エポキシ化大豆油
3Ba−オレート
0.8Zn−メタトルエート 0
.4テトラ(C+□−1,アルキル)・ 0.4
ビスフエノールAジホスフアイト
ジベンゾイルメタン 0.05過塩素
酸バリウム 0.2第 1
表
#:過塩素酸バリウムの配合量
d: DHT−4A (協和化学工業株式会社製)/過
塩素酸=110.5モル処理品
本2: DHT 4A (協和化学工業株式会社製)
/過塩素酸−1/1モル処理品
率3: DHT−4A (協和化学工業株式会社製)/
過塩素酸=1/1.5モル処理品
*4:アルカマイザ−4(協和化学工業株式会社製)/
過塩素酸=1/1モル処理品
本5:珪酸マグネシウム/過塩素酸−1/1モル処理品
*6:珪酸カルシ’y A /過塩素酸−1/1モル処
理品*7:ゼオライl−4A/過塩素酸=1/1モル処
理品
尚、熱老化後の着色性は10段階で評価し、1は変色が
ないことを示し、10は着色が極めて著しいことを示す
。<Formulation> Weight parts Polyvinyl chloride resin 100 Di(C9-,,)alkyl phthalate 50 Epoxidized soybean oil
3Ba-Olate
0.8Zn-Metatoluate 0
.. 4 tetra(C+□-1, alkyl)・0.4
Bisphenol A diphosphite dibenzoylmethane 0.05 Barium perchlorate 0.2 1st
Table #: Compounding amount of barium perchlorate d: DHT-4A (manufactured by Kyowa Chemical Industry Co., Ltd.) / Perchloric acid = 110.5 mol Processed product Book 2: DHT 4A (manufactured by Kyowa Chemical Industry Co., Ltd.)
/ Perchloric acid - 1/1 mole treatment rate 3: DHT-4A (manufactured by Kyowa Chemical Industry Co., Ltd.) /
Perchloric acid = 1/1.5 mole treated product *4: Alkamizer-4 (manufactured by Kyowa Chemical Industry Co., Ltd.) /
Perchloric acid = 1/1 mole treated product Book 5: Magnesium silicate / perchloric acid - 1/1 mole treated product *6: Calcium silicate / perchloric acid - 1/1 mole treated product *7: Zeolite I -4A/perchloric acid = 1/1 mole treated product The coloring property after heat aging was evaluated on a scale of 10, with 1 indicating no discoloration and 10 indicating extremely significant discoloration.
実施例2
次の配合物を用いて、実施例1と同様の試験を行なった
。Example 2 A test similar to Example 1 was conducted using the following formulations.
その結果を下記第2表に示す。The results are shown in Table 2 below.
〈配合〉 重量部ポリ塩化
ビニル樹脂 100ジ(Cq−++)アル
キルフタレート 50エポキシ化大豆油
3Ba−オレート
0.8Zn−メタトルエート0.4
テトラ(C+□−15アルキル)・ 0.4ビス
フエノールAジホスフアイト
ジベンゾイルメタン 0.05試料
20.1
過塩素酸塩(第2表) (第2表)第
2 表
#:試料2の配合量
実施例3
次の配合物をロール混練し、次いでプレス加工を行い厚
さ1鵬のシートを作成した。このシートについて、19
0°Cでの熱安定性を測定した。<Formulation> Weight parts Polyvinyl chloride resin 100 Di(Cq-++) alkyl phthalate 50 Epoxidized soybean oil
3Ba-Olate
0.8 Zn-metatoluate 0.4 Tetra(C+□-15 alkyl)・0.4 Bisphenol A diphosphite dibenzoylmethane 0.05 sample
20.1 Perchlorate (Table 2) (Table 2)
2 Table #: Blend amount of sample 2 Example 3 The following blend was roll-kneaded and then press-processed to produce a sheet with a thickness of 1 inch. About this sheet, 19
Thermal stability at 0°C was measured.
また、このシートを金型にセットし、ウレタンフオーム
用ポリオールとポリイソシアネートを攪拌して素早く金
型に流し込みウレタンフオーム層を形成させ、ウレタン
裏打ちシート(ウレタンフオーム層10mm)を作成し
た。Further, this sheet was set in a mold, and the urethane foam polyol and polyisocyanate were stirred and quickly poured into the mold to form a urethane foam layer, thereby creating a urethane backing sheet (urethane foam layer 10 mm thick).
このウレタン裏打ちシートを用い、110″C×400
時間熱老化させた後の着色(熱老化性)及びブラックパ
ネル温度83゛Cのフェードメーター中で600時間光
照射後の着色(耐光性)を観察し、1(着色なし)〜1
0(著しく着色)の10段階で表示した。Using this urethane backing sheet, 110"C x 400
The coloration (heat aging resistance) after time heat aging and the coloration (light resistance) after 600 hours of light irradiation in a fade meter with a black panel temperature of 83°C were observed, ranging from 1 (no coloration) to 1.
It was displayed on a scale of 10 to 0 (severely colored).
その結果を下記第3表に示す。The results are shown in Table 3 below.
〈配合〉 重量部ポリ塩化
ビニル樹脂 100ジ(Ca−+□デアル
ル)フタレート 70エポキシ化大豆油
3.0炭酸カルシウム 2
0酸化チタン 10オクチル酸
亜鉛 0.5ステアリン酸バリウ
ム 1.0過塩素酸バリウム
0,1試料化合物(第3表)0.1
第 3 表
#:過塩素酸バリウムの配合量
宰8:珪酸it lL’t’y A /過塩素酸=11
0.5モル処理品*9:珪酸バリウム/過塩素酸=11
0.5モル処理品*10;ゼオライト4A/過塩素酸−
110,5モル処理品
実施例4
次の配合物を用いて、実施例1と同様にして厚すlam
+のシートを作成し、このシートについて、120°C
及び190°Cでの熱安定性を測定した。<Composition> Weight parts Polyvinyl chloride resin 100 di(Ca-+□Dealle) phthalate 70 Epoxidized soybean oil
3.0 Calcium carbonate 2
0 Titanium oxide 10 Zinc octylate 0.5 Barium stearate 1.0 Barium perchlorate
0.1 Sample compound (Table 3) 0.1 Table 3 #: Blend amount of barium perchlorate 8: Silicic acid it lL't'y A / perchloric acid = 11
0.5 mol processed product *9: Barium silicate/perchloric acid = 11
0.5 mol treated product *10; Zeolite 4A/Perchloric acid-
110.5 mol processed product Example 4 A thick laminate was prepared as in Example 1 using the following formulation:
Create a + sheet and set the temperature to 120°C for this sheet.
and thermal stability at 190°C.
その結果を下記第4表に示す。The results are shown in Table 4 below.
く配合〉 重量部ポリ塩化
ビニル樹脂 50ABS樹脂
5ONBR10
エポキシ化大豆油 10ステアリン酸
バリウム 0.8ラウリン酸亜鉛
0.4過塩素酸バリウム
0.1試料化合物 (第4表)0.1
第 4 表
#:過塩素酸バリウムの配合量
*二試料1又は試料7の配合量
実施例5
次の配合物を均一に分散して得られたペーストゾルを、
ステンレス板上に0.5■の厚さに塗布し、200°C
で5分間キュアした。得られたシートを金型にセットし
、ウレタンフオーム用ポリオールとポリイソシアネート
を攪拌して素早(金型に流し込み、厚さ10rImのウ
レタンフオーム層を形成させ、ウレタン裏打ちシートを
作成した。Blend> Part by weight Polyvinyl chloride resin 50ABS resin
5ONBR10 Epoxidized soybean oil 10 Barium stearate 0.8 Zinc laurate
0.4 barium perchlorate
0.1 Sample compound (Table 4) 0.1 Table 4 #: Blend amount of barium perchlorate *2 Blend amount of sample 1 or sample 7 Example 5 Obtained by uniformly dispersing the following compound. paste sol,
Apply to a thickness of 0.5cm on a stainless steel plate and heat at 200°C.
Cure for 5 minutes. The obtained sheet was set in a mold, and the polyol for urethane foam and polyisocyanate were quickly stirred and poured into the mold to form a urethane foam layer with a thickness of 10 rIm, thereby producing a urethane backing sheet.
このシートを用い、110°Cでの熱老化試験を行い、
経時的に着色を観察した。Using this sheet, a heat aging test was conducted at 110°C.
Coloring was observed over time.
その結果を下記第5表に示す。The results are shown in Table 5 below.
く配合〉 重量部炭酸カル
シウム 10エポキシ化亜麻仁油
4フエニル・ジトリデシルホスファイ
ト 1.0オレイン酸バリウム 0
.6第三ブチル安息香酸亜鉛 0.3過塩
素酸バリウム 0.1試料化合物(
第5表)0.1
第 5 表
#:過塩素酸バリウムの配合量
実施例6
次の配合物をヘンシェルミキサーで混合し、パウダーコ
ンパウンドを作成した。このパウダーコンパウンドを厚
さ3圓とし、230“Cのギヤーオーブン中で4分間ゲ
ル化させ、厚さ1.8胴のシートを作成した。このシー
トについて、実施例3と同様にして熱安定性、熱老化性
及び耐光性の試験を行った。Formulated: Part by weight Calcium carbonate 10 Epoxidized linseed oil
4 Phenyl ditridecyl phosphite 1.0 Barium oleate 0
.. 6 Zinc tert-butylbenzoate 0.3 Barium perchlorate 0.1 Sample compound (
Table 5) 0.1 Table 5 #: Blend amount of barium perchlorate Example 6 The following formulations were mixed in a Henschel mixer to create a powder compound. This powder compound was made into a thickness of 3 circles and gelled in a gear oven at 230"C for 4 minutes to produce a sheet with a thickness of 1.8 mm. This sheet was tested for thermal stability in the same manner as in Example 3. , heat aging resistance and light resistance tests were conducted.
その結果を下記第6表に示す。The results are shown in Table 6 below.
〈配合〉 重量部ポリ塩
化ビニル樹脂 90ペースト用ポリ塩
化ビニル樹脂 10トリ (C7−9アルキル)
トリメリテート 70エポキシ化大豆油
5二酸化チタン 10
オクチル酸亜鉛 0.3ステア
リン酸バリウム 1.0試料 20
.5
試料 70.1
過塩素酸塩(第6表) (第6表)第
6 表
〔発明の効果〕
過塩素酸の金属塩を単独に添加した場合には、比較的低
温時の熱安定性(熱老化性)及び耐光性の改善効果はあ
る程度認められるものの未だ不十分であり、また、高温
時の熱安定性の改善効果は小さいものでしかない。<Composition> Part by weight Polyvinyl chloride resin 90 Polyvinyl chloride resin for paste 10 Tri (C7-9 alkyl)
trimellitate 70 epoxidized soybean oil
5 Titanium dioxide 10
Zinc octylate 0.3 Barium stearate 1.0 Sample 20
.. 5 Sample 70.1 Perchlorate (Table 6) (Table 6) No.
Table 6 [Effects of the invention] When a metal salt of perchloric acid is added alone, the effect of improving thermal stability (heat aging resistance) and light resistance at relatively low temperatures is observed to some extent, but it is still insufficient. However, the effect of improving thermal stability at high temperatures is only small.
これに対し、過塩素酸の金属塩及び過塩素酸処理ハイド
ロタルサイトまたは過塩素酸処理珪酸塩の少なくとも1
種を併用した本発明の組成物は、高温時の熱安定性、比
較的低温時の熱安定性(熱老化性)及び耐光性が、これ
らを単独で添加した場合の結果から予想されるよりも著
しく優れており、本発明の効果が極めて特異的なもので
あることが明らかである。In contrast, at least one of a metal salt of perchloric acid and a perchloric acid-treated hydrotalcite or a perchloric acid-treated silicate
The composition of the present invention in which seeds are used in combination has better thermal stability at high temperatures, thermal stability at relatively low temperatures (heat aging resistance), and light resistance than would be expected from the results when these are added alone. It is clear that the effects of the present invention are extremely specific.
特許出願人 旭電化工業株式会社Patent applicant: Asahi Denka Kogyo Co., Ltd.
Claims (1)
処理珪酸塩の少なくとも1種を添加してなる安定化され
た塩素含有樹脂組成物。[Scope of Claims] Adding (a) at least one metal salt of perchloric acid and (b) at least one of perchloric acid-treated hydrotalcite or perchloric acid-treated silicate to a chlorine-containing resin. A stabilized chlorine-containing resin composition.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP30142290A JPH04173854A (en) | 1990-11-07 | 1990-11-07 | Stabilized chlorine-containing resin composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP30142290A JPH04173854A (en) | 1990-11-07 | 1990-11-07 | Stabilized chlorine-containing resin composition |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH04173854A true JPH04173854A (en) | 1992-06-22 |
Family
ID=17896687
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP30142290A Pending JPH04173854A (en) | 1990-11-07 | 1990-11-07 | Stabilized chlorine-containing resin composition |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH04173854A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002138180A (en) * | 2000-11-01 | 2002-05-14 | Asahi Denka Kogyo Kk | Vinyl chloride resin plasisol composition |
JP2015124317A (en) * | 2013-12-26 | 2015-07-06 | 東ソー株式会社 | Vinyl chloride resin for paste processing and vinyl chloride resin composition for paste processing using the same |
JP2015223934A (en) * | 2014-05-28 | 2015-12-14 | 勝田化工株式会社 | Seat for vehicle |
JP2017155197A (en) * | 2016-03-04 | 2017-09-07 | ダイヤプラスフィルム株式会社 | Polyvinyl chloride resin composition and reflection film |
-
1990
- 1990-11-07 JP JP30142290A patent/JPH04173854A/en active Pending
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002138180A (en) * | 2000-11-01 | 2002-05-14 | Asahi Denka Kogyo Kk | Vinyl chloride resin plasisol composition |
JP2015124317A (en) * | 2013-12-26 | 2015-07-06 | 東ソー株式会社 | Vinyl chloride resin for paste processing and vinyl chloride resin composition for paste processing using the same |
JP2015223934A (en) * | 2014-05-28 | 2015-12-14 | 勝田化工株式会社 | Seat for vehicle |
JP2017155197A (en) * | 2016-03-04 | 2017-09-07 | ダイヤプラスフィルム株式会社 | Polyvinyl chloride resin composition and reflection film |
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