JPS6330938B2 - - Google Patents
Info
- Publication number
- JPS6330938B2 JPS6330938B2 JP1056682A JP1056682A JPS6330938B2 JP S6330938 B2 JPS6330938 B2 JP S6330938B2 JP 1056682 A JP1056682 A JP 1056682A JP 1056682 A JP1056682 A JP 1056682A JP S6330938 B2 JPS6330938 B2 JP S6330938B2
- Authority
- JP
- Japan
- Prior art keywords
- acid
- bis
- phosphite
- dipentaerythritol
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002253 acid Substances 0.000 claims description 23
- 229910052751 metal Inorganic materials 0.000 claims description 17
- 239000002184 metal Substances 0.000 claims description 17
- 150000003839 salts Chemical class 0.000 claims description 17
- 229920005989 resin Polymers 0.000 claims description 15
- 239000011347 resin Substances 0.000 claims description 15
- 150000005846 sugar alcohols Polymers 0.000 claims description 15
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 14
- 239000000460 chlorine Substances 0.000 claims description 14
- 229910052801 chlorine Inorganic materials 0.000 claims description 14
- 150000002148 esters Chemical class 0.000 claims description 8
- 150000007524 organic acids Chemical class 0.000 claims description 8
- 150000001735 carboxylic acids Chemical class 0.000 claims description 7
- 229910052736 halogen Inorganic materials 0.000 claims description 6
- 150000002367 halogens Chemical class 0.000 claims description 5
- 239000011342 resin composition Substances 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- -1 triester compounds Chemical class 0.000 description 26
- 239000000203 mixture Substances 0.000 description 20
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 17
- 229920001577 copolymer Polymers 0.000 description 14
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 12
- 239000011575 calcium Substances 0.000 description 10
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical class OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 10
- 239000011701 zinc Substances 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 9
- 229910052700 potassium Inorganic materials 0.000 description 9
- 229910052708 sodium Inorganic materials 0.000 description 9
- 229910052791 calcium Inorganic materials 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 8
- 239000007983 Tris buffer Substances 0.000 description 7
- 229910052788 barium Inorganic materials 0.000 description 7
- 229910052744 lithium Inorganic materials 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 6
- 229920000915 polyvinyl chloride Polymers 0.000 description 6
- 239000004800 polyvinyl chloride Substances 0.000 description 6
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 6
- 229910052712 strontium Inorganic materials 0.000 description 6
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 6
- 239000004593 Epoxy Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000005886 esterification reaction Methods 0.000 description 5
- MNWFXJYAOYHMED-UHFFFAOYSA-N heptanoic acid Chemical compound CCCCCCC(O)=O MNWFXJYAOYHMED-UHFFFAOYSA-N 0.000 description 5
- 229910052749 magnesium Inorganic materials 0.000 description 5
- 239000011777 magnesium Substances 0.000 description 5
- 239000004014 plasticizer Substances 0.000 description 5
- 239000003549 soybean oil Substances 0.000 description 5
- 235000012424 soybean oil Nutrition 0.000 description 5
- 229910052725 zinc Inorganic materials 0.000 description 5
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 4
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- OOULUYZFLXDWDQ-UHFFFAOYSA-L barium perchlorate Chemical compound [Ba+2].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O OOULUYZFLXDWDQ-UHFFFAOYSA-L 0.000 description 4
- UJMDYLWCYJJYMO-UHFFFAOYSA-N benzene-1,2,3-tricarboxylic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1C(O)=O UJMDYLWCYJJYMO-UHFFFAOYSA-N 0.000 description 4
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 4
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 4
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- ZQPPMHVWECSIRJ-MDZDMXLPSA-N elaidic acid Chemical compound CCCCCCCC\C=C\CCCCCCCC(O)=O ZQPPMHVWECSIRJ-MDZDMXLPSA-N 0.000 description 4
- 230000032050 esterification Effects 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 4
- MEYFIGJKMVBYOG-UHFFFAOYSA-N hexanedioic acid;2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OC(=O)CCCCC(O)=O.OCC(CO)(CO)COCC(CO)(CO)CO.OCC(CO)(CO)COCC(CO)(CO)CO MEYFIGJKMVBYOG-UHFFFAOYSA-N 0.000 description 4
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 4
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 4
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 4
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 4
- 231100000252 nontoxic Toxicity 0.000 description 4
- 230000003000 nontoxic effect Effects 0.000 description 4
- UTOPWMOLSKOLTQ-UHFFFAOYSA-N octacosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O UTOPWMOLSKOLTQ-UHFFFAOYSA-N 0.000 description 4
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 4
- CKMXAIVXVKGGFM-UHFFFAOYSA-N p-cumic acid Chemical compound CC(C)C1=CC=C(C(O)=O)C=C1 CKMXAIVXVKGGFM-UHFFFAOYSA-N 0.000 description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 4
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 4
- CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 description 4
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 4
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 4
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 4
- SZHOJFHSIKHZHA-UHFFFAOYSA-N tridecanoic acid Chemical compound CCCCCCCCCCCCC(O)=O SZHOJFHSIKHZHA-UHFFFAOYSA-N 0.000 description 4
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 4
- ZDPHROOEEOARMN-UHFFFAOYSA-N undecanoic acid Chemical compound CCCCCCCCCCC(O)=O ZDPHROOEEOARMN-UHFFFAOYSA-N 0.000 description 4
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 4
- WMYINDVYGQKYMI-UHFFFAOYSA-N 2-[2,2-bis(hydroxymethyl)butoxymethyl]-2-ethylpropane-1,3-diol Chemical compound CCC(CO)(CO)COCC(CC)(CO)CO WMYINDVYGQKYMI-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 3
- AGXUVMPSUKZYDT-UHFFFAOYSA-L barium(2+);octadecanoate Chemical compound [Ba+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AGXUVMPSUKZYDT-UHFFFAOYSA-L 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- ZJIPHXXDPROMEF-UHFFFAOYSA-N dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O ZJIPHXXDPROMEF-UHFFFAOYSA-N 0.000 description 3
- 239000000944 linseed oil Substances 0.000 description 3
- 235000021388 linseed oil Nutrition 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 3
- 150000002989 phenols Chemical class 0.000 description 3
- 229960004889 salicylic acid Drugs 0.000 description 3
- 230000000087 stabilizing effect Effects 0.000 description 3
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 3
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- 239000001124 (E)-prop-1-ene-1,2,3-tricarboxylic acid Substances 0.000 description 2
- BPXVHIRIPLPOPT-UHFFFAOYSA-N 1,3,5-tris(2-hydroxyethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound OCCN1C(=O)N(CCO)C(=O)N(CCO)C1=O BPXVHIRIPLPOPT-UHFFFAOYSA-N 0.000 description 2
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 2
- RIZUCYSQUWMQLX-UHFFFAOYSA-N 2,3-dimethylbenzoic acid Chemical compound CC1=CC=CC(C(O)=O)=C1C RIZUCYSQUWMQLX-UHFFFAOYSA-N 0.000 description 2
- XSXWOBXNYNULJG-UHFFFAOYSA-N 2-(2,4,4-trimethylpentan-2-yl)phenol Chemical compound CC(C)(C)CC(C)(C)C1=CC=CC=C1O XSXWOBXNYNULJG-UHFFFAOYSA-N 0.000 description 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 2
- DVVXXHVHGGWWPE-UHFFFAOYSA-N 2-(dimethylamino)benzoic acid Chemical compound CN(C)C1=CC=CC=C1C(O)=O DVVXXHVHGGWWPE-UHFFFAOYSA-N 0.000 description 2
- CGMMPMYKMDITEA-UHFFFAOYSA-N 2-ethylbenzoic acid Chemical compound CCC1=CC=CC=C1C(O)=O CGMMPMYKMDITEA-UHFFFAOYSA-N 0.000 description 2
- YSJWNEDBIWZWOI-UHFFFAOYSA-N 2-hydroxy-3,4-dimethylbenzoic acid Chemical compound CC1=CC=C(C(O)=O)C(O)=C1C YSJWNEDBIWZWOI-UHFFFAOYSA-N 0.000 description 2
- KIHBGTRZFAVZRV-UHFFFAOYSA-N 2-hydroxyoctadecanoic acid Chemical compound CCCCCCCCCCCCCCCCC(O)C(O)=O KIHBGTRZFAVZRV-UHFFFAOYSA-N 0.000 description 2
- GADSJKKDLMALGL-UHFFFAOYSA-N 2-propylbenzoic acid Chemical compound CCCC1=CC=CC=C1C(O)=O GADSJKKDLMALGL-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- ODJQKYXPKWQWNK-UHFFFAOYSA-N 3,3'-Thiobispropanoic acid Chemical compound OC(=O)CCSCCC(O)=O ODJQKYXPKWQWNK-UHFFFAOYSA-N 0.000 description 2
- YEXOWHQZWLCHHD-UHFFFAOYSA-N 3,5-ditert-butyl-4-hydroxybenzoic acid Chemical compound CC(C)(C)C1=CC(C(O)=O)=CC(C(C)(C)C)=C1O YEXOWHQZWLCHHD-UHFFFAOYSA-N 0.000 description 2
- WGLQHUKCXBXUDV-UHFFFAOYSA-N 3-aminophthalic acid Chemical compound NC1=CC=CC(C(O)=O)=C1C(O)=O WGLQHUKCXBXUDV-UHFFFAOYSA-N 0.000 description 2
- BKFXSOCDAQACQM-UHFFFAOYSA-N 3-chlorophthalic acid Chemical compound OC(=O)C1=CC=CC(Cl)=C1C(O)=O BKFXSOCDAQACQM-UHFFFAOYSA-N 0.000 description 2
- DKIDEFUBRARXTE-UHFFFAOYSA-N 3-mercaptopropanoic acid Chemical compound OC(=O)CCS DKIDEFUBRARXTE-UHFFFAOYSA-N 0.000 description 2
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 description 2
- XRHGYUZYPHTUJZ-UHFFFAOYSA-N 4-chlorobenzoic acid Chemical compound OC(=O)C1=CC=C(Cl)C=C1 XRHGYUZYPHTUJZ-UHFFFAOYSA-N 0.000 description 2
- KDVYCTOWXSLNNI-UHFFFAOYSA-N 4-t-Butylbenzoic acid Chemical compound CC(C)(C)C1=CC=C(C(O)=O)C=C1 KDVYCTOWXSLNNI-UHFFFAOYSA-N 0.000 description 2
- VBHRLSQLJDHSCO-UHFFFAOYSA-N 5,5-dimethylhexanoic acid Chemical compound CC(C)(C)CCCC(O)=O VBHRLSQLJDHSCO-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- BSYNRYMUTXBXSQ-UHFFFAOYSA-N Aspirin Chemical compound CC(=O)OC1=CC=CC=C1C(O)=O BSYNRYMUTXBXSQ-UHFFFAOYSA-N 0.000 description 2
- 235000021357 Behenic acid Nutrition 0.000 description 2
- 239000005711 Benzoic acid Substances 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 2
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 2
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 2
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000005639 Lauric acid Substances 0.000 description 2
- HPEUJPJOZXNMSJ-UHFFFAOYSA-N Methyl stearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC HPEUJPJOZXNMSJ-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- 235000021314 Palmitic acid Nutrition 0.000 description 2
- 239000005643 Pelargonic acid Substances 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- 239000003490 Thiodipropionic acid Substances 0.000 description 2
- 229940091181 aconitic acid Drugs 0.000 description 2
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 2
- 239000001361 adipic acid Substances 0.000 description 2
- 235000011037 adipic acid Nutrition 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 2
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 2
- 229960004050 aminobenzoic acid Drugs 0.000 description 2
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 229940116226 behenic acid Drugs 0.000 description 2
- QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 description 2
- 235000010233 benzoic acid Nutrition 0.000 description 2
- 239000004305 biphenyl Substances 0.000 description 2
- 235000010290 biphenyl Nutrition 0.000 description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- DKSMCEUSSQTGBK-UHFFFAOYSA-M bromite Chemical compound [O-]Br=O DKSMCEUSSQTGBK-UHFFFAOYSA-M 0.000 description 2
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 2
- 150000001661 cadmium Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- GTZCVFVGUGFEME-IWQZZHSRSA-N cis-aconitic acid Chemical compound OC(=O)C\C(C(O)=O)=C\C(O)=O GTZCVFVGUGFEME-IWQZZHSRSA-N 0.000 description 2
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 2
- 229940018557 citraconic acid Drugs 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 239000001530 fumaric acid Substances 0.000 description 2
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 2
- 229960004488 linolenic acid Drugs 0.000 description 2
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- YDSWCNNOKPMOTP-UHFFFAOYSA-N mellitic acid Chemical compound OC(=O)C1=C(C(O)=O)C(C(O)=O)=C(C(O)=O)C(C(O)=O)=C1C(O)=O YDSWCNNOKPMOTP-UHFFFAOYSA-N 0.000 description 2
- HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 2
- HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 description 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 2
- IXQGCWUGDFDQMF-UHFFFAOYSA-N o-Hydroxyethylbenzene Natural products CCC1=CC=CC=C1O IXQGCWUGDFDQMF-UHFFFAOYSA-N 0.000 description 2
- ZWLPBLYKEWSWPD-UHFFFAOYSA-N o-toluic acid Chemical compound CC1=CC=CC=C1C(O)=O ZWLPBLYKEWSWPD-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 229960002446 octanoic acid Drugs 0.000 description 2
- GJYCVCVHRSWLNY-UHFFFAOYSA-N ortho-butylphenol Natural products CCCCC1=CC=CC=C1O GJYCVCVHRSWLNY-UHFFFAOYSA-N 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 235000019260 propionic acid Nutrition 0.000 description 2
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 2
- 229940116351 sebacate Drugs 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-L sebacate(2-) Chemical compound [O-]C(=O)CCCCCCCCC([O-])=O CXMXRPHRNRROMY-UHFFFAOYSA-L 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 2
- 235000019303 thiodipropionic acid Nutrition 0.000 description 2
- GTZCVFVGUGFEME-UHFFFAOYSA-N trans-aconitic acid Natural products OC(=O)CC(C(O)=O)=CC(O)=O GTZCVFVGUGFEME-UHFFFAOYSA-N 0.000 description 2
- KQTIIICEAUMSDG-UHFFFAOYSA-N tricarballylic acid Chemical compound OC(=O)CC(C(O)=O)CC(O)=O KQTIIICEAUMSDG-UHFFFAOYSA-N 0.000 description 2
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 2
- 229940005605 valeric acid Drugs 0.000 description 2
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 2
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- 229920003067 (meth)acrylic acid ester copolymer Polymers 0.000 description 1
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- ZWVMLYRJXORSEP-UHFFFAOYSA-N 1,2,6-Hexanetriol Chemical compound OCCCCC(O)CO ZWVMLYRJXORSEP-UHFFFAOYSA-N 0.000 description 1
- OUPZKGBUJRBPGC-UHFFFAOYSA-N 1,3,5-tris(oxiran-2-ylmethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound O=C1N(CC2OC2)C(=O)N(CC2OC2)C(=O)N1CC1CO1 OUPZKGBUJRBPGC-UHFFFAOYSA-N 0.000 description 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- RZRNAYUHWVFMIP-KTKRTIGZSA-N 1-oleoylglycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-KTKRTIGZSA-N 0.000 description 1
- ICVIFRMLTBUBGF-UHFFFAOYSA-N 2,2,6,6-tetrakis(hydroxymethyl)cyclohexan-1-ol Chemical compound OCC1(CO)CCCC(CO)(CO)C1O ICVIFRMLTBUBGF-UHFFFAOYSA-N 0.000 description 1
- WZUNUACWCJJERC-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)butyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CC)(CO)CO WZUNUACWCJJERC-UHFFFAOYSA-N 0.000 description 1
- NAEDWKNFXVUORY-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;hexanedioic acid Chemical compound OCC(CO)(CO)CO.OC(=O)CCCCC(O)=O NAEDWKNFXVUORY-UHFFFAOYSA-N 0.000 description 1
- WSNUXYSIWZSVLT-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;hexanedioic acid Chemical compound OCC(CO)(CO)CO.OCC(CO)(CO)CO.OC(=O)CCCCC(O)=O WSNUXYSIWZSVLT-UHFFFAOYSA-N 0.000 description 1
- GVXADFDPIZACOX-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;terephthalic acid Chemical compound OCC(CO)(CO)CO.OC(=O)C1=CC=C(C(O)=O)C=C1 GVXADFDPIZACOX-UHFFFAOYSA-N 0.000 description 1
- STMRWVUTGPZZER-UHFFFAOYSA-N 2,3-bis(2-methylpropyl)phenol Chemical compound CC(C)CC1=CC=CC(O)=C1CC(C)C STMRWVUTGPZZER-UHFFFAOYSA-N 0.000 description 1
- JKTAIYGNOFSMCE-UHFFFAOYSA-N 2,3-di(nonyl)phenol Chemical compound CCCCCCCCCC1=CC=CC(O)=C1CCCCCCCCC JKTAIYGNOFSMCE-UHFFFAOYSA-N 0.000 description 1
- SXSWMAUXEHKFGX-UHFFFAOYSA-N 2,3-dimethylbutan-1-ol Chemical compound CC(C)C(C)CO SXSWMAUXEHKFGX-UHFFFAOYSA-N 0.000 description 1
- PTMRDOLOEDPHLB-UHFFFAOYSA-N 2,3-dipentylphenol Chemical compound CCCCCC1=CC=CC(O)=C1CCCCC PTMRDOLOEDPHLB-UHFFFAOYSA-N 0.000 description 1
- RRKBRXPIJHVKIC-UHFFFAOYSA-N 2-(2-ethylhexyl)phenol Chemical compound CCCCC(CC)CC1=CC=CC=C1O RRKBRXPIJHVKIC-UHFFFAOYSA-N 0.000 description 1
- QJQIVZBVEBCTKR-UHFFFAOYSA-N 2-(3-methylbutyl)phenol Chemical compound CC(C)CCC1=CC=CC=C1O QJQIVZBVEBCTKR-UHFFFAOYSA-N 0.000 description 1
- LLIGXYDULHXBDJ-UHFFFAOYSA-N 2-(4-methylpentyl)phenol Chemical compound CC(C)CCCC1=CC=CC=C1O LLIGXYDULHXBDJ-UHFFFAOYSA-N 0.000 description 1
- NFAOATPOYUWEHM-UHFFFAOYSA-N 2-(6-methylheptyl)phenol Chemical compound CC(C)CCCCCC1=CC=CC=C1O NFAOATPOYUWEHM-UHFFFAOYSA-N 0.000 description 1
- QEAHTUJZOZSKCY-UHFFFAOYSA-N 2-(hydroxymethyl)-2-methylbutane-1,3-diol Chemical compound CC(O)C(C)(CO)CO QEAHTUJZOZSKCY-UHFFFAOYSA-N 0.000 description 1
- PTJWCLYPVFJWMP-UHFFFAOYSA-N 2-[[3-hydroxy-2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)COCC(CO)(CO)CO PTJWCLYPVFJWMP-UHFFFAOYSA-N 0.000 description 1
- VXRUADVCBZMFSV-UHFFFAOYSA-N 2-acetyloxypropane-1,2,3-tricarboxylic acid Chemical compound CC(=O)OC(CC(O)=O)(CC(O)=O)C(O)=O VXRUADVCBZMFSV-UHFFFAOYSA-N 0.000 description 1
- GPNNOCMCNFXRAO-UHFFFAOYSA-N 2-aminoterephthalic acid Chemical compound NC1=CC(C(O)=O)=CC=C1C(O)=O GPNNOCMCNFXRAO-UHFFFAOYSA-N 0.000 description 1
- ZPXGNBIFHQKREO-UHFFFAOYSA-N 2-chloroterephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(Cl)=C1 ZPXGNBIFHQKREO-UHFFFAOYSA-N 0.000 description 1
- MVRPPTGLVPEMPI-UHFFFAOYSA-N 2-cyclohexylphenol Chemical compound OC1=CC=CC=C1C1CCCCC1 MVRPPTGLVPEMPI-UHFFFAOYSA-N 0.000 description 1
- FDIPWBUDOCPIMH-UHFFFAOYSA-N 2-decylphenol Chemical compound CCCCCCCCCCC1=CC=CC=C1O FDIPWBUDOCPIMH-UHFFFAOYSA-N 0.000 description 1
- QUWKZLFACARLDF-UHFFFAOYSA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol hexanedioic acid Chemical compound C(CCCCC(=O)O)(=O)O.C(O)C(CC)(CO)CO.C(O)C(CC)(CO)CO QUWKZLFACARLDF-UHFFFAOYSA-N 0.000 description 1
- TZLVUWBGUNVFES-UHFFFAOYSA-N 2-ethyl-5-methylpyrazol-3-amine Chemical compound CCN1N=C(C)C=C1N TZLVUWBGUNVFES-UHFFFAOYSA-N 0.000 description 1
- XKZGIJICHCVXFV-UHFFFAOYSA-N 2-ethylhexyl diphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OCC(CC)CCCC)OC1=CC=CC=C1 XKZGIJICHCVXFV-UHFFFAOYSA-N 0.000 description 1
- CRBJBYGJVIBWIY-UHFFFAOYSA-N 2-isopropylphenol Chemical compound CC(C)C1=CC=CC=C1O CRBJBYGJVIBWIY-UHFFFAOYSA-N 0.000 description 1
- AIDLAEPHWROGFI-UHFFFAOYSA-N 2-methylbenzene-1,3-dicarboxylic acid Chemical compound CC1=C(C(O)=O)C=CC=C1C(O)=O AIDLAEPHWROGFI-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- WCRKLZYTQVZTMM-UHFFFAOYSA-N 2-octadecylphenol Chemical compound CCCCCCCCCCCCCCCCCCC1=CC=CC=C1O WCRKLZYTQVZTMM-UHFFFAOYSA-N 0.000 description 1
- WJQOZHYUIDYNHM-UHFFFAOYSA-N 2-tert-Butylphenol Chemical compound CC(C)(C)C1=CC=CC=C1O WJQOZHYUIDYNHM-UHFFFAOYSA-N 0.000 description 1
- SKWTVENEYZYQLV-UHFFFAOYSA-N 3,4-diaminophthalic acid Chemical compound NC1=CC=C(C(O)=O)C(C(O)=O)=C1N SKWTVENEYZYQLV-UHFFFAOYSA-N 0.000 description 1
- YLUZWKKWWSCRSR-UHFFFAOYSA-N 3,9-bis(8-methylnonoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound C1OP(OCCCCCCCC(C)C)OCC21COP(OCCCCCCCC(C)C)OC2 YLUZWKKWWSCRSR-UHFFFAOYSA-N 0.000 description 1
- PZRWFKGUFWPFID-UHFFFAOYSA-N 3,9-dioctadecoxy-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound C1OP(OCCCCCCCCCCCCCCCCCC)OCC21COP(OCCCCCCCCCCCCCCCCCC)OC2 PZRWFKGUFWPFID-UHFFFAOYSA-N 0.000 description 1
- ODJQKYXPKWQWNK-UHFFFAOYSA-L 3-(2-carboxylatoethylsulfanyl)propanoate Chemical compound [O-]C(=O)CCSCCC([O-])=O ODJQKYXPKWQWNK-UHFFFAOYSA-L 0.000 description 1
- KHBQLLFLZPJPSA-UHFFFAOYSA-N 3-(hydroxymethyl)-2,4-dimethylpentane-2,4-diol Chemical compound CC(C)(O)C(CO)C(C)(C)O KHBQLLFLZPJPSA-UHFFFAOYSA-N 0.000 description 1
- IWTIBPIVCKUAHK-UHFFFAOYSA-N 3-[bis(2-carboxyethyl)amino]propanoic acid Chemical compound OC(=O)CCN(CCC(O)=O)CCC(O)=O IWTIBPIVCKUAHK-UHFFFAOYSA-N 0.000 description 1
- REHCNBGWPLVSIJ-UHFFFAOYSA-N 3-methyl-2-(4-methylpentyl)phenol Chemical compound CC(C)CCCC1=C(C)C=CC=C1O REHCNBGWPLVSIJ-UHFFFAOYSA-N 0.000 description 1
- FCUBUGPGVCEURB-UHFFFAOYSA-N 3-methyl-2-propylphenol Chemical compound CCCC1=C(C)C=CC=C1O FCUBUGPGVCEURB-UHFFFAOYSA-N 0.000 description 1
- AHHQDHCTHYTBSV-UHFFFAOYSA-N 3-methylpentane-1,3,5-triol Chemical compound OCCC(O)(C)CCO AHHQDHCTHYTBSV-UHFFFAOYSA-N 0.000 description 1
- IBFJDBNISOJRCW-UHFFFAOYSA-N 3-methylphthalic acid Chemical compound CC1=CC=CC(C(O)=O)=C1C(O)=O IBFJDBNISOJRCW-UHFFFAOYSA-N 0.000 description 1
- OECTYKWYRCHAKR-UHFFFAOYSA-N 4-vinylcyclohexene dioxide Chemical compound C1OC1C1CC2OC2CC1 OECTYKWYRCHAKR-UHFFFAOYSA-N 0.000 description 1
- YPIFGDQKSSMYHQ-UHFFFAOYSA-N 7,7-dimethyloctanoic acid Chemical compound CC(C)(C)CCCCCC(O)=O YPIFGDQKSSMYHQ-UHFFFAOYSA-N 0.000 description 1
- XXGAZFAEPGHUAP-UHFFFAOYSA-N 7-oxabicyclo[4.1.0]heptan-4-yl 5-methyl-7-oxabicyclo[4.1.0]heptane-6-carboxylate Chemical compound C1CC2OC2CC1OC(=O)C12OC2CCCC1C XXGAZFAEPGHUAP-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- LCFVJGUPQDGYKZ-UHFFFAOYSA-N Bisphenol A diglycidyl ether Chemical compound C=1C=C(OCC2OC2)C=CC=1C(C)(C)C(C=C1)=CC=C1OCC1CO1 LCFVJGUPQDGYKZ-UHFFFAOYSA-N 0.000 description 1
- 239000004709 Chlorinated polyethylene Substances 0.000 description 1
- IVRFYNSETZKRSJ-UHFFFAOYSA-N ClC=C.N#CC=CC=CC1=CC=CC=C1 Chemical compound ClC=C.N#CC=CC=CC1=CC=CC=C1 IVRFYNSETZKRSJ-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- SQUHHTBVTRBESD-UHFFFAOYSA-N Hexa-Ac-myo-Inositol Natural products CC(=O)OC1C(OC(C)=O)C(OC(C)=O)C(OC(C)=O)C(OC(C)=O)C1OC(C)=O SQUHHTBVTRBESD-UHFFFAOYSA-N 0.000 description 1
- 229930195725 Mannitol Natural products 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- AAJLYDMRWVXCJV-UHFFFAOYSA-N OP(O)OP(O)O.C(CCCCCO)O.C(CCC)(C1=CC(=C(C=C1C)O)C(C)(C)C)C1=CC(=C(C=C1C)O)C(C)(C)C.C(CCC)(C1=CC(=C(C=C1C)O)C(C)(C)C)C1=CC(=C(C=C1C)O)C(C)(C)C Chemical compound OP(O)OP(O)O.C(CCCCCO)O.C(CCC)(C1=CC(=C(C=C1C)O)C(C)(C)C)C1=CC(=C(C=C1C)O)C(C)(C)C.C(CCC)(C1=CC(=C(C=C1C)O)C(C)(C)C)C1=CC(=C(C=C1C)O)C(C)(C)C AAJLYDMRWVXCJV-UHFFFAOYSA-N 0.000 description 1
- PWZDGWCRBINXHV-UHFFFAOYSA-N OP(O)OP(O)O.OCC(CO)(CO)CO.C=1C=C(O)C(C=2C=CC=CC=2)=CC=1C(C)(C)C1=CC=C(O)C=C1 Chemical compound OP(O)OP(O)O.OCC(CO)(CO)CO.C=1C=C(O)C(C=2C=CC=CC=2)=CC=1C(C)(C)C1=CC=C(O)C=C1 PWZDGWCRBINXHV-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 1
- 229920012485 Plasticized Polyvinyl chloride Polymers 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- 235000019485 Safflower oil Nutrition 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 description 1
- BLXLSQIOCCHAHJ-UHFFFAOYSA-N [2,3,4-tri(nonyl)phenyl] dihydrogen phosphite Chemical compound CCCCCCCCCC1=CC=C(OP(O)O)C(CCCCCCCCC)=C1CCCCCCCCC BLXLSQIOCCHAHJ-UHFFFAOYSA-N 0.000 description 1
- XKTYGFMHWGOIND-UHFFFAOYSA-N [Cl].ClC=C Chemical compound [Cl].ClC=C XKTYGFMHWGOIND-UHFFFAOYSA-N 0.000 description 1
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 1
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 1
- 150000008360 acrylonitriles Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 239000003429 antifungal agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- XOIXUOQWXVZBRQ-UHFFFAOYSA-N barium;2-nonylphenol Chemical compound [Ba].CCCCCCCCCC1=CC=CC=C1O XOIXUOQWXVZBRQ-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 150000008366 benzophenones Chemical class 0.000 description 1
- 150000001565 benzotriazoles Chemical class 0.000 description 1
- NIDNOXCRFUCAKQ-UHFFFAOYSA-N bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2C(O)=O NIDNOXCRFUCAKQ-UHFFFAOYSA-N 0.000 description 1
- BKDVBBSUAGJUBA-UHFFFAOYSA-N bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylic acid Chemical compound C1=CC2C(C(O)=O)C(C(=O)O)C1C(C(O)=O)C2C(O)=O BKDVBBSUAGJUBA-UHFFFAOYSA-N 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 1
- SXXILWLQSQDLDL-UHFFFAOYSA-N bis(8-methylnonyl) phenyl phosphite Chemical compound CC(C)CCCCCCCOP(OCCCCCCCC(C)C)OC1=CC=CC=C1 SXXILWLQSQDLDL-UHFFFAOYSA-N 0.000 description 1
- 229940106691 bisphenol a Drugs 0.000 description 1
- SXDBWCPKPHAZSM-UHFFFAOYSA-M bromate Inorganic materials [O-]Br(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-M 0.000 description 1
- SXDBWCPKPHAZSM-UHFFFAOYSA-N bromic acid Chemical compound OBr(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-N 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- GGAUUQHSCNMCAU-UHFFFAOYSA-N butane-1,2,3,4-tetracarboxylic acid Chemical compound OC(=O)CC(C(O)=O)C(C(O)=O)CC(O)=O GGAUUQHSCNMCAU-UHFFFAOYSA-N 0.000 description 1
- JODNECOOAJMIKX-UHFFFAOYSA-N butane-1,2,3-tricarboxylic acid Chemical compound OC(=O)C(C)C(C(O)=O)CC(O)=O JODNECOOAJMIKX-UHFFFAOYSA-N 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910001919 chlorite Inorganic materials 0.000 description 1
- 229910052619 chlorite group Inorganic materials 0.000 description 1
- ZJPJECQPVMSILT-UHFFFAOYSA-N chloroethene 3-(2-phenylethenyl)furan-2,5-dione Chemical compound ClC=C.O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 ZJPJECQPVMSILT-UHFFFAOYSA-N 0.000 description 1
- IEJNAGSUKYCWCR-UHFFFAOYSA-N chloroethene;1,1-dichloroethene;ethenyl acetate Chemical compound ClC=C.ClC(Cl)=C.CC(=O)OC=C IEJNAGSUKYCWCR-UHFFFAOYSA-N 0.000 description 1
- VSJDEWYENWWMAV-UHFFFAOYSA-N chloroethene;2-methylprop-2-enoic acid Chemical compound ClC=C.CC(=C)C(O)=O VSJDEWYENWWMAV-UHFFFAOYSA-N 0.000 description 1
- KRGNPJFAKZHQPS-UHFFFAOYSA-N chloroethene;ethene Chemical group C=C.ClC=C KRGNPJFAKZHQPS-UHFFFAOYSA-N 0.000 description 1
- SQNNHEYXAJPPKH-UHFFFAOYSA-N chloroethene;prop-2-enoic acid Chemical compound ClC=C.OC(=O)C=C SQNNHEYXAJPPKH-UHFFFAOYSA-N 0.000 description 1
- QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical compound OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 description 1
- 150000001844 chromium Chemical class 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- GLOQRSIADGSLRX-UHFFFAOYSA-N decyl diphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OCCCCCCCCCC)OC1=CC=CC=C1 GLOQRSIADGSLRX-UHFFFAOYSA-N 0.000 description 1
- 238000007033 dehydrochlorination reaction Methods 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 229940105990 diglycerin Drugs 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- CZHYKKAKFWLGJO-UHFFFAOYSA-N dimethyl phosphite Chemical compound COP([O-])OC CZHYKKAKFWLGJO-UHFFFAOYSA-N 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- CAMHHLOGFDZBBG-UHFFFAOYSA-N epoxidized methyl oleate Natural products CCCCCCCCC1OC1CCCCCCCC(=O)OC CAMHHLOGFDZBBG-UHFFFAOYSA-N 0.000 description 1
- XWENCHGJOCJZQO-UHFFFAOYSA-N ethane-1,1,2,2-tetracarboxylic acid Chemical compound OC(=O)C(C(O)=O)C(C(O)=O)C(O)=O XWENCHGJOCJZQO-UHFFFAOYSA-N 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 235000021323 fish oil Nutrition 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- NBZBKCUXIYYUSX-UHFFFAOYSA-N iminodiacetic acid Chemical compound OC(=O)CNCC(O)=O NBZBKCUXIYYUSX-UHFFFAOYSA-N 0.000 description 1
- CDAISMWEOUEBRE-GPIVLXJGSA-N inositol Chemical compound O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@H](O)[C@@H]1O CDAISMWEOUEBRE-GPIVLXJGSA-N 0.000 description 1
- 229960000367 inositol Drugs 0.000 description 1
- ICIWUVCWSCSTAQ-UHFFFAOYSA-N iodic acid Chemical class OI(=O)=O ICIWUVCWSCSTAQ-UHFFFAOYSA-N 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- QQVIHTHCMHWDBS-UHFFFAOYSA-L isophthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC(C([O-])=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-L 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 239000006078 metal deactivator Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 150000002898 organic sulfur compounds Chemical class 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- GGRGTHFWHGANTA-UHFFFAOYSA-N pentane-1,3,3,5-tetracarboxylic acid Chemical compound OC(=O)CCC(C(O)=O)(C(O)=O)CCC(O)=O GGRGTHFWHGANTA-UHFFFAOYSA-N 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
- KHIWWQKSHDUIBK-UHFFFAOYSA-N periodic acid Chemical compound OI(=O)(=O)=O KHIWWQKSHDUIBK-UHFFFAOYSA-N 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000008029 phthalate plasticizer Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 1
- 229920005671 poly(vinyl chloride-propylene) Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- JXHDZGPVOXKUSI-UHFFFAOYSA-N propane-1,2,2,3-tetracarboxylic acid Chemical compound OC(=O)CC(C(O)=O)(C(O)=O)CC(O)=O JXHDZGPVOXKUSI-UHFFFAOYSA-N 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 150000003873 salicylate salts Chemical class 0.000 description 1
- CDAISMWEOUEBRE-UHFFFAOYSA-N scyllo-inosotol Natural products OC1C(O)C(O)C(O)C(O)C1O CDAISMWEOUEBRE-UHFFFAOYSA-N 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000012756 surface treatment agent Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- BKFSDYFSRDUZIV-UHFFFAOYSA-N tetradecane-1,6,8,14-tetracarboxylic acid Chemical compound OC(=O)CCCCCCC(C(O)=O)CC(C(O)=O)CCCCCC(O)=O BKFSDYFSRDUZIV-UHFFFAOYSA-N 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- XTTGYFREQJCEML-UHFFFAOYSA-N tributyl phosphite Chemical compound CCCCOP(OCCCC)OCCCC XTTGYFREQJCEML-UHFFFAOYSA-N 0.000 description 1
- IVIIAEVMQHEPAY-UHFFFAOYSA-N tridodecyl phosphite Chemical compound CCCCCCCCCCCCOP(OCCCCCCCCCCCC)OCCCCCCCCCCCC IVIIAEVMQHEPAY-UHFFFAOYSA-N 0.000 description 1
- 125000005591 trimellitate group Chemical group 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- ILLOBGFGKYTZRO-UHFFFAOYSA-N tris(2-ethylhexyl) phosphite Chemical compound CCCCC(CC)COP(OCC(CC)CCCC)OCC(CC)CCCC ILLOBGFGKYTZRO-UHFFFAOYSA-N 0.000 description 1
- JZNDMMGBXUYFNQ-UHFFFAOYSA-N tris(dodecylsulfanyl)phosphane Chemical compound CCCCCCCCCCCCSP(SCCCCCCCCCCCC)SCCCCCCCCCCCC JZNDMMGBXUYFNQ-UHFFFAOYSA-N 0.000 description 1
- QQBLOZGVRHAYGT-UHFFFAOYSA-N tris-decyl phosphite Chemical compound CCCCCCCCCCOP(OCCCCCCCCCC)OCCCCCCCCCC QQBLOZGVRHAYGT-UHFFFAOYSA-N 0.000 description 1
- WRSPWQHUHVRNFV-UHFFFAOYSA-N tris[3,5-di(nonyl)phenyl] phosphite Chemical compound CCCCCCCCCC1=CC(CCCCCCCCC)=CC(OP(OC=2C=C(CCCCCCCCC)C=C(CCCCCCCCC)C=2)OC=2C=C(CCCCCCCCC)C=C(CCCCCCCCC)C=2)=C1 WRSPWQHUHVRNFV-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 150000003739 xylenols Chemical class 0.000 description 1
- VNTDZUDTQCZFKN-UHFFFAOYSA-L zinc 2,2-dimethyloctanoate Chemical compound [Zn++].CCCCCCC(C)(C)C([O-])=O.CCCCCCC(C)(C)C([O-])=O VNTDZUDTQCZFKN-UHFFFAOYSA-L 0.000 description 1
- 229940098697 zinc laurate Drugs 0.000 description 1
- GPYYEEJOMCKTPR-UHFFFAOYSA-L zinc;dodecanoate Chemical compound [Zn+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O GPYYEEJOMCKTPR-UHFFFAOYSA-L 0.000 description 1
- JBCJMTUHAXHILC-UHFFFAOYSA-N zinc;octanoic acid Chemical compound [Zn+2].CCCCCCCC(O)=O JBCJMTUHAXHILC-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Description
本発明は、安定化された含塩素樹脂組成物、詳
しくは、含塩素樹脂に有機酸金属塩、多価アルコ
ールのカルボン酸部分エステル及びハロゲン酸素
酸塩類を添加して成る含塩素樹脂組成物に関す
る。
含塩素樹脂は、加熱成形加工を行なう際に、主
として脱塩化水素に起因する熱分解を起しやす
く、このために加工製品の機械的性質の低下、色
調の悪化を生じ、著しい不利益をまねく。かかる
不利益をさけるために、一種または数種の熱安定
剤を該合成樹脂に添加し、加工工程における劣化
を抑制する必要がある。
従来、かかる目的で各種の有機酸金属塩、有機
錫化合物が使用されてきた。その結果熱安定性の
面ではほぼ満足すべき結果が得られている。しか
し近年これらの金属塩、特にカドミウム塩は毒性
上の問題が大きく、その使用が著しく制限されて
いる。この為にカドミウム塩以外の各種金属塩を
種々組み合せて使用すること、例えばBa/Zn系、
Ca/Zn系、Ba/Ca/Zn系等が提案された。し
かし、その性能は十分ではなく、各種の安定化助
剤、例えばエポキシ化合物、多価アルコール類、
有機リン化合物、有機硫黄化合物、フエノール化
合物、β―ジケトン化合物等の使用が提案されて
いるが、まだ十分とは言えず、更に改善する必要
があつた。
本発明者等は、かかる現状に鑑み、種々検討を
重ねた結果、含塩素樹脂に(a)有機酸の金属塩の少
なくとも一種、(b)多価アルコールのカルボン酸部
分エステルの少なくとも一種及び(c)ハロゲン酸素
酸の金属塩類の少なくとも一種を添加することに
より、著しい安定化効果が得られることを見い出
し本発明に到達したものである。
以下に本発明について詳述する。
本発明において使用する(a)成分の有機酸の金属
塩を構成する有機酸としてはカルボン酸、フエノ
ール類などが有用である。
上記カルボン酸の例としては、酢酸、プロピオ
ン酸、酪酸、吉草酸、カプロン酸、エナント酸、
カプリル酸、ネオオクタン酸、2―エチルヘキシ
ル酸、ペラルゴン酸、カプリン酸、ネオデカン
酸、ウンデカン酸、ラウリン酸、トリデカン酸、
ミリスチン酸、パルミチン酸、イソステアリン
酸、ステアリン酸、2―ヒドロキシステアリン
酸、ベヘン酸、モンタン酸、安息香酸、モノクロ
安息香酸、P―tert―ブチル安息香酸、ジメチル
ヒドロキシ安息香酸、3,5―ジtert―ブチル―
4―ヒドロキシ安息香酸、トルイル酸、ジメチル
安息香酸、エチル安息香酸、クミン酸、n―プロ
ピル安息香酸、アミノ安息香酸、N,N―ジメチ
ルアミノ安息香酸、アセトキシ安息香酸、サリチ
ル酸、P―tert―オクチルサリチル酸、オレイン
酸、エライジン酸、リノール酸、リノレン酸、チ
オグリコール酸、メルカプトプロピオン酸、オク
チルメルカプトプロピオン酸などの一価カルボン
酸、シユウ酸、マロン酸、コハク酸、グルタル
酸、アジピン酸、ピメリン酸、スベリン酸、アゼ
ライン酸、セバチン酸、フタル酸、イソフタル
酸、テレフタル酸、オキシフタル酸、クロルフタ
ル酸、アミノフタル酸、マレイン酸、フマール
酸、シトラコン酸、メサコン酸、イタコン酸、ア
コニツト酸、チオジプロピオン酸などの二価カル
ボン酸のモノエステル又はモノアマイド化合物、
ヘミメリツト酸、トリメリツト酸、メロフアン
酸、ピロメリツト酸などの三価又は四価カルボン
酸のジ又はトリエステル化合物があげられる。
また、上記フエノール類の例としては、tert―
ブチルフエノール、ノニルフエノール、ジノニル
フエノール、シクロヘキシルフエノール、フエニ
ルフエノール、オクチルフエノール、フエノー
ル、クレゾール、キシレノール、n―ブチルフエ
ノール、イソアミルフエノール、エチルフエノー
ル、イソプロピルフエノール、イソオクチルフエ
ノール、2―エチルヘキシルフエノール、tert―
ノニルフエノール、デシルフエノール、tert―オ
クチルフエノール、イソヘキシルフエノール、オ
クタデシルフエノール、ジイソブチルフエノー
ル、メチルプロピルフエノール、ジアミルフエノ
ール、メチルイソヘキシルフエノール、メチル―
tert―オクチルフエノールなどがあげられる。
また、(a)成分の有機酸の金属塩を構成する金属
の具体例としては、Na、K、Li等のIa族金属、
Mg、Ca、Sr、Ba等のa族金属、Zn、Zr、Sn
等があげられる。
本発明に係る上記有機酸の金属塩の添加量は樹
脂100重量部に対して0.01〜10重量部、好ましく
は0.1〜3重量部である。
本発明において使用する(b)成分の多価アルコー
ルのカルボン酸部分エステルを構成する3価以上
の多価アルコールとしては、例えばトリメチロー
ルエタン、トリメチロールプロパン、グリセリ
ン、2―ヒドロキシメチル―3―メチルブタン―
1,3―ジオール、3―メチルペンタン―1,
3,5―トリオール、トリス―(2―ヒドロキシ
エチル)イソシアヌレート、ヘキサン―1,2,
6―トリオール、2―ヒドロキシメチル―2―メ
チルブタン―1,3―ジオール、2,4―ジメチ
ル―3―ヒドロキシメチルペンタン―2,4―ジ
オール、ペンタエリスリトール、ジグリセリン、
ジトリメチロールエタン、ジトリメチロールプロ
パン、2,2,6,6―テトラメチロールシクロ
ヘキサノール、ジペンタエリスリトール、イノシ
トール、マニトール、ソルビトール、ポリペンタ
エリスリトールなどがあげられる。
また、(b)成分の多価アルコールのカルボン酸部
分エステルを構成する1価カルボン酸の例として
は、酢酸、プロピオン酸、酪酸、吉草酸、カプロ
ン酸、エナント酸、カプリル酸、ネオオクタン
酸、2―エチルヘキシル酸、ペラルゴン酸、カプ
リン酸、ウンデカン酸、ラウリン酸、トリデカン
酸、ミリスチン酸、パルミチン酸、イソステアリ
ン酸、ステアリン酸、2―ヒドロキシステアリン
酸、ベヘン酸、モンタン酸、安息香酸、モノクロ
ル安息香酸、P―tert―ブチル安息香酸、ジメチ
ルヒドロキシ安息香酸、3,5―ジtert―ブチル
―4―ヒドロキシ安息香酸、トルイル酸、ジメチ
ル安息香酸、エチル安息香酸、クミン酸、n―プ
ロピル安息香酸、アミノ安息香酸、N,N―ジメ
チルアミノ安息香酸、アセトキシ安息香酸、サリ
チル酸、P―tert―オクチルサリチル酸、オレイ
ン酸、エライジン酸、リノール酸、リノレン酸、
チオグリコール酸、メルカプトプロピオン酸、オ
クチルメルカプトプロピオン酸などがあげられ
る。2乃至6価の多価カルボン酸の例としては、
フタル酸、イソフタル酸、テレフタル酸、3―メ
チルフタル酸、2―メチルイソフタル酸、オキシ
フタル酸、ジオキシフタル酸、アミノフタル酸、
アミノテレフタル酸、ジアミノフタル酸、3―ク
ロルフタル酸、クロルテレフタル酸などの二価カ
ルボン酸、ヘミメリツト酸、トリメリツト酸、ト
リメシン酸、メロフアン酸、ピロメリツト酸、メ
リツト酸などの芳香族多価カルボン酸、シユウ
酸、マロン酸、コハク酸、グルタル酸、アジピン
酸、ピメリン酸、スベリン酸、アゼライン酸、セ
バチン酸、リンゴ酸、マレイン酸、フマール酸、
シトラコン酸、メサコン酸、イタコン酸、アコニ
ツト酸、チオジプロピオン酸、酒石酸、イミノジ
酢酸、ブタン―1,2,3―トリカルボン酸、プ
ロパン―1,2,3―トリカルボン酸、ブテン―
1,2,3―トリカルボン酸、クエン酸、アセチ
ルクエン酸、ニトリロトリ酢酸、ニトリロトリプ
ロピオン酸、トリス(カルボキシエチル)イソシ
アヌレート、ブタン―1,2,3,4―テトラカ
ルボン酸、ペンタン―1,3,3,5―テトラカ
ルボン酸、1,1,2,2―エタンテトラカルボ
ン酸、1,2,2,3―プロパンテトラカルボン
酸、エチレンジアミンテトラ酢酸、5―ビシクロ
〔2.2.1〕ヘプテン―2,3―ジカルボン酸、5―
ビシクロ〔2.2.2〕オクテン―2,3―ジカルボ
ン酸、7―ビシクロ〔2.2.2〕オクテン―2,3,
5,6―テトラカルボン酸、1,6,8,14―テ
トラデカンテトラカルボン酸、1,6,7,8,
9,14―テトラデカンヘキサカルボン酸などの脂
肪族多価カルボン酸があげられる。
本発明において使用する多価アルコールのカル
ボン酸部分エステル化合物は、上記多価アルコー
ルと上記1価カルボン酸又は多価カルボン酸又は
上記多価カルボン酸と上記1価カルボン酸の混合
酸を任意の比率で混合し、通常のエステル化反応
により約100〜200℃で数時間脱水することにより
容易に得ることができる。これらの化合物は少な
くとも1個の水酸基を含有するものであれば本発
明組成物の熱安定性向上に寄与するが、多価アル
コールが本来有している水酸基を全部またはほと
んどエステル化したものはあまり効果がなく、ま
た水酸基のエステル化度の低すぎるものは揮発し
たり、樹脂との相溶性が劣るなど変性の効果が少
ない。またエステル化度の極端に高いポリエステ
ル型の化合物でも塩素含有樹脂との相溶性が悪
く、熱安定性及び透明性が劣る傾向があるので適
宜エステル化度を調節するのが好ましい。水酸基
の含有量及びエステル化度を調節することは多価
アルコールとカルボン酸のモル比、反応温度及び
反応時間を調節することで容易にできる。
本発明における(b)成分の多価アルコールのカル
ボン酸部分エステルの具体例としては、例えばグ
リセリン・モノオレエート、グリセリン・モノス
テアレート、ポリグリセリン・オレエート、ポリ
グリセリン・ステアレート、ポリグリセリン・ア
ジペート、ビス(トリメチロールプロパン)・ア
ジペート、ビス(トリメチロールエタン)・イタ
コネート、ビス(トリメチロールプロパン)・テ
レフタレート、ビス〔トリス(ヒドロキシエチ
ル)イソシアヌレート〕・アジペート、ペンタエ
リスリトール・モノステアレート、ビス(ペンタ
エリスリトール)・テレフタレート、ビス(ペン
タエリスリトール)・スクシネート、ペンタエリ
スリトール・アジペート、ビス(ペンタエリスリ
トール)・アジペート、ジペンタエリスリトー
ル・ジステアレート、ジペンタエリスリトール・
モノベンゾエート、ジペンタエリスリトール・ア
ジペート、ビス(ジペンタエリスリトール)・ア
ジペート、ジペンタエリスリトール・ジアジペー
ト、ビス(ジペンタエリスリトール)・テレフタ
レート、ビス(ジペンタエリスリトール)・テレ
フタレート・アジペート、ビス(ジペンタエリス
リトール)・セバケート、ビス(ジペンタエリス
リトール)・セバケート・アセテート、ビス(ジ
ペンタエリスリトール)・フタレート、ビス(ジ
ペンタエリスリトール)・イソフタレート、ビス
(ジペンタエリスリトール)・チオジプロピオネー
ト、ビス(ジペンタエリスリトール)・マレエー
ト、ビス(ジペンタエリスリトール)・マリート、
ビス(ジペンタエリスリトール)・ニトリロトリ
アセテート、トリス(ジペンタエリスリトー
ル)・トリメリテート、テトラ(ジペンタエリス
リトール)・ピロメリテート、ジペンタエリスリ
トール・モノアセテート、ジペンタエリスリトー
ル・モノオクタノエート、ジトリメチロールプロ
パン・テレフタレート、ビス(ジトリメチロール
プロパン)・テレフタレート、トリペンタエリス
リトール・フタレート、ポリ(モノ、ジ、トリ混
合)ペンタエリスリトール・テレフタレート、ビ
ス(ソルビトール)・アジペート・オクタノエー
ト、ビス(ソルビトール)・サイトレートなどが
あげられる。
本発明に係る上記多価アルコールのカルボン酸
部分エステルの添加量は樹脂100重量部に対して
0.005〜10重量部、好ましくは0.01〜5重量部で
ある。
また、本発明において使用する(c)成分のハロゲ
ン酸素酸塩類としては、例えば過塩素酸塩(Zn、
Al、K、Ca、Sr、Na、Ba、Mg、Li)、過沃素
酸塩(Zn、K、Na、Ba、Li)、塩素酸塩(Zn、
Al、K、Ca、Sr、Na、Ba、Mg、Li)、臭素酸
塩(Zn、Al、K、Ca、Sr、Na、Ba、Mg、Li)、
沃素酸塩(Zn、Al、K、Ca、Sr、Na、Ba、
Mg、Li)、亜塩素酸塩(Zn、Ca、K、Na、
Ba)、次亜塩素酸塩(Li、Na、K、Ca、Sr、
Ba)、亜臭素酸(Na、K、Ca、Ba)などがあげ
られる。これらは当然ながら含水塩であつても良
い。
上記ハロゲン酸素酸塩の添加量は含塩素樹脂
100重量部に対して0.001〜3重量部、好ましくは
0.01〜2重量部である。
本発明組成物に更に有機ホスフアイト化合物及
び/またはエポキシ化合物を併用することにより
すぐれた相剰効果を示す。
本発明で使用できる有機ホスフアイト化合物と
しては、ジフエニルデシルホスフアイト、トリフ
エニルホスフアイト、トリス―ノニルフエニルホ
スフアイト、トリデシルホスフアイト、トリス
(2―エチルヘキシル)ホスフアイト、トリブチ
ルホスフアイト、ジラウリルアシドホスフアイ
ト、ジブチルアシドホスフアイト、トリス(ジノ
ニルフエニル)ホスフアイト、トリラウリルトリ
チオホスフアイト、トリラウリルホスフアイト、
ビス(ネオペンチルグリコール)―1,4―シク
ロヘキサンジメチルホスフアイト、ジステアリル
ペンタエリスリトールジホスフアイト、ジイソデ
シルペンタエリスリトールジホスフアイト、ジフ
エニルアシドホスフアイト、トリス(ラウリル―
2―チオエチル)ホスフアイト、テトラトリデシ
ル―1,1,3―トリス(2′―メチル―5′―第3
ブチル―4′―オキシフエニル)ブタンジホスフア
イト、テトラ(C12〜C15混合アルキル)4,4′―
イソプロピリデンジフエニルジホスフアイト、ト
リス(4―オキシ―2,5―ジ―第3ブチルフエ
ニル)ホスフアイト、トリス(4―オキシ―3,
5―ジ―第3ブチルフエニル)ホスフアイト、2
―エチルヘキシルジフエニルホスフアイト、トリ
ス(モノ、ジ混合ノニルフエニル)ホスフアイ
ト、水素化―4,4′―イソプロピリデンジフエノ
ールポリホスフアイト、ジフエニル・ビス〔4,
4′―n―ブチリデンビス(2―第3ブチル―5―
メチルフエノール)〕チオジエタノールジホスフ
アイト、ビス(オクチルフエニル)・ビス〔4,
4′―n―ブチリデンビス(2―第3ブチル―5―
メチルフエノール)〕―1,6―ヘキサンジオー
ルジホスフアイト、フエニル―4,4′―イソプロ
ピリデンジフエノール・ペンタエリスリトールジ
ホスフアイト、フエニルジイソデシルホスフアイ
ト、テトラトリデシル―4,4′―n―ブチリデン
ビス(2―第3ブチル―5―メチルフエノール)
ジホスフアイト、トリス(2,4―ジ―第3ブチ
ルフエニル)ホスフアイト、などがあげられる。
これら有機ホスフアイト化合物の添加量は樹脂
100重量部に対して0.01〜5重量部、好ましくは
0.1〜3重量部である。
本発明で使用しうるエポキシ化合物としては、
エポキシ化大豆油、エポキシ化アマニ油、エポキ
シ化魚油、エポキシ化トール油脂肪酸エステル、
エポキシ化牛脂油、エポキシ化ポリブタジエン、
エポキシステアリン酸メチル、―ブチル、―2エ
チルヘキシル、―ステアリル、トリス(エポキシ
プロピル)イソシアヌレート、エポキシ化ヒマシ
油、エポキシ化サフラワー油、エポキシ化アマニ
油脂肪酸ブチル、3―(2―キセノキシ)―1,
2―エポキシプロパン、ビスフエノール―Aジグ
リシジルエーテル、ビニルシクロヘキセンジエポ
キサイド、ジシクロペンタジエンジエポキサイ
ド、3,4―エポキシシクロヘキシル―6―メチ
ルエポキシシクロヘキサンカルボキシレートなど
があげられる。
これらエポキシ化合物の添加量は樹脂100重量
部に対して0.01〜10重量部、好ましくは0.5〜5
重量部である。
本発明の重合体組成物にはフタール酸エステル
系可塑剤もしくはその他のエステル系可塑剤、又
はポリエステル系可塑剤、燐酸エステル系可塑
剤、塩素系可塑剤、その他の可塑剤などが用途に
応じて適宜使用できる。
本発明の重合体組成物に酸化防止剤を添加する
ことは該重合体組成物の酸化劣化防止性を増大さ
せ得るので、使用目的に応じて適宜使用できる。
これら酸化防止剤には、フエノール系酸化防止
剤、含硫黄化合物などが含まれる。
本発明の重合体組成物に紫外線吸収剤を添加す
るならば、光安定性を向上させ得るので、使用目
的に応じて適宜これらを選択して使用することが
可能である。これらにはベンゾフエノン系、ベン
ゾトリアゾール系、サリシレート系、置換アクリ
ロニトリル系、各種の金属塩又は金属キレート、
特にニツケル又はクロムの塩又はキレート類、ト
リアジン系、ピペリジン系などが包含される。
更に無毒な塩素を含有する重合体を得るために
は、前記の通常用いられる金属石けんのうち、無
毒なものを選んで用いれば無毒且つ熱安定性の良
好な塩素を含有する重合体組成物が得られる。
その他必要に応じて、例えば架橋剤、顔料、充
填剤、発泡剤、帯電防止剤、防曇剤、プレートア
ウト防止剤、表面処理剤、滑剤、難燃剤、蛍光
剤、防黴剤、殺菌剤、金属不活性剤、光劣化剤、
加工助剤、離型剤、補強剤などを包含させること
ができる。
本発明に用いられる塩素を含有する重合体とし
ては次のようなものがある。例えば、ポリ塩化ビ
ニル、ポリ塩化ビニリデン、塩素化ポリエチレ
ン、塩素化ポリプロピレン、塩化ゴム、塩化ビニ
ル―酢酸ビニル共重合体、塩化ビニル―エチレン
共重合体、塩化ビニル―プロピレン共重合体、塩
化ビニル―スチレン共重合体、塩化ビニル―イソ
ブチレン共重合体、塩化ビニル―塩化ビニリデン
共重合体、塩化ビニル―スチレン―無水マレイン
酸三元共重合体、塩化ビニル―スチレン―アクリ
ロニトリル共重合体、塩化ビニル―ブタジエン共
重合体、塩化ビニル―イソプレン共重合体、塩化
ビニル―塩素化プロピレン共重合体、塩化ビニル
―塩化ビニリデン―酢酸ビニル三元共重合体、塩
化ビニル―アクリル酸エステル共重合体、塩化ビ
ニル―マレイン酸エステル共重合体、塩化ビニル
―メタクリル酸エステル共重合体、塩化ビニル―
アクリロニトリル共重合体、内部可塑化ポリ塩化
ビニルなどの含塩素合成樹脂および上記含塩素樹
脂とポリエチレン、ポリプロピレン、ポリブテ
ン、ポリ―3―メチルブテンなどのα―オレフイ
ン重合体又はエチレン―酢酸ビニル共重合体、エ
チレン―プロピレン共重合体などのポリオレフイ
ン及びこれらの共重合体、ポリスチレン、アクリ
ル樹脂、スチレンと他の単量体(例えば無水マレ
イン酸、ブタジエン、アクリロニトリルなど)と
の共重合体、アクリロニトリル―ブタジエン―ス
チレン共重合体、アクリル酸エステル―ブタジエ
ン―スチレン共重合体、メタクリル酸エステル―
ブタジエン―スチレン共重合体とのブレンド品な
どを挙げることができる。
次に示す実施例は本発明による塩素樹脂組成物
の効果を示すものであるが、本発明はこれらの実
施例によつて制限されるものではない。
実施例 1
次の配合物をロール混練し、次いでプレス加工
を行ない厚さ1mmのシートを作成した。このシー
トを用いて初期着色性、透明性及び190℃での熱
安定性を調べた。その結果を第1表に示す。
<配 合>
ポリ塩化ビニル樹脂 100 重量部
エポキシ化アマニ油 2.0
ステアリン酸亜鉛 0.5
ステアリン酸バリウム 1.0
過塩素酸バリウム 0.1
多価アルコール類(第1表) 0.2
The present invention relates to a stabilized chlorine-containing resin composition, and more particularly, to a chlorine-containing resin composition obtained by adding an organic acid metal salt, a carboxylic acid partial ester of a polyhydric alcohol, and a halogen oxyacid salt to a chlorine-containing resin. . Chlorine-containing resins are prone to thermal decomposition, mainly due to dehydrochlorination, when subjected to thermoforming processing, resulting in a decrease in mechanical properties and color tone of processed products, resulting in significant disadvantages. . In order to avoid such disadvantages, it is necessary to add one or more kinds of heat stabilizers to the synthetic resin to suppress deterioration during processing steps. Conventionally, various organic acid metal salts and organic tin compounds have been used for this purpose. As a result, almost satisfactory results were obtained in terms of thermal stability. However, in recent years, these metal salts, especially cadmium salts, have serious toxicity problems and their use has been severely restricted. For this purpose, various combinations of metal salts other than cadmium salts are used, such as Ba/Zn salts,
Ca/Zn series, Ba/Ca/Zn series, etc. were proposed. However, its performance is not sufficient, and various stabilizing agents such as epoxy compounds, polyhydric alcohols,
Although the use of organic phosphorus compounds, organic sulfur compounds, phenol compounds, β-diketone compounds, etc. has been proposed, it is still not sufficient and there is a need for further improvements. In view of the current situation, the present inventors have conducted various studies and found that (a) at least one metal salt of an organic acid, (b) at least one carboxylic acid partial ester of a polyhydric alcohol, and ( c) The present invention was achieved by discovering that a significant stabilizing effect can be obtained by adding at least one metal salt of a halogen oxyacid. The present invention will be explained in detail below. Carboxylic acids, phenols, and the like are useful as the organic acids constituting the metal salt of the organic acid as component (a) used in the present invention. Examples of the above carboxylic acids include acetic acid, propionic acid, butyric acid, valeric acid, caproic acid, enanthic acid,
Caprylic acid, neooctanoic acid, 2-ethylhexylic acid, pelargonic acid, capric acid, neodecanoic acid, undecanoic acid, lauric acid, tridecanoic acid,
Myristic acid, palmitic acid, isostearic acid, stearic acid, 2-hydroxystearic acid, behenic acid, montanic acid, benzoic acid, monochlorobenzoic acid, P-tert-butylbenzoic acid, dimethylhydroxybenzoic acid, 3,5-ditert -Butyl-
4-Hydroxybenzoic acid, toluic acid, dimethylbenzoic acid, ethylbenzoic acid, cumic acid, n-propylbenzoic acid, aminobenzoic acid, N,N-dimethylaminobenzoic acid, acetoxybenzoic acid, salicylic acid, P-tert-octyl Monocarboxylic acids such as salicylic acid, oleic acid, elaidic acid, linoleic acid, linolenic acid, thioglycolic acid, mercaptopropionic acid, octylmercaptopropionic acid, oxalic acid, malonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid , suberic acid, azelaic acid, sebacic acid, phthalic acid, isophthalic acid, terephthalic acid, oxyphthalic acid, chlorphthalic acid, aminophthalic acid, maleic acid, fumaric acid, citraconic acid, mesaconic acid, itaconic acid, aconitic acid, thiodipropionic acid monoester or monoamide compounds of dihydric carboxylic acids, such as
Examples include di- or triester compounds of trivalent or tetravalent carboxylic acids such as hemimellitic acid, trimellitic acid, merophonic acid, and pyromellitic acid. In addition, examples of the above phenols include tert-
Butylphenol, nonylphenol, dinonylphenol, cyclohexylphenol, phenylphenol, octylphenol, phenol, cresol, xylenol, n-butylphenol, isoamylphenol, ethylphenol, isopropylphenol, isooctylphenol, 2-ethylhexylphenol, tert ―
Nonylphenol, decylphenol, tert-octylphenol, isohexylphenol, octadecylphenol, diisobutylphenol, methylpropylphenol, diamylphenol, methylisohexylphenol, methyl-
Examples include tert-octylphenol. Specific examples of metals constituting the metal salt of the organic acid as component (a) include group Ia metals such as Na, K, and Li;
Group a metals such as Mg, Ca, Sr, Ba, etc., Zn, Zr, Sn
etc. can be mentioned. The amount of the metal salt of the organic acid according to the present invention added is 0.01 to 10 parts by weight, preferably 0.1 to 3 parts by weight, per 100 parts by weight of the resin. Examples of the trihydric or higher polyhydric alcohol constituting the carboxylic acid partial ester of polyhydric alcohol used in the present invention (b) include trimethylolethane, trimethylolpropane, glycerin, and 2-hydroxymethyl-3-methylbutane. ―
1,3-diol, 3-methylpentane-1,
3,5-triol, tris-(2-hydroxyethyl)isocyanurate, hexane-1,2,
6-triol, 2-hydroxymethyl-2-methylbutane-1,3-diol, 2,4-dimethyl-3-hydroxymethylpentane-2,4-diol, pentaerythritol, diglycerin,
Examples include ditrimethylolethane, ditrimethylolpropane, 2,2,6,6-tetramethylolcyclohexanol, dipentaerythritol, inositol, mannitol, sorbitol, and polypentaerythritol. In addition, examples of monovalent carboxylic acids constituting the carboxylic acid partial ester of polyhydric alcohol as component (b) include acetic acid, propionic acid, butyric acid, valeric acid, caproic acid, enanthic acid, caprylic acid, neooctanoic acid, - Ethylhexylic acid, pelargonic acid, capric acid, undecanoic acid, lauric acid, tridecanoic acid, myristic acid, palmitic acid, isostearic acid, stearic acid, 2-hydroxystearic acid, behenic acid, montanic acid, benzoic acid, monochlorobenzoic acid, P-tert-butylbenzoic acid, dimethylhydroxybenzoic acid, 3,5-ditert-butyl-4-hydroxybenzoic acid, toluic acid, dimethylbenzoic acid, ethylbenzoic acid, cumic acid, n-propylbenzoic acid, aminobenzoic acid Acid, N,N-dimethylaminobenzoic acid, acetoxybenzoic acid, salicylic acid, P-tert-octylsalicylic acid, oleic acid, elaidic acid, linoleic acid, linolenic acid,
Examples include thioglycolic acid, mercaptopropionic acid, and octylmercaptopropionic acid. Examples of divalent to hexavalent polycarboxylic acids include:
Phthalic acid, isophthalic acid, terephthalic acid, 3-methylphthalic acid, 2-methylisophthalic acid, oxyphthalic acid, dioxyphthalic acid, aminophthalic acid,
Dihydric carboxylic acids such as aminoterephthalic acid, diaminophthalic acid, 3-chlorophthalic acid, and chlorterephthalic acid; aromatic polycarboxylic acids such as hemimellitic acid, trimellitic acid, trimesic acid, merophanoic acid, pyromellitic acid, and mellitic acid; Acid, malonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, malic acid, maleic acid, fumaric acid,
Citraconic acid, mesaconic acid, itaconic acid, aconitic acid, thiodipropionic acid, tartaric acid, iminodiacetic acid, butane-1,2,3-tricarboxylic acid, propane-1,2,3-tricarboxylic acid, butene-
1,2,3-tricarboxylic acid, citric acid, acetylcitric acid, nitrilotriacetic acid, nitrilotripropionic acid, tris(carboxyethyl)isocyanurate, butane-1,2,3,4-tetracarboxylic acid, pentane-1,3 , 3,5-tetracarboxylic acid, 1,1,2,2-ethanetetracarboxylic acid, 1,2,2,3-propane tetracarboxylic acid, ethylenediaminetetraacetic acid, 5-bicyclo[2.2.1]heptene-2 ,3-dicarboxylic acid,5-
Bicyclo [2.2.2] octene-2,3-dicarboxylic acid, 7-bicyclo [2.2.2] octene-2,3,
5,6-tetracarboxylic acid, 1,6,8,14-tetradecanetetracarboxylic acid, 1,6,7,8,
Examples include aliphatic polycarboxylic acids such as 9,14-tetradecane hexacarboxylic acid. The carboxylic acid partial ester compound of a polyhydric alcohol used in the present invention is prepared by combining the polyhydric alcohol and the monohydric carboxylic acid or the mixed acid of the polyhydric carboxylic acid or the mixed acid of the polyhydric carboxylic acid and the monohydric carboxylic acid in any ratio. It can be easily obtained by mixing at 100° C. and dehydrating it at about 100 to 200° C. for several hours by a normal esterification reaction. If these compounds contain at least one hydroxyl group, they contribute to improving the thermal stability of the composition of the present invention, but compounds in which all or most of the hydroxyl groups originally possessed by polyhydric alcohols are esterified are not very effective. It has no effect, and those whose hydroxyl group has a too low degree of esterification tend to volatilize or have poor compatibility with resins, resulting in little modification effect. Further, even polyester type compounds having an extremely high degree of esterification have poor compatibility with chlorine-containing resins and tend to have poor thermal stability and transparency, so it is preferable to adjust the degree of esterification as appropriate. The content of hydroxyl groups and the degree of esterification can be easily adjusted by adjusting the molar ratio of polyhydric alcohol and carboxylic acid, reaction temperature, and reaction time. Specific examples of the carboxylic acid partial ester of polyhydric alcohol as component (b) in the present invention include glycerin monooleate, glycerin monostearate, polyglycerin oleate, polyglycerin stearate, polyglycerin adipate, bis (trimethylolpropane) adipate, bis(trimethylolethane) itaconate, bis(trimethylolpropane) terephthalate, bis[tris(hydroxyethyl)isocyanurate] adipate, pentaerythritol monostearate, bis(pentaerythritol) )・terephthalate, bis(pentaerythritol) succinate, pentaerythritol adipate, bis(pentaerythritol) adipate, dipentaerythritol distearate, dipentaerythritol・
Monobenzoate, dipentaerythritol adipate, bis(dipentaerythritol) adipate, dipentaerythritol diadipate, bis(dipentaerythritol) terephthalate, bis(dipentaerythritol) terephthalate adipate, bis(dipentaerythritol)・Sebacate, bis(dipentaerythritol) ・Sebacate ・acetate, bis(dipentaerythritol) ・phthalate, bis(dipentaerythritol) ・isophthalate, bis(dipentaerythritol) ・thiodipropionate, bis(dipentaerythritol) ), maleate, bis(dipentaerythritol), maleate,
Bis(dipentaerythritol) nitrilotriacetate, tris(dipentaerythritol) trimellitate, tetra(dipentaerythritol) pyromellitate, dipentaerythritol monoacetate, dipentaerythritol monooctanoate, ditrimethylolpropane terephthalate, Examples include bis(ditrimethylolpropane) terephthalate, tripentaerythritol phthalate, poly(mono-, di-, and tri-mixture) pentaerythritol terephthalate, bis(sorbitol) adipate octanoate, bis(sorbitol) citrate, and the like. The amount of the carboxylic acid partial ester of polyhydric alcohol according to the present invention added is based on 100 parts by weight of the resin.
The amount is 0.005 to 10 parts by weight, preferably 0.01 to 5 parts by weight. Further, as the halogen oxyacid salts of component (c) used in the present invention, for example, perchlorate (Zn,
Al, K, Ca, Sr, Na, Ba, Mg, Li), periodate (Zn, K, Na, Ba, Li), chlorate (Zn,
Al, K, Ca, Sr, Na, Ba, Mg, Li), bromate (Zn, Al, K, Ca, Sr, Na, Ba, Mg, Li),
Iodates (Zn, Al, K, Ca, Sr, Na, Ba,
Mg, Li), chlorite (Zn, Ca, K, Na,
Ba), hypochlorite (Li, Na, K, Ca, Sr,
Examples include Ba), bromite (Na, K, Ca, Ba), etc. Naturally, these may be hydrated salts. The amount of halogen oxyacid added above is for chlorine-containing resin.
0.001 to 3 parts by weight per 100 parts by weight, preferably
It is 0.01 to 2 parts by weight. When the composition of the present invention is further combined with an organic phosphite compound and/or an epoxy compound, an excellent synergistic effect is exhibited. Examples of organic phosphite compounds that can be used in the present invention include diphenyldecyl phosphite, triphenyl phosphite, tris-nonylphenyl phosphite, tridecyl phosphite, tris(2-ethylhexyl) phosphite, tributyl phosphite, and dilauryl acid. Phosphite, dibutyl acid phosphite, tris(dinonylphenyl) phosphite, trilauryl trithiophosphite, trilauryl phosphite,
Bis(neopentyl glycol)-1,4-cyclohexane dimethyl phosphite, distearyl pentaerythritol diphosphite, diisodecyl pentaerythritol diphosphite, diphenyl acid phosphite, tris(lauryl-
2-thioethyl) phosphite, tetratridecyl-1,1,3-tris(2'-methyl-5'-tertiary)
Butyl-4'-oxyphenyl)butane diphosphite, tetra( C12 - C15 mixed alkyl)4,4'-
Isopropylidene diphenyl diphosphite, tris(4-oxy-2,5-di-tert-butylphenyl) phosphite, tris(4-oxy-3,
5-di-tert-butylphenyl) phosphite, 2
-Ethylhexyl diphenyl phosphite, tris(mono-, di-mixed nonylphenyl) phosphite, hydrogenated-4,4'-isopropylidene diphenol polyphosphite, diphenyl bis[4,
4'-n-butylidene bis(2-tert-butyl-5-
methylphenol)] thiodiethanol diphosphite, bis(octylphenyl) bis[4,
4'-n-butylidene bis(2-tert-butyl-5-
methylphenol)]-1,6-hexanediol diphosphite, phenyl-4,4'-isopropylidene diphenol pentaerythritol diphosphite, phenyl diisodecyl phosphite, tetratridecyl-4,4'-n- Butylidene bis(2-tert-butyl-5-methylphenol)
Examples include diphosphite, tris(2,4-di-tert-butylphenyl) phosphite, and the like. The amount of these organic phosphite compounds added is
0.01 to 5 parts by weight per 100 parts by weight, preferably
It is 0.1 to 3 parts by weight. Epoxy compounds that can be used in the present invention include:
Epoxidized soybean oil, epoxidized linseed oil, epoxidized fish oil, epoxidized tall oil fatty acid ester,
Epoxidized tallow oil, epoxidized polybutadiene,
Epoxy methyl stearate, -butyl, -2 ethylhexyl, -stearyl, tris(epoxypropyl) isocyanurate, epoxidized castor oil, epoxidized safflower oil, epoxidized linseed oil butyl fatty acid, 3-(2-xenoxy)-1 ,
Examples include 2-epoxypropane, bisphenol-A diglycidyl ether, vinylcyclohexene diepoxide, dicyclopentadiene diepoxide, and 3,4-epoxycyclohexyl-6-methylepoxycyclohexane carboxylate. The amount of these epoxy compounds added is 0.01 to 10 parts by weight, preferably 0.5 to 5 parts by weight, per 100 parts by weight of the resin.
Parts by weight. The polymer composition of the present invention may contain a phthalate plasticizer or other ester plasticizer, a polyester plasticizer, a phosphate plasticizer, a chlorine plasticizer, or other plasticizer depending on the purpose. Can be used as appropriate. Adding an antioxidant to the polymer composition of the present invention can increase the oxidative deterioration prevention properties of the polymer composition, so it can be used as appropriate depending on the purpose of use.
These antioxidants include phenolic antioxidants, sulfur-containing compounds, and the like. If an ultraviolet absorber is added to the polymer composition of the present invention, the photostability can be improved, so it is possible to appropriately select and use these depending on the purpose of use. These include benzophenones, benzotriazoles, salicylates, substituted acrylonitriles, various metal salts or metal chelates,
In particular, nickel or chromium salts or chelates, triazine type, piperidine type, etc. are included. Furthermore, in order to obtain a non-toxic chlorine-containing polymer, a non-toxic chlorine-containing polymer composition that is non-toxic and has good thermal stability can be obtained by selecting a non-toxic one from among the commonly used metal soaps mentioned above. can get. In addition, as necessary, for example, crosslinking agents, pigments, fillers, foaming agents, antistatic agents, antifogging agents, plate-out prevention agents, surface treatment agents, lubricants, flame retardants, fluorescent agents, antifungal agents, bactericidal agents, metal deactivators, photodegradants,
Processing aids, mold release agents, reinforcing agents, etc. can be included. Examples of the chlorine-containing polymer used in the present invention include the following. For example, polyvinyl chloride, polyvinylidene chloride, chlorinated polyethylene, chlorinated polypropylene, chlorinated rubber, vinyl chloride-vinyl acetate copolymer, vinyl chloride-ethylene copolymer, vinyl chloride-propylene copolymer, vinyl chloride-styrene Copolymer, vinyl chloride-isobutylene copolymer, vinyl chloride-vinylidene chloride copolymer, vinyl chloride-styrene-maleic anhydride terpolymer, vinyl chloride-styrene-acrylonitrile copolymer, vinyl chloride-butadiene copolymer Polymer, vinyl chloride-isoprene copolymer, vinyl chloride-chlorinated propylene copolymer, vinyl chloride-vinylidene chloride-vinyl acetate terpolymer, vinyl chloride-acrylic acid ester copolymer, vinyl chloride-maleic acid Ester copolymer, vinyl chloride-methacrylic acid ester copolymer, vinyl chloride
Chlorine-containing synthetic resins such as acrylonitrile copolymers and internally plasticized polyvinyl chloride, and the above chlorine-containing resins and α-olefin polymers such as polyethylene, polypropylene, polybutene, and poly-3-methylbutene, or ethylene-vinyl acetate copolymers; Polyolefins such as ethylene-propylene copolymers and their copolymers, polystyrene, acrylic resins, copolymers of styrene and other monomers (e.g. maleic anhydride, butadiene, acrylonitrile, etc.), acrylonitrile-butadiene-styrene Copolymer, acrylic ester - butadiene-styrene copolymer, methacrylic ester -
Examples include blended products with butadiene-styrene copolymers. The following examples show the effects of the chlorine resin composition according to the present invention, but the present invention is not limited by these examples. Example 1 The following composition was roll-kneaded and then pressed to produce a sheet with a thickness of 1 mm. Using this sheet, initial colorability, transparency, and thermal stability at 190°C were examined. The results are shown in Table 1. <Composition> Polyvinyl chloride resin 100 parts by weight Epoxidized linseed oil 2.0 Zinc stearate 0.5 Barium stearate 1.0 Barium perchlorate 0.1 Polyhydric alcohols (Table 1) 0.2
【表】
実施例 2
次の配合物を用いて、実施例1と同様にして厚
さ1mmのシートを作成し、120℃及び190℃での熱
安定性及び120℃、382時間劣化後の伸びを測定し
た。その結果を第2表に示す。
<配 合>
ポリ塩化ビニル樹脂 50 重量部
ABS樹脂 50
NBR 10
エポキシ化大豆油 10
テトラ(C12〜15混合アルキル)ビスフエノール
A・ジホスフアイト 1.0
ステアリン酸バリウム 1.0
ラウリン酸亜鉛 0.5
過塩素酸バリウム 0.2
多価アルコール類(第2表) 0.2 [Table] Example 2 A sheet with a thickness of 1 mm was prepared in the same manner as in Example 1 using the following formulation, and the thermal stability at 120°C and 190°C and the elongation after aging at 120°C for 382 hours were determined. was measured. The results are shown in Table 2. <Composition> Polyvinyl chloride resin 50 parts by weight ABS resin 50 NBR 10 Epoxidized soybean oil 10 Tetra (C 12-15 mixed alkyl) bisphenol A diphosphite 1.0 Barium stearate 1.0 Zinc laurate 0.5 Barium perchlorate 0.2 Poly Alcohols (Table 2) 0.2
【表】【table】
【表】
実施例 3
次の配合物を用いて、実施例1と同様にして厚
さ1mmのシートを作成し、175℃における熱老化
試験を行なつた。その結果を第3表に示す。
<配 合>
ポリ塩化ビニル樹脂 100 重量部
ジオクチルフタレート 50
エポキシ化大豆油 1.0
ノニルフエノール・バリウム塩 1.0
ネオデカン酸亜鉛 0.5
ビス(ジペンタエリスリトール)・アジペート
0.3
ハロゲン酸素酸塩(第3表) 0.1 [Table] Example 3 A sheet with a thickness of 1 mm was prepared in the same manner as in Example 1 using the following formulation, and a heat aging test at 175°C was conducted. The results are shown in Table 3. <Composition> Polyvinyl chloride resin 100 parts by weight Dioctyl phthalate 50 Epoxidized soybean oil 1.0 Nonylphenol barium salt 1.0 Zinc neodecanoate 0.5 Bis(dipentaerythritol) adipate
0.3 Oxygen halogen acid salts (Table 3) 0.1
【表】
実施例 4
本発明組成物に有機ホスフアイト化合物を併用
した場合には、より一層の安定化効果が得られ
た。次の配合物を用いて実施例1と同様な方法に
よりその効果を調べた。その結果を第4表に示
す。
<配 合>
ポリ塩化ビニル樹脂 100 重量部
ジオクチルフタレート 50
エポキシ化大豆油 1.0
オクチル酸亜鉛 0.5
ステアリン酸バリウム 0.5
ビス(ジペンタエリスリトール)・アジペート
0.2
過塩素酸バリウム 0.05
有機ホスフアイト化合物(第4表)
0.2 [Table] Example 4 When an organic phosphite compound was used in combination with the composition of the present invention, a further stabilizing effect was obtained. The effects were investigated in the same manner as in Example 1 using the following formulations. The results are shown in Table 4. <Composition> Polyvinyl chloride resin 100 parts by weight Dioctyl phthalate 50 Epoxidized soybean oil 1.0 Zinc octylate 0.5 Barium stearate 0.5 Bis(dipentaerythritol) adipate
0.2 Barium perchlorate 0.05 Organic phosphite compounds (Table 4)
0.2
【表】【table】
【表】
実施例 5
本発明組成物に他の位定化助剤を併用した場合
の効果を調べるため、次の配合物を用いて実施例
1と同様にして厚さ1mmのシートを作成し、180
℃における熱安定性試験を行なつた。その結果を
第5表に示す。
<配 合>
ポリ塩化ビニル樹脂 100 重量部
エポキシ化大豆油 5
ステアリン酸マグネシウム 0.2
ステアリン酸カルシウム 0.5
ステアリン酸亜鉛 0.5
ビス(ジペンタエリスリトール)・アジペート
0.1
過塩素酸バリウム 0.1
他安定化助剤(第5表) (第5表) [Table] Example 5 In order to investigate the effect of using the composition of the present invention together with other positioning aids, a sheet with a thickness of 1 mm was prepared in the same manner as in Example 1 using the following formulation. , 180
A thermal stability test at ℃ was conducted. The results are shown in Table 5. <Composition> Polyvinyl chloride resin 100 parts by weight Epoxidized soybean oil 5 Magnesium stearate 0.2 Calcium stearate 0.5 Zinc stearate 0.5 Bis(dipentaerythritol) adipate
0.1 Barium perchlorate 0.1 Other stabilizing aids (Table 5) (Table 5)
Claims (1)
一種、(b)多価アルコールのカルボン酸部分エステ
ルの少なくとも一種及び(c)ハロゲン酸素酸の金属
塩類の少なくとも一種を添加して成る安定化され
た塩素含有樹脂組成物。1 Stable product made by adding (a) at least one metal salt of an organic acid, (b) at least one carboxylic acid partial ester of a polyhydric alcohol, and (c) at least one metal salt of a halogen oxygen acid to a chlorine-containing resin. chlorine-containing resin composition.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1056682A JPS58127751A (en) | 1982-01-26 | 1982-01-26 | Stabilized halogen-containing resin composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1056682A JPS58127751A (en) | 1982-01-26 | 1982-01-26 | Stabilized halogen-containing resin composition |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS58127751A JPS58127751A (en) | 1983-07-29 |
JPS6330938B2 true JPS6330938B2 (en) | 1988-06-21 |
Family
ID=11753792
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP1056682A Granted JPS58127751A (en) | 1982-01-26 | 1982-01-26 | Stabilized halogen-containing resin composition |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS58127751A (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6094441A (en) * | 1983-10-28 | 1985-05-27 | Nissan Fuero Yuki Kagaku Kk | Stabilized halogen-containing resin composition |
JPS624739A (en) * | 1985-07-02 | 1987-01-10 | Kanegafuchi Chem Ind Co Ltd | Rigid transparent vinyl chloride resin composition hardly causing whitening |
JPH0696657B2 (en) * | 1986-04-25 | 1994-11-30 | 勝田化工株式会社 | Polyvinyl chloride resin composition |
-
1982
- 1982-01-26 JP JP1056682A patent/JPS58127751A/en active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS58127751A (en) | 1983-07-29 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JPS5836012B2 (en) | Halogen-containing resin composition | |
EP2599830B1 (en) | Vinyl-chloride-based resin composition for transparent product | |
JPH0227376B2 (en) | ||
CN111684042A (en) | Stabilizer composition, vinyl chloride resin composition containing same, and molded article thereof | |
JP3018199B2 (en) | Stabilized chlorine-containing resin composition | |
JP5530104B2 (en) | Vinyl chloride resin composition | |
JP2012021122A (en) | Vinyl chloride-based resin composition | |
JPS6330938B2 (en) | ||
JPS6234271B2 (en) | ||
JPS6234346B2 (en) | ||
JPH0816183B2 (en) | Stabilizer for chlorine-containing resin | |
JP5036289B2 (en) | Vinyl chloride resin composition | |
JP3122165B2 (en) | Agricultural vinyl chloride resin composition | |
JPH0562131B2 (en) | ||
JP2009167289A (en) | Nonfoamable vinylchloride resin composition | |
JPH0135015B2 (en) | ||
JPH0228614B2 (en) | ||
JPS6234062B2 (en) | ||
JPH04216845A (en) | Vinyl chloride resin composition | |
JP2980727B2 (en) | Stabilized chlorine-containing resin composition | |
JPH0552856B2 (en) | ||
JPS6234063B2 (en) | ||
JPS6333499B2 (en) | ||
JP3534918B2 (en) | Stabilized chlorine-containing resin composition | |
JPS63152654A (en) | Chlorine-containing resin composition |