JPH04173204A - Preparation of reinforced inorganic molding - Google Patents

Preparation of reinforced inorganic molding

Info

Publication number
JPH04173204A
JPH04173204A JP29977790A JP29977790A JPH04173204A JP H04173204 A JPH04173204 A JP H04173204A JP 29977790 A JP29977790 A JP 29977790A JP 29977790 A JP29977790 A JP 29977790A JP H04173204 A JPH04173204 A JP H04173204A
Authority
JP
Japan
Prior art keywords
molding
inorg
molded body
viscosity
reinforced
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP29977790A
Other languages
Japanese (ja)
Other versions
JP2971555B2 (en
Inventor
Kenji Morohashi
諸橋 健二
Hiroshi Murakami
村上 弘史
Masafumi Fuji
雅史 藤
Yukio Akimoto
幸男 秋元
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
A&A Material Corp
Original Assignee
Ask Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ask Corp filed Critical Ask Corp
Priority to JP29977790A priority Critical patent/JP2971555B2/en
Publication of JPH04173204A publication Critical patent/JPH04173204A/en
Application granted granted Critical
Publication of JP2971555B2 publication Critical patent/JP2971555B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Laminated Bodies (AREA)
  • Press-Shaping Or Shaping Using Conveyers (AREA)
  • Devices For Post-Treatments, Processing, Supply, Discharge, And Other Processes (AREA)

Abstract

PURPOSE:To attempt to improve bending strength of a molded body consisting of an inorg. material by a method wherein when processing and molding are performed, a reinforcing member and a kneaded product are laminated through an adhesive material with a viscosity of a specified value to prepare a reinforced inorg. molding. CONSTITUTION:A kneaded product consisting of a hydraulic inorg. compsn. is processed and molded by using a mold to prepare an inorg. molding and when processing and molding are performed, a reinforcing member and the kneaded product are laminated through an adhesive material with a viscosity of 1,000-200,000cps to prepare a reinforced inorg. molding. When the viscosity is smaller than 1,000cps, it flows with a filtrate during molding or it permeates to the inorg. kneaded material side. For example, a kneaded product 10 consisting of a hydraulic inorg. compsn. is obtd. and after a reinforcing material 11 is coated with an adhesive material to form an adhesive layer 12, it is placed in a mold 13 and the kneaded product 10 is fed therein and press molding is performed. The first curing and the second curing are performed and then, drying is done to obtain a reinforced inorg. molding 14.

Description

【発明の詳細な説明】 〈産業上の利用分野〉 本発明は無機材料からなる成形体の曲げ強度の向上を図
った補強無機質成形体の製造方法に関する。
DETAILED DESCRIPTION OF THE INVENTION <Industrial Field of Application> The present invention relates to a method for producing a reinforced inorganic molded body that improves the bending strength of the molded body made of an inorganic material.

〈従来の技術〉 従来より、セメント等からなる無機質成形体は抄造法、
押出成形法、プレスモールド法及びキャスティング法な
どの製造法によって目的に応して製造されているが、こ
の無機質成形体は床材等の用途によっては高い耐圧性が
要求されるが、補強材を併用しないと、充分な強度が得
られないという問題がある。
<Conventional technology> Conventionally, inorganic molded bodies made of cement, etc. have been produced using the papermaking method,
This inorganic molded body is manufactured according to the purpose using manufacturing methods such as extrusion molding, press molding, and casting, but high pressure resistance is required for some applications such as flooring, but reinforcing materials are not required. If they are not used together, there is a problem that sufficient strength cannot be obtained.

そこで、従来においては成形体の製造時に、成形体中に
繊維(短繊維や長繊維)を混入させたり、金属のネット
(金網)や合成繊維のネット又は鉄板等の板材を用いて
補強したり、あるいは異種材料を積層させたりして補強
するようにしている。
Therefore, in the past, when manufacturing a molded object, fibers (short fibers or long fibers) were mixed into the molded object, or reinforcement was made using a metal net (wire mesh), a synthetic fiber net, or a plate material such as an iron plate. Or, they are reinforced by laminating different materials.

〈発明が解決しようとする課題〉 ところで、前述した従来例に係る成形体において、金網
等のネット状物あるいは鉄板等の板材を用い、該板材と
無機質成形体とから積層体を製造して、例えば床材とし
て使用する場合、第4図に示すように、ある応力の限界
を超えるとマトリクスの一部破壊や積層体の剥離が生じ
てしまい、実用上の耐久性に問題がある。
<Problems to be Solved by the Invention> By the way, in the molded body according to the conventional example described above, a laminate is manufactured from the plate material and the inorganic molded body using a net-like material such as a wire mesh or a plate material such as an iron plate, For example, when used as a flooring material, as shown in FIG. 4, if a certain stress limit is exceeded, part of the matrix will break or the laminate will peel off, which poses a problem in practical durability.

これは特に、板材として亜鉛鉄板等を用いる場合に、こ
の現象は顕著となる。このため、亜鉛鉄板等の板材の表
面に爪立て加工して剥離を防止しようとしているが、更
なる効果は発現されないという問題がある。
This phenomenon becomes particularly noticeable when a galvanized iron plate or the like is used as the plate material. For this reason, attempts have been made to prevent peeling by applying nail polishing to the surface of a plate material such as a galvanized iron plate, but there is a problem in that no further effect is achieved.

本発明は以上述へた事情に鑑み、無機材料からなる成形
体の曲げ強度の向上を図った補強無機質成形体の製造方
法を提供することを目的とする。
In view of the above-mentioned circumstances, it is an object of the present invention to provide a method for manufacturing a reinforced inorganic molded body that improves the bending strength of a molded body made of an inorganic material.

〈課題を解決するための手段〉 前記目的を達成するための本発明に係る補強無機質成形
体の製造方法の構成は、水硬性無機質組成物からなる混
練物を成形用型を用いて加圧成形して無機質成形体を製
造する方法において、該加圧成形時に、粘度1000〜
200.000 cpsの粘性を有する接着材料を介し
て、補強部材と上記混練物とを積層させて、補強無機質
成形体を製造することを特徴とする。
<Means for Solving the Problems> The method for producing a reinforced inorganic molded body according to the present invention to achieve the above object is configured by press-molding a kneaded material of a hydraulic inorganic composition using a mold. In the method for producing an inorganic molded body, the viscosity is 1000 to 1,000 during the pressure molding.
The reinforcing member and the kneaded material are laminated via an adhesive material having a viscosity of 200.000 cps to produce a reinforced inorganic molded body.

以下、本発明の詳細な説明する。The present invention will be explained in detail below.

ここで、本発明で無機質成形体とは、一般にセメント、
石こう等を主原料とし、その他ケイ酸質原利2石灰質原
料、補強材、骨材等の種々の窯業材料及び減水剤、増粘
剤等の添加剤を目的により適宜配合した水硬性無機質組
成物を、抄造法、押出成形法、半乾式成形法等により成
形した材料や混練した材料を直接成形用型を用いて加圧
成形するものをいい、その後養生硬化させて例えば床材
、外壁材。
Here, in the present invention, the inorganic molded body generally refers to cement,
A hydraulic inorganic composition whose main raw material is gypsum, and various ceramic materials such as siliceous raw materials, reinforcing materials, aggregates, etc., and additives such as water reducing agents and thickeners as appropriate for the purpose. refers to materials molded or kneaded by papermaking methods, extrusion molding methods, semi-dry molding methods, etc., which are pressure-molded using direct molding molds, and then cured and hardened to produce, for example, flooring and exterior wall materials.

内装材等に用いられるものをいう。Refers to materials used for interior materials, etc.

本発明で混線物とは、上記水硬性無機質組成物に、目的
に応じて適量の水を加えて、混合又は混練して得られた
ものであって、種々の成形方法により賦形されるものを
いう。
In the present invention, the mixed material is a material obtained by adding an appropriate amount of water depending on the purpose to the above-mentioned hydraulic inorganic composition, mixing or kneading it, and shaping it by various molding methods. means.

本発明で成形用型とは、セメント、石こう等を主原料と
する水硬性無機質組成物を混合又は混練して得られた混
練物を、板状に一次成形した生板、あるいは混練物を直
接所定形状の型づけや模様づけを施すもので、例えばモ
ールドプレス法や平プレス法やロールプレス法等の窯業
材料での加圧成形法で用いられるものをいう。
In the present invention, the molding mold refers to a green plate obtained by primarily forming a kneaded material obtained by mixing or kneading a hydraulic inorganic composition whose main raw materials are cement, gypsum, etc. It refers to a device that is molded into a predetermined shape or patterned, and is used, for example, in pressure molding methods for ceramic materials, such as mold press method, flat press method, and roll press method.

また、本発明で接着材料とは、合成樹脂系。Further, in the present invention, the adhesive material is a synthetic resin type.

合成ゴム系、混合系等の有機合成系接着剤をいう。合成
樹脂系接着剤の代表的なものとしては、例えばポリウレ
ンタン、ポリビニル等の熱可塑性接着剤及び例えばエポ
キシ、シリコン等の熱硬化性接着剤を挙げることができ
る。合成ゴム系接着剤の代表例としてはCR。
Refers to organic synthetic adhesives such as synthetic rubber adhesives and mixed adhesives. Typical synthetic resin adhesives include thermoplastic adhesives such as polyurethane and polyvinyl, and thermosetting adhesives such as epoxy and silicone. A typical example of synthetic rubber adhesive is CR.

NBR等を挙げることができる。また混合系接着剤の代
表例としてはフェノリック−NBR。
NBR etc. can be mentioned. A typical example of a mixed adhesive is phenolic-NBR.

フェノリック−CR,エポキシ−NBR4を挙げる乙と
がてきる。
Here comes the list of phenolic-CR and epoxy-NBR4.

との接着材料の粘度は、1000〜200.000cp
s(20℃)、より好ましくは1400〜50000 
cps (20℃)の範囲が適当である。
The viscosity of the adhesive material with
s (20°C), more preferably 1400 to 50000
cps (20°C) is suitable.

これは1000 Cps未満の粘性の低い場合には、成
形時の炉液と共に流れ出てしまったり、無機質混線材料
側に浸透してしまったり、又は混線材料投入時に原料の
フローと共に流れ出てしまったりして、接着力が発揮せ
ず、好ましくないからである。また、200.000 
cpsを超えた粘度の高い場合には、塗布等の作業性に
劣り実用的でなく、好ましくないからである。
If the viscosity is low (less than 1000 Cps), it may flow out with the furnace liquid during molding, penetrate into the inorganic mixed material, or flow out with the flow of raw materials when the mixed material is input. This is because adhesive strength is not exhibited, which is not preferable. Also, 200.000
This is because when the viscosity is high, exceeding cps, the workability of coating etc. is poor and it is not practical and is not preferred.

この接着材料を介して補強部材と混練物とを積層させる
には、補強部材に接着材料を塗布した接着層を形成した
ものを、成形用型内に設置し、その後混練物又は生板を
投入して加圧するようにすればよい。
In order to laminate the reinforcing member and the kneaded material via this adhesive material, the reinforcing member is coated with an adhesive material to form an adhesive layer, and then placed in a mold, and then the kneaded material or green plate is introduced. All you have to do is pressurize it.

上記補強部材に接着材料を塗布して接着層を形成する方
法としては、ロール法、スプレー法、含浸法等の公知の
処理手段を挙げることができる。
As a method for forming an adhesive layer by applying an adhesive material to the reinforcing member, known processing methods such as a roll method, a spray method, and an impregnation method can be used.

また、接着層を形成する工程は加圧成形工程と同時に行
ってその度、接着層を補強部材に施す方法や、別工程で
、あらかしめ接着層を施した補強部材を別に用意して、
加圧成形工程にその度供給する方法など、いずれを用い
てもよい。尚、後者の場合は、加工工程は増えるが接着
材料の粘度は1000cps以下であっても良好な接着
状態を得ることも可能である。
In addition, the process of forming the adhesive layer may be performed at the same time as the pressure molding process, and the adhesive layer may be applied to the reinforcing member each time, or the reinforcing member may be separately prepared with a roughened adhesive layer applied in a separate process.
Any method may be used, such as a method of supplying the material to the pressure molding process each time. In the latter case, although the number of processing steps increases, it is possible to obtain a good adhesive state even if the viscosity of the adhesive material is 1000 cps or less.

上記混練物と接着材料を介して積層される補強部材とし
ては、亜鉛鉄板、鋼板等の平板材や網状材等をいい、平
板材に穴明板を使用すれば、混練物の含水分が多いもの
でも、成形時に混練物からの脱水が容易となり、成形効
率の向上が得られたり、反対側の成形体の表面に平滑性
を付与したり、あるい(よプレス型に模様を施しておけ
ば、成形体の表面に模様を施すことも可能となる。
The reinforcing member to be laminated with the above-mentioned kneaded material via the adhesive material is a flat plate material such as a galvanized iron plate or a steel plate, or a net-like material. Even if the material is molded, water can be easily removed from the kneaded material during molding, improving molding efficiency. For example, it becomes possible to apply a pattern to the surface of the molded body.

加圧成形後の接着材料が硬化した後の該接着層の硬度は
、ゴム硬度計(JISAタイプ■)チクロック社製)を
用いて測定し、20゜以上が適当である。これは、該硬
度は、混線物の板材に加わる応力を補強部材側に伝播す
るのに充分な硬度を必要とするためであり、20°未満
と軟かすぎると、無機質硬化体と補強部材との間(接着
層)てせん断応力のため、剥離が生じて補強効果が発揮
されず好ましくないからである。
The hardness of the adhesive layer after the pressure-molded adhesive material is cured is measured using a rubber hardness meter (JISA type ■, manufactured by Chiklok Co., Ltd.), and is suitably 20° or more. This is because the hardness must be sufficient to propagate the stress applied to the plate material of the crosstalk to the reinforcing member, and if it is too soft (less than 20°), the inorganic hardened material and the reinforcing member This is because peeling occurs due to shear stress between the layers (adhesive layer) and the reinforcing effect is not exhibited, which is not preferable.

本発明;こ係る補強無機質成形体の製造例の一例を第1
図を参照して息下に説明する。
The present invention; an example of manufacturing such a reinforced inorganic molded body is shown in the first example.
This will be explained in detail with reference to the diagram.

■ 水硬性無機質組成分(セメント、パーライト、補強
繊維、水)からなる混練物10を得る。
(2) A kneaded material 10 consisting of hydraulic inorganic components (cement, perlite, reinforcing fibers, water) is obtained.

■ 補強部材11に、接着材料塗布し、接着層12を形
成した後、成形用型13内に設置する。
(2) After applying an adhesive material to the reinforcing member 11 and forming an adhesive layer 12, the reinforcing member 11 is placed in a mold 13.

■ 次いて、成形用型13内に上記混練物を投入し、プ
レス成型する。
(2) Next, the kneaded material is put into the mold 13 and press-molded.

■ −次養生、二次養生を行った後、乾燥させて、補強
無機質成形体14を得る。
(2) After performing the second curing and second curing, the reinforced inorganic molded body 14 is obtained by drying.

得られた補強無機質成形体は、耐荷重が医れているため
、床材等の大きな力がかかる部材として用いても、耐久
性に冨み、長期間安定して使用することができる。
The obtained reinforced inorganic molded product has a high load capacity, so even if it is used as a member such as a flooring material that is subjected to a large force, it is highly durable and can be used stably for a long period of time.

く実 施 例〉 以下、本発明の好適な一実施例を説明する。Example of implementation A preferred embodiment of the present invention will be described below.

下記配合(第1表下欄*3)の水硬性無機質組成物から
なる混練物と、第1表中に示す各種接着材料(a)〜(
1)を塗布した補強部材(亜鉛ひき鋼板;厚さ0.3m
m) とを、第1図に示したのと同様にして、成形用型
に投入し、プレス成型(:1.Ocm X 20 cm
、  t = 10 m/m 、圧力50kg/cイ)
した。成形体(比重1.4)を得た後、−次養生(スチ
ーム養生、60℃、8時間)し、次いて二次養生(20
℃、1週間)行い、105℃で24時間乾燥した。
A kneaded product consisting of a hydraulic inorganic composition of the following formulation (lower column of Table 1 *3) and various adhesive materials (a) to (
1) Reinforcement member (galvanized steel plate; thickness 0.3m)
m) were put into a mold in the same manner as shown in Fig. 1, and press molded (: 1.Ocm x 20cm).
, t = 10 m/m, pressure 50 kg/c)
did. After obtaining a molded body (specific gravity 1.4), it was subjected to second curing (steam curing, 60°C, 8 hours), and then second curing (20
°C for 1 week) and dried at 105 °C for 24 hours.

その後、得られた補強無機質成形体の曲げ試験を行った
Thereafter, the obtained reinforced inorganic molded body was subjected to a bending test.

尚、比較例として従来例(■補強部材を用いないもの、
■成形体に石綿を混入したもの、■亜鉛ひき鋼板て接着
なしのもの、■爪立て亜鉛鉄板を用いて補強したもの)
の成形体を作製し、同様にして試験を行った。
In addition, as a comparative example, conventional examples (■ those that do not use reinforcing members,
■Those with asbestos mixed into the molded body; ■Those made from galvanized steel sheets without adhesive; ■Those reinforced using galvanized steel sheets)
A molded article was prepared and tested in the same manner.

曲げ試験はスパン15cm、2線支持の中央一線荷重法
で行った。
The bending test was conducted with a span of 15 cm and a central single-line loading method with two-wire support.

これらの結果を第1表に示す。These results are shown in Table 1.

次に応用例として、セメント(99wt%)と有機合成
繊維(1wt%)の無機質組成物から成る混練物と、第
1表Fd)に示す接着材料を塗布した亜鉛鉄板とを、プ
レス成型(50X 50cm、  t = 2cm、圧
力50 kg/cn?) シた。
Next, as an application example, press molding (50X 50cm, t = 2cm, pressure 50 kg/cn?) Shita.

成形体(比重1.9)を得た後、上記と同様に養生、乾
燥し、供試体とした。
After obtaining a molded body (specific gravity: 1.9), it was cured and dried in the same manner as above to obtain a specimen.

なお、比較例として■補強部材を用いないもの■亜鉛鉄
板で接着剤なしのもの■爪立て亜鉛鉄板を用いて接着剤
なしのものの供試体を作製した。
As comparative examples, specimens were prepared: (1) without a reinforcing member; (2) A galvanized iron plate without adhesive; and (3) A nail holder without adhesive.

これら得られた供試体の集中圧縮荷重試験は、第2図に
示す4つの支持部材20て成形体21を支持し、中央に
おもり(φ50mm)22を載置して行う4点支持・中
央載荷法を行った。
The concentrated compressive load test of the obtained specimens was carried out by four-point support and central loading, in which the molded body 21 was supported by four support members 20 shown in Fig. 2, and a weight (φ50 mm) 22 was placed in the center. practiced law.

これらの結果を第3図に示す。These results are shown in FIG.

尚接着部材の粘度は、東京計器■製のB型粘度計を用い
た。
The viscosity of the adhesive member was measured using a B-type viscometer manufactured by Tokyo Keiki ■.

第1表 *1(a)〜(glエポキシ系(コニシ社製、セメダイ
ン社製及びカネボウNSC社製) 、 (b)ゴム系(
漬水化学工業社製)、 (i)ウレタン系(コニシ社製
)*2 石綿(クリソタイル石綿6クラス)15%添加
品(セメントと置換) *3 ・セメント84wt% ・パーライト15wt% ・有機合成繊維1 w t% これらの結果から明らかなように、粘度1000〜16
0. OOOcpsの接着材料を用いてマトリックスと
補強部材とを接合させることにより、密着性が向上し、
補強力の向上が図れた。
Table 1 *1 (a) ~ (GL epoxy type (manufactured by Konishi, Cemedine, and Kanebo NSC), (b) Rubber type (
(manufactured by Tsukumi Kagaku Kogyo Co., Ltd.), (i) Urethane-based (manufactured by Konishi Co., Ltd.) *2 Asbestos (class 6 chrysotile asbestos) 15% additive (replacement with cement) *3 ・Cement 84wt% ・Perlite 15wt% ・Organic synthetic fiber 1 wt% As is clear from these results, the viscosity is 1000-16
0. By joining the matrix and reinforcing member using OOOcps adhesive material, adhesion is improved,
The reinforcing force was improved.

〈発明の効果〉 本発明は以上実施例と共に述べたように、本発明によれ
ば、粘度1000〜200.0GOcpsの粘性を有す
る接着材料を介して、補強部材と混練物を積層させて曲
げ強度の高い補強無機質成形体を提供する乙とができる
<Effects of the Invention> As described above in conjunction with the embodiments, according to the present invention, the reinforcing member and the kneaded material are laminated via an adhesive material having a viscosity of 1000 to 200.0 GOcps to increase the bending strength. It is possible to provide a highly reinforced inorganic molded body.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は補強無機質成形体の製造工程図、第2図は集中
圧縮荷重試験の概略図、第3図、第4図は各々成形体の
集中荷重とたわみとの関係を示すグラフである。 図面中、 10は混練物、11は補強部材、12は接着層、13は
成形用型、14は無機質成形体である。 =11− \7                       
uQ            −0
FIG. 1 is a manufacturing process diagram of a reinforced inorganic molded body, FIG. 2 is a schematic diagram of a concentrated compressive load test, and FIGS. 3 and 4 are graphs showing the relationship between concentrated load and deflection of a molded body. In the drawings, 10 is a kneaded material, 11 is a reinforcing member, 12 is an adhesive layer, 13 is a mold, and 14 is an inorganic molded body. =11-\7
uQ −0

Claims (1)

【特許請求の範囲】 水硬性無機質組成物からなる混練物を成形用型を用いて
加圧成形して無機質成形体を製造する方法において、 該加圧成形時に、粘度1000〜200,000cps
の粘性を有する接着材料を介して、補強部材と上記混練
物とを積層させて、補強無機質成形体を製造することを
特徴とする補強無機質成形体の製造方法。
Scope of Claims: A method for producing an inorganic molded body by pressure-molding a kneaded material consisting of a hydraulic inorganic composition using a mold, wherein the viscosity is 1000 to 200,000 cps during the pressure molding.
1. A method for manufacturing a reinforced inorganic molded body, which comprises laminating a reinforcing member and the above-mentioned kneaded material via an adhesive material having a viscosity of .
JP29977790A 1990-11-07 1990-11-07 Method for producing reinforced inorganic molded article Expired - Fee Related JP2971555B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP29977790A JP2971555B2 (en) 1990-11-07 1990-11-07 Method for producing reinforced inorganic molded article

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP29977790A JP2971555B2 (en) 1990-11-07 1990-11-07 Method for producing reinforced inorganic molded article

Publications (2)

Publication Number Publication Date
JPH04173204A true JPH04173204A (en) 1992-06-19
JP2971555B2 JP2971555B2 (en) 1999-11-08

Family

ID=17876832

Family Applications (1)

Application Number Title Priority Date Filing Date
JP29977790A Expired - Fee Related JP2971555B2 (en) 1990-11-07 1990-11-07 Method for producing reinforced inorganic molded article

Country Status (1)

Country Link
JP (1) JP2971555B2 (en)

Also Published As

Publication number Publication date
JP2971555B2 (en) 1999-11-08

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