JPH04171384A - Composite layer rubber hose - Google Patents
Composite layer rubber hoseInfo
- Publication number
- JPH04171384A JPH04171384A JP29630590A JP29630590A JPH04171384A JP H04171384 A JPH04171384 A JP H04171384A JP 29630590 A JP29630590 A JP 29630590A JP 29630590 A JP29630590 A JP 29630590A JP H04171384 A JPH04171384 A JP H04171384A
- Authority
- JP
- Japan
- Prior art keywords
- rubber
- layer
- acrylic
- vulcanizate
- rubber layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920001971 elastomer Polymers 0.000 title claims abstract description 80
- 239000002131 composite material Substances 0.000 title 1
- 229920000800 acrylic rubber Polymers 0.000 claims abstract description 23
- 229920000058 polyacrylate Polymers 0.000 claims abstract description 23
- 238000004073 vulcanization Methods 0.000 claims abstract description 15
- 239000000203 mixture Substances 0.000 claims abstract description 8
- 239000011347 resin Substances 0.000 claims abstract description 6
- 229920005989 resin Polymers 0.000 claims abstract description 6
- MBBWTVUFIXOUBE-UHFFFAOYSA-L zinc;dicarbamodithioate Chemical compound [Zn+2].NC([S-])=S.NC([S-])=S MBBWTVUFIXOUBE-UHFFFAOYSA-L 0.000 claims description 5
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 claims description 2
- 229920005558 epichlorohydrin rubber Polymers 0.000 claims description 2
- 241000195940 Bryophyta Species 0.000 claims 1
- 235000011929 mousse Nutrition 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract description 5
- 238000002156 mixing Methods 0.000 abstract description 5
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 abstract description 4
- 230000006866 deterioration Effects 0.000 abstract description 4
- 238000005299 abrasion Methods 0.000 abstract description 2
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 abstract 3
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 abstract 2
- -1 dithiocarbamic acid zinc salt Chemical class 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- 238000009434 installation Methods 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 74
- 230000003014 reinforcing effect Effects 0.000 description 9
- 239000000446 fuel Substances 0.000 description 7
- 239000000853 adhesive Substances 0.000 description 6
- 230000001070 adhesive effect Effects 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 239000000463 material Substances 0.000 description 4
- 241000238557 Decapoda Species 0.000 description 3
- 239000002033 PVDF binder Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- XENVCRGQTABGKY-ZHACJKMWSA-N chlorohydrin Chemical compound CC#CC#CC#CC#C\C=C\C(Cl)CO XENVCRGQTABGKY-ZHACJKMWSA-N 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 239000011229 interlayer Substances 0.000 description 3
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- 230000003712 anti-aging effect Effects 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 239000012990 dithiocarbamate Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- STMDPCBYJCIZOD-UHFFFAOYSA-N 2-(2,4-dinitroanilino)-4-methylpentanoic acid Chemical compound CC(C)CC(C(O)=O)NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O STMDPCBYJCIZOD-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- REEBWSYYNPPSKV-UHFFFAOYSA-N 3-[(4-formylphenoxy)methyl]thiophene-2-carbonitrile Chemical compound C1=CC(C=O)=CC=C1OCC1=C(C#N)SC=C1 REEBWSYYNPPSKV-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 238000013040 rubber vulcanization Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
Landscapes
- Rigid Pipes And Flexible Pipes (AREA)
Abstract
Description
【発明の詳細な説明】
〈産業上の利用分野〉
本発明は、ゴムホースに関する。特に、燃料ホースに適
用した場合好適な発明である。DETAILED DESCRIPTION OF THE INVENTION <Industrial Application Field> The present invention relates to a rubber hose. This invention is particularly suitable when applied to fuel hoses.
以下の説明で配合単位は、特にことわらない限り、重量
単位である。In the following description, the compounding unit is a weight unit unless otherwise specified.
〈従来の技術〉
ここでは、燃料ホースを例に採り説明をするがこれに限
られるものではない。<Prior Art> Here, explanation will be given using a fuel hose as an example, but the invention is not limited to this.
上記タイプの燃料ホースとして、例えば、時開−昭６２
−５１４３９号公報で提案されているものがある゛（第
２図参照）。As the above type of fuel hose, for example,
There is one proposed in Publication No. 51439 (see Figure 2).
内面ゴム層１と外面ゴム層３と内面ゴム層ｌと外面ゴム
層３との間に介在する補強層５とからなる構成である。The structure includes an inner rubber layer 1, an outer rubber layer 3, and a reinforcing layer 5 interposed between the inner rubber layer 1 and the outer rubber layer 3.
そして、耐劣化ガソリン性等の見地から、内面ゴム層ｌ
を、アクリル系ゴムとフッ化ビニリデン樹脂（以下ｒＰ
ＶＤＦＪ ）とのブレンド物（以下ｒＡＦＲＪと略す、
）のゴム加硫物で、外面ゴム層３を耐ガス透過性・耐オ
ゾン性等の見地からエピクロロヒドリンゴム（以下単に
「ヒドリンゴム」と称す、）のゴム加硫物で形成した複
層ゴムホースが提案されている。From the standpoint of deterioration gasoline resistance, etc., the inner rubber layer l
, acrylic rubber and vinylidene fluoride resin (rP
VDFJ) (hereinafter abbreviated as rAFRJ)
), and the outer rubber layer 3 is formed from a rubber vulcanizate of epichlorohydrin rubber (hereinafter simply referred to as "hydrin rubber") from the viewpoint of gas permeability and ozone resistance. is proposed.
〈発明が解決しようどする課題〉
しかし、昨今、燃料ホースの高性能化の要求に伴ない、
上記内面ゴム層（ＡＰＲ層）１と外面ゴム層（ヒドリン
ゴム層）３との各ゴム加硫物の間により高い接着性が要
求されるようになってきた特に、内面ゴム層１、補強層
５、外面ゴム層３を略同時的にかつ連続的に同一部位で
成形するような連続成形法で成形するような場合（特開
昭５１−１００１６１号公報等参照）、接着剤を介在さ
せずに、加硫接着だけで一体化する必要があり、内面ゴ
ム層と外面ゴム層との間に高度の接着性を得がたかった
。<Problems to be solved by the invention> However, with the recent demand for higher performance fuel hoses,
Higher adhesion has become required between the rubber vulcanizates of the inner rubber layer (APR layer) 1 and the outer rubber layer (hydrin rubber layer) 3, especially the inner rubber layer 1 and the reinforcing layer 5. When the outer rubber layer 3 is molded by a continuous molding method in which the outer rubber layer 3 is molded substantially simultaneously and continuously at the same location (see Japanese Patent Application Laid-Open No. 100161/1989, etc.), it is possible to mold the outer rubber layer 3 without using an adhesive. , it was necessary to integrate them only by vulcanization adhesion, and it was difficult to obtain a high degree of adhesion between the inner rubber layer and the outer rubber layer.
〈課題を解決するための手段〉
そこで、ヒドリンゴム加硫物とＡＰＲ加硫物の双方に良
好な密着性を有する介在層を形成する材料を模索して、
特定加硫系のアクリルゴムで当該介在層を形成すればよ
いことを見出し、下記構成の複層ゴムホースに想到した
。<Means for solving the problem> Therefore, we searched for a material that forms an intervening layer that has good adhesion to both the hydrin rubber vulcanizate and the APR vulcanizate.
We discovered that the intervening layer could be formed from a specific vulcanized acrylic rubber, and came up with a multilayer rubber hose with the following configuration.
ＡＰＲ層とヒドリンゴム層とを具備するゴムホースにお
いて、これらの両層の間に介在層が、アクリルゴムで形
成され、該アクリルゴムの加硫系がジチオカルバミン酸
亜鉛（以下「ＰＺ」と略す、）とジチオカルバミン酸第
二鉄（以下ｒ ”Ｉ’ Ｔ ＦＥＪ）の併用系である、
ことを特徴とする。In a rubber hose comprising an APR layer and a hydrin rubber layer, an intervening layer between these two layers is formed of acrylic rubber, and the vulcanization system of the acrylic rubber is zinc dithiocarbamate (hereinafter abbreviated as "PZ"). It is a combination system of ferric dithiocarbamate (hereinafter referred to as "I' T FEJ"),
It is characterized by
く手段の詳細な説明〉
（１）本発明の複層ゴムホースは、ヒドリンゴムヒドリ
ンゴム層とＡＰＲゴム層とを具備するものならば、特に
限定されないが、例えば、燃料ホースに適用する場合、
従来と同様内面ゴム層１、補強層５及び外面ゴム層３と
を具備するが、さらに、本発明では、内面ゴム層１と外
面ゴム層３との間に実質的に両層を介在する中間ゴム層
７を具備する。なお、補強層５は、通常、合成繊維糸で
スパイラルにより形成され網目は粗である。Detailed Description of Means for Carrying Out the Effects> (1) The multilayer rubber hose of the present invention is not particularly limited as long as it includes a hydrin rubber layer and an APR rubber layer, but for example, when applied to a fuel hose,
Although the inner rubber layer 1, the reinforcing layer 5, and the outer rubber layer 3 are provided as in the conventional case, the present invention further includes an intermediate layer between the inner rubber layer 1 and the outer rubber layer 3, which substantially interposes both layers. A rubber layer 7 is provided. Note that the reinforcing layer 5 is usually formed of synthetic fiber yarn in a spiral manner and has a coarse mesh.
（２）上記内面ゴム層１は、ＡＰＲゴム加硫物で形成さ
れている。(2) The inner rubber layer 1 is formed of an APR rubber vulcanizate.
ここでＡＰＲとは、アクリルゴムとＰＶＤＦとを含有し
重量混合比が前者／後者＝９５１５〜４０／６０である
ブレンド物のことである。APR herein refers to a blend containing acrylic rubber and PVDF and having a weight mixing ratio of the former/latter = 9515 to 40/60.
■上記アクリルゴムには、アクリル酸アルキルエステル
と２−クロロエチルビニルエーテルとの共重合体でｒＡ
ＣＭＪの略号で示されるタイプ、および、アクリル酸ア
ルキルエステルとアクリロニトリルとの共重合体でｒＡ
ＮＭＪの略号で示されるタイプ、いずれのタイプのもの
も含まれる。■The above acrylic rubber is a copolymer of acrylic acid alkyl ester and 2-chloroethyl vinyl ether.
The type indicated by the abbreviation CMJ, and the copolymer of acrylic acid alkyl ester and acrylonitrile.
It includes any type indicated by the abbreviation NMJ.
耐寒性の見地からは、ＡＣＭが望ましい。From the viewpoint of cold resistance, ACM is preferable.
具体的には、前述の特開昭６２−５１４３９号公報に例
示されているもの、即ち、（ａ）アクリル酸アルキルエ
ステル及び／又はアクルル酸アルコキシ置換アルキルエ
ステル化合物３０〜９９．９％、（ｂ）架橋性子ツマ−
０，１〜ｌＯ％、および、（ｃ）前記（ａ） 、（ｂ）
と共重合可能な他のエチレン性化合物０〜７０％の重量
組成を有するものが使用可能である。上記架橋性モノマ
ーとしては、通常、アリルグリシジルヘーテル等のエポ
キシ基含有エチレン性不飽和化合物を使用する。Specifically, those exemplified in the above-mentioned JP-A No. 62-51439, namely (a) 30 to 99.9% of an acrylic acid alkyl ester and/or an acrylic acid alkoxy-substituted alkyl ester compound, (b) ) cross-linked polymer
0.1 to 1O%, and (c) the above (a), (b)
It is possible to use compounds having a weight composition of 0 to 70% of other ethylenic compounds copolymerizable with the ethylenic compound. As the crosslinking monomer, an epoxy group-containing ethylenically unsaturated compound such as allyl glycidyl ether is usually used.
■上記ＰＶＤＦの含量が、５部未満では、耐劣化ガソリ
ン性を得がたく、６０部を超えると樹脂的性質が強くな
り望ましくない、望ましいＰＶＤＦ含量は、１０〜４０
部である。■ If the PVDF content is less than 5 parts, it is difficult to obtain anti-aging gasoline properties, and if it exceeds 60 parts, the resin properties become strong, which is undesirable.The desirable PVDF content is 10 to 40 parts.
Department.
（２）外面ゴム層３はヒドリンゴム加硫物で形成されて
いる。(2) The outer rubber layer 3 is made of hydrin rubber vulcanizate.
上記エビクロロヒドリン系ゴムには、エビクロロヒドリ
ン単独重合体で「ＣＯ」の略号で示されるタイプ、エビ
クロロヒドリンとエチレンオキシドとの共重合体で、ｒ
ＥｃＯＪの略号で示されるタイプ等、汎用のものを使用
可能である。The above-mentioned shrimp chlorohydrin rubber includes shrimp chlorohydrin homopolymer, which is indicated by the abbreviation "CO," shrimp chlorohydrin and ethylene oxide copolymer, and r
A general-purpose type, such as the type indicated by the abbreviation EcOJ, can be used.
（３）上記介在層がアクリルゴム加硫物で形成されてい
る。(3) The intervening layer is made of acrylic rubber vulcanizate.
■上記アクリルゴムは、上記内面ゴム層ｌのブレンドベ
ースに使用したものと同様のものを使用可能である。(2) The same acrylic rubber as that used for the blend base of the inner rubber layer 1 can be used.
■上記アクリルゴム加硫物の加硫系が、ジチオカルバミ
ン酸亜鉛（ＰＺ）とジチオカルバミン酸第二鉄（以下「
ＴＴＦＥ」）の併用系である。それ以外では、充分な本
発明の効果を奏し力≦たｌ／）。■The vulcanization system of the above acrylic rubber vulcanizate contains zinc dithiocarbamate (PZ) and ferric dithiocarbamate (hereinafter referred to as "
It is a combined use system of TTFE). Otherwise, the effect of the present invention is sufficient.
■そして上記加硫系におけＰｚとＴＴＦＥとの配合量は
、通常、ＰＺ＋ＴＴＦＥ＝０．６〜３，０ＰＨＲ（望ま
しくは１．１〜２．５ Ｐ）ＩＲ）であり、ＰＺ／Ｔ
ＴＦＥ （重量比）＝０．８〜３（望ましくｃま１．２
〜ｌ、５）とする。■The blending amount of Pz and TTFE in the above vulcanization system is usually PZ + TTFE = 0.6 to 3.0 PHR (preferably 1.1 to 2.5 PHR), and PZ/T
TFE (weight ratio) = 0.8 to 3 (preferably c to 1.2
~l, 5).
ここで、ＰＺは加硫剤的作用を担い、ＴＴＦＥは加硫促
進剤的作用を担う。Here, PZ acts as a vulcanizing agent, and TTFE acts as a vulcanization accelerator.
■ここで、中間ゴム層７の肉厚は、０．２〜１．０ｍｍ
ｔが望ましい。０．２ｍｍ を未満では、充分な接着性
介在層の作用を奏し難く、 １． Ｏｍｍ ｔまでの肉
厚があれば接着性介在層の作用としては十分である（４
）上記ＡＰＲ、ヒドリンゴム、アクリルゴムの各ゴム成
分には、補強剤（ｅｘ、カーボンブラック）、可塑剤、
加工助剤、加硫促進剤、加硫剤、老化防止剤、その他の
副資材を配合し、ロール、バンバリーミキサ−、インタ
ーミキサー等を使用して混練することにより、ゴムホー
ス用材料を調製する。■Here, the thickness of the intermediate rubber layer 7 is 0.2 to 1.0 mm.
t is desirable. If the thickness is less than 0.2 mm, it is difficult for the adhesive intervening layer to function sufficiently. A wall thickness of up to 0 mm t is sufficient for the adhesive intervening layer (4
) Each rubber component of the above APR, hydrin rubber, and acrylic rubber contains a reinforcing agent (ex, carbon black), a plasticizer,
A material for a rubber hose is prepared by blending processing aids, vulcanization accelerators, vulcanizing agents, anti-aging agents, and other auxiliary materials and kneading using a roll, Banbury mixer, intermixer, etc.
各ゴムホース用材料は、補強層形成装置（例えば、スパ
イラル装置）を挟んで配設された複数台の押出機から押
出されて、又は、前述の補強ホースの連続成形装置を用
いて略同時的に押出されて、複層補強ゴムホースの各層
となる。The materials for each rubber hose are extruded from a plurality of extruders arranged with a reinforcing layer forming device (for example, a spiral device) in between, or almost simultaneously using the continuous reinforcing hose forming device described above. It is extruded into layers of a multi-layer reinforced rubber hose.
（４）なお、補強層は、通常、レゾルシン・ホルマリン
・ラテックス系の接着剤処理をしたナイロン糸又はポリ
エステル糸を使用し、スパイラル装置でスパイラル層と
して形成する。但し押出連続成形装置を用いるとか補強
層への接着剤処理なしのものも使用できる。(4) The reinforcing layer is usually formed as a spiral layer using a spiral device using nylon thread or polyester thread treated with a resorcinol/formalin/latex adhesive. However, it is also possible to use a continuous extrusion molding device or to use a reinforcing layer without adhesive treatment.
〈発明の作用・効果〉
本発明の複層ゴムホースは、ＡＦＲ層とヒドリンゴム層
とを具備するゴムホースにおいて、これらの両層の間に
介在層が、アクリルゴムで形成され、該アクリルゴムの
加硫系がＰＺとＴＴＦＥとの併用系であることを特徴と
することにより、下記のような作用・効果を奏する。<Operations and Effects of the Invention> The multilayer rubber hose of the present invention is a rubber hose comprising an AFR layer and a hydrin rubber layer, in which an intervening layer is formed of acrylic rubber between these two layers, and the acrylic rubber is vulcanized. Since the system is characterized by being a combination system of PZ and TTFE, the following actions and effects can be achieved.
ＡＦＲ層とヒドリンゴム層との開本発明の特定加硫系の
アクリルゴム層を介在させた場合、後述の実施例で示す
如く、該アクリルゴム層はそれぞれＡＦＲ層およびヒド
リンゴム層と良好な加硫接着が可能となる。また、本加
硫系のアクリルゴム加硫物は、他の加硫系に比して、糸
劣化促進性が小さい。When an acrylic rubber layer of the specific vulcanization system of the present invention is interposed between the AFR layer and the hydrin rubber layer, the acrylic rubber layer has good vulcanization adhesion with the AFR layer and the hydrin rubber layer, respectively, as shown in the examples below. becomes possible. Furthermore, the acrylic rubber vulcanizate of this vulcanization system has a lower ability to accelerate yarn deterioration than other vulcanization systems.
従って、自動車のエンジンルーム内等の振動な受ける部
位に繕装可能な層間接着性を充分備え、高度の耐劣化ガ
ソリン性および耐摩耗性を具備する複層ゴムホースを提
供できる。Therefore, it is possible to provide a multilayer rubber hose that has sufficient interlayer adhesion to be able to be repaired in areas subject to vibration, such as in the engine room of an automobile, and has high deterioration gasoline resistance and abrasion resistance.
また、内面ゴム層、補強層、外面ゴム層を略同時的にか
つ連続的に同一部位で成形するような連続成形法で成形
することも可能となり、高品質の複層ゴムホースを生産
性良好に製造可能となる。In addition, it is now possible to mold the inner rubber layer, reinforcing layer, and outer rubber layer almost simultaneously and continuously in the same area using a continuous molding method, making it possible to produce high-quality multilayer rubber hoses with good productivity. Manufacturable.
〈試験例〉
以下、本・発明の効果を確認するために行なった試験例
について説明をする。<Test Examples> Test examples conducted to confirm the effects of the present invention will be explained below.
（１）第１〜４表に示すＡＰＲ，ＡＮＭ−１・２、ヒド
リンゴム、ＣＳＭの各ゴム配合物を混線後、カレンダー
リングにより略２ｍｍｔのシーティグしたものを所定大
きさ裁断して、ＡＰＲ層／ＡＮＭ層、ＡＮＭ層／層上ヒ
ドリンゴム層合せで、積層体を形成し、該積層体を加硫
成形（条件：１５０℃×６０分）後、２４ｈ放置した後
、１８０°剥離試験（引っ張り速度： ５０ ｍｍ／
ｍ１ｎ）を行なった、それらの結果を第５表に示すが、
本発明に使用利用する各層ゴム層の層間接着力は、充分
大きいのに対し、ＡＮＭが他の加硫系であるＡＮＭ−２
層や、Ｃ３Ｍ層とＥＣ０層の層間接着力が格段に小さい
。(1) After mixing each rubber compound of APR, ANM-1/2, hydrin rubber, and CSM shown in Tables 1 to 4, sheeting approximately 2 mmt by calendering was cut into a predetermined size, and the APR layer/ A laminate was formed by combining the ANM layer and the ANM layer/hydrin rubber layer on the layer, and the laminate was vulcanized and molded (conditions: 150°C x 60 minutes), left for 24 hours, and then subjected to a 180° peel test (pulling speed: 50mm/
m1n), and the results are shown in Table 5.
The interlayer adhesion of each rubber layer used in the present invention is sufficiently large, whereas ANM-2, which is a different vulcanization system,
The interlayer adhesion between the C3M layer and the EC0 layer is extremely low.
（２）また、未処理のＰＥＴ系ポリエステル糸（初期強
度＋３．８ｋｇｆ）を上記ＡＮＭ−１・２の各配合処方
の未加硫ゴムシートを挟んで金型で圧縮成形加硫を行な
った後、各層を取り出し、糸強度を測定した。その結果
、本発明に使用するＡＮＭ−１の場合、３．５ ｋｇｆ
で変化率−７％であったのに対し、他の加硫系であるＡ
ＮＭ−２の場合、２３ ｋｇｆであり変化率−３９％で
あった。(2) In addition, untreated PET-based polyester yarn (initial strength + 3.8 kgf) was compressed and vulcanized in a mold with unvulcanized rubber sheets of the above ANM-1 and 2 formulations sandwiched between them. , each layer was taken out and the yarn strength was measured. As a result, in the case of ANM-1 used in the present invention, 3.5 kgf
The change rate was -7% in A, which is another vulcanization system.
In the case of NM-2, it was 23 kgf and the rate of change was -39%.
（３）なお、ＡＮＭ−１・２の各配合処方のゴム加硫特
性・ゴム加硫物物性について第６表に参考的に記す。(3) The rubber vulcanization properties and physical properties of the rubber vulcanizate of each compounding formulation of ANM-1 and 2 are listed for reference in Table 6.
第 １ 表
二士豆
第 ２ 表
第 ３ 表
第 ４ 表
第 ５ 表
（接着強さ単位；にｇｆ／２５４ｃｍ）第６表 ＡＮＭ
： 士Table 1 Futashizu Table 2 Table 3 Table 4 Table 5 (Adhesive strength unit: gf/254cm) Table 6 ANM
: Master
第１図は本発明を適用可能な燃料ホース（複層ゴムホー
ス）の−例を示す斜視図、
第２図は従来の燃料ホースの一例を示す斜視図である。
ｌ・・・内面ゴム層、
３・・・外面ゴム層、
５・・・補強層、
７・・・中間ゴムＪｉＦ（介在層）４
特 許 出 願 人FIG. 1 is a perspective view showing an example of a fuel hose (multilayer rubber hose) to which the present invention can be applied, and FIG. 2 is a perspective view showing an example of a conventional fuel hose. 1... Inner surface rubber layer, 3... Outer surface rubber layer, 5... Reinforcement layer, 7... Intermediate rubber JiF (intervening layer) 4 Patent applicant
Claims (1)
物の加硫物で形成されるゴム層と、エピクロロヒドリン
ゴム加硫物で形成されるゴム層とを具備するゴムースに
おいて、 これらの両層の間に介在させるゴム層を、アクリルゴム
加硫物で形成し、 該アクリルゴム加硫物の加硫系が、ジチオカルバミン酸
亜鉛（以下「ＰＺ」と略す。）とジチオカルバミン酸第
二鉄（以下「ＴＴＦＥ」）の併用系である、 ことを特徴とする複層ゴムホース。[Scope of Claims] A rubber mousse comprising a rubber layer formed from a vulcanizate of a blend of acrylic rubber and vinylidene fluoride resin, and a rubber layer formed from an epichlorohydrin rubber vulcanizate, The rubber layer interposed between these two layers is formed of an acrylic rubber vulcanizate, and the vulcanization system of the acrylic rubber vulcanizate contains zinc dithiocarbamate (hereinafter abbreviated as "PZ") and zinc dithiocarbamate. A multilayer rubber hose characterized by being a combination system of diferonite (hereinafter referred to as "TTFE").
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP29630590A JPH04171384A (en) | 1990-10-31 | 1990-10-31 | Composite layer rubber hose |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP29630590A JPH04171384A (en) | 1990-10-31 | 1990-10-31 | Composite layer rubber hose |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH04171384A true JPH04171384A (en) | 1992-06-18 |
Family
ID=17831832
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP29630590A Pending JPH04171384A (en) | 1990-10-31 | 1990-10-31 | Composite layer rubber hose |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH04171384A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104613251A (en) * | 2015-01-30 | 2015-05-13 | 柳州市二和汽车零部件有限公司 | High-pressure rubber pipe |
-
1990
- 1990-10-31 JP JP29630590A patent/JPH04171384A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104613251A (en) * | 2015-01-30 | 2015-05-13 | 柳州市二和汽车零部件有限公司 | High-pressure rubber pipe |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US5427831A (en) | Fluoropolymer laminates | |
| JP3150561B2 (en) | Pneumatic tire | |
| JPH02190692A (en) | Rubber hose | |
| JPH05286080A (en) | Double-layer rubber hose and manufacture thereof | |
| JPH0464507B2 (en) | ||
| JPH1025375A (en) | Thermoplastic elastomer composition and pneumatic tire and hose using the same | |
| JP3319309B2 (en) | Reinforced rubber hose | |
| JP2001200961A (en) | Composite flexible hose | |
| JP4063046B2 (en) | Fuel hose and manufacturing method thereof | |
| JPH0834886A (en) | Rubber composition, rubber/resin laminate, and hose | |
| JPH04171384A (en) | Composite layer rubber hose | |
| JPH10245452A (en) | Low-permeable rubber laminate, and pneumatic tire and hose using the same | |
| JPH06145425A (en) | Rubber composition | |
| JP2936213B2 (en) | Rubber laminate | |
| JP3921682B2 (en) | Acrylic rubber composition and heat-resistant hose | |
| US20050000582A1 (en) | Fuel hose | |
| JP7163118B2 (en) | Inner liners for tires and pneumatic tires | |
| JPH0488281A (en) | Multilayer rubber hose | |
| JP3267838B2 (en) | Composite flexible hose | |
| JP3109244B2 (en) | Rubber laminate | |
| JPH09112756A (en) | Hose | |
| JP3265345B2 (en) | Rubber laminate | |
| JP2004149566A (en) | Hose for fuel | |
| JP3236247B2 (en) | Elastomer composition and pneumatic tire | |
| JPH11300892A (en) | Vulcanized nitrile rubber laminate |