JPH0415298A - Detergent composition - Google Patents
Detergent compositionInfo
- Publication number
- JPH0415298A JPH0415298A JP11910990A JP11910990A JPH0415298A JP H0415298 A JPH0415298 A JP H0415298A JP 11910990 A JP11910990 A JP 11910990A JP 11910990 A JP11910990 A JP 11910990A JP H0415298 A JPH0415298 A JP H0415298A
- Authority
- JP
- Japan
- Prior art keywords
- formulas
- tables
- formula
- salts
- hydrogen atom
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 22
- 239000003599 detergent Substances 0.000 title abstract description 18
- 239000002280 amphoteric surfactant Substances 0.000 claims abstract description 10
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 8
- 125000001183 hydrocarbyl group Chemical group 0.000 claims abstract description 7
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 5
- 229930195734 saturated hydrocarbon Natural products 0.000 claims abstract description 5
- 150000001340 alkali metals Chemical class 0.000 claims abstract description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 3
- XOAAWQZATWQOTB-UHFFFAOYSA-N Taurine Natural products NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 claims description 12
- 238000004140 cleaning Methods 0.000 claims description 12
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 8
- 229960003080 taurine Drugs 0.000 claims description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 229920006395 saturated elastomer Polymers 0.000 claims description 4
- 229930195735 unsaturated hydrocarbon Natural products 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims 5
- 238000005187 foaming Methods 0.000 abstract description 12
- 230000000622 irritating effect Effects 0.000 abstract description 4
- 238000013329 compounding Methods 0.000 abstract 1
- -1 alkyl sulfate salts Chemical class 0.000 description 20
- 210000004209 hair Anatomy 0.000 description 14
- 150000003839 salts Chemical class 0.000 description 14
- 239000012459 cleaning agent Substances 0.000 description 8
- 125000002091 cationic group Chemical group 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Natural products CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 5
- 239000003205 fragrance Substances 0.000 description 5
- 230000007794 irritation Effects 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- 206010040880 Skin irritation Diseases 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 235000019441 ethanol Nutrition 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 210000004400 mucous membrane Anatomy 0.000 description 4
- 239000002453 shampoo Substances 0.000 description 4
- 231100000475 skin irritation Toxicity 0.000 description 4
- 230000036556 skin irritation Effects 0.000 description 4
- 206010015150 Erythema Diseases 0.000 description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 3
- 150000003863 ammonium salts Chemical class 0.000 description 3
- 239000000356 contaminant Substances 0.000 description 3
- 231100000321 erythema Toxicity 0.000 description 3
- 238000000691 measurement method Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 229920001296 polysiloxane Chemical class 0.000 description 3
- 210000002268 wool Anatomy 0.000 description 3
- 208000001840 Dandruff Diseases 0.000 description 2
- 239000004166 Lanolin Substances 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 229920006317 cationic polymer Polymers 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000003750 conditioning effect Effects 0.000 description 2
- 238000010411 cooking Methods 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229940039717 lanolin Drugs 0.000 description 2
- 235000019388 lanolin Nutrition 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 239000012266 salt solution Substances 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 229920003169 water-soluble polymer Polymers 0.000 description 2
- YYGNTYWPHWGJRM-UHFFFAOYSA-N (6E,10E,14E,18E)-2,6,10,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaene Chemical compound CC(C)=CCCC(C)=CCCC(C)=CCCC=C(C)CCC=C(C)CCC=C(C)C YYGNTYWPHWGJRM-UHFFFAOYSA-N 0.000 description 1
- WBIHHWHWKXCPOI-UHFFFAOYSA-N 2-[2-[2-hydroxyethyl(tetradecanoyl)amino]ethylamino]acetic acid Chemical compound CCCCCCCCCCCCCC(=O)N(CCO)CCNCC(O)=O WBIHHWHWKXCPOI-UHFFFAOYSA-N 0.000 description 1
- KGSSQSMFQRTYQF-UHFFFAOYSA-N 2-[2-[dodecanoyl(2-hydroxyethyl)amino]ethylamino]acetic acid Chemical compound CCCCCCCCCCCC(=O)N(CCO)CCNCC(O)=O KGSSQSMFQRTYQF-UHFFFAOYSA-N 0.000 description 1
- DABQDIXIAXPQFG-UHFFFAOYSA-N 2-[dodecanoyl(methyl)amino]ethanesulfonic acid Chemical compound CCCCCCCCCCCC(=O)N(C)CCS(O)(=O)=O DABQDIXIAXPQFG-UHFFFAOYSA-N 0.000 description 1
- FAZHDESNRICLLX-UHFFFAOYSA-N 2-[methyl(tetradecanoyl)amino]ethanesulfonic acid Chemical compound CCCCCCCCCCCCCC(=O)N(C)CCS(O)(=O)=O FAZHDESNRICLLX-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- AFDDTAVVOJKBOW-UHFFFAOYSA-N 3-[2-carboxyethyl-[2-[2-hydroxyethyl(tetradecanoyl)amino]ethyl]amino]propanoic acid Chemical compound CCCCCCCCCCCCCC(=O)N(CCO)CCN(CCC(O)=O)CCC(O)=O AFDDTAVVOJKBOW-UHFFFAOYSA-N 0.000 description 1
- VJSLRFYBDKLPBX-UHFFFAOYSA-N 3-[2-carboxyethyl-[2-[dodecanoyl(2-hydroxyethyl)amino]ethyl]amino]propanoic acid Chemical compound CCCCCCCCCCCC(=O)N(CCO)CCN(CCC(O)=O)CCC(O)=O VJSLRFYBDKLPBX-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- AMHBMSCZRBABOR-UHFFFAOYSA-N CCCCCCCCCCCC(=O)N(CC)CCS(O)(=O)=O Chemical compound CCCCCCCCCCCC(=O)N(CC)CCS(O)(=O)=O AMHBMSCZRBABOR-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 102100025597 Caspase-4 Human genes 0.000 description 1
- 229920001661 Chitosan Polymers 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical group CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 101100273284 Homo sapiens CASP4 gene Proteins 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- BHEOSNUKNHRBNM-UHFFFAOYSA-N Tetramethylsqualene Natural products CC(=C)C(C)CCC(=C)C(C)CCC(C)=CCCC=C(C)CCC(C)C(=C)CCC(C)C(C)=C BHEOSNUKNHRBNM-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000000783 alginic acid Substances 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 229960001126 alginic acid Drugs 0.000 description 1
- 150000004781 alginic acids Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- LHIJANUOQQMGNT-UHFFFAOYSA-N aminoethylethanolamine Chemical compound NCCNCCO LHIJANUOQQMGNT-UHFFFAOYSA-N 0.000 description 1
- 229920006318 anionic polymer Polymers 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000002354 daily effect Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N dodecahydrosqualene Natural products CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 1
- 238000000909 electrodialysis Methods 0.000 description 1
- 150000002169 ethanolamines Chemical class 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical group C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- MCWIUHSHFGHVIS-UHFFFAOYSA-N n,n-dimethyldodecan-1-amine;sodium Chemical compound [Na].CCCCCCCCCCCCN(C)C MCWIUHSHFGHVIS-UHFFFAOYSA-N 0.000 description 1
- 229920001206 natural gum Polymers 0.000 description 1
- 239000010702 perfluoropolyether Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 239000011505 plaster Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 229920005573 silicon-containing polymer Polymers 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 229940031439 squalene Drugs 0.000 description 1
- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は洗浄剤組成物に関し、更に詳しくは起泡力、洗
浄力等が優れ、しかも皮膚や毛髪、眼粘膜に温和な洗浄
剤組成物に関する。[Detailed Description of the Invention] [Field of Industrial Application] The present invention relates to a detergent composition, and more specifically to a detergent composition that has excellent foaming power, detergency, etc., and is gentle on the skin, hair, and eye mucous membranes. Regarding.
〔従来の技術及び発明が解決しようとする課題〕従来よ
り、洗浄剤用の界面活性剤としてアルキル硫酸エステル
塩、ポリオキシエチレンアルキル硫酸エステル塩、アル
キルベンゼンスルホン酸塩、α−オレフィンスルホン酸
塩等のアニオン性界面活性剤が広く用いられてきた。と
ころがこれらの界面活性剤は、程度の差はあるがいずれ
も皮膚刺激性を有し、連用すると皮膚を荒らすという欠
点を有する。[Prior art and problems to be solved by the invention] Conventionally, alkyl sulfate salts, polyoxyethylene alkyl sulfate salts, alkylbenzene sulfonates, α-olefin sulfonates, etc. have been used as surfactants for cleaning agents. Anionic surfactants have been widely used. However, these surfactants all have skin irritation to varying degrees, and have the disadvantage of irritating the skin when used repeatedly.
ところで、アミドアミン型両性界面活性剤は皮膚や眼粘
膜に対する刺激性が低く極めて温和な界面活性剤である
ことが知られており、洗浄剤組成物の一成分として利用
されている。しかしこのアミドアミン型両性界面活性剤
には洗浄剤組成物に要求される必須性能である起泡特性
の点で劣ることを始めいくつかの難点があり、洗浄剤組
成物の主たる界面活性剤として用いることは困難であっ
た。By the way, amidoamine type amphoteric surfactants are known to be extremely mild surfactants with low irritation to the skin and eye mucous membranes, and are used as one component of cleaning compositions. However, this amidoamine-type amphoteric surfactant has several drawbacks, including inferior foaming properties, which is an essential performance required for cleaning compositions, and is therefore used as the main surfactant in cleaning compositions. That was difficult.
一方、Ｎ−アシルタウリン型陰イオン性界面活性剤は、
洗浄剤の一成分として有用であることが知られている（
特開昭５８−１３８７９９号、同５９−１００１９９号
）。上記先行文献によれば、この界面活性剤は単独使用
で起泡性が充分でないばかりか、蛋白質変性作用を有す
るという欠点が挙げられている。On the other hand, N-acyl taurine type anionic surfactants are
It is known to be useful as a component of cleaning agents (
JP 58-138799, JP 59-100199). According to the above-mentioned prior art literature, this surfactant not only does not have sufficient foaming properties when used alone, but also has the disadvantage of having a protein denaturing effect.
従って、起泡力、洗浄力等に優れ、しかも皮膚や毛髪、
眼粘膜等に温和な洗浄剤組成物が望まれていた。Therefore, it has excellent foaming power, cleaning power, etc., and it also protects the skin and hair.
There has been a desire for a detergent composition that is gentle on the eye mucous membranes and the like.
そこで本発明者らは、鋭意検討した結果、アミドアミン
型両性界面活性剤とＮ−アシルタウリン型陰イオン性界
面活性剤を併用すれば、以外にも起泡性が相乗的に向上
し、しかも皮膚等への刺激性がなく極めて温和な洗浄剤
が得られることを見出し、本発明を完成した。As a result of extensive studies, the present inventors found that the combined use of an amidoamine type amphoteric surfactant and an N-acyl taurine type anionic surfactant can synergistically improve foaming properties, and also The present invention was completed based on the discovery that an extremely mild cleaning agent that does not cause irritation to the skin or the like can be obtained.
すなわち、本発明は次の成分（Ａ）及び（Ｂ）〔式中、
Ｒ１及びＲ３は各々炭素数７〜１９の飽和又は不飽和炭
化水素基を、Ｒ２及びＲ４は基−ＣＨ２ＣＯＯＭ。That is, the present invention provides the following components (A) and (B) [in the formula,
R1 and R3 each represent a saturated or unsaturated hydrocarbon group having 7 to 19 carbon atoms, and R2 and R4 represent a group -CH2COOM.
−Ｃ１１２Ｃ）１．Ｃ００Ｍ又は−１１’）１２ｃ）Ｉ
ｆ：）１２ｓ［１，Ｍ （ここでＭは水Ｈ
素原子、アルカリ金属原子若しくはアルカノールアミン
を示す）を示し、Ｒ３は水素原子又は基−ＣＨ２ＣＯＯ
Ｍ、−ＣＨ，ＣＨ２Ｃ００Ｍ又は−ＣＨ２Ｃ）ＩＣＨ２
ＳＯ３Ｍ （Ｍ叶
は前記した意味を有する）を示す〕
で表わされるアミドアミン型両性界面活性剤から選ばれ
る一種又は二種以上、
（Ｂ）次の一般式（ＩＩＩ）
（式中、Ｒ５は炭素数７〜１９の飽和又は不飽和炭化水
素基を、Ｒ７は水素原子又は炭素数１〜４の水酸基を有
していてもよい炭化水素基を示し、Ｍは水素原子、アル
カリ金属原子又はアルカノールアミンを示す）
で表わされるＮ−アシルタウリン型陰イオン性界面活性
剤の一種又は二種以上
を含有する洗浄剤組成物を提供するものである。-C112C)1. C00M or -11')12c)I
f:)12s[1,M (here, M represents a hydrogen atom, an alkali metal atom, or an alkanolamine), and R3 is a hydrogen atom or a group -CH2COO
M, -CH,CH2C00M or -CH2C)ICH2
One or more amidoamine type amphoteric surfactants represented by (B) the following general formula (III) (wherein R5 is the number of carbon atoms) 7 to 19 saturated or unsaturated hydrocarbon groups, R7 represents a hydrogen atom or a hydrocarbon group optionally having a hydroxyl group having 1 to 4 carbon atoms, and M represents a hydrogen atom, an alkali metal atom, or an alkanolamine. The present invention provides a cleaning composition containing one or more N-acyl taurine type anionic surfactants represented by:
本発明の（Ａ）成分であるアミドアミン型両性界面活性
剤のうち、一般式（１）で表わされるものの好ましい具
体例としては、Ｎ−ラウロイル−Ｎ′−力ルボキシメチ
ル−Ｎ′〜（２−ヒドロキシエチル）エチレンジアミン
、Ｎ−ラウロイルＮ′−力ルボキシエチルーＮ’ −（
２−ヒドロキシエチル）エチレンジアミン、Ｎ−ミリス
トイル−Ｎ’ −力ルボキシメチルーＮ’ −（２−ヒ
ドロキシエチル）エチレンジアミン、Ｎ−ミリストイル
−Ｎ′−力ルボキシエチルーＮ’ −（２−ヒドロキシ
エチル）エチレンジアミン、Ｎ−バルミトイル−Ｎ′−
力ルボキシメチルーＮ’ −（２−ヒドロキシエチル）
エチレンジアミン、Ｎ−バルミトイル−Ｎ′−力ルボキ
シエチルーＮ’−（２−ヒドロキシエチル）エチレンジ
アミン等及びこれらの塩が挙げられる。また、一般式（
Ｉ［）で表わされるものの好ましい具体例としては、Ｎ
−ラウロイル−Ｎ−（２−ヒドロキシエチル）−Ｎ’カ
ルボキシメチルエチレンジアミン、Ｎ−ラウロイル−Ｎ
−（２−ヒドロキシエチル）−Ｎ′Ｎ′−ビス（カルボ
キシメチル）エチレンジアミン、Ｎ−ラウロイル−Ｎ−
（２−ヒドロキシエチル）−Ｎ’ 、Ｎ’ −ビス（カ
ルボキシエチル）エチレンジアミン、Ｎ−ミリストイル
−Ｎ−（２−ヒドロキシエチル）−Ｎ′−力ルボキシメ
チルエチレンジアミン、Ｎ−ミリストイル−Ｎ−（２−
ヒドロキシエチル）−Ｎ’ Ｎ’ −ビス（カルポジ
キメチル）エチレンジアミン、Ｎ−ミリストイル−Ｎ−
（２−ヒドロキシエチル）−Ｎ’ 、Ｎ’−ビス（カル
ボキシエチル）エチレンジアミン、Ｎ−バルミトイル−
Ｎ−（２−ヒドロキシエチル）−Ｎ′−力ルボキシメチ
ルエチレンジアミン、Ｎ−バルミトイル−Ｎ−（２−ヒ
ドロキシエチル）−Ｎ’ 、Ｎ’ −ビス（カルボキシ
メチル）エチレンジアミン、Ｎ−バルミトイル−Ｎ−（
２−ヒドロキシエチル）−Ｎ’ 、Ｎ’ −ビス（カル
ボキシエチル）エチレンジアミン及びこれらの塩等が挙
げられる。Among the amidoamine type amphoteric surfactants which are component (A) of the present invention, preferred specific examples of those represented by general formula (1) include N-lauroyl-N'-hydroxymethyl-N' to (2-hydroxy ethyl) ethylenediamine, N-lauroylN'-carboxyethyl-N'-(
2-hydroxyethyl)ethylenediamine, N-myristoyl-N'-hydroxymethyl-N'-(2-hydroxyethyl)ethylenediamine, N-myristoyl-N'-hydroxyethyl-N'-(2-hydroxyethyl)ethylenediamine, N-valmitoyl -N'-
Ruboxymethyl-N'-(2-hydroxyethyl)
Examples include ethylenediamine, N-valmitoyl-N'-carboxyethyl-N'-(2-hydroxyethyl)ethylenediamine, and salts thereof. Also, the general formula (
Preferred specific examples of what is represented by I[) include N
-Lauroyl-N-(2-hydroxyethyl)-N'carboxymethylethylenediamine, N-Lauroyl-N
-(2-hydroxyethyl)-N'N'-bis(carboxymethyl)ethylenediamine, N-lauroyl-N-
(2-hydroxyethyl)-N', N'-bis(carboxyethyl)ethylenediamine, N-myristoyl-N-(2-hydroxyethyl)-N'-carboxymethylethylenediamine, N-myristoyl-N-(2 −
hydroxyethyl)-N'N'-bis(carpodikimethyl)ethylenediamine, N-myristoyl-N-
(2-hydroxyethyl)-N', N'-bis(carboxyethyl)ethylenediamine, N-balmitoyl-
N-(2-hydroxyethyl)-N'-carboxymethylethylenediamine, N-valmitoyl-N-(2-hydroxyethyl)-N', N'-bis(carboxymethyl)ethylenediamine, N-valmitoyl-N- (
Examples include 2-hydroxyethyl)-N', N'-bis(carboxyethyl)ethylenediamine, and salts thereof.
これらの塩としてはナトリウム塩等のアルカリ金属塩、
マグネシウム塩等のアルカリ土類金属塩、トリエタノー
ルアミン塩、ジェタノールアミン塩、モノエタノールア
ミン塩等のアルカノールアミン塩、更にはアンモニウム
塩が挙げられる。また、これらの塩を用いた場合、夾雑
物として無機塩類を含みやすいが、これらの無機塩の一
部又は全部を除き、夾雑無機塩類含量が１重量％（以下
車に％で示す）以下となるようにした、脱塩したアミド
アミン型両性界面活性剤を用いるのが好ましい。These salts include alkali metal salts such as sodium salts,
Examples include alkaline earth metal salts such as magnesium salts, alkanolamine salts such as triethanolamine salts, jetanolamine salts, monoethanolamine salts, and ammonium salts. In addition, when these salts are used, they tend to contain inorganic salts as contaminants, but if some or all of these inorganic salts are excluded, the content of contaminant inorganic salts should be 1% by weight or less (hereinafter expressed in %). It is preferable to use a desalted amidoamine type amphoteric surfactant which has the following properties.
脱塩したアミドアミン型両性界面活性剤は溶媒抽出、電
気透析その他の方法で調製することができる。特に、下
記一般式（Ｉ ａ）で示される２級アミドアミノ酸をア
ンモニウム若しくはトリエタノールアミンの塩とし、夾
雑無機塩含量が１％以下となるよう調整したものが下記
の如き水溶性で濃厚無機溶液に不溶な高分子を容易に０
．０５〜１０％配合できるので好ましい。Desalted amidoamine-type amphoteric surfactants can be prepared by solvent extraction, electrodialysis, or other methods. In particular, a secondary amide amino acid represented by the following general formula (I a) is made into a salt of ammonium or triethanolamine, and the content of contaminant inorganic salts is adjusted to 1% or less, and the water-soluble and concentrated inorganic solution as shown below is prepared. easily removes polymers insoluble in
．． It is preferable because it can be blended in an amount of 0.05 to 10%.
（式中、Ｒ１は前記と同じものを示す）ここでいう水溶
性で濃厚塩溶液に不溶な高分子とは、カチオン性セルロ
ース、カチオン性テンブン、カチオン性グア〜ガム等の
カチオン性天然ガム、カチオン性ポリビニルアルコール
、キトサン、カチオン性シリコーン重合体、ジアリル４
級アンモニウム塩ホモポリマー等の皮膚、毛髪繊維に対
しコンデイショニング性を示すカチオン性高分子；アル
ギン酸、カルボキシメチルセルロース、カルボキシビニ
ルポリマー等の増粘性を示すアニオン性高分子；更には
ヒドロキシエチルセルロース、ポリビニルアルコール、
ポリエチレンオキシド等の増粘性、皮膚、毛髪の感触向
上効果を示す非イオン性高分子をいう。(In the formula, R1 is the same as above.) The polymers that are water-soluble and insoluble in concentrated salt solutions include cationic natural gums such as cationic cellulose, cationic tenbune, and cationic guar-gum; Cationic polyvinyl alcohol, chitosan, cationic silicone polymer, diallyl 4
Cationic polymers that show conditioning properties for the skin and hair fibers, such as class ammonium salt homopolymers; Anionic polymers that show viscosity thickening properties, such as alginic acid, carboxymethylcellulose, and carboxyvinyl polymers; Furthermore, hydroxyethylcellulose and polyvinyl alcohol. ,
A nonionic polymer such as polyethylene oxide that has thickening properties and improves the feel of the skin and hair.
また、（Ｂ）成分である式（ＩＩＩ）で表わされるＮ−
了シルタウリン型陰イオン性界面活性剤の好ましいもの
としては、例えばＮ−ラウロイル−Ｎ−メチルタウリン
、Ｎ−ラウロイル−Ｎ−エチルタウリン、Ｎ−ミリスト
イル−Ｎ−メチルタウリン、Ｎ−バルミトイル−Ｎ−メ
チルタウリン、Ｎ−ｔレオイル−Ｎ−メチルタウリン、
Ｎ−ラウロイル−Ｎ−（２−ヒドロキシエチル）タウリ
ン、Ｎ−ミリストイル−Ｎ−（２−ヒドロキシエチル）
タウリン、Ｎ−バルミトイル＝Ｎ−（２−ヒドロキシエ
チル）タウリン、Ｎ−ラウロイル−Ｎ−（３−ヒドロキ
シプロピル）タウリン、Ｎ−ラウロイル−Ｎ−（２−ヒ
ドロキシプロピル）タウリン、Ｎ−ミリストイル−Ｎ−
（２−ヒドロキシプロピル）タウリン、Ｎ−バルミトイ
ル−Ｎ−（３−ヒドロキシプロピル）タウリン等又はそ
の塩が挙げられる。就中、トリエタノールアミン等のア
ルカノールアミン塩又はアンモニウム塩としたものが、
前記記載の水溶性で濃厚無機塩溶液に不溶な高分子を容
易に０．０５〜１０％配合できるので好ましい。In addition, N- represented by the formula (III) which is the component (B)
Preferred examples of the siltaurine type anionic surfactants include N-lauroyl-N-methyltaurine, N-lauroyl-N-ethyltaurine, N-myristoyl-N-methyltaurine, and N-valmitoyl-N-methyl. Taurine, Nt-leoyl-N-methyltaurine,
N-lauroyl-N-(2-hydroxyethyl)taurine, N-myristoyl-N-(2-hydroxyethyl)
Taurine, N-valmitoyl=N-(2-hydroxyethyl)taurine, N-lauroyl-N-(3-hydroxypropyl)taurine, N-lauroyl-N-(2-hydroxypropyl)taurine, N-myristoyl-N-
Examples include (2-hydroxypropyl)taurine, N-valmitoyl-N-(3-hydroxypropyl)taurine, and salts thereof. Among them, alkanolamine salts such as triethanolamine or ammonium salts,
This is preferred because 0.05 to 10% of the water-soluble polymer insoluble in the concentrated inorganic salt solution described above can be easily blended.
本発明の洗浄剤組成物は常法に従い、（Ａ）成分及び（
８）成分を配合することにより調製される。The cleaning composition of the present invention is prepared using the conventional method including component (A) and (
8) Prepared by blending the ingredients.
本発明の洗浄剤組成物が液体洗浄剤である場合、（Ａ）
成分の配合量は５〜３５％、好ましくは１０〜３０％で
あり、（６）成分の配合量は１−１５％、好ましくは１
〜１０％である。When the cleaning composition of the present invention is a liquid cleaning agent, (A)
The blending amount of component (6) is 5 to 35%, preferably 10 to 30%, and the blending amount of component (6) is 1 to 15%, preferably 1
~10%.
斯くして得られる本発明の洗浄剤組成物には、更に必要
に応じて公知の任意成分、例えば高級脂肪酸塩、アルキ
ルアミンオキサイド、アルキルアマイト、エーテルサル
フェート、脂肪酸アルカノールアマイド、アルキル酢酸
ベタイン、アシルアミドベタイン等の補助活性剤；スク
ワレン、ラノリン、陽イオン性界面活性剤、高級アルコ
ール、シリコーン、シリコーン誘導体、パーフルオロポ
リエーテル等の感触向上剤；無機塩及び有機塩、希釈剤
、真珠光沢剤、動植物エキス、香料、色素、殺菌剤、粘
度調整剤、可溶化剤、保湿剤、防腐剤、前記記載の水溶
性高分子等を本発明の効果を損なわない範囲で配合する
ことができる。特にコンデイショニング性を付与するた
めには、上記のうちでカチオン性高分子化合物、陽イオ
ン性界面活性剤、シリコーン誘導体が好適に使用される
。The detergent composition of the present invention obtained in this way may further contain known optional ingredients, such as higher fatty acid salts, alkylamine oxides, alkylamites, ether sulfates, fatty acid alkanolamides, alkyl acetate betaines, and acyl acetates. Auxiliary active agents such as amidobetaine; feel improvers such as squalene, lanolin, cationic surfactants, higher alcohols, silicones, silicone derivatives, perfluoropolyethers; inorganic and organic salts, diluents, pearlescent agents, Animal and plant extracts, fragrances, pigments, bactericides, viscosity modifiers, solubilizers, humectants, preservatives, water-soluble polymers described above, and the like can be blended within the range that does not impair the effects of the present invention. Among the above, cationic polymer compounds, cationic surfactants, and silicone derivatives are preferably used to impart conditioning properties.
本発明によれば、優れた起泡力、洗浄力を有し、かつ人
体に対する刺激性が極めて少なく、感触に優れた洗浄剤
組成物が提供される。According to the present invention, there is provided a detergent composition that has excellent foaming power and detergency, is extremely less irritating to the human body, and has an excellent feel.
従って、本発明洗浄剤組成物は皮膚、粘膜等に対して刺
激が低いことが要求される洗浄剤、例えば、乳幼児用の
毛髪、皮膚洗浄剤、手の荒れやすい主婦のためのウール
、台所用洗剤、浴室清掃剤、毎日洗髪する人のためのデ
イリーシャンプー等として有利に利用することができる
。Therefore, the detergent composition of the present invention can be used as a detergent that is required to be less irritating to the skin, mucous membranes, etc., such as hair and skin detergents for infants, wool for housewives who tend to get rough hands, and detergents for kitchen use. It can be advantageously used as detergent, bathroom cleaning agent, daily shampoo for people who wash their hair every day, etc.
次に実施例を挙げ、本発明を更に説明する。 Next, the present invention will be further explained with reference to Examples.
実施例１
第１表に示す組成の洗浄剤組成物を調製し、その起泡力
を下記の測定方法で測定した。また、これを用いて洗髪
した後の毛髪の感触も評価した。Example 1 A cleaning composition having the composition shown in Table 1 was prepared, and its foaming power was measured by the following measuring method. The feel of the hair after washing with this was also evaluated.
この結果も同表に示す。The results are also shown in the same table.
（測定方法）
起泡力の測定条件及び方法：
試料洗浄剤の１％水溶液に人工汚れとしてラノリンを０
．５％加え、平型プロペラで４０℃に於いて回転数１０
０Ｏｒｐｍで５秒毎反転の条件下で５分間シリンダー中
で攪拌し、攪拌終了から３０秒後の泡の体積を測定した
。(Measurement method) Foaming power measurement conditions and method: Add 0 lanolin as an artificial stain to a 1% aqueous solution of sample detergent.
．． 5%, and 10 rotations at 40℃ with a flat propeller.
The mixture was stirred in a cylinder for 5 minutes at 0 rpm and inverted every 5 seconds, and the volume of foam was measured 30 seconds after the end of stirring.
毛髪の感触：
試料洗浄剤１ｇを２０ｇのかもしに塗布し、１分間泡立
てた後、泡立てた髪を流水ですすぎ、毛髪の感触を次の
基準で評価した。Hair feel: 1 g of the sample cleansing agent was applied to 20 g of hair, lathered for 1 minute, and the lathered hair was rinsed with running water, and the hair feel was evaluated according to the following criteria.
○・・・非常になめらかである。○...Very smooth.
△・・・ややきしむ。△...Slight squeak.
×・・・非常にきしむ。×...Very squeaky.
（結果）
以下余白
第１表より明らかなように、本発明品は比較品に比べて
泡特性に優れ、毛髪の感触がよいことが認められた。(Results) As is clear from Table 1 below, the products of the present invention were found to have better foaming properties and a better feel on the hair than the comparative products.
実施例２
第２表に示す組成の洗浄剤組成物を調製し、その起泡力
を実施例１の測定方法で測定した。また、これを用いて
洗髪した後の毛髪の感触を実施例１と同様に、また、皮
膚刺激性を下記測定方法によりそれぞれ評価した。この
結果も同表に示す。Example 2 A cleaning composition having the composition shown in Table 2 was prepared, and its foaming power was measured by the measuring method of Example 1. Further, the feel of the hair after washing with this product was evaluated in the same manner as in Example 1, and the skin irritation was evaluated using the following measurement method. The results are also shown in the same table.
（測定方法）
皮膚への刺激性：
試料洗浄剤の１％水溶液０．１ｍｌ！をしみ込ませたバ
ッチテスト用絆創膏を２０人の被検者に２４時間貼付し
、貼付除去後２４時間後に刺激性を判定し、次の基準で
評価した。(Measurement method) Skin irritation: 0.1ml of 1% aqueous solution of sample cleaning agent! A batch test adhesive plaster impregnated with was applied to 20 subjects for 24 hours, and 24 hours after removal, the irritation was determined and evaluated using the following criteria.
○・・・２０人中紅斑を示した者が２Å以下であった。○: Out of 20 people, those who showed erythema were 2 Å or less.
Δ・・・２０人中紅斑を示した者が３Å以上１０Å以下
であった。Δ: Out of 20 people, those who showed erythema ranged from 3 Å to 10 Å.
Ｘ・・・２０人中紅斑を示した者が１１Å以上であった
。X: Out of 20 people, those who showed erythema were 11 Å or more.
（結果）
第２表より明らかなように本発明品は泡特性に優れ、皮
膚に対する刺激が少なく、毛髪の感触がよいことが認め
られた。(Results) As is clear from Table 2, the products of the present invention were found to have excellent foaming properties, less irritation to the skin, and a good feel to the hair.
実施例３〜５
次に示すシャンプー、羊毛・軽質洗浄剤、食器調理具用
洗浄剤はいずれも皮膚に対する刺激性が極めて弱く、ま
た、洗浄性は良好であった。Examples 3 to 5 The following shampoos, wool/light detergents, and tableware cooking utensil detergents all had extremely low irritation to the skin and had good cleaning properties.
実施例３
シャンプー： （％）羊毛
・軽質洗浄剤：
ンナトリウム
ラウリルジメチルアミンオキンド
メチルセルロース
エチルアルコール
香 料
（％）
適量
計
実施例５
食器調理具用洗浄剤：
（％）
香料１色素
適量
計
実施例４
（カーボボール９４１． Ｇｏｏｄｒ ＋ｃｈ社）エチ
ルアルコール
香料１色素、濁り剤
適量
計 １００実
施例６
次に示す抗フケシャンプー組成物は皮膚に対する刺激性
が極めて弱く、また、抗フケ効果も良好であった。Example 3 Shampoo: (%) Wool/Light detergent: Sodium lauryl dimethylamine oquindo methyl cellulose Ethyl alcohol Fragrance (%) Dosage meter Example 5 Cleaning agent for tableware and cooking utensils: (%) Fragrance 1 Dye Dosage meter implementation Example 4 (Carbo Ball 941. Goodr +ch Company) Ethyl alcohol fragrance 1 color, clouding agent appropriate amount 100 Example 6 The following anti-dandruff shampoo composition has very weak skin irritation and also has good anti-dandruff effect. there were.
（％）
計 １００実施
例７
次に示す浴室清掃剤は良好な洗浄性を示し、浴槽等に付
着した石鹸カスを効率よく落とす。(%) Total: 100 Example 7 The bathroom cleaning agent shown below exhibits good cleaning properties and efficiently removes soap scum adhering to bathtubs and the like.
（％） ナトリウム 塩化ナトリウム クエン酸 ジエチレングリコールモノエチルエ ーテル ０．１５ ０．７ 計 以上 エチルアルコール 香料１色素 適量(%) sodium sodium chloride citric acid Diethylene glycol monoethyl ether -tel 0.15 0.7 Total that's all Ethyl alcohol Fragrance 1 color Appropriate amount
Claims (1)
又は不飽和炭化水素基を、Ｒ＿２及びＲ＿４は基−ＣＨ
＿２ＣＯＯＭ、−ＣＨ＿２ＣＨ＿２ＣＯＯＭ又は▲数式
、化学式、表等があります▼（ここでＭは水素原子、ア
ルカリ金属原子若しくはアルカノールアミンを示す）を
示し、Ｒ＿５は水素原子又は基−ＣＨ＿２ＣＯＯＭ、−
ＣＨ＿２ＣＨ＿２ＣＯＯＭ又は▲数式、化学式、表等が
あります▼（Ｍは前記した意味を有する）を示す〕 で表わされるアミドアミン型両性界面活性剤から選ばれ
る一種又は二種以上、 （Ｂ）次の一般式（III） ▲数式、化学式、表等があります▼（III） （式中、Ｒ＿６は炭素数７〜１９の飽和又は不飽和炭化
水素基を、Ｒ＿７は水素原子又は炭素数１〜４の水酸基
を有していてもよい炭化水素基を示し、Ｍは水素原子、
アルカリ金属原子又はアルカノールアミンを示す） で表わされるＮ−アシルタウリン型陰イオン性界面活性
剤の一種又は二種以上 を含有する洗浄剤組成物。[Claims] 1. The following components (A) and (B) (A) The following general formulas (I) and (II) ▲There are mathematical formulas, chemical formulas, tables, etc.▼(I) ▲Mathematical formulas, chemical formulas, There are tables, etc.▼(II) [In the formula, R_1 and R_3 are each a saturated or unsaturated hydrocarbon group having 7 to 19 carbon atoms, and R_2 and R_4 are groups -CH
_2COOM, -CH_2CH_2COOM or ▲There are mathematical formulas, chemical formulas, tables, etc.▼ (where M represents a hydrogen atom, an alkali metal atom, or an alkanolamine), and R_5 is a hydrogen atom or a group -CH_2COOM, -
CH_2CH_2COOM or ▲There are mathematical formulas, chemical formulas, tables, etc.▼ (M has the meaning described above)] One or more kinds selected from amidoamine type amphoteric surfactants represented by (B) the following general formula ( III) ▲There are mathematical formulas, chemical formulas, tables, etc.▼(III) (In the formula, R_6 is a saturated or unsaturated hydrocarbon group having 7 to 19 carbon atoms, and R_7 is a hydrogen atom or a hydroxyl group having 1 to 4 carbon atoms. M is a hydrogen atom,
A cleaning composition containing one or more N-acyl taurine type anionic surfactants represented by:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11910990A JP2829769B2 (en) | 1990-05-09 | 1990-05-09 | Detergent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11910990A JP2829769B2 (en) | 1990-05-09 | 1990-05-09 | Detergent composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0415298A true JPH0415298A (en) | 1992-01-20 |
| JP2829769B2 JP2829769B2 (en) | 1998-12-02 |
Family
ID=14753139
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11910990A Expired - Fee Related JP2829769B2 (en) | 1990-05-09 | 1990-05-09 | Detergent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2829769B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1095718A (en) * | 1996-09-19 | 1998-04-14 | Shiseido Co Ltd | Composition for hair shampoo |
| WO2001026614A1 (en) * | 1999-10-12 | 2001-04-19 | Kao Corporation | Detergent composition |
| JP2002121588A (en) * | 2000-10-18 | 2002-04-26 | Lion Corp | Composition for hard surface detergent |
-
1990
- 1990-05-09 JP JP11910990A patent/JP2829769B2/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1095718A (en) * | 1996-09-19 | 1998-04-14 | Shiseido Co Ltd | Composition for hair shampoo |
| WO2001026614A1 (en) * | 1999-10-12 | 2001-04-19 | Kao Corporation | Detergent composition |
| JP2002121588A (en) * | 2000-10-18 | 2002-04-26 | Lion Corp | Composition for hard surface detergent |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2829769B2 (en) | 1998-12-02 |
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