JPH04149299A - Liquid detergent composition - Google Patents
Liquid detergent compositionInfo
- Publication number
- JPH04149299A JPH04149299A JP27568690A JP27568690A JPH04149299A JP H04149299 A JPH04149299 A JP H04149299A JP 27568690 A JP27568690 A JP 27568690A JP 27568690 A JP27568690 A JP 27568690A JP H04149299 A JPH04149299 A JP H04149299A
- Authority
- JP
- Japan
- Prior art keywords
- amino acid
- formula
- fatty acid
- neutral amino
- acyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 10
- 239000007788 liquid Substances 0.000 title claims description 8
- 239000003599 detergent Substances 0.000 title description 7
- -1 amino acid salt Chemical class 0.000 claims abstract description 33
- 150000004665 fatty acids Chemical group 0.000 claims abstract description 20
- 230000007935 neutral effect Effects 0.000 claims abstract description 16
- 150000001413 amino acids Chemical class 0.000 claims abstract description 10
- 229920006395 saturated elastomer Polymers 0.000 claims abstract description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims abstract description 4
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 4
- 150000001340 alkali metals Chemical group 0.000 claims abstract description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims 2
- 238000004140 cleaning Methods 0.000 claims 1
- 239000002453 shampoo Substances 0.000 abstract description 19
- 238000002156 mixing Methods 0.000 abstract description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 19
- 239000000194 fatty acid Substances 0.000 description 19
- 229930195729 fatty acid Natural products 0.000 description 19
- 235000001014 amino acid Nutrition 0.000 description 13
- 238000000034 method Methods 0.000 description 8
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 8
- 229910052708 sodium Inorganic materials 0.000 description 8
- 239000011734 sodium Substances 0.000 description 8
- 239000003240 coconut oil Substances 0.000 description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 6
- 235000019864 coconut oil Nutrition 0.000 description 6
- 108010077895 Sarcosine Proteins 0.000 description 4
- 125000002252 acyl group Chemical group 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- 238000005187 foaming Methods 0.000 description 4
- 229940043230 sarcosine Drugs 0.000 description 4
- 239000004472 Lysine Substances 0.000 description 3
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 3
- BACYUWVYYTXETD-UHFFFAOYSA-N N-Lauroylsarcosine Chemical compound CCCCCCCCCCCC(=O)N(C)CC(O)=O BACYUWVYYTXETD-UHFFFAOYSA-N 0.000 description 3
- 238000003287 bathing Methods 0.000 description 3
- 108700004121 sarkosyl Proteins 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- NGOZDSMNMIRDFP-UHFFFAOYSA-N 2-[methyl(tetradecanoyl)amino]acetic acid Chemical compound CCCCCCCCCCCCCC(=O)N(C)CC(O)=O NGOZDSMNMIRDFP-UHFFFAOYSA-N 0.000 description 2
- UNWFFCPRJXMCNV-UHFFFAOYSA-N 3-[dodecanoyl(methyl)amino]propanoic acid Chemical compound CCCCCCCCCCCC(=O)N(C)CCC(O)=O UNWFFCPRJXMCNV-UHFFFAOYSA-N 0.000 description 2
- 229920002101 Chitin Polymers 0.000 description 2
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 description 2
- 239000005639 Lauric acid Substances 0.000 description 2
- DIOYAVUHUXAUPX-KHPPLWFESA-N Oleoyl sarcosine Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)N(C)CC(O)=O DIOYAVUHUXAUPX-KHPPLWFESA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 235000004279 alanine Nutrition 0.000 description 2
- POJWUDADGALRAB-UHFFFAOYSA-N allantoin Chemical compound NC(=O)NC1NC(=O)NC1=O POJWUDADGALRAB-UHFFFAOYSA-N 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- UCMIRNVEIXFBKS-UHFFFAOYSA-N beta-alanine Chemical compound NCCC(O)=O UCMIRNVEIXFBKS-UHFFFAOYSA-N 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 2
- 230000003020 moisturizing effect Effects 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- KIUKXJAPPMFGSW-DNGZLQJQSA-N (2S,3S,4S,5R,6R)-6-[(2S,3R,4R,5S,6R)-3-Acetamido-2-[(2S,3S,4R,5R,6R)-6-[(2R,3R,4R,5S,6R)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylic acid Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 KIUKXJAPPMFGSW-DNGZLQJQSA-N 0.000 description 1
- HJDITXMCJQRQLU-UHFFFAOYSA-N 2-[dodecanoyl(methyl)amino]acetate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCC(=O)N(C)CC(O)=O HJDITXMCJQRQLU-UHFFFAOYSA-N 0.000 description 1
- WEDYWSNRZRMXRS-UHFFFAOYSA-N 3-[dodecanoyl(methyl)amino]propanoate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCC(=O)N(C)CCC(O)=O WEDYWSNRZRMXRS-UHFFFAOYSA-N 0.000 description 1
- NBDYSLCMCUDINP-UHFFFAOYSA-N 3-[dodecanoyl(methyl)amino]propanoic acid;sodium Chemical compound [Na].CCCCCCCCCCCC(=O)N(C)CCC(O)=O NBDYSLCMCUDINP-UHFFFAOYSA-N 0.000 description 1
- DCVMAYAWOPBYKB-UHFFFAOYSA-N 3-[methyl(tetradecanoyl)amino]propanoic acid Chemical compound CCCCCCCCCCCCCC(=O)N(C)CCC(O)=O DCVMAYAWOPBYKB-UHFFFAOYSA-N 0.000 description 1
- WHOGJRRLCCEDIU-UHFFFAOYSA-N 3-[methyl(tetradecanoyl)amino]propanoic acid;sodium Chemical compound [Na].CCCCCCCCCCCCCC(=O)N(C)CCC(O)=O WHOGJRRLCCEDIU-UHFFFAOYSA-N 0.000 description 1
- LIFHMKCDDVTICL-UHFFFAOYSA-N 6-(chloromethyl)phenanthridine Chemical compound C1=CC=C2C(CCl)=NC3=CC=CC=C3C2=C1 LIFHMKCDDVTICL-UHFFFAOYSA-N 0.000 description 1
- POJWUDADGALRAB-PVQJCKRUSA-N Allantoin Natural products NC(=O)N[C@@H]1NC(=O)NC1=O POJWUDADGALRAB-PVQJCKRUSA-N 0.000 description 1
- 239000004475 Arginine Substances 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- DWIYFHPNCGKDJM-UHFFFAOYSA-N CN(C)CC(=O)O.C(CCCCCCCCCCC)(=O)O Chemical compound CN(C)CC(=O)O.C(CCCCCCCCCCC)(=O)O DWIYFHPNCGKDJM-UHFFFAOYSA-N 0.000 description 1
- 229920001661 Chitosan Polymers 0.000 description 1
- 208000001840 Dandruff Diseases 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 description 1
- KDXKERNSBIXSRK-YFKPBYRVSA-N L-lysine Chemical compound NCCCC[C@H](N)C(O)=O KDXKERNSBIXSRK-YFKPBYRVSA-N 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- BNFUDBGMKOPYAA-UHFFFAOYSA-N N(CCO)(CCO)CCO.C(CCCCCCCCCCC)(=O)CNCCC(=O)O Chemical compound N(CCO)(CCO)CCO.C(CCCCCCCCCCC)(=O)CNCCC(=O)O BNFUDBGMKOPYAA-UHFFFAOYSA-N 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229920002385 Sodium hyaluronate Polymers 0.000 description 1
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 229960000458 allantoin Drugs 0.000 description 1
- ZOJBYZNEUISWFT-UHFFFAOYSA-N allyl isothiocyanate Chemical compound C=CCN=C=S ZOJBYZNEUISWFT-UHFFFAOYSA-N 0.000 description 1
- 229940069521 aloe extract Drugs 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 229940121363 anti-inflammatory agent Drugs 0.000 description 1
- 239000002260 anti-inflammatory agent Substances 0.000 description 1
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 229940000635 beta-alanine Drugs 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 239000003974 emollient agent Substances 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 229960004949 glycyrrhizic acid Drugs 0.000 description 1
- 235000019410 glycyrrhizin Nutrition 0.000 description 1
- LPLVUJXQOOQHMX-QWBHMCJMSA-N glycyrrhizinic acid Chemical compound O([C@@H]1[C@@H](O)[C@H](O)[C@H](O[C@@H]1O[C@@H]1C([C@H]2[C@]([C@@H]3[C@@]([C@@]4(CC[C@@]5(C)CC[C@@](C)(C[C@H]5C4=CC3=O)C(O)=O)C)(C)CC2)(C)CC1)(C)C)C(O)=O)[C@@H]1O[C@H](C(O)=O)[C@@H](O)[C@H](O)[C@H]1O LPLVUJXQOOQHMX-QWBHMCJMSA-N 0.000 description 1
- 229920002674 hyaluronan Polymers 0.000 description 1
- 229960003160 hyaluronic acid Drugs 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 1
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 1
- 229960002216 methylparaben Drugs 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 239000008164 mustard oil Substances 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- BTSZTGGZJQFALU-UHFFFAOYSA-N piroctone olamine Chemical compound NCCO.CC(C)(C)CC(C)CC1=CC(C)=CC(=O)N1O BTSZTGGZJQFALU-UHFFFAOYSA-N 0.000 description 1
- 229940081510 piroctone olamine Drugs 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229940010747 sodium hyaluronate Drugs 0.000 description 1
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 description 1
- YWIVKILSMZOHHF-QJZPQSOGSA-N sodium;(2s,3s,4s,5r,6r)-6-[(2s,3r,4r,5s,6r)-3-acetamido-2-[(2s,3s,4r,5r,6r)-6-[(2r,3r,4r,5s,6r)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2- Chemical compound [Na+].CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 YWIVKILSMZOHHF-QJZPQSOGSA-N 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 229940043810 zinc pyrithione Drugs 0.000 description 1
- PICXIOQBANWBIZ-UHFFFAOYSA-N zinc;1-oxidopyridine-2-thione Chemical compound [Zn+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S PICXIOQBANWBIZ-UHFFFAOYSA-N 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Abstract
Description
【発明の詳細な説明】
産 の ］
本発明は、泡立ち、使用感が優れたシャンプーボディシ
ャンプー等の液体洗浄剤組成物に関するものである。[Detailed Description of the Invention] [Product] The present invention relates to a liquid detergent composition such as a shampoo/body shampoo that has excellent lathering and feels when used.
従ｍ支簀−
近年、ヘアケア及びスキンケア意識の高まりによりシャ
ンプー、ボディシャンプー等身体洗浄剤の使用頻度が増
えてきた。そしてそのことによりより低刺激でかつ泡立
ち、使用感の良好なものが求められてきた。このような
目的にそう身体洗浄剤用基剤の一つにＮ−アシル中性ア
ミノ酸塩がある。In recent years, with increasing awareness of hair care and skin care, the frequency of use of body cleansers such as shampoo and body shampoo has increased. As a result, there has been a demand for products that are less irritating, foamy, and have a good feel when used. One of the bases for body cleansers for this purpose is N-acyl neutral amino acid salts.
Ｎ−アシル中性アミノ酸塩はシャンプー等に使用した場
合、低刺激で使用後の髪のまとまりをよくしたり、肌に
しっとりとした感触を与えるため近年多量に使用される
ようになってきた。When N-acyl neutral amino acid salts are used in shampoos and the like, they have been used in large quantities in recent years because they are mildly irritating, improve the manageability of hair after use, and give a moist feel to the skin.
しかし、Ｎ−アシル中性アミノ酸塩は、一般的なシャン
プー基剤であるアルキル硫酸塩やアルキルエーテル硫酸
塩に較べると、泡立ちが劣り、シャンプー等の主剤とし
て使用するには充分ではない。このような欠点を改良す
る方法として、脂肪酸ジェタノールアミドを用いる方法
、アミドベタイン型両性界面活性剤を配合する方法（特
開昭６０−１９５２００＞ 、アミドアミンオキサイド
を用いる方法（特開昭６２−２０５９６） 、ポリオキ
シエチレンアルキルエーテル、ポリオキシエチレン硬化
しマシ油を配合する方法（特開昭６Ｏ−８７２０９）な
どが提案されているが充分ではない。However, N-acyl neutral amino acid salts have inferior foaming properties compared to alkyl sulfates and alkyl ether sulfates, which are common shampoo bases, and are not sufficient for use as a main ingredient in shampoos and the like. Methods for improving these drawbacks include a method using fatty acid jetanolamide, a method incorporating an amidobetaine type amphoteric surfactant (JP-A-60-195200), and a method using amidoamine oxide (JP-A-62-20596). ), a method of blending polyoxyethylene alkyl ether, polyoxyethylene hardened mustard oil (Japanese Patent Application Laid-open No. 60-87209), but these methods are not sufficient.
が解′ しようとする課題
本発明の目的は、泡立ち、使用感が良好な液体洗浄剤組
成物を提供することにある。SUMMARY OF THE INVENTION An object of the present invention is to provide a liquid detergent composition that foams and has a good feel when used.
課題を解゛するための手段
上記本発明の目的は、Ｎ−アシル中性アミノ酸塩にＮ−
アシル中性アミノ酸をある特定の比率で組合せることに
より達成される。Means for Solving the Problems The object of the present invention is to add N-acyl neutral amino acid salts to N-acyl neutral amino acid salts.
This is achieved by combining acyl neutral amino acids in certain ratios.
すなわち、本発明は下記の成分（Ａ）、（Ｂ）（Ａ）一
般式く１）
ＣＨ３
Ｒ＋Ｃ０−Ｎ −（ＣＨ２）ｎｃＯＯＨ（１）（式中、
Ｒ，Ｃｏは炭素数１０〜１８直鎖又は分岐鎖の飽和又は
脂肪酸残基、ｎは１ないし２の整数を表す。）
て示されるＮ−アシル中性アミノ酸
（Ｂ）一般式（２）
％式％（２）
（式中、Ｒ２Ｃ０は炭素数１０〜１８直鎖又は分岐鎖の
飽和又は脂肪酸残基、ｎは１ないし２の整数、Ｍはアル
カリ金属、アルカノールアミン、アンモニウム、塩基性
アミノ酸を表わす。）を必須成分とし、（Ａ）・ （Ｂ
）の比が５＝９５〜４０ ： ６０である液体洗浄剤組
成物に関するものである。That is, the present invention provides the following components (A), (B) (A) general formula (1) CH3 R+C0-N -(CH2)ncOOH (1) (in the formula,
R and Co represent linear or branched saturated or fatty acid residues having 10 to 18 carbon atoms, and n represents an integer of 1 to 2. ) N-acyl neutral amino acid (B) general formula (2) % formula % (2) (wherein R2C0 is a linear or branched saturated or fatty acid residue having 10 to 18 carbon atoms, n is 1 An integer from 2 to 2, M represents an alkali metal, alkanolamine, ammonium, basic amino acid.) is an essential component, and (A) and (B
) has a ratio of 5=95 to 40:60.
本発明の（Ａ、 ）成分である式（１〉のＮ−アシル中
性アミノ酸のＲ，Ｃｏとしては、Ｃ１□〜Ｃ１ｇが好ま
しく、特に好ましいものとしてＣ１２〜ＣＩ４が用いら
れる。ｎは工ないし２のものを用いることができる。（
Ａ）成分の代表的なものとして、ヤシ油脂肪酸アシルサ
ルコシン、ラウロイルサルコシン、ミリストイルサルコ
シン、バルミトイルサルコシン、オレイルサルコシン、
Ｎ−ヤシ油脂肪酸アシル−Ｎ−メチル−β−アラニン、
Ｎ−ラウロイル−Ｎ−メチル−β−アラニン、Ｎ−ミリ
ストイル−Ｎ−メチル−β−アラニン、Ｎ−バルミトイ
ル−Ｎ−メチル−β−アラニン、Ｎ−オレイル−Ｎ−メ
チル−β−アラニン等がある。R and Co of the N-acyl neutral amino acid of formula (1) which is the component (A, ) of the present invention are preferably C1□ to C1g, and particularly preferably C12 to CI4. 2 can be used. (
A) Typical ingredients include coconut oil fatty acid acylsarcosine, lauroylsarcosine, myristoylsarcosine, valmitoylsarcosine, oleylsarcosine,
N-coco fatty acid acyl-N-methyl-β-alanine,
N-lauroyl-N-methyl-β-alanine, N-myristoyl-N-methyl-β-alanine, N-valmitoyl-N-methyl-β-alanine, N-oleyl-N-methyl-β-alanine, etc. .
（Ｂ）成分である式（２）のＮ−アシル中性アミノ酸塩
のＲ，Ｃｏとしては、ＣＩ２〜ｃｔｇが好ましく、特に
好ましいものとしてＣ１２〜ＣＩ４が用いられる。ｎは
工ないし２のものを用いることができ、Ｍはナトリウム
、カリウムなどのアルカリ金属塩、トリエタノールアミ
ンなどのアルカノールアミン、アンモニウム、リジン、
アルギニンなどの塩基性アミノ酸を用いることができる
。（Ｂ）成分の代表的なものとして、ヤシ油脂肪酸アシ
ルサルコシンナトリウム、ラウロイルサルコシンナトリ
ウム、ミリストイルサルコシンナトリウム、バルミトイ
ルサルコシンナトリウム、オレイルサルコシンナトリウ
ム、Ｎ−ヤシ油脂肪酸アシルＮ−メチル〜β−アラニン
ナトリウム、Ｎ−ラウロイル−Ｎ−メチル−β−アラニ
ンナトリウム、Ｎ−ミリストイル−Ｎ−メチル−β−ア
ラニンナトリウム、Ｎ−バルミトイル−Ｎ−メチル−β
−アラニンナトリウム、Ｎ−オレイル−Ｎ−メチル−β
−アラニンナトリウム、ヤシ油脂肪酸アシルサルコシン
トリエタノールアミン、ラウロイルサルコシントリエタ
ノールアミン、Ｎ−ヤシ油脂肪酸アシル−Ｎ−メチル−
β−アラニントリエタノールアミン、Ｎ−ラウロイル−
Ｎ−メチル−βアラニントリエタノールアミン、ヤシ油
脂肪酸アシルサルコシンリジン、ラウロイルサルコシン
リシン、Ｎ−ヤシ油脂肪酸アシル−Ｎ〜メチル−β−ア
ラニンリジン、Ｎ−ラウロイル−Ｎ−メチル−β−アラ
ニンリジン等がある。R and Co of the N-acyl neutral amino acid salt of formula (2), which is the component (B), are preferably CI2 to ctg, and particularly preferably C12 to CI4. n can be selected from 1 to 2, and M is an alkali metal salt such as sodium or potassium, an alkanolamine such as triethanolamine, ammonium, lysine,
Basic amino acids such as arginine can be used. Representative components of (B) include sodium coconut oil fatty acid acyl sarcosine, sodium lauroyl sarcosine, sodium myristoyl sarcosine, sodium balmitoyl sarcosine, sodium oleyl sarcosine, and sodium N-coco fatty acid acyl N-methyl to β-alanine. , N-lauroyl-N-methyl-β-alanine sodium, N-myristoyl-N-methyl-β-alanine sodium, N-valmitoyl-N-methyl-β
- Sodium alanine, N-oleyl-N-methyl-β
- Sodium alanine, coconut oil fatty acid acyl sarcosine triethanolamine, lauroyl sarcosine triethanolamine, N-coco fatty acid acyl-N-methyl-
β-alanine triethanolamine, N-lauroyl-
N-methyl-β-alanine triethanolamine, coconut oil fatty acid acyl sarcosine lysine, lauroyl sarcosine lysine, N-coco fatty acid acyl-N~methyl-β-alanine lysine, N-lauroyl-N-methyl-β-alanine lysine, etc. There is.
本発明の（Ａ）成分と（Ｂ）成分の配合比率は５：９５
〜４０：６０が好ましく。この比率以外では、泡立ちが
劣り好ましくない。The blending ratio of component (A) and component (B) of the present invention is 5:95
-40:60 is preferable. A ratio other than this is not preferable due to poor foaming.
本発明のシャンプー組成物に配合される他の界面活性剤
としては、脂肪酸石けん、高級アルコール硫酸エステル
塩、ポリオキシエチレン高級アルコール硫酸エステル塩
、高級アルコールリン酸エステル塩、ポリオキシエチレ
ン高級アルコールリン酸エステル塩、ポリオキシエチレ
ン高級脂肪酸リン酸エステル塩、スルホン化高級脂肪酸
塩、スルホン化高級脂肪酸塩、高級アルコールエステル
塩、高級アルコールスルホコハク酸エステル塩、アシル
メチルタウリン、Ｎ−長鎖アシル−グルタミン酸塩、ア
シルイセチオン酸塩、α−オレフィンスルホン酸塩など
のアニオン界面活性剤、脂肪酸ジェタノールアミド、脂
肪酸モノエタノールアミド、ポリオキシエチレン脂肪酸
モノエタノールアミド等のノニオン界面活性剤、イミダ
シリン型及びアミドベタイン型両性界面活性剤、第４級
アンモニウム塩型カチオン界面活性剤等のカチオン界面
活性剤等である。Other surfactants that may be incorporated into the shampoo composition of the present invention include fatty acid soap, higher alcohol sulfate salt, polyoxyethylene higher alcohol sulfate salt, higher alcohol phosphate salt, and polyoxyethylene higher alcohol phosphate salt. Ester salt, polyoxyethylene higher fatty acid phosphate ester salt, sulfonated higher fatty acid salt, sulfonated higher fatty acid salt, higher alcohol ester salt, higher alcohol sulfosuccinate ester salt, acylmethyltaurine, N-long chain acyl-glutamate, Anionic surfactants such as acyl isethionate and α-olefin sulfonate, nonionic surfactants such as fatty acid jetanolamide, fatty acid monoethanolamide, polyoxyethylene fatty acid monoethanolamide, imidacillin type and amidobetaine type amphoteric surfactants and cationic surfactants such as quaternary ammonium salt type cationic surfactants.
なお、必要に応じて、グリコール類等の可溶化剤、エス
テル油等のエモリエント剤、ヒアルロン酸、キチン、キ
トサン等の保湿剤、アロエエキス胎磐抽出液等の細胞賦
活剤、アラントイン、グリチルリチン酸等の消炎剤、ジ
ンクピリチオン、ピロクトンオラミン等の抗フケ剤及び
殺菌剤、香料色素などを加えることができる。In addition, if necessary, solubilizers such as glycols, emollients such as ester oil, moisturizers such as hyaluronic acid, chitin, and chitosan, cell activators such as aloe extract and staghorn extract, allantoin, glycyrrhizinic acid, etc. Anti-inflammatory agents, anti-dandruff agents and bactericidal agents such as zinc pyrithione and piroctone olamine, fragrance pigments, etc. can be added.
以下実施例により本発明の詳細な説明する。The present invention will be explained in detail below with reference to Examples.
実施例１〜７５、比較例１〜３
有効成分２０％の液体洗浄剤組成物を調製し、使用感（
洗髪後）、泡立ちを評価した。結果を第１表に示す。Examples 1 to 75, Comparative Examples 1 to 3 Liquid detergent compositions containing 20% of active ingredients were prepared, and the feeling of use (
After hair washing), foaming was evaluated. The results are shown in Table 1.
〈評価方法〉
何１４
純分０．２５％、４０°Ｃでロス・マイルス方法にて測
定。<Evaluation method> 14 Measured using the Ross-Miles method at 40°C with a pure content of 0.25%.
使用感
長さ約２０ｃｍ、重さ約５ｇの毛束を予め濡らしておき
、シャンプー１ｇをつけ、軽く指先で洗髪しな。その後
、温水で充分にすすいだ後、風乾燥し、毛束の外観を肉
眼で観察した。各シャンプーについてこの操作を５回お
こない次ぎのように判定した。Pre-wet a bundle of hair approximately 20 cm long and weighing approximately 5 g, apply 1 g of shampoo, and lightly wash with your fingertips. Thereafter, the hair strands were thoroughly rinsed with warm water, air-dried, and the appearance of the hair bundles was visually observed. This operation was repeated 5 times for each shampoo and the results were evaluated as follows.
毛束のまとまりがよいもの・・・ ・○毛束のまとまり
が比較的よいもの・・Δ毛束のまとまりが悪いもの ・
・・・×実施例６〜１０、比較例４〜６
活性剤骨２０％の液体洗浄剤を調製し、使用感（入浴後
のしっとり感）、泡立ちを評価した。結果を第２表に示
す。Hair bundles that are well organized... ○ Hair bundles that are relatively well organized...Δ Hair bundles that are poorly organized.
...x Examples 6 to 10, Comparative Examples 4 to 6 Liquid detergents containing 20% active agent bone were prepared, and the feeling of use (moist feeling after bathing) and foaming were evaluated. The results are shown in Table 2.
（使用感の評価方法）
各ボディシャンプーを５人のパネルに入浴時に使わせ入
浴後のしっとり感が、
優れていたもの・・・・・・・・・・・＋１点ややしっ
とり感が認められるなもの・・・Ｏ点しっとり怒の認め
られなかったもの・・＝１点と評価させその合計により
、次ぎのように評価した。(Method for evaluating the feeling of use) Each body shampoo was used by a panel of 5 people during bathing, and the moist feeling after bathing was excellent. +1 point. Slightly moist feeling was recognized. Items were evaluated as O. Items in which no anger was recognized were evaluated as 1 point. Based on the total, the following evaluations were made.
３〜５点・・・・・０
２〜２点・・・・・Δ
３〜−５点・・・・×
実施例１１
コンディショニングシャンプー 重量％・ヤシ
油脂肪酸アシルサルコシン ３％ラウロイルメ
チル−β−アラニントリエタノールアミン
１２％ステアリルトリメチルアンモニウ
ムクロライド１％
トリエタノールアミンラウリルサルフェート５％
ラウリン酸ジェタノールアミド ０．５％・カチ
オン化セルロース ０．５％・カルボキ
シメチルキチン ０．２％・ＥＤＴＡ
Ｏ，１％・水
残部実施例１２
ボディシャンプー 重量％ラウロ
イルサルコシントリエノールアミン１５％
・ラウロイルメチル−β−アラニン ２％・ラウ
リン酸アミドプロピルジメチルアミノ酢酸ベタイン
５％・Ｎ−ヤシ油脂肪酸
アシル−し−グルタミン酸モノトリエタノールアミン
３％・ラウリン酸ジェタノールアミド
２％・ジステアリン酸エチレングリコール
１％・ヤシ油脂肪酸モノエタノールアミド ０．５
％・ヒアルロン酸ナトリウム ０．５％メ
チルパラベン ０１％・香料
適量・水
残部実施例１１と１２の各液
体洗浄剤の泡立ちは優れており、実施例１０のシャンプ
ー組成物は使用後の髪のまとまり良く、実施例１１のボ
ディシャンプーは使用後のしっとり惑が優れていた。3-5 points...0 2-2 points...Δ 3--5 points...× Example 11 Conditioning shampoo Weight% Coconut oil fatty acid acylsarcosine 3% lauroylmethyl-β- alanine triethanolamine
12% stearyltrimethylammonium chloride 1% triethanolamine lauryl sulfate 5% lauric acid jetanolamide 0.5%, cationized cellulose 0.5%, carboxymethyl chitin 0.2%, EDTA
O, 1%/water
Remaining Example 12 Body Shampoo Weight % Lauroylsarcosine trienolamine 15% ・Lauroylmethyl-β-alanine 2% ・Amidopropyl laurate dimethylaminoacetic acid betaine
5% N-coconut oil fatty acid acyl-glutamic acid monotriethanolamine
3% Lauric acid jetanolamide
2% ethylene glycol distearate
1% Coconut oil fatty acid monoethanolamide 0.5
%・Sodium hyaluronate 0.5% Methylparaben 01%・Fragrance
Appropriate amount/water
The remaining liquid detergents of Examples 11 and 12 had excellent lathering, the shampoo composition of Example 10 had good hair tightness after use, and the body shampoo of Example 11 had excellent moisturizing properties after use. .
ｉ−Δ１」
Ｎ−アシル中性アミノ酸とＮ−アシル中性アミノ酸塩を
特定の比率で併用することにより、泡立ちが優れ、シャ
ンプーに使用したときは洗髪後の髪のまとまりが良く、
ボディシャンプーに使用した時は使用後のしっとり感が
優れた液体洗浄剤が得られる。i-Δ1" By using N-acyl neutral amino acid and N-acyl neutral amino acid salt together in a specific ratio, it has excellent lathering, and when used in shampoo, it makes the hair manageable after washing.
When used as a body shampoo, a liquid detergent with excellent moisturizing feeling after use can be obtained.
Claims (1)
の飽和又は脂肪酸残基、ｎは１ないし２の整数を表す。 ） で示されるＮ−アシル中性アミノ酸、 （Ｂ）一般式（２） ▲数式、化学式、表等があります▼（２） （式中、Ｒ＿２ＣＯは炭素数１０〜１８直鎖又は分岐鎖
の飽和又は脂肪酸残基、ｎは１ないし２の整数、Ｍはア
ルカリ金属、アルカノールアミン、アンモニウム、塩基
性アミノ酸を表わす。）で示されるＮ−アシル中性アミ
ノ酸塩、 を必須成分とし、（Ａ）：（Ｂ）の比が５：９５〜４０
：６０である液体洗浄剤組成物。[Claims] 1. The following two components (A) and (B) (A) General formula (1) ▲ Numerical formulas, chemical formulas, tables, etc. ▼ (1) (In the formula, R_1CO has 10 to 10 carbon atoms. (B) General formula (2) ▲ Numerical formula, chemical formula, table, etc. ▼(2) (In the formula, R_2CO is a linear or branched saturated or fatty acid residue with 10 to 18 carbon atoms, n is an integer of 1 to 2, and M is an alkali metal, alkanolamine, ammonium, or basic amino acid. N-acyl neutral amino acid salt represented by ) is an essential component, and the ratio of (A):(B) is 5:95 to 40.
:60 liquid cleaning composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP27568690A JP2961216B2 (en) | 1990-10-15 | 1990-10-15 | Liquid detergent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP27568690A JP2961216B2 (en) | 1990-10-15 | 1990-10-15 | Liquid detergent composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH04149299A true JPH04149299A (en) | 1992-05-22 |
| JP2961216B2 JP2961216B2 (en) | 1999-10-12 |
Family
ID=17558943
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP27568690A Expired - Fee Related JP2961216B2 (en) | 1990-10-15 | 1990-10-15 | Liquid detergent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2961216B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2014205857A (en) * | 2014-08-04 | 2014-10-30 | 旭化成ケミカルズ株式会社 | Detergent composition |
-
1990
- 1990-10-15 JP JP27568690A patent/JP2961216B2/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2014205857A (en) * | 2014-08-04 | 2014-10-30 | 旭化成ケミカルズ株式会社 | Detergent composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2961216B2 (en) | 1999-10-12 |
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