JPH0913096A - Detergent composition - Google Patents
Detergent compositionInfo
- Publication number
- JPH0913096A JPH0913096A JP7188223A JP18822395A JPH0913096A JP H0913096 A JPH0913096 A JP H0913096A JP 7188223 A JP7188223 A JP 7188223A JP 18822395 A JP18822395 A JP 18822395A JP H0913096 A JPH0913096 A JP H0913096A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- composition
- foam
- formula
- feel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、高級脂肪酸塩、つまり
石鹸を用いたボデイシヤンプ―、洗顔フオ―ムなどの身
体洗浄用の洗浄剤組成物に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a detergent composition for body washing such as body soap, facial cleansing foam, etc. using a higher fatty acid salt, that is, soap.
【０００２】[0002]
【従来の技術】従来、ボデイシヤンプ―、洗顔料などの
皮膚洗浄料の主成分は石鹸であつた。しかし、石鹸は洗
浄後につつぱり感を有するとともに、近年皮膚に対する
刺激などが指摘されるようになつてきている。2. Description of the Related Art Conventionally, soap has been the main component of skin cleansing agents such as body wash and facial cleanser. However, soap has a dry feeling after being washed, and in recent years, it has been pointed out that irritation to the skin or the like has occurred.
【０００３】そこで、“皮膚に対してマイルド”といつ
た低刺激性の界面活性剤であるアシルアミノ酸塩、アシ
ルメチルタウリン塩、アミドエ―テルサルフエ―トなど
のアニオン性界面活性剤や、アミドプロピルベタイン、
アミドアミン塩、アルキルイミノジ酢酸塩などの両性界
面活性剤との併用がなされるようになつている。しかし
ながら、これらのイオン性界面活性剤を使用すると、洗
浄時および洗浄後に不快な“ぬめり”が生じて、さつぱ
り感が損なわれるだけでなく、安定性においても“た
れ”などを生じることがあつた。Therefore, anionic surfactants such as acylamino acid salt, acylmethyl taurine salt, amide ether sulphate, which are mild surfactants for "skin mild", and amidopropyl betaine. ,
It has come to be used in combination with amphoteric surfactants such as amidoamine salts and alkyliminodiacetic acid salts. However, when these ionic surfactants are used, unpleasant "sliminess" occurs during and after washing, not only the feeling of dryness is impaired, but also "sagging" occurs in stability. Atsuta
【０００４】このため、特開平５−２６２６３９号公報
においては、石鹸とポリエチレングリコ―ルまたはエス
テルノニオンを組み合わせることにより、石鹸の持つさ
つぱり感を損なわずに皮膚に対する刺激を小さくした洗
浄剤組成物を提案している。しかるに、この洗浄剤組成
物は、泡のクリ―ミ―性に欠けるだけでなく、安定性に
も問題があつた。また、製品における外観の改善を目的
として、パ―ル化剤の添加を行う場合、パ―ル化が起こ
りにくく、パ―ル状の製品とすることが困難であつた。
さらに、経時的な粘度変化が大きく、一定の品質の製品
を製造することが困難であるという問題もあつた。Therefore, in JP-A-5-262639, a detergent composition in which soap and polyethylene glycol or ester nonion are combined to reduce irritation to the skin without impairing the dry feeling of soap. Proposing a thing. However, this cleaning composition not only lacked the creaminess of foam, but also had a problem in stability. In addition, when a palling agent is added for the purpose of improving the appearance of the product, it is difficult to form a pal, and it is difficult to form a pallet-shaped product.
Further, there is a problem that it is difficult to manufacture a product of constant quality because the change in viscosity with time is large.
【０００５】[0005]
【発明が解決しようとする課題】本発明は、このような
従来技術の問題点に鑑み、皮膚刺激性が低く、起泡性に
すぐれるとともに、経時的な粘度変化が小さく、安定性
にすぐれており、またクリ―ミ―な泡質を有し、洗い上
がりの感触が良好で、しかもパ―ル状を呈することが容
易である洗浄剤組成物を提供することを目的とする。In view of such problems of the prior art, the present invention has low skin irritation, excellent foaming property, small change in viscosity with time, and excellent stability. It is also an object of the present invention to provide a detergent composition which has a creamy foam quality, has a good feeling after washing, and is easily formed into a pallet.
【０００６】[0006]
【課題を解決するための手段】本発明者らは、上記の目
的を達成するために、鋭意検討した結果、石鹸とポリエ
チレングリコ―ルとアルカノ―ルアミド型界面活性剤と
を特定の比率で組み合わせることにより、前記の特性を
すべて満足する洗浄剤組成物が得られることを見い出
し、本発明を完成するに至つた。Means for Solving the Problems As a result of intensive studies to achieve the above object, the present inventors have combined soap, polyethylene glycol and an alkanolamide type surfactant in a specific ratio. As a result, it was found that a detergent composition satisfying all of the above characteristics can be obtained, and the present invention has been completed.
【０００７】すなわち、本発明は、下記のａ〜ｃ成分； ａ）式（Ｉ) で示される高級脂肪酸塩３〜５０重量％ Ｒ1 ＣＯＯＭ1 …（Ｉ） （Ｒ1 は炭素数７〜２１の水酸基を有することがある直
鎖状もしくは分岐状の飽和または不飽和の炭化水素基、
Ｍ1 はアルカリ金属原子、アンモニウム基または有機ア
ミンのカチオン性残基である） ｂ）式（II) で示されるポリエチレングリコ―ル０．１
〜１０重量％ ＨＯ−（ＣＨ2 ＣＨ2 Ｏ）n −Ｈ …（II） （ｎはエチレンオキサイドの平均付加モル数で、１０〜
５００である） ｃ）式（III ) で示されるアルカノ―ルアミド型界面活
性剤１〜１０重量％ （Ｒ2 は炭素数７〜２１の水酸基を有することがある直
鎖状もしくは分岐状の飽和または不飽和の炭化水素基、
ｏ，ｐは各々０〜４の整数で、少なくともひとつは０で
ない）を含有し、ａ成分＋ｂ成分＋ｃ成分＝５〜６０重
量％であることを特徴とする洗浄剤組成物に係るもので
ある。That is, the present invention provides the following components a to c: a) 3 to 50% by weight of a higher fatty acid salt represented by the formula (I) R 1 COOM 1 (I) (R 1 has 7 to 21 carbon atoms) A linear or branched saturated or unsaturated hydrocarbon group which may have a hydroxyl group,
M 1 is an alkali metal atom, an ammonium group or a cationic residue of an organic amine) b) Polyethylene glycol 0.1 represented by the formula (II)
10 wt% HO- by (CH 2 CH 2 O) n -H ... (II) (n is the average addition number of moles of ethylene oxide, 10
500) c) 1 to 10% by weight of an alkanolamide type surfactant represented by the formula (III) (R 2 is a linear or branched saturated or unsaturated hydrocarbon group which may have a hydroxyl group having 7 to 21 carbon atoms,
o and p are each an integer of 0 to 4, at least one of which is not 0), and a component + b component + c component = 5 to 60% by weight. .
【０００８】[0008]
【発明の構成・作用】本発明におけるａ成分の高級脂肪
酸塩は、前記の式（Ｉ) で示されるもので、式中、Ｒ1
は炭素数７〜２１の水酸基を有することがある直鎖状も
しくは分岐状の飽和または不飽和の炭化水素基であり、
またＭ1 はアルカリ金属原子、アンモニウム基または有
機アミンのカチオン性残基である。The higher fatty acid salt of the component a in the present invention is represented by the above formula (I), wherein R 1
Is a linear or branched saturated or unsaturated hydrocarbon group which may have a hydroxyl group having 7 to 21 carbon atoms,
M 1 is an alkali metal atom, an ammonium group or a cationic residue of an organic amine.
【０００９】このような高級脂肪酸塩としては、たとえ
ば、ラウリン酸カリウム、ラウリン酸ナトリウム、ラウ
リン酸トリエタノ―ルアミン塩、ミリスチン酸カリウ
ム、ミリスチン酸ナトリウム、ミリスチン酸トリエタノ
―ルアミン塩、パルミチン酸カリウム、パルミチン酸ナ
トリウム、パルミチン酸トリエタノ―ルアミン塩、ステ
アリン酸カリウム、ステアリン酸ナトリウム、ステアリ
ン酸トリエタノ―ルアミン塩、オレイン酸カリウム、オ
レイン酸ナトリウム、オレイン酸トリエタノ―ルアミン
塩、ヤシ油脂肪酸カリウム、ヤシ油脂肪酸ナトリウム、
ヤシ油脂肪酸トリエタノ―ルアミン塩、牛脂脂肪酸カリ
ウム、牛脂脂肪酸ナトリウム、牛脂脂肪酸トリエタノ―
ルアミン塩などがある。Examples of such higher fatty acid salts include potassium laurate, sodium laurate, triethanolamine laurate, potassium myristate, sodium myristate, triethanolamine myristate, potassium palmitate, palmitate. Sodium, palmitic acid triethanolamine salt, potassium stearate, sodium stearate, stearic acid triethanolamine salt, potassium oleate, sodium oleate, oleic acid triethanolamine salt, coconut oil fatty acid potassium, coconut oil fatty acid sodium,
Palm oil fatty acid triethanolamine salt, tallow fatty acid potassium, tallow fatty acid sodium, tallow fatty acid triethano
There are ruamine salts.
【００１０】なお、これらの高級脂肪酸塩を洗浄剤組成
物中に配合するにあたり、あらかじめ生成した塩を配合
する代わりに、水を含む配合系に高級脂肪酸と水酸化カ
リウム、水酸化ナトリウムなどの塩基を添加混合して、
酸−塩基の反応により相当する高級脂肪酸塩を生成させ
るようにしてもよい。When these higher fatty acid salts are blended in the detergent composition, instead of blending the salt formed in advance, the higher fatty acid and a base such as potassium hydroxide or sodium hydroxide are added to a blending system containing water. Add and mix
Corresponding higher fatty acid salts may be formed by acid-base reaction.
【００１１】本発明におけるｂ成分のポリエチレングリ
コ―ルは、前記の式（II) で示されるもので、式中、エ
チレンオキサイドの平均付加モル数は１０〜５００、好
ましくは２０〜２００であり、たとえば、ポリエチレン
グリコ―ル（２０モル）、ポリエチレングリコ―ル（３
０モル）、ポリエチレングリコ―ル（３５モル）、ポリ
エチレングリコ―ル（４５モル）、ポリエチレングリコ
―ル（７０モル）、ポリエチレングリコ―ル（９０モ
ル）、ポリエチレングリコ―ル（１１０モル）、ポリエ
チレングリコ―ル（１４０モル）などが挙げられる。The polyethylene glycol as the component b in the present invention is represented by the above formula (II), wherein the average number of moles of ethylene oxide added is 10 to 500, preferably 20 to 200, For example, polyethylene glycol (20 mol), polyethylene glycol (3
0 mol), polyethylene glycol (35 mol), polyethylene glycol (45 mol), polyethylene glycol (70 mol), polyethylene glycol (90 mol), polyethylene glycol (110 mol), polyethylene Examples thereof include glycol (140 mol).
【００１２】本発明におけるｃ成分のアルカノ―ルアミ
ド型界面活性剤は、前記の式（III）で示されるもの
で、式中、Ｒ2 は炭素数７〜２１の水酸基を有すること
がある直鎖状もしくは分岐状の飽和または不飽和の炭化
水素基であり、またｏ，ｐは各々０〜４の整数であり、
少なくともひとつは０でない。The alkanolamide type surfactant of component c in the present invention is represented by the above formula (III), in which R 2 may be a linear chain which may have a hydroxyl group having 7 to 21 carbon atoms. A branched or branched saturated or unsaturated hydrocarbon group, and o and p are each an integer of 0 to 4,
At least one is not zero.
【００１３】このようなアルカノ―ルアミド型界面活性
剤としては、たとえば、ラウリン酸モノエタノ―ルアミ
ド、ラウリン酸ジエタノ―ルアミド、ヤシ油脂肪酸モノ
エタノ―ルアミド、ヤシ油脂肪酸ジエタノ―ルアミド、
ミリスチン酸モノエタノ―ルアミド、ミリスチン酸ジエ
タノ―ルアミド、ステアリン酸モノエタノ―ルアミド、
ステアリン酸ジエタノ―ルアミド、オレイン酸モノエタ
ノ―ルアミド、オレイン酸ジエタノ―ルアミド、牛脂脂
肪酸モノエタノ―ルアミド、牛脂脂肪酸ジエタノ―ルア
ミドなどが挙げられる。Examples of such alkanolamide-type surfactants include lauric acid monoethanolamide, lauric acid dietanolamide, coconut oil fatty acid monoethanolamide, coconut oil fatty acid dietanolamide,
Myristic acid monoethanolamide, myristic acid diethanolamide, stearic acid monoethanolamide,
Examples thereof include stearic acid diethanolamide, oleic acid monoethanolamide, oleic acid diethanolamide, tallow fatty acid monoethanolamide, and tallow fatty acid ethanolamide.
【００１４】本発明において、上記のａ成分は、洗浄剤
組成物全体の３〜５０重量％、好ましくは５〜４０重量
％の割合で用いられる。３重量％未満では、十分な洗浄
力および起泡力が得られず、５０重量％を超えると、刺
激性および安定性において問題が生じる。また、上記の
ｂ成分は、洗浄剤組成物全体の０．１〜１０重量％、好
ましくは０．５〜７重量％の割合で用いられる。０．１
重量％未満では、刺激性に問題を生じ、１０重量％を超
えると、泡立ちが悪くなる。さらに、上記のｃ成分は、
洗浄剤組成物全体の１〜１０重量％、好ましくは２〜７
重量％の割合で用いられる。１重量％未満では、泡質お
よび安定性が悪くなるだけでなく、洗浄剤組成物をパ―
ル状にすることが困難であり、しかも経時的な粘度変化
が大きくなり、１０重量％を超えると、泡立ちが悪くな
る。In the present invention, the component a is used in a proportion of 3 to 50% by weight, preferably 5 to 40% by weight, based on the entire detergent composition. If it is less than 3% by weight, sufficient detergency and foaming power cannot be obtained, and if it exceeds 50% by weight, problems occur in irritation and stability. Further, the above-mentioned component b is used in a proportion of 0.1 to 10% by weight, preferably 0.5 to 7% by weight, based on the entire detergent composition. 0.1
If it is less than 10% by weight, there is a problem in irritation and if it exceeds 10% by weight, foaming becomes poor. Furthermore, the c component above is
1 to 10% by weight of the total detergent composition, preferably 2 to 7
Used in percentages by weight. If it is less than 1% by weight, not only the foam quality and stability are deteriorated, but also the detergent composition is impaired.
It is difficult to form a gel, and the change in viscosity over time becomes large, and if it exceeds 10% by weight, foaming becomes worse.
【００１５】また、本発明において、上記のａ成分とｂ
成分とｃ成分とは、これら三成分の合計量が洗浄剤組成
物全体の５〜６０重量％、好ましくは１０〜５０重量％
となるように、各使用量が決定される。５重量％未満で
は、十分な洗浄力および起泡力が得られず、６０重量％
を超えると、安定性が悪くなる。Further, in the present invention, the above-mentioned a component and b
As for the component and the c component, the total amount of these three components is 5 to 60% by weight, preferably 10 to 50% by weight of the entire detergent composition.
Each usage amount is determined so that If it is less than 5% by weight, sufficient detergency and foaming power cannot be obtained, and 60% by weight
If it exceeds, stability becomes poor.
【００１６】本発明においては、洗浄剤組成物をパ―ル
化するために、一般的なパ―ル化剤であるエチレングリ
コ―ル脂肪酸エステルや、ポリエチレングリコ―ル（２
〜３モル）脂肪酸エステル、たとえば、エチレングリコ
―ルモノステアレ―ト、エチレングリコ―ルジステアレ
―ト、ジエチレングリコ―ルモノステアレ―ト、ジエチ
レングリコ―ルジステアレ―トなどを使用できる。In the present invention, ethylene glycol fatty acid ester or polyethylene glycol (2
~ 3 mol) fatty acid ester such as ethylene glycol monostearate, ethylene glycol distearate, diethylene glycol monostearate, diethylene glycol distearate and the like can be used.
【００１７】本発明の洗浄剤組成物には、上記のａ〜ｃ
成分またはこれと上記のパ―ル化剤とのほかに、洗浄剤
に常用されている成分や、添加剤を配合することができ
る。たとえば、高級アルコ―ル、シリコ―ン誘導体、蛋
白誘導体、スクワラン、ホホバ油、オリ―ブ油、ヒマシ
油、ラノリン、レシチンなどの油性成分や、グリセリ
ン、エチレングリコ―ル、プロピレングリコ―ル、１，
３−ブタンジオ―ルなどの保湿剤などを配合することが
できる。The detergent composition of the present invention includes the above ac.
In addition to the components or the above and the above-mentioned pallating agent, components or additives that are commonly used in detergents can be added. For example, oily components such as higher alcohols, silicone derivatives, protein derivatives, squalane, jojoba oil, olive oil, castor oil, lanolin and lecithin, glycerin, ethylene glycol, propylene glycol, 1 ，
A moisturizing agent such as 3-butanediol may be added.
【００１８】また、ポリオキシエチレンアルキルエ―テ
ルなどのノニオン性界面活性剤、アルキルサルフエ―
ト、アルキルエ―テルサルフエ―ト、ポリオキシエチレ
ンアミドエ―テルサルフエ―ト、アシルメチルタウリン
塩、アシルグルタミン酸塩などのアニオン性界面活性
剤、アミドプロピルベタイン、アミドアミン塩、アルキ
ルイミノジ酢酸塩などの両性界面活性剤、第３級アミン
オキシドなどの半極性界面活性剤を配合してもよい。さ
らに、カルボキシビニルポリマ―、ヒドロキシプロピル
メチルセルロ―ス、ヒドロキシエチルセルロ―スなどの
水溶性高分子、殺菌剤、キレ―ト剤、紫外線吸収剤、ｐ
Ｈ調整剤、動植物由来の天然エキス、色素、香料などを
配合することができる。Further, nonionic surfactants such as polyoxyethylene alkyl ethers, alkyl sulfides, etc.
, Alkyl ether sulphate, polyoxyethylene amide ether sulphate, anionic surfactants such as acylmethyl taurine salts and acyl glutamate salts, amphoteric interfaces such as amidopropyl betaine, amido amine salts and alkyl iminodiacetic acid salts You may mix | blend a semipolar surfactant, such as an active agent and a tertiary amine oxide. In addition, water-soluble polymers such as carboxyvinyl polymer, hydroxypropylmethyl cellulose and hydroxyethyl cellulose, bactericides, chelating agents, UV absorbers, p
H regulators, natural extracts derived from animals and plants, pigments, fragrances and the like can be added.
【００１９】[0019]
【実施例】つぎに、実施例によつて本発明をさらに詳細
に説明する。Next, the present invention will be described in more detail with reference to examples.
【００２０】実施例１〜５ 表１に示す配合組成により、５種のボデイシヤンプ―組
成物を調製した。Examples 1 to 5 Five kinds of body pump compositions were prepared according to the composition shown in Table 1.
【００２１】[0021]
【表１】 [Table 1]
【００２２】比較例１〜９ 表２および表３に示す配合組成により、９種のボデイシ
ヤンプ―組成物を調製した。Comparative Examples 1 to 9 Nine kinds of body pump compositions were prepared according to the formulations shown in Tables 2 and 3.
【００２３】[0023]
【表２】 [Table 2]
【００２４】[0024]
【表３】 [Table 3]
【００２５】上記の実施例１〜５および比較例１〜９の
ボデイシヤンプ―組成物について、以下の要領により、
皮膚刺激性、起泡性、粘度変化、経時安定性、泡のクリ
―ミ―性、すすぎ後のぬめり感、すすぎ後のさつぱり
感、パ―ル化の状態を評価した。これらの結果は、後記
の表４および表５に示されるとおりであつた。The body pump compositions of Examples 1 to 5 and Comparative Examples 1 to 9 were prepared as follows.
The skin irritation, foaming property, viscosity change, stability over time, foam creaminess, slimy feeling after rinsing, dry feeling after rinsing, and state of palling were evaluated. These results were as shown in Tables 4 and 5 below.
【００２６】＜皮膚刺激性＞蛋白質変性率により評価し
た。すなわち、水系高速液体クロマトグラフイ―を利用
し、卵白アルブミン０．０２５重量％濃度のｐＨ７緩衝
溶液を用いて、試料濃度１重量％になるように試料を加
えたときの２２０ｎｍの吸収ピ―クの高さを測定し、つ
ぎの式により蛋白質変性率を求めた。 蛋白質変性率＝〔（Ｈ０−ＨＳ）／Ｈ０〕×１００ Ｈ０：試料未添加のときの吸収ピ―クの高さ ＨＳ：試料を添加したときの吸収ピ―クの高さ このように求められる蛋白質変性率により、つぎの４段
階で評価した。 蛋白質変性率３０％未満 ：皮膚刺激性が非常
に弱い 蛋白質変性率３０％以上６０％未満：皮膚刺激性が弱い 蛋白質変性率６０％以上８０％未満：皮膚刺激性が中程
度 蛋白質変性率８０％以上 ：皮膚刺激性が強い<Skin irritation> Evaluation was made by the protein denaturation rate. That is, using an aqueous high-performance liquid chromatograph, using a pH7 buffer solution having a concentration of 0.025% by weight of ovalbumin, and adding a sample to a concentration of 1% by weight, an absorption peak of 220 nm was obtained. Was measured, and the protein denaturation rate was calculated by the following formula. Protein denaturation rate = [(H0−HS) / H0] × 100 H0: height of absorption peak when no sample is added HS: height of absorption peak when sample is added The following four steps were used to evaluate the protein denaturation rate. Protein denaturation rate of less than 30%: very low skin irritation Protein denaturation rate of 30% or more and less than 60%: low skin irritation Protein denaturation rate of 60% or more and less than 80%: moderate skin irritation 80% of protein denaturation rate Above: Strong skin irritation
【００２７】＜起泡性＞試料濃度１重量％の水溶液を調
製してロスマイルス法により、２５℃で試料投入直後と
５分後の泡高さを測定した。試料投入直後の泡高さが２
４０mm以上のものであつて、かつ、つぎの式より求めら
れる泡の持続率が９０％以上のものを泡立ちの良い洗浄
剤と評価した。 泡の持続率＝〔（５分後の泡高さ）／（試料投入直後の
泡高さ）〕×１００<Foaming property> An aqueous solution having a sample concentration of 1% by weight was prepared and the foam height was measured at 25 ° C. immediately after the sample was put in and after 5 minutes by the Los Miles method. The bubble height is 2 immediately after the sample is loaded.
A cleaning agent having a foam length of 40 mm or more and having a foam retention rate of 90% or more obtained by the following formula was evaluated as a cleaning agent having a good foaming property. Foam persistence = [(foam height after 5 minutes) / (foam height immediately after sample introduction)] × 100
【００２８】＜粘度変化＞試料（ボデイシヤンプ―組成
物）の調製直後と３日後の２５℃における粘度をＢ型粘
度計にて測定し、下記の式にしたがつて粘度の変化率を
求め、つぎの３段階で評価した。なお、試料は室温にて
保存した。 ○：粘度の変化率（絶対値）が１０％未満である △：粘度の変化率（絶対値）が１０％以上３０％未満で
ある ×：粘度の変化率（絶対値）が３０％以上である<Viscosity Change> The viscosity at 25 ° C. immediately after the preparation of the sample (body polish composition) and after 3 days was measured with a B type viscometer, and the rate of change in viscosity was calculated according to the following formula. It was evaluated in three stages. The sample was stored at room temperature. ◯: Viscosity change rate (absolute value) is less than 10% Δ: Viscosity change rate (absolute value) is 10% or more and less than 30% x: Viscosity change rate (absolute value) is 30% or more is there
【００２９】＜経時安定性＞試料（ボデイシヤンプ―組
成物）を０℃、２５℃、４５℃で１ケ月間保存し、その
外観を観察して、つぎの３段階で評価した。 ○：安定性良好（固化せず流動性を保ち、外観の変化が
ない） △：安定性やや不良（固化または分離しないが、着色を
生じる） ×：安定性不良（固化または分離する、着色が著しい）<Stability with time> A sample (body-shamp composition) was stored at 0 ° C, 25 ° C and 45 ° C for 1 month, and its appearance was observed and evaluated according to the following three grades. ◯: Good stability (flowability without solidification, no change in appearance) Δ: Slightly poor stability (no solidification or separation, but coloration) X: Poor stability (solidification or separation, coloring Remarkable)
【００３０】＜泡のクリ―ミ―性＞２０名の女性をパネ
ラ―とし、試料（ボデイシヤンプ―組成物）５ｍｌを浴
用スポンジ上にとつたものを用いて、手指および前腕部
を洗浄したときの泡のクリ―ミ―性について評価した。
泡がクリ―ミ―であると感じた場合を２点、ややクリ―
ミ―であると感じた場合を１点、泡がクリ―ミ―でなく
粗いと感じた場合を０点として、２０名の平均値を求め
た。平均値が１．５点以上であるものを泡のクリ―ミ―
性が良好であると評価した。<Creaming creaminess of foam> When 20 women were used as panelers and 5 ml of the sample (body polish composition) was put on a bath sponge, the fingers and forearms were washed. The creaminess of the foam was evaluated.
2 points if you feel the bubbles are creamy, a little clear
The average value of 20 persons was calculated by setting 1 point when it was felt as a meal and 0 point when it was felt that the foam was not creamy but rough. Cream cream with an average value of 1.5 or more
It was evaluated that the property was good.
【００３１】＜すすぎ後のぬめり感＞２０名の女性をパ
ネラ―とし、試料（ボデイシヤンプ―組成物）５ｍｌを
浴用スポンジ上にとつたものを用いて、手指および前腕
部を洗浄し、約４０℃の温湯１リツトルずつを用いて流
しながら、３回すすいだ後のぬめり感を評価した。ぬめ
り感がないと感じた場合を４点、ぬめり感がほとんどな
いと感じた場合を３点、ぬめり感がややあると感じた場
合を２点、ぬめり感がしつこいと感じた場合を１点とし
て、２０名の平均値を求めた。平均値が３．０点以上で
あるものをぬめり感のない組成物と評価した。<Slick feeling after rinsing> Using 20 women as panelers, 5 ml of the sample (body polish composition) was sprinkled on a bath sponge, and the fingers and forearms were washed to about 40 ° C. The sensation of sliminess after rinsing three times was evaluated while flowing 1 liter of warm water each. 4 points if you feel no slimy feeling, 3 points if you feel little slimy feeling, 2 points if you feel a little slimy feeling, 1 point if you feel a slimy feeling is persistent , 20 persons were averaged. A composition having an average value of 3.0 or more was evaluated as a composition having no slimy feel.
【００３２】＜すすぎ後のさつぱり感＞２０名の女性を
パネラ―とし、試料（ボデイシヤンプ―組成物）５ｍｌ
を浴用スポンジ上にとつたものを用いて、手指および前
腕部を洗浄し、約４０℃の温湯１リツトルずつを用いて
流しながら、３回すすいだ後のさつぱり感を評価した。
さつぱり感があると感じた場合を４点、さつぱり感がや
やあると感じた場合を３点、さつぱり感がほとんどない
と感じた場合を２点、さつぱり感が全くないと感じた場
合を１点として、２０名の平均値を求めた。平均値が
３．０点以上であるものをさつぱり感のある組成物と評
価した。<Crisp feeling after rinsing> 20 women as panelers, 5 ml of sample (body polish composition)
The hands and forearms were washed with a bath sponge and washed with 3 liters of hot water at about 40 ° C., and the feeling of dryness after rinsing three times was evaluated.
4 points when you feel that there is a feeling of crispness, 3 points when you feel that there is a feeling of crispness, 2 points when you feel that there is little crispness, and a feeling of crispness at all The average value of 20 persons was calculated by setting 1 point when there was no feeling. A composition having an average value of 3.0 or more was evaluated as a composition having a dry feel.
【００３３】＜パ―ル化の状態＞試料（ボデイシヤンプ
―組成物）を調製したときの状態を観察し、つぎの３段
階で評価した。 ○：調製時に速やかにパ―ル化し、きれいなパ―ル状を
呈する △：パ―ル化に長時間を要し、やや薄いパ―ル状である ×：ほとんどパ―ル化しない、パ―ルが非常に薄い<State of Pallization> The state when the sample (body-shamp composition) was prepared was observed and evaluated in the following three stages. ◯: Produces a clean pallet quickly during preparation Δ: It takes a long time to palletize, and it is a slightly thin pallet. Very thin
【００３４】[0034]
【表４】 [Table 4]
【００３５】[0035]
【表５】 [Table 5]
【００３６】以上の評価結果から明らかなように、実施
例１〜５の本発明のボデイシヤンプ―組成物は、いずれ
も、皮膚に対する刺激性が低いとともに、起泡性にすぐ
れており、しかも粘度変化が小さく、経時安定性にもす
ぐれており、また泡がクリ―ミ―であつて、使用時およ
び使用後の感触が良好であり、そのうえ、きれいなパ―
ル状を呈するものであることがわかる。As is clear from the above evaluation results, all of the bodywash compositions of the present invention of Examples 1 to 5 have low irritation to the skin, excellent foamability, and change in viscosity. Is small, has excellent stability over time, has a creamy foam, has a good feel during and after use, and has a clean surface.
It can be seen that it has a luster shape.
【００３７】これに対して、比較例１〜９のボデイシヤ
ンプ―組成物では十分な性能が得られていない。すなわ
ち、比較例１ではａ成分が本発明の範囲より少なく配合
されているため、泡立ちおよび洗浄後の感触が悪い。比
較例２ではａ成分が本発明の範囲を超えて配合されてい
るため、経時安定性が悪い。比較例３，４ではｂ成分が
配合されていないため、洗浄後の感触が悪くなつてい
る。比較例５ではｂ成分が本発明の範囲を超えて配合さ
れているため、泡立ちが悪い。On the other hand, the body compositions of Comparative Examples 1 to 9 do not show sufficient performance. That is, in Comparative Example 1, since the amount of the component a was less than the range of the present invention, the feel after foaming and washing was poor. In Comparative Example 2, since the component a was blended beyond the range of the present invention, the stability over time was poor. In Comparative Examples 3 and 4, since the component b was not blended, the feel after washing deteriorated. In Comparative Example 5, since the component b was blended beyond the range of the present invention, foaming was poor.
【００３８】また、比較例６，７ではｃ成分が配合され
ていないため、安定性が悪くなつたり、洗浄後の感触が
悪くなつているだけでなく、経時的な粘度変化が著し
く、パ―ル化の状態が悪くなつている。比較例８ではｃ
成分が本発明の範囲を超えて配合されているため、泡立
ちが悪い。比較例９ではａ〜ｃ三成分の合計量が本発明
の範囲を超えているため、安定性に問題を生じている。
この比較例９と前記の比較例２とは、試料調製時に固化
したため、粘度測定は不能であつた。Further, in Comparative Examples 6 and 7, since the component c was not blended, not only the stability was poor and the feeling after washing was poor, but also the viscosity change with time was remarkable, and The condition of the conversion is getting worse. C in Comparative Example 8
Foaming is poor because the ingredients are compounded beyond the scope of the present invention. In Comparative Example 9, since the total amount of the three components a to c exceeds the range of the present invention, stability is a problem.
This Comparative Example 9 and the above Comparative Example 2 were solidified at the time of sample preparation, so that viscosity measurement was impossible.
【００３９】実施例６ ラウリン酸５重量％、ミリスチン酸１５重量％、パルミ
チン酸５重量％、ステアリン酸３重量％、オレイン酸２
重量％、水酸化カリウム５．２重量％、水酸化ナトリウ
ム０．２重量％、ポリエチレングリコ―ル（３０モル）
３重量％、ポリエチレングリコ―ル（１４０モル）２重
量％、ラウリン酸ジエタノ―ルアミド３重量％、Ｎ−ラ
ウロイル−Ｎ−メチルタウリンマグネシウム１重量％、
ラウリルアミドプロピルジメチルアミノ酢酸ベタイン１
重量％、グリセリン４重量％、１，３−ブタンジオ―ル
８重量％およびエチレングリコ―ルジステアレ―ト２重
量％、防腐剤０．３重量％、香料０．４重量％および精
製水残部により、洗顔フオ―ム組成物を調製した。Example 6 Lauric acid 5% by weight, myristic acid 15% by weight, palmitic acid 5% by weight, stearic acid 3% by weight, oleic acid 2
% By weight, 5.2% by weight of potassium hydroxide, 0.2% by weight of sodium hydroxide, polyethylene glycol (30 mol)
3% by weight, polyethylene glycol (140 mol) 2% by weight, lauric acid dietanolamide 3% by weight, N-lauroyl-N-methyltaurine magnesium 1% by weight,
Laurylamidopropyl dimethylaminoacetic acid betaine 1
%, Glycerin 4%, 1,3-butanediol 8% by weight and ethylene glycol distearate 2% by weight, preservative 0.3% by weight, perfume 0.4% by weight and a balance of purified water to cleanse the face. A foam composition was prepared.
【００４０】この洗顔フオ―ム組成物について、皮膚刺
激性、起泡性、経時安定性、泡のクリ―ミ―性、すすぎ
時のぬめり感、洗顔後のさつぱり感、洗顔後の肌のつつ
ぱり感、パ―ル化の状態を評価した。評価方法は、皮膚
刺激性、起泡性、パ―ル化の状態については前記と同じ
であり、他の項目は以下の要領で評価した。About this face-washing foam composition, skin irritation, foaming property, stability over time, foam creaminess, slimy feeling during rinsing, dry feeling after washing, skin after washing The feeling of crunch and the state of palletization were evaluated. The evaluation method was the same as the above with respect to skin irritation, foaming property, and palletized state, and other items were evaluated according to the following procedures.
【００４１】＜経時安定性＞試料（洗顔フオ―ム組成
物）を０℃、２５℃、４０℃で１ケ月間保存し、その外
観を観察して、つぎの３段階で評価した。 ○：安定性良好（外観の変化がない、「たれ」が生じな
い、「ぶつ」などを生じない） △：安定性やや不良（やや「たれ」が生じる、やや「ぶ
つ」などを生じる、着色する） ×：安定性不良（固化する、「たれ」が生じる、「ぶ
つ」などを生じる、着色が著しい）<Stability over time> The sample (facial washing foam composition) was stored at 0 ° C, 25 ° C and 40 ° C for 1 month, and its appearance was observed and evaluated according to the following three grades. ◯: Good stability (no change in appearance, no “dripping”, no “bugs”) Δ: Slightly poor stability (slightly “dripping”, some “bugs”, coloring X): Poor stability (solidification, “sag” occurs, “bumps”, etc., coloring is remarkable)
【００４２】＜泡のクリ―ミ―性＞２０名の女性をパネ
ラ―とし、試料（洗顔フオ―ム組成物）２ｇで洗顔した
ときの泡のクリ―ミ―性について評価した。泡がクリ―
ミ―であると感じた場合を２点、ややクリ―ミ―である
と感じた場合を１点、泡がクリ―ミ―でなく粗いと感じ
た場合を０点として、２０名の平均値を求めた。平均値
が１．５点以上であるものを泡のクリ―ミ―性が良好で
あると評価した。<Creaming Creaminess of Foam> The creaminess of foam when 20 women were panelists and the face was washed with 2 g of the sample (facial cleansing foam composition) was evaluated. Bubbles are clear
The average value of 20 people, with 2 points when it was felt to be meal, 1 point when it was felt to be slightly creamy, and 0 point when it was felt that the bubbles were not creamy but rough. I asked. Those having an average value of 1.5 or more were evaluated as having good foam creaminess.
【００４３】＜すすぎ時のぬめり感＞２０名の女性をパ
ネラ―とし、試料（洗顔フオ―ム組成物）２ｇで洗顔
し、すすいだ時のぬめり感を評価した。ぬめり感がない
と感じた場合を４点、ぬめり感がほとんどないと感じた
場合を３点、ぬめり感がややあると感じた場合を２点、
ぬめり感がしつこいと感じた場合を１点として、２０名
の平均値を求めた。平均値が３．０点以上であるものを
ぬめり感のない組成物と評価した。<Slick feeling at the time of rinsing> 20 women were used as panelers to wash their faces with 2 g of the sample (facial cleansing foam composition), and the slimy feeling at the time of rinsing was evaluated. 4 points if you feel no slimy feeling, 3 points if you feel little slimy feeling, 2 points if you feel a little slimy feeling,
The average value of 20 persons was calculated with one point when the feeling of sliminess was persistent. A composition having an average value of 3.0 or more was evaluated as a composition having no slimy feel.
【００４４】＜洗顔後のさつぱり感＞２０名の女性をパ
ネラ―とし、試料（洗顔フオ―ム組成物）２ｇで洗顔
し、すすいだ後のさつぱり感を評価した。さつぱり感が
あると感じた場合を４点、さつぱり感がややあると感じ
た場合を３点、さつぱり感がほとんどないと感じた場合
を２点、さつぱり感が全くないと感じた場合を１点とし
て、２０名の平均値を求めた。平均値が３．０点以上で
あるものを洗顔後にさつぱり感のある組成物と評価し
た。<Rashing Feeling after Washing> Twenty (20) women were used as panelers to wash their faces with 2 g of a sample (facial washing foam composition), and the touching feeling after rinsing was evaluated. 4 points when you feel that there is a feeling of crispness, 3 points when you feel that there is a feeling of crispness, 2 points when you feel that there is little crispness, and a feeling of crispness at all The average value of 20 persons was calculated by setting 1 point when there was no feeling. A composition having an average value of 3.0 or more was evaluated as a composition having a dry feeling after washing the face.
【００４５】＜洗顔後の肌のつつぱり感＞２０名の女性
をパネラ―とし、試料（洗顔フオ―ム組成物）２ｇで洗
顔し、すすいだ後の肌のつつぱり感を評価した。つつぱ
り感が全くないと感じた場合を４点、つつぱり感がほと
んどないと感じた場合を３点、つつぱり感がややあると
感じた場合を２点、強いつつぱり感を感じた場合を１点
として、２０名の平均値を求めた。平均値が３．０点以
上であるものを洗顔後に肌のつつぱり感のない組成物と
評価した。<Peeling sensation of skin after face washing> 20 women were used as panelers to wash their faces with 2 g of a sample (facial cleansing foam composition), and the tingling sensation of skin after rinsing was evaluated. 4 points if you feel no trumpiness at all, 3 points if you feel little twitching, 2 points if you feel a little twitching, and 2 points if you feel a strong twitching Was set as 1 point and the average value of 20 persons was calculated. A composition having an average value of 3.0 or more was evaluated as a composition having no tingling sensation on the skin after washing the face.
【００４６】結果は、蛋白質変性率は２６％、試料投入
直後の高さは２４２mm、泡の持続率は９７％、経時安定
性は○、泡のクリ―ミ―性は１．８、すすぎ後のぬめり
感は３．８、洗顔後のさつぱり感は３．９、洗顔後の肌
のつつぱり感は３．７、パ―ル化の状態は○であつた。
この結果から、この洗顔フオ―ム組成物は、皮膚に対す
る刺激性が低く、しかも起泡性にすぐれているととも
に、経時安定性にもすぐれており、また泡がクリ―ミ―
であつて、使用時および使用後の感触が良好であり、肌
がつつぱらず、パ―ル化の状態も良好であることがわか
る。As a result, the protein denaturation rate was 26%, the height immediately after the introduction of the sample was 242 mm, the foam retention rate was 97%, the stability over time was ○, the foam creaminess was 1.8, and after rinsing. The slimy feeling was 3.8, the dry feeling after washing the face was 3.9, the tingling sensation of the skin after washing the face was 3.7, and the state of palletization was ○.
From these results, this facial cleansing foam composition has low irritation to the skin, excellent foaming property, and excellent stability over time, and has a creamy foam.
In addition, it can be seen that the feel during and after use is good, the skin does not crumble, and the state of palling is also good.
【００４７】実施例７ ミリスチン酸２１重量％、パルミチン酸５重量％、ステ
アリン酸４重量％、オレイン酸２重量％、水酸化カリウ
ム５．２重量％、水酸化ナトリウム０．２重量％、ポリ
エチレングリコ―ル（３０モル）３重量％、ポリエチレ
ングリコ―ル（１４０モル）１重量％、ラウリン酸ジエ
タノ―ルアミド１重量％、ヤシ油脂肪酸ジエタノ―ルア
ミド２重量％、グリセリン９重量％、１，３−ブタンジ
オ―ル９重量％、防腐剤０．３重量％、香料０．４重量
％および精製水残部により、洗顔フオ―ム組成物を調製
した。Example 7 21% by weight myristic acid, 5% by weight palmitic acid, 4% by weight stearic acid, 2% by weight oleic acid, 5.2% by weight potassium hydroxide, 0.2% by weight sodium hydroxide, polyethylene glycol -(30 mol) 3% by weight, polyethylene glycol (140 mol) 1% by weight, lauric acid diethylanolamide 1% by weight, coconut oil fatty acid dietanolamide 2% by weight, glycerin 9% by weight, 1,3- A facial cleansing foam composition was prepared with 9% by weight of butanediol, 0.3% by weight of preservative, 0.4% by weight of fragrance and the balance of purified water.
【００４８】この洗顔フオ―ム組成物について、前記と
同様にして評価した。結果は、蛋白質変性率は２７％、
試料投入直後の高さは２４７mm、泡の持続率は９６％、
経時安定性は○、泡のクリ―ミ―性は１．８、すすぎ後
のぬめり感は３．９、洗顔後のさつぱり感は３．９、洗
顔後の肌のつつぱり感は３．８、パ―ル化の状態は○で
あつた。この結果から、この洗顔フオ―ム組成物は、皮
膚に対する刺激性が低く、しかも起泡性にすぐれている
とともに、経時安定性にもすぐれており、また泡がクリ
―ミ―であつて、使用時および使用後の感触が良好であ
り、肌がつつぱらず、パ―ル化の状態も良好であること
がわかる。The facial cleansing foam composition was evaluated in the same manner as described above. The result shows that the protein denaturation rate is 27%,
Height immediately after sample loading is 247 mm, foam retention rate is 96%,
Stability with time is ○, creaminess of foam is 1.8, sliminess after rinsing is 3.9, dryness after washing the face is 3.9, skin tingling after washing is 3 .8, the state of palletization was ○. From this result, this facial cleansing foam composition has low irritation to the skin, is excellent in foaming property, is also excellent in stability over time, and has a creamy foam. It can be seen that the feel during use and after use is good, the skin does not crumble, and the state of palling is also good.
【００４９】実施例８ ラウリン酸カリウム８重量％、ミリスチン酸カリウム４
重量％、パルミチン酸カリウム２重量％、オレイン酸カ
リウム２重量％、ポリエチレングリコ―ル（３０モル）
１重量％、ラウリン酸ジエタノ―ルアミド５重量％、エ
チレングリコ―ルジステアレ―ト１．７重量％、防腐剤
０．３重量％、香料０．５重量％および精製水残部によ
り、ボデイシヤンプ―組成物を調製した。Example 8 Potassium laurate 8% by weight, potassium myristate 4
% By weight, potassium palmitate 2% by weight, potassium oleate 2% by weight, polyethylene glycol (30 mol)
1% by weight, 5% by weight of lauric acid diethylanolamide, 1.7% by weight of ethylene glycol distearate, 0.3% by weight of preservative, 0.5% by weight of perfume and the balance of purified water to form a body-shamp composition. Prepared.
【００５０】このボデイシヤンプ―組成物について、前
記と同様にして評価した。結果は、蛋白質変性率は２６
％、試料投入直後の高さは２６１mm、泡の持続率は９５
％、調製直後の粘度（２５℃）は１，０４３ｃｐｓ、３
日後の同粘度は１，０４７ｃｐｓで、粘度変化は○、経
時安定性は○、泡のクリ―ミ―性は２．０、すすぎ後の
ぬめり感は３．９、すすぎ後のさつぱり感は３．９、パ
―ル化の状態は○であつた。この結果から、このボデイ
シヤンプ―組成物は、皮膚に対する刺激性が低く、しか
も起泡性にすぐれているとともに、粘度変化が小さく、
経時安定性にもすぐれており、また泡がクリ―ミ―であ
つて、使用時および使用後の感触が良好であり、パ―ル
化の状態も良好であることがわかる。The body composition was evaluated in the same manner as above. The result shows that the protein denaturation rate is 26.
%, Height immediately after sample introduction is 261 mm, and foam retention rate is 95%
%, Viscosity immediately after preparation (25 ° C.) is 1,043 cps, 3
Same viscosity after day, 1,047 cps, change in viscosity was ○, stability with time was ○, creaminess of foam was 2.0, sliminess after rinsing was 3.9, crispness after rinsing Was 3.9, and the state of palletization was ○. From this result, this body polish composition has low irritation to the skin, excellent foaming property, and small change in viscosity,
It can be seen that it has excellent stability over time, and that the foam is creamy, and that it has a good feel during and after use, and that it is in a well-palled state.
【００５１】実施例９ ラウリン酸カリウム７重量％、ミリスチン酸カリウム３
重量％、パルミチン酸カリウム１重量％、ステアリン酸
カリウム１重量％、オレイン酸カリウム２重量％、ポリ
エチレングリコ―ル（３０モル）１重量％、ポリエチレ
ングリコ―ル（１４０モル）１重量％、ヤシ油脂肪酸ジ
エタノ―ルアミド５重量％、Ｎ−ココイル−Ｎ−メチル
タウリンナトリウム２重量％、エチレングリコ―ルジス
テアレ―ト１．７重量％、防腐剤０．３重量％、香料
０．５重量％および精製水残部により、ボデイシヤンプ
―組成物を調製した。Example 9 7% by weight potassium laurate, 3 potassium myristate
% By weight, potassium palmitate 1% by weight, potassium stearate 1% by weight, potassium oleate 2% by weight, polyethylene glycol (30 mol) 1% by weight, polyethylene glycol (140 mol) 1% by weight, coconut oil Fatty acid diethanolamide 5% by weight, N-cocoyl-N-methyltaurine sodium 2% by weight, ethylene glycol distearate 1.7% by weight, preservative 0.3% by weight, perfume 0.5% by weight and purified water A balance was used to prepare a body pump composition.
【００５２】このボデイシヤンプ―組成物について、前
記と同様にして評価した。結果は、蛋白質変性率は２５
％、試料投入直後の高さは２５９mm、泡の持続率は９６
％、調製直後の粘度（２５℃）は１，３２５ｃｐｓ、３
日後の同粘度は１，３３４ｃｐｓで、粘度変化は○、経
時安定性は○、泡のクリ―ミ―性は１．９、すすぎ後の
ぬめり感は３．８、すすぎ後のさつぱり感は３．８、パ
―ル化の状態は○であつた。この結果から、このボデイ
シヤンプ―組成物は、皮膚に対する刺激性が低く、しか
も起泡性にすぐれているとともに、粘度変化が小さく、
経時安定性にもすぐれており、また泡がクリ―ミ―であ
つて、使用時および使用後の感触が良好であり、パ―ル
化の状態も良好であることがわかる。The body composition was evaluated in the same manner as described above. The result shows that the protein denaturation rate is 25.
%, Height immediately after sample introduction is 259 mm, foam retention rate is 96
%, Viscosity immediately after preparation (25 ° C.) is 1,325 cps, 3
Same viscosity after day, 1,334 cps, change in viscosity is ○, stability over time is ○, creaminess of foam is 1.9, slimy feeling after rinsing is 3.8, crisp feeling after rinsing Was 3.8 and the state of palletization was ○. From this result, this body polish composition has low irritation to the skin, excellent foaming property, and small change in viscosity,
It can be seen that it has excellent stability over time, and that the foam is creamy, and that it has a good feel during and after use, and that it is in a well-palled state.
【００５３】実施例１０ ラウリン酸トリエタノ―ルアミン塩７重量％、ミリスチ
ン酸トリエタノ―ルアミン塩３重量％、パルミチン酸ト
リエタノ―ルアミン塩０．８重量％、ステアリン酸トリ
エタノ―ルアミン塩０．８重量％、オレイン酸トリエタ
ノ―ルアミン塩２．２重量％、ポリエチレングリコ―ル
（３０モル）１．５重量％、ラウリン酸ジエタノ―ルア
ミド２重量％、ヤシ油脂肪酸ジエタノ―ルアミド２重量
％、エチレングリコ―ルジステアレ―ト１．７重量％、
防腐剤０．３重量％、香料０．５重量％および精製水残
部により、ボデイシヤンプ―組成物を調製した。Example 10 7% by weight of lauric acid triethanolamine salt, 3% by weight of myristic acid triethanolamine salt, 0.8% by weight of palmitic acid triethanolamine salt, 0.8% by weight of stearic acid triethanolamine salt, Oleic acid triethanolamine salt 2.2% by weight, polyethylene glycol (30 mol) 1.5% by weight, lauric acid dietanolamide 2% by weight, coconut oil fatty acid dietanolamide 2% by weight, ethylene glycol disteare 1.7% by weight,
A bodywash composition was prepared with 0.3% by weight of preservative, 0.5% by weight of perfume and the balance of purified water.
【００５４】このボデイシヤンプ―組成物について、前
記と同様にして評価した。結果は、蛋白質変性率は２８
％、試料投入直後の高さは２５７mm、泡の持続率は９５
％、調製直後の粘度（２５℃）は１，８５３ｃｐｓ、３
日後の同粘度は１，８５９ｃｐｓで、粘度変化は○、経
時安定性は○、泡のクリ―ミ―性は１．９、すすぎ後の
ぬめり感は３．７、すすぎ後のさつぱり感は３．６、パ
―ル化の状態は○であつた。この結果から、このボデイ
シヤンプ―組成物は、皮膚に対する刺激性が低く、しか
も起泡性にすぐれているとともに、粘度変化が小さく、
経時安定性にもすぐれており、また泡がクリ―ミ―であ
つて、使用時および使用後の感触が良好であり、パ―ル
化の状態も良好であることがわかる。The body composition was evaluated in the same manner as above. The result shows that the protein denaturation rate is 28.
%, Height immediately after charging the sample is 257 mm, and foam retention rate is 95
%, Viscosity immediately after preparation (25 ° C.) is 1,853 cps, 3
Same viscosity after day is 1,859 cps, viscosity change is ○, stability over time is ○, creaminess of foam is 1.9, slimy feeling after rinsing is 3.7, dry feeling after rinsing Was 3.6 and the state of palletization was ○. From this result, this body polish composition has low irritation to the skin, excellent foaming property, and small change in viscosity,
It can be seen that it has excellent stability over time, and that the foam is creamy, and that it has a good feel during and after use, and that it is in a well-palled state.
【００５５】実施例１１ ラウリン酸カリウム６重量％、ミリスチン酸カリウム１
重量％、パルミチン酸カリウム０．５重量％、オレイン
酸カリウム２．５重量％、ポリエチレングリコ―ル（３
０モル）３重量％、ポリエチレングリコ―ル（１４０モ
ル）１重量％、ヤシ油脂肪酸ジエタノ―ルアミド３重量
％、エチレングリコ―ルジステアレ―ト２重量％、Ｎ−
ココイル−Ｎ−メチルタウリンナトリウム２重量％、Ｎ
−ココイル−Ｎ´−カルボキシメチル−Ｎ´−（２−ヒ
ドロキシエチル）エチレンジアミン４重量％、ジステア
リルジメチルアンモニウムクロリド０．４重量％、カチ
オン性ポリマ―（メルク社製の商品名「マ―コ―ト１０
０」）１重量％、防腐剤０．３重量％、香料０．５重量
％および精製水残部により、石鹸シヤンプ―組成物を調
製した。Example 11 6% by weight potassium laurate, 1 potassium myristate
Wt%, potassium palmitate 0.5 wt%, potassium oleate 2.5 wt%, polyethylene glycol (3
0 mol) 3% by weight, polyethylene glycol (140 mol) 1% by weight, coconut oil fatty acid dietanolamide 3% by weight, ethylene glycol distearate 2% by weight, N-
Cocoyl-N-methyltaurine sodium 2% by weight, N
-Cocoyl-N'-carboxymethyl-N '-(2-hydroxyethyl) ethylenediamine 4% by weight, distearyldimethylammonium chloride 0.4% by weight, cationic polymer (trade name "Marko-Merco-made by Merck" To 10
0 ") 1% by weight, 0.3% by weight of preservative, 0.5% by weight of perfume, and the balance of purified water to prepare a soap sham-composition.
【００５６】この石鹸シヤンプ―組成物について、皮膚
刺激性、起泡性、粘度変化、経時安定性、泡のクリ―ミ
―性、洗髪時の指通り性、洗髪後の櫛通り性、洗髪後の
コンデイシヨニング効果、パ―ル化の状態を評価した。
評価方法は、皮膚刺激性、起泡性、粘度変化、パ―ル化
の状態については前記と同じであり、他の項目について
は、以下の要領により、評価した。With respect to this soap shampoo composition, skin irritation, foaming property, viscosity change, stability over time, foam creaminess, finger combability during hair wash, comb combability after hair wash, after hair wash Was evaluated for the conditioning effect and the state of palletization.
The evaluation method was the same as described above with respect to skin irritation, foaming property, viscosity change, and palling state, and other items were evaluated according to the following procedures.
【００５７】＜経時安定性＞試料（石鹸シヤンプ―組成
物）を−５℃、２５℃、４５℃で１ケ月間保存し、その
外観を観察して、つぎの３段階で評価した。 ○：安定性良好（透明または微濁状態で、外観の変化が
ない） △：安定性やや不良（やや濁り、着色を生じる） ×：安定性不良（沈殿が認められる、または固化する、
着色が著しい）<Stability with time> A sample (soap sham-composition) was stored at -5 ° C, 25 ° C and 45 ° C for 1 month, and its appearance was observed and evaluated according to the following three grades. ◯: Good stability (transparent or slightly turbid state, no change in appearance) Δ: Slightly poor stability (slightly turbid or colored) ×: Poor stability (precipitation or solidification,
(Coloring is remarkable)
【００５８】＜泡のクリ―ミ―性＞２０名の女性をパネ
ラ―とし、試料（石鹸シヤンプ―組成物）５ｍｌで洗髪
したときの泡のクリ―ミ―性について評価した。泡がク
リ―ミ―であると感じた場合を２点、ややクリ―ミ―で
あると感じた場合を１点、泡がクリ―ミ―でなく粗いと
感じた場合を０点として、２０名の平均値を求めた。平
均値が１．５点以上であるものを泡のクリ―ミ―性が良
好であると評価した。<Foam Creaminess> 20 women were used as panelers, and the foam creaminess when the hair was washed with 5 ml of the sample (soap sham composition) was evaluated. 20 points when the foam is felt creamy is 2 points, 1 point when the foam is felt slightly creamy, and 0 when the foam is not creamy but coarse. The average of the names was determined. Those having an average value of 1.5 or more were evaluated as having good foam creaminess.
【００５９】＜洗髪時の指通り性＞２０名の女性をパネ
ラ―とし、試料（石鹸シヤンプ―組成物）５ｍｌで洗髪
したときの指通り性を評価した。指通りがスム―スで髪
がひつかからないと感じた場合を２点、髪がやや指にひ
つかかると感じた場合を１点、指通りが非常に悪いと感
じた場合を０点として、２０名の平均値を求めた。平均
値が１．５点以上であるものを指通り性の良好な組成物
と評価した。<Finger-passing property when washing hair> 20 women were used as panelers, and the finger-passing property when washing hair with 5 ml of a sample (soap sham composition) was evaluated. 2 points if you feel that your fingers are smooth and that your hair does not get caught, 1 point if you feel that your hair is slightly hitting your fingers, and 0 points if you feel that your fingering is very poor. The average value of the names was calculated. A composition having an average value of 1.5 or more was evaluated as a composition having good finger-passing property.
【００６０】＜洗髪後の櫛通り性＞２０名の女性をパネ
ラ―とし、試料（石鹸シヤンプ―組成物）５ｍｌで洗
髪、乾燥したのちの櫛通り性を評価した。髪にきしみ感
がなく、櫛通りがスム―スであると感じた場合を２点、
髪がやや櫛にひつかかると感じた場合を１点、櫛通りが
非常に悪いと感じた場合を０点として、２０名の平均値
を求めた。平均値が１．５点以上であるものを洗髪後の
櫛通り性の良好な組成物と評価した。<Combability after Washing Hair> Twenty women were used as panelers, and the combability was evaluated after washing and drying hair with 5 ml of a sample (soap sham composition). 2 points when the hair does not feel squeaky and the comb passage feels smooth.
The average value of 20 persons was calculated with 1 point when the hair was felt to be slightly caught on the comb and 0 point when the hair was felt to be very badly combed. A composition having an average value of 1.5 or more was evaluated as a composition having good combability after washing hair.
【００６１】＜洗髪後のコンデイシヨニング効果＞２０
名の女性をパネラ―とし、試料（石鹸シヤンプ―組成
物）５ｍｌで洗髪、乾燥したのちのコンデイシヨニング
効果を評価した。コンデイシヨニング効果がすぐれてい
ると感じた場合を２点、ややコンデイシヨニング効果が
得られると感じた場合を１点、コンデイシヨニング効果
が得られないと感じた場合を０点として、２０名の平均
値を求めた。平均値が１．５点以上であるものを洗髪後
のコンデイシヨニング効果の良好な組成物と評価した。<Conditioning effect after washing hair> 20
The female of the name was used as a paneler, and the conditioning effect after washing and drying the hair with 5 ml of a sample (soap sham composition) was evaluated. 2 points when you feel that the conditioning effect is excellent, 1 point when you feel that the conditioning effect is obtained, and 0 point when you feel that the conditioning effect cannot be obtained. The average value of 20 persons was calculated. A composition having an average value of 1.5 or more was evaluated as a composition having a good conditioning effect after washing hair.
【００６２】結果は、蛋白質変性率は２４％、試料投入
直後の高さは２６３mm、泡の持続率は９６％、調製直後
の粘度（２５℃）は６３２ｃｐｓ、３日後の同粘度は６
３５ｃｐｓで、粘度変化は○、経時安定性は○、泡のク
リ―ミ―性は１．９、洗髪後時の指通り性は１．７、洗
髪後の櫛通り性は１．７、洗髪後のコンデイシヨニング
効果は１．７、パ―ル化の状態は○であつた。この結果
から、この石鹸シヤンプ―組成物は、皮膚に対する刺激
性が低く、しかも起泡性にすぐれているとともに、粘度
変化が小さく、経時安定性にもすぐれており、また泡が
クリ―ミ―であつて、使用時および使用後の感触が良好
であり、肌がつつぱらず、パ―ル化の状態も良好である
ことがわかる。As a result, the protein denaturation rate was 24%, the height immediately after the sample was charged was 263 mm, the foam retention rate was 96%, the viscosity (25 ° C.) immediately after preparation was 632 cps, and the same viscosity after 3 days was 6%.
At 35 cps, viscosity change is good, stability over time is good, foam creaminess is 1.9, finger combability after hair wash is 1.7, comb combability after hair wash is 1.7, hair wash. The subsequent conditioning effect was 1.7 and the state of palletization was ○. From this result, the soap sham composition has low irritation to the skin, excellent foaming property, small viscosity change, and excellent stability over time, and has a creamy foam. In addition, it can be seen that the feel during and after use is good, the skin does not crumble, and the state of palling is also good.
【００６３】[0063]
【発明の効果】以上のように、本発明によれば、低刺激
性で、かつ起泡性にすぐれ、しかも粘度変化が小さく、
経時安定性にもすぐれており、またクリ―ミ―な泡質を
有し、洗浄時および洗浄後の感触が良好であり、そのう
え、きれいなパ―ル状を呈することが可能な洗浄剤組成
物を提供することができる。As described above, according to the present invention, it is hypoallergenic, has excellent foaming properties, and has a small change in viscosity.
A detergent composition which has excellent stability over time, has a creamy foam quality, has a good feel during and after washing, and can have a clean pal shape. Can be provided.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 白崎 斉美 兵庫県西宮市東鳴尾町２丁目５−３−101 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Masami Shirasaki 2-5-3-101 Higashi-Naruo-cho, Nishinomiya-shi, Hyogo
Claims (1)
鎖状もしくは分岐状の飽和または不飽和の炭化水素基、
Ｍ1 はアルカリ金属原子、アンモニウム基または有機ア
ミンのカチオン性残基である） ｂ）式（II) で示されるポリエチレングリコ―ル０．１
〜１０重量％ ＨＯ−（ＣＨ2 ＣＨ2 Ｏ）n −Ｈ …（II） （ｎはエチレンオキサイドの平均付加モル数で、１０〜
５００である） ｃ）式（III ) で示されるアルカノ―ルアミド型界面活
性剤１〜１０重量％ （Ｒ2 は炭素数７〜２１の水酸基を有することがある直
鎖状もしくは分岐状の飽和または不飽和の炭化水素基、
ｏ，ｐは各々０〜４の整数で、少なくともひとつは０で
ない）を含有し、ａ成分＋ｂ成分＋ｃ成分＝５〜６０重
量％であることを特徴とする洗浄剤組成物。1. The following a to c components; a) a higher fatty acid salt represented by the formula (I): 3 to 50% by weight R 1 COOM 1 ... (I) (R 1 has a hydroxyl group having 7 to 21 carbon atoms. A linear or branched saturated or unsaturated hydrocarbon group which may be
M 1 is an alkali metal atom, an ammonium group or a cationic residue of an organic amine) b) Polyethylene glycol 0.1 represented by the formula (II)
10 wt% HO- by (CH 2 CH 2 O) n -H ... (II) (n is the average addition number of moles of ethylene oxide, 10
500) c) 1 to 10% by weight of an alkanolamide type surfactant represented by the formula (III) (R 2 is a linear or branched saturated or unsaturated hydrocarbon group which may have a hydroxyl group having 7 to 21 carbon atoms,
Each of o and p is an integer of 0 to 4, at least one of which is not 0), and a component + b component + c component = 5 to 60% by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7188223A JPH0913096A (en) | 1995-06-30 | 1995-06-30 | Detergent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7188223A JPH0913096A (en) | 1995-06-30 | 1995-06-30 | Detergent composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0913096A true JPH0913096A (en) | 1997-01-14 |
Family
ID=16219936
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7188223A Pending JPH0913096A (en) | 1995-06-30 | 1995-06-30 | Detergent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0913096A (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11131097A (en) * | 1997-10-27 | 1999-05-18 | Asahi Denka Kogyo Kk | Fatty acid soap and washing agent composition |
| JP2001072998A (en) * | 1999-06-28 | 2001-03-21 | Nof Corp | Detergent composition |
| JP2002338993A (en) * | 2001-05-16 | 2002-11-27 | Kawaken Fine Chem Co Ltd | Liquid detergent composition |
| JP2007314463A (en) * | 2006-05-25 | 2007-12-06 | Kao Corp | Liquid composition containing fine bubble |
| JP2007313425A (en) * | 2006-05-25 | 2007-12-06 | Kao Corp | Production method for liquid composition with microbubbles |
| KR101042716B1 (en) * | 2003-12-18 | 2011-06-20 | 주식회사 엘지생활건강 | Dispersion emulsifier for diesel emulsion |
| JP2012046760A (en) * | 2011-10-07 | 2012-03-08 | Kawaken Fine Chem Co Ltd | Method for improving low-temperature stability of aqueous solution containing long-chain acyliminodiacetic acid type surfactant compound |
| JP2014108927A (en) * | 2012-11-30 | 2014-06-12 | Dariya:Kk | Hair cosmetic composition |
| KR20150067127A (en) | 2012-10-01 | 2015-06-17 | 라이온 가부시키가이샤 | Skin cleansing agent composition |
| WO2022059747A1 (en) * | 2020-09-17 | 2022-03-24 | 株式会社 資生堂 | Cleaning agent composition |
-
1995
- 1995-06-30 JP JP7188223A patent/JPH0913096A/en active Pending
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11131097A (en) * | 1997-10-27 | 1999-05-18 | Asahi Denka Kogyo Kk | Fatty acid soap and washing agent composition |
| JP2001072998A (en) * | 1999-06-28 | 2001-03-21 | Nof Corp | Detergent composition |
| JP2002338993A (en) * | 2001-05-16 | 2002-11-27 | Kawaken Fine Chem Co Ltd | Liquid detergent composition |
| KR101042716B1 (en) * | 2003-12-18 | 2011-06-20 | 주식회사 엘지생활건강 | Dispersion emulsifier for diesel emulsion |
| JP2007314463A (en) * | 2006-05-25 | 2007-12-06 | Kao Corp | Liquid composition containing fine bubble |
| JP2007313425A (en) * | 2006-05-25 | 2007-12-06 | Kao Corp | Production method for liquid composition with microbubbles |
| JP2012046760A (en) * | 2011-10-07 | 2012-03-08 | Kawaken Fine Chem Co Ltd | Method for improving low-temperature stability of aqueous solution containing long-chain acyliminodiacetic acid type surfactant compound |
| KR20150067127A (en) | 2012-10-01 | 2015-06-17 | 라이온 가부시키가이샤 | Skin cleansing agent composition |
| JP2014108927A (en) * | 2012-11-30 | 2014-06-12 | Dariya:Kk | Hair cosmetic composition |
| WO2022059747A1 (en) * | 2020-09-17 | 2022-03-24 | 株式会社 資生堂 | Cleaning agent composition |
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