JPH0412754B2 - - Google Patents
Info
- Publication number
- JPH0412754B2 JPH0412754B2 JP58503731A JP50373183A JPH0412754B2 JP H0412754 B2 JPH0412754 B2 JP H0412754B2 JP 58503731 A JP58503731 A JP 58503731A JP 50373183 A JP50373183 A JP 50373183A JP H0412754 B2 JPH0412754 B2 JP H0412754B2
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- ultrastable
- zeolite
- oil
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003054 catalyst Substances 0.000 description 126
- 239000010457 zeolite Substances 0.000 description 112
- 239000003921 oil Substances 0.000 description 90
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 78
- 229910021536 Zeolite Inorganic materials 0.000 description 76
- 238000000034 method Methods 0.000 description 54
- 238000009835 boiling Methods 0.000 description 29
- 238000005336 cracking Methods 0.000 description 27
- 238000006243 chemical reaction Methods 0.000 description 22
- 229930195733 hydrocarbon Natural products 0.000 description 22
- 150000002430 hydrocarbons Chemical class 0.000 description 22
- 230000008929 regeneration Effects 0.000 description 22
- 238000011069 regeneration method Methods 0.000 description 22
- 230000008569 process Effects 0.000 description 21
- 239000002245 particle Substances 0.000 description 18
- 238000004519 manufacturing process Methods 0.000 description 17
- 239000000463 material Substances 0.000 description 17
- 239000004215 Carbon black (E152) Substances 0.000 description 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 15
- 229910052799 carbon Inorganic materials 0.000 description 15
- 239000007789 gas Substances 0.000 description 15
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 14
- 239000000571 coke Substances 0.000 description 13
- 230000000694 effects Effects 0.000 description 13
- 239000000047 product Substances 0.000 description 13
- 230000003197 catalytic effect Effects 0.000 description 12
- 239000000203 mixture Substances 0.000 description 12
- 230000009467 reduction Effects 0.000 description 11
- 238000004523 catalytic cracking Methods 0.000 description 10
- 238000000354 decomposition reaction Methods 0.000 description 10
- 229910052751 metal Inorganic materials 0.000 description 9
- 239000002184 metal Substances 0.000 description 9
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 8
- 239000011159 matrix material Substances 0.000 description 8
- 229910052761 rare earth metal Inorganic materials 0.000 description 8
- 239000011734 sodium Substances 0.000 description 8
- 239000003575 carbonaceous material Substances 0.000 description 7
- 239000010779 crude oil Substances 0.000 description 7
- 150000002910 rare earth metals Chemical class 0.000 description 7
- 239000000377 silicon dioxide Substances 0.000 description 7
- 238000000889 atomisation Methods 0.000 description 6
- 238000004821 distillation Methods 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 230000008901 benefit Effects 0.000 description 5
- 238000001704 evaporation Methods 0.000 description 5
- 239000000295 fuel oil Substances 0.000 description 5
- 150000002739 metals Chemical class 0.000 description 5
- 239000002244 precipitate Substances 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 229910052783 alkali metal Inorganic materials 0.000 description 4
- 150000001340 alkali metals Chemical class 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 4
- 230000008020 evaporation Effects 0.000 description 4
- 238000004231 fluid catalytic cracking Methods 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- 229910001413 alkali metal ion Inorganic materials 0.000 description 3
- 150000001491 aromatic compounds Chemical class 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 239000004927 clay Substances 0.000 description 3
- -1 clays Inorganic materials 0.000 description 3
- 238000005342 ion exchange Methods 0.000 description 3
- 239000012263 liquid product Substances 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 238000003889 chemical engineering Methods 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 150000002902 organometallic compounds Chemical class 0.000 description 2
- 229910052814 silicon oxide Inorganic materials 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000013585 weight reducing agent Substances 0.000 description 2
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
- 125000004008 6 membered carbocyclic group Chemical group 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical group [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 239000012084 conversion product Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 230000004807 localization Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000012925 reference material Substances 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
- C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
- Saccharide Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/US1983/001644 WO1985001740A1 (en) | 1983-10-20 | 1983-10-20 | A method for catalytically converting residual oils |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61500316A JPS61500316A (ja) | 1986-02-27 |
| JPH0412754B2 true JPH0412754B2 (de) | 1992-03-05 |
Family
ID=22175509
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58503731A Granted JPS61500316A (ja) | 1983-10-20 | 1983-10-20 | 残滓油の接触変換法 |
Country Status (7)
| Country | Link |
|---|---|
| JP (1) | JPS61500316A (de) |
| AU (1) | AU573554B2 (de) |
| BR (1) | BR8307756A (de) |
| DE (1) | DE3390537C2 (de) |
| GB (1) | GB2159535B (de) |
| NL (1) | NL8320358A (de) |
| WO (1) | WO1985001740A1 (de) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009148655A (ja) * | 2007-12-18 | 2009-07-09 | Jgc Catalysts & Chemicals Ltd | 炭化水素の接触分解用触媒組成物およびその製造方法 |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1986002889A1 (en) * | 1984-11-05 | 1986-05-22 | Francis Patrick Zikan | Steering and anti-theft device for vehicles |
| BRPI0800236B1 (pt) * | 2008-01-24 | 2019-05-14 | Petroleo Brasileiro S.A. - Petrobras | Processo e equipamento de craqueamento catalítico fluido para a produção de destilados médios de baixa aromaticidade |
Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52133304A (en) * | 1976-04-29 | 1977-11-08 | Mobil Oil | Thermal cracking method of oil decontaminated with metal |
| JPS54161593A (en) * | 1978-06-07 | 1979-12-21 | Exxon Research Engineering Co | Octane improving cracking catalyst |
| US4239654A (en) * | 1979-05-31 | 1980-12-16 | Exxon Research & Engineering Co. | Hydrocarbon cracking catalyst and process utilizing the same |
| JPS55162349A (en) * | 1979-05-31 | 1980-12-17 | Exxon Research Engineering Co | Catalyst for cracking of hydrocarbon and process using said catalyst |
| US4259212A (en) * | 1978-06-07 | 1981-03-31 | Exxon Research And Engineering Co. | Octane improvement cracking catalyst |
| US4276150A (en) * | 1979-11-05 | 1981-06-30 | Standard Oil Company (Indiana) | Fluid catalytic cracking of heavy petroleum fractions |
| US4292169A (en) * | 1976-11-30 | 1981-09-29 | Exxon Research & Engineering Co. | Hydrocarbon conversion with zeolite catalyst in metals-absorbing matrix |
| JPS5791742A (en) * | 1980-10-10 | 1982-06-08 | Exxon Research Engineering Co | Hydrocarbon inverted catalyst and method using said catalyst |
| JPS5791741A (en) * | 1980-10-10 | 1982-06-08 | Exxon Research Engineering Co | Hydrocarbon inverted catalyst and method using said catalyst |
| US4336160A (en) * | 1980-07-15 | 1982-06-22 | Dean Robert R | Method and apparatus for cracking residual oils |
| US4347122A (en) * | 1979-11-14 | 1982-08-31 | Ashland Oil, Inc. | Carbo-metallic oil conversion with liquid water |
| US4354923A (en) * | 1979-11-14 | 1982-10-19 | Ashland Oil, Inc. | Carbo-metallic oil conversion with liquid water, ballistic separation and controlled CO:CO2 ratio during catalyst regeneration |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4401556A (en) * | 1979-11-13 | 1983-08-30 | Union Carbide Corporation | Midbarrel hydrocracking |
| US4316794A (en) * | 1980-03-06 | 1982-02-23 | Mobil Oil Corporation | Direct conversion of residual oils |
| US4331533A (en) * | 1980-07-15 | 1982-05-25 | Dean Robert R | Method and apparatus for cracking residual oils |
| US4332674A (en) * | 1980-07-15 | 1982-06-01 | Dean Robert R | Method and apparatus for cracking residual oils |
| US4414098A (en) * | 1981-07-30 | 1983-11-08 | Ashland Oil, Inc. | Upgrading carbo-metallic oils with used catalyst |
| NZ202130A (en) * | 1981-10-26 | 1986-02-21 | Mobil Oil Corp | Gas oil cracking using a zeolite catalyst |
| US4415438A (en) * | 1981-11-24 | 1983-11-15 | Dean Robert R | Method for catalytically converting residual oils |
| US4440868A (en) * | 1981-12-07 | 1984-04-03 | Ashland Oil, Inc. | Carbo-metallic oil conversion catalysts |
-
1983
- 1983-10-20 GB GB08510127A patent/GB2159535B/en not_active Expired
- 1983-10-20 NL NL8320358A patent/NL8320358A/nl active Search and Examination
- 1983-10-20 DE DE3390537T patent/DE3390537C2/de not_active Expired - Lifetime
- 1983-10-20 JP JP58503731A patent/JPS61500316A/ja active Granted
- 1983-10-20 BR BR8307756A patent/BR8307756A/pt not_active IP Right Cessation
- 1983-10-20 WO PCT/US1983/001644 patent/WO1985001740A1/en active Application Filing
- 1983-10-20 AU AU22631/83A patent/AU573554B2/en not_active Expired
Patent Citations (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52133304A (en) * | 1976-04-29 | 1977-11-08 | Mobil Oil | Thermal cracking method of oil decontaminated with metal |
| US4292169A (en) * | 1976-11-30 | 1981-09-29 | Exxon Research & Engineering Co. | Hydrocarbon conversion with zeolite catalyst in metals-absorbing matrix |
| JPS54161593A (en) * | 1978-06-07 | 1979-12-21 | Exxon Research Engineering Co | Octane improving cracking catalyst |
| US4259212A (en) * | 1978-06-07 | 1981-03-31 | Exxon Research And Engineering Co. | Octane improvement cracking catalyst |
| US4239654A (en) * | 1979-05-31 | 1980-12-16 | Exxon Research & Engineering Co. | Hydrocarbon cracking catalyst and process utilizing the same |
| JPS55162349A (en) * | 1979-05-31 | 1980-12-17 | Exxon Research Engineering Co | Catalyst for cracking of hydrocarbon and process using said catalyst |
| US4242237A (en) * | 1979-05-31 | 1980-12-30 | Exxon Research & Engineering Co. | Hydrocarbon cracking catalyst and process utilizing the same |
| US4276150A (en) * | 1979-11-05 | 1981-06-30 | Standard Oil Company (Indiana) | Fluid catalytic cracking of heavy petroleum fractions |
| US4347122A (en) * | 1979-11-14 | 1982-08-31 | Ashland Oil, Inc. | Carbo-metallic oil conversion with liquid water |
| US4354923A (en) * | 1979-11-14 | 1982-10-19 | Ashland Oil, Inc. | Carbo-metallic oil conversion with liquid water, ballistic separation and controlled CO:CO2 ratio during catalyst regeneration |
| US4336160A (en) * | 1980-07-15 | 1982-06-22 | Dean Robert R | Method and apparatus for cracking residual oils |
| JPS5791742A (en) * | 1980-10-10 | 1982-06-08 | Exxon Research Engineering Co | Hydrocarbon inverted catalyst and method using said catalyst |
| JPS5791741A (en) * | 1980-10-10 | 1982-06-08 | Exxon Research Engineering Co | Hydrocarbon inverted catalyst and method using said catalyst |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009148655A (ja) * | 2007-12-18 | 2009-07-09 | Jgc Catalysts & Chemicals Ltd | 炭化水素の接触分解用触媒組成物およびその製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| AU573554B2 (en) | 1988-06-16 |
| DE3390537C2 (de) | 1995-08-10 |
| GB2159535B (en) | 1988-06-29 |
| GB8510127D0 (en) | 1985-05-30 |
| NL8320358A (nl) | 1985-09-02 |
| WO1985001740A1 (en) | 1985-04-25 |
| GB2159535A (en) | 1985-12-04 |
| AU2263183A (en) | 1985-05-07 |
| JPS61500316A (ja) | 1986-02-27 |
| DE3390537T1 (de) | 1986-09-18 |
| BR8307756A (pt) | 1985-08-27 |
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