JPH0386526A - Method for applying surface embossed pattern to fiber reinforced phenol resin foam - Google Patents
Method for applying surface embossed pattern to fiber reinforced phenol resin foamInfo
- Publication number
- JPH0386526A JPH0386526A JP1223407A JP22340789A JPH0386526A JP H0386526 A JPH0386526 A JP H0386526A JP 1223407 A JP1223407 A JP 1223407A JP 22340789 A JP22340789 A JP 22340789A JP H0386526 A JPH0386526 A JP H0386526A
- Authority
- JP
- Japan
- Prior art keywords
- phenol resin
- type phenol
- foamed
- resole type
- embossed pattern
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000005011 phenolic resin Substances 0.000 title claims abstract description 19
- 239000006260 foam Substances 0.000 title claims description 14
- 238000000034 method Methods 0.000 title claims description 7
- 239000000835 fiber Substances 0.000 title abstract description 3
- 229920005989 resin Polymers 0.000 claims abstract description 14
- 239000011347 resin Substances 0.000 claims abstract description 14
- 239000000945 filler Substances 0.000 claims abstract description 6
- 230000009257 reactivity Effects 0.000 claims abstract description 6
- 239000007788 liquid Substances 0.000 claims abstract description 5
- 239000012783 reinforcing fiber Substances 0.000 claims abstract description 5
- 150000001875 compounds Chemical class 0.000 claims abstract 3
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 10
- 229920001568 phenolic resin Polymers 0.000 claims description 10
- 239000011134 resol-type phenolic resin Substances 0.000 claims description 7
- 229920003987 resole Polymers 0.000 abstract description 6
- 239000000463 material Substances 0.000 abstract description 5
- 238000010438 heat treatment Methods 0.000 abstract description 3
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 239000011521 glass Substances 0.000 abstract description 2
- 239000000454 talc Substances 0.000 abstract description 2
- 229910052623 talc Inorganic materials 0.000 abstract description 2
- 238000004049 embossing Methods 0.000 abstract 2
- 239000004088 foaming agent Substances 0.000 abstract 1
- 238000001723 curing Methods 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 239000004604 Blowing Agent Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000010097 foam moulding Methods 0.000 description 1
- 238000013007 heat curing Methods 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
Landscapes
- Shaping Of Tube Ends By Bending Or Straightening (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
この発明は繊維強化フェノール樹脂発泡体の表面凹凸模
様付方法に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] This invention relates to a method for providing a textured surface of a fiber-reinforced phenolic resin foam.
従来、建築用壁板として繊維強化フェノール樹脂発泡体
から威る壁板が好適として広く用いられている。Conventionally, wall panels made of fiber-reinforced phenolic resin foam have been widely used as suitable architectural wall panels.
この種材質の壁板は軽量かつ、難燃性に富み、また、繊
維強化さているので、強度も優れるなど種々の利点を有
する。Wall boards made of this type of material have various advantages, such as being lightweight, highly flame retardant, and, since they are reinforced with fibers, have excellent strength.
ところで、上記繊維強化フェノール樹脂発泡板より威る
壁板に凹凸模様を付する場合、従来にあってはプレス成
形時に凹凸金型を用い、これでプレスすると同時に硬化
させること、ルータ−等の加工機により表面を切削して
模様を付すること、あるいは成形後の平板表面に加熱プ
レスを行なうことなどが考えられるが、金型によりプレ
スして成形硬化する手段は、樹脂の粘調度が高いことと
相俟って金型の凹凸模様個所に空気、ガスが溜まりやす
く正確な模様付が出来ず、さらに深い凹凸模様も付すこ
とが出来ないと言った問題が有り、また、成形後の切削
加工は切削部分の材料が全く無駄となるばかりでなく、
繊維強化発泡体にあっては表面状態が見苦しくなる問題
が有った。By the way, when adding an uneven pattern to a wall board that is better than the above-mentioned fiber-reinforced phenol resin foam board, the conventional method is to use an uneven mold during press molding, press with this and simultaneously harden it, and process using a router, etc. Possible methods include cutting the surface with a machine to create a pattern, or heating and pressing the surface of a flat plate after molding, but pressing with a mold and molding and hardening means that the resin has a high viscosity. Combined with this, there is a problem that air and gas tend to accumulate in the uneven pattern parts of the mold, making it impossible to create accurate patterns and even deeper uneven patterns. Not only is the material of the cutting part completely wasted, but
Fiber-reinforced foams have a problem in that the surface condition becomes unsightly.
また、成形後の板体にプレスするのは、フェノール樹脂
発泡体は硬度は有する反面脆い性質を有するので組織が
破壊され板材として携帯そのものを維持出来なくなる問
題が有った。Furthermore, pressing the molded plate into a plate has the problem that, although the phenol resin foam has hardness, it also has brittle properties, so the structure is destroyed, making it impossible to maintain the cell phone as a plate.
この発明は上記問題点に鑑み、脆い材質である繊維強化
酸硬化系フェノール樹脂発泡板であっても、これらを破
壊することなく、しかも彫りの深い凹凸模様を容易に付
することの出来る方法を提供することを目的としてなさ
れたものである。In view of the above-mentioned problems, the present invention has developed a method that can easily create a deep uneven pattern on fiber-reinforced acid-curing phenolic resin foam boards, which are brittle materials, without destroying them. It was made for the purpose of providing.
即ち、この発明の繊維強化フェノール樹脂発泡体の表面
凹凸模様付方法は液状レゾール型フェノール樹脂に充填
材、補強繊維を添加してなる配合物に、前記樹脂より反
応性の低い粉末状レゾール型フェノール樹脂を添加して
繊維強化フェノール樹脂発泡体を成形し、該成形体を凹
凸プレスによりその表面を圧壊し得る圧力で加圧すると
同時に加熱し、前記粉末状レゾール型フェノール樹脂を
硬化させることを特徴とするものである。That is, the method for imparting a pattern on the surface of a fiber-reinforced phenolic resin foam according to the present invention is to add a powdered resol type phenol having a lower reactivity than the resin to a mixture obtained by adding fillers and reinforcing fibers to a liquid resol type phenol resin. A fiber-reinforced phenolic resin foam is molded by adding a resin, and the molded product is pressed with a pressure capable of crushing its surface using a concave-convex press and heated at the same time to harden the powdered resol type phenolic resin. That is.
既述のように、繊維強化フェノール樹脂発泡体は跪く、
−窓以上の圧力を加えて押圧すると、容易に破壊され、
原形を保つことは出来ない。As already mentioned, fiber-reinforced phenolic foam kneels,
- If pressed with more pressure than the window, it will be easily destroyed;
It is not possible to maintain the original shape.
そこで、レゾール型フェノール樹脂の反応性は組成によ
り調整可能であることに着目し、ベースレジンとなる樹
脂にそれよりも反応性の低い樹脂を混合しておき、反応
性の高いベースレジンとなる樹脂でまず発泡成形を行い
、この成形品表面に凹凸模様金型でプレスし、同時に加
熱することにより反応性の低い樹脂を熱硬化させるので
ある。Therefore, we focused on the fact that the reactivity of resol type phenolic resin can be adjusted by changing the composition, and we mixed a resin with lower reactivity with the resin that will become the base resin, and created a resin that will become the highly reactive base resin. First, foam molding is performed, and the surface of the molded product is pressed with a mold with a concavo-convex pattern, and at the same time heated, the resin with low reactivity is thermoset.
このとき、もとの発泡体はプレス圧により凹凸模様表面
に沿って圧壊されるが、これに含まれているフェノール
樹脂が熱により流動化し圧壊部に浸透し、かつ、そのま
まの状態で加熱硬化されるので、硬化完了後はこの樹脂
により表面状態が補強され、強度に優れた凹凸模様面が
形成されるのである。At this time, the original foam is crushed along the uneven pattern surface by the press pressure, but the phenolic resin contained in it becomes fluidized by heat and penetrates into the crushed area, and then heat cures in that state. Therefore, after curing is completed, the surface condition is reinforced by this resin, and an uneven patterned surface with excellent strength is formed.
即ち、含まれた粉末状フェノール樹脂がバインダ及び充
填剤となって破壊組織を再び一体化させるのである。That is, the powdered phenolic resin contained serves as a binder and filler to reunite the fractured tissue.
次に、この発明の詳細な説明する。 Next, the present invention will be explained in detail.
硬化反応熱が１００℃の液状レゾール型フェノール樹脂
に硬化反応熱が１５０℃の粉末状レゾール型フェノール
樹脂を１０重量部添加し、これをベースレジンとして５
０重量部の充填材（タルク〉及び必要量の発泡剤・硬化
剤を添加し１５重量部のガラス補強繊維に含浸したのち
加熱、加圧によって発泡硬化させ密度５００ ｋｔｒ
／ｃｉ、中４．５ｃｍ 、長さ１．８ｍ、厚さ１ｃｍの
繊維強化フェノール樹脂発泡板を成形した。10 parts by weight of a powdered resol type phenolic resin with a curing reaction heat of 150°C was added to a liquid resol type phenolic resin with a curing reaction heat of 100°C, and this was used as a base resin.
0 parts by weight of a filler (talc) and the required amount of blowing agent/curing agent were added, impregnated into 15 parts by weight of glass reinforcing fibers, and then foamed and cured by heating and pressurizing to a density of 500 ktr.
/ci, a fiber-reinforced phenolic resin foam board with a medium diameter of 4.5 cm, a length of 1.8 m, and a thickness of 1 cm was molded.
ついでこれを凹凸差３開 の木目調模様の凹凸金型に配
置し、１０ ｋｇ ／ ｃｄでプレスすると同時に１
５０℃に加熱し、３０分そのままの状態で維持し脱型し
た。Next, this was placed in a concave-convex mold with a woodgrain pattern with a concavo-convex difference of 3 degrees, and pressed at 10 kg/cd at the same time.
The mold was heated to 50° C., maintained for 30 minutes, and demolded.
得た板材は、表面がきわめて美麗な凹凸模様があられさ
れ、かつ、表面状態もなめらかな面で、かつ、表面硬度
も高かった。The obtained board material had a very beautiful uneven pattern on its surface, had a smooth surface, and had high surface hardness.
また、曲げ試験を行なったところ、曲げ強度２００ ｋ
ｇ／ｃｄの強度を有し、壁板として強度に優れることも
判明した。In addition, when a bending test was conducted, the bending strength was 200 k.
It was also found that it had a strength of g/cd and was excellent in strength as a wall board.
Claims (1)
維を添加してなる配合物に、前記樹脂より反応性の低い
粉末状レゾール型フェノール樹脂を添加して繊維強化フ
ェノール樹脂発泡体を成形し、該成形体を凹凸プレスに
よりその表面を圧壊し得る圧力で加圧すると同時に加熱
し、前記粉末状レゾール型フェノール樹脂を硬化させる
ことを特徴とする繊維強化フェノール樹脂発泡体の表面
凹凸模様付方法(1) Adding a powdered resol type phenolic resin having lower reactivity than the resin to a compound formed by adding a filler and reinforcing fiber to a liquid resol type phenolic resin to form a fiber-reinforced phenolic resin foam, A method for imparting an uneven pattern on the surface of a fiber-reinforced phenolic resin foam, characterized in that the molded body is pressed with a pressure capable of crushing the surface using an uneven press and simultaneously heated to cure the powdered resol type phenolic resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1223407A JPH0386526A (en) | 1989-08-30 | 1989-08-30 | Method for applying surface embossed pattern to fiber reinforced phenol resin foam |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1223407A JPH0386526A (en) | 1989-08-30 | 1989-08-30 | Method for applying surface embossed pattern to fiber reinforced phenol resin foam |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0386526A true JPH0386526A (en) | 1991-04-11 |
Family
ID=16797660
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1223407A Pending JPH0386526A (en) | 1989-08-30 | 1989-08-30 | Method for applying surface embossed pattern to fiber reinforced phenol resin foam |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0386526A (en) |
-
1989
- 1989-08-30 JP JP1223407A patent/JPH0386526A/en active Pending
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