JPH0372561B2 - - Google Patents
Info
- Publication number
- JPH0372561B2 JPH0372561B2 JP59012676A JP1267684A JPH0372561B2 JP H0372561 B2 JPH0372561 B2 JP H0372561B2 JP 59012676 A JP59012676 A JP 59012676A JP 1267684 A JP1267684 A JP 1267684A JP H0372561 B2 JPH0372561 B2 JP H0372561B2
- Authority
- JP
- Japan
- Prior art keywords
- reforming
- gas
- catalyst
- temperature
- carbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000007789 gas Substances 0.000 claims description 60
- 238000002407 reforming Methods 0.000 claims description 33
- 238000000034 method Methods 0.000 claims description 26
- 239000002994 raw material Substances 0.000 claims description 18
- 150000003464 sulfur compounds Chemical class 0.000 claims description 18
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 14
- 229930195733 hydrocarbon Natural products 0.000 claims description 13
- 150000002430 hydrocarbons Chemical class 0.000 claims description 13
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 9
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 8
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 7
- 239000001569 carbon dioxide Substances 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- 239000001257 hydrogen Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
- 239000001301 oxygen Substances 0.000 claims description 5
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- 239000003054 catalyst Substances 0.000 description 31
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 22
- 229910052799 carbon Inorganic materials 0.000 description 22
- 238000001556 precipitation Methods 0.000 description 19
- 230000000607 poisoning effect Effects 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 10
- 239000003607 modifier Substances 0.000 description 10
- 238000006057 reforming reaction Methods 0.000 description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 7
- 239000004215 Carbon black (E152) Substances 0.000 description 6
- 229910000831 Steel Inorganic materials 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000010959 steel Substances 0.000 description 6
- 230000006378 damage Effects 0.000 description 5
- 238000007323 disproportionation reaction Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 229910052717 sulfur Inorganic materials 0.000 description 4
- 239000011593 sulfur Substances 0.000 description 4
- 238000005979 thermal decomposition reaction Methods 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 231100000572 poisoning Toxicity 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- JJWKPURADFRFRB-UHFFFAOYSA-N carbonyl sulfide Chemical compound O=C=S JJWKPURADFRFRB-UHFFFAOYSA-N 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000002898 organic sulfur compounds Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 238000000629 steam reforming Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
Landscapes
- Carbon And Carbon Compounds (AREA)
- Hydrogen, Water And Hydrids (AREA)
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59012676A JPS60161302A (ja) | 1984-01-26 | 1984-01-26 | 炭化水素の改質方法 |
| IN6/MAS/85A IN163752B (enrdf_load_stackoverflow) | 1984-01-26 | 1985-01-01 | |
| AU37987/85A AU555269B2 (en) | 1984-01-26 | 1985-01-23 | Reforming hydrocarbons |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59012676A JPS60161302A (ja) | 1984-01-26 | 1984-01-26 | 炭化水素の改質方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60161302A JPS60161302A (ja) | 1985-08-23 |
| JPH0372561B2 true JPH0372561B2 (enrdf_load_stackoverflow) | 1991-11-19 |
Family
ID=11811975
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59012676A Granted JPS60161302A (ja) | 1984-01-26 | 1984-01-26 | 炭化水素の改質方法 |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JPS60161302A (enrdf_load_stackoverflow) |
| AU (1) | AU555269B2 (enrdf_load_stackoverflow) |
| IN (1) | IN163752B (enrdf_load_stackoverflow) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0497403U (enrdf_load_stackoverflow) * | 1991-04-01 | 1992-08-24 | ||
| JP6103628B2 (ja) * | 2012-11-26 | 2017-03-29 | 国立研究開発法人産業技術総合研究所 | メタン改質方法および、それに用いるメタン改質触媒 |
| US9809453B2 (en) * | 2013-03-15 | 2017-11-07 | Lg Fuel Cell Systems, Inc. | Catalysts for hydrocarbon reforming |
-
1984
- 1984-01-26 JP JP59012676A patent/JPS60161302A/ja active Granted
-
1985
- 1985-01-01 IN IN6/MAS/85A patent/IN163752B/en unknown
- 1985-01-23 AU AU37987/85A patent/AU555269B2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| IN163752B (enrdf_load_stackoverflow) | 1988-11-05 |
| JPS60161302A (ja) | 1985-08-23 |
| AU3798785A (en) | 1985-08-01 |
| AU555269B2 (en) | 1986-09-18 |
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