JPH0362173B2 - - Google Patents
Info
- Publication number
- JPH0362173B2 JPH0362173B2 JP58079463A JP7946383A JPH0362173B2 JP H0362173 B2 JPH0362173 B2 JP H0362173B2 JP 58079463 A JP58079463 A JP 58079463A JP 7946383 A JP7946383 A JP 7946383A JP H0362173 B2 JPH0362173 B2 JP H0362173B2
- Authority
- JP
- Japan
- Prior art keywords
- methanol
- polymer
- cyclohexane
- cement
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 376
- 229920000642 polymer Polymers 0.000 claims description 71
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 65
- 239000004568 cement Substances 0.000 claims description 50
- 239000002002 slurry Substances 0.000 claims description 47
- 238000000034 method Methods 0.000 claims description 33
- 238000001556 precipitation Methods 0.000 claims description 26
- 239000011414 polymer cement Substances 0.000 claims description 20
- 238000009835 boiling Methods 0.000 claims description 18
- 239000000178 monomer Substances 0.000 claims description 18
- 239000007787 solid Substances 0.000 claims description 16
- 238000004094 preconcentration Methods 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 14
- 239000007788 liquid Substances 0.000 claims description 11
- RMDKEBZUCHXUER-UHFFFAOYSA-N 4-methylbicyclo[2.2.1]hept-2-ene Chemical compound C1CC2C=CC1(C)C2 RMDKEBZUCHXUER-UHFFFAOYSA-N 0.000 claims description 9
- 229920001577 copolymer Polymers 0.000 claims description 8
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 claims description 7
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 claims description 4
- 229920001897 terpolymer Polymers 0.000 claims description 4
- 239000007795 chemical reaction product Substances 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 229920001519 homopolymer Polymers 0.000 claims description 3
- 230000001376 precipitating effect Effects 0.000 claims description 3
- 238000007151 ring opening polymerisation reaction Methods 0.000 claims description 3
- 238000001704 evaporation Methods 0.000 claims description 2
- 238000004064 recycling Methods 0.000 claims 3
- 238000002156 mixing Methods 0.000 claims 2
- 238000007865 diluting Methods 0.000 claims 1
- 239000002904 solvent Substances 0.000 description 43
- -1 cyclic olefins Chemical class 0.000 description 27
- 238000011084 recovery Methods 0.000 description 23
- 239000003054 catalyst Substances 0.000 description 20
- 238000006116 polymerization reaction Methods 0.000 description 15
- 229910052721 tungsten Inorganic materials 0.000 description 12
- 239000010937 tungsten Substances 0.000 description 12
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 10
- 239000012535 impurity Substances 0.000 description 9
- 229910052750 molybdenum Inorganic materials 0.000 description 9
- 239000011733 molybdenum Substances 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- 238000000926 separation method Methods 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 125000004432 carbon atom Chemical group C* 0.000 description 7
- 150000001925 cycloalkenes Chemical class 0.000 description 7
- 238000000605 extraction Methods 0.000 description 7
- 239000005078 molybdenum compound Substances 0.000 description 7
- 150000002752 molybdenum compounds Chemical class 0.000 description 7
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 6
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 6
- 150000001298 alcohols Chemical class 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 125000004122 cyclic group Chemical group 0.000 description 4
- 239000012454 non-polar solvent Substances 0.000 description 4
- 229920003050 poly-cycloolefin Polymers 0.000 description 4
- 239000002244 precipitate Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- 239000012190 activator Substances 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000003607 modifier Substances 0.000 description 3
- 150000003658 tungsten compounds Chemical class 0.000 description 3
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Natural products CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 2
- 125000005234 alkyl aluminium group Chemical group 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminum chloride Substances Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 239000007810 chemical reaction solvent Substances 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 230000001788 irregular Effects 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 150000002736 metal compounds Chemical class 0.000 description 2
- 239000012046 mixed solvent Substances 0.000 description 2
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical class [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 description 2
- 150000002848 norbornenes Chemical group 0.000 description 2
- 125000003518 norbornenyl group Chemical group C12(C=CC(CC1)C2)* 0.000 description 2
- 125000002524 organometallic group Chemical group 0.000 description 2
- QMMOXUPEWRXHJS-UHFFFAOYSA-N pentene-2 Natural products CCC=CC QMMOXUPEWRXHJS-UHFFFAOYSA-N 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 description 2
- 238000003809 water extraction Methods 0.000 description 2
- LGAQJENWWYGFSN-PLNGDYQASA-N (z)-4-methylpent-2-ene Chemical compound C\C=C/C(C)C LGAQJENWWYGFSN-PLNGDYQASA-N 0.000 description 1
- LAZHUUGOLCHESB-UHFFFAOYSA-N 2,3-dimethylbicyclo[2.2.1]hept-5-ene Chemical compound C1C2C(C)C(C)C1C=C2 LAZHUUGOLCHESB-UHFFFAOYSA-N 0.000 description 1
- CMAOLVNGLTWICC-UHFFFAOYSA-N 2-fluoro-5-methylbenzonitrile Chemical compound CC1=CC=C(F)C(C#N)=C1 CMAOLVNGLTWICC-UHFFFAOYSA-N 0.000 description 1
- YHQXBTXEYZIYOV-UHFFFAOYSA-N 3-methylbut-1-ene Chemical compound CC(C)C=C YHQXBTXEYZIYOV-UHFFFAOYSA-N 0.000 description 1
- YSWATWCBYRBYBO-UHFFFAOYSA-N 5-butylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(CCCC)CC1C=C2 YSWATWCBYRBYBO-UHFFFAOYSA-N 0.000 description 1
- VVKPRHOUENDOED-UHFFFAOYSA-N 5-dodecylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(CCCCCCCCCCCC)CC1C=C2 VVKPRHOUENDOED-UHFFFAOYSA-N 0.000 description 1
- QHJIJNGGGLNBNJ-UHFFFAOYSA-N 5-ethylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(CC)CC1C=C2 QHJIJNGGGLNBNJ-UHFFFAOYSA-N 0.000 description 1
- WMWDGZLDLRCDRG-UHFFFAOYSA-N 5-hexylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(CCCCCC)CC1C=C2 WMWDGZLDLRCDRG-UHFFFAOYSA-N 0.000 description 1
- GOLQZWYZZWIBCA-UHFFFAOYSA-N 5-octylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(CCCCCCCC)CC1C=C2 GOLQZWYZZWIBCA-UHFFFAOYSA-N 0.000 description 1
- PZMNDDBVLSUSNR-UHFFFAOYSA-N 5-propan-2-ylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C(C)C)CC1C=C2 PZMNDDBVLSUSNR-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 239000000701 coagulant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- FWFSEYBSWVRWGL-UHFFFAOYSA-N cyclohex-2-enone Chemical compound O=C1CCCC=C1 FWFSEYBSWVRWGL-UHFFFAOYSA-N 0.000 description 1
- LRZCOABZEULHCP-UHFFFAOYSA-N cyclohexane;methanol Chemical compound OC.C1CCCCC1 LRZCOABZEULHCP-UHFFFAOYSA-N 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 1
- CGGWHUZJDXLSTD-UHFFFAOYSA-M dimethylalumanylium;iodide Chemical compound C[Al](C)I CGGWHUZJDXLSTD-UHFFFAOYSA-M 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- NARCMUVKZHPJHP-UHFFFAOYSA-L ethyl(diiodo)alumane Chemical compound [I-].[I-].CC[Al+2] NARCMUVKZHPJHP-UHFFFAOYSA-L 0.000 description 1
- UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 150000004820 halides Chemical group 0.000 description 1
- 150000002432 hydroperoxides Chemical class 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052987 metal hydride Inorganic materials 0.000 description 1
- 150000004681 metal hydrides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000005649 metathesis reaction Methods 0.000 description 1
- 239000000401 methanolic extract Substances 0.000 description 1
- GICWIDZXWJGTCI-UHFFFAOYSA-I molybdenum pentachloride Chemical compound Cl[Mo](Cl)(Cl)(Cl)Cl GICWIDZXWJGTCI-UHFFFAOYSA-I 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000011112 process operation Methods 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 229920006395 saturated elastomer Chemical group 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
- C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
- C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
- C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
Description
ïŒçºæã®èæ¯ïŒ
ã·ã¯ããªã¬ãã€ã³ã®æº¶æ¶²éç°éåã«ãããŠãå
å¿åšããåãåºãããçæç©ã¯äž»ãšããŠãäžã«é
åäœã溶解ããŠããé極æ§ãã€ãªã€ãŒæº¶å€ããæ
ãèèæ§ã»ã¡ã³ãã§ããããã®éåäœã®å«æé
ã¯ãéåžžçŽ15ééïŒ ã®ãªãŒããŒã§ããããã®éé
äœã¯ããã«ãã«ãã³åºãå«æããïŒçš®åã¯è€æ°çš®
ã®ã·ã¯ããªã¬ãã€ã³ã®åç¬éååã¯å ±éåã«ãã€
ãŠè£œé ãããä»»æã®ç³»çµ±ã®éåäœã§ãã€ãŠããã
éåã¯ååçåã¯é£ç¶çã«è¡ãããšãã§ããã ïŒå è¡æè¡ïŒ èèæ§ã»ã¡ã³ããçæããããåŸãéåäœãã
ã®ãã€ãªã€ãŒæº¶å€ããåé¢ããå¿ èŠããããåŸ
æ¥ããã€ãªã€ãŒæº¶å€ããéåäœãæœåºããããã®
è£ çœ®ã®é転ã«ãããŠã¯ãã€ã±ãèžæ°ã¹ããªããã³
ã°ãè¡ãããŠãããèžæ°ã¹ããªããã³ã°ã«ãããŠ
ã¯ãç±æ°Žãå容ãã容åšäžã«åããããèžæ°åŽæµ
äžã«ã»ã¡ã³ããæ³šå ¥ããããã»ã¡ã³ããšèžæ°ãšã®
æ¥è§Šã®éã«ãã€ãªã€ãŒæº¶å€ãèžçºåé¢ããéåäœ
ã¯ç²ç¶ãšãªã€ãŠç±æ°Žäžã«æ²ç©ããã èžæ°ã¹ããªããã³ã°ã¯å€ãã®æ·±å»ãªæ¬ ç¹ãæã
ãããçŸåšã¯äœ¿çšãããŠããªãã ããã«æè¿ã«ãªã€ãŠããã€ãªã€ãŒæº¶å€ããã·ã¯
ããªã¬ãã€ã³ã®éåäœãåé¢ããããã®åèšã®æ¹
æ³ã«ä»£ãæ¹æ³ãçºèŠãããããã®æ¹æ³ã«åŸãã°ã
ã»ã¡ã³ãã¯ãé«åªææ··åæ©äžã§ãé溶å€ãšã»ã¡ã³
ãã®å®¹éæ¯ãçŽïŒïŒïŒã«ãªãããã«æ¯æº¶å€ãšæ··å
ãããããã«ããéåäœãæ²æŸ±ãããé溶å€ã¯ã
éååå¿ã«ãããŠäœ¿çšãããé極æ§æº¶å€ãšã¯æ··å
æ§ã§ãããéåäœã溶解ããªã液äœã§ãããé©åœ
ãªé溶å€ã®äŸã«ã¯ãšã¿ããŒã«ããããããŒã«ãã€
ãœãããããŒã«åã³ãããã«é¡ãããã®ãå«ãŸã
ããããå Žåã«ã¯ãã®ååæ¹æ³ã«ããçŽ0.144
ïœïŒc.c.ããªãã¡ïŒïœïŒft3ã®åµ©å¯åºŠãæããé¡
ç²ç¶ã§ä¹Ÿç¥å®¹æãªçæç©ã圢æãããããããã
ã®çµæã¯åçŸæ§ã確å®ã§ãªãã€ããéåžžåŸããã
çæç©ã¯ã埮现ãªãäžèŠåãªæ¯çŸœç«ã¡ãã埮现ç¹
ç¶ã®éç¶ç©ã§ãã€ãŠãéã«éããŠç¶¿ç¶ã«è©°ãŸ
ãããããŠä¹Ÿç¥åã³åæ±ãå°é£ã§ãã€ãã也ç¥ç
æç©ã¯éåžž0.08ïœïŒc.c.ããªãã¡ïŒïœïŒft3ãã
å°ãã嵩å¯åºŠãæããŠããã éåäœã»ã¡ã³ããé溶å€äžã§æ²æŸ±åã¯ååºãã
å Žåãé«éåäœã¯é溶å€âæ··å溶å€ç³»ããæ²æŸ±ã
ãããªãªãŽããŒã觊åªæ®æž£åã³ãããã«é¡ããã
ã®ã¯è©²æ··å溶å€ç³»ã«æº¶è§£ããŠæ®çãããå®è³ªçé
ã®äžçŽç©ãé溶å€ã«æº¶è§£ããããããã®ååæ¹æ³
ã«ããéåäœããå€éã®äžçŽç©ãé€å»ããããšã
ã§ãããããããªããããã®æ¹æ³ã«ãããŠã¯ãé
溶å€ãç°ç¶åéäœãåå¿æº¶å€ãåã³éååå¿ã®æ®
çåå¿åæ¢å€ãåå¿åæ¢å€ãšè§Šåªæ®æž£ãšã®ä»å
ç©ãæ®ç觊åªæåããªãªãŽããŒçãå«ãäžçŽç©ã
ããªãå€éã®æ±æ液ãçæãããããå®å šã«ã¯æº
足ãã¹ããã®ã§ã¯ãªãã€ããå€éã®é溶å€â溶å€
液ããã®æº¶å€ã®ååã¯å°é£ã§ãããããŠçµæžçã§
ãªããããã«ãæ°Žåã³æº¶å€ãšå ±æ²žæ··åç©ã圢æã
ãé溶å€ãæ°Žãå«æããªãç¶æ ã§äœ¿çšããªããã°
ãªããªããšããè€éãã䌎ã€ãã ããã«è©³ããã¯ãéåäœã®æœåºã«é溶å€ã䜿çš
ããããšã«é¢ãããã³ã«ã¯ïŒMinchakïŒã®ç±³åœ
ç¹èš±ç¬¬4069376å·æ现æžç¬¬ïŒæ¬ã«ã¯ãã¡ã¿ããŒã«ã
ãšã¿ããŒã«ãã€ãœãããããŒã«åã³ãããã«é¡ã
ããã®ã®ããšããäœçŽã¢ã«ã³ãŒã«ããéžã°ããé
溶å€ã䜿çšããŠæ²æŸ±ããããããšã«ãããïŒçš®å
ã¯è€æ°çš®ã®ã·ã¯ããªã¬ãã€ã³ã®éåäœãåé¢ãã
ããšãã§ããæšé瀺ãããŠããããã®å ¬ç¥æ¹æ³ã«
ãããŠã¯ãé«åªæ匷åæ··åæ©äžã§éåäœã»ã¡ã³ã
ãšé溶å€ãæ··åãããããã«ããã¹ã©ãªãŒã圢æ
ãããã次ã«ãã®ã¹ã©ãªãŒã¯ã¹ã©ãªãŒã¿ã³ã¯ã«èŒž
éãããããã§åšå²æž©åºŠã«ãããŠããã«æ¹æã
ãããããŠã¹ã©ãªãŒã¯ã¹ã©ãªãŒã¿ã³ã¯ããåãåº
ãããé å¿åé¢åã¯éãããããã§éåäœãå
é¢ããããããŠä¹Ÿç¥ãããä»æ¹æ¶²ã¯åå段éã«
ãã³ãã³èŒžéãããããã§é溶å€ããç°ç¶é極æ§
溶å€ãåé¢ããããããŠååãããã液ã¯æ¬è³ª
äžç°ç¶é極æ§æº¶å€ãšé溶å€çåæ°ŽçŽ ãããªãã ïŒçºæã®æŠèŠïŒ ãã®çºæã¯ãã¡ã¿ããŒã«ïŒã·ã¯ããããµã³å ±æ²ž
æ··åç©ã®æ²žç¹åã¯ãã®è¿åããã¡ã¿ããŒã«ã®æ²žç¹
ã®ç¯å²ã®æž©åºŠã«ãããŠã»ã¡ã³ãããããªã·ã¯ããª
ã¬ãã€ã³ãã¡ã¿ããŒã«ã«ããæ²æŸ±ããããã¡ã¿ã
ãŒã«ïŒã·ã¯ããããµã³å ±æ²žæ··åç©ãèžæ°ãšããŠå
ãåºãããããåçž®ããããå瞮液ãã»ãšãã©ã
ã¹ãŠã·ã¯ããããµã³ã§ããäžå±€ãšå€éã®ã¡ã¿ããŒ
ã«ãå«æããäžå±€ã«å±€åé¢ãã次ã«ã·ã¯ããªã¬ã
ã€ã³ãåé¢ãããããŠã¡ã¿ããŒã«ãååããæ¹æ³
ã«é¢ãããæ²æŸ±æž©åºŠã®ç¯å²ã¯å€§æ°å§äžã§çŽ55ã65
âã§ããã ïŒå ·äœçãªèª¬æïŒ ãã®çºæã¯ãã¡ã¿ããŒã«ïŒã·ã¯ããããµã³äºå
å ±æ²žæ··åç©ã®æ²žç¹åã¯ãã®è¿åããã¡ã¿ããŒã«ã®
沞ç¹ã®ç¯å²ã®æž©åºŠã«ãããããªã·ã¯ããªã¬ãã€ã³
åã³ã·ã¯ããããµã³æº¶å€ãå«ãã§æãéåäœã»ã¡
ã³ãã®æ²æŸ±ã«ãããŠãé溶å€ãšããŠã¡ã¿ããŒã«ã
䜿çšããããšã«é¢ããã倧æ°å§äžã«ãããŠäœ¿çšã
ãã枩床ç¯å²ã¯çŽ55ã65âã§ããã倧æ°å§ããäœ
ãåã¯é«ãå§åã«ãããŠæ²æŸ±ãè¡ãå Žåã«ã¯ãã
ãã«åŸã€ãŠæäœæž©åºŠãå€ããããšãã§ãããäžèš
ã®æž©åºŠç¯å²ã«ãããŠæäœããããšã«ããã»ã¡ã³ã
ã¹ã©ãªãŒãã54âã§æ²žéš°ããã¡ã¿ããŒã«ïŒã·ã¯ã
ãããµã³äºå å ±æ²žæ··åç©ãåãåºããããããå
çž®ããããããšã«ããã»ãšãã©ãã¹ãŠãã·ã¯ãã
ããµã³ã§ããäžå±€ãšã¡ã¿ããŒã«ãå€éã«å«ãäžå±€
ãšã«åé¢ããã溶å€ãå€éã«å«ãäžå±€ãåãåºã
ããšã«ãã溶å€ã®ååãä¿é²ãããåä»ã®å©ç¹ã
åŸãããã ãã®æ²æŸ±å·¥çšããäºåæ¿çž®å·¥çšãšå ±ã«ç¬¬ïŒå³ã«
瀺ãããŠãããäºåæ¿çž®å·¥çšã«ãããŠã¯çŽ15ïŒ ã®
åºåœ¢åãå«ãã»ã¡ã³ããçŽ20ã35ïŒ ã®åºåœ¢åãå«
ãã»ã¡ã³ãã«æ¿çž®ãããããã€ãšããããã«æ¿åºŠ
ãäžããããšãå¯èœã§ããããã®äºåæ¿çž®ã¯å Žå
ã«ããè¡ããäºåæ¿çž®ãè¡ãå Žåãã»ã¡ã³ãã¯çŽ
15ïŒ ããé«ãåºåœ¢åæ¿åºŠãæããããäºåæ¿çž®ã
è¡ããªãå Žåã«ã¯éåžžçŽ15ïŒ ã®åºåœ¢åãå«ãã»ã¡
ã³ããéåéšäœããçŽæ¥æ²æŸ±å·¥çšã«éãããã 第ïŒå³ã«ãããŠãã·ã¯ããããµã³æº¶å€äžã«æº¶è§£
ããã·ã¯ããªã¬ãã€ã³éåäœãå«ãã§æãéåäœ
ã»ã¡ã³ãã¯ç®¡è·¯ïŒïŒãéããŠæ··åæ©ïŒïŒã«å°å ¥ã
ãããéåäœã»ã¡ã³ãã¯çŽ15ïŒ ã®åºåœ¢åæ¿åºŠãæ
ããã»ã¡ã³ãã®åºåœ¢åã¯æ¬è³ªäž90éééšã®ã¡ãã«
ããã©ã·ã¯ãããã»ã³ãš10éééšã¡ãã«ãã«ãã«
ãã³ãããªãå ±éåäœã§ããããããŠ85ïŒ ã®æ¶²éš
åã¯æ¬è³ªäžã·ã¯ããããµã³ã§ãããæ··åæ©ïŒïŒã«
ã¯ããã«ç®¡è·¯ïŒïŒãéããŠã¡ã¿ããŒã«ãå ãã
ããããã§ã¡ã¿ããŒã«ãšã»ã¡ã³ããæ··åãããã
ãã®æ¹æ³ã«ãããŠã¯ãã¡ã¿ããŒã«ãã»ã¡ã³ããã
溶å€ã®å®è³ªçéšåãæœåºããããã«ãã溶解ãã
éåäœæåãå¢å ããã²ã«ç¶ç©ã圢æããããã
ãäºåæ¿çž®ã»ã¡ã³ããšç§°ãããäºåæ¿çž®ã»ã¡ã³ã
ã¯æ··åæ©ïŒïŒãã管路ïŒïŒãéããŠåé¢ã¿ã³ã¯ïŒ
ïŒã«ãã³ã茞éãããããã§æ¹æã䌎ããªãã§ã»
ã¡ã³ãã¹ã©ãªãŒãïŒå±€ã«åé¢ãããããªãã¡ãäž
å±€ã¯ã¡ã¿ããŒã«åã³ã·ã¯ããããµã³ãå«æããã
ãã¯ç®¡è·¯ïŒïŒãéã€ãŠååå·¥çšã«ãã³ã茞éã
ããä»æ¹äžå±€ã¯ã²ã«æ§ã®äºåæ¿çž®ç©ãããªãã äºåæ¿çž®æäœã«äœ¿çšããã¡ã¿ããŒã«ã®äœ¿çšé
ã¯ãäºåæ¿çž®ããããã«ã¯ååã§ããéåäœãæ²
柱ããããããã«ã¯äžååãªéãšãã¹ãã§ããã
ãã®éã¯ã»ã¡ã³ã100容ééšã«å¯ŸããŠçŽïŒã100容
ééšã§ããã äºåæ¿çž®æäœã¯åšå²æž©åºŠã«ãããŠè¡ãããšãã§
ããããäžè¬ã«ã¯ã¡ã¿ããŒã«âã·ã¯ããããµã³å ±
沞混åç©ã®æ°·ç¹ãã沞ç¹ã®ç¯å²ã§è¡ãã æ··åæ©ïŒïŒã«èŒžéãããã»ã¡ã³ããéåå·¥çšã
ãçŽæ¥åãå ¥ããå Žåã«ã¯ã»ã¡ã³ãã®æž©åºŠã¯çŽ40
ã50âã§ããããã®å Žåã«ã¯äºåæ¿çž®ãããã«é«
ã枩床ã«ãããŠè¡ãããšãã§ããããããããšã«
ããã»ã¡ã³ãã®ç²åºŠãäœäžããã»ã¡ã³ãã®äºåæ¿
çž®ãæ¹è¯ãããããŠäžçŽç©ã®æœåºãæ¹è¯ãããã
ãæäœã容æã«ãªãããã®å Žåã管路ïŒïŒãéã
ãŠæ··åæ©ïŒïŒã«å ¥ãã¡ã¿ããŒã«ã®æ¿åºŠã¯65âã§ã
ãããé«æž©ã«ãããäºåæ¿çž®ãå ç±ããããšãªã
è¡ãããšãã§ããã äºåæ¿çž®äžå±€ã¯ãã·ã¯ããããµã³åã³éåäœã
å«æããŠãããåé¢ã¿ã³ã¯ïŒïŒãã管路ïŒïŒãé
ããŠåãåºããããããŠé«åªæ匷åæ··åæ©ïŒïŒã«
茞éããããæ··åæ©ïŒïŒã¯ãšããã³ããã
ïŒEppenbachïŒåã®é«åªæ匷åæ··åæ©ã§ãããæ··
åæ©ïŒïŒã«ãããŠã¡ã¿ããŒã«ãšã»ã¡ã³ããšãæ··å
ãããå Žåç¬éçã«æ²æŸ±ããããããããŠéåäœ
ç²åã«ããã·ã¯ããããµã³åã³ã¡ã¿ããŒã«ãå«æ
ãã液çžäžåæ£äœã圢æããããæ²æŸ±ããéåäœ
ã®æ¶²çžäžæ··åç©ãéåäœã»ã©ãªãŒãšç§°ããã æ··åæ©ïŒïŒããã®éåäœã¹ã©ãªãŒã¯ç®¡è·¯ïŒïŒã
éããŠãå€éšèžæ°ãžã€ã±ããïŒïŒã®ããšãå ç±æ
段åã³æ¹ææ©ïŒïŒãè£ çããã¹ã©ãªãŒã¿ã³ã¯ïŒïŒ
ã«èŒžéããããååå·¥çšããã®ã¡ã¿ããŒã«ã管路
ïŒïŒãéããŠã¹ã©ãªãŒã¿ã³ã¯ã«å ããããšãã§ã
ããã¹ã©ãªãŒã¿ã³ã¯äžã§ããããã®è¿œå ã®æœåºã
è¡ãããšãã§ããã ãã§ã«èšèŒããããã«ãæ²æŸ±ã¯ã¡ã¿ããŒã«ïŒã·
ã¯ããããµã³å ±æ²žæ··åç©ã®æ²žç¹åã¯ãã®è¿åãã
ã¡ã¿ããŒã«ã®æ²žç¹ã®ç¯å²ã®æž©åºŠã«ãããŠè¡ãã倧
æ°å§ã«ãããŠã¯äžèšã®ããšãå®çŸ©ãã枩床ç¯å²ã¯
çŽ55ã65âã§ããããã®æž©åºŠç¯å²ã奜ãŸããã¯ã¡
ã¿ããŒã«ã®æ²žç¹åã¯ãã®è¿åã®æž©åºŠã«ãããŠã¹ã©
ãªãŒã¿ã³ã¯ïŒïŒãé転ããããšã«ããã¡ã¿ããŒ
ã«ïŒã·ã¯ããããµã³å ±æ²žæ··åç©ãéåäœã¹ã©ãªãŒ
ããèžçºãåãåºããããåŸã«æ€èšããçç±ã«ã
ãã¹ã©ãªãŒã¿ã³ã¯äžã®æž©åºŠã¯ã¡ã¿ããŒã«ã®æ²žç¹å
ã¯ãã®è¿åã«ä¿æãã¹ãã§ããã éåäœã»ã¡ã³ãã®æ²æŸ±ã«ãããŠã¯ãã¡ã¿ããŒã«
ã®éãã»ã¡ã³ãïŒå®¹ééšã«å¯ŸããŠïŒã15容ééšã
奜ãŸããã¯ïŒãïŒå®¹ééšã®ç¯å²ã§å€ããããšãã§
ããã éåäœã¹ã©ãªãŒãã¹ã©ãªãŒã¿ã³ã¯ïŒïŒã«å ¥ã€ã
å Žåããããæ¹æããå ç±ããåã¯ææã®æž©åºŠã«
ä¿æãããéåäœã¹ã©ãªãŒãã管路ïŒïŒãéããŠ
åºãŠããèžæ°ã¯ã¡ã¿ããŒã«ïŒã·ã¯ããããµã³ã®å ±
沞混åç©ã§ãã€ãŠãçŽ55âã®æ²žç¹ãæããæšæºå§
äžã§æž¬å®ããèžæ°çžã®çµæã¯37ééïŒ ã®ã¡ã¿ããŒ
ã«ãš63ééïŒ ã®ã·ã¯ããããµã³ããæããèžæ°ç¶
æ ã®å ±æ²žæ··åç©ã¯å å¡«å¡ïŒïŒãéããŠåçž®åšïŒïŒ
ã«èŒžéãããããã§åçž®ãããããããããŠåšå²
枩床ãŸã§å·åŽãããã次ã«å瞮液ã¯ç®¡è·¯ïŒïŒãé
ããŠãã«ã³ãã¿ã³ã¯ïŒïŒã«éãããããã§ããã
次ã®å®¹éãããªãïŒå±€ã«åé¢ããã äž å±€ïŒ43ïŒ äž å±€ïŒ57ïŒ åå±€ã«ãããã¡ã¿ããŒã«ãšã·ã¯ããããµã³ã®é
éçµæã¯æ¬¡ã®éãã§ããã äžå±€ ã¡ã¿ããŒã«ïŒïŒïŒ ã·ã¯ããããµã³ïŒ97ïŒ äžå±€ ã¡ã¿ããŒã«ïŒ61ïŒ ã·ã¯ããããµã³ïŒ39ïŒ äžå±€ã¯ã»ãšãã©ãã¹ãŠãã·ã¯ããããµã³ã§ãã
ã¡ã¿ããŒã«ã¯ãããã«ïŒïŒ ã§ããããäžå±€ã¯ã¡ã¿
ããŒã«ãå€éã«å«ã¿ãã·ã¯ããããµã³ã¯39ïŒ ã§ã
ãããšã«æ³šæããå¿ èŠãããã åèšã®ããšããå®è³ªäžãã¹ãŠã®ã·ã¯ããããµã³
ãèžçºããããããã«ã¡ã¿ããŒã«ã®æ²žç¹åã¯ãã®
è¿åã®æž©åºŠã§ã¹ã©ãªãŒã¿ã³ã¯ã®é転ãè¡ãã®ã奜
ãŸããã第ïŒå³ã«ç€ºããããªé£ç¶åŒæ²æŸ±æäœã«ã
ããŠã¯ãéå°ã®ã¡ã¿ããŒã«ãé¢è±ããããªããã
ã«å ±æ²žèžæ°ã®äžéšåãã¹ã©ãªãŒã¿ã³ã¯ã«æ®çãã
ããã®ã奜ãŸããããã®ããã«æäœããããã«
ã¯ãå ±æ²žæ··åç©ã®å瞮液ã®ã¡ã¿ããŒã«ãå€ãå«ã
äžå±€ã®äžéšã管路ïŒïŒã®éæµãšããŠäœ¿çšãããã®
éãéåžžã®èžçå·¥çšã®å Žåãšåæ§ã«åçž®åšã«å ¥ã
èžæ°ã®æž©åºŠã«ããå¶åŸ¡ããã®ãæã奜ãŸããã ã¹ã©ãªãŒã¿ã³ã¯ããã®å°éã®è¿œå ã®ã¡ã¿ããŒã«
ã®èžçºã¯ããŸãåé¡ã§ã¯ãªããããããªãããã
ã®ãããªæ¡ä»¶ãååšããã¡ã¿ããŒã«ãèžçºãã
ã°ãã¡ã¿ããŒã«ã¯åçž®ãããããŠãã«ã³ã¿ãŒã¿ã³
ã¯ïŒïŒã«èŒžéãããããã§äžå±€ãšäžå±€ã«åé ãã
ãã§ãããããã®å Žåã«ã¯äžå±€ã®éãæžå°ããã·
ã¯ããããµã³ãã¡ã¿ããŒã«ããåé¢ããååå·¥çš
ã«äžå¿ èŠãªè² æ ããããããšã«ãªããã åŸã€ãŠããã®çºæã®èŠä»¶ã¯åçž®åŸã«ã¡ã¿ããŒ
ã«ïŒã·ã¯ããããµã³å ±æ²žæ··åç©ã®å±€åé¢ãè¡ãã
ãšã«ããããã®ç¹åŸŽã¯ã(1)åçž®ããå ±æ²žæ··åç©ã®
äžå±€ã¯ã»ãšãã©ãã¹ãŠã·ã«ããããµã³ã§ãããã
ããŠ(2)ã¡ã¿ããŒã«ããã·ã¯ããããµã³ãããã«å
é¢ããããã®æ°Žæœåºãè¡ãããšãªãååå·¥çšãå®
æœããããšãã§ãããšããäºå®ã®ããã«ååå·¥çš
ãéåžžã«ä¿é²ããããã®æ现æžã«èšèŒããæ²æŸ±ã
æœåºåã³ååå·¥çšã¯åååŒã«è¡ãããšãã§ããå
第ïŒå³ã«ç€ºãããã«å®å šã«é£ç¶çã«è¡ãããšãã§
ããããã®çºæã®å ·äœåã«ãããŠã¯ããŸãéèŠã§
ã¯ãªãå®éççç±åã³æè¡ççç±ã«ããé£ç¶æ³ã
奜ãŸããã é£ç¶æäœã«ãããŠãã·ã¯ããããµã³ïŒã¡ã¿ããŒ
ã«å ±æ²žæ··åç©ã®äžéšãšããŠã¹ã©ãªãŒã¿ã³ã¯ããé€
å»ãããã¡ã¿ããŒã«èžæ°ãè£ãããã«ã¡ã¿ããŒã«
ãå·¥çšã«äŸçµŠããå Žåã第ïŒå³ã«ç€ºãããã«ã¹ã©
ãªãŒã¿ã³ã¯ã«çŽæ¥äŸçµŠãããããããŸãæçµæŽæµ
ãšããŠé å¿åé¢æ©ãéãããããŠé å¿åé¢æ©ãã
ã®æ¶²ãšå ±ã«ãæ²æŸ±ã«å¿ èŠã§ããã°å¥åã«æ··åæ©
ã«äŸçµŠããã®ã奜ãŸããã äºåæ¿çž®å·¥çšã¯å Žåã«ããè¡ããããããè¡ã
ã°ã管路ïŒïŒãéããŠæ²æŸ±å·¥çšã«å埪éãããã¡
ã¿ããŒã«äžã«æ®çããŠãããããããªãäžçŽç©ã
é€å»ããããšããç¹å¥ãªå©ç¹ãåŸããããäºåæ¿
çž®ãè¡ããªãå Žåããã«ä»£ãèªæã®æ¹æ³ã¯ææã«
ããæµãïŒïŒããã®ããã®ååå·¥çšã«éãããšã§
ããã äžå±€ã¯ãã«ã³ãã¿ã³ã¯ïŒïŒãã管路ïŒïŒãéã
ãŠã·ã¯ããããµã³ååå·¥çšã«ãã³ã茞éãããäž
å±€ã¯ç®¡è·¯ïŒïŒãéããŠã¡ã¿ããŒã«ååå·¥çšã«ãã³
ã茞éããããååå·¥çšã¯ãã®çºæã®äžéšãæ§æ
ããªããããã®æ现æžã«èšèŒããªãã éåäœåã³ã¡ã¿ããŒã«ã®æ··åç©ã¯ã¹ã©ãªãŒã¿ã³
ã¯ïŒïŒã®åºãã管路ïŒïŒãéããŠåãåºãããã
ããŠåé¢æ©ïŒïŒã«èŒžéããããåé¢æ©ã¯é å¿åé¢
æ©åã¯éåšã§ãã€ãŠããããåä»ã®é©åœãªåé¢
æ段ã§ãã€ãŠããããéåäœã¯åé¢æ©ïŒïŒã«ãã
ãŠã¡ã¿ããŒã«ããåé¢ããããããŠä¹Ÿç¥æ©ïŒïŒã«
茞éãããä»æ¹ã¡ã¿ããŒã«ã¯ç®¡è·¯ïŒïŒãéããŠã
ã³ã茞éããããã®äžéšã¯ç®¡è·¯ïŒïŒãéããŠæ··å
æ©ïŒïŒã«èŒžéããããããŠä»ã®éšåã¯ç®¡è·¯ïŒïŒã
éããŠæ··åæ©ïŒïŒã«èŒžéããããåé¢æ©ïŒïŒãã
åãåºãããçŽ70ééïŒ ã®ã¡ã¿ããŒã«ãå«æãã
湿最éåäœã¯ç®¡è·¯ïŒïŒãéããŠä¹Ÿç¥æ©ïŒïŒã«èŒžé
ãããããã§éåäœã¯ã¡ã¿ããŒã«å«éïŒïŒ æªæºãŸ
ã§ä¹Ÿç¥ãããã也ç¥ããéåäœã¯è²¯èµã®ããã«ç®¡
è·¯ïŒïŒãéããŠåãåºãããä»æ¹ä¹Ÿç¥æ©ããã®ã¡
ã¿ããŒã«ã¯ç®¡è·¯ïŒïŒãéããŠããã«ã³ãã¿ã³ã¯ïŒ
ïŒã®äžå±€æ¶²ãšç®¡è·¯ïŒïŒã«ãããŠäœµåããããããŠ
ã¡ã¿ããŒã«ååå·¥çšã«éãããããããã¯ããã«
代ããŠããã®ã¡ã¿ããŒã«ã¯çŽæ¥ã«æ²æŸ±æ®µéåã¯äº
åæ¿çž®æ®µéã«å埪éãããããã«ã³ã¿ãŒããã®äž
局液ã¯æ¬è³ªäž61ééïŒ ã®ã¡ã¿ããŒã«åã³39ééïŒ
ã®ã·ã¯ããããµã³ããæãã ã¡ã¿ããŒã«ïŒã·ã¯ããããµã³å ±æ²žæ··åç©æ¿çž®æ¶²
ã®ïŒå±€åé¢ã¯ç¹åŸŽçã§ãããä»ã®ã¢ã«ã³ãŒã«ã§ã¯
ãã®ããã«ããããšãã§ããªããåçž®ããå ±æ²žæ··
åç©ã®äžå±€ãã»ãšãã©ãã¹ãŠã·ã¯ããããµã³ã§ã
ãã®ã§ãååèœåããšãã«ã®ãŒçµè²»ãååé転çµ
è²»çãå°ãªããŠãããšããå€ãã®å©ç¹ãåŸãã
ããããªãã¡ãæ²æŸ±ã«å¿ èŠãªå€éã®ã¡ã¿ããŒã«
ããããã«åååŠçããããšãªããåé¢æ©ããçŽ
æ¥æ²æŸ±å·¥çšã«å埪éããããšãã§ãããé«æž©ã§æ
äœããããšã«ãã溶å€ã調ç¯å€åã³äžçŽç©ã«é¢ã
ãã¡ã¿ããŒã«ã®æœåºåã匷åããããäŸãã°ãã¡
ã¿ããŒã«ã¯ãããã»ã³âïŒãååé調ç¯å€ãšå ±ã«
å ±æ²žæ··åç©ã圢æããçŽ48âã§æ²žéš°ããããã®ã
ãšã¯ã調ç¯å€ãåã³ããããè¥å¹²ã®äžçŽç©ã¯ã·ã¯
ããããµã³ãšå ±ã«èžæ°ãšããŠé«æž©éåäœã¹ã©ãªãŒ
ããèžçºé€å»ãããããšãæå³ãããåŸã€ãŠé«æž©
ã§æäœããããšã«ããå¿ èŠãªã¡ã¿ããŒã«ã®å®¹ç©ã
å°ãªããŠãã¿ããã®å¹çãæ¹è¯ããããããã«ã
é«æž©ã«ãããŠã¯ãæåã®äŸçµŠåæåã¯äºåæ¿çž®ã»
ã¡ã³ããšããŠã®ã»ã¡ã³ãã®ç²åºŠãäœäžããããšã«
ããåæ±ã容æã«ãªããããŠæœåºå¹æãæ¹è¯ã
ããããã«éåäœç²åããã®æ®çäžçŽç©ã®æœåºã
匷åãããããšã«ãã補åã®å質ãæ¹è¯ãããã
åãã¡ã¿ããŒã«ã䜿çšããããšã«ãããä»ã®ã¢ã«
ã³ãŒã«ã䜿çšããå Žåã«æ¯ã¹ãŠã容æã«ä¹Ÿç¥ãã
ããŠåæ±ãããšãã§ããããå¯åºŠã®é«ããããŠç²
圢ã®å€§ããéåäœç²ãåŸãããããšãèŠåºãã
ããåãä»ã®ã¢ã«ã³ãŒã«ã䜿çšããå Žåãšç°ãª
ãããã®æ²æŸ±æ¹æ³ã¯æ°Žã䜿çšããªãããã®å Žåã«
ã¯ãåèšã®ããšããåæ§ã®ç³»ã«ãããŠé溶å€ãšã
ãŠä»ã®ã¢ã«ã³ãŒã«ã䜿çšããå Žåã®ããã«æº¶å€å
åã®ããã«æ°Žæœåºãå¿ èŠãšããªãã ãã«ãã«ãã³æåãå«æããç°ç¶ãªã¬ãã€ã³ã®
éåäœã¯ãå°ãªããšãïŒçš®é¡ã®ããã²ã³åã¢ã«ã
ã«ã¢ã«ãããŠã å©è§Šåªãšå°ãªããšãïŒçš®é¡ã®ã¿ã³
ã°ã¹ãã³åã¯ã¢ãªããã³ååç©è§Šåªãå«ãã§ãªã
è€å解觊åªã®ååšäžã§ã®ç°ç¶ãªã¬ãã€ã³ã®éç°é
åã«ãã€ãŠè£œé ããããšãã§ãããéå±ååç©è§Š
åªäžã®ã¿ã³ã°ã¹ãã³åã³ã¢ãªããã³ã¯ãããã²ã³
åã¿ã³ã°ã¹ãã³ãããã¯ããã²ã³åã¢ãªããã³äž
ã«ãããããšãéœã€ãªã³ãšããŠãåã¯ã¿ã³ã°ã¹ã
ã³é žååç©ãããã¯ã¢ãªããã³é žååç©äžã«ãã
ãããšãé°ã€ãªã³ãšããŠååšããããããšãã§ã
ããéåã«ããã€ãŠã¯ãåéäœç°ç¶ãªã¬ãã€ã³å
ã¯ãã®æ··åç©ããä»ã®å ±éåäœåéäœã䌎ã€ãŠå
ã¯äŒŽããªãã§ãã·ã¯ããããµã³é極æ§çåæ°ŽçŽ æº¶
å€ãšå ±ã«åå¿åšäžã§æ··åããã次ã«ãéå ±åœ¹éç°
ç¶ãªã¬ãã€ã³é¡ããéžã°ããååé調ç¯å€ãåå¿
åšã«å ãã次ã«ããã²ã³åã¢ã«ãã«ã¢ã«ãããŠã
å©è§Šåªãåã³ã¿ã³ã°ã¹ãã³åã¯ã¢ãªããã³ååç©
觊åªãå ãããéååå¿ã¯ãæ¹æããªããïŒã
200âã奜ãŸããã¯25ã100âã«ãããŠè¡ããã»ãš
ãã©ç±ãçæããªããåå¿å®çµæéã¯ïŒæéæªæº
ã®ãªãŒããŒã§ããã ã·ã¯ããªã¬ãã€ã³ã®éåã¯åååŒåã¯é£ç¶åŒã«
è¡ãããšãã§ãããäžèšã®æ²æŸ±æ¹æ³ã¯ãïŒçš®é¡ã®
åå¿æ¹åŒã®éã«ååšããåºæã®åååŠçå·®ç°ã«ã
ãçããã»ã¡ã³ãã®ååŠçµæã®çžéã«ãããã
ãããããã®æ¹åŒã«ãããŠãåæ§ã«è¡ãããšãã§
ãããé£ç¶åŒéåã«ãããŠã¯åååŒæäœã«æ¯ã¹ãŠ
ååé調ç¯å€åã³è§Šåªãå®è³ªäžå°ãªããŠãããã
ããŠååéã®ååžãçãéåäœãçæããããã®
ãããªçç±ãåã³ãã®çºæã®å ·äœäŸã«ãããŠã¯é
éã§ãªãä»ã®æè¡çãªå®éäžã®èæ ®ãããé£ç¶åŒ
éåãå·¥çšæäœã«æãäžè¬çã«æ¡çšããã奜ãŸã
ãæ¹æ³ã§ãããåå¿åšããçŽæ¥ååãããåå¿ç
æç©ã¯ã溶å€ã«åæ£ããéåäœãå«ãã§æãèè
æ§çš 床ãæããæ»ããã§ç²çš ãªã»ã¡ã³ãã§ããã
ã»ã¡ã³ãäžã®éåäœåã¯åºåœ¢ç©æ¿åºŠã¯çŽ15ïŒ ã§ã
ãããããŠéåäœã®çšè溶液ç²åºŠã¯éåžžçŽ0.1ã
ïŒã®ç¯å²ã«ãããçšè溶液ç²åºŠã¯ããã«ãšã³1d
äžéåäœ0.25ïœã®æº¶æ¶²ã®25âã«ãããç²åºŠæž¬å®
å€ã§ããã ãã®æ现æžã«èšèŒããæ¹æ³ã«åŸã€ãŠéåããã
ãããšãã§ããã·ã¯ããªã¬ãã€ã³ã®ãã«ãã«ãã³
ååéäœã¯ã次ã®åŒ () ã§è¡šãããã眮æãããŠããåã¯çœ®æãããŠããª
ããã«ãã«ãã³åºã®ååšã«ããç¹è²ãããããã
ãã®å®çŸ©ã«åŸãã°ãé©åœãªãã«ãã«ãã³ååéäœ
ã«ã¯çœ®æãããåã³çœ®æãããŠããªããã«ãã«ã
ã³é¡ããžã·ã¯ããã³ã¿ãžãšã³é¡ããžããããžã·ã¯
ããã³ã¿ãžãšã³é¡ãã·ã¯ããã³ã¿ãžãšã³ã®äžé
äœãåã³ããã©ã·ã¯ãããã»ã³é¡ãå«ãŸãããã
ã«ãã«ãã³åã®å¥œãŸããåéäœãšããŠã次ã®åŒ
ïŒïŒååïŒïŒã
å¿åšããåãåºãããçæç©ã¯äž»ãšããŠãäžã«é
åäœã溶解ããŠããé極æ§ãã€ãªã€ãŒæº¶å€ããæ
ãèèæ§ã»ã¡ã³ãã§ããããã®éåäœã®å«æé
ã¯ãéåžžçŽ15ééïŒ ã®ãªãŒããŒã§ããããã®éé
äœã¯ããã«ãã«ãã³åºãå«æããïŒçš®åã¯è€æ°çš®
ã®ã·ã¯ããªã¬ãã€ã³ã®åç¬éååã¯å ±éåã«ãã€
ãŠè£œé ãããä»»æã®ç³»çµ±ã®éåäœã§ãã€ãŠããã
éåã¯ååçåã¯é£ç¶çã«è¡ãããšãã§ããã ïŒå è¡æè¡ïŒ èèæ§ã»ã¡ã³ããçæããããåŸãéåäœãã
ã®ãã€ãªã€ãŒæº¶å€ããåé¢ããå¿ èŠããããåŸ
æ¥ããã€ãªã€ãŒæº¶å€ããéåäœãæœåºããããã®
è£ çœ®ã®é転ã«ãããŠã¯ãã€ã±ãèžæ°ã¹ããªããã³
ã°ãè¡ãããŠãããèžæ°ã¹ããªããã³ã°ã«ãããŠ
ã¯ãç±æ°Žãå容ãã容åšäžã«åããããèžæ°åŽæµ
äžã«ã»ã¡ã³ããæ³šå ¥ããããã»ã¡ã³ããšèžæ°ãšã®
æ¥è§Šã®éã«ãã€ãªã€ãŒæº¶å€ãèžçºåé¢ããéåäœ
ã¯ç²ç¶ãšãªã€ãŠç±æ°Žäžã«æ²ç©ããã èžæ°ã¹ããªããã³ã°ã¯å€ãã®æ·±å»ãªæ¬ ç¹ãæã
ãããçŸåšã¯äœ¿çšãããŠããªãã ããã«æè¿ã«ãªã€ãŠããã€ãªã€ãŒæº¶å€ããã·ã¯
ããªã¬ãã€ã³ã®éåäœãåé¢ããããã®åèšã®æ¹
æ³ã«ä»£ãæ¹æ³ãçºèŠãããããã®æ¹æ³ã«åŸãã°ã
ã»ã¡ã³ãã¯ãé«åªææ··åæ©äžã§ãé溶å€ãšã»ã¡ã³
ãã®å®¹éæ¯ãçŽïŒïŒïŒã«ãªãããã«æ¯æº¶å€ãšæ··å
ãããããã«ããéåäœãæ²æŸ±ãããé溶å€ã¯ã
éååå¿ã«ãããŠäœ¿çšãããé極æ§æº¶å€ãšã¯æ··å
æ§ã§ãããéåäœã溶解ããªã液äœã§ãããé©åœ
ãªé溶å€ã®äŸã«ã¯ãšã¿ããŒã«ããããããŒã«ãã€
ãœãããããŒã«åã³ãããã«é¡ãããã®ãå«ãŸã
ããããå Žåã«ã¯ãã®ååæ¹æ³ã«ããçŽ0.144
ïœïŒc.c.ããªãã¡ïŒïœïŒft3ã®åµ©å¯åºŠãæããé¡
ç²ç¶ã§ä¹Ÿç¥å®¹æãªçæç©ã圢æãããããããã
ã®çµæã¯åçŸæ§ã確å®ã§ãªãã€ããéåžžåŸããã
çæç©ã¯ã埮现ãªãäžèŠåãªæ¯çŸœç«ã¡ãã埮现ç¹
ç¶ã®éç¶ç©ã§ãã€ãŠãéã«éããŠç¶¿ç¶ã«è©°ãŸ
ãããããŠä¹Ÿç¥åã³åæ±ãå°é£ã§ãã€ãã也ç¥ç
æç©ã¯éåžž0.08ïœïŒc.c.ããªãã¡ïŒïœïŒft3ãã
å°ãã嵩å¯åºŠãæããŠããã éåäœã»ã¡ã³ããé溶å€äžã§æ²æŸ±åã¯ååºãã
å Žåãé«éåäœã¯é溶å€âæ··å溶å€ç³»ããæ²æŸ±ã
ãããªãªãŽããŒã觊åªæ®æž£åã³ãããã«é¡ããã
ã®ã¯è©²æ··å溶å€ç³»ã«æº¶è§£ããŠæ®çãããå®è³ªçé
ã®äžçŽç©ãé溶å€ã«æº¶è§£ããããããã®ååæ¹æ³
ã«ããéåäœããå€éã®äžçŽç©ãé€å»ããããšã
ã§ãããããããªããããã®æ¹æ³ã«ãããŠã¯ãé
溶å€ãç°ç¶åéäœãåå¿æº¶å€ãåã³éååå¿ã®æ®
çåå¿åæ¢å€ãåå¿åæ¢å€ãšè§Šåªæ®æž£ãšã®ä»å
ç©ãæ®ç觊åªæåããªãªãŽããŒçãå«ãäžçŽç©ã
ããªãå€éã®æ±æ液ãçæãããããå®å šã«ã¯æº
足ãã¹ããã®ã§ã¯ãªãã€ããå€éã®é溶å€â溶å€
液ããã®æº¶å€ã®ååã¯å°é£ã§ãããããŠçµæžçã§
ãªããããã«ãæ°Žåã³æº¶å€ãšå ±æ²žæ··åç©ã圢æã
ãé溶å€ãæ°Žãå«æããªãç¶æ ã§äœ¿çšããªããã°
ãªããªããšããè€éãã䌎ã€ãã ããã«è©³ããã¯ãéåäœã®æœåºã«é溶å€ã䜿çš
ããããšã«é¢ãããã³ã«ã¯ïŒMinchakïŒã®ç±³åœ
ç¹èš±ç¬¬4069376å·æ现æžç¬¬ïŒæ¬ã«ã¯ãã¡ã¿ããŒã«ã
ãšã¿ããŒã«ãã€ãœãããããŒã«åã³ãããã«é¡ã
ããã®ã®ããšããäœçŽã¢ã«ã³ãŒã«ããéžã°ããé
溶å€ã䜿çšããŠæ²æŸ±ããããããšã«ãããïŒçš®å
ã¯è€æ°çš®ã®ã·ã¯ããªã¬ãã€ã³ã®éåäœãåé¢ãã
ããšãã§ããæšé瀺ãããŠããããã®å ¬ç¥æ¹æ³ã«
ãããŠã¯ãé«åªæ匷åæ··åæ©äžã§éåäœã»ã¡ã³ã
ãšé溶å€ãæ··åãããããã«ããã¹ã©ãªãŒã圢æ
ãããã次ã«ãã®ã¹ã©ãªãŒã¯ã¹ã©ãªãŒã¿ã³ã¯ã«èŒž
éãããããã§åšå²æž©åºŠã«ãããŠããã«æ¹æã
ãããããŠã¹ã©ãªãŒã¯ã¹ã©ãªãŒã¿ã³ã¯ããåãåº
ãããé å¿åé¢åã¯éãããããã§éåäœãå
é¢ããããããŠä¹Ÿç¥ãããä»æ¹æ¶²ã¯åå段éã«
ãã³ãã³èŒžéãããããã§é溶å€ããç°ç¶é極æ§
溶å€ãåé¢ããããããŠååãããã液ã¯æ¬è³ª
äžç°ç¶é極æ§æº¶å€ãšé溶å€çåæ°ŽçŽ ãããªãã ïŒçºæã®æŠèŠïŒ ãã®çºæã¯ãã¡ã¿ããŒã«ïŒã·ã¯ããããµã³å ±æ²ž
æ··åç©ã®æ²žç¹åã¯ãã®è¿åããã¡ã¿ããŒã«ã®æ²žç¹
ã®ç¯å²ã®æž©åºŠã«ãããŠã»ã¡ã³ãããããªã·ã¯ããª
ã¬ãã€ã³ãã¡ã¿ããŒã«ã«ããæ²æŸ±ããããã¡ã¿ã
ãŒã«ïŒã·ã¯ããããµã³å ±æ²žæ··åç©ãèžæ°ãšããŠå
ãåºãããããåçž®ããããå瞮液ãã»ãšãã©ã
ã¹ãŠã·ã¯ããããµã³ã§ããäžå±€ãšå€éã®ã¡ã¿ããŒ
ã«ãå«æããäžå±€ã«å±€åé¢ãã次ã«ã·ã¯ããªã¬ã
ã€ã³ãåé¢ãããããŠã¡ã¿ããŒã«ãååããæ¹æ³
ã«é¢ãããæ²æŸ±æž©åºŠã®ç¯å²ã¯å€§æ°å§äžã§çŽ55ã65
âã§ããã ïŒå ·äœçãªèª¬æïŒ ãã®çºæã¯ãã¡ã¿ããŒã«ïŒã·ã¯ããããµã³äºå
å ±æ²žæ··åç©ã®æ²žç¹åã¯ãã®è¿åããã¡ã¿ããŒã«ã®
沞ç¹ã®ç¯å²ã®æž©åºŠã«ãããããªã·ã¯ããªã¬ãã€ã³
åã³ã·ã¯ããããµã³æº¶å€ãå«ãã§æãéåäœã»ã¡
ã³ãã®æ²æŸ±ã«ãããŠãé溶å€ãšããŠã¡ã¿ããŒã«ã
䜿çšããããšã«é¢ããã倧æ°å§äžã«ãããŠäœ¿çšã
ãã枩床ç¯å²ã¯çŽ55ã65âã§ããã倧æ°å§ããäœ
ãåã¯é«ãå§åã«ãããŠæ²æŸ±ãè¡ãå Žåã«ã¯ãã
ãã«åŸã€ãŠæäœæž©åºŠãå€ããããšãã§ãããäžèš
ã®æž©åºŠç¯å²ã«ãããŠæäœããããšã«ããã»ã¡ã³ã
ã¹ã©ãªãŒãã54âã§æ²žéš°ããã¡ã¿ããŒã«ïŒã·ã¯ã
ãããµã³äºå å ±æ²žæ··åç©ãåãåºããããããå
çž®ããããããšã«ããã»ãšãã©ãã¹ãŠãã·ã¯ãã
ããµã³ã§ããäžå±€ãšã¡ã¿ããŒã«ãå€éã«å«ãäžå±€
ãšã«åé¢ããã溶å€ãå€éã«å«ãäžå±€ãåãåºã
ããšã«ãã溶å€ã®ååãä¿é²ãããåä»ã®å©ç¹ã
åŸãããã ãã®æ²æŸ±å·¥çšããäºåæ¿çž®å·¥çšãšå ±ã«ç¬¬ïŒå³ã«
瀺ãããŠãããäºåæ¿çž®å·¥çšã«ãããŠã¯çŽ15ïŒ ã®
åºåœ¢åãå«ãã»ã¡ã³ããçŽ20ã35ïŒ ã®åºåœ¢åãå«
ãã»ã¡ã³ãã«æ¿çž®ãããããã€ãšããããã«æ¿åºŠ
ãäžããããšãå¯èœã§ããããã®äºåæ¿çž®ã¯å Žå
ã«ããè¡ããäºåæ¿çž®ãè¡ãå Žåãã»ã¡ã³ãã¯çŽ
15ïŒ ããé«ãåºåœ¢åæ¿åºŠãæããããäºåæ¿çž®ã
è¡ããªãå Žåã«ã¯éåžžçŽ15ïŒ ã®åºåœ¢åãå«ãã»ã¡
ã³ããéåéšäœããçŽæ¥æ²æŸ±å·¥çšã«éãããã 第ïŒå³ã«ãããŠãã·ã¯ããããµã³æº¶å€äžã«æº¶è§£
ããã·ã¯ããªã¬ãã€ã³éåäœãå«ãã§æãéåäœ
ã»ã¡ã³ãã¯ç®¡è·¯ïŒïŒãéããŠæ··åæ©ïŒïŒã«å°å ¥ã
ãããéåäœã»ã¡ã³ãã¯çŽ15ïŒ ã®åºåœ¢åæ¿åºŠãæ
ããã»ã¡ã³ãã®åºåœ¢åã¯æ¬è³ªäž90éééšã®ã¡ãã«
ããã©ã·ã¯ãããã»ã³ãš10éééšã¡ãã«ãã«ãã«
ãã³ãããªãå ±éåäœã§ããããããŠ85ïŒ ã®æ¶²éš
åã¯æ¬è³ªäžã·ã¯ããããµã³ã§ãããæ··åæ©ïŒïŒã«
ã¯ããã«ç®¡è·¯ïŒïŒãéããŠã¡ã¿ããŒã«ãå ãã
ããããã§ã¡ã¿ããŒã«ãšã»ã¡ã³ããæ··åãããã
ãã®æ¹æ³ã«ãããŠã¯ãã¡ã¿ããŒã«ãã»ã¡ã³ããã
溶å€ã®å®è³ªçéšåãæœåºããããã«ãã溶解ãã
éåäœæåãå¢å ããã²ã«ç¶ç©ã圢æããããã
ãäºåæ¿çž®ã»ã¡ã³ããšç§°ãããäºåæ¿çž®ã»ã¡ã³ã
ã¯æ··åæ©ïŒïŒãã管路ïŒïŒãéããŠåé¢ã¿ã³ã¯ïŒ
ïŒã«ãã³ã茞éãããããã§æ¹æã䌎ããªãã§ã»
ã¡ã³ãã¹ã©ãªãŒãïŒå±€ã«åé¢ãããããªãã¡ãäž
å±€ã¯ã¡ã¿ããŒã«åã³ã·ã¯ããããµã³ãå«æããã
ãã¯ç®¡è·¯ïŒïŒãéã€ãŠååå·¥çšã«ãã³ã茞éã
ããä»æ¹äžå±€ã¯ã²ã«æ§ã®äºåæ¿çž®ç©ãããªãã äºåæ¿çž®æäœã«äœ¿çšããã¡ã¿ããŒã«ã®äœ¿çšé
ã¯ãäºåæ¿çž®ããããã«ã¯ååã§ããéåäœãæ²
柱ããããããã«ã¯äžååãªéãšãã¹ãã§ããã
ãã®éã¯ã»ã¡ã³ã100容ééšã«å¯ŸããŠçŽïŒã100容
ééšã§ããã äºåæ¿çž®æäœã¯åšå²æž©åºŠã«ãããŠè¡ãããšãã§
ããããäžè¬ã«ã¯ã¡ã¿ããŒã«âã·ã¯ããããµã³å ±
沞混åç©ã®æ°·ç¹ãã沞ç¹ã®ç¯å²ã§è¡ãã æ··åæ©ïŒïŒã«èŒžéãããã»ã¡ã³ããéåå·¥çšã
ãçŽæ¥åãå ¥ããå Žåã«ã¯ã»ã¡ã³ãã®æž©åºŠã¯çŽ40
ã50âã§ããããã®å Žåã«ã¯äºåæ¿çž®ãããã«é«
ã枩床ã«ãããŠè¡ãããšãã§ããããããããšã«
ããã»ã¡ã³ãã®ç²åºŠãäœäžããã»ã¡ã³ãã®äºåæ¿
çž®ãæ¹è¯ãããããŠäžçŽç©ã®æœåºãæ¹è¯ãããã
ãæäœã容æã«ãªãããã®å Žåã管路ïŒïŒãéã
ãŠæ··åæ©ïŒïŒã«å ¥ãã¡ã¿ããŒã«ã®æ¿åºŠã¯65âã§ã
ãããé«æž©ã«ãããäºåæ¿çž®ãå ç±ããããšãªã
è¡ãããšãã§ããã äºåæ¿çž®äžå±€ã¯ãã·ã¯ããããµã³åã³éåäœã
å«æããŠãããåé¢ã¿ã³ã¯ïŒïŒãã管路ïŒïŒãé
ããŠåãåºããããããŠé«åªæ匷åæ··åæ©ïŒïŒã«
茞éããããæ··åæ©ïŒïŒã¯ãšããã³ããã
ïŒEppenbachïŒåã®é«åªæ匷åæ··åæ©ã§ãããæ··
åæ©ïŒïŒã«ãããŠã¡ã¿ããŒã«ãšã»ã¡ã³ããšãæ··å
ãããå Žåç¬éçã«æ²æŸ±ããããããããŠéåäœ
ç²åã«ããã·ã¯ããããµã³åã³ã¡ã¿ããŒã«ãå«æ
ãã液çžäžåæ£äœã圢æããããæ²æŸ±ããéåäœ
ã®æ¶²çžäžæ··åç©ãéåäœã»ã©ãªãŒãšç§°ããã æ··åæ©ïŒïŒããã®éåäœã¹ã©ãªãŒã¯ç®¡è·¯ïŒïŒã
éããŠãå€éšèžæ°ãžã€ã±ããïŒïŒã®ããšãå ç±æ
段åã³æ¹ææ©ïŒïŒãè£ çããã¹ã©ãªãŒã¿ã³ã¯ïŒïŒ
ã«èŒžéããããååå·¥çšããã®ã¡ã¿ããŒã«ã管路
ïŒïŒãéããŠã¹ã©ãªãŒã¿ã³ã¯ã«å ããããšãã§ã
ããã¹ã©ãªãŒã¿ã³ã¯äžã§ããããã®è¿œå ã®æœåºã
è¡ãããšãã§ããã ãã§ã«èšèŒããããã«ãæ²æŸ±ã¯ã¡ã¿ããŒã«ïŒã·
ã¯ããããµã³å ±æ²žæ··åç©ã®æ²žç¹åã¯ãã®è¿åãã
ã¡ã¿ããŒã«ã®æ²žç¹ã®ç¯å²ã®æž©åºŠã«ãããŠè¡ãã倧
æ°å§ã«ãããŠã¯äžèšã®ããšãå®çŸ©ãã枩床ç¯å²ã¯
çŽ55ã65âã§ããããã®æž©åºŠç¯å²ã奜ãŸããã¯ã¡
ã¿ããŒã«ã®æ²žç¹åã¯ãã®è¿åã®æž©åºŠã«ãããŠã¹ã©
ãªãŒã¿ã³ã¯ïŒïŒãé転ããããšã«ããã¡ã¿ããŒ
ã«ïŒã·ã¯ããããµã³å ±æ²žæ··åç©ãéåäœã¹ã©ãªãŒ
ããèžçºãåãåºããããåŸã«æ€èšããçç±ã«ã
ãã¹ã©ãªãŒã¿ã³ã¯äžã®æž©åºŠã¯ã¡ã¿ããŒã«ã®æ²žç¹å
ã¯ãã®è¿åã«ä¿æãã¹ãã§ããã éåäœã»ã¡ã³ãã®æ²æŸ±ã«ãããŠã¯ãã¡ã¿ããŒã«
ã®éãã»ã¡ã³ãïŒå®¹ééšã«å¯ŸããŠïŒã15容ééšã
奜ãŸããã¯ïŒãïŒå®¹ééšã®ç¯å²ã§å€ããããšãã§
ããã éåäœã¹ã©ãªãŒãã¹ã©ãªãŒã¿ã³ã¯ïŒïŒã«å ¥ã€ã
å Žåããããæ¹æããå ç±ããåã¯ææã®æž©åºŠã«
ä¿æãããéåäœã¹ã©ãªãŒãã管路ïŒïŒãéããŠ
åºãŠããèžæ°ã¯ã¡ã¿ããŒã«ïŒã·ã¯ããããµã³ã®å ±
沞混åç©ã§ãã€ãŠãçŽ55âã®æ²žç¹ãæããæšæºå§
äžã§æž¬å®ããèžæ°çžã®çµæã¯37ééïŒ ã®ã¡ã¿ããŒ
ã«ãš63ééïŒ ã®ã·ã¯ããããµã³ããæããèžæ°ç¶
æ ã®å ±æ²žæ··åç©ã¯å å¡«å¡ïŒïŒãéããŠåçž®åšïŒïŒ
ã«èŒžéãããããã§åçž®ãããããããããŠåšå²
枩床ãŸã§å·åŽãããã次ã«å瞮液ã¯ç®¡è·¯ïŒïŒãé
ããŠãã«ã³ãã¿ã³ã¯ïŒïŒã«éãããããã§ããã
次ã®å®¹éãããªãïŒå±€ã«åé¢ããã äž å±€ïŒ43ïŒ äž å±€ïŒ57ïŒ åå±€ã«ãããã¡ã¿ããŒã«ãšã·ã¯ããããµã³ã®é
éçµæã¯æ¬¡ã®éãã§ããã äžå±€ ã¡ã¿ããŒã«ïŒïŒïŒ ã·ã¯ããããµã³ïŒ97ïŒ äžå±€ ã¡ã¿ããŒã«ïŒ61ïŒ ã·ã¯ããããµã³ïŒ39ïŒ äžå±€ã¯ã»ãšãã©ãã¹ãŠãã·ã¯ããããµã³ã§ãã
ã¡ã¿ããŒã«ã¯ãããã«ïŒïŒ ã§ããããäžå±€ã¯ã¡ã¿
ããŒã«ãå€éã«å«ã¿ãã·ã¯ããããµã³ã¯39ïŒ ã§ã
ãããšã«æ³šæããå¿ èŠãããã åèšã®ããšããå®è³ªäžãã¹ãŠã®ã·ã¯ããããµã³
ãèžçºããããããã«ã¡ã¿ããŒã«ã®æ²žç¹åã¯ãã®
è¿åã®æž©åºŠã§ã¹ã©ãªãŒã¿ã³ã¯ã®é転ãè¡ãã®ã奜
ãŸããã第ïŒå³ã«ç€ºããããªé£ç¶åŒæ²æŸ±æäœã«ã
ããŠã¯ãéå°ã®ã¡ã¿ããŒã«ãé¢è±ããããªããã
ã«å ±æ²žèžæ°ã®äžéšåãã¹ã©ãªãŒã¿ã³ã¯ã«æ®çãã
ããã®ã奜ãŸããããã®ããã«æäœããããã«
ã¯ãå ±æ²žæ··åç©ã®å瞮液ã®ã¡ã¿ããŒã«ãå€ãå«ã
äžå±€ã®äžéšã管路ïŒïŒã®éæµãšããŠäœ¿çšãããã®
éãéåžžã®èžçå·¥çšã®å Žåãšåæ§ã«åçž®åšã«å ¥ã
èžæ°ã®æž©åºŠã«ããå¶åŸ¡ããã®ãæã奜ãŸããã ã¹ã©ãªãŒã¿ã³ã¯ããã®å°éã®è¿œå ã®ã¡ã¿ããŒã«
ã®èžçºã¯ããŸãåé¡ã§ã¯ãªããããããªãããã
ã®ãããªæ¡ä»¶ãååšããã¡ã¿ããŒã«ãèžçºãã
ã°ãã¡ã¿ããŒã«ã¯åçž®ãããããŠãã«ã³ã¿ãŒã¿ã³
ã¯ïŒïŒã«èŒžéãããããã§äžå±€ãšäžå±€ã«åé ãã
ãã§ãããããã®å Žåã«ã¯äžå±€ã®éãæžå°ããã·
ã¯ããããµã³ãã¡ã¿ããŒã«ããåé¢ããååå·¥çš
ã«äžå¿ èŠãªè² æ ããããããšã«ãªããã åŸã€ãŠããã®çºæã®èŠä»¶ã¯åçž®åŸã«ã¡ã¿ããŒ
ã«ïŒã·ã¯ããããµã³å ±æ²žæ··åç©ã®å±€åé¢ãè¡ãã
ãšã«ããããã®ç¹åŸŽã¯ã(1)åçž®ããå ±æ²žæ··åç©ã®
äžå±€ã¯ã»ãšãã©ãã¹ãŠã·ã«ããããµã³ã§ãããã
ããŠ(2)ã¡ã¿ããŒã«ããã·ã¯ããããµã³ãããã«å
é¢ããããã®æ°Žæœåºãè¡ãããšãªãååå·¥çšãå®
æœããããšãã§ãããšããäºå®ã®ããã«ååå·¥çš
ãéåžžã«ä¿é²ããããã®æ现æžã«èšèŒããæ²æŸ±ã
æœåºåã³ååå·¥çšã¯åååŒã«è¡ãããšãã§ããå
第ïŒå³ã«ç€ºãããã«å®å šã«é£ç¶çã«è¡ãããšãã§
ããããã®çºæã®å ·äœåã«ãããŠã¯ããŸãéèŠã§
ã¯ãªãå®éççç±åã³æè¡ççç±ã«ããé£ç¶æ³ã
奜ãŸããã é£ç¶æäœã«ãããŠãã·ã¯ããããµã³ïŒã¡ã¿ããŒ
ã«å ±æ²žæ··åç©ã®äžéšãšããŠã¹ã©ãªãŒã¿ã³ã¯ããé€
å»ãããã¡ã¿ããŒã«èžæ°ãè£ãããã«ã¡ã¿ããŒã«
ãå·¥çšã«äŸçµŠããå Žåã第ïŒå³ã«ç€ºãããã«ã¹ã©
ãªãŒã¿ã³ã¯ã«çŽæ¥äŸçµŠãããããããŸãæçµæŽæµ
ãšããŠé å¿åé¢æ©ãéãããããŠé å¿åé¢æ©ãã
ã®æ¶²ãšå ±ã«ãæ²æŸ±ã«å¿ èŠã§ããã°å¥åã«æ··åæ©
ã«äŸçµŠããã®ã奜ãŸããã äºåæ¿çž®å·¥çšã¯å Žåã«ããè¡ããããããè¡ã
ã°ã管路ïŒïŒãéããŠæ²æŸ±å·¥çšã«å埪éãããã¡
ã¿ããŒã«äžã«æ®çããŠãããããããªãäžçŽç©ã
é€å»ããããšããç¹å¥ãªå©ç¹ãåŸããããäºåæ¿
çž®ãè¡ããªãå Žåããã«ä»£ãèªæã®æ¹æ³ã¯ææã«
ããæµãïŒïŒããã®ããã®ååå·¥çšã«éãããšã§
ããã äžå±€ã¯ãã«ã³ãã¿ã³ã¯ïŒïŒãã管路ïŒïŒãéã
ãŠã·ã¯ããããµã³ååå·¥çšã«ãã³ã茞éãããäž
å±€ã¯ç®¡è·¯ïŒïŒãéããŠã¡ã¿ããŒã«ååå·¥çšã«ãã³
ã茞éããããååå·¥çšã¯ãã®çºæã®äžéšãæ§æ
ããªããããã®æ现æžã«èšèŒããªãã éåäœåã³ã¡ã¿ããŒã«ã®æ··åç©ã¯ã¹ã©ãªãŒã¿ã³
ã¯ïŒïŒã®åºãã管路ïŒïŒãéããŠåãåºãããã
ããŠåé¢æ©ïŒïŒã«èŒžéããããåé¢æ©ã¯é å¿åé¢
æ©åã¯éåšã§ãã€ãŠããããåä»ã®é©åœãªåé¢
æ段ã§ãã€ãŠããããéåäœã¯åé¢æ©ïŒïŒã«ãã
ãŠã¡ã¿ããŒã«ããåé¢ããããããŠä¹Ÿç¥æ©ïŒïŒã«
茞éãããä»æ¹ã¡ã¿ããŒã«ã¯ç®¡è·¯ïŒïŒãéããŠã
ã³ã茞éããããã®äžéšã¯ç®¡è·¯ïŒïŒãéããŠæ··å
æ©ïŒïŒã«èŒžéããããããŠä»ã®éšåã¯ç®¡è·¯ïŒïŒã
éããŠæ··åæ©ïŒïŒã«èŒžéããããåé¢æ©ïŒïŒãã
åãåºãããçŽ70ééïŒ ã®ã¡ã¿ããŒã«ãå«æãã
湿最éåäœã¯ç®¡è·¯ïŒïŒãéããŠä¹Ÿç¥æ©ïŒïŒã«èŒžé
ãããããã§éåäœã¯ã¡ã¿ããŒã«å«éïŒïŒ æªæºãŸ
ã§ä¹Ÿç¥ãããã也ç¥ããéåäœã¯è²¯èµã®ããã«ç®¡
è·¯ïŒïŒãéããŠåãåºãããä»æ¹ä¹Ÿç¥æ©ããã®ã¡
ã¿ããŒã«ã¯ç®¡è·¯ïŒïŒãéããŠããã«ã³ãã¿ã³ã¯ïŒ
ïŒã®äžå±€æ¶²ãšç®¡è·¯ïŒïŒã«ãããŠäœµåããããããŠ
ã¡ã¿ããŒã«ååå·¥çšã«éãããããããã¯ããã«
代ããŠããã®ã¡ã¿ããŒã«ã¯çŽæ¥ã«æ²æŸ±æ®µéåã¯äº
åæ¿çž®æ®µéã«å埪éãããããã«ã³ã¿ãŒããã®äž
局液ã¯æ¬è³ªäž61ééïŒ ã®ã¡ã¿ããŒã«åã³39ééïŒ
ã®ã·ã¯ããããµã³ããæãã ã¡ã¿ããŒã«ïŒã·ã¯ããããµã³å ±æ²žæ··åç©æ¿çž®æ¶²
ã®ïŒå±€åé¢ã¯ç¹åŸŽçã§ãããä»ã®ã¢ã«ã³ãŒã«ã§ã¯
ãã®ããã«ããããšãã§ããªããåçž®ããå ±æ²žæ··
åç©ã®äžå±€ãã»ãšãã©ãã¹ãŠã·ã¯ããããµã³ã§ã
ãã®ã§ãååèœåããšãã«ã®ãŒçµè²»ãååé転çµ
è²»çãå°ãªããŠãããšããå€ãã®å©ç¹ãåŸãã
ããããªãã¡ãæ²æŸ±ã«å¿ èŠãªå€éã®ã¡ã¿ããŒã«
ããããã«åååŠçããããšãªããåé¢æ©ããçŽ
æ¥æ²æŸ±å·¥çšã«å埪éããããšãã§ãããé«æž©ã§æ
äœããããšã«ãã溶å€ã調ç¯å€åã³äžçŽç©ã«é¢ã
ãã¡ã¿ããŒã«ã®æœåºåã匷åããããäŸãã°ãã¡
ã¿ããŒã«ã¯ãããã»ã³âïŒãååé調ç¯å€ãšå ±ã«
å ±æ²žæ··åç©ã圢æããçŽ48âã§æ²žéš°ããããã®ã
ãšã¯ã調ç¯å€ãåã³ããããè¥å¹²ã®äžçŽç©ã¯ã·ã¯
ããããµã³ãšå ±ã«èžæ°ãšããŠé«æž©éåäœã¹ã©ãªãŒ
ããèžçºé€å»ãããããšãæå³ãããåŸã€ãŠé«æž©
ã§æäœããããšã«ããå¿ èŠãªã¡ã¿ããŒã«ã®å®¹ç©ã
å°ãªããŠãã¿ããã®å¹çãæ¹è¯ããããããã«ã
é«æž©ã«ãããŠã¯ãæåã®äŸçµŠåæåã¯äºåæ¿çž®ã»
ã¡ã³ããšããŠã®ã»ã¡ã³ãã®ç²åºŠãäœäžããããšã«
ããåæ±ã容æã«ãªããããŠæœåºå¹æãæ¹è¯ã
ããããã«éåäœç²åããã®æ®çäžçŽç©ã®æœåºã
匷åãããããšã«ãã補åã®å質ãæ¹è¯ãããã
åãã¡ã¿ããŒã«ã䜿çšããããšã«ãããä»ã®ã¢ã«
ã³ãŒã«ã䜿çšããå Žåã«æ¯ã¹ãŠã容æã«ä¹Ÿç¥ãã
ããŠåæ±ãããšãã§ããããå¯åºŠã®é«ããããŠç²
圢ã®å€§ããéåäœç²ãåŸãããããšãèŠåºãã
ããåãä»ã®ã¢ã«ã³ãŒã«ã䜿çšããå Žåãšç°ãª
ãããã®æ²æŸ±æ¹æ³ã¯æ°Žã䜿çšããªãããã®å Žåã«
ã¯ãåèšã®ããšããåæ§ã®ç³»ã«ãããŠé溶å€ãšã
ãŠä»ã®ã¢ã«ã³ãŒã«ã䜿çšããå Žåã®ããã«æº¶å€å
åã®ããã«æ°Žæœåºãå¿ èŠãšããªãã ãã«ãã«ãã³æåãå«æããç°ç¶ãªã¬ãã€ã³ã®
éåäœã¯ãå°ãªããšãïŒçš®é¡ã®ããã²ã³åã¢ã«ã
ã«ã¢ã«ãããŠã å©è§Šåªãšå°ãªããšãïŒçš®é¡ã®ã¿ã³
ã°ã¹ãã³åã¯ã¢ãªããã³ååç©è§Šåªãå«ãã§ãªã
è€å解觊åªã®ååšäžã§ã®ç°ç¶ãªã¬ãã€ã³ã®éç°é
åã«ãã€ãŠè£œé ããããšãã§ãããéå±ååç©è§Š
åªäžã®ã¿ã³ã°ã¹ãã³åã³ã¢ãªããã³ã¯ãããã²ã³
åã¿ã³ã°ã¹ãã³ãããã¯ããã²ã³åã¢ãªããã³äž
ã«ãããããšãéœã€ãªã³ãšããŠãåã¯ã¿ã³ã°ã¹ã
ã³é žååç©ãããã¯ã¢ãªããã³é žååç©äžã«ãã
ãããšãé°ã€ãªã³ãšããŠååšããããããšãã§ã
ããéåã«ããã€ãŠã¯ãåéäœç°ç¶ãªã¬ãã€ã³å
ã¯ãã®æ··åç©ããä»ã®å ±éåäœåéäœã䌎ã€ãŠå
ã¯äŒŽããªãã§ãã·ã¯ããããµã³é極æ§çåæ°ŽçŽ æº¶
å€ãšå ±ã«åå¿åšäžã§æ··åããã次ã«ãéå ±åœ¹éç°
ç¶ãªã¬ãã€ã³é¡ããéžã°ããååé調ç¯å€ãåå¿
åšã«å ãã次ã«ããã²ã³åã¢ã«ãã«ã¢ã«ãããŠã
å©è§Šåªãåã³ã¿ã³ã°ã¹ãã³åã¯ã¢ãªããã³ååç©
觊åªãå ãããéååå¿ã¯ãæ¹æããªããïŒã
200âã奜ãŸããã¯25ã100âã«ãããŠè¡ããã»ãš
ãã©ç±ãçæããªããåå¿å®çµæéã¯ïŒæéæªæº
ã®ãªãŒããŒã§ããã ã·ã¯ããªã¬ãã€ã³ã®éåã¯åååŒåã¯é£ç¶åŒã«
è¡ãããšãã§ãããäžèšã®æ²æŸ±æ¹æ³ã¯ãïŒçš®é¡ã®
åå¿æ¹åŒã®éã«ååšããåºæã®åååŠçå·®ç°ã«ã
ãçããã»ã¡ã³ãã®ååŠçµæã®çžéã«ãããã
ãããããã®æ¹åŒã«ãããŠãåæ§ã«è¡ãããšãã§
ãããé£ç¶åŒéåã«ãããŠã¯åååŒæäœã«æ¯ã¹ãŠ
ååé調ç¯å€åã³è§Šåªãå®è³ªäžå°ãªããŠãããã
ããŠååéã®ååžãçãéåäœãçæããããã®
ãããªçç±ãåã³ãã®çºæã®å ·äœäŸã«ãããŠã¯é
éã§ãªãä»ã®æè¡çãªå®éäžã®èæ ®ãããé£ç¶åŒ
éåãå·¥çšæäœã«æãäžè¬çã«æ¡çšããã奜ãŸã
ãæ¹æ³ã§ãããåå¿åšããçŽæ¥ååãããåå¿ç
æç©ã¯ã溶å€ã«åæ£ããéåäœãå«ãã§æãèè
æ§çš 床ãæããæ»ããã§ç²çš ãªã»ã¡ã³ãã§ããã
ã»ã¡ã³ãäžã®éåäœåã¯åºåœ¢ç©æ¿åºŠã¯çŽ15ïŒ ã§ã
ãããããŠéåäœã®çšè溶液ç²åºŠã¯éåžžçŽ0.1ã
ïŒã®ç¯å²ã«ãããçšè溶液ç²åºŠã¯ããã«ãšã³1d
äžéåäœ0.25ïœã®æº¶æ¶²ã®25âã«ãããç²åºŠæž¬å®
å€ã§ããã ãã®æ现æžã«èšèŒããæ¹æ³ã«åŸã€ãŠéåããã
ãããšãã§ããã·ã¯ããªã¬ãã€ã³ã®ãã«ãã«ãã³
ååéäœã¯ã次ã®åŒ () ã§è¡šãããã眮æãããŠããåã¯çœ®æãããŠããª
ããã«ãã«ãã³åºã®ååšã«ããç¹è²ãããããã
ãã®å®çŸ©ã«åŸãã°ãé©åœãªãã«ãã«ãã³ååéäœ
ã«ã¯çœ®æãããåã³çœ®æãããŠããªããã«ãã«ã
ã³é¡ããžã·ã¯ããã³ã¿ãžãšã³é¡ããžããããžã·ã¯
ããã³ã¿ãžãšã³é¡ãã·ã¯ããã³ã¿ãžãšã³ã®äžé
äœãåã³ããã©ã·ã¯ãããã»ã³é¡ãå«ãŸãããã
ã«ãã«ãã³åã®å¥œãŸããåéäœãšããŠã次ã®åŒ
ïŒïŒååïŒïŒã
ãåŒã
ïŒåŒäžãåã³R1ã¯ãããããç¬ç«ã«ãæ°ŽçŽ ã
ã¢ã«ãã«åºããããã¯ççŽ ååæ°ïŒã20åã®ã¢ãª
ãŒã«åºãåã¯ïŒ²ãšR1ãäžç·ã«ãªã€ãŠããããçµ
åããŠããïŒåã®ç°ççŽ ååãšå ±ã«æ§æãããç
çŽ ååæ°ïŒã12åã®é£œåãããã¯äžé£œåã®ç°ç¶åº
ãè¡šããïŒã§è¡šãããããããããå°ãªããšãïŒ
ã®ãã«ãã«ãã³åºãå«æããåéäœãæããããš
ãã§ããã奜ãŸããå ·äœäŸã«ãããŠã¯ãåã³
R1ã¯ãããããç¬ç«ã«æ°ŽçŽ åã³ççŽ ååæ°ïŒã
ïŒåã®ã¢ã«ãã«åºããéžã°ããããã®æ现æžã«ã
ããŠèšåããåéäœã®äŸã«ã¯ãžã·ã¯ããã³ã¿ãžãš
ã³ãã¡ãã«ããã©ã·ã¯ãããã»ã³ãïŒâãã«ãã«
ãã³ã䞊ã³ã«ãïŒâã¡ãã«âïŒãã«ãã«ãšã³ã
ïŒïŒïŒâãžã¡ãã«âïŒâãã«ãã«ãã³ãïŒâã€ãœ
ãããã«âïŒâãã«ãã«ãã³ãïŒâãšãã«âïŒâ
ãã«ãã«ãã³ãïŒâããã«âïŒâãã«ãã«ãã³ã
ïŒâããã·ã«âïŒâãã«ãã«ãã³ãïŒâãªã¯ãã«
âïŒâãã«ãã«ãã³ãåã³ïŒâããã·ã«âïŒâã
ã«ãã«ãã³ã®ããšãä»ã®ãã«ãã«ãã³åéäœãå«
ãŸããã ã·ã¯ããªã¬ãã€ã³ã®åæ£äœäžã«äœ¿çšãã觊åªãš
ããŠã¯ãå çŽ ããã²ã³ã䌎ãããã²ã³åã¢ã«ãã
ãŠã åã¯ããã²ã³åã¢ã«ãã«ã¢ã«ãããŠã å©è§Šåª
ãšã¿ã³ã°ã¹ãã³åã¯ã¢ãªããã³ååç©è§Šåªãšã®çµ
åããã奜ãŸãããéå±ååç©è§Šåªäžã®ã¿ã³ã°ã¹
ãã³åã³ã¢ãªããã³ã¯ãããã²ã³åã¿ã³ã°ã¹ãã³
åã¯ããã²ã³åã¢ãªããã³äžã«ååšãããããªéœ
ã€ãªã³ã§ãã€ãŠããããåã¿ã³ã°ã¹ãã³é žååç©
åã¯ã¢ãªããã³é žååç©äžã«ååšãããããªé°ã€
ãªã³ã§ãã€ãŠãããã æçšãªã¢ãªããã³ååç©åã³ã¿ã³ã°ã¹ãã³åå
ç©è§Šåªã«ã¯äºå¡©åã¢ãªããã³ãå å¡©åã¢ãªãã
ã³ãäºèåã¢ãªããã³ãå åŒåã¢ãªããã³ãäºãš
ãŠåã¢ãªããã³ãå å¡©åã¿ã³ã°ã¹ãã³ãå åŒåã¿
ã³ã°ã¹ãã³ãåã³ãããã«é¡ãããã®ã®ããšãã¢
ãªããã³åã³ã¿ã³ã°ã¹ãã³ã®ããã²ã³åç©ãå«ãŸ
ããã觊åªãšããŠããã²ã³åã¢ãªããã³ãç¹ã«äº
å¡©åã¢ãªããã³ã奜ãŸããã ããã²ã³åã¢ã«ãã«ã¢ã«ãããŠã åã³ããã²ã³
åã¢ã«ãããŠã å©è§Šåªã¯ã次ã®åŒãRAlX2ã
R2AlXãR3Al2X3ãR3AlãAlX3ã§ç€ºããããã
ã²ã³åç©åã³ãããã®æ··åç©ããéžã°ããããã
ã²ã³åã¢ã«ãã«ã¢ã«ãããŠã 觊åªã®åŒã«ãããŠã
ã¯ççŽ ååæ°ïŒã12åã奜ãŸããã¯çŽïŒãïŒå
ã®ã¢ã«ãã«åºã§ãããã¯å¡©çŽ ããšãŠçŽ ãèçŽ å
ã³åŒçŽ ã®äžããéžã°ããããã²ã³ã§ããããã®ã
ããªããã²ã³åã¢ã«ãã«ã¢ã«ãããŠã ã®ç¹å®ã®äŸ
ã«ã¯ããšãã«ã¢ã«ãããŠã ãžã¯ããªãããžãšãã«
ã¢ã«ãããŠã ã¢ãã¯ããªãããšãã«ã¢ã«ãããŠã
ã»ã¹ãã¯ããªãããžã¡ãã«ã¢ã«ãããŠã ã€ãªãž
ãããšãã«ã¢ã«ãããŠã ãžã€ãªãžããå çŽ ç¶ãšãŠ
çŽ ã䌎ãããªã¢ã«ãã«ã¢ã«ãããŠã ååç©ãå«ãŸ
ããã ã¢ã«ãããŠã ã¯ãå¡©åã¢ã«ãã«ã¢ã«ãããŠã å©
觊åªäžã§å¥œãŸããéå å€ã§ããããä»ã®ææ©éå±
ããã²ã³åç©éå å€ãè¯å¥œã«æ©èœãããé©åœãªæ
æ©éå±å©è§Šåªãæ§æããéå±ã«ã¯ãªããŠã ããã°
ãã·ãŠã ãç¡ŒçŽ ãéãäºéãé«ãçªçŽ åã³ã²ã«ã
ããŠã ãå«ãŸãããåãææ©éå±å©è§Šåªã®å šéšå
ã¯äžéšã«ä»£ããŠéå±æ°ŽçŽ åç©ã䜿çšããããšãã§
ããã ã¢ãªããã³ååç©ãããã¯ã¿ã³ã°ã¹ãã³ååç©
觊åªãåã¯ãããã®æ··åç©ã¯ãå šåéäœïŒã¢ã«åœ
ããã¢ãªããã³åã¯ã¿ã³ã°ã¹ãã³ãçŽ0.01ã50ã
ãªã¢ã«ã奜ãŸããã¯0.1ã10ããªã¢ã«ãšãªãã¬ã
ã«ã§äœ¿çšãããããã²ã³åã¢ã«ãã«ã¢ã«ãããŠã
ãšã¢ãªããã³åã³ïŒåã¯ã¿ã³ã°ã¹ãã³ååç©è§Šåª
ãšã®ã¢ã«æ¯ã¯èšççã§ã¯ãªããã¢ã«ãããŠã ãšã¢
ãªããã³åã¯ã¿ã³ã°ã¹ãã³ãšã®æ¯çãçŽ200ïŒïŒ
以äžãïŒïŒ10ã奜ãŸããã¯10ïŒïŒãïŒïŒïŒã®ç¯å²
ãšããããšãã§ããã ãã®çºæã®æ¹æ³ã«ãããŠãéååå¿æº¶å€ã䜿çš
ããããšãå¿ èŠæ¡ä»¶ã§ããã溶å€ã䜿çšããªãå Ž
åã«ã¯ãæ²æŸ±æäœãè¡ãåã«éåäœã溶å€ã«æº¶è§£
ããªããã°ãªããªãããã®çºæã«ãããŠäœ¿çšãã
éåäœã溶解ããé極æ§æº¶å€ã¯ã·ã¯ããããµã³ã§
ããã溶å€ã¯ä»èŸŒäœæ¥ã®ä»»æã®æç¹ã§å ããããš
ãå¯èœã§ããããäžéšåã奜ãŸããã¯å šæº¶å€ã®
0.1ã10ïŒ ã觊åªã溶解ããããã«äœ¿çšããæ®ã
ã觊åªæº¶æ¶²ã®åã«å ãããäžè¬ã«ãåéäœ100ïœ
åœãïŒïŒïŒãïŒã®æº¶å€ã䜿çšããã éå掻æ§åå€ã䜿çšããããšãã§ããããäžè¬
ã«ã¯å¿ èŠã§ãªãã掻æ§åã¯ã空æ°åã¯éé žåç©ã
ããã¯ãããããŒãªãã·ããç¹ã«éé žåãã³ãŸã€
ã«ã®ããšãææ©éé žåç©ã«ããè¡ãããšãã§ã
ãã掻æ§åå€ã¯ãå¡©åã¢ã«ãã«ã¢ã«ãããŠã å©è§Š
åªïŒã¢ã«åœããïŒã¢ã«ä»¥äžã奜ãŸããã¯ïŒã¢ã«ä»¥
äžã®ç¯å²ã§äœ¿çšããããšãã§ããã掻æ§åå€ã¯ä»
蟌æäœã®ä»»æã®æç¹ã§å ããããšãã§ããããã¿
ã³ã°ã¹ãã³åã¯ã¢ãªããã³ååç©è§Šåªã®æ·»å ã®çµ
æã«ãåã¯ãããšå ±ã«å ããã®ã奜ãŸããã ååé調ç¯å€ãšããŠã¯ãåäºéçµåççŽ ååã«
å°ãªããšãïŒåã®æ°ŽçŽ ãæãããããŠïŒã12åã
ããã«å¥œãŸããã¯ïŒãïŒåã®ççŽ ååãå«æãã
éå ±åœ¹éç°åŒãªã¬ãã€ã³ã®ïŒçš®ä»¥äžã䜿çšããã
ãšãã§ãããé©åœãªéç°åŒãªã¬ãã€ã³ã®äŸã«ã¯ïŒ
âããã³ãïŒâããã»ã³ãïŒâãã³ãã³ãïŒâã¡
ãã«âïŒâããã³ïŒâã¡ãã«âïŒâãã³ãã³ãå
ã³ãããã«é¡ãããã®ãå«ãŸããããã®çºæã®æ¹
æ³ã«ãããŠã¯ãæ¡çšããéç°åŒãªã¬ãã€ã³ããã
èªäœãšããŠãåã¯ã¹ã©ãªãŒã¿ã³ã¯äžã®ä»ã®ã·ã¹ã
ã æåãšã®å ±æ²žæ··åç©ãšããŠãã¡ã¿ããŒã«ã®æ²žç¹
åã¯ãã®è¿åã§æ²žéš°ããããšã奜ãŸããã éå ±åœ¹éç°åŒãªã¬ãã€ã³ã¯åéäœä»èŸŒéïŒã¢ã«
åœããçŽ0.0001ãïŒã¢ã«ã®ã¬ãã«ã§äœ¿çšããããš
ãã§ãããéå ±åœ¹éç°åŒãªã¬ãã€ã³ã¯ãä»èŸŒæäœ
ã®ä»»æã®æç¹ã§ãçŽæ¥ã«åã¯æº¶æ¶²ãšããŠå ããã
ãšãã§ããããåéäœãšäžç·ã«å ããã®ã奜ãŸã
ããåŸã«å ããå Žåã«ã¯ãéå ±åœ¹éç°åŒãªã¬ãã€
ã³ã¯åå¿éå§åã«å ããã®ã奜ãŸããã éååå¿ã«é¢ããåéäœã¯ä»èŸŒæäœã®ä»»æã®æ
ç¹ã§å ããããšãã§ãããããããªããäžè¬ã«ã
é£ç¶åŒéåã«ãããŠã¯ãåéäœã溶å€åã³éå ±åœ¹
éç°åŒãªã¬ãã€ã³ã¯æ··åç©ãšããŠãããã²ã³åã¢
ã«ãã«ã¢ã«ãããŠã å©è§Šåªãšäžç·ã«å ãããã¿ã³
ã°ã¹ãã³åã¯ã¢ãªããã³ååç©è§Šåªã¯å¥éçåæ°Ž
çŽ æº¶å€äžã«å ãããéååå¿ã®å®çµã¯ãä»èŸŒåæ
äžã®åéäœã®æ¶å€±ã«ãã€ãŠç€ºãããããã¯äŸãã°
ã¬ã¹ã¯ãããã°ã©ãã€ãŒã«ããç£èŠãããã æ²æŸ±ã®ããã®ã¡ã¿ããŒã«ãšã»ã¡ã³ããšã®æ¯çã¯
çŽïŒïŒïŒã15ïŒïŒã奜ãŸããã¯ïŒïŒïŒãïŒïŒïŒã®
ç¯å²ã§å€ããããšãã§ãããããŠäºåæ¿çž®ã»ã¡ã³
ãã®å Žåã«ã¯ããã«é«ãæ¯çãéåžžçŽ10ïŒïŒãšã
ããé«ã¬ãã«ã«ããã«åŸã€ãŠåŸã®å·¥çšæ®µéã«ãã
ãéåäœç²åã®åéãå°ãªããªãããäžèšç¯å²ã®
ããäœãåŽã«ãããŠå·¥çšçµæžäžéåžžã«æå©ã§ã
ããã¡ã¿ããŒã«ã®éã¯åã»ã¡ã³ãäžã®åºåœ¢ç©æ¿åºŠ
ã«äŸåããã»ã¡ã³ããæ¿çž®ããã«åŸã€ãŠããå€ã
ã®ã¡ã¿ããŒã«ãå¿ èŠã§ããããäžè¬ã«éåäœã¯é
åžžé·ããïŒãã€ã¯ãã¡ãŒããªããçãããã€ãã
å€æ°ã®ç¹ç¶ããæãæ¯çŸœç«ã€ãéãšããŠæ²æŸ±ãã
ããã¡ã¿ããŒã«ã䜿çšããå Žåãã®åŸåã¯ä»ã®æ¥µ
æ§é溶å€æ²æŸ±å€ã䜿çšããå Žåãããå°ãããª
ãã次ã«ãéåäœã¯éåã¯é å¿åé¢ã«ããåé¢
ããããããŠåœæ¥çã«ãããŠããç¥ãããŠããã
ãã«çš®ã ã®æ·»å å€ãšé åãããã ãã®çºæã®é åãããéåäœã¯ãå°åºåœ¢æã«ã
ãæ©æ¢°éšåã容åšãé»åæ§æéšåçã®è£œé ã«äœ¿çš
ããããšãã§ãããããã¯æŒåºæ圢ããŠç°åœ¢æŒåº
æãæ£æãåç補åã䞊ã³ã«ãã¬ã¹æ圢ã圢æŒå
ã³ä»ã®æ圢ææ³ã«ããåŸãããä»ã®æ©æ¢°ç補åã«
å€ããããšãã§ããã 次ã«ãäŸã«ãããç¹èš±ã®ææåã³æ¡ä»¶ãçšããŠ
ãã®çºæãããã«è©³çŽ°ã«èª¬æããã ãªãããã®çºæã®éåäœãšããŠã¯ç¹ã«ãã¡ãã«
ãã«ãã«ãã³ãã¡ãã«ããã©ã·ã¯ãããã»ã³ãå
ã³ãžã·ã¯ããã³ã¿ãžãšã³ã®åç¬éåäœããããã
ãªãå ±éåäœåã³äžå å ±éåäœãæåŸ ããããã
ãŠã¡ãã«ããã©ã·ã¯ãããã»ã³ã®åç¬éåäœãå
ã³ã¡ãã«ããã©ã·ã¯ãããã»ã³ãšã¡ãã«ãã«ãã«
ãã³ã®å ±éåäœã奜ãŸãããå ±éåäœã¯ïŒã75é
éïŒ ã奜ãŸããã¯10ã30ïŒ ã®éåã¡ãã«ãã«ãã«
ãã³ãšæ®äœéã®éåã¡ãã«ããã©ã·ã¯ãããã»ã³
ãå«æããã®ã奜ãŸãããä»æ¹äžå å ±éåäœã¯ïŒ
ã75ééïŒ ã奜ãŸããã¯ïŒã45ïŒ ã®éåã¡ãã«ã
ã«ãã«ãã³ã25ã98ééïŒ ã奜ãŸããã¯50ã98ïŒ
ã®ééã¡ãã«ããã©ã·ã¯ãããã»ã³ãåã³æ®äœé
ã®éåãžã·ã¯ããã³ã¿ãžãšã³ãå«æããã®ã奜ãŸ
ããããã«ãã«ãã³ååéäœãåã¯ãã®æ··åç©ã«
ã¯ãçŽ20ééïŒ ä»¥äžã®å°ãªããšãïŒçš®ã®ä»ã®å ±é
åæ§åéäœãå«æããããããšãã§ããã äŸ ïŒ ç¬¬ïŒå³ã«é¢ããïŒæéåœãã100éééšïŒ100é
ééšïŒæïŒã®éåäœã»ã¡ã³ããæµããšããŠæ··å
æ©ïŒïŒã«å°å ¥ããããéåäœã»ã¡ã³ãã¯çŽ15ïŒ ã®
åºåœ¢åãå«æãã枩床ãçŽ45âã§ãããéåäœã¯
ééæ¯80ïŒ20ã®ã¡ãã«ããã©ã·ã¯ããã»ã³
ïŒMTDïŒãšã¡ãã«ãã«ãã«ãã³ïŒMNBïŒãšãã
æãå ±éåäœã§ããã0.86ã®çšè溶液ç²åºŠãæã
ããããã«ãïŒæéåœããåé¢åšïŒïŒããã®å埪
éæµã§ãã300éééšã®ã¡ã¿ããŒã«ãæµããšã
ãŠæ··åæ©ïŒïŒã«å ãããããã¡ã¿ããŒã«ã®æž©åºŠã¯
çŽ65âã§ããã次ã«ã»ã¡ã³ãã¹ã©ãªãŒã¯åé¢ã¿ã³
ã¯ïŒïŒã«ãã³ã茞éãããããã§äžå±€ãšäžå±€ã®åœ¢
æã«ããäºåæ¿çž®ãè¡ãããäžå±€ã¯æµããšããŠ
é éšããåãåºããããããŠäžå±€ã¯æµããšããŠ
ã¿ã³ã¯ïŒïŒã®åºéšããåãåºããããæµãã¯æ¬
質äžïŒæéåœãã300éšã®ã¡ã¿ããŒã«ãš215éšã®ã·
ã¯ããããµã³ããæããæµãã¯æ¬è³ªäžïŒæéåœ
ã350éšã®ã·ã¯ããããµã³ãš100éšã®éåäœãããª
ã枩床çŽ65âã®äºåæ¿çž®ã»ã¡ã³ãã§ãããçŽ22ïŒ
åºåœ¢åãå«æãããæ··åæ©ïŒïŒã¯ããšããã³ãã
ãïŒEppenbachïŒåã®åŒ·åãã€ãã©ã€ã³ãããµ
ãŒã§ãããæ¬è³ªäž215éšïŒæã®ã·ã¯ããããµã³ãš
300éšïŒæã®ã¡ã¿ããŒã«ãå«ãåé¢ã¿ã³ã¯ïŒïŒã
ãã®æµãã¯ååå·¥çšã«ãã³ã茞éãããããã§
ïŒæåãåé¢ããããçŽ22ïŒ ã®åºåœ¢åãå«æãã
450éšïŒæã®äºåæ¿çž®æµïŒ€ã¯ãæµããšããŠã®
1500éšïŒæã®ã¡ã¿ããŒã«ãšå ±ã«æ··åæ©ïŒïŒã«èŒžé
ãããããã§ïŒã€ã®æµããæ··åãããååºå€åã¯
æ²æŸ±å€ãšããŠæ©èœããã¡ã¿ããŒã«é溶å€ãšæ¥è§Šã
ãéã«æ²æŸ±ãçãããéåäœç²åãã¡ã¿ããŒã«å
ã³ã·ã¯ããããµã³ã®æ··åç©ãããªãã¡éåäœã¹ã©
ãªãŒã¯æ··åæ©ïŒïŒããåãåºããããããŠç®¡è·¯ïŒ
ïŒãéããŠ1950éšïŒæã®éãšããŠã¹ã©ãªãŒã¿ã³ã¯
ïŒïŒã«èŒžéãããã605éšïŒæã®è¿œå ã®ã¡ã¿ããŒ
ã«ãæµããšããŠã¹ã©ãªãŒã¿ã³ã¯ã«å ããããã
ã¹ã©ãªãŒã¿ã³ã¯äžã®éåäœã¹ã©ãªãŒã¯ããã€ãã
æ¹æãåããªãããçŽ65âã«å ç±ãããåã¯è©²æž©
床ã«ä¿æããããã¹ã©ãªãŒã¿ã³ã¯ïŒïŒããã®é éš
èžæ°æµïŒ§ã¯ã¡ã¿ããŒã«ãšã·ã¯ããããµã³ãšã®å ±æ²ž
æ··åç©ã§ãã€ãŠ54âã§æ²žéš°ãããæµãã¯ã205
éšïŒæã®ã¡ã¿ããŒã«ã350éšïŒæã®ã·ã¯ããããµ
ã³ãåã³çè·¡éã®äžçŽç©ããæããããã»ã³âïŒ
ãåã¡ã¿ããŒã«ãšå ±æ²žæ··åç©ã圢æããŠçŽ48âã§
沞隰ããããããã®å ±æ²žæ··åç©ã¯ã¡ã¿ããŒã«ïŒã·
ã¯ããããµã³å ±æ²žæ··åç©ãšå ±ã«çåºãããæ¬è³ªäž
1900éšïŒæã®ã¡ã¿ããŒã«ãš100éšïŒæã®éåäœãš
ããæãæµãã¯ãåé¢æ©ïŒïŒã«èŒžéããããã
ã§éåäœãåé¢ããããããŠä¹Ÿç¥æ©ïŒïŒã«åãå ¥
ãããããã¡ã¿ããŒã«ã¯ããã®1500éšïŒæãæ²æŸ±
ã®ããæ··åæ©ïŒïŒã«ããããŠ300éšïŒæãäºåæ¿
çž®ã®ããã«ããããå埪éããããåé¢æ©ããã®
éåäœã¯çŽ100éšïŒæã®ã¡ã¿ããŒã«ãå«æããã
也ç¥ã®éã«æ¹¿æœ€éåäœããã®ã¡ã¿ããŒã«ã®ã»ãšã
ã©ãé€å»ããããããŠã¡ã¿ããŒã«å«éãïŒééïŒ
æªæºã®ä¹Ÿç¥éåäœã貯èµã®ããåãåºãããã é éšèžæ°æµïŒ§ãããªãã¡ã¡ã¿ããŒã«ïŒã·ã¯ãã
ããµã³å ±æ²žæ··åç©ã¯ãåçž®åšïŒïŒã§åçž®ãããã
ãããããŠå瞮液ã¯ãã«ã³ãã¿ã³ã¯ïŒïŒã«å°å ¥ã
ããããã§ãããã43容éïŒ ãš57容éïŒ ã®äžå±€ãš
äžå±€ã«åé¢ããããé éšããæµãïŒãšããŠåãåº
ãããäžå±€ã¯ãæ¬è³ªäžïŒéšïŒæã®ã¡ã¿ããŒã«ãš
206éšïŒæã®ã·ã¯ããããµã³ããæããããã¯å
åå·¥çšã«èŒžéãããä»æ¹ãã«ã³ãã¿ã³ã¯ïŒïŒã®åº
éšããåãåºãããæ¬è³ªäž198éšïŒæã®ã¡ã¿ããŒ
ã«ãšãš144éšïŒæã®ã·ã¯ããããµã³ããæãæµã
ã¯ä¹Ÿç¥æ©ããã®ã¡ã¿ããŒã«èžæ°ãšæ··åãããã
ããŠååå·¥çšã«èŒžéãããã çæç©ã¯äžèŠåãªæ¯çŸœç«ã€ã埮å°ç¹ç¶ç¶ã®éç¶
äœã§ãããéã®éã«ç¶¿ç¶ã«è©°ãŸãããããŠä¹Ÿç¥
åã³åæ±ãå°é£ã§ããã也ç¥çæç©ã¯çŽ0.08ïœïŒ
c.c.ãããªãã¡ïŒïœïŒft3ã®åµ©å¯åºŠãæããã ãã®äŸã®ããŒã¿ã第ïŒè¡šã«èŠçŽãããéã¯éé
éšïŒæã§è¡šããã
ã¢ã«ãã«åºããããã¯ççŽ ååæ°ïŒã20åã®ã¢ãª
ãŒã«åºãåã¯ïŒ²ãšR1ãäžç·ã«ãªã€ãŠããããçµ
åããŠããïŒåã®ç°ççŽ ååãšå ±ã«æ§æãããç
çŽ ååæ°ïŒã12åã®é£œåãããã¯äžé£œåã®ç°ç¶åº
ãè¡šããïŒã§è¡šãããããããããå°ãªããšãïŒ
ã®ãã«ãã«ãã³åºãå«æããåéäœãæããããš
ãã§ããã奜ãŸããå ·äœäŸã«ãããŠã¯ãåã³
R1ã¯ãããããç¬ç«ã«æ°ŽçŽ åã³ççŽ ååæ°ïŒã
ïŒåã®ã¢ã«ãã«åºããéžã°ããããã®æ现æžã«ã
ããŠèšåããåéäœã®äŸã«ã¯ãžã·ã¯ããã³ã¿ãžãš
ã³ãã¡ãã«ããã©ã·ã¯ãããã»ã³ãïŒâãã«ãã«
ãã³ã䞊ã³ã«ãïŒâã¡ãã«âïŒãã«ãã«ãšã³ã
ïŒïŒïŒâãžã¡ãã«âïŒâãã«ãã«ãã³ãïŒâã€ãœ
ãããã«âïŒâãã«ãã«ãã³ãïŒâãšãã«âïŒâ
ãã«ãã«ãã³ãïŒâããã«âïŒâãã«ãã«ãã³ã
ïŒâããã·ã«âïŒâãã«ãã«ãã³ãïŒâãªã¯ãã«
âïŒâãã«ãã«ãã³ãåã³ïŒâããã·ã«âïŒâã
ã«ãã«ãã³ã®ããšãä»ã®ãã«ãã«ãã³åéäœãå«
ãŸããã ã·ã¯ããªã¬ãã€ã³ã®åæ£äœäžã«äœ¿çšãã觊åªãš
ããŠã¯ãå çŽ ããã²ã³ã䌎ãããã²ã³åã¢ã«ãã
ãŠã åã¯ããã²ã³åã¢ã«ãã«ã¢ã«ãããŠã å©è§Šåª
ãšã¿ã³ã°ã¹ãã³åã¯ã¢ãªããã³ååç©è§Šåªãšã®çµ
åããã奜ãŸãããéå±ååç©è§Šåªäžã®ã¿ã³ã°ã¹
ãã³åã³ã¢ãªããã³ã¯ãããã²ã³åã¿ã³ã°ã¹ãã³
åã¯ããã²ã³åã¢ãªããã³äžã«ååšãããããªéœ
ã€ãªã³ã§ãã€ãŠããããåã¿ã³ã°ã¹ãã³é žååç©
åã¯ã¢ãªããã³é žååç©äžã«ååšãããããªé°ã€
ãªã³ã§ãã€ãŠãããã æçšãªã¢ãªããã³ååç©åã³ã¿ã³ã°ã¹ãã³åå
ç©è§Šåªã«ã¯äºå¡©åã¢ãªããã³ãå å¡©åã¢ãªãã
ã³ãäºèåã¢ãªããã³ãå åŒåã¢ãªããã³ãäºãš
ãŠåã¢ãªããã³ãå å¡©åã¿ã³ã°ã¹ãã³ãå åŒåã¿
ã³ã°ã¹ãã³ãåã³ãããã«é¡ãããã®ã®ããšãã¢
ãªããã³åã³ã¿ã³ã°ã¹ãã³ã®ããã²ã³åç©ãå«ãŸ
ããã觊åªãšããŠããã²ã³åã¢ãªããã³ãç¹ã«äº
å¡©åã¢ãªããã³ã奜ãŸããã ããã²ã³åã¢ã«ãã«ã¢ã«ãããŠã åã³ããã²ã³
åã¢ã«ãããŠã å©è§Šåªã¯ã次ã®åŒãRAlX2ã
R2AlXãR3Al2X3ãR3AlãAlX3ã§ç€ºããããã
ã²ã³åç©åã³ãããã®æ··åç©ããéžã°ããããã
ã²ã³åã¢ã«ãã«ã¢ã«ãããŠã 觊åªã®åŒã«ãããŠã
ã¯ççŽ ååæ°ïŒã12åã奜ãŸããã¯çŽïŒãïŒå
ã®ã¢ã«ãã«åºã§ãããã¯å¡©çŽ ããšãŠçŽ ãèçŽ å
ã³åŒçŽ ã®äžããéžã°ããããã²ã³ã§ããããã®ã
ããªããã²ã³åã¢ã«ãã«ã¢ã«ãããŠã ã®ç¹å®ã®äŸ
ã«ã¯ããšãã«ã¢ã«ãããŠã ãžã¯ããªãããžãšãã«
ã¢ã«ãããŠã ã¢ãã¯ããªãããšãã«ã¢ã«ãããŠã
ã»ã¹ãã¯ããªãããžã¡ãã«ã¢ã«ãããŠã ã€ãªãž
ãããšãã«ã¢ã«ãããŠã ãžã€ãªãžããå çŽ ç¶ãšãŠ
çŽ ã䌎ãããªã¢ã«ãã«ã¢ã«ãããŠã ååç©ãå«ãŸ
ããã ã¢ã«ãããŠã ã¯ãå¡©åã¢ã«ãã«ã¢ã«ãããŠã å©
觊åªäžã§å¥œãŸããéå å€ã§ããããä»ã®ææ©éå±
ããã²ã³åç©éå å€ãè¯å¥œã«æ©èœãããé©åœãªæ
æ©éå±å©è§Šåªãæ§æããéå±ã«ã¯ãªããŠã ããã°
ãã·ãŠã ãç¡ŒçŽ ãéãäºéãé«ãçªçŽ åã³ã²ã«ã
ããŠã ãå«ãŸãããåãææ©éå±å©è§Šåªã®å šéšå
ã¯äžéšã«ä»£ããŠéå±æ°ŽçŽ åç©ã䜿çšããããšãã§
ããã ã¢ãªããã³ååç©ãããã¯ã¿ã³ã°ã¹ãã³ååç©
觊åªãåã¯ãããã®æ··åç©ã¯ãå šåéäœïŒã¢ã«åœ
ããã¢ãªããã³åã¯ã¿ã³ã°ã¹ãã³ãçŽ0.01ã50ã
ãªã¢ã«ã奜ãŸããã¯0.1ã10ããªã¢ã«ãšãªãã¬ã
ã«ã§äœ¿çšãããããã²ã³åã¢ã«ãã«ã¢ã«ãããŠã
ãšã¢ãªããã³åã³ïŒåã¯ã¿ã³ã°ã¹ãã³ååç©è§Šåª
ãšã®ã¢ã«æ¯ã¯èšççã§ã¯ãªããã¢ã«ãããŠã ãšã¢
ãªããã³åã¯ã¿ã³ã°ã¹ãã³ãšã®æ¯çãçŽ200ïŒïŒ
以äžãïŒïŒ10ã奜ãŸããã¯10ïŒïŒãïŒïŒïŒã®ç¯å²
ãšããããšãã§ããã ãã®çºæã®æ¹æ³ã«ãããŠãéååå¿æº¶å€ã䜿çš
ããããšãå¿ èŠæ¡ä»¶ã§ããã溶å€ã䜿çšããªãå Ž
åã«ã¯ãæ²æŸ±æäœãè¡ãåã«éåäœã溶å€ã«æº¶è§£
ããªããã°ãªããªãããã®çºæã«ãããŠäœ¿çšãã
éåäœã溶解ããé極æ§æº¶å€ã¯ã·ã¯ããããµã³ã§
ããã溶å€ã¯ä»èŸŒäœæ¥ã®ä»»æã®æç¹ã§å ããããš
ãå¯èœã§ããããäžéšåã奜ãŸããã¯å šæº¶å€ã®
0.1ã10ïŒ ã觊åªã溶解ããããã«äœ¿çšããæ®ã
ã觊åªæº¶æ¶²ã®åã«å ãããäžè¬ã«ãåéäœ100ïœ
åœãïŒïŒïŒãïŒã®æº¶å€ã䜿çšããã éå掻æ§åå€ã䜿çšããããšãã§ããããäžè¬
ã«ã¯å¿ èŠã§ãªãã掻æ§åã¯ã空æ°åã¯éé žåç©ã
ããã¯ãããããŒãªãã·ããç¹ã«éé žåãã³ãŸã€
ã«ã®ããšãææ©éé žåç©ã«ããè¡ãããšãã§ã
ãã掻æ§åå€ã¯ãå¡©åã¢ã«ãã«ã¢ã«ãããŠã å©è§Š
åªïŒã¢ã«åœããïŒã¢ã«ä»¥äžã奜ãŸããã¯ïŒã¢ã«ä»¥
äžã®ç¯å²ã§äœ¿çšããããšãã§ããã掻æ§åå€ã¯ä»
蟌æäœã®ä»»æã®æç¹ã§å ããããšãã§ããããã¿
ã³ã°ã¹ãã³åã¯ã¢ãªããã³ååç©è§Šåªã®æ·»å ã®çµ
æã«ãåã¯ãããšå ±ã«å ããã®ã奜ãŸããã ååé調ç¯å€ãšããŠã¯ãåäºéçµåççŽ ååã«
å°ãªããšãïŒåã®æ°ŽçŽ ãæãããããŠïŒã12åã
ããã«å¥œãŸããã¯ïŒãïŒåã®ççŽ ååãå«æãã
éå ±åœ¹éç°åŒãªã¬ãã€ã³ã®ïŒçš®ä»¥äžã䜿çšããã
ãšãã§ãããé©åœãªéç°åŒãªã¬ãã€ã³ã®äŸã«ã¯ïŒ
âããã³ãïŒâããã»ã³ãïŒâãã³ãã³ãïŒâã¡
ãã«âïŒâããã³ïŒâã¡ãã«âïŒâãã³ãã³ãå
ã³ãããã«é¡ãããã®ãå«ãŸããããã®çºæã®æ¹
æ³ã«ãããŠã¯ãæ¡çšããéç°åŒãªã¬ãã€ã³ããã
èªäœãšããŠãåã¯ã¹ã©ãªãŒã¿ã³ã¯äžã®ä»ã®ã·ã¹ã
ã æåãšã®å ±æ²žæ··åç©ãšããŠãã¡ã¿ããŒã«ã®æ²žç¹
åã¯ãã®è¿åã§æ²žéš°ããããšã奜ãŸããã éå ±åœ¹éç°åŒãªã¬ãã€ã³ã¯åéäœä»èŸŒéïŒã¢ã«
åœããçŽ0.0001ãïŒã¢ã«ã®ã¬ãã«ã§äœ¿çšããããš
ãã§ãããéå ±åœ¹éç°åŒãªã¬ãã€ã³ã¯ãä»èŸŒæäœ
ã®ä»»æã®æç¹ã§ãçŽæ¥ã«åã¯æº¶æ¶²ãšããŠå ããã
ãšãã§ããããåéäœãšäžç·ã«å ããã®ã奜ãŸã
ããåŸã«å ããå Žåã«ã¯ãéå ±åœ¹éç°åŒãªã¬ãã€
ã³ã¯åå¿éå§åã«å ããã®ã奜ãŸããã éååå¿ã«é¢ããåéäœã¯ä»èŸŒæäœã®ä»»æã®æ
ç¹ã§å ããããšãã§ãããããããªããäžè¬ã«ã
é£ç¶åŒéåã«ãããŠã¯ãåéäœã溶å€åã³éå ±åœ¹
éç°åŒãªã¬ãã€ã³ã¯æ··åç©ãšããŠãããã²ã³åã¢
ã«ãã«ã¢ã«ãããŠã å©è§Šåªãšäžç·ã«å ãããã¿ã³
ã°ã¹ãã³åã¯ã¢ãªããã³ååç©è§Šåªã¯å¥éçåæ°Ž
çŽ æº¶å€äžã«å ãããéååå¿ã®å®çµã¯ãä»èŸŒåæ
äžã®åéäœã®æ¶å€±ã«ãã€ãŠç€ºãããããã¯äŸãã°
ã¬ã¹ã¯ãããã°ã©ãã€ãŒã«ããç£èŠãããã æ²æŸ±ã®ããã®ã¡ã¿ããŒã«ãšã»ã¡ã³ããšã®æ¯çã¯
çŽïŒïŒïŒã15ïŒïŒã奜ãŸããã¯ïŒïŒïŒãïŒïŒïŒã®
ç¯å²ã§å€ããããšãã§ãããããŠäºåæ¿çž®ã»ã¡ã³
ãã®å Žåã«ã¯ããã«é«ãæ¯çãéåžžçŽ10ïŒïŒãšã
ããé«ã¬ãã«ã«ããã«åŸã€ãŠåŸã®å·¥çšæ®µéã«ãã
ãéåäœç²åã®åéãå°ãªããªãããäžèšç¯å²ã®
ããäœãåŽã«ãããŠå·¥çšçµæžäžéåžžã«æå©ã§ã
ããã¡ã¿ããŒã«ã®éã¯åã»ã¡ã³ãäžã®åºåœ¢ç©æ¿åºŠ
ã«äŸåããã»ã¡ã³ããæ¿çž®ããã«åŸã€ãŠããå€ã
ã®ã¡ã¿ããŒã«ãå¿ èŠã§ããããäžè¬ã«éåäœã¯é
åžžé·ããïŒãã€ã¯ãã¡ãŒããªããçãããã€ãã
å€æ°ã®ç¹ç¶ããæãæ¯çŸœç«ã€ãéãšããŠæ²æŸ±ãã
ããã¡ã¿ããŒã«ã䜿çšããå Žåãã®åŸåã¯ä»ã®æ¥µ
æ§é溶å€æ²æŸ±å€ã䜿çšããå Žåãããå°ãããª
ãã次ã«ãéåäœã¯éåã¯é å¿åé¢ã«ããåé¢
ããããããŠåœæ¥çã«ãããŠããç¥ãããŠããã
ãã«çš®ã ã®æ·»å å€ãšé åãããã ãã®çºæã®é åãããéåäœã¯ãå°åºåœ¢æã«ã
ãæ©æ¢°éšåã容åšãé»åæ§æéšåçã®è£œé ã«äœ¿çš
ããããšãã§ãããããã¯æŒåºæ圢ããŠç°åœ¢æŒåº
æãæ£æãåç補åã䞊ã³ã«ãã¬ã¹æ圢ã圢æŒå
ã³ä»ã®æ圢ææ³ã«ããåŸãããä»ã®æ©æ¢°ç補åã«
å€ããããšãã§ããã 次ã«ãäŸã«ãããç¹èš±ã®ææåã³æ¡ä»¶ãçšããŠ
ãã®çºæãããã«è©³çŽ°ã«èª¬æããã ãªãããã®çºæã®éåäœãšããŠã¯ç¹ã«ãã¡ãã«
ãã«ãã«ãã³ãã¡ãã«ããã©ã·ã¯ãããã»ã³ãå
ã³ãžã·ã¯ããã³ã¿ãžãšã³ã®åç¬éåäœããããã
ãªãå ±éåäœåã³äžå å ±éåäœãæåŸ ããããã
ãŠã¡ãã«ããã©ã·ã¯ãããã»ã³ã®åç¬éåäœãå
ã³ã¡ãã«ããã©ã·ã¯ãããã»ã³ãšã¡ãã«ãã«ãã«
ãã³ã®å ±éåäœã奜ãŸãããå ±éåäœã¯ïŒã75é
éïŒ ã奜ãŸããã¯10ã30ïŒ ã®éåã¡ãã«ãã«ãã«
ãã³ãšæ®äœéã®éåã¡ãã«ããã©ã·ã¯ãããã»ã³
ãå«æããã®ã奜ãŸãããä»æ¹äžå å ±éåäœã¯ïŒ
ã75ééïŒ ã奜ãŸããã¯ïŒã45ïŒ ã®éåã¡ãã«ã
ã«ãã«ãã³ã25ã98ééïŒ ã奜ãŸããã¯50ã98ïŒ
ã®ééã¡ãã«ããã©ã·ã¯ãããã»ã³ãåã³æ®äœé
ã®éåãžã·ã¯ããã³ã¿ãžãšã³ãå«æããã®ã奜ãŸ
ããããã«ãã«ãã³ååéäœãåã¯ãã®æ··åç©ã«
ã¯ãçŽ20ééïŒ ä»¥äžã®å°ãªããšãïŒçš®ã®ä»ã®å ±é
åæ§åéäœãå«æããããããšãã§ããã äŸ ïŒ ç¬¬ïŒå³ã«é¢ããïŒæéåœãã100éééšïŒ100é
ééšïŒæïŒã®éåäœã»ã¡ã³ããæµããšããŠæ··å
æ©ïŒïŒã«å°å ¥ããããéåäœã»ã¡ã³ãã¯çŽ15ïŒ ã®
åºåœ¢åãå«æãã枩床ãçŽ45âã§ãããéåäœã¯
ééæ¯80ïŒ20ã®ã¡ãã«ããã©ã·ã¯ããã»ã³
ïŒMTDïŒãšã¡ãã«ãã«ãã«ãã³ïŒMNBïŒãšãã
æãå ±éåäœã§ããã0.86ã®çšè溶液ç²åºŠãæã
ããããã«ãïŒæéåœããåé¢åšïŒïŒããã®å埪
éæµã§ãã300éééšã®ã¡ã¿ããŒã«ãæµããšã
ãŠæ··åæ©ïŒïŒã«å ãããããã¡ã¿ããŒã«ã®æž©åºŠã¯
çŽ65âã§ããã次ã«ã»ã¡ã³ãã¹ã©ãªãŒã¯åé¢ã¿ã³
ã¯ïŒïŒã«ãã³ã茞éãããããã§äžå±€ãšäžå±€ã®åœ¢
æã«ããäºåæ¿çž®ãè¡ãããäžå±€ã¯æµããšããŠ
é éšããåãåºããããããŠäžå±€ã¯æµããšããŠ
ã¿ã³ã¯ïŒïŒã®åºéšããåãåºããããæµãã¯æ¬
質äžïŒæéåœãã300éšã®ã¡ã¿ããŒã«ãš215éšã®ã·
ã¯ããããµã³ããæããæµãã¯æ¬è³ªäžïŒæéåœ
ã350éšã®ã·ã¯ããããµã³ãš100éšã®éåäœãããª
ã枩床çŽ65âã®äºåæ¿çž®ã»ã¡ã³ãã§ãããçŽ22ïŒ
åºåœ¢åãå«æãããæ··åæ©ïŒïŒã¯ããšããã³ãã
ãïŒEppenbachïŒåã®åŒ·åãã€ãã©ã€ã³ãããµ
ãŒã§ãããæ¬è³ªäž215éšïŒæã®ã·ã¯ããããµã³ãš
300éšïŒæã®ã¡ã¿ããŒã«ãå«ãåé¢ã¿ã³ã¯ïŒïŒã
ãã®æµãã¯ååå·¥çšã«ãã³ã茞éãããããã§
ïŒæåãåé¢ããããçŽ22ïŒ ã®åºåœ¢åãå«æãã
450éšïŒæã®äºåæ¿çž®æµïŒ€ã¯ãæµããšããŠã®
1500éšïŒæã®ã¡ã¿ããŒã«ãšå ±ã«æ··åæ©ïŒïŒã«èŒžé
ãããããã§ïŒã€ã®æµããæ··åãããååºå€åã¯
æ²æŸ±å€ãšããŠæ©èœããã¡ã¿ããŒã«é溶å€ãšæ¥è§Šã
ãéã«æ²æŸ±ãçãããéåäœç²åãã¡ã¿ããŒã«å
ã³ã·ã¯ããããµã³ã®æ··åç©ãããªãã¡éåäœã¹ã©
ãªãŒã¯æ··åæ©ïŒïŒããåãåºããããããŠç®¡è·¯ïŒ
ïŒãéããŠ1950éšïŒæã®éãšããŠã¹ã©ãªãŒã¿ã³ã¯
ïŒïŒã«èŒžéãããã605éšïŒæã®è¿œå ã®ã¡ã¿ããŒ
ã«ãæµããšããŠã¹ã©ãªãŒã¿ã³ã¯ã«å ããããã
ã¹ã©ãªãŒã¿ã³ã¯äžã®éåäœã¹ã©ãªãŒã¯ããã€ãã
æ¹æãåããªãããçŽ65âã«å ç±ãããåã¯è©²æž©
床ã«ä¿æããããã¹ã©ãªãŒã¿ã³ã¯ïŒïŒããã®é éš
èžæ°æµïŒ§ã¯ã¡ã¿ããŒã«ãšã·ã¯ããããµã³ãšã®å ±æ²ž
æ··åç©ã§ãã€ãŠ54âã§æ²žéš°ãããæµãã¯ã205
éšïŒæã®ã¡ã¿ããŒã«ã350éšïŒæã®ã·ã¯ããããµ
ã³ãåã³çè·¡éã®äžçŽç©ããæããããã»ã³âïŒ
ãåã¡ã¿ããŒã«ãšå ±æ²žæ··åç©ã圢æããŠçŽ48âã§
沞隰ããããããã®å ±æ²žæ··åç©ã¯ã¡ã¿ããŒã«ïŒã·
ã¯ããããµã³å ±æ²žæ··åç©ãšå ±ã«çåºãããæ¬è³ªäž
1900éšïŒæã®ã¡ã¿ããŒã«ãš100éšïŒæã®éåäœãš
ããæãæµãã¯ãåé¢æ©ïŒïŒã«èŒžéããããã
ã§éåäœãåé¢ããããããŠä¹Ÿç¥æ©ïŒïŒã«åãå ¥
ãããããã¡ã¿ããŒã«ã¯ããã®1500éšïŒæãæ²æŸ±
ã®ããæ··åæ©ïŒïŒã«ããããŠ300éšïŒæãäºåæ¿
çž®ã®ããã«ããããå埪éããããåé¢æ©ããã®
éåäœã¯çŽ100éšïŒæã®ã¡ã¿ããŒã«ãå«æããã
也ç¥ã®éã«æ¹¿æœ€éåäœããã®ã¡ã¿ããŒã«ã®ã»ãšã
ã©ãé€å»ããããããŠã¡ã¿ããŒã«å«éãïŒééïŒ
æªæºã®ä¹Ÿç¥éåäœã貯èµã®ããåãåºãããã é éšèžæ°æµïŒ§ãããªãã¡ã¡ã¿ããŒã«ïŒã·ã¯ãã
ããµã³å ±æ²žæ··åç©ã¯ãåçž®åšïŒïŒã§åçž®ãããã
ãããããŠå瞮液ã¯ãã«ã³ãã¿ã³ã¯ïŒïŒã«å°å ¥ã
ããããã§ãããã43容éïŒ ãš57容éïŒ ã®äžå±€ãš
äžå±€ã«åé¢ããããé éšããæµãïŒãšããŠåãåº
ãããäžå±€ã¯ãæ¬è³ªäžïŒéšïŒæã®ã¡ã¿ããŒã«ãš
206éšïŒæã®ã·ã¯ããããµã³ããæããããã¯å
åå·¥çšã«èŒžéãããä»æ¹ãã«ã³ãã¿ã³ã¯ïŒïŒã®åº
éšããåãåºãããæ¬è³ªäž198éšïŒæã®ã¡ã¿ããŒ
ã«ãšãš144éšïŒæã®ã·ã¯ããããµã³ããæãæµã
ã¯ä¹Ÿç¥æ©ããã®ã¡ã¿ããŒã«èžæ°ãšæ··åãããã
ããŠååå·¥çšã«èŒžéãããã çæç©ã¯äžèŠåãªæ¯çŸœç«ã€ã埮å°ç¹ç¶ç¶ã®éç¶
äœã§ãããéã®éã«ç¶¿ç¶ã«è©°ãŸãããããŠä¹Ÿç¥
åã³åæ±ãå°é£ã§ããã也ç¥çæç©ã¯çŽ0.08ïœïŒ
c.c.ãããªãã¡ïŒïœïŒft3ã®åµ©å¯åºŠãæããã ãã®äŸã®ããŒã¿ã第ïŒè¡šã«èŠçŽãããéã¯éé
éšïŒæã§è¡šããã
ãè¡šã
äŸ ïŒ
ãã®äŸã¯ãMTDïŒMNBïŒ80ïŒ20ïŒå
±éåäœã
ã·ã¯ããããµã³ã«æº¶è§£ããŠãªããçŽ15ïŒ ã®åºåœ¢å
æ¿åºŠãš0.86ã®çšè溶液ç²åºŠãæããéåäœã»ã¡ã³
ããæ²æŸ±ããããããã®ã¡ã¿ããŒã«ã®äœ¿çšã«ã€ã
ãŠç€ºãã å®éã¯ãéåäœã»ã¡ã³ãåã³ã¡ã¿ããŒã«ãïŒã€
ã³ãã®ãšããã³ããã匷åãã€ãã©ã€ã³ãããµãŒ
ã«é£ç¶äŸçµŠãããããŠãããµãŒããã®éåäœã¹ã©
ãªãŒãã¹ã©ãªãŒã¿ã³ã¯ã«äŸçµŠããããšã«ããè¡ã€
ããéåäœã¹ã©ãªãŒã¯ãæ¬è³ªäžãã·ã¯ããããµã³
åã³ã¡ã¿ããŒã«ãå«ã液åªäœäžã«åæ£ããæ²æŸ±é
åäœããæãã æåã«ãçŽ30Kgã®ã¡ã¿ããŒã«ãæ¹æããã¹ã©ãª
ãŒã¿ã³ã¯ã«å ¥ãããããŠ43âã«å ç±ãããã»ã¡ã³
ãåã³ã¡ã¿ããŒã«ã®ãããµãŒãžã®äŸçµŠé床ã¯ãã
ããã0.41KgïŒååã³2.7KgïŒåã«èšå®ãããã¡
ã¿ããŒã«ã¯ãããµãŒã«å ¥ããåã«40âã«å ç±ã
ããã¹ã©ãªãŒã®åœ¢ã§æ²æŸ±ããéåäœã¯é«æž©ã®ã¹ã©
ãªãŒã¿ã³ã¯ã«ç§»ããã ãã®å·¥çšããçŽ10Kgã®ã»ã¡ã³ãããããµãŒã«å
ãããããŸã§ç¶ããã次ã«ã¹ã©ãªãŒã¿ã³ã¯ãçŽ63
âã«å ç±ãããããŠé éšæž©åºŠ60âã«ãããŠã·ã¯ã
ãããµã³ïŒã¡ã¿ããŒã«å ±æ²žæ··åç©ãåã³è¥å¹²ã®ã¡
ã¿ããŒã«ãèžçºãããããå·åŽããããšã«ããç
åºæ¶²ã¯ïŒå±€ã«åé¢ãããèžçå·¥çšãé éšæž©åºŠã62
âã«äžæãããŸã§ç¶ããããã®æž©åºŠã¯ãã»ãšãã©
ã®ã·ã¯ããããµã³ãã¹ã©ãªãŒã¿ã³ã¯ããèžçºãã
ããšã瀺ããã¹ã©ãªãŒã¿ã³ã¯ãåšå²æž©åºŠãŸã§å·åŽ
ãããããŠåååŒéåšãçšããŠã¹ã©ãªãŒãé
ããã也ç¥ããéåäœã¯ç¹ç¶ç¶ã§ããããããŠçŽ
0.06ïœïŒc.c.ã®åµ©å¯åºŠãæããŠããã
ã·ã¯ããããµã³ã«æº¶è§£ããŠãªããçŽ15ïŒ ã®åºåœ¢å
æ¿åºŠãš0.86ã®çšè溶液ç²åºŠãæããéåäœã»ã¡ã³
ããæ²æŸ±ããããããã®ã¡ã¿ããŒã«ã®äœ¿çšã«ã€ã
ãŠç€ºãã å®éã¯ãéåäœã»ã¡ã³ãåã³ã¡ã¿ããŒã«ãïŒã€
ã³ãã®ãšããã³ããã匷åãã€ãã©ã€ã³ãããµãŒ
ã«é£ç¶äŸçµŠãããããŠãããµãŒããã®éåäœã¹ã©
ãªãŒãã¹ã©ãªãŒã¿ã³ã¯ã«äŸçµŠããããšã«ããè¡ã€
ããéåäœã¹ã©ãªãŒã¯ãæ¬è³ªäžãã·ã¯ããããµã³
åã³ã¡ã¿ããŒã«ãå«ã液åªäœäžã«åæ£ããæ²æŸ±é
åäœããæãã æåã«ãçŽ30Kgã®ã¡ã¿ããŒã«ãæ¹æããã¹ã©ãª
ãŒã¿ã³ã¯ã«å ¥ãããããŠ43âã«å ç±ãããã»ã¡ã³
ãåã³ã¡ã¿ããŒã«ã®ãããµãŒãžã®äŸçµŠé床ã¯ãã
ããã0.41KgïŒååã³2.7KgïŒåã«èšå®ãããã¡
ã¿ããŒã«ã¯ãããµãŒã«å ¥ããåã«40âã«å ç±ã
ããã¹ã©ãªãŒã®åœ¢ã§æ²æŸ±ããéåäœã¯é«æž©ã®ã¹ã©
ãªãŒã¿ã³ã¯ã«ç§»ããã ãã®å·¥çšããçŽ10Kgã®ã»ã¡ã³ãããããµãŒã«å
ãããããŸã§ç¶ããã次ã«ã¹ã©ãªãŒã¿ã³ã¯ãçŽ63
âã«å ç±ãããããŠé éšæž©åºŠ60âã«ãããŠã·ã¯ã
ãããµã³ïŒã¡ã¿ããŒã«å ±æ²žæ··åç©ãåã³è¥å¹²ã®ã¡
ã¿ããŒã«ãèžçºãããããå·åŽããããšã«ããç
åºæ¶²ã¯ïŒå±€ã«åé¢ãããèžçå·¥çšãé éšæž©åºŠã62
âã«äžæãããŸã§ç¶ããããã®æž©åºŠã¯ãã»ãšãã©
ã®ã·ã¯ããããµã³ãã¹ã©ãªãŒã¿ã³ã¯ããèžçºãã
ããšã瀺ããã¹ã©ãªãŒã¿ã³ã¯ãåšå²æž©åºŠãŸã§å·åŽ
ãããããŠåååŒéåšãçšããŠã¹ã©ãªãŒãé
ããã也ç¥ããéåäœã¯ç¹ç¶ç¶ã§ããããããŠçŽ
0.06ïœïŒc.c.ã®åµ©å¯åºŠãæããŠããã
第ïŒå³ã¯ãã¡ã¿ããŒã«ïŒã·ã¯ããããµã³å
±æ²žæ··
åç©ã®æ²žç¹åã¯ãã®è¿åããã¡ã¿ããŒã«ã®æ²žç¹ã®
éã®æž©åºŠã«ãããŠãã¡ã¿ããŒã«é溶å€ã«ãããã·
ã¯ããããµã³æº¶å€äžã«æº¶è§£ããããªã·ã¯ããªã¬ã
ã€ã³ãå«ãã§æãã»ã¡ã³ãããããªã·ã¯ããªã¬ã
ã€ã³ãæ²æŸ±ããããããã®æµãå³ã瀺ãã å³äžãïŒïŒã¯åæã»ã¡ã³ãã®ç®¡è·¯ãïŒïŒã¯æ··å
æ©ãïŒïŒã¯å埪éã¡ã¿ããŒã«ã®ç®¡è·¯ãïŒïŒã¯åé¢
ã¿ã³ã¯ãïŒïŒã¯äºåæ¿çž®ã»ã¡ã³ãã®ç®¡è·¯ãïŒïŒã¯
é«åªææ··åæ©ãïŒïŒã¯å埪éã¡ã¿ããŒã«ã®ç®¡è·¯ã
ïŒïŒã¯éåäœã¹ã©ãªãŒã®ç®¡è·¯ãïŒïŒã¯ã¹ã©ãªãŒã¿
ã³ã¯ãïŒïŒã¯éåäœãšã¡ã¿ããŒã«ã®æ··åç©ã®ç®¡
è·¯ãïŒïŒã¯åé¢æ©ãïŒïŒã¯æ¹¿æœ€éåäœã®ç®¡è·¯ãã
ããŠïŒïŒã¯ä¹Ÿç¥æ©ã§ããã
åç©ã®æ²žç¹åã¯ãã®è¿åããã¡ã¿ããŒã«ã®æ²žç¹ã®
éã®æž©åºŠã«ãããŠãã¡ã¿ããŒã«é溶å€ã«ãããã·
ã¯ããããµã³æº¶å€äžã«æº¶è§£ããããªã·ã¯ããªã¬ã
ã€ã³ãå«ãã§æãã»ã¡ã³ãããããªã·ã¯ããªã¬ã
ã€ã³ãæ²æŸ±ããããããã®æµãå³ã瀺ãã å³äžãïŒïŒã¯åæã»ã¡ã³ãã®ç®¡è·¯ãïŒïŒã¯æ··å
æ©ãïŒïŒã¯å埪éã¡ã¿ããŒã«ã®ç®¡è·¯ãïŒïŒã¯åé¢
ã¿ã³ã¯ãïŒïŒã¯äºåæ¿çž®ã»ã¡ã³ãã®ç®¡è·¯ãïŒïŒã¯
é«åªææ··åæ©ãïŒïŒã¯å埪éã¡ã¿ããŒã«ã®ç®¡è·¯ã
ïŒïŒã¯éåäœã¹ã©ãªãŒã®ç®¡è·¯ãïŒïŒã¯ã¹ã©ãªãŒã¿
ã³ã¯ãïŒïŒã¯éåäœãšã¡ã¿ããŒã«ã®æ··åç©ã®ç®¡
è·¯ãïŒïŒã¯åé¢æ©ãïŒïŒã¯æ¹¿æœ€éåäœã®ç®¡è·¯ãã
ããŠïŒïŒã¯ä¹Ÿç¥æ©ã§ããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ ã·ã¯ããããµã³äžã«æº¶è§£ããéåäœãå«ãã§
æãã»ã¡ã³ããã該ã»ã¡ã³ããæ²æŸ±ããããããŠ
ã·ã¯ããããµã³åã³ã¡ã¿ããŒã«äžã«åæ£ããéå
äœåºåœ¢ç©ãå«æããéåäœã¹ã©ãªãŒã圢æããã®
ã«ååãªéã®ã¡ã¿ããŒã«ãšæ··åãïŒè©²ã¹ã©ãªãŒã
ãå ±æ²žçµæã®ã¡ã¿ããŒã«åã³ã·ã¯ããããµã³ãèž
çºããããŠå®è³ªäžéåäœãšã¡ã¿ããŒã«ãå«æãã
ã¹ãã³ãéåäœã¹ã©ãªãŒãæ®çãããïŒèžçºãã
ã¡ã¿ããŒã«åã³ã·ã¯ããããµã³ãåçž®ããããã
ããŠå瞮液ãå®è³ªäžãã¹ãŠã·ã¯ããããµã³ã§ãã
äžå±€ãšã¡ã¿ããŒã«ãå€éã«å«ãäžå±€ãšåé¢ãïŒã
ããŠè©²éåäœãã¡ã¿ããŒã«ããåé¢ãã段éãã
æãïŒè©²éåäœãå°ãªããšãïŒçš®ã®ãã«ãã«ãã³
ååéäœã®éç°éåã«ããçæããåå¿çæç©ã§
ããããšãç¹åŸŽãšããã»ã¡ã³ãããã®éåäœã®æ²
柱æ¹æ³ã ïŒ ã¡ã¿ããŒã«ãšåèšéåäœã»ã¡ã³ãã®çžå¯Ÿéã
çŽïŒïŒïŒã15ïŒïŒå®¹éæ¯ã®ç¯å²ã§ããç¹èš±è«æ±ã®
ç¯å²ç¬¬ïŒé èšèŒã®æ¹æ³ã ïŒ åèšéåäœãçŽ0.1ãïŒã®çšè溶液ç²åºŠãæ
ãããããŠã¡ãã«ãã«ãã«ãã³ãã¡ãã«ããã©ã·
ã¯ãããã»ã³åã³ãžã·ã¯ããã³ã¿ãžãšã³ã®åç¬é
åäœã䞊ã³ã«ãããã®å ±éåäœåã³äžå å ±éåäœ
ããéžã°ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æ¹æ³ã ïŒ èžæ°ã«ãããçµæãã¡ã¿ããŒã«37éééšãšã·
ã¯ããããµã³63éééšã§ãããããŠå€§æ°å§ã«ãã
ãŠçŽ54âã§æ²žéš°ããã¡ã¿ããŒã«ãšã·ã¯ããããµã³
ãšã®å ±æ²žæ··åç©ã®æ²žç¹ã®è¿ååã¯ããããé«ãæž©
床ã«ãããŠæ²æŸ±ãè¡ãç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒ
ã®æ¹æ³ã ïŒ åçž®ããã¡ã¿ããŒã«åã³ã·ã¯ããããµã³ãã
ã»ãšãã©ãã¹ãŠã·ã¯ããããµã³ã§ããäžå±€çŽ43容
éïŒ ãšã¡ã¿ããŒã«ãå€éã«å«ãäžå±€çŽ57容éïŒ ãš
ã«å±€åé¢ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æ¹æ³ã ïŒ åèšã®æ²æŸ±ã倧æ°å§äžçŽ65âããäœã枩床ã«
ãããŠè¡ããåšå²æ¡ä»¶ã«ãããŠåçž®ããã¡ã¿ããŒ
ã«åã³ã·ã¯ããããµã³ã®äžå±€ãçŽ97ééïŒ ã®ã·ã¯
ããããµã³ãšçŽïŒééïŒ ã®ã¡ã¿ããŒã«ããæãã
ãããŠäžå±€ãçŽ61ééïŒ ã®ã¡ã¿ããŒã«ãšçŽ39éé
ïŒ ã®ã·ã¯ããããµã³ããæãç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒ
é èšèŒã®æ¹æ³ã ïŒ åé¢ããã¡ã¿ããŒã«ãåèšéåäœã»ã¡ã³ãã®
æ²æŸ±ã®ããã«å埪éãã段éãåé¢ããéåäœã»
ã¡ã³ãã也ç¥ãã段éãåçž®ããã¡ã¿ããŒã«ãšã·
ã¯ããããµã³ã®äžå±€ãã·ã¯ããããµã³ãååãã
ããã«èŒžéãã段éãåã³åçž®ããã¡ã¿ããŒã«ãš
ã·ã¯ããããµã³ã®äžå±€ãã¡ã¿ããŒã«ãååããã
ãã«èŒžéãã段éãå«ãã§ãªãç¹èš±è«æ±ã®ç¯å²ç¬¬
ïŒé èšèŒã®æ¹æ³ã ïŒ åèšéåäœã»ã¡ã³ããã該éåäœã»ã¡ã³ãã
äºåçž®ããããã«ã¯ååã§ãããæ²æŸ±ããããã
ãã«ã¯äžååã§ããéã®ã¡ã¿ããŒã«ãšæ··åããã
ãã«ããå®è³ªäžã¡ã¿ããŒã«åã³ã·ã¯ããããµã³ã
å«ãäžå±€ã®çšéå±€ãšå®è³ªäžã·ã¯ããããµã³åã³é
åäœãå«ãäžå±€ã®äºåæ¿çž®ã»ã¡ã³ãå±€ããæãïŒ
局系ã圢æãã段éã䞊ã³ã«äºåæ¿çž®ããã»ã¡ã³
ãã該ã»ã¡ã³ãïŒå®¹ééšã«å¯ŸããŠïŒã15容ééšã®
ã¡ã¿ããŒã«ãšæ··åããããšã«ãã該äºåæ¿çž®ã»ã¡
ã³ããæ²æŸ±ãããã段éãå«ãç¹èš±è«æ±ã®ç¯å²ç¬¬
ïŒé èšèŒã®æ¹æ³ã ïŒ éåäœã»ã¡ã³ã100容ééšã«å¯ŸããŠçŽïŒã100
容ééšãããªãåé¢ã¡ã¿ããŒã«ã®äžéšåã該éå
äœã»ã¡ã³ãã®äºåæ¿çž®ã®ããã«å埪éãã段éã
åã³äºåæ¿çž®ãããã»ã¡ã³ãïŒå®¹ééšã«å¯ŸããŠïŒ
ã15容ééšãããªãåé¢ã¡ã¿ããŒã«ã®äžéšåã該
äºåæ¿çž®ã»ã¡ã³ãã®æ²æŸ±ã®ããã«å埪éãã段é
ãå«ãç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æ¹æ³ã ïŒïŒ åèšéåäœã»ã¡ã³ããçŽ15ïŒ ã®åºåœ¢åãå«
æããåèšäºåæ¿çž®ãããéåäœã»ã¡ã³ããçŽ20
ïŒ ä»¥äžã®åºåœ¢åãå«æãããããŠæ¿çž®ã«éåäœã»
ã¡ã³ãïŒå®¹ééšã«å¯ŸããŠçŽïŒãçŽïŒå®¹ééšã®ã¡ã¿
ããŒã«ã䜿çšããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æ¹
æ³ã
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US376368 | 1982-05-10 | ||
| US06/376,368 US4400501A (en) | 1982-05-10 | 1982-05-10 | Anhydrous precipitation of polycycloolefins |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58204024A JPS58204024A (ja) | 1983-11-28 |
| JPH0362173B2 true JPH0362173B2 (ja) | 1991-09-25 |
Family
ID=23484743
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58079463A Granted JPS58204024A (ja) | 1982-05-10 | 1983-05-09 | ããªã·ã¯ããªã¬ãã€ã³ã®æ²æŸ±æ¹æ³ |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US4400501A (ja) |
| EP (1) | EP0094016B1 (ja) |
| JP (1) | JPS58204024A (ja) |
| CA (1) | CA1210195A (ja) |
| DE (1) | DE3367228D1 (ja) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4492613A (en) * | 1982-08-02 | 1985-01-08 | The B. F. Goodrich Company | Recovery of components of a binary azeotrope |
| US4614778A (en) * | 1984-02-03 | 1986-09-30 | Hirokazu Kajiura | Random copolymer |
| US4943621A (en) * | 1988-08-04 | 1990-07-24 | The B. F. Goodrich Company | Storage stable components of reactive formulations for bulk polymerization of cycloolefin monomers |
| DE4329638C2 (de) * | 1993-09-02 | 1996-10-24 | Telefunken Microelectron | Lauthöreinrichtung |
| KR100590474B1 (ko) * | 2004-01-29 | 2006-06-19 | 죌ìíì¬ ìì§íí | ë²í¬ ë°ëê° ëì ê³ ëŠ¬í ì¬ë í ê³ ë¶ìì ì ì¡° ë°©ë² ë°ìŽì ìíì¬ ì ì¡°ë ê³ ëŠ¬í ì¬ë í ê³ ë¶ì |
| KR20080051399A (ko) | 2006-12-05 | 2008-06-11 | 죌ìíì¬ ìì§íí | ì€í©ì²Ž íì ì¥ì¹ ë° ì€í©ì²Ž íì ë°©ë² |
| WO2019217381A1 (en) | 2018-05-07 | 2019-11-14 | Teebs R&D, Llc | A method of forming a composition and the composition formed therefrom |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58120630A (ja) * | 1982-01-06 | 1983-07-18 | ã¶ã»ãâã»ãšãã»ã°ãããªããã»ã«ã³ããâ | é«ååéã·ã¯ããªã¬ãã€ã³ã®é溶å€äºåæ¿çž®æ¹æ³ |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4176220A (en) * | 1973-10-09 | 1979-11-27 | Japan Synthetic Rubber Co., Ltd. | Catalyst composition for ring-opening polymerization of norbornene derivatives and process for polymerizing same |
| US4069376A (en) * | 1975-04-17 | 1978-01-17 | The B. F. Goodrich Company | Process for substantially gel-free polymerization of norbornene with dicyclopentadiene |
| US4178424A (en) * | 1977-12-05 | 1979-12-11 | The Bf Goodrich Company | Cycloolefin copolymers |
-
1982
- 1982-05-10 US US06/376,368 patent/US4400501A/en not_active Expired - Lifetime
-
1983
- 1983-05-02 CA CA000427188A patent/CA1210195A/en not_active Expired
- 1983-05-04 DE DE8383104364T patent/DE3367228D1/de not_active Expired
- 1983-05-04 EP EP83104364A patent/EP0094016B1/en not_active Expired
- 1983-05-09 JP JP58079463A patent/JPS58204024A/ja active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58120630A (ja) * | 1982-01-06 | 1983-07-18 | ã¶ã»ãâã»ãšãã»ã°ãããªããã»ã«ã³ããâ | é«ååéã·ã¯ããªã¬ãã€ã³ã®é溶å€äºåæ¿çž®æ¹æ³ |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0094016B1 (en) | 1986-10-29 |
| JPS58204024A (ja) | 1983-11-28 |
| CA1210195A (en) | 1986-08-19 |
| EP0094016A3 (en) | 1984-02-22 |
| DE3367228D1 (en) | 1986-12-04 |
| US4400501A (en) | 1983-08-23 |
| EP0094016A2 (en) | 1983-11-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR940007561B1 (ko) | ì -ë°ë ëë ì€-ë°ë ì§ì íŽëŠ¬ìížë ì ì ì¡°ë°©ë² ë° ê·žì ì í©í ìŽë§€ | |
| JPH0362173B2 (ja) | ||
| EP0083561B1 (en) | Nonsolvent preconcentration of polymeric cycloolefins | |
| US4414386A (en) | Precipitation of polycycloolefins having high bulk density | |
| US4994426A (en) | Catalyst and process for polymerization of norbornene derivatives | |
| EP0184935B1 (en) | Method for high temperature phase separation of solution containing polymers | |
| US4410691A (en) | Precipitation of polycycloolefins | |
| EP0094017B1 (en) | Precipitation of polymeric cycloolefins | |
| US2802813A (en) | Terpene resin | |
| US4492613A (en) | Recovery of components of a binary azeotrope | |
| US3740381A (en) | Purification of olefinic polymers obtained in liquid phase | |
| US3639374A (en) | Process for flashing propylene diluent from polypropylene in cyclone separator | |
| US3119797A (en) | Process for refining polyolefins | |
| JPS5996146A (ja) | ã¢ã«ãã¢ãªã¬ãã€ã³éåäœçµæç©ããã³ãã®è£œé æ¹æ³ | |
| US3431249A (en) | Recovery of alpha-olefin polymers from solution | |
| US3136747A (en) | Continuous process for polymerizing polyethylene | |
| JPH027329B2 (ja) | ||
| US3272787A (en) | Extraction of soluble matter from polymer solids | |
| US2930787A (en) | Solids recovery from a polymer solution | |
| US3160622A (en) | Process for polymerizing olefins utilizing a ziegler catalyst | |
| US3535296A (en) | Continuous process for the production of alfin polymers in crumb form | |
| US3640978A (en) | Continuous process for the production of alfin polymers by polymerization of alfin monomers in an organic solvent and for recovering and recycling solvent | |
| US3706720A (en) | Continuous process for the production of alfin polymers | |
| KR930007878B1 (ko) | ìíŽë¡ì¬ë íë¥ì ì€í©ì© ìŽë§€ ì¡°ì±ë¬Œ ë° ìŽì ì ì¡°ë°©ë² | |
| JPH0471088B2 (ja) |