JPH0353747B2 - - Google Patents
Info
- Publication number
- JPH0353747B2 JPH0353747B2 JP56114335A JP11433581A JPH0353747B2 JP H0353747 B2 JPH0353747 B2 JP H0353747B2 JP 56114335 A JP56114335 A JP 56114335A JP 11433581 A JP11433581 A JP 11433581A JP H0353747 B2 JPH0353747 B2 JP H0353747B2
- Authority
- JP
- Japan
- Prior art keywords
- sodium
- metal
- sulfur battery
- alumina
- milliohms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 46
- 229910052751 metal Inorganic materials 0.000 claims description 34
- 239000002184 metal Substances 0.000 claims description 34
- 229910052708 sodium Inorganic materials 0.000 claims description 34
- 239000011734 sodium Substances 0.000 claims description 34
- BNOODXBBXFZASF-UHFFFAOYSA-N [Na].[S] Chemical compound [Na].[S] BNOODXBBXFZASF-UHFFFAOYSA-N 0.000 claims description 26
- 229910000873 Beta-alumina solid electrolyte Inorganic materials 0.000 claims description 25
- 239000003792 electrolyte Substances 0.000 claims description 18
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 15
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 7
- 229910052719 titanium Inorganic materials 0.000 claims description 7
- 239000010936 titanium Substances 0.000 claims description 7
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 5
- 239000011593 sulfur Substances 0.000 claims description 5
- 229910052717 sulfur Inorganic materials 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- 239000011236 particulate material Substances 0.000 claims description 4
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 4
- HYHCSLBZRBJJCH-UHFFFAOYSA-N sodium polysulfide Chemical compound [Na+].S HYHCSLBZRBJJCH-UHFFFAOYSA-N 0.000 claims description 4
- 239000002043 β-alumina solid electrolyte Substances 0.000 claims description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
- 229910052770 Uranium Inorganic materials 0.000 claims description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 3
- 239000011777 magnesium Substances 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 claims description 3
- 229910052727 yttrium Inorganic materials 0.000 claims description 3
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 3
- 229910052726 zirconium Inorganic materials 0.000 claims description 3
- 229910000528 Na alloy Inorganic materials 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims 1
- 238000012360 testing method Methods 0.000 description 9
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 7
- 229940046892 lead acetate Drugs 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 229910045601 alloy Inorganic materials 0.000 description 5
- 239000000956 alloy Substances 0.000 description 5
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 239000002001 electrolyte material Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 229910001415 sodium ion Inorganic materials 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- QXJJQWWVWRCVQT-UHFFFAOYSA-K calcium;sodium;phosphate Chemical compound [Na+].[Ca+2].[O-]P([O-])([O-])=O QXJJQWWVWRCVQT-UHFFFAOYSA-K 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 238000005247 gettering Methods 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000007784 solid electrolyte Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/36—Accumulators not provided for in groups H01M10/05-H01M10/34
- H01M10/39—Accumulators not provided for in groups H01M10/05-H01M10/34 working at high temperature
- H01M10/3909—Sodium-sulfur cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Secondary Cells (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8023739 | 1980-07-21 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5753072A JPS5753072A (en) | 1982-03-29 |
| JPH0353747B2 true JPH0353747B2 (US07601507-20091013-C00025.png) | 1991-08-16 |
Family
ID=10514909
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP56114335A Granted JPS5753072A (en) | 1980-07-21 | 1981-07-21 | Sodium sulfur battery |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US4356241A (US07601507-20091013-C00025.png) |
| EP (1) | EP0044638B1 (US07601507-20091013-C00025.png) |
| JP (1) | JPS5753072A (US07601507-20091013-C00025.png) |
| DE (1) | DE3166814D1 (US07601507-20091013-C00025.png) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3117382C2 (de) * | 1981-05-02 | 1986-01-02 | Brown, Boveri & Cie Ag, 6800 Mannheim | Elektrochemische Speicherzelle |
| US4609596A (en) * | 1985-07-10 | 1986-09-02 | The United States Of America As Represented By The United States Department Of Energy | Electrochemical devices utilizing molten alkali metal electrode-reactant |
| JPS62133679A (ja) * | 1985-12-06 | 1987-06-16 | Hitachi Ltd | ナトリウム硫黄電池 |
| GB8623071D0 (en) * | 1986-09-25 | 1986-10-29 | Lilliwyte Sa | Ceramic surface wetting |
| GB8728394D0 (en) * | 1987-12-04 | 1988-01-13 | Lilliwyte Sa | Electrochemical cell |
| USH858H (en) | 1988-10-24 | 1990-12-04 | The United States Of America As Represented By The Secretary Of The Air Force | Electrical battery cell wicking structure and method |
| USH971H (en) | 1988-10-24 | 1991-10-01 | The United States Of America As Represented By The Secretary Of The Air Force | Regidized porous material and method |
| US5059497A (en) * | 1990-04-20 | 1991-10-22 | Hughes Aircraft Company | Composite ion-conductive electrolyte member |
| US20120052398A1 (en) * | 2010-08-24 | 2012-03-01 | Battelle Memorial Institute | Electrochemical Energy Storage Devices Having a Metallic Interfacial Conducting Agent at the Electrode-Electrolyte Interface |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5078830A (US07601507-20091013-C00025.png) * | 1973-11-16 | 1975-06-26 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3933523A (en) * | 1974-03-18 | 1976-01-20 | General Electric Company | Solid sodium ion-conductive electrolyte with liquid metallic layer |
| GB1526249A (en) * | 1974-11-27 | 1978-09-27 | Battelle Institut E V | Rechargeable galvanic sodium-sulphur cells and batteries and methods of manufacturing same |
| GB1511152A (en) * | 1975-04-24 | 1978-05-17 | Chloride Silent Power Ltd | Alkali metal-sulphur cells |
| US4162202A (en) * | 1976-03-08 | 1979-07-24 | P. R. Mallory & Co. Inc. | Means for improving contact between Li and the anode current collector |
| GB1586072A (en) * | 1977-05-05 | 1981-03-18 | Chloride Silent Power Ltd | Sealing of ceramic electrolyte material in electrochemical cells |
| GB1548263A (en) * | 1976-11-29 | 1979-07-11 | Chloride Silent Power Ltd | Sodium-sulphur cells |
| US4220691A (en) * | 1978-09-25 | 1980-09-02 | Electric Power Research Institute, Inc. | Sodium sulfur cell |
| US4348468A (en) * | 1979-12-28 | 1982-09-07 | Chloride Silent Power Limited | Beta alumina solid electrolyte material and its manufacture and electrochemical cells or other energy conversion devices containing such material |
| US4248943A (en) * | 1980-04-21 | 1981-02-03 | Ford Motor Company | Sodium sulfur container with chromium/chromium oxide coating |
-
1981
- 1981-07-01 DE DE8181303005T patent/DE3166814D1/de not_active Expired
- 1981-07-01 EP EP81303005A patent/EP0044638B1/en not_active Expired
- 1981-07-07 US US06/280,957 patent/US4356241A/en not_active Expired - Fee Related
- 1981-07-21 JP JP56114335A patent/JPS5753072A/ja active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5078830A (US07601507-20091013-C00025.png) * | 1973-11-16 | 1975-06-26 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5753072A (en) | 1982-03-29 |
| EP0044638A1 (en) | 1982-01-27 |
| DE3166814D1 (en) | 1984-11-29 |
| EP0044638B1 (en) | 1984-10-24 |
| US4356241A (en) | 1982-10-26 |
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