JPH0347831B2 - - Google Patents

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Publication number
JPH0347831B2
JPH0347831B2 JP63299308A JP29930888A JPH0347831B2 JP H0347831 B2 JPH0347831 B2 JP H0347831B2 JP 63299308 A JP63299308 A JP 63299308A JP 29930888 A JP29930888 A JP 29930888A JP H0347831 B2 JPH0347831 B2 JP H0347831B2
Authority
JP
Japan
Prior art keywords
dextrin
dietary fiber
amylase
roasted
food
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP63299308A
Other languages
Japanese (ja)
Other versions
JPH02145169A (en
Inventor
Kazuhiro Ookuma
Takao Hanno
Kazuyuki Inada
Isao Matsuda
Yasuo Katsuta
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Matsutani Chemical Industries Co Ltd
Original Assignee
Matsutani Chemical Industries Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsutani Chemical Industries Co Ltd filed Critical Matsutani Chemical Industries Co Ltd
Priority to JP63299308A priority Critical patent/JPH02145169A/en
Priority to EP89309269A priority patent/EP0368451B1/en
Priority to DE68914401T priority patent/DE68914401T2/en
Priority to KR1019890013379A priority patent/KR0135075B1/en
Publication of JPH02145169A publication Critical patent/JPH02145169A/en
Publication of JPH0347831B2 publication Critical patent/JPH0347831B2/ja
Priority to US08/438,113 priority patent/US5620873A/en
Granted legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12PFERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P19/00Preparation of compounds containing saccharide radicals
    • C12P19/14Preparation of compounds containing saccharide radicals produced by the action of a carbohydrase (EC 3.2.x), e.g. by alpha-amylase, e.g. by cellulase, hemicellulase
    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D2/00Treatment of flour or dough by adding materials thereto before or during baking
    • A21D2/08Treatment of flour or dough by adding materials thereto before or during baking by adding organic substances
    • A21D2/14Organic oxygen compounds
    • A21D2/18Carbohydrates
    • A21D2/186Starches; Derivatives thereof
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/34Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
    • A23G3/346Finished or semi-finished products in the form of powders, paste or liquids
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/30Foods or foodstuffs containing additives; Preparation or treatment thereof containing carbohydrate syrups; containing sugars; containing sugar alcohols, e.g. xylitol; containing starch hydrolysates, e.g. dextrin
    • A23L29/35Degradation products of starch, e.g. hydrolysates, dextrins; Enzymatically modified starches
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L33/00Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
    • A23L33/20Reducing nutritive value; Dietetic products with reduced nutritive value
    • A23L33/21Addition of substantially indigestible substances, e.g. dietary fibres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08BPOLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B30/00Preparation of starch, degraded or non-chemically modified starch, amylose, or amylopectin
    • C08B30/12Degraded, destructured or non-chemically modified starch, e.g. mechanically, enzymatically or by irradiation; Bleaching of starch
    • C08B30/18Dextrin, e.g. yellow canari, white dextrin, amylodextrin or maltodextrin; Methods of depolymerisation, e.g. by irradiation or mechanically
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12YENZYMES
    • C12Y302/00Hydrolases acting on glycosyl compounds, i.e. glycosylases (3.2)
    • C12Y302/01Glycosidases, i.e. enzymes hydrolysing O- and S-glycosyl compounds (3.2.1)
    • C12Y302/01001Alpha-amylase (3.2.1.1)
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G2200/00COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF containing organic compounds, e.g. synthetic flavouring agents
    • A23G2200/14COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF containing organic compounds, e.g. synthetic flavouring agents containing fruits, nuts, e.g. almonds, seeds, plants, plant extracts, essential oils

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Food Science & Technology (AREA)
  • Wood Science & Technology (AREA)
  • Biochemistry (AREA)
  • Zoology (AREA)
  • General Engineering & Computer Science (AREA)
  • Nutrition Science (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Molecular Biology (AREA)
  • Microbiology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Biotechnology (AREA)
  • Mycology (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Medicinal Chemistry (AREA)
  • Coloring Foods And Improving Nutritive Qualities (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明の焙焼デキストリンを酵素処理すること
により、食物繊維分を含有したデキストリンを製
造する方法に関する。
DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to a method for producing dextrin containing dietary fiber by enzymatically treating the roasted dextrin of the present invention.

〔従来技術〕[Prior art]

焙焼デキストリンは周知の通り澱粉を高熱処理
したものであつて、その処理により澱粉分子は加
水分解及び再重合が起こり、複雑な構造を呈して
いると言われ、水溶性になると共に、難消化性の
ものがかなりの割合をしめている。
As is well known, roasted dextrin is starch that has been subjected to high heat treatment.As a result of this treatment, starch molecules are hydrolyzed and repolymerized, resulting in a complex structure that becomes water-soluble and indigestible. Sexual matters account for a large proportion.

一方近時日本人の食生活が変化し、多様化した
結果、繊維分の摂取量が目立つて減少しており、
この繊維分の欠乏は成人病の起因の一つにも挙げ
られており、食物繊維の必要性が注目を集め、蛋
白質、糖類、脂質、ビタミン、ミネラルに次ぐ六
番目の栄養素と言われる様になつて来た。
On the other hand, as the Japanese diet has changed and become more diverse in recent years, the intake of fiber has decreased noticeably.
This lack of fiber has been cited as one of the causes of adult diseases, and the necessity of dietary fiber has attracted attention, and it is now said to be the sixth nutrient after protein, sugars, lipids, vitamins, and minerals. I'm getting used to it.

現在食物繊維としては植物性のものや、動物性
のもので、水溶性、不溶性と色々挙げられてお
り、又合成品としてポリデキストロースが挙げら
れている。これらはぶどう糖或いはその誘導体、
ぶどう糖以外の糖類が多数結合した形の繊維状を
なしたもの、或いは蛋白質多糖と言つたもので形
作られている。その構造は複雑で体内に摂取され
てもその消化が困難で、そのまま体外に排出され
るため繊維としての効果があると云われている。
Currently, there are a variety of dietary fibers, including plant-based and animal-based fibers, water-soluble and insoluble, and polydextrose as a synthetic product. These are glucose or its derivatives,
It is made up of a fibrous structure in which many sugars other than glucose are bound together, or a protein polysaccharide. Its structure is complex and it is difficult to digest even if it is ingested into the body, and it is said to be effective as a fiber because it is excreted from the body as is.

〔発明が解決しようとする課題〕[Problem to be solved by the invention]

本発明者は従来から食物繊維について研究を続
けてきたが、この研究に於いて、従来その激しい
刺激臭や望ましくない味覚のために全く食物繊維
として考えても見られなかつた焙焼デキストリン
を、新しい食物繊維として利用することが出来な
いであろうかという全く新しい着想に至つた。
The present inventor has been researching dietary fiber for some time, and in this research, roasted dextrin, which had not been considered as a dietary fiber at all due to its strong pungent odor and undesirable taste, was discovered. I came up with a completely new idea that it might be possible to use it as a new dietary fiber.

従つて本発明が解決しようとする課題は、上記
新しい着想を実現し、食物繊維として充分に使用
しうる食物繊維分を含有したデキストリンを焙焼
デキストリンから製造しうる方法を開発すること
である。
Therefore, the problem to be solved by the present invention is to realize the above-mentioned new idea and develop a method for producing dextrin from roasted dextrin containing a sufficient amount of dietary fiber that can be used as dietary fiber.

〔課題を解決するための手段〕[Means to solve the problem]

この課題は、焙焼デキストリンを水に溶解し、
これにα−アミラーゼを作用させ、必要に応じ更
に水素添加することにより解決される。
This task involves dissolving roasted dextrin in water,
This can be solved by allowing α-amylase to act on this and further hydrogenating if necessary.

〔発明の構成並びに作用〕[Structure and operation of the invention]

本発明に於いては焙焼デキストリンをα−アミ
ラーゼで処理してデキストリンをα−リミツトデ
キストリンまで進行せしめて、焙焼デキストリン
の有する刺激臭や好ましくない味覚を解消する。
In the present invention, roasted dextrin is treated with α-amylase to progress the dextrin to α-limited dextrin, thereby eliminating the irritating odor and unfavorable taste of roasted dextrin.

以下に本発明をその製造法に従つて順に説明す
る。
The present invention will be explained below in order according to its manufacturing method.

先ず焙焼デキストリンを原料とするが、この焙
焼デキストリンとしては、従来から知られている
ものが使用できるが、特に本発明に於いては、そ
の刺激臭や好ましくない味覚を効率良く除去する
には、次のような方法で製造された焙焼デキスト
リンを使用するのが好ましい。即ち原料澱粉に鉱
酸好ましくは塩酸の水溶液を加え、次いで水分量
が5%前後になるまで予備乾燥し、続いて焙焼し
て製造したものが好ましい。この際の原料澱粉と
しては、広く各種のものがいずれも使用出来、た
とえば馬鈴薯、トーモロコシ、キヤツサバなど何
れでもよく、又食品用加工澱粉として市販されて
いるものでよい。これらの原料澱粉に硫酸、塩
酸、硝酸などの鉱酸好ましくは塩酸を好ましくは
その濃度を1重量%程度となして原料に対して数
重量%の量を添加好ましくは噴霧して均一になる
様良く混合し、100〜120℃程度で予備乾燥する。
この予備乾燥では澱粉の水分を5%前後まで乾燥
する。続いて150℃〜220℃に温度を上げて、1時
間〜5時間程度焙焼して焙焼デキストリンとす
る。ここで出来た焙焼デキストリンはDE(デキス
トロース当量)1〜10位のものが好ましい。
First, roasted dextrin is used as a raw material. As this roasted dextrin, conventionally known ones can be used, but especially in the present invention, in order to efficiently remove the irritating odor and unpleasant taste, It is preferable to use roasted dextrin produced by the following method. That is, it is preferable to add an aqueous solution of a mineral acid, preferably hydrochloric acid, to the raw material starch, then pre-dry it until the moisture content becomes around 5%, and then roast it. As the raw material starch in this case, any of a wide variety of starches can be used, such as potato, corn, or mackerel, or any starch that is commercially available as processed starch for food. A mineral acid such as sulfuric acid, hydrochloric acid, or nitric acid, preferably hydrochloric acid, is added to these raw starches in an amount of several weight percent based on the raw material, preferably at a concentration of about 1 weight percent, preferably by spraying so that it becomes uniform. Mix well and pre-dry at about 100-120℃.
In this pre-drying, the water content of starch is dried to around 5%. Subsequently, the temperature is raised to 150°C to 220°C and roasted for about 1 to 5 hours to obtain roasted dextrin. The roasted dextrin produced here preferably has a DE (dextrose equivalent) of 1 to 10.

次にこの焙焼デキストリンを水に溶かし30〜50
重量%の液となし、中和してPH5.5〜6.5好ましく
は5.8となし、市販のα−アミラーゼ(カビ由来
のもの、細菌由来のもの等何れでもよい)を焙焼
デキストリンに対して0.05〜0.2重量%添加して
該アミラーゼの作用温度85℃〜100℃前後となし、
30分〜2時間保持する。これにより酵素によるデ
キストリンの分解がα−リミツトデキストリンま
で進む。次いで温度を120℃まで上げα−アミラ
ーゼの酵素作用を終了させる。
Next, dissolve this roasted dextrin in water and add 30 to 50%
% by weight, neutralize to pH 5.5 to 6.5, preferably 5.8, and add commercially available α-amylase (either mold-derived, bacterial-derived, etc.) to roasted dextrin at 0.05%. By adding ~0.2% by weight, the action temperature of the amylase is around 85°C to 100°C,
Hold for 30 minutes to 2 hours. This causes the enzymatic decomposition of dextrin to progress to α-limit dextrin. The temperature is then raised to 120°C to terminate the enzymatic action of α-amylase.

以上の操作により得られた液を活性炭脱色、脱
塩等の通常の精製工程を通し、濃縮、噴霧乾燥し
て異臭、刺激味のない食品用に利用できるデキス
トリン粉末を得ることが出来る。
The liquid obtained by the above operations is subjected to conventional purification processes such as decolorization with activated carbon and desalination, concentrated and spray-dried to obtain a dextrin powder that can be used for food products and has no off-odor or irritating taste.

本発明に於いては上記精製工程が終了したデキ
ストリンに更に水素添加を施すことが出来る。こ
の水素添加により水素添加したものは着色がな
くなる。還元基を取られたため還元性を無く
し、メーラード反応を出し難くする。味が良く
なり、また舌ざわりが良くなる。難醗酵性にな
り、たとえば乳酸菌にアタツクされなくなる等の
効果が発揮される。水素添加手段自体は特に限定
されない。水素添加の程度は末端還元基が無くな
る程度である。好ましい水素添加方法としてはた
とえば上記精製されたデキストリンを再び水溶液
の形態となし、PHを調整し、触媒たとえばラネー
ニツケル等を共存させて、必要に応じ加熱しなが
ら水素と接触せしめる方法を例示出来る。
In the present invention, the dextrin that has undergone the above purification step can be further subjected to hydrogenation. By this hydrogenation, the hydrogenated product loses its coloring. Since the reducing group is removed, it loses reducibility and makes it difficult for the Maillard reaction to occur. It tastes better and has a better texture. It becomes difficult to ferment and has the effect of not being attacked by lactic acid bacteria, for example. The hydrogenation means itself is not particularly limited. The degree of hydrogenation is such that terminal reducing groups are eliminated. A preferred hydrogenation method is, for example, a method in which the purified dextrin is made into an aqueous solution again, the pH is adjusted, a catalyst such as Raney nickel is present, and the solution is brought into contact with hydrogen while heating if necessary.

本発明に於いては、水素添加を施す場合には、
焙焼デキストリンを上記本発明の方法でα−アミ
ラーゼで作用させた後、更にトランスグルコシダ
ーゼ及びβ−アミラーゼの少なくとも1種で更に
酵素処理することも出来る。この酵素処理は上記
α−アミラーゼ処理が終了した後、この後液温を
下げ、PHを調整し、トランスグルコシダーゼ(市
販品)を元の焙焼デキストリンに対して0.05〜
0.2重量%添加し、24時間〜48時間作用させる。
この反応は液中に存在することがあるぶどう糖や
オリゴ糖の様な小さい分子を大きい分子の方へ再
重合させると共に、焙焼デキストリンの複雑な構
造を更に増加させるものである。かくして所定の
時間後一旦温度を上げて(たとえば80℃前後に)
トランスグルコシダーゼの酵素作用を終了させ
る。尚このトランスグルコシダーゼの添加の際β
−アミラーゼ(市販品)を同時に作用させてもよ
い。これにより反応が促進される。
In the present invention, when hydrogenation is performed,
After the roasted dextrin is treated with α-amylase in the method of the present invention, it can be further enzymatically treated with at least one of transglucosidase and β-amylase. This enzyme treatment is carried out after the above α-amylase treatment is completed, after which the liquid temperature is lowered, the pH is adjusted, and transglucosidase (commercially available) is added to the original roasted dextrin by 0.05~
Add 0.2% by weight and let it act for 24 to 48 hours.
This reaction repolymerizes small molecules such as glucose and oligosaccharides that may be present in the liquid into larger molecules and further increases the complex structure of the torrefied dextrin. After a predetermined period of time, the temperature is raised (for example, to around 80°C).
Terminates the enzymatic action of transglucosidase. In addition, when adding this transglucosidase, β
-Amylase (commercially available) may be used at the same time. This accelerates the reaction.

またトランスグルコシダーゼで処理する場合に
は、原料焙焼デキストリンに単糖類やオリゴ糖を
添加することができる。これ等糖類の添加は繊維
分を増加せしめることが出来、通常その糖含有量
が40〜60重量%の糖液を、澱粉に対し1〜10重量
%程度添加する。
Furthermore, in the case of treatment with transglucosidase, monosaccharides and oligosaccharides can be added to the roasted dextrin raw material. Addition of these sugars can increase the fiber content, and usually a sugar solution with a sugar content of 40 to 60% by weight is added to the starch in an amount of about 1 to 10% by weight.

かくして得られたデキストリンは繊維素成分が
含有され、しかも望ましくない異臭がなく、食品
用として好ましいものである。しかも水素添加す
ることにより還元され前記した諸効果が発揮さ
れ、更に好ましいものとなる。加えて水素添加す
る場合に更にトランスグルコシダーゼあるいは
(及び)β−アミラーゼで処理することにより、
繊維素成分が更に高分子化され、難消化性成分が
更に増加する。
The dextrin thus obtained contains cellulose components and has no undesirable odor, making it suitable for use in foods. Moreover, by hydrogenation, it is reduced and the above-mentioned effects are exhibited, making it even more preferable. In addition, in the case of hydrogenation, by further treatment with transglucosidase or (and) β-amylase,
The cellulose component is further polymerized, and the indigestible component is further increased.

従つて本発明デキストリンは食品用原料として
広く各種の食品に適用され、たとえば各種飲料、
ドレツシング類、菓子類たとえばキヤンデイー、
ゼリー、パン、ケーキ、米菓等、基礎調味料たと
えば味噌、ソール等、水畜産練り製品たとえばか
まぼこ、ソーセージ等、調理食品たとえばハンバ
ーグ、ミンチカツ等、乳製品、冷菓等に有効に使
用出来る。
Therefore, the dextrin of the present invention can be widely applied as a food raw material to various foods, such as various beverages,
Dressings, sweets such as candy,
It can be effectively used in jelly, bread, cakes, rice crackers, etc., basic seasonings such as miso, sole, etc., water and livestock paste products such as kamaboko, sausages, etc., cooked foods such as hamburgers, minced meat cutlets, etc., dairy products, frozen desserts, etc.

〔実地例〕[Practical example]

以下実施例により本発明を説明する。 The present invention will be explained below with reference to Examples.

実施例 1 市販の馬鈴薯澱粉5000Kgをリボン式ミキサーに
入れ、撹拌しながら1.0%塩酸150をスプレー、
続いて粉砕機を通し均一にした後、更にリボン式
ミキサー中で5時間熟成した。この混合物をフラ
ツシユドライヤーで水分3%に予備乾燥した後、
ロータリーキルン式焙焼機に連続投入し、180℃
で2時間焙焼した。
Example 1 5000 kg of commercially available potato starch was placed in a ribbon mixer, and while stirring, 150 kg of 1.0% hydrochloric acid was sprayed.
Subsequently, the mixture was homogenized through a pulverizer, and then further aged in a ribbon mixer for 5 hours. After pre-drying this mixture with a flash dryer to a moisture content of 3%,
Continuously fed into a rotary kiln roaster at 180℃
Roasted for 2 hours.

次に、上記方法で得た焙焼デキストリン2000Kg
に水4000を添加し、PHを6.0に調整し、α−ア
ミラーゼ(ターマミル60、ノボ社)0.2%を添
加し95℃で1時間加水分解し、この反応終了液を
脱色、脱塩等の精製を行い、スプレードライヤー
で乾燥し、1700Kgの粉末品を得た。このようにし
て得られた焙焼デキストリン精製物の食物繊維含
量はプロスキー−AOAC法で定量した時35%で
あつた。
Next, 2000 kg of roasted dextrin obtained by the above method
Add 4,000 ml of water to adjust the pH to 6.0, add 0.2% α-amylase (Termamyl 60, Novo) and hydrolyze at 95°C for 1 hour. Purify the reaction solution by decolorizing, desalting, etc. and dried with a spray dryer to obtain a powder product weighing 1700 kg. The dietary fiber content of the roasted dextrin purified product thus obtained was 35% when determined by the Prosky-AOAC method.

実施例 2 実施例1で得られた食物繊維含有デキストリン
を40%濃度に再調製し、液に対して0.4%相当の
8%第二リン酸ナトリウム液を加え、更に20%水
酸化ナトリウム液を加えPH9.5とした。この溶液
をオートクレーブに入れ、液に対して1%のラネ
ーニツケル(日興理化性R−100)を添加し、温
度21℃、水素ガスゲージ圧95Kg/cm2まで充填した
後オートクレーブを振とうさせながら130℃まで
加熱し120分間保持し還元反応を終了させた。放
冷後、反応液に活性炭を加え触媒も同時にろ過し
た。ろ液はイオン交換樹脂により脱塩し、濃縮し
75%溶液を得た。
Example 2 The dietary fiber-containing dextrin obtained in Example 1 was re-adjusted to a 40% concentration, and an 8% dibasic sodium phosphate solution equivalent to 0.4% was added to the solution, followed by a 20% sodium hydroxide solution. In addition, the pH was set to 9.5. This solution was placed in an autoclave, 1% Raney Nickel (Nikko Rikasei R-100) was added to the solution, the temperature was 21℃, and the hydrogen gas gauge pressure was 95Kg/ cm2.The autoclave was heated to 130℃ while shaking. The reduction reaction was completed by heating the mixture to 120 minutes and holding it for 120 minutes. After cooling, activated carbon was added to the reaction solution, and the catalyst was also filtered at the same time. The filtrate was desalted using an ion exchange resin and concentrated.
A 75% solution was obtained.

この濃縮液は無色透明な粘凋液で食物繊維27%
(プロスキー−AOAC法により)含んでいた。
This concentrate is a colorless and transparent viscous liquid with 27% dietary fiber.
(by Prosky-AOAC method).

実施例 3 食物繊維含有食品の製造 実施例1で得られた食物繊維含有デキストリン
を添加して下記のような処方の食品を製造した。
また、その食品の食物繊維含量は次のようであつ
た。
Example 3 Production of dietary fiber-containing food The dietary fiber-containing dextrin obtained in Example 1 was added to produce a food with the following formulation.
In addition, the dietary fiber content of the food was as follows.

食パン 強力粉 250g 砂 糖 17g 食 塩 5g 圧搾酵母 3g イーストフード 6g バター 11g 実施例1で得たデキストリン 30g 水 190g 上記成分を用いて常法に従い食パンとした。Plain bread 250g strong flour 17g sugar 5g table salt 3g pressed yeast Yeast food 6g 11g butter 30g of dextrin obtained in Example 1 190g water Bread was made using the above ingredients according to a conventional method.

食物繊維含量 3.7% アイスクリーム バター 6.5 全脂練乳 8.0 脱脂粉乳 6.5 実施例1で得たデキストリン 8.0 砂 糖 5.0 乳化剤 0.3 安定剤 0.2 水 62.5 上記成分を用い常法によりアイスクリームを製
造した。
Dietary fiber content 3.7% Ice cream butter 6.5 Whole fat condensed milk 8.0 Skimmed milk powder 6.5 Dextrin obtained in Example 1 8.0 Sugar 5.0 Emulsifier 0.3 Stabilizer 0.2 Water 62.5 Ice cream was produced by a conventional method using the above ingredients.

食物繊維含量 2.8% 炭酸飲料(サイダー味) グラニユー糖 125g クエン酸 1.5g クエン酸Na 0.1g ビタミンC 0.15g サイダーエツセンス 1.0ml 実施例1で得たデキストリン 50g 炭酸水 520g 水 385ml 上記成分を常法に従つて処理して炭酸飲料を得
た。
Dietary fiber content 2.8% Carbonated drink (cider flavor) Granulated sugar 125g Citric acid 1.5g Sodium citrate 0.1g Vitamin C 0.15g Cider essence 1.0ml Dextrin obtained in Example 1 50g Carbonated water 520g Water 385ml The above ingredients were mixed in the usual manner A carbonated beverage was obtained.

食物繊維含量 1.8% ドレツシング サラダ油 56g 食用酢 30g 香辛料 3.5g MSG 0.5g 実施例1で得たデキストリン 10g 上記成分を用いて常法によりドレツシングを製
造した。
Dietary fiber content 1.8% Dressing Salad oil 56g Edible vinegar 30g Spices 3.5g MSG 0.5g Dextrin obtained in Example 1 10g A dressing was produced using the above ingredients in a conventional manner.

食物繊維含量 3.5% 実施例2で得られた食物繊維含有デキストリン
を添加して下記のような処方の食品を製造した。
但し、下記の食品の製造法は夫々の食品の常法に
よつた。また、その食品の食物繊維含量は次のよ
うであつた。
Dietary fiber content: 3.5% The dietary fiber-containing dextrin obtained in Example 2 was added to produce a food product with the following formulation.
However, the following food products were manufactured using conventional methods for each food product. In addition, the dietary fiber content of the food was as follows.

キヤンデイー 砂 糖 50g 水 飴 35g 酒石酸 0.15g クエン酸 0.35g 食用色素 適 量 食品香料 適 量 実施例3で得たデキストリンアルコール 20g 食物繊維含量 7.0% かまぼこ すり身 100部 食 塩 3部 澱 粉 5部 実施例3で得たデキストリンアルコール 7.5部 水 32.5部 食物繊維含量 3.0% 比較例 実施例1で得られた焙焼デキストリンと同等の
DE値を持つマルトデキストリン(パインデツク
ス#1、松谷化学社製)を50%まで濃縮して0.2
%トランスグルコシダーゼを添加して48時間反応
させた結果、次の様な糖を得た。
Candy sugar 50g Water Candy 35g Tartaric acid 0.15g Citric acid 0.35g Food coloring Appropriate amount Food flavoring Appropriate amount Dextrin alcohol obtained in Example 3 20g Dietary fiber content 7.0% Fish paste 100 parts Salt 3 parts Starch 5 parts Example Dextrin obtained in Example 3 Alcohol 7.5 parts Water 32.5 parts Dietary fiber content 3.0% Comparative example Same as the roasted dextrin obtained in Example 1
Maltodextrin (Pinedex #1, manufactured by Matsutani Chemical Co., Ltd.) with DE value is concentrated to 50% and 0.2
As a result of adding % transglucosidase and reacting for 48 hours, the following sugars were obtained.

DP1 65%DP2 10.5%(マルトース2.3%、コー
ジビオース2.5%、イソマルトース5.7%)DP3
6.2%(マルトトリオース1.2%、パノース3.8%、
イソマルトトリオース1.2%)DP4以上18.3%難消
化性デキストリン含量5.0%であつた。
DP1 65% DP2 10.5% (maltose 2.3%, cordibiose 2.5%, isomaltose 5.7%) DP3
6.2% (maltotriose 1.2%, panose 3.8%,
Isomaltotriose 1.2%) DP4 or higher 18.3% Indigestible dextrin content 5.0%.

Claims (1)

【特許請求の範囲】 1 焙焼デキストリンを水に溶解し、これにα−
アミラーゼを作用させる事を特徴とする食物繊維
含有デキストリンの製造法。 2 α−アミラーゼを作用させた後、更に水素添
加することを特徴とする請求項1に記載の食物繊
維含有デキストリンの製造法。 3 α−アミラーゼ作用後、水素添加前にトラン
スグルコシダーゼまたは(及び)β−アミラーゼ
を作用させることを特徴とする請求項2に記載の
食物繊維含有デキストリンの製造法。 4 焙焼デキストリンとして澱粉単独、或いはこ
れに単糖類及びオリゴ糖の少なくとも1種を混合
したものを常法で焙焼して製造したものを使用す
る請求項1乃至3のいずれかに記載の食物繊維含
有デキストリンの製造法。
[Claims] 1. Dissolve roasted dextrin in water and add α-
A method for producing dietary fiber-containing dextrin, which is characterized by allowing amylase to act. 2. The method for producing dietary fiber-containing dextrin according to claim 1, which further comprises hydrogenating after the action of α-amylase. 3. The method for producing a dietary fiber-containing dextrin according to claim 2, characterized in that after the action of α-amylase, transglucosidase or (and) β-amylase is allowed to act. 4. The food according to any one of claims 1 to 3, wherein the roasted dextrin is prepared by roasting starch alone or a mixture thereof with at least one of monosaccharides and oligosaccharides in a conventional manner. Method for producing fiber-containing dextrin.
JP63299308A 1988-10-07 1988-11-25 Preparation of dextrin containing food fiber Granted JPH02145169A (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP63299308A JPH02145169A (en) 1988-11-25 1988-11-25 Preparation of dextrin containing food fiber
EP89309269A EP0368451B1 (en) 1988-10-07 1989-09-12 Process for preparing dextrin containing dietary fiber
DE68914401T DE68914401T2 (en) 1988-10-07 1989-09-12 Process for the production of fibrous food products containing dextrin.
KR1019890013379A KR0135075B1 (en) 1988-10-07 1989-09-12 Preparation process of dextrin containing food fiber
US08/438,113 US5620873A (en) 1988-10-07 1995-05-08 Process for preparing dextrin containing food fiber

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP63299308A JPH02145169A (en) 1988-11-25 1988-11-25 Preparation of dextrin containing food fiber

Publications (2)

Publication Number Publication Date
JPH02145169A JPH02145169A (en) 1990-06-04
JPH0347831B2 true JPH0347831B2 (en) 1991-07-22

Family

ID=17870858

Family Applications (1)

Application Number Title Priority Date Filing Date
JP63299308A Granted JPH02145169A (en) 1988-10-07 1988-11-25 Preparation of dextrin containing food fiber

Country Status (1)

Country Link
JP (1) JPH02145169A (en)

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JPH082270B2 (en) * 1990-09-19 1996-01-17 松谷化学工業株式会社 Method for producing dextrin containing dietary fiber
JPH04173094A (en) * 1990-11-08 1992-06-19 Matsutani Kagaku Kogyo Kk Production of low calorie dextrin
US5236719A (en) * 1991-09-27 1993-08-17 Wm. Wrigley Jr. Company Chewing gum and other comestibles containing purified indigestible dextrin
JPH05178902A (en) * 1991-10-29 1993-07-20 Matsutani Kagaku Kogyo Kk Difficultly digestible dextrin
US5342631A (en) * 1992-12-29 1994-08-30 Wm. Wrigley Jr. Company Wax-free chewing gum including special oligosaccharide binders
JP2654529B2 (en) 1992-03-27 1997-09-17 大塚製薬株式会社 Health drink composition
JP3980851B2 (en) * 2001-08-30 2007-09-26 有限会社ゴトーコーポレーション Solid preparation, method for producing the same, and food
FR2831541B1 (en) * 2001-10-30 2005-08-19 Roquette Freres SOLUBLE HYDROGEN STARCH DERIVATIVES CONTAINING NON-DIGESTIBLE FOOD FIBERS
JP2005287454A (en) 2004-04-02 2005-10-20 Matsutani Chem Ind Ltd Food and beverage for imparting health function and method for imparting health function to food and beverage
JP4753588B2 (en) * 2005-01-28 2011-08-24 松谷化学工業株式会社 Method for producing starch degradation product and white dextrin
JP4570572B2 (en) * 2006-01-31 2010-10-27 ハウス食品株式会社 Qualitative method for reducing indigestible dextrin
KR100682453B1 (en) * 2006-05-19 2007-02-16 주식회사 뜨레봄 Method for manufacturing organic gain syrup and dextrin
JP2008099681A (en) * 2006-09-22 2008-05-01 Sanei Gen Ffi Inc Method for masking unfavorable taste of composition containing dietary fiber and/or dextrin
JP4989956B2 (en) 2006-12-11 2012-08-01 松谷化学工業株式会社 Powdered plant sterol ester preparation, method for producing the same, and food and drink containing the same
JP2007291136A (en) * 2007-07-31 2007-11-08 Matsutani Chem Ind Ltd Body fat regulator containing reduced hard-digestive dextrin
WO2013072638A2 (en) * 2011-11-18 2013-05-23 Roquette Freres Partially soluble dextrins of high molecular weight
JP6990548B2 (en) * 2017-09-26 2022-01-12 理研ビタミン株式会社 Bread quality improver

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4947547A (en) * 1972-09-11 1974-05-08
US3974032A (en) * 1973-03-05 1976-08-10 Cpc International Inc. Low D.E. starch hydrolysates of improved stability prepared by enzymatic hydrolysis of dextrins

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4947547A (en) * 1972-09-11 1974-05-08
US3974032A (en) * 1973-03-05 1976-08-10 Cpc International Inc. Low D.E. starch hydrolysates of improved stability prepared by enzymatic hydrolysis of dextrins

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