JPH0347318B2 - - Google Patents
Info
- Publication number
- JPH0347318B2 JPH0347318B2 JP60033504A JP3350485A JPH0347318B2 JP H0347318 B2 JPH0347318 B2 JP H0347318B2 JP 60033504 A JP60033504 A JP 60033504A JP 3350485 A JP3350485 A JP 3350485A JP H0347318 B2 JPH0347318 B2 JP H0347318B2
- Authority
- JP
- Japan
- Prior art keywords
- acid
- adipic acid
- tablet
- sodium bicarbonate
- carbonate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 52
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 26
- 239000001361 adipic acid Substances 0.000 claims description 26
- 235000011037 adipic acid Nutrition 0.000 claims description 26
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 13
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 13
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 12
- -1 chloroisocyanuric acid compound Chemical class 0.000 claims description 12
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 10
- 238000005187 foaming Methods 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 239000003599 detergent Substances 0.000 claims description 4
- 238000009472 formulation Methods 0.000 claims description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 18
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 9
- 239000001530 fumaric acid Substances 0.000 description 8
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 8
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Chemical class 0.000 description 6
- 239000000460 chlorine Substances 0.000 description 6
- 229910052801 chlorine Inorganic materials 0.000 description 6
- 235000015165 citric acid Nutrition 0.000 description 6
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 5
- 239000000314 lubricant Substances 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 239000011975 tartaric acid Substances 0.000 description 5
- 235000002906 tartaric acid Nutrition 0.000 description 5
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 4
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 4
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 4
- 239000004310 lactic acid Substances 0.000 description 4
- 235000014655 lactic acid Nutrition 0.000 description 4
- 239000001630 malic acid Substances 0.000 description 4
- 235000011090 malic acid Nutrition 0.000 description 4
- 150000007524 organic acids Chemical class 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- MSFGZHUJTJBYFA-UHFFFAOYSA-M sodium dichloroisocyanurate Chemical compound [Na+].ClN1C(=O)[N-]C(=O)N(Cl)C1=O MSFGZHUJTJBYFA-UHFFFAOYSA-M 0.000 description 4
- 239000001384 succinic acid Substances 0.000 description 4
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 3
- 239000004327 boric acid Substances 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
- 235000013373 food additive Nutrition 0.000 description 3
- 239000002778 food additive Substances 0.000 description 3
- 239000004570 mortar (masonry) Substances 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- ISAOUZVKYLHALD-UHFFFAOYSA-N 1-chloro-1,3,5-triazinane-2,4,6-trione Chemical compound ClN1C(=O)NC(=O)NC1=O ISAOUZVKYLHALD-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- CEJLBZWIKQJOAT-UHFFFAOYSA-N dichloroisocyanuric acid Chemical compound ClN1C(=O)NC(=O)N(Cl)C1=O CEJLBZWIKQJOAT-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 235000011087 fumaric acid Nutrition 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- YRIZYWQGELRKNT-UHFFFAOYSA-N 1,3,5-trichloro-1,3,5-triazinane-2,4,6-trione Chemical compound ClN1C(=O)N(Cl)C(=O)N(Cl)C1=O YRIZYWQGELRKNT-UHFFFAOYSA-N 0.000 description 1
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- 235000012501 ammonium carbonate Nutrition 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 238000012669 compression test Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000002973 irritant agent Substances 0.000 description 1
- 239000010446 mirabilite Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000011736 potassium bicarbonate Substances 0.000 description 1
- 229910000028 potassium bicarbonate Inorganic materials 0.000 description 1
- 235000015497 potassium bicarbonate Nutrition 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 235000011181 potassium carbonates Nutrition 0.000 description 1
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
- IFIDXBCRSWOUSB-UHFFFAOYSA-N potassium;1,3-dichloro-1,3,5-triazinane-2,4,6-trione Chemical compound [K+].ClN1C(=O)NC(=O)N(Cl)C1=O IFIDXBCRSWOUSB-UHFFFAOYSA-N 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- PYILKOIEIHHYGD-UHFFFAOYSA-M sodium;1,5-dichloro-4,6-dioxo-1,3,5-triazin-2-olate;dihydrate Chemical compound O.O.[Na+].[O-]C1=NC(=O)N(Cl)C(=O)N1Cl PYILKOIEIHHYGD-UHFFFAOYSA-M 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229950009390 symclosene Drugs 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Description
（産業上の利用分野）
この発明は、クロルイソシアヌル酸系化合物を
有効成分とする発泡性清浄剤の製法に関するもの
であり、本発明方法によつて製造された発泡性清
浄剤は、便所用、風呂水用あるいは入れ歯用等の
洗浄剤として有用である。
（従来の技術）
従来この種錠剤を製造するに当り、水中に投じ
た際に発泡しながら速やかに溶解させるために、
炭酸塩と酸化合物を併用することは広く知られて
おり、炭酸塩としては重炭酸ソーダ、炭酸ソー
ダ、重炭酸カリ、炭酸カリ、炭酸アンモニウム等
が用いられ、酸化合物としては酒石酸、クエン
酸、コハク酸、フマル酸、乳酸、リンゴ酸等の有
機酸、酸性燐酸、酸性芒硝等の無機化合物が使用
されている。
例えば、クロルイソシアヌル酸系化合物を有効
成分とし、これに炭酸塩と酸化合物を加えて打錠
成型する際に、特公昭46−40277号公報に記載の
発明は酸化合物としてクエン酸を用い、特開昭56
−161301号公報に記載の発明はクエン酸及び酒石
酸を用い、また特開昭56−163199号及び同56−
164110号公報に記載の発明には、酒石酸、クエン
酸、コハク酸、フマル酸、乳酸及びリンゴ酸を用
いることが開示されている。
（発明が解決しようとする問題点）
しかしながら、クロルイソシアヌル酸系化合物
に炭酸塩と酸化合物を配合して打錠成型するに当
り、酸化合物として前記の有機酸を用いた場合、
クエン酸、酒石酸、乳酸、リンゴ酸にあつては、
打錠成型物が臼杵に付着して打錠機からの排出が
困難であるため、ステアリン酸塩、硼酸等の滑沢
剤を併用しなければならず、一方フマル酸にあつ
ては臼杵に対する付着トラブルを回避しうるもの
の、配合状態においてクロルイソシアヌル酸系化
合物の分解を促進する傾向が認められ、塩素を含
有する刺激性のガスを発生するので実用に供し難
い。またコハク酸は打錠性、配合安定性及び溶解
性の面でほぼ満足しうる性能を与えるが、高価で
あるため量産に適さない。
（問題点を解決するための手段）
本発明者はこのような事情に鑑み克明な試験研
究を重ねた結果、クロルイソシアヌル酸系化合物
を含み、且つアジピン酸を５〜50重量％と該アジ
ピン酸に対して当量比で0.25〜3.0倍の重炭酸ソ
ーダまたは炭酸ソーダを含む配合物を均一に混合
して打錠することにより、打錠性、配合安定性及
び溶解性ならびに経済性に優れた発泡性清浄錠剤
を製造し得る方法を見い出したものである。
本発明方法において、良好な打錠性が得られる
理由としては、アジピン酸にはステアリン酸塩や
硼酸などの公知の滑沢剤を添加して打錠する際に
見られるような優れた滑沢性を有し、しかも滑沢
剤には見られない特有の圧縮成型性の両性質を兼
ね備えていることによるものと考えられる。
本発明において使用されるクロルイソシアヌル
酸系化合物としては、トリクロロイソシアヌル
酸、ジクロロイソシアヌル酸、ジクロロイソシア
ヌル酸ナトリウム及びその水和物、ジクロロイソ
シアヌル酸カリウム等が代表的なものである。
アジピン酸は工業用あるいは食添用のいずれで
も良いが、５〜50重量％の範囲で使用すべきであ
る。アジピン酸の配合量が少な過ぎると錠剤の溶
解速度が極度に低下するものであり、また多くな
り過ぎると錠剤中の活性塩素含有量が減少して、
所期の清浄効果を発揮し得ない。
またアジピン酸の粒径が32メツシユより大きい
ものになれば、錠剤を水中に投入した際、冷水に
あつてはこれが直ちに溶解せず水面に浮上する傾
向があるので、微粉砕化すべきである。
重炭酸ソーダ又は炭酸ソーダは、市販の粉末
状、顆粒状のいずれも好適であり、アジピン酸に
対して当量比で0.25ないし３倍の割合で使用すべ
きである。
アジピン酸に対する炭酸塩の添加量は、少な過
ぎると錠剤の発泡性が悪く、溶解に甚だ長時間を
要するものであり、逆にアジピン酸に対する重炭
酸ソーダ、炭酸ソーダの配合量が多くなり過ぎる
と、水中に投入した錠剤がブロツク状に崩壊して
水底に推積し、溶解速度が低下するのみならず局
部的に活性塩素濃度が高まり器壁等を損傷する虞
がある。
本発明方法の実施に当たつては、クロルイソシ
アヌル酸系化合物、アジピン酸及び炭酸塩からな
る組成物に少量の増量剤、PH調節剤、水軟化剤、
キレート剤、界面活性剤、香料等を添加すること
ができる。
以下実施例及び参考例によつて本発明方法を具
体的に説明する。
参考例 １
市販の有機酸を粉砕して100〜200メツシユの粒
度範囲の粉末状とし、これを平坦な塩ビ板に塗布
し、100cm2の底面積を有する0.7Kgの錘りを載置
し、この錘りが滑り始める角度を測定しそれぞれ
の滑性を比較した結果、フマル酸14°、アジピン
酸16°、コハク酸20°、酒石酸24°、クエン酸30°、
リンゴ酸33°、乳酸35°であり、アジピン酸の滑性
はフマル酸についで大きく、コハク酸より良好で
あつた。
参考例 ２
ジクロロイソシアヌル酸ナトリウム２水和物
（以下SDIC・2H2Oという）に粒度60〜100メツシ
ユの各種有機酸と食添用重炭酸ソーダを所定の割
合で配合し、その組成物10ｇを直径30mmのダイス
に採り、圧力1000Kg／cm2を加えて打錠試験を行つ
たところ、第１表に示したとおりの結果であり、
フマル酸とアジピン酸のみがいずれの配合比にお
いても打錠可能であつた。
(Industrial Application Field) The present invention relates to a method for producing a foaming detergent containing a chloroisocyanuric acid compound as an active ingredient, and the foaming detergent produced by the method of the present invention can be used for toilets, It is useful as a cleaning agent for bath water or dentures. (Prior art) Conventionally, in manufacturing this type of tablet, in order to foam and dissolve quickly when thrown into water,
It is widely known that carbonates and acid compounds are used together; carbonates include sodium bicarbonate, sodium carbonate, potassium bicarbonate, potassium carbonate, ammonium carbonate, etc., and acid compounds include tartaric acid, citric acid, and succinic acid. , organic acids such as fumaric acid, lactic acid, and malic acid, and inorganic compounds such as acidic phosphoric acid and acidic mirabilite. For example, the invention described in Japanese Patent Publication No. 46-40277 uses citric acid as the acid compound when compressing a chloroisocyanuric acid-based compound as an active ingredient and adding a carbonate and an acid compound to the tablet. 1976
The invention described in JP-A-161301 uses citric acid and tartaric acid, and also uses JP-A-56-163199 and JP-A-56-
The invention described in Publication No. 164110 discloses the use of tartaric acid, citric acid, succinic acid, fumaric acid, lactic acid, and malic acid. (Problems to be Solved by the Invention) However, when the above-mentioned organic acid is used as the acid compound when blending a carbonate and an acid compound with a chloroisocyanuric acid compound and molding the mixture into a tablet,
For citric acid, tartaric acid, lactic acid, and malic acid,
Since the tablet molded product adheres to the die and is difficult to discharge from the tablet press, a lubricant such as stearate or boric acid must be used in combination, while fumaric acid does not adhere to the die. Although this method can avoid problems, it is difficult to put it into practical use because it tends to accelerate the decomposition of the chloroisocyanuric acid compound in the blended state and generates irritating gas containing chlorine. Furthermore, although succinic acid provides almost satisfactory performance in terms of tabletability, formulation stability, and solubility, it is expensive and is not suitable for mass production. (Means for Solving the Problems) In view of the above circumstances, the present inventors have conducted extensive testing and research, and have found that the adipic acid containing a chloroisocyanuric acid compound and containing 5 to 50% by weight of adipic acid. By uniformly mixing and tableting a formulation containing 0.25 to 3.0 times the equivalent amount of sodium bicarbonate or soda carbonate, an effervescent detergent with excellent tabletting properties, formulation stability, solubility, and economic efficiency is produced. We have discovered a method for manufacturing tablets. The reason why good tableting properties can be obtained in the method of the present invention is that adipic acid has excellent lubricity, which is seen when tabletting is done by adding known lubricants such as stearate and boric acid. This is thought to be due to the fact that it has both properties, such as a unique compression moldability that is not found in lubricants. Typical chloroisocyanuric acid compounds used in the present invention include trichloroisocyanuric acid, dichloroisocyanuric acid, sodium dichloroisocyanurate and its hydrate, potassium dichloroisocyanurate, and the like. Adipic acid may be used for industrial purposes or as a food additive, but should be used in an amount of 5 to 50% by weight. If the amount of adipic acid is too small, the dissolution rate of the tablet will be extremely reduced, and if it is too large, the active chlorine content in the tablet will decrease.
The desired cleaning effect cannot be achieved. Furthermore, if the particle size of adipic acid is larger than 32 mesh, when the tablet is placed in water, it will not dissolve immediately in cold water and will tend to float to the surface of the water, so it should be pulverized. Sodium bicarbonate or soda carbonate, commercially available in powder or granule form, is suitable, and should be used in an equivalent ratio of 0.25 to 3 times that of adipic acid. If the amount of carbonate added to adipic acid is too small, the effervescence of the tablet will be poor and it will take an extremely long time to dissolve.On the other hand, if the amount of sodium bicarbonate or soda carbonate added to adipic acid is too large, Tablets placed in the water disintegrate into blocks and accumulate on the bottom of the water, which not only reduces the dissolution rate but also locally increases the concentration of active chlorine, which may damage the vessel walls. When carrying out the method of the present invention, a small amount of a filler, a PH regulator, a water softener, a chloroisocyanuric acid compound, adipic acid and a carbonate,
Chelating agents, surfactants, fragrances, etc. can be added. The method of the present invention will be specifically explained below using Examples and Reference Examples. Reference Example 1 A commercially available organic acid is crushed into a powder with a particle size range of 100 to 200 mesh, and this is applied to a flat PVC board, and a 0.7 kg weight with a base area of 100 cm 2 is placed on it. As a result of measuring the angle at which this weight starts to slide and comparing the lubricity of each, we found that fumaric acid was 14°, adipic acid was 16°, succinic acid was 20°, tartaric acid was 24°, citric acid was 30°,
Malic acid was 33° and lactic acid was 35°, and the slipperiness of adipic acid was the second highest after fumaric acid and better than succinic acid. Reference Example 2 Sodium dichloroisocyanurate dihydrate (hereinafter referred to as SDIC・2H 2 O) is blended with various organic acids with a particle size of 60 to 100 mesh and sodium bicarbonate for food additive in a predetermined ratio, and 10 g of the composition is mixed into a powder with a diameter of 30 mm. When a tablet compression test was performed by applying a pressure of 1000 kg/cm 2 to a die, the results were as shown in Table 1.
Only fumaric acid and adipic acid could be compressed into tablets at any blending ratio.
【表】
但し、表中○印は臼杵に対する付着がなく打錠
性が良い状態を示し、△印は臼杵に対する付着傾
向があり、排出抵抗はやや大きいが打錠が可能な
状態を示し、×印は臼杵に付着して打錠困難な状
態であることを示す。
参考例 ３
SDIC・2H2O20.7重量％とフマル酸を25重量％
と重炭酸ソーダをフマル酸に対して当量比１：
1.5の割合で配合した組成物を参考例２と同様の
条件で打錠し、その錠剤10ケを厚さ50μのポリエ
チレン袋に密封し、温度35℃、相対湿度80％の恒
温恒湿器に入れて１週間放置した結果、ポリエチ
レン袋内には塩素を含むガスが充満し、錠剤の活
性塩素含有量は初期の11.3％から9.5％に低下し
た。
実施例 １
SDIC・2H2Oに、60メツシユ以下の粒径に粉砕
したアジピン酸及び食添用重炭酸ソーダを所定の
割合で混合し、次いでこの組成物の10ｇを直径30
mmのダイスに採り、圧力1000Kg／cm2を加えて打錠
成型し、その打錠性（排出時の抵抗）、発泡性
（15℃の水１に錠剤１ケを投入し、静置状態で
調べた発泡時間）及び完全溶解（条件は発泡性と
同じ）に要する時間等を測定した。
この試験結果は、第２表に示したとおりであ
り、アジピン酸の配合下限量は組成物全量に対し
て５〜10重量％の範囲にあると推定され、また重
炭酸ソーダの当量比はアジピン酸に対して0.25〜
3.5の範囲が良好と認められた。[Table] However, in the table, the ○ mark indicates that there is no adhesion to the mortar and the tableting properties are good, the △ mark indicates that there is a tendency to stick to the mortar and the ejection resistance is somewhat large, but tabletting is possible, and × The mark indicates that the tablet is stuck to the mortar and tableting is difficult. Reference example 3 SDIC・2H2O20.7 % by weight and fumaric acid 25% by weight
and sodium bicarbonate to fumaric acid in an equivalent ratio of 1:
A composition blended at a ratio of 1.5 was tableted under the same conditions as in Reference Example 2, and the 10 tablets were sealed in a polyethylene bag with a thickness of 50μ, and placed in a constant temperature and humidity chamber at a temperature of 35°C and a relative humidity of 80%. After leaving the tablets in the polyethylene bag for a week, the polyethylene bag was filled with chlorine-containing gas, and the active chlorine content of the tablets dropped from 11.3% to 9.5%. Example 1 Adipic acid pulverized to a particle size of 60 mesh or less and sodium bicarbonate for food additive are mixed in a predetermined ratio with SDIC・2H 2 O, and then 10 g of this composition is mixed into a particle size of 30 mesh or less in diameter.
It was taken into a die of 1.0 mm in diameter and compressed into a tablet by applying a pressure of 1000 Kg/ cm2 , and the tableting properties (resistance during ejection) and foamability (1 tablet was put into 1 part of water at 15°C and left to stand still) The foaming time) and the time required for complete dissolution (under the same conditions as foaming properties) were measured. The test results are shown in Table 2, and it is estimated that the lower limit of adipic acid is in the range of 5 to 10% by weight based on the total amount of the composition, and the equivalent ratio of sodium bicarbonate to adipic acid is estimated to be in the range of 5 to 10% by weight based on the total amount of the composition. 0.25~
A range of 3.5 was recognized as good.
【表】【table】
【表】
(注) 当量比は、重炭酸ナトリウムをアジピン酸で除
した値を示す。
実施例 ２
実施例１と同様にして、SDIC・2H2O、アジピ
ン酸、重炭酸ソーダを配合して造つた10ｇの錠剤
10個を厚さ50μのポリエチレン袋に入れ、ヒート
シールしたのち温度35℃、相対湿度80％の恒温恒
湿器内に１ケ月間放置し安定性試験を行つた。
その結果は第３表に示したとおりであり、いず
れも錠剤中の活性塩素の経時変化は実質的に認め
られず、ガスの発生も全くなかつた。[Table] (Note) Equivalence ratio indicates the value obtained by dividing sodium bicarbonate by adipic acid.
Example 2 10 g tablet made by blending SDIC・2H 2 O, adipic acid, and sodium bicarbonate in the same manner as in Example 1.
Ten pieces were placed in a 50μ thick polyethylene bag, heat-sealed, and then left in a constant temperature and humidity chamber at a temperature of 35°C and a relative humidity of 80% for one month to conduct a stability test. The results are shown in Table 3, and in all cases, there was virtually no change in the active chlorine in the tablets over time, and no gas was generated.
【表】
(注) 当量比は重炭酸ソーダをアジピン酸
で除した値を示す。
実施例 ３
実施例１において、重炭酸ソーダの代わりに炭
酸ソーダを用いて同様の試験を行つた。その結果
は第４表に示したとおりであり、アジピン酸の配
合率が高くなるほど打錠性が良くなるが、５％以
下では排出抵抗が大きくなつて打錠困難であり、
また炭酸ソーダのアジピン酸に対する当量比は
0.25〜3.0が良好であると認められた。[Table] (Note) Equivalence ratio indicates the value obtained by dividing sodium bicarbonate by adipic acid.
Example 3 A similar test was conducted in Example 1 using soda carbonate instead of sodium bicarbonate. The results are shown in Table 4. The higher the blending ratio of adipic acid, the better the tableting properties are, but if it is less than 5%, the ejection resistance increases and tableting becomes difficult.
Also, the equivalent ratio of soda carbonate to adipic acid is
A value of 0.25 to 3.0 was considered good.
【表】【table】
【表】
(注) 当量比は、炭酸ソーダをアジピン酸で除した値
を示す。
（発明の効果）
本発明方法によれば、アジピン酸が打錠時に優
れた滑沢性と圧縮成型性を示すため、ステアリン
酸塩や硼酸などの滑沢剤を併用することなく打錠
成型しうるものであり、クロルイソシアヌル酸系
化合物とアジピン酸及び炭酸塩の配合時の安定性
が良好であつて、錠剤を長期に亘つて保存するこ
とができ、これを水中に投与したときにはアジピ
ン酸と重炭酸ソーダまたは炭酸ソーダが反応して
発泡し、錠剤を水中で移動させながら速やかに溶
解することができ、錠剤が水に溶けた際には、不
溶性物質として汚りの原因となるステアリン酸塩
や硼酸などの滑沢剤を一切使用していないので、
透明な清浄溶液を形成しうるものである。[Table] (Note) Equivalence ratio indicates the value obtained by dividing sodium carbonate by adipic acid.
(Effects of the Invention) According to the method of the present invention, since adipic acid exhibits excellent lubricity and compression moldability during tabletting, tabletting can be performed without using lubricants such as stearate or boric acid. The stability of the combination of the chloroisocyanuric acid compound, adipic acid, and carbonate is good, and the tablet can be stored for a long period of time. Sodium bicarbonate or sodium carbonate reacts and foams, allowing the tablet to move and dissolve quickly in water. Since we do not use any lubricants such as
It is capable of forming a clear cleaning solution.
Claims (1)
アジピン酸を５〜50重量％と該アジピン酸に対し
て当量比で0.25〜3.0倍の重炭酸ソーダまたは炭
酸ソーダを含む配合物を均一に混合して打錠する
ことを特徴とする発泡性清浄剤の製造方法。1. A formulation containing a chloroisocyanuric acid compound and 5 to 50% by weight of adipic acid and 0.25 to 3.0 times the equivalent ratio of sodium bicarbonate or soda carbonate to the adipic acid is uniformly mixed and tableted. A method for producing a foaming detergent, characterized by:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60033504A JPS61192800A (en) | 1985-02-20 | 1985-02-20 | Production of foamable cleanser |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60033504A JPS61192800A (en) | 1985-02-20 | 1985-02-20 | Production of foamable cleanser |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61192800A JPS61192800A (en) | 1986-08-27 |
| JPH0347318B2 true JPH0347318B2 (en) | 1991-07-18 |
Family
ID=12388377
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60033504A Granted JPS61192800A (en) | 1985-02-20 | 1985-02-20 | Production of foamable cleanser |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61192800A (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5230903A (en) * | 1987-11-18 | 1993-07-27 | Nissan Chemical Industries, Ltd. | Chloroisocyanurate composition |
| JP2005053853A (en) | 2003-08-06 | 2005-03-03 | Shikoku Chem Corp | Molded product of foamable chlorinated isocyanuric acid |
| JP2009203419A (en) * | 2008-02-29 | 2009-09-10 | Lion Chemical Kk | Sodium dichloroisocyanurate-containing tablet |
| JP5985547B2 (en) * | 2013-07-25 | 2016-09-06 | 四国化成工業株式会社 | Floating effervescent tablets |
| JP7391032B2 (en) * | 2018-10-19 | 2023-12-04 | 杏林製薬株式会社 | Effervescent tablets containing sodium dichloroisocyanurate |
| CN110150297B (en) * | 2019-05-09 | 2021-08-27 | 青岛职业技术学院 | Compound disinfection instant tablet and preparation method thereof |
| JP7082727B2 (en) * | 2020-05-12 | 2022-06-09 | レーアライフ株式会社 | Method for manufacturing a disinfectant solution for a space atomizer and a space atomizer |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56143226A (en) * | 1980-04-09 | 1981-11-07 | Kao Corp | Frothing composition |
| JPS5930879A (en) * | 1982-08-11 | 1984-02-18 | Nissan Chem Ind Ltd | Frothing molded product |
-
1985
- 1985-02-20 JP JP60033504A patent/JPS61192800A/en active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56143226A (en) * | 1980-04-09 | 1981-11-07 | Kao Corp | Frothing composition |
| JPS5930879A (en) * | 1982-08-11 | 1984-02-18 | Nissan Chem Ind Ltd | Frothing molded product |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS61192800A (en) | 1986-08-27 |
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