JP2009203419A - Sodium dichloroisocyanurate-containing tablet - Google Patents

Sodium dichloroisocyanurate-containing tablet Download PDF

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JP2009203419A
JP2009203419A JP2008049546A JP2008049546A JP2009203419A JP 2009203419 A JP2009203419 A JP 2009203419A JP 2008049546 A JP2008049546 A JP 2008049546A JP 2008049546 A JP2008049546 A JP 2008049546A JP 2009203419 A JP2009203419 A JP 2009203419A
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sodium dichloroisocyanurate
tablet
containing tablet
sodium
polyacrylic acid
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Shiro Oyama
史朗 大山
Kenzo Ueda
賢三 上田
Gengo Tanaka
源悟 田中
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LION CHEMICAL KK
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LION CHEMICAL KK
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a sodium dichloroisocyanurate-containing tablet having an effervescence duration, i.e., time duration between throw into water and completion of effervescence, adjustable and administerable to be long. <P>SOLUTION: The sodium dichloroisocyanurate-containing tablet is prepared by formulating sodium dichloroisocyanurate with an organic acid, a carbonate, a hydrogencarbonate, and a polyacrylic acid. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

本発明は、ジクロロイソシアヌル酸ナトリウム含有錠剤に関し、特に、水中で分解、分散(溶解)して、殺菌、洗浄、脱臭等の作用を奏する錠剤の発泡の終了までの時間を長い時間に亘って調整、管理することができるジクロロイソシアヌル酸ナトリウム含有錠剤に関するものである。   The present invention relates to a sodium dichloroisocyanurate-containing tablet, and in particular, adjusts the time until the end of foaming of a tablet that decomposes, disperses (dissolves) in water and exhibits sterilization, washing, deodorization and the like over a long period of time. It relates to a tablet containing sodium dichloroisocyanurate that can be controlled.

従来、ジクロロイソシアヌル酸ナトリウム含有錠剤は、家族全員が入浴した風呂水を翌日に炊き返して使用する風呂水の濁りや異臭を低減させる風呂水浄化剤やパイプ洗浄剤として広く利用されている(例えば、特許文献1〜2参照)。   Conventionally, tablets containing sodium dichloroisocyanurate have been widely used as bath water purifiers and pipe cleaning agents that reduce the turbidity and off-flavor of bath water used by recooking bath water bathed by the whole family the next day (for example, And Patent Documents 1 and 2).

ところで、これら風呂水浄化剤やパイプ洗浄剤は、水中で短時間に発泡(崩壊)が終了してしまうため、錠剤内の成分を長時間に亘って放出させ、その効果を長時間持続することができないという問題があった。
特公昭58−41111号公報 特公昭61−11929号公報
By the way, these bath water purifiers and pipe cleaners end foaming (disintegration) in a short time in water, so that the components in the tablet are released over a long period of time, and the effect is maintained for a long time. There was a problem that could not.
Japanese Patent Publication No.58-41111 Japanese Examined Patent Publication No. 61-11929

本発明は、上記従来のジクロロイソシアヌル酸ナトリウム含有錠剤の有する問題点に鑑み、錠剤を水中に投入してから発泡が終了するまでの時間を長い時間に亘って調整、管理することができるジクロロイソシアヌル酸ナトリウム含有錠剤を提供することを目的とする。   In view of the problems of the conventional sodium dichloroisocyanurate-containing tablets, the present invention is able to adjust and manage the time from when a tablet is put into water until foaming is completed over a long time. An object is to provide a sodium acid-containing tablet.

上記目的を達成するため、本発明のジクロロイソシアヌル酸ナトリウム含有錠剤は、ジクロロイソシアヌル酸ナトリウムに、有機酸、炭酸塩、炭酸水素塩及びポリアクリル酸を配合したことを特徴とする。   In order to achieve the above object, the sodium dichloroisocyanurate-containing tablet of the present invention is characterized in that an organic acid, carbonate, bicarbonate and polyacrylic acid are blended with sodium dichloroisocyanurate.

この場合において、ジクロロイソシアヌル酸ナトリウム35重量部に対して、ポリアクリル酸を1〜6重量部配合することができる。   In this case, 1 to 6 parts by weight of polyacrylic acid can be blended with 35 parts by weight of sodium dichloroisocyanurate.

本発明のジクロロイソシアヌル酸ナトリウム含有錠剤によれば、ジクロロイソシアヌル酸ナトリウムに、有機酸、炭酸塩、炭酸水素塩及びポリアクリル酸を配合することにより、特に、高吸水性高分子の一種であるポリアクリル酸を配合することによって、水中に投入してから発泡が終了するまでの時間を長い時間に亘って調整、管理することができ、必要に応じて、錠剤の成分を長時間に亘って放出するようにすることができるジクロロイソシアヌル酸ナトリウム含有錠剤を提供することができる。   According to the sodium dichloroisocyanurate-containing tablet of the present invention, by blending organic acid, carbonate, hydrogen carbonate and polyacrylic acid with sodium dichloroisocyanurate, in particular, polyisocyanate is a kind of superabsorbent polymer. By blending acrylic acid, it is possible to adjust and manage the time from foaming to the end of foaming for a long time, and release the tablet components for a long time if necessary. It is possible to provide a tablet containing sodium dichloroisocyanurate that can be made to do so.

また、ジクロロイソシアヌル酸ナトリウム35重量部に対して、ポリアクリル酸を1〜6重量部配合することにより、ポリアクリル酸の配合分量を変化させ錠剤の発泡終了時間を容易に調整、管理することができる   In addition, by blending 1 to 6 parts by weight of polyacrylic acid with respect to 35 parts by weight of sodium dichloroisocyanurate, it is possible to easily adjust and manage the foaming end time of the tablet by changing the blended amount of polyacrylic acid. it can

以下、本発明のジクロロイソシアヌル酸ナトリウム含有錠剤の実施の形態を具体例を挙げて説明する。   Hereinafter, embodiments of the sodium dichloroisocyanurate-containing tablet of the present invention will be described with specific examples.

本発明のジクロロイソシアヌル酸ナトリウム含有錠剤は、ジクロロイソシアヌル酸ナトリウムに、有機酸、炭酸塩、炭酸水素塩及びポリアクリル酸を配合するようにしたものである。   The sodium dichloroisocyanurate-containing tablet of the present invention is one in which an organic acid, carbonate, bicarbonate and polyacrylic acid are blended with sodium dichloroisocyanurate.

ここで、有機酸には、コハク酸、グルタル酸、アジピン酸、クエン酸等の有機酸の一種を単独で用いたり、また複数種を併用することができる。
また、炭酸塩には、炭酸ナトリウム、重炭酸ナトリウム、炭酸カリウム、重炭酸カリウム等の炭酸塩を単独で用いたり、また複数種を併用することができる。
また、炭酸水素塩には、炭酸水素ナトリウム、炭酸水素カリウム等の炭酸水素塩を単独で用いたり、また複数種を併用することができる。
Here, as the organic acid, one kind of organic acid such as succinic acid, glutaric acid, adipic acid or citric acid can be used alone, or a plurality of kinds can be used in combination.
Moreover, carbonates, such as sodium carbonate, sodium bicarbonate, potassium carbonate, potassium bicarbonate, etc. can be used independently, or multiple types can be used together.
Moreover, hydrogencarbonate, such as sodium hydrogencarbonate and potassium hydrogencarbonate, can be used alone, or a plurality of types can be used in combination.

そして、ジクロロイソシアヌル酸ナトリウム35重量部に対して、ポリアクリル酸を1〜6重量部配合することができる。
この場合、ポリアクリル酸の配合分量の増減に対して、炭酸塩や炭酸水素塩の配合分量の変動させることが好ましい。
And 1-6 weight part of polyacrylic acid can be mix | blended with respect to 35 weight part of sodium dichloroisocyanurate.
In this case, it is preferable to change the blending amount of carbonate or bicarbonate with respect to the increase or decrease of the blending amount of polyacrylic acid.

表1に、本発明のジクロロイソシアヌル酸ナトリウム含有錠剤のより具体的な実施例の各成分の配合量の割合を示す。   In Table 1, the ratio of the compounding quantity of each component of the more specific Example of the sodium dichloroisocyanurate containing tablet of this invention is shown.

Figure 2009203419
Figure 2009203419

表中、Aはジクロロイソシアヌル酸ナトリウム、Bはコハク酸、Cは炭酸ナトリウム、Dは炭酸水素ナトリウム、Eはポリアクリル酸を示す。   In the table, A is sodium dichloroisocyanurate, B is succinic acid, C is sodium carbonate, D is sodium hydrogen carbonate, and E is polyacrylic acid.

表2に、本発明のジクロロイソシアヌル酸ナトリウム含有錠剤の発泡終了時間の計測結果を示す。
試験方法は、2リットルのビーカーに1リットルの水を入れ、表1に記載の成分割合の粉体を打錠成型した錠剤(固形発泡剤)3gの発泡終了までの時間を計測した。
In Table 2, the measurement result of the foaming end time of the sodium dichloroisocyanurate-containing tablet of the present invention is shown.
In the test method, 1 liter of water was put into a 2 liter beaker, and the time until the end of foaming of 3 g of a tablet (solid foaming agent) obtained by tableting the powder having the component ratio shown in Table 1 was measured.

Figure 2009203419
Figure 2009203419

表2に示すとおり、ポリアクリル酸を配合成分全体の4%含有させた実施例1のジクロロイソシアヌル酸ナトリウム含有錠剤は、その発泡終了時間が55分となり、ポリアクリル酸を配合成分全体の1%含有させた実施例3のジクロロイソシアヌル酸ナトリウム含有錠剤や市販品(比較例)のものと比べて20倍以上となり、錠剤の成分を長時間に亘って放出するようにできることを確認した。   As shown in Table 2, the sodium dichloroisocyanurate-containing tablet of Example 1 containing 4% of polyacrylic acid in the total blending component had a foaming end time of 55 minutes, and polyacrylic acid was 1% of the total blending component. Compared to the sodium dichloroisocyanurate-containing tablet of Example 3 and the commercially available product (Comparative Example), it was confirmed that the tablet components could be released over a long period of time.

また、ポリアクリル酸を配合成分全体の1%含有させた実施例3のジクロロイソシアヌル酸ナトリウム含有錠剤は、その発泡終了時間が3分30秒となり、市販品(比較例)のものと比べて約1.35倍となった。
このように、発泡終了時間は、ポリアクリル酸の配合成分量に比例して変化し、ポリアクリル酸の配合成分量を変更させることによって、ジクロロイソシアヌル酸ナトリウム含有錠剤の発泡終了時間を容易に調整、管理することができることを確認した。
In addition, the sodium dichloroisocyanurate-containing tablet of Example 3 containing 1% of the total blending component of polyacrylic acid had an end-of-foaming time of 3 minutes and 30 seconds, which was approximately the same as that of a commercially available product (Comparative Example). 1.35 times.
As described above, the foaming end time changes in proportion to the amount of the polyacrylic acid compounding component, and the foaming end time of the sodium dichloroisocyanurate-containing tablet can be easily adjusted by changing the amount of the polyacrylic acid compounding component. , Confirmed that can be managed.

以上、本発明のジクロロイソシアヌル酸ナトリウム含有錠剤について、その実施例に基づいて説明したが、本発明は上記実施例に記載した構成に限定されるものではなく、その趣旨を逸脱しない範囲において適宜その構成を変更することができるものである。   As described above, the sodium dichloroisocyanurate-containing tablet of the present invention has been described based on the examples thereof, but the present invention is not limited to the configurations described in the above examples, and may be appropriately selected within the scope of the invention. The configuration can be changed.

本発明のジクロロイソシアヌル酸ナトリウム含有錠剤は、錠剤を水中に投入してから発泡が終了するまでの時間を長い時間に亘って調整、管理することができるという特性を有していることから、風呂水浄化剤やパイプ洗浄剤の用途に好適に用いることができる。   The sodium dichloroisocyanurate-containing tablet of the present invention has a characteristic that the time from when the tablet is put into water to when foaming is completed can be adjusted and managed over a long period of time. It can be suitably used for water purification agents and pipe cleaning agents.

Claims (2)

ジクロロイソシアヌル酸ナトリウムに、有機酸、炭酸塩、炭酸水素塩及びポリアクリル酸を配合したことを特徴とするジクロロイソシアヌル酸ナトリウム含有錠剤。   A sodium dichloroisocyanurate-containing tablet comprising sodium dichloroisocyanurate mixed with an organic acid, carbonate, hydrogen carbonate and polyacrylic acid. ジクロロイソシアヌル酸ナトリウム35重量部に対して、ポリアクリル酸を1〜6重量部配合したことを特徴とする請求項1記載のジクロロイソシアヌル酸ナトリウム含有錠剤。   The sodium dichloroisocyanurate-containing tablet according to claim 1, wherein 1 to 6 parts by weight of polyacrylic acid is blended with 35 parts by weight of sodium dichloroisocyanurate.
JP2008049546A 2008-02-29 2008-02-29 Sodium dichloroisocyanurate-containing tablet Pending JP2009203419A (en)

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5989623A (en) * 1982-10-12 1984-05-23 リチヤードソン−ヴイツクス リミテツド Sterilizing tablet composition and tablet
JPS61192800A (en) * 1985-02-20 1986-08-27 四国化成工業株式会社 Production of foamable cleanser
JPS6253919A (en) * 1985-05-30 1987-03-09 Showa Yakuhin Kako Kk Release-controlling drug
JPH11511486A (en) * 1996-03-11 1999-10-05 トライ―リンク アンリミティッド リミテッド、ドゥーイング ビジネス アズ サウスランド リミテッド Disinfecting effervescent tablet composition
JP2002537410A (en) * 1998-08-02 2002-11-05 ザ ビー.エフ.グッドリッチ カンパニー Controlled release polyacrylic acid granules and process for producing the same
JP2003246998A (en) * 2002-02-26 2003-09-05 Daiichi Shoji Kk Foaming detergent
JP2003336098A (en) * 2002-05-22 2003-11-28 Shikoku Chem Corp Foaming composition
JP2007077202A (en) * 2005-09-12 2007-03-29 Shikoku Chem Corp Colored oxidizing agent composition

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5989623A (en) * 1982-10-12 1984-05-23 リチヤードソン−ヴイツクス リミテツド Sterilizing tablet composition and tablet
JPS61192800A (en) * 1985-02-20 1986-08-27 四国化成工業株式会社 Production of foamable cleanser
JPS6253919A (en) * 1985-05-30 1987-03-09 Showa Yakuhin Kako Kk Release-controlling drug
JPH11511486A (en) * 1996-03-11 1999-10-05 トライ―リンク アンリミティッド リミテッド、ドゥーイング ビジネス アズ サウスランド リミテッド Disinfecting effervescent tablet composition
JP2002537410A (en) * 1998-08-02 2002-11-05 ザ ビー.エフ.グッドリッチ カンパニー Controlled release polyacrylic acid granules and process for producing the same
JP2003246998A (en) * 2002-02-26 2003-09-05 Daiichi Shoji Kk Foaming detergent
JP2003336098A (en) * 2002-05-22 2003-11-28 Shikoku Chem Corp Foaming composition
JP2007077202A (en) * 2005-09-12 2007-03-29 Shikoku Chem Corp Colored oxidizing agent composition

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