JPH0335273B2 - - Google Patents

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Publication number
JPH0335273B2
JPH0335273B2 JP61297743A JP29774386A JPH0335273B2 JP H0335273 B2 JPH0335273 B2 JP H0335273B2 JP 61297743 A JP61297743 A JP 61297743A JP 29774386 A JP29774386 A JP 29774386A JP H0335273 B2 JPH0335273 B2 JP H0335273B2
Authority
JP
Japan
Prior art keywords
cement
film
forming material
hardened
hardened cement
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP61297743A
Other languages
Japanese (ja)
Other versions
JPS63151692A (en
Inventor
Shoichi Nakano
Kyoshi Kuboyama
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Materials Corp
Original Assignee
Mitsubishi Materials Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Materials Corp filed Critical Mitsubishi Materials Corp
Priority to JP29774386A priority Critical patent/JPS63151692A/en
Publication of JPS63151692A publication Critical patent/JPS63151692A/en
Publication of JPH0335273B2 publication Critical patent/JPH0335273B2/ja
Granted legal-status Critical Current

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Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は硬化したコンクリート、モルタル、セ
メントペーストの如きセメント硬化体の表面仕上
方法に関するもので、さらに詳しくはセメント硬
化体表面に被膜を形成させる新規な方法に関する
ものである。
[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a method for finishing the surface of a hardened cement body such as hardened concrete, mortar, or cement paste, and more specifically relates to a method for forming a film on the surface of a hardened cement body. It concerns a novel method.

〔従来の技術〕[Conventional technology]

セメント硬化体は表面を処理しないで用いる
と、化学物質による硬化体自体の腐食、空気中の
炭酸ガス等の作用による中性化、あるいは海水等
の塩分の作用による鉄筋腐食のための亀裂の発生
等により、劣化が早くなる。
If hardened cement is used without surface treatment, cracks may occur due to corrosion of the hardened material itself due to chemical substances, neutralization due to the action of carbon dioxide in the air, or corrosion of reinforcing steel due to the action of salt such as seawater. etc., the deterioration will be accelerated.

このため、セメント硬化体の表面に被膜を形成
し、化学物質、炭酸ガス、塩分、水分等の進入を
防止するための表面仕上げを施しており、表面仕
上方法としては一般に無機系または有機系材料を
塗布または接着する方法がある。
For this reason, a film is formed on the surface of the hardened cement to provide a surface finish to prevent the ingress of chemicals, carbon dioxide, salt, moisture, etc. Generally, inorganic or organic materials are used to finish the surface. There is a method of applying or gluing.

〔発明が解決しようとする手段〕[Means to be solved by the invention]

しかし、従来の方法による被膜は、セメント硬
化体の乾燥収縮、あるいはセメント硬化体との熱
膨張率の違い等により剥れることがあり、その役
目を十分には果していない。
However, the coating formed by the conventional method may peel off due to drying shrinkage of the hardened cement product or a difference in coefficient of thermal expansion from the hardened cement product, and thus does not fulfill its role satisfactorily.

〔問題点を解決するための手段〕[Means for solving problems]

上記の問題点を解決するために、本発明はセメ
ント硬化体成形用型枠の該セメント硬化体の表面
仕上げを要する面を成形する内面に、有機高分子
組成物からなりセメントペーストが進入可能な空
隙を有する被膜形成材を展着し、該型枠にセメン
ト混合物を打設し、該セメント混合物が固化した
のち脱型し養生して硬化させた後、該セメント硬
化体の表面に露出している該被膜形成材を加熱溶
融後冷却固化して該セメント硬化体の表面に被膜
を形成させることを特徴とするセメント硬化体の
表面仕上方法を提供するものである。
In order to solve the above-mentioned problems, the present invention provides an inner surface of a formwork for molding a hardened cement product, which is made of an organic polymer composition and into which a cement paste can enter. A film-forming material having voids is spread, a cement mixture is poured into the mold, and after the cement mixture has solidified, it is removed from the mold, cured, and then exposed on the surface of the hardened cement body. The present invention provides a method for finishing the surface of a hardened cement body, which comprises heating and melting the film-forming material and then cooling and solidifying it to form a film on the surface of the hardened cement body.

〔作用〕[Effect]

本発明の作用を図面を用いて説明する。 The operation of the present invention will be explained using the drawings.

第1図は本発明の方法における被膜の形成過程
を示す模式断面図で、1はセメント硬化体成形用
型枠、2は被膜形成材、3はセメント硬化体、4
は被膜である。
FIG. 1 is a schematic cross-sectional view showing the process of forming a film in the method of the present invention, in which 1 is a mold for forming a hardened cement product, 2 is a film forming material, 3 is a hardened cement product, and 4 is a mold for forming a hardened cement product.
is a film.

型枠1の内面に、有機高分子組成物からなりセ
メントペーストが進入可能な空隙を有する被膜形
成材2を展着し(第1図a)、この型枠内にセメ
ント混合物を打設すると、セメント混合物中のセ
メントペーストの一部は、被膜形成材2のセメン
ト混合物に接する面からセメントペーストが進入
可能な空隙に進入し、セメント混合物が固化した
のち脱型し養生して硬化させると、被膜形成材2
はセメントペーストが進入した部分によつてセメ
ント硬化体3の表層に固着される(第1図b)。
A film-forming material 2 made of an organic polymer composition and having voids into which cement paste can enter is spread on the inner surface of the formwork 1 (FIG. 1a), and a cement mixture is poured into the formwork. A part of the cement paste in the cement mixture enters into the gap where the cement paste can enter from the surface of the film forming material 2 that is in contact with the cement mixture, and after the cement mixture is solidified, it is removed from the mold and cured to form a film. Forming material 2
is fixed to the surface layer of the hardened cement body 3 by the portion into which the cement paste has entered (FIG. 1b).

この状態の被膜形成材2を加熱すると、被膜形
成材2は溶融してセメント硬化体3の表面を覆
い、冷却後固化して被膜4を形成する。
When the film-forming material 2 in this state is heated, the film-forming material 2 melts and covers the surface of the hardened cement body 3, and solidifies after cooling to form the film 4.

被膜形成材2は、セメント硬化体3の表面仕上
げを要する面を成形する型枠1の内面に展着され
る。
The film-forming material 2 is spread on the inner surface of a mold 1 for forming the surface of the hardened cement body 3 that requires surface finishing.

被膜形成材は、加熱により溶融しセメント硬化
体の表面を覆つて被膜を形成し得る有機高分子組
成物を素材とし、かつセメント混合物中のセメン
トペーストが進入可能な空隙を有する形状のもの
であるならば特に限定されるものではないが、素
材の溶融温度の高いものは高い加熱温度を必要と
し、セメント硬化体に温度上昇による亀裂発生や
劣化等の悪影響を与えるので、溶融温度の低いも
のが望ましく、ポリエチレン、ポリプロピレン等
が好適であり、これ等を混合して使用してもよ
い。また、形状は、織布、不織布、人工皮革、合
成皮革、連続気泡を有する発泡体(所謂海綿構
造)等をとり得るが、織布、不織布、人工皮革、
合成皮革は入手およびとりあつかいが容易で好適
である。
The film forming material is made of an organic polymer composition that can be melted by heating to form a film covering the surface of the hardened cement body, and has a shape that has voids into which the cement paste in the cement mixture can enter. If so, there are no particular restrictions, but materials with a high melting temperature require high heating temperatures, which can have an adverse effect on the hardened cement such as cracking and deterioration due to temperature rise, so materials with a low melting temperature are recommended. Desirably, polyethylene, polypropylene, etc. are suitable, and a mixture of these may be used. In addition, the shape can be woven fabric, non-woven fabric, artificial leather, synthetic leather, foam having open cells (so-called sponge structure), etc., but woven fabric, non-woven fabric, artificial leather,
Synthetic leather is suitable because it is easy to obtain and handle.

被膜形成材のセメント硬化体との付着を良く
し、また被膜形成材の型枠に接した面までセメン
トペーストが進入して、被膜形成材の溶融の妨げ
とならないようにするため、被膜形成材をセメン
ト硬化体側を粗に、型枠側を密にした構成のもの
を用いることもできる。
In order to improve the adhesion of the film-forming material to the hardened cement, and to prevent the cement paste from entering the surface of the film-forming material in contact with the formwork and interfering with the melting of the film-forming material, the film-forming material is It is also possible to use a structure in which the hardened cement body side is coarse and the formwork side is dense.

被膜形成材の型枠への展着は、底面への展着で
あれば底面に載置しただけでもよく、適度の水分
を型枠表面あるいは被膜形成材の型枠への展着面
に与えることにより貼付けることができる。型枠
側面への展着、あるいは底面へある程度の強さで
展着する必要がある場合は接着剤で接着すること
ができる。接着剤としては加熱溶融時に被膜形成
材とともに溶融し冷却後固化するものが使用さ
れ、溶融温度が低く加熱により炭化しない、例え
ばポリビニルアルコール水溶液の使用が適当であ
る。
When spreading the film-forming material onto the formwork, if it is being spread on the bottom surface, it is sufficient to simply place it on the bottom surface, and apply appropriate moisture to the surface of the formwork or the surface where the film-forming material is spread onto the formwork. It can be pasted by If it is necessary to spread it to the side of the formwork or to the bottom of the formwork with a certain degree of strength, it can be adhered with adhesive. The adhesive to be used is one that melts together with the film-forming material when heated and solidified after cooling. For example, an aqueous solution of polyvinyl alcohol, which has a low melting temperature and does not carbonize when heated, is suitable.

セメント硬化体の表面に露出している被膜形成
材の加熱溶融の方法としては、加熱炉、赤外線照
射、高周波加熱、熱風吹付け等による方法が使用
されるが、赤外線照射、高周波加熱等の、加熱に
よるセメント硬化体の温度上昇が小さく、急激な
熱変化を与えない方法が適当である。
Methods for heating and melting the film-forming material exposed on the surface of the hardened cement body include methods using a heating furnace, infrared irradiation, high-frequency heating, hot air blowing, etc. A method that causes a small temperature rise in the hardened cement body due to heating and does not cause sudden thermal changes is suitable.

また、加熱溶融前に被膜形成材の表面に顔料を
散布、または顔料と水との混合物を塗布し、加熱
溶融することにより被膜に着色することも可能で
ある。
It is also possible to color the film by spraying a pigment or applying a mixture of a pigment and water on the surface of the film-forming material before heating and melting, and then heating and melting the mixture.

本発明の表面仕上方法が適用されるセンメト硬
化体はポルトランドセメント、高炉セメント、シ
リカセメント、フライアツシユセメント等により
作製可能で、鉄筋、補強繊維等の補強材で補強さ
れていても、補強されていなくてもよい。
The cement hardened body to which the surface finishing method of the present invention is applied can be made from Portland cement, blast furnace cement, silica cement, fly ash cement, etc., and may or may not be reinforced with reinforcing materials such as reinforcing bars or reinforcing fibers. You don't have to.

〔実施例〕〔Example〕

本発明を実施例によりさらに詳述する。 The present invention will be explained in further detail with reference to Examples.

実施例に用いた材料は次の通りである。 The materials used in the examples are as follows.

コンクリートの配合 普通ポルトランドセメント 286Kg/m3 水 186 〃 細骨材 894 〃 粗骨材 917 〃 AE減水剤 0.72 〃 モルタルの配合 普通ポルトランドセメント 519Kg/m3 水 241 〃 細骨材 1557 〃 不織布 素材 ポリプロピレン 厚さ 1mm 実施例 1 (試験体1) 縦500mm、横500mm、高さ100mmの型枠内の底面
に、縦500mm、横500mmの不織布を載置し、この型
枠内にコンクリートを打設し、20℃の恒温室で24
時間養生後脱型、さらに20℃の恒温室で28日間養
生した。
Concrete mix Ordinary Portland cement 286Kg/m 3 Water 186 〃 Fine aggregate 894 〃 Coarse aggregate 917 〃 AE water reducer 0.72 〃 Mortar mix Ordinary Portland cement 519Kg/m 3 Water 241 〃 Fine aggregate 1557 〃 Non-woven material Polypropylene thickness Example 1 (Test specimen 1) A non-woven fabric measuring 500 mm long and 500 mm wide was placed on the bottom of a formwork measuring 500 mm long, 500 mm wide and 100 mm high, and concrete was poured into this formwork. 24 in a constant temperature room at 20℃
After curing for an hour, the mold was removed and further cured for 28 days in a constant temperature room at 20°C.

養生が終了したコンクリート表面に露出してい
る不織布を、赤外線加熱装置で加熱して溶融した
のち放冷して固化させ、コンクリートの表面に被
膜を形成させた。
The nonwoven fabric exposed on the concrete surface after curing was heated with an infrared heating device to melt it, and then allowed to cool and solidify to form a film on the concrete surface.

(試験体2) 縦500mm、横100mm、高さ500mmの鉄製型枠内の
一側面に縦500mm、横500mmの不織布を接着した。
接着に際しては、型枠面にポリビニルアルコール
水溶液を薄く塗布した。不織布が接着したのちコ
ンクリートを打設した。打設したコンクリートは
試験体1と同様の方法で処理した。
(Test specimen 2) A nonwoven fabric measuring 500 mm long and 500 mm wide was adhered to one side of an iron formwork measuring 500 mm long, 100 mm wide, and 500 mm high.
For adhesion, a thin layer of polyvinyl alcohol aqueous solution was applied to the surface of the mold. After the nonwoven fabric was bonded, concrete was poured. The poured concrete was treated in the same manner as Test Specimen 1.

試験体1および2は、加熱溶融した表面は共に
円滑に仕上つた。また、コンクリートよりコアー
を採取して仕上げ面を実体顕微鏡で観察した結果
も、共に表面は円滑で被膜が完全に形成され、コ
ンクリートと被膜の固着も完全であつた。
Both test specimens 1 and 2 had a smooth surface after being heated and melted. Furthermore, when cores were taken from the concrete and the finished surfaces were observed using a stereomicroscope, the results showed that the surfaces were smooth, the coating was completely formed, and the adhesion between the concrete and the coating was perfect.

実施例 2 透水試験用および吸水試験用供試体を成形し、
透水試験および吸水試験を行つた。
Example 2 Molding specimens for water permeability test and water absorption test,
A water permeability test and a water absorption test were conducted.

供試体作製用型枠は、透水試験用は直径150mm、
高さ40mmのものを用い、内側底面に不織布を載置
し、吸水試験用型枠は縦160mm、横40mm、高さ40
mmのものを用い、内側の底面、両端面および両側
面に不織布をポリビニルアルコール水溶液を薄く
塗布して接着した。
The formwork for making the specimen is 150mm in diameter for water permeability testing.
A mold with a height of 40 mm was used, and a non-woven fabric was placed on the inside bottom, and the formwork for the water absorption test was 160 mm long, 40 mm wide, and 40 mm high.
mm, and a nonwoven fabric was adhered to the inner bottom surface, both end surfaces, and both sides by applying a thin layer of polyvinyl alcohol aqueous solution.

透水試験用供試体および吸水試験用供試体は、
共にモルタルをテーブルバイブレータを用いて2
層詰めとし、養生および不織布の加熱溶融方法は
実施例1と同様に行つた。
The specimens for water permeability test and water absorption test are:
Both mortar using table vibrator 2
The method of curing and heating and melting the nonwoven fabric was performed in the same manner as in Example 1.

JIS A 1404(建築用セメント防水剤の試験方
法)により透水試験および吸水試験を行つた。透
水試験における試験水圧は3Kg/cm2、試験時間は
1時間とし、吸水試験における試験日数は7日間
とした。
A water permeability test and a water absorption test were conducted in accordance with JIS A 1404 (test method for cement waterproofing agents for construction). The test water pressure in the water permeability test was 3 Kg/cm 2 , the test time was 1 hour, and the number of test days in the water absorption test was 7 days.

試験結果を、不織布を用いなかつた外は実施例
と同様にした比較例と共に第1表に示す。
The test results are shown in Table 1 together with a comparative example that was the same as the example except that no nonwoven fabric was used.

第1表 透水量(g) 吸水量(g) 実施例 0.1 0.2 比較例 19.7 29.6 本発明の方法による被膜は十分な防水生を示し
た。
Table 1 Water permeability (g) Water absorption (g) Example 0.1 0.2 Comparative example 19.7 29.6 The coating produced by the method of the present invention showed sufficient waterproofness.

実施例 3 縦400mm、横100mm、高さ100mmの型枠内の底面
に不織布を載置してコンクリートを打設し、養生
および不織布の加熱溶融は実施例1と同様に行つ
た。
Example 3 A nonwoven fabric was placed on the bottom of a formwork measuring 400 mm in length, 100 mm in width, and 100 mm in height, and concrete was poured, and curing and heating and melting of the nonwoven fabric were performed in the same manner as in Example 1.

得られた供試体は、CO2濃度10容量%の試験槽
を用いて中性化促進試験を6ケ月間行い、試験終
了後、試験体を切断し、切断面にフエノールフタ
レイン1%アルコール溶液を噴霧し、赤変しない
部分の表面からの距離を測定し中性化深さとし
た。
The obtained specimen was subjected to an accelerated neutralization test for 6 months using a test tank with a CO 2 concentration of 10% by volume. After the test, the specimen was cut and a 1% alcohol solution of phenolphthalein was applied to the cut surface. The distance from the surface of the part that did not turn red was measured and determined as the neutralization depth.

測定結果を、不織布を用いなかつたほかは実施
例と同様にした比較例と共に第2表に示す。
The measurement results are shown in Table 2 together with a comparative example that was the same as the example except that no nonwoven fabric was used.

第2表 中性化深さ(mm) 平均 最大 最小 実施例 0.0 0.0 0.0 比較例 11.1 18.0 4.5 実施例においては全く中性化せず、本発明の方
法による被膜は通気性がないことを示した。
Table 2 Carbonation depth (mm) Average Maximum Minimum Example 0.0 0.0 0.0 Comparative example 11.1 18.0 4.5 In the example, there was no neutralization at all, indicating that the coating formed by the method of the present invention was not breathable. .

〔発明の効果〕〔Effect of the invention〕

本発明の方法により、セメント硬化体と一体に
なつて形成されているので剥離の恐れがなく、十
分な防水性を有すると共に通気性がないので、セ
メント硬化体の化学物質による腐食、炭酸ガスに
よる中性化、海水の塩分の作用による鉄筋腐食の
ための亀裂等による劣化を防ぐことができる被膜
を得ることができた。
By the method of the present invention, since it is formed integrally with the cement hardened body, there is no risk of peeling, and it has sufficient waterproofness and has no air permeability, so We were able to obtain a coating that can prevent deterioration due to carbonation and cracking due to corrosion of reinforcing steel due to the action of salt in seawater.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明の方法における被膜の形成過程
を示す模式断面図である。 1……型枠、2……被膜形成材、3……セメン
ト硬化体、4……被膜。
FIG. 1 is a schematic cross-sectional view showing the process of forming a film in the method of the present invention. 1... Formwork, 2... Film forming material, 3... Cement hardened body, 4... Film.

Claims (1)

【特許請求の範囲】 1 セメント硬化体成形用型枠の該セメント硬化
体の表面仕上げを要する面を成形する内面に、熱
可塑性有機高分子組成物からなりセメントペース
トが進入可能な空隙を有する被膜形成材を展着
し、該型枠内にセメント混合物を打設し、該セメ
ント混合物が固化したのち脱型し養生して硬化さ
せた後、該セメント硬化体の表面に露出している
該被膜形成材を加熱溶融後冷却固化して、該セメ
ント硬化体の表面に被膜を形成させることを特徴
とするセメント硬化体の表面仕上方法。 2 被膜形成材が織布、不織布、人工皮革あるい
は合成皮革であることを特徴とする特許請求の範
囲第1項に記載のセメント硬化体の表面仕上方
法。
[Scope of Claims] 1. A coating made of a thermoplastic organic polymer composition and having voids into which cement paste can enter, on the inner surface of a formwork for molding a hardened cement product, which forms the surface of the hardened cement product that requires surface finishing. The film exposed on the surface of the hardened cement body after spreading the forming material and pouring the cement mixture into the mold, and after the cement mixture has solidified, is removed from the mold and cured to harden. A method for finishing the surface of a hardened cement body, which comprises heating and melting a forming material and then cooling and solidifying it to form a film on the surface of the hardened cement body. 2. The method for finishing the surface of a cured cement body according to claim 1, wherein the film-forming material is a woven fabric, a non-woven fabric, artificial leather, or synthetic leather.
JP29774386A 1986-12-16 1986-12-16 Surface finishment for cement set body Granted JPS63151692A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP29774386A JPS63151692A (en) 1986-12-16 1986-12-16 Surface finishment for cement set body

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP29774386A JPS63151692A (en) 1986-12-16 1986-12-16 Surface finishment for cement set body

Publications (2)

Publication Number Publication Date
JPS63151692A JPS63151692A (en) 1988-06-24
JPH0335273B2 true JPH0335273B2 (en) 1991-05-27

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
JP29774386A Granted JPS63151692A (en) 1986-12-16 1986-12-16 Surface finishment for cement set body

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Country Link
JP (1) JPS63151692A (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2696115B2 (en) * 1988-08-08 1998-01-14 株式会社大林組 Fiber-reinforced cellular gypsum cement board and method for producing the same
JPH03183673A (en) * 1989-12-11 1991-08-09 Misawa Homes Co Ltd Lightweight cellular concrete molded product and production thereof
JP2001164665A (en) * 1999-12-09 2001-06-19 Shizuoka Rekisei Kogyo Kk Waterproofing construction method for concrete surface
JP2001164666A (en) * 1999-12-10 2001-06-19 Shizuoka Rekisei Kogyo Kk Waterproofing construction method for concrete surface

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5860682A (en) * 1981-10-06 1983-04-11 凸版印刷株式会社 Dressing inorganic board and manufacture

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5860682A (en) * 1981-10-06 1983-04-11 凸版印刷株式会社 Dressing inorganic board and manufacture

Also Published As

Publication number Publication date
JPS63151692A (en) 1988-06-24

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