JPH03287817A - Separable composite fiber - Google Patents

Separable composite fiber

Info

Publication number
JPH03287817A
JPH03287817A JP2148416A JP14841690A JPH03287817A JP H03287817 A JPH03287817 A JP H03287817A JP 2148416 A JP2148416 A JP 2148416A JP 14841690 A JP14841690 A JP 14841690A JP H03287817 A JPH03287817 A JP H03287817A
Authority
JP
Japan
Prior art keywords
branch
fan
cross
fiber
peripheral edge
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2148416A
Other languages
Japanese (ja)
Inventor
Keum-Kon Kim
キム,ケウム―コン
Chi-Hyung Kim
キム,チーヒュン
Joo-Chul Park
パーク,ジョー―チュル
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hyosung T&C Co Ltd
Original Assignee
Hyosung T&C Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hyosung T&C Co Ltd filed Critical Hyosung T&C Co Ltd
Publication of JPH03287817A publication Critical patent/JPH03287817A/en
Pending legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/12Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/28Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
    • D01D5/30Conjugate filaments; Spinnerette packs therefor
    • D01D5/36Matrix structure; Spinnerette packs therefor
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/28Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
    • D01D5/30Conjugate filaments; Spinnerette packs therefor
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/14Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Multicomponent Fibers (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)

Abstract

PURPOSE: To obtain a divisible conjugate fiber having excellent dyeability, etc., and giving a high-density knitted and woven cloth or artificial leather of high quality by constituting a central part in a cross section and a branch portion extending from the central part to peripheral edge part as a polyester and a fan-shaped part between the branch portions as a polyamide. CONSTITUTION: This divisible conjugate fiber in which a central portion A1 in a cross section and branch portions A2 extending from the central portion A1 to a peripheral edge is composed of a polyester and a fan-shaped portion B between the branch portions A2 is composed of a polyamide and between the branch portions A2 and the fan-shaped portion B has a curved face, and a total area of the fan-shaped portion occupies 60-80% of a cross sectional area, and a ratio of a diameter (d) of the central portion A1 to a diameter D of the cross sectional area: (d/D) is (1/10)-(1/5) and a ratio of a maximum breadth (b) of the branch portion A2 to a breadth (a) of the branch portion of the peripheral edge: (b/a) is (4/3)-2, and excellent in spinnability and drawing operability and has high separating degree is obtained by subjecting a polyester and a polyamide to conjugate spinning.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 この発明は、その横断面の中心から外周縁部に向って延
びる枝部と、上記中心に設けられた小内部とを第1繊維
形成物質であるポリエステルにて構成しかつ互いに隣り
合う上記枝部間の扇形部を第2繊維形成物質であるポリ
アミドにて構成した可分形複合緬維に関する。
Detailed Description of the Invention [Industrial Field of Application] The present invention provides a first fiber-forming material that comprises a branch extending from the center of the cross section toward the outer peripheral edge and a small interior provided at the center. The present invention relates to a divisible composite silk fiber made of polyester, and in which the fan-shaped portion between the adjacent branch portions is made of polyamide, which is a second fiber-forming substance.

〔発明の概要〕[Summary of the invention]

この発明は、その横断面の中心から外周縁部に向って延
びる枝部と、上記中心に設けられた小内部とを第1繊維
形成物質のポリエステルにて構成しかつ互いに隣り合う
上記枝部間の扇形部を第2繊維形成物質のポリアミドに
て構成した可分形複合繊維において、上記枝部と上記扇
形部との間の境界を曲面で構成すると共に、上記扇形部
の総面積を上記横断面面積の60〜80%の範囲に収め
、さらに上記小内部の直径と上記横断面の直径との比を
1/10〜115の範囲に、また上記枝部の最大幅と、
上記外周縁部におけるこの枝部の幅との比を4/3〜2
の範囲に収めることにより、紡糸性や繊維の延伸作業性
を向上させると共に、分離度や分離度差を改善して、染
色性が良好でかつ高品質な高密度編織物、あるいは人工
皮革を提供できるようにしたものである。
In the present invention, the branch extending from the center of the cross section toward the outer peripheral edge and the small interior provided at the center are made of polyester as a first fiber-forming substance, and the branch parts adjacent to each other are In the splittable composite fiber in which the fan-shaped portion is made of polyamide as a second fiber-forming substance, the boundary between the branch portion and the fan-shaped portion is formed by a curved surface, and the total area of the fan-shaped portion is defined as the cross section. Within a range of 60 to 80% of the area, furthermore, the ratio of the diameter of the small interior to the diameter of the cross section is in the range of 1/10 to 115, and the maximum width of the branch part,
The ratio of the width of this branch at the outer peripheral edge is 4/3 to 2.
By keeping it within this range, we can improve spinnability and fiber drawing workability, improve the degree of separation and the difference in degree of separation, and provide high-density knitted fabrics or artificial leather with good dyeability and high quality. It has been made possible.

〔従来の技術〕[Conventional technology]

可分形複合繊維を用いて高密度編織物や人工皮革を製造
する場合、例えば特公昭53−38764号公報、特公
昭58−5311号公報および特開昭51−60769
号公報に開示されたように、第2A図〜第2D図に示す
ごとき横断面を持つ複合繊維、すなわち第1繊維形成物
質(図のハツチング部分)と、第2繊維形成物質(図の
白地部分)との組合せから成る可分形複合繊維がしばし
ば使用される。
When producing high-density knitted fabrics or artificial leather using divisible composite fibers, for example, Japanese Patent Publication No. 53-38764, Japanese Patent Publication No. 58-5311, and Japanese Patent Application Laid-Open No. 51-60769
As disclosed in the publication, a composite fiber having a cross section as shown in FIGS. 2A to 2D, that is, a first fiber-forming substance (hatched area in the figure) and a second fiber-forming substance (white area in the figure) ) are often used.

ところで第2B図に示す横断面の複合繊維の場合を除け
ば、これらの可分形複合繊維の場合、上記2つの繊維形
成物質間の境界がすべて平面から成っている。このため
後述するように(第1表参照)、これらの複合繊維は比
較的に分離度が低く、また分離度差が極めて大である。
In the case of these splittable conjugate fibers, except for the conjugate fiber having the cross section shown in FIG. 2B, the boundaries between the two fiber-forming substances are all planes. Therefore, as will be described later (see Table 1), these composite fibers have a relatively low degree of separation, and the difference in degree of separation is extremely large.

他方、第2B図に示す横断面の上記複合繊維の場合には
、第2C図に示す類イ以横断面の複合繊維と較べると分
離度が高く、また分離度差も小である。しかしながらそ
の改善の度合は僅少であり、却って複雑な横断面のため
に延伸作業性が低下するという問題を生じる。なおここ
で[分離度」と「分離度差」とは、それぞれ次式で表さ
れる値で、スピンドルタイプの加熱機を使用して加熱し
た後に測定する。
On the other hand, in the case of the conjugate fiber having the cross section shown in FIG. 2B, the degree of separation is higher than that of the conjugate fiber having a similar cross section shown in FIG. 2C, and the difference in degree of separation is also small. However, the degree of improvement is small, and on the contrary, the problem arises that the drawing workability is lowered due to the complicated cross section. Note that the "separation degree" and "separation degree difference" are values expressed by the following formulas, respectively, and are measured after heating using a spindle type heating machine.

分離度差=(最大分離度−最小分離度)  (χ)(発
明が解決しようとする課題) ところで分離度が低い既述のような可分形複合過維を使
用すると、期待通りの高密度編織物を得ることが難しい
。また人工皮革を作れば、柔軟な触感が得られにクク、
天然皮革に極めて似たものを作ることができない。
Difference in degree of separation = (Maximum degree of separation - Minimum degree of separation) (χ) (Problem to be solved by the invention) By the way, if a separable composite fiber like the one mentioned above with a low degree of separation is used, the expected high-density knitting will be achieved. Difficult to obtain textiles. Also, if you make artificial leather, you will be able to get a soft texture.
It is not possible to make something that closely resembles natural leather.

また分離度差が既述のごとく大きい可分形複合繊維を使
用すると、高密度編織物または人工皮革の表面において
、良く分離されたところは明るい色で染色され、また良
く分離されていないところtよ暗い色で染色される。こ
のため均一に染色された高密度tv6物または人工皮革
を得ることができない。
Furthermore, when using separable composite fibers with large differences in degree of separation as mentioned above, on the surface of high-density knitted fabrics or artificial leather, well-separated areas will be dyed in bright colors, and areas that are not well-separated will be dyed in bright colors. dyed in a dark color. For this reason, it is not possible to obtain uniformly dyed high-density TV6 material or artificial leather.

本発明は上述の点に鑑み、上記諸問題を解決できる可分
形複合緬維を提供するものである。
In view of the above-mentioned points, the present invention provides a divisible composite silk fiber that can solve the above-mentioned problems.

[課題を解決するための手段〕 本発明は、その横断面の中心から外周縁部に向って延び
る枝部と、上記中心に設けられた小内部とを第1繊維形
成物質であるポリエステルにて構成しかつ互いに隣り合
う上記枝部間の扇形部を第2繊維形成物質であるポリア
ミドにて構成した可分形複合祇維において、上記枝部と
上記扇形部との間の境界を曲面で構成すると共に、上記
扇形部の総面積を上記横断面面積の60〜80%の範囲
に収め、上記小内部の直径と上記横断面の直径との比を
1/10〜115の範囲(1/10と115を除く)に
、また上記枝部の最大幅と、上記外周縁部におけるこの
枝部の幅との比を4/3〜2の範囲(4/3と2とを含
む)に収めるように可分形複合繊維を構成した。
[Means for Solving the Problems] The present invention is characterized in that the branch portion extending from the center of the cross section toward the outer peripheral edge and the small interior provided at the center are made of polyester, which is a first fiber-forming material. In the separable composite fiber in which the fan-shaped portion between the branch portions adjacent to each other is made of polyamide as a second fiber-forming substance, the boundary between the branch portion and the fan-shaped portion is formed by a curved surface. At the same time, the total area of the fan-shaped portion is within the range of 60 to 80% of the cross-sectional area, and the ratio of the diameter of the small interior to the diameter of the cross-section is within the range of 1/10 to 115 (1/10 and 1/10). 115), and the ratio of the maximum width of the branch to the width of the branch at the outer peripheral edge is within the range of 4/3 to 2 (including 4/3 and 2). A separable composite fiber was constructed.

〔作用〕[Effect]

したがって、上記可分形複合繊維を物理的又は化学的に
処理して分離を行った際の分離度は極めて高く、また分
離度差も15%以下に収めることができる。
Therefore, when the above-mentioned splittable conjugate fibers are physically or chemically treated and separated, the degree of separation is extremely high, and the difference in degree of separation can be kept within 15%.

〔実施例〕〔Example〕

以下本発明の実施例につき第1図を参照しながら説明す
る。
Embodiments of the present invention will be described below with reference to FIG.

本発明に係る可分形複合緬維の横断面を第1図に示す、
同図でハツチングを施した部分は、横断面の中心0に位
置を占める小内部A、と、上記中心0から上記横断面の
外周縁部pに向って延びる枝部A2とから成り、第1繊
維形成物質であるポリエステルにて構成される。
A cross section of the divisible composite silk fiber according to the present invention is shown in FIG.
The hatched part in the figure consists of a small interior A located at the center 0 of the cross section, and a branch A2 extending from the center 0 toward the outer peripheral edge p of the cross section. Composed of polyester, a fiber-forming substance.

また互いに隣り合う上記枝部A2間の扇形部Bは第2繊
維形成物質であるポリアミドにて構成される。なお扇形
部Bの総面積は、上記横断面の面積の60〜80%の範
囲に保たれる。
Further, the fan-shaped portions B between the adjacent branch portions A2 are made of polyamide, which is the second fiber-forming material. Note that the total area of the fan-shaped portion B is kept within a range of 60 to 80% of the area of the above-mentioned cross section.

すなわち扇形部Bの上記総面積が60%を切ると、扇形
部Bが紡糸後の延伸時に分離を起し易く、このため延伸
作業性が低下する。また80%を超えると、第1図に示
すごとき横断面の可分形複合繊維を得ることが困難にな
る。
That is, if the total area of the fan-shaped portions B is less than 60%, the fan-shaped portions B are likely to separate during stretching after spinning, resulting in a decrease in stretching workability. If it exceeds 80%, it becomes difficult to obtain a splittable conjugate fiber having a cross section as shown in FIG.

次に上記枝部A2と上記扇形部Bとの間の境界は曲面で
構成される。また横断面の直径をD、小内部A1の直径
をdとすれば、その比d/Dは次の範囲に保持される。
Next, the boundary between the branch portion A2 and the fan-shaped portion B is constituted by a curved surface. Further, assuming that the diameter of the cross section is D and the diameter of the small interior A1 is d, the ratio d/D is maintained within the following range.

1/10<d/D< 115 すなわち上記比d/Dが1/10を切ると、扇形部Bの
中心0に近い端部における幅が小になって分離度差を高
める原因となる。また115を超えると、扇形部Bが繊
維の延伸時に分離を起し易く、このため延伸作業性が低
下する。
1/10<d/D<115 That is, when the ratio d/D is less than 1/10, the width at the end of the fan-shaped portion B near the center 0 becomes small, which causes an increase in the difference in degree of separation. On the other hand, if it exceeds 115, the fan-shaped portion B tends to separate during stretching of the fibers, resulting in a decrease in stretching workability.

次に前記枝部A2の最大幅をb、上記外周縁部pにおけ
るこの枝部A2の幅をaとすれば、その比b / aは
次の範囲に保持される。
Next, if the maximum width of the branch portion A2 is b and the width of the branch portion A2 at the outer peripheral edge p is a, the ratio b/a is maintained within the following range.

4 / 3 < b / a < 2 すなわち上記比b / aが2以上になると扇形部Bの
分離が著しく不均一となる。このため染色時に緯方向の
染色差を起し易い。また4/3以下になると、上記横断
面が第2A図に示す形に近付くから、本発明の目的を達
成できなくなる。
4/3<b/a<2 In other words, when the ratio b/a becomes 2 or more, the separation of the fan-shaped portions B becomes significantly non-uniform. For this reason, dyeing differences in the weft direction tend to occur during dyeing. Moreover, if it is less than 4/3, the cross section approaches the shape shown in FIG. 2A, making it impossible to achieve the object of the present invention.

ところで第1繊維形成物質には固有粘度0.62のポリ
エステルを使用し、また第217a維形成物質には相対
粘度2.47のナイロン6を使用して複合紡糸を行い、
テークアツプ速度1000 m/ff1in 、延伸比
3.5で第1図に示す横断面の可分形複合繊維を得た。
By the way, polyester with an intrinsic viscosity of 0.62 is used as the first fiber-forming material, and nylon 6 with a relative viscosity of 2.47 is used as the 217a fiber-forming material, and composite spinning is performed.
A splittable composite fiber having a cross section shown in FIG. 1 was obtained at a take-up speed of 1000 m/ff1in and a drawing ratio of 3.5.

次にこの繊維をスピンドルタイプの加熱機で加熱し、そ
のあとで分離度等を測定した。
Next, this fiber was heated with a spindle type heating machine, and the degree of separation etc. was then measured.

第1表には、上記試験で得られた結果を第1実施例およ
び第2実施例、第1比較例および第2比較例として表示
しである。また第1表には比較のために、第2A図〜第
2D図に示した横断面の複合繊維についての試験結果も
、第3比較例〜第6比較例として表示しである。
Table 1 shows the results obtained in the above test as a first example, a second example, a first comparative example, and a second comparative example. For comparison, Table 1 also shows the test results for composite fibers having the cross sections shown in FIGS. 2A to 2D as Comparative Examples 3 to 6.

(以下余白) 同表によれば、第1実施例および第2実施例に示すよう
な諸条件を付与した可分形複合祇維の場合は、紡糸性、
延伸作業性が良好であるばかりでなく、平均分離度や分
離度差も満足すべき値となった。
(Left below) According to the same table, in the case of divisible composite fibers given the various conditions shown in the first and second examples, spinnability, spinnability,
Not only was the stretching workability good, but the average degree of separation and the difference in degree of separation were also satisfactory values.

かくして第1実施例および第2実施例に示すような可分
形複合繊維を使用すれば、外観が良好で触感も優れた高
品質の編物や織物、あるいは人工皮革を製造することが
でき、また均一な染色も容易に行うことができる。した
がってたとえば高性能のワイパーやクリーナ用の材料と
して適する。
Thus, by using the divisible composite fibers shown in the first and second embodiments, it is possible to produce high-quality knitted fabrics, woven fabrics, or artificial leathers that have a good appearance and feel, and also have a uniform texture. It can also be easily dyed. Therefore, it is suitable as a material for high-performance wipers and cleaners, for example.

〔発明の効果〕 本発明は上述のような構成であるから、紡糸性や繊維の
延伸作業性を向上させることができる。
[Effects of the Invention] Since the present invention has the above-described configuration, it is possible to improve spinnability and fiber drawing workability.

また分離度や分離度差が著しく改善されるため、染色性
が良好でかつ高品質の高密度編織物や人工皮革を容易に
生産することが可能になる。
Furthermore, since the degree of separation and the difference in degree of separation are significantly improved, it becomes possible to easily produce high-density knitted fabrics and artificial leather with good dyeability and high quality.

第1図はこの発明の実施例を示す可分形複合繊維の横断
面図である。また第2A図〜第2D図は従来の可分形複
合纏維の4例に関するそれぞれの横断面図である。
FIG. 1 is a cross-sectional view of a divisible composite fiber showing an embodiment of the present invention. Moreover, FIGS. 2A to 2D are cross-sectional views of four examples of conventional separable composite fibers.

なお図面に用いられた符号において、 A+”−・−−−−−−−−−−−−一小内部A Z−
一−−−−−−−−枝部 B  −−−−−−−一扇形部 d  −直径 D −−直径 b−−−−一 最大幅 a −−−−−一−−外周縁部における幅0−−−−・
−中心 p−−−−−・  −外周縁部 である。
In addition, in the symbols used in the drawings, A+”-・−−−−−−−−−−−−One small internal A Z−
1 ---------- Branch B ---------- 1 Fan-shaped part d - Diameter D - Diameter b - 1 Maximum width a - 1 - At the outer peripheral edge Width 0----
-Center p-------Outer periphery.

Claims (1)

【特許請求の範囲】 その横断面の中心oから外周縁部pに向って延びる枝部
A_2と、上記中心oに設けられた小内部A_1とを第
1繊維形成物質であるポリエステルにて構成しかつ互い
に隣り合う上記枝部A_2間の扇形部Bを第2繊維形成
物質であるポリアミドにて構成した可分形複合繊維にお
いて、 上記枝部A_2と上記扇形部Bとの間の境界を曲面で構
成すると共に、上記扇形部Bの総面積を上記横断面面積
の60〜80%の範囲に収め、上記小内部A_1の直径
dと上記横断面の直径Dとの比d/Dを1/10〜1/
5の範囲(1/10と1/5とを除く)に、また上記枝
部A_2の最大幅bと、上記外周縁部pにおけるこの枝
部A_2の幅aとの比b/aを4/3〜2の範囲(4/
3と2とを含む)に収めたことを特徴とする可分形複合
繊維。
[Claims] The branch portion A_2 extending from the center o of the cross section toward the outer peripheral edge p and the small interior A_1 provided at the center o are made of polyester, which is the first fiber-forming substance. And in the splittable composite fiber in which the fan-shaped portion B between the branch portions A_2 adjacent to each other is made of polyamide as a second fiber-forming substance, the boundary between the branch portion A_2 and the fan-shaped portion B is made of a curved surface. At the same time, the total area of the fan-shaped portion B is within the range of 60 to 80% of the cross-sectional area, and the ratio d/D of the diameter d of the small interior A_1 to the diameter D of the cross-section is 1/10 to 1/10. 1/
5 (excluding 1/10 and 1/5), and the ratio b/a of the maximum width b of the branch A_2 to the width a of this branch A_2 at the outer peripheral edge p is 4/ Range of 3 to 2 (4/
3 and 2)).
JP2148416A 1990-03-30 1990-06-06 Separable composite fiber Pending JPH03287817A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR4366 1990-03-30
KR1019900004366A KR920005730B1 (en) 1990-03-30 1990-03-30 Separating type conjugated yarn

Publications (1)

Publication Number Publication Date
JPH03287817A true JPH03287817A (en) 1991-12-18

Family

ID=19297533

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2148416A Pending JPH03287817A (en) 1990-03-30 1990-06-06 Separable composite fiber

Country Status (4)

Country Link
JP (1) JPH03287817A (en)
KR (1) KR920005730B1 (en)
FR (1) FR2660327B1 (en)
GB (1) GB2242391B (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100313363B1 (en) * 1999-08-13 2001-11-14 조민호 Divisible composite fiber composed of multi flat segment and its spining pack
KR20010064270A (en) * 1999-12-27 2001-07-09 구광시 A composite fiber having an excellent spinning properties

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3117362A (en) * 1961-06-20 1964-01-14 Du Pont Composite filament
GB1120241A (en) * 1965-07-27 1968-07-17 Kanegafuchi Spinning Co Ltd Composite filaments and spinneret for producing same
ZA71888B (en) * 1970-02-16 1971-10-27 Ici Ltd Improvements in or relating to process and apparatus for the manufacture of conjugate filaments
JPS4887119A (en) * 1972-02-24 1973-11-16
JPS5335633B2 (en) * 1973-04-21 1978-09-28
CH641844A5 (en) * 1978-01-25 1984-03-15 Akzo Nv METHOD AND DEVICE FOR PRODUCING A MULTI-COMPONENT THREAD WITH A MATRIX COMPONENT AND AT LEAST ONE SEGMENT COMPONENT.
AU525860B2 (en) * 1978-03-03 1982-12-02 Akzo N.V. Fibre structures of split multicomponent fibres
DE2850713C2 (en) * 1978-11-23 1986-10-09 Akzo Gmbh, 5600 Wuppertal Antistatic thread structure
JPS5593818A (en) * 1978-12-29 1980-07-16 Toray Ind Inc Production of mixed yarn
JPS585311A (en) * 1981-07-03 1983-01-12 Mitsubishi Petrochem Co Ltd Catalytic component for olefin polymerization
KR830002440B1 (en) * 1981-09-05 1983-10-26 주식회사 코오롱 Composite fiber

Also Published As

Publication number Publication date
GB2242391A (en) 1991-10-02
FR2660327B1 (en) 1992-07-31
FR2660327A1 (en) 1991-10-04
KR920005730B1 (en) 1992-07-16
GB9017187D0 (en) 1990-09-19
GB2242391B (en) 1994-02-02
KR910016983A (en) 1991-11-05

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