JPH03236303A - Plant bacterium disease-preventing agent - Google Patents
Plant bacterium disease-preventing agentInfo
- Publication number
- JPH03236303A JPH03236303A JP3156990A JP3156990A JPH03236303A JP H03236303 A JPH03236303 A JP H03236303A JP 3156990 A JP3156990 A JP 3156990A JP 3156990 A JP3156990 A JP 3156990A JP H03236303 A JPH03236303 A JP H03236303A
- Authority
- JP
- Japan
- Prior art keywords
- compound
- plant
- preventing agent
- tea
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 241000196324 Embryophyta Species 0.000 title claims abstract description 25
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 title claims abstract description 14
- 201000010099 disease Diseases 0.000 title claims abstract description 13
- 241000894006 Bacteria Species 0.000 title abstract description 5
- 235000013824 polyphenols Nutrition 0.000 claims abstract description 13
- 235000018927 edible plant Nutrition 0.000 claims abstract description 5
- 239000002075 main ingredient Substances 0.000 claims abstract 2
- 208000035143 Bacterial infection Diseases 0.000 claims description 16
- 150000008442 polyphenolic compounds Chemical class 0.000 claims description 10
- 208000022362 bacterial infectious disease Diseases 0.000 claims description 9
- 230000001580 bacterial effect Effects 0.000 claims description 8
- 230000002554 disease preventive effect Effects 0.000 claims description 7
- XMOCLSLCDHWDHP-IUODEOHRSA-N epi-Gallocatechin Chemical compound C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@H]2O)=CC(O)=C(O)C(O)=C1 XMOCLSLCDHWDHP-IUODEOHRSA-N 0.000 claims description 6
- 235000014620 theaflavin Nutrition 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 3
- PFTAWBLQPZVEMU-DZGCQCFKSA-N (+)-catechin Chemical compound C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@@H]2O)=CC=C(O)C(O)=C1 PFTAWBLQPZVEMU-DZGCQCFKSA-N 0.000 claims description 2
- PFTAWBLQPZVEMU-UKRRQHHQSA-N (-)-epicatechin Chemical compound C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@H]2O)=CC=C(O)C(O)=C1 PFTAWBLQPZVEMU-UKRRQHHQSA-N 0.000 claims description 2
- LSHVYAFMTMFKBA-TZIWHRDSSA-N (-)-epicatechin-3-O-gallate Chemical compound O([C@@H]1CC2=C(O)C=C(C=C2O[C@@H]1C=1C=C(O)C(O)=CC=1)O)C(=O)C1=CC(O)=C(O)C(O)=C1 LSHVYAFMTMFKBA-TZIWHRDSSA-N 0.000 claims description 2
- LSHVYAFMTMFKBA-UHFFFAOYSA-N ECG Natural products C=1C=C(O)C(O)=CC=1C1OC2=CC(O)=CC(O)=C2CC1OC(=O)C1=CC(O)=C(O)C(O)=C1 LSHVYAFMTMFKBA-UHFFFAOYSA-N 0.000 claims description 2
- IPMYMEWFZKHGAX-UHFFFAOYSA-N Isotheaflavin Natural products OC1CC2=C(O)C=C(O)C=C2OC1C(C1=C2)=CC(O)=C(O)C1=C(O)C(=O)C=C2C1C(O)CC2=C(O)C=C(O)C=C2O1 IPMYMEWFZKHGAX-UHFFFAOYSA-N 0.000 claims description 2
- UXRMWRBWCAGDQB-UHFFFAOYSA-N Theaflavin Natural products C1=CC(C2C(CC3=C(O)C=C(O)C=C3O2)O)=C(O)C(=O)C2=C1C(C1OC3=CC(O)=CC(O)=C3CC1O)=CC(O)=C2O UXRMWRBWCAGDQB-UHFFFAOYSA-N 0.000 claims description 2
- KMJPKUVSXFVQGZ-WQLSNUALSA-N [(2r,3r)-5,7-dihydroxy-2-[3,4,5-trihydroxy-6-oxo-1-[(2r,3r)-3,5,7-trihydroxy-3,4-dihydro-2h-chromen-2-yl]benzo[7]annulen-8-yl]-3,4-dihydro-2h-chromen-3-yl] 3,4,5-trihydroxybenzoate Chemical compound O([C@@H]1CC2=C(O)C=C(O)C=C2O[C@@H]1C1=CC(=O)C(O)=C2C(O)=C(O)C=C(C2=C1)[C@H]1OC2=CC(O)=CC(O)=C2C[C@H]1O)C(=O)C1=CC(O)=C(O)C(O)=C1 KMJPKUVSXFVQGZ-WQLSNUALSA-N 0.000 claims description 2
- 235000013339 cereals Nutrition 0.000 claims description 2
- 235000013399 edible fruits Nutrition 0.000 claims description 2
- IPMYMEWFZKHGAX-ZKSIBHASSA-N theaflavin Chemical compound C1=C2C([C@H]3OC4=CC(O)=CC(O)=C4C[C@H]3O)=CC(O)=C(O)C2=C(O)C(=O)C=C1[C@@H]1[C@H](O)CC2=C(O)C=C(O)C=C2O1 IPMYMEWFZKHGAX-ZKSIBHASSA-N 0.000 claims description 2
- 229940026509 theaflavin Drugs 0.000 claims description 2
- 235000013311 vegetables Nutrition 0.000 claims description 2
- 241001122767 Theaceae Species 0.000 claims 2
- 229930013915 (+)-catechin Natural products 0.000 claims 1
- 235000007219 (+)-catechin Nutrition 0.000 claims 1
- PFTAWBLQPZVEMU-ZFWWWQNUSA-N (+)-epicatechin Natural products C1([C@@H]2OC3=CC(O)=CC(O)=C3C[C@@H]2O)=CC=C(O)C(O)=C1 PFTAWBLQPZVEMU-ZFWWWQNUSA-N 0.000 claims 1
- WMBWREPUVVBILR-WIYYLYMNSA-N (-)-Epigallocatechin-3-o-gallate Chemical compound O([C@@H]1CC2=C(O)C=C(C=C2O[C@@H]1C=1C=C(O)C(O)=C(O)C=1)O)C(=O)C1=CC(O)=C(O)C(O)=C1 WMBWREPUVVBILR-WIYYLYMNSA-N 0.000 claims 1
- WMBWREPUVVBILR-UHFFFAOYSA-N GCG Natural products C=1C(O)=C(O)C(O)=CC=1C1OC2=CC(O)=CC(O)=C2CC1OC(=O)C1=CC(O)=C(O)C(O)=C1 WMBWREPUVVBILR-UHFFFAOYSA-N 0.000 claims 1
- XMOCLSLCDHWDHP-UHFFFAOYSA-N L-Epigallocatechin Natural products OC1CC2=C(O)C=C(O)C=C2OC1C1=CC(O)=C(O)C(O)=C1 XMOCLSLCDHWDHP-UHFFFAOYSA-N 0.000 claims 1
- GPLOTACQBREROW-UHFFFAOYSA-N Phlegmanol A-acetat Natural products OC1CC2=C(O)C=C(O)C=C2OC1C(=CC1=2)C=C(O)C(=O)C1=C(O)C(O)=CC=2C1OC2=CC(O)=CC(O)=C2CC1OC(=O)C1=CC(O)=C(O)C(O)=C1 GPLOTACQBREROW-UHFFFAOYSA-N 0.000 claims 1
- LPTRNLNOHUVQMS-UHFFFAOYSA-N epicatechin Natural products Cc1cc(O)cc2OC(C(O)Cc12)c1ccc(O)c(O)c1 LPTRNLNOHUVQMS-UHFFFAOYSA-N 0.000 claims 1
- 235000012734 epicatechin Nutrition 0.000 claims 1
- DZYNKLUGCOSVKS-UHFFFAOYSA-N epigallocatechin Natural products OC1Cc2cc(O)cc(O)c2OC1c3cc(O)c(O)c(O)c3 DZYNKLUGCOSVKS-UHFFFAOYSA-N 0.000 claims 1
- 229940030275 epigallocatechin gallate Drugs 0.000 claims 1
- FJYGFTHLNNSVPY-BBXLVSEPSA-N theaflavin digallate Chemical compound C1=C([C@@H]2[C@@H](CC3=C(O)C=C(O)C=C3O2)O)C=C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(=O)C2=C1C([C@H]1OC3=CC(O)=CC(O)=C3C[C@H]1O)=CC(O)=C2OC(=O)C1=CC(O)=C(O)C(O)=C1 FJYGFTHLNNSVPY-BBXLVSEPSA-N 0.000 claims 1
- 244000269722 Thea sinensis Species 0.000 abstract description 13
- 239000003795 chemical substances by application Substances 0.000 abstract description 13
- 240000008415 Lactuca sativa Species 0.000 abstract description 4
- 235000003228 Lactuca sativa Nutrition 0.000 abstract description 4
- 235000007688 Lycopersicon esculentum Nutrition 0.000 abstract description 3
- 240000003768 Solanum lycopersicum Species 0.000 abstract description 3
- 244000061458 Solanum melongena Species 0.000 abstract description 3
- 235000002597 Solanum melongena Nutrition 0.000 abstract description 3
- 235000009754 Vitis X bourquina Nutrition 0.000 abstract description 3
- 235000012333 Vitis X labruscana Nutrition 0.000 abstract description 3
- 240000006365 Vitis vinifera Species 0.000 abstract description 3
- 235000014787 Vitis vinifera Nutrition 0.000 abstract description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 2
- -1 polyphenol compound Chemical class 0.000 abstract 4
- 150000001875 compounds Chemical class 0.000 abstract 3
- 238000013329 compounding Methods 0.000 abstract 1
- 239000005445 natural material Substances 0.000 abstract 1
- 244000052616 bacterial pathogen Species 0.000 description 11
- 229930184207 Polyphenon Natural products 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 230000003449 preventive effect Effects 0.000 description 4
- 239000002689 soil Substances 0.000 description 3
- ADRVNXBAWSRFAJ-UHFFFAOYSA-N catechin Natural products OC1Cc2cc(O)cc(O)c2OC1c3ccc(O)c(O)c3 ADRVNXBAWSRFAJ-UHFFFAOYSA-N 0.000 description 2
- 235000005487 catechin Nutrition 0.000 description 2
- 150000001765 catechin Chemical class 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 229930014626 natural product Natural products 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- 229930013783 (-)-epicatechin Natural products 0.000 description 1
- 235000007355 (-)-epicatechin Nutrition 0.000 description 1
- 241000237537 Ensis Species 0.000 description 1
- 206010027146 Melanoderma Diseases 0.000 description 1
- 241000123069 Ocyurus chrysurus Species 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000009528 severe injury Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 235000008118 thearubigins Nutrition 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 230000002747 voluntary effect Effects 0.000 description 1
- 210000004916 vomit Anatomy 0.000 description 1
- 230000008673 vomiting Effects 0.000 description 1
Abstract
Description
【発明の詳細な説明】
[産業上の利用分野]
本発明は植物細菌病に対する予防剤に関し、詳しくは野
菜、果樹、穀類等の食用となる植物における細菌病に対
する有効な予防剤に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to a preventive agent against bacterial diseases in plants, and more particularly to an effective preventive agent against bacterial diseases in edible plants such as vegetables, fruit trees, and cereals.
〔従来の技術、発明が解決しようとする課題〕植物細菌
病は、病原細菌の植物への感染により引き起こされ、症
状として作物の腐敗や斑点が生ずることにより、商品価
値の著しい低下を招くため、ひとたび作物が植物細菌病
に感染すると、その土壌伝播により栽培農家は甚大な被
害を受ける。[Prior art and problems to be solved by the invention] Bacterial plant diseases are caused by infection of plants with pathogenic bacteria, and the symptoms include rotting and spotting of crops, resulting in a significant decrease in commercial value. Once a crop is infected with a bacterial plant disease, farmers suffer severe damage due to its soil transmission.
この対策としては、農薬の散布が挙げられるが、農薬は
人体に毒性をもつ化学合成品であり、土壌汚染の心配も
あることから、その使用には問題が多い。One way to deal with this problem is to spray pesticides, but there are many problems with their use because pesticides are chemically synthesized products that are toxic to the human body, and there are concerns about soil contamination.
そのため、植物細菌病を予防でき、かつ人体に対し有害
な副作用をもたず、土壌汚染の心配のない、安心して使
用できる薬剤が強く求められていた。Therefore, there has been a strong need for a drug that can be used safely and that can prevent bacterial plant diseases, has no harmful side effects on the human body, and is free from soil contamination.
そこで、本発明者は化学的合成品でなく、天然物の中か
ら植物細菌病の病原細菌を殺滅するか、またはその生育
を抑制できる物質を検索すべく研究を重ねた結果、茶の
成分中に目的とする物質が含まれていることを見出し、
本発明に到達した。Therefore, the present inventor conducted repeated research to search for substances that can kill or suppress the growth of pathogenic bacteria of plant bacterial diseases from among natural products, rather than chemically synthesized products. discovered that it contained the desired substance,
We have arrived at the present invention.
すなわち、本発明は茶ポリフェノールを主成分とする植
物細菌病予防剤、特に食用となる植物における細菌病に
対する予防剤を提供するものである。That is, the present invention provides a plant bacterial disease preventive agent containing tea polyphenols as a main component, particularly a preventive agent against bacterial diseases in edible plants.
本発明の植物細菌病予防剤の主成分である茶ポリフェノ
ール類は、下記の一般式Iで表される茶カテキン類と一
般式■で表される茶テアフラビン類であり、テアルビジ
ンを含むものである。The tea polyphenols which are the main components of the plant bacterial disease preventive agent of the present invention are tea catechins represented by the following general formula I and tea theaflavins represented by the general formula (■), which contain thearubigin.
一般式
(一般式■中、R1=H2R2=H)
(−)エピガロカテキン
(一般式I中、R,=OH,RZ=H)(−)エピカテ
キンガレート
H
[IM
(−)エピガロカテキンガレート
H
カテキン類を具体的に示すと、以下のものがある。General formula (in general formula ■, R1=H2R2=H) (-) epigallocatechin (in general formula I, R, = OH, RZ=H) (-) epicatechin gallate H [IM (-) epigallocatechin Specific examples of gallate H catechins include the following.
(−)エピカテキン テアフラビン類を具体的に示すと、以下のものがある。(-)Epicatechin Specific examples of theaflavins include the following.
遊離型テアフラビン
(一般式■中、R,=H,R,=H)
テアフラビンモノガレートA
することができ、その製法は特開昭59−219384
号公報、同60−13780号公報、同61−1302
85号公報などに記載されている。Free theaflavin (in the general formula ①, R, = H, R, = H) Theaflavin monogallate A can be produced, and its production method is disclosed in JP-A-59-219384.
No. 60-13780, No. 61-1302
It is described in Publication No. 85, etc.
本発明の対象とされる植物細菌病は、ブドウ巨峰の組頭
がんしゅ病(病原細菌: A robacterium
tumefaciens ); )マドのかいよう病(
病原細菌:C1avibacter m1chi an
ensis 5ubsp、1tichi anensi
s );レタスの腐敗病やナスの褐斑細菌病(病原細菌
:Pseudos+onas cichorii) ;
)マド、ナスの青枯病(病原細菌: P、 5ola
nacearus+); レタスの腐敗病(病原細菌:
P、柱4h吐is pv、4肛1n侘±鰭);トマトの
黒斑細菌病やレタスの腐敗病(病原細菌: P、 vi
rtdiflava);トマトの斑点細菌病(病原細菌
: Xanthos+onas■り出trispv、゛
vesicatoria) :レタスの斑点細菌病(病
原細菌:X、 n粁勉立匡pv、vitians)など
である。The bacterial plant disease that is the subject of the present invention is Kumitouganshu disease of grape Kyoho (pathogenic bacteria: A robacterium
tumefaciens); ) madder canker disease (
Pathogenic bacteria: C1avibacter m1chian
ensis 5ubsp, 1tichi anensi
Lettuce rot disease and eggplant brown spot bacterial disease (pathogenic bacteria: Pseudos + onas cichorii);
) Bacterial wilt of Madoka and eggplant (pathogenic bacteria: P, 5ola
lettuce rot disease (pathogenic bacteria:
P, column 4h vomit is pv, 4 anal 1n wabi ± fin); bacterial black spot disease of tomatoes and rot disease of lettuce (pathogenic bacteria: P, vi
rtdiflava); Bacterial spot disease of tomato (pathogenic bacteria:
本発明の植物細菌病予防剤を植物に使用する場合は、上
記した主成分である茶ポリフェノールを水。When using the plant bacterial disease preventive agent of the present invention on plants, the tea polyphenols, which are the main components mentioned above, are mixed with water.
アルコールなどの溶媒に溶解させて植物に直接噴霧また
は塗布するか、あるいは根より植物に吸収させればよい
。その際の溶解濃度としては、50〜2000ppm、
好ましくは50〜1000ppn+である。その他の使
用形態として、適当な担体と混合して乳剤、粉剤1粒剤
なとがあり、その場合の茶ポリフェノールの配合量につ
いては、上記濃度を参考にして十分な効果が奏される範
囲で決定すればよく、所望により界面活性剤などを加え
て展着性などの改良を図ることもできる。It may be dissolved in a solvent such as alcohol and sprayed or applied directly to plants, or it may be absorbed by plants through their roots. The dissolved concentration at that time is 50 to 2000 ppm,
Preferably it is 50 to 1000 ppn+. Other usage forms include emulsions and powders mixed with an appropriate carrier.In such cases, the amount of tea polyphenols to be blended should be within the range that provides sufficient effects, with reference to the above concentrations. If desired, a surfactant or the like may be added to improve spreadability and the like.
次に、実施例により本発明の詳細な説明する。 Next, the present invention will be explained in detail with reference to Examples.
実施例
茶ポリフェノール類の植物細菌病病原細菌に対する最小
発育阻゛止濃度(MIC)を測定し、その結果を第1表
に示した。The minimum inhibitory concentration (MIC) of the tea polyphenols of Example against bacteria causing plant bacterial diseases was measured, and the results are shown in Table 1.
試験に用いた茶ポリフェノール類は、総力チキン量が9
0%以上である茶ポリフェノール製剤ポリフェノン10
0 (三井農林■製)、同じく60%以上であるポリフ
ェノン60(三井農林■製)、同じく30%以上である
ポリフェノン30(三井農林■製)。The total amount of tea polyphenols used in the test was 9.
Tea polyphenol preparation Polyphenon 10 with 0% or more
0 (manufactured by Mitsui Norin ■), Polyphenon 60 (manufactured by Mitsui Norin ■), which also has a content of 60% or more, and Polyphenon 30 (manufactured by Mitsui Norin ■), which also has a content of 30% or more.
その地租製品であるポリフェノンG(三井農林■製)の
4種類である。There are four types of polyphenon G (manufactured by Mitsui Norin ■), which is a land tax product.
/
表から明らかなように、茶ポリフェノール類は病原細菌
に対し、低濃度の添加で殺菌効果を示し、植物細菌病予
防剤として有効である。なお、MICの試験は、市販の
Nutrient brothを培地として用い、常法
によりMICを求めた。/ As is clear from the table, tea polyphenols exhibit a bactericidal effect against pathogenic bacteria when added at low concentrations, and are effective as preventive agents for plant bacterial diseases. In addition, in the MIC test, MIC was determined by a conventional method using commercially available nutrient broth as a medium.
本発明の植物細菌病予防剤は、日常相当量飲用されてい
る天然物を主成分とするので、食用とする植物に残留し
ても人体に対する副作用の心配がなく、植物細菌病の病
原細菌に対して強力に作用する。したがって、本発明の
植物細菌病予防剤は極めて実用性の高いものである。Since the plant bacterial disease preventive agent of the present invention is mainly composed of natural products that are consumed in considerable amounts on a daily basis, there is no fear of side effects on the human body even if it remains in edible plants, and it is not harmful to the pathogenic bacteria of plant bacterial diseases. It acts strongly against. Therefore, the plant bacterial disease preventive agent of the present invention is highly practical.
手続補正書(自発) 平成2年3月27日Procedural amendment (voluntary) March 27, 1990
Claims (3)
剤。(1) A plant bacterial disease preventive agent whose main ingredient is tea polyphenol.
、エピカテキンガレート、エピガロカテキン、エピカテ
キン、(+)カテキン、遊離型テアフラビン、テアフラ
ビンモノガレートA、テアフラビンモノガレートBおよ
びテアフラビンジガレートの中から選ばれた少なくとも
1種の物質である請求項1記載の植物細菌病予防剤。(2) The tea polyphenol is selected from epigallocatechin gallate, epicatechin gallate, epigallocatechin, epicatechin, (+) catechin, free theaflavin, theaflavin monogallate A, theaflavin monogallate B, and theaflavin digallate. The agent for preventing bacterial plant diseases according to claim 1, which is at least one substance.
植物に対するものである請求項1記載の植物細菌病予防
剤。(3) The plant bacterial disease preventive agent according to claim 1, wherein the plant bacterial disease is directed against edible plants such as vegetables, fruit trees, and cereals.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP3156990A JPH03236303A (en) | 1990-02-14 | 1990-02-14 | Plant bacterium disease-preventing agent |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP3156990A JPH03236303A (en) | 1990-02-14 | 1990-02-14 | Plant bacterium disease-preventing agent |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH03236303A true JPH03236303A (en) | 1991-10-22 |
Family
ID=12334812
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP3156990A Pending JPH03236303A (en) | 1990-02-14 | 1990-02-14 | Plant bacterium disease-preventing agent |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH03236303A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003095825A (en) * | 2001-09-21 | 2003-04-03 | Kumiai Chem Ind Co Ltd | Fungicidal composition for agriculture and horticulture and synergistic agent for strobilurin-based fungicide |
KR100852398B1 (en) * | 2007-05-08 | 2008-08-14 | 케이씨피주식회사 | Composition for controlling noxious animals in horticultural crops and using method thereof |
JP2012509850A (en) * | 2008-11-25 | 2012-04-26 | インデナ エッセ ピ ア | Plant extract for use as a phytochemical |
JP2017002161A (en) * | 2015-06-09 | 2017-01-05 | 株式会社パイロットコーポレーション | Water-based ink composition for writing instrument and water-based ink product using the same, and writing instrument |
CN111226925A (en) * | 2020-03-25 | 2020-06-05 | 浙江新安化工集团股份有限公司 | Pesticide adjuvant and application thereof |
-
1990
- 1990-02-14 JP JP3156990A patent/JPH03236303A/en active Pending
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003095825A (en) * | 2001-09-21 | 2003-04-03 | Kumiai Chem Ind Co Ltd | Fungicidal composition for agriculture and horticulture and synergistic agent for strobilurin-based fungicide |
KR100852398B1 (en) * | 2007-05-08 | 2008-08-14 | 케이씨피주식회사 | Composition for controlling noxious animals in horticultural crops and using method thereof |
JP2012509850A (en) * | 2008-11-25 | 2012-04-26 | インデナ エッセ ピ ア | Plant extract for use as a phytochemical |
JP2017002161A (en) * | 2015-06-09 | 2017-01-05 | 株式会社パイロットコーポレーション | Water-based ink composition for writing instrument and water-based ink product using the same, and writing instrument |
CN111226925A (en) * | 2020-03-25 | 2020-06-05 | 浙江新安化工集团股份有限公司 | Pesticide adjuvant and application thereof |
WO2021189987A1 (en) * | 2020-03-25 | 2021-09-30 | 浙江新安化工集团股份有限公司 | Pesticide adjuvant and application thereof |
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