JPH03226548A - Steel for cold forging - Google Patents
Steel for cold forgingInfo
- Publication number
- JPH03226548A JPH03226548A JP2177690A JP2177690A JPH03226548A JP H03226548 A JPH03226548 A JP H03226548A JP 2177690 A JP2177690 A JP 2177690A JP 2177690 A JP2177690 A JP 2177690A JP H03226548 A JPH03226548 A JP H03226548A
- Authority
- JP
- Japan
- Prior art keywords
- steel
- cold
- cold forging
- present
- wear resistance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 37
- 239000010959 steel Substances 0.000 title claims abstract description 37
- 238000010273 cold forging Methods 0.000 title claims abstract description 15
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 5
- 239000012535 impurity Substances 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 229910052804 chromium Inorganic materials 0.000 abstract description 10
- 230000007797 corrosion Effects 0.000 abstract description 9
- 238000005260 corrosion Methods 0.000 abstract description 9
- 238000000034 method Methods 0.000 abstract description 6
- 229910052799 carbon Inorganic materials 0.000 abstract description 4
- 229910052748 manganese Inorganic materials 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 229910052750 molybdenum Inorganic materials 0.000 abstract description 4
- 229910052720 vanadium Inorganic materials 0.000 abstract description 3
- 239000011651 chromium Substances 0.000 abstract 3
- 229910000851 Alloy steel Inorganic materials 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 2
- 238000003754 machining Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 14
- 150000001247 metal acetylides Chemical class 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 6
- 238000005520 cutting process Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 229910000822 Cold-work tool steel Inorganic materials 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 229910000746 Structural steel Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 229910001105 martensitic stainless steel Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 238000005482 strain hardening Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
Landscapes
- Valve-Gear Or Valve Arrangements (AREA)
Abstract
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、冷間鍛造用鋼に関するものである。[Detailed description of the invention] [Industrial application field] The present invention relates to steel for cold forging.
従来より、5U5440C綱は、自動車エンジン用をは
じめ、各種の耐食性および耐摩耗性を要求される用途に
広く使用されている。また、自動車用エンジンのバルブ
リフタは、耐摩耗性と耐食性が必要であるが、本用途で
は耐食性よりむしろ耐摩耗性が重要とされ、冷間工具鋼
の一種である5KDIIが使用されている。Conventionally, 5U5440C steel has been widely used in various applications requiring corrosion resistance and wear resistance, including automobile engines. Further, valve lifters for automobile engines require wear resistance and corrosion resistance, but in this application, wear resistance is more important than corrosion resistance, and 5KDII, a type of cold work tool steel, is used.
本用途としての5KDIIは従来切削加工によって製造
されていたが、加工費の低減のため、近年切削加工から
冷間鍛造によって製造する試みが行なわれるようになっ
てきた。5KDII for this purpose has conventionally been manufactured by cutting, but in recent years attempts have been made to manufacture it by cold forging instead of cutting in order to reduce processing costs.
上記自動車部品等、一定以上の耐食性を要求される例は
非常に多い。There are many examples in which a certain level of corrosion resistance is required, such as the above-mentioned automobile parts.
前記5KDIIは、組織的にはM、 C,型の巨大炭化
物が生成するが、この巨大炭化物は通常の凝固過程で既
に生成しており、その後の熱間加工を経ても残留する。In the 5KDII, giant carbides of type M and C are formed structurally, but these giant carbides are already formed during the normal solidification process and remain even after the subsequent hot working.
従来の切削加工でこの巨大炭化物は、特に問題とならず
、むしろ耐摩耗性を向上させる効果があった。しかし、
冷間鍛造においては、この巨大炭化物を起点として割れ
に至る不具合が起こり、加工工程および製品の信頼上大
きな問題となっている。These giant carbides did not pose a particular problem during conventional cutting, but rather had the effect of improving wear resistance. but,
In cold forging, defects that lead to cracking occur from these giant carbides, which poses a major problem in terms of the processing process and product reliability.
この問題は、一連の冷間鍛造工程に中間焼鈍を1〜2回
行なうことにより、ある程度防止することができるが、
工数増加により冷間鍛造によるコストメリットが低下す
るという欠点がある。しかしながら、現在まで5KDI
Iに替わる材料がなかったため、耐摩耗性の特性を優先
して、やむを得ず5KDIIを使用している状態にあっ
た。This problem can be prevented to some extent by performing intermediate annealing once or twice in a series of cold forging steps, but
There is a disadvantage that the cost advantage of cold forging is reduced due to the increase in man-hours. However, until now 5KDI
Since there was no material to replace I, 5KDII had no choice but to be used, giving priority to wear resistance.
本発明は、通常の使用に十分対応可能な耐食性を有し、
耐摩耗性を維持しつつ冷間加工性(冷間鍛造性)を向上
させ、冷間加工性と耐摩耗性にすぐれた安価な材料を提
供し、上述の従来の課題を解決せんとするもので、特に
バルブリフタ製造を従来の切削加工から冷間鍛造による
加工に変更可能とし、かつバルブリフタの材料として十
分な耐摩耗性を付与できる鋼を提供するものである。The present invention has corrosion resistance sufficient for normal use,
The objective is to improve cold workability (cold forgeability) while maintaining wear resistance, provide an inexpensive material with excellent cold workability and wear resistance, and solve the above-mentioned conventional problems. In particular, it is an object of the present invention to provide a steel that can change the manufacturing process of valve lifters from conventional cutting to cold forging, and that can provide sufficient wear resistance as a material for valve lifters.
〔課題を解決するための手段]
本発明は、重量比でC0.70〜0.95%、Si0.
50〜1.00%、Mn 0.30〜0.80%、Cr
6.0−8.0%、M。[Means for Solving the Problems] The present invention has a weight ratio of C0.70 to 0.95% and Si0.
50-1.00%, Mn 0.30-0.80%, Cr
6.0-8.0%, M.
0.50〜1.20%、V 0.20〜0.50%、ま
たは、さらにNb0.03〜0.07%を含み、Fe残
部および不可避的不純物よりなることを特徴とする冷間
鍛造用鋼である。For cold forging, containing 0.50 to 1.20%, V 0.20 to 0.50%, or further Nb 0.03 to 0.07%, and consisting of the remainder of Fe and inevitable impurities. It is steel.
本発明鋼に対する類似成分鋼として、特公昭54−22
770号でG 0.45〜0.80%、Cr 4.0−
8.0%、M。As a steel with similar composition to the steel of the present invention,
No. 770, G 0.45-0.80%, Cr 4.0-
8.0%, M.
0.5〜2.0%、■0.1〜1.5%、N 0.01
2〜o、 io%またはさらにWO01〜1.5%を含
み、残部Feよりなる「靭性のすぐれたハネ出しビン用
工具鋼」が、また特開平1−176054号で、C00
7〜1.5%、Si0.7〜2.0%、Cr 7.0−
11.0%、Mo 1.3−3.0%、またはさらにN
i1.5%以下とそれぞれ特定%範囲のGo、Zr、T
i。0.5-2.0%, ■0.1-1.5%, N 0.01
``Tool steel for sputtering bottles with excellent toughness'' containing 0.2~1.5% or even WO01~1.5% and the balance Fe is also disclosed in Japanese Patent Application Laid-Open No. 1-176054.
7-1.5%, Si0.7-2.0%, Cr 7.0-
11.0%, Mo 1.3-3.0%, or even N
Go, Zr, and T in specific % ranges with i1.5% or less
i.
N b 、 Wの1種または2種以上を、単独または複
合で含有し、残部Feからなるダイスおよびポンチ、抜
型、成形型に用いられる「冷間工具鋼」がそれぞれ開示
されている。A "cold work tool steel" containing one or more of Nb and W, singly or in combination, and used for dies and punches, punches, cutting dies, and forming dies, the remainder of which is Fe, is disclosed.
また、冷間加工性を重視した構造用鋼として、特公昭5
4−3123号、特開昭59−13048号および特開
昭60−255957号で、Crを最大1.5%含む、
それぞれ[冷間加工性のすぐれた構造用鋼」、「冷間鍛
造用強靭鋼」および「冷間鍛造用鋼」が開示され、また
、特公昭64−455号、同62−54394号および
特開昭60−255960号でCr 13−19%を含
む冷間圧造用高強度マルテンサイトステンレス鋼等、が
それぞれ開示されている。In addition, it was developed as a structural steel with emphasis on cold workability.
No. 4-3123, JP-A-59-13048 and JP-A-60-255957, containing up to 1.5% Cr;
``Structural steel with excellent cold workability'', ``strong steel for cold forging'', and ``steel for cold forging'' are disclosed respectively, and Japanese Patent Publications No. 64-455, No. 62-54394 and Japanese Patent Publication No. 60-255960 discloses a high-strength martensitic stainless steel for cold heading containing 13-19% Cr.
本発明鋼は、上記の類似成分鋼とは成分および用途を異
にし、また、上記冷間加工性を重視した綱の低Cr綱や
、低C−高Cr鋼に対して、中C−中Crとして耐食性
をそれ程損なわずに耐摩耗性と冷間鍛造性の講和を図っ
たものである。The steel of the present invention differs in composition and use from the above-mentioned steels with similar compositions, and is different from the above-mentioned low-Cr steel, which emphasizes cold workability, and low-C-high Cr steel, as well as medium-C to medium-C steel. Cr is used to improve wear resistance and cold forgeability without significantly impairing corrosion resistance.
次に本発明の成分限定理由を説明する。 Next, the reason for limiting the components of the present invention will be explained.
(:、 : 0.70〜0.95%
Cは基地に固溶して硬さを高くするとともに炭化物を形
成し耐摩耗性を向上させる元素である。(:, : 0.70 to 0.95% C is an element that solidly dissolves in the matrix to increase hardness and forms carbides to improve wear resistance.
本組成においては、0.70%未満では硬さおよび炭化
物の形成が十分でない。したがって、下限を0.70%
とした。Cは多量に添加すると、M、C,型の巨大炭化
物を形成する。0.95%を越えて添加すると巨大炭化
物の生成が顕著となり冷間加工性を阻害するため上限を
0.95%とした。In this composition, if it is less than 0.70%, hardness and carbide formation are insufficient. Therefore, the lower limit is 0.70%
And so. When C is added in large amounts, it forms M, C, type giant carbides. If added in excess of 0.95%, the formation of giant carbides becomes noticeable and impedes cold workability, so the upper limit was set at 0.95%.
Si 0.50〜1.00%
Siは脱酸剤として添加されるが、焼もどし軟化抵抗を
向上させる効果もある。0.50%未満ではその効果が
少なく、また1、00%を越えて添加すると熱間加工性
と冷間加工性を阻害するので0.50〜1.00%とし
た。Si 0.50-1.00% Si is added as a deoxidizing agent, but it also has the effect of improving tempering softening resistance. If it is less than 0.50%, the effect will be small, and if it is added in excess of 1,00%, hot workability and cold workability will be inhibited, so the content was set at 0.50 to 1.00%.
Mn : 0.30−0.80%
Mnは、Siと同様に脱酸剤としての効果があるが、焼
入性を向上させる効果がある。0.30%末滴では脱酸
剤としての効果のみのため焼入性には効果が少ない。ま
た0、80%を越えて添加すると冷間加工性と耐食性を
阻害するので、0.30〜0.80%とした。Mn: 0.30-0.80% Mn has the effect of deoxidizing agent like Si, but also has the effect of improving hardenability. The 0.30% powder droplet only has an effect as a deoxidizing agent and has little effect on hardenability. Moreover, if added in excess of 0.80%, cold workability and corrosion resistance will be impaired, so the content was set at 0.30 to 0.80%.
Cr : 6.0−8.0%
Crは、基地に固溶して強度を向上させ、またCと反応
して炭化物を形成する。この場合、C量によっては、巨
大なM、 C,型の炭化物を形成する。Cr: 6.0-8.0% Cr dissolves in the matrix to improve strength, and reacts with C to form carbide. In this case, depending on the amount of C, huge M, C, type carbides are formed.
冷間加工上、M、C,の巨大炭化物は有害であるが、C
rが6.0%未満では添加物そのものの生成量が少なく
、耐摩耗性が劣る。また、Crを8.0%を越えて添加
するとM、C,の巨大炭化物が多量に形成され冷間加工
性を阻害する。したがってCrの範囲を6.0〜8.0
%とした。Giant carbides of M and C are harmful during cold working, but C
When r is less than 6.0%, the amount of the additive itself produced is small, resulting in poor wear resistance. Furthermore, if Cr is added in an amount exceeding 8.0%, a large amount of giant carbides of M and C will be formed, impeding cold workability. Therefore, the range of Cr is 6.0 to 8.0.
%.
Mo : 0.50−1.20%
MoはCrと同様に基地に固溶してこれを強化し、また
耐食性を向上させる。 0.50%未満ではその効果は
少なく、1.20%を越えて添加しても添加量に見合う
効果が得られない。したがって0.50〜1.20%と
した。Mo: 0.50-1.20% Mo, like Cr, forms a solid solution in the matrix to strengthen it and improve corrosion resistance. If it is less than 0.50%, the effect is small, and if it is added in excess of 1.20%, the effect commensurate with the amount added cannot be obtained. Therefore, it was set at 0.50 to 1.20%.
V : 0.20〜0.50%、Nb:0.03〜0.
07%■は微細なVC炭化物を形成し、強度を向上させ
る。0.20%未満ではその効果が少なく、0.50%
を越えて添加すると巨大なVC炭化物となって、冷間加
工性を低下するため0.20〜0.50%とした。また
、Nbは■と同様の作用効果をもたらすので、複合添加
することができるが、■に比較し固溶度が低いため、■
の添加量の約177にする必要があり、0.03%以下
では添加効果が小さく、0.07%よりも多量に添加す
ると巨大なNbCを生成して冷間加工性を阻害する。V: 0.20-0.50%, Nb: 0.03-0.
07% ■ forms fine VC carbides and improves strength. If it is less than 0.20%, the effect is small, and 0.50%
If it is added in excess of this amount, it becomes a huge VC carbide and deteriorates cold workability, so the content was set at 0.20 to 0.50%. In addition, Nb can be added in combination because it has the same effect as ■, but it has a lower solid solubility compared to ■.
It is necessary to add approximately 177% of NbC, and if it is less than 0.03%, the effect of addition will be small, and if it is added in an amount greater than 0.07%, a huge amount of NbC will be generated and the cold workability will be inhibited.
次に本発明の実施例について説明する。 Next, examples of the present invention will be described.
第1表に、本発明鋼の実施例および比較鋼(SKDll
)の化学成分およびそれらの評価結果をまとめて示す。Table 1 shows examples of the steel of the present invention and comparative steel (SKDll
) chemical components and their evaluation results are summarized below.
本発明の実施例N011〜8と比較鋼5KDIIを、真
空中で溶解(20kg)、鋳造し、鍛伸により直径15
mmの棒鋼とし、焼鈍を行なって供試材とした。Examples N011 to 8 of the present invention and comparative steel 5KDII were melted (20 kg) in vacuum, cast, and forged to a diameter of 15 mm.
It was made into a steel bar with a thickness of mm, and was annealed to prepare a test material.
冷間加工性の評価は、日本塑性加工学会冷間鍛造分科会
の冷間据込み性試験法(暫定基準:cf。Cold workability was evaluated using the cold upsetting test method (temporary standard: cf) of the Cold Forging Subcommittee of the Japan Society of Plasticity Working.
塑性と加工vo1.22 No241 P138)に準
拠して行ない、第1表中の最大据込率は、第1図(本発
明鋼N018と比較鋼5KDIIについて、据込み率に
対する累積割れ発生率の関係を示す図)から判るように
割れの発生しない最大の据込率である。第1表から本発
明の各実施例鋼は、従来の5KDIl鋼の最大据込率5
5%に対し、最低でも71%と大幅に向上していること
がわかる。Plasticity and Processing Vol. 1.22 No. 241 P138), and the maximum upsetting rates in Table 1 are as shown in Figure 1 (Relationship of Cumulative Crack Occurrence Rate to Upsetting Rate for Inventive Steel N018 and Comparative Steel 5KDII) This is the maximum upsetting rate without cracking. From Table 1, each example steel of the present invention has a maximum upsetting rate of 5 of the conventional 5KDIl steel.
It can be seen that this is a significant improvement of at least 71% compared to 5%.
第2図は、本発明実施例N007と比較鋼(SKDII
)の焼鈍状態でのミクロ組織写真を示すものであり、同
様の観察によるミクロ組織判定結果を第1表に示す。第
1表、第2図から本発明鋼は巨大炭化物は認められず、
このことからも本発明鋼が5KDIIに対し、冷間加工
性で優位性を示すことが理解できる。Figure 2 shows Example No. 007 of the present invention and comparative steel (SKDII).
) shows a photograph of the microstructure in an annealed state, and Table 1 shows the results of microstructure evaluation based on similar observation. From Table 1 and Figure 2, no giant carbides were observed in the steel of the present invention.
From this, it can be understood that the steel of the present invention is superior to 5KDII in cold workability.
第1表の硬さ値は、1030℃空冷焼入、200℃X1
hr焼もどしの熱処理材について測定したもので、これ
によると本発明鋼の焼入、焼もどし硬さは、5KDII
とほぼ同等であることがわかる。The hardness values in Table 1 are 1030℃ air-cooled quenching, 200℃X1
The hardness of the quenched and tempered steel of the present invention is 5KDII.
It can be seen that they are almost equivalent.
第3図は、上記硬さ試験と同条件の熱処理材における大
越式摩耗試験の概要と、それによる本発明鋼N001と
N o、8および5KDIIについての結果をまとめた
ものであり、第1表に他の本発明鋼についての結果をま
とめた。ここでA−またはA−は、Aに対しやや劣るこ
とを示す。これによると本発明鋼は、5KDIIに対し
やや劣る耐摩耗特性を有することがわかる。Figure 3 summarizes the outline of the Okoshi type wear test on heat-treated materials under the same conditions as the hardness test described above, and the results for the invention steels No. 001, No. 8, and 5KDII. The results for other steels of the present invention are summarized below. Here, A- or A- indicates that it is slightly inferior to A. This shows that the steel of the present invention has wear resistance properties that are slightly inferior to 5KDII.
以上述べたように、本発明はC0.70〜0.95%、
S i 0.50〜1.00%、Mn 0.30−0.
80%、Cr 6.0−8.0%、Mo 0.50−1
.20%、V 0.20〜0o50%または、さらにN
b 0.03−0.07%、残部Feからなるもので、
従来の5KDIIに比較するとやや劣るが、実用上十分
な耐摩耗性を兼備しつつ、大幅に冷間加工性を改善する
ものである。さらに素材コストはほぼ同等であり、例え
ばパルプリフターを本発明鋼で製造する場合には、従来
の切削加工法に代えて冷間鍛造法が採用できるのでトー
タルのコストが下げられ、その効果は非常に大きい。As mentioned above, the present invention has C0.70 to 0.95%,
Si 0.50-1.00%, Mn 0.30-0.
80%, Cr 6.0-8.0%, Mo 0.50-1
.. 20%, V 0.20~0o50% or more N
b 0.03-0.07%, the balance consisting of Fe,
Although it is slightly inferior to conventional 5KDII, it has practically sufficient wear resistance and significantly improves cold workability. Furthermore, the material costs are almost the same; for example, when manufacturing a pulp lifter using the steel of the present invention, a cold forging method can be used instead of the conventional cutting method, which reduces the total cost and is extremely effective. big.
第1図は、本発明実施例No、8および比較鋼5KD1
1についての冷間据込み試験結果の一例を示す図、施例
No、1.8および比較鋼5KDI 1の大越式摩耗試
験結果と試験概要を示す図である。
第
図
鄭
′)ソ1
本発明鋼P= f) 、 7
(×コjす)
S K ’J、’) 、1 二
rX:oちJ
第
図
、scpヅ21ソンク“Figure 1 shows Example No. 8 of the present invention and comparative steel 5KD1.
1 is a diagram showing an example of a cold upsetting test result for Example No. 1.8, and a diagram showing an Okoshi type wear test result and test summary for Example No. 1.8 and comparative steel 5KDI 1. FIG. Fig. Zheng') So1 Invention steel P= f), 7 (×kojsu) S K 'J,'), 1 2rX: ochiJ
Claims (1)
1.00%、Mn0.30〜0.80%、Cr6.0〜
8.0%、Mo0.50〜1.20%V0.20〜0.
50%、Fe残部および不可避的不純物よりなることを
特徴とする冷間鍛造用鋼。 2 重量比でC0.70〜0.95%、Si0.50〜
1.00%、Mn0.30〜0.80%、Cr6.0〜
8.0%、Mo0.50〜1.20%、V0.20〜0
.50%、Nb0.03〜0.07%、Fe残部および
不可避的不純物よりなることを特徴とする冷間鍛造用鋼
。[Claims] 1. C0.70-0.95%, Si0.50-0.50% by weight
1.00%, Mn0.30~0.80%, Cr6.0~
8.0%, Mo0.50-1.20%V0.20-0.
A steel for cold forging characterized by comprising 50% Fe, the balance Fe and unavoidable impurities. 2 Weight ratio: C0.70~0.95%, Si0.50~
1.00%, Mn0.30~0.80%, Cr6.0~
8.0%, Mo0.50-1.20%, V0.20-0
.. 50% Nb, 0.03 to 0.07% Nb, the balance Fe and unavoidable impurities.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2177690A JPH03226548A (en) | 1990-01-31 | 1990-01-31 | Steel for cold forging |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2177690A JPH03226548A (en) | 1990-01-31 | 1990-01-31 | Steel for cold forging |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH03226548A true JPH03226548A (en) | 1991-10-07 |
Family
ID=12064467
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2177690A Pending JPH03226548A (en) | 1990-01-31 | 1990-01-31 | Steel for cold forging |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH03226548A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5492573A (en) * | 1993-04-19 | 1996-02-20 | Hitachi Metals, Ltd. | High-strength stainless steel for use as material of fuel injection nozzle or needle for internal combustion engine, fuel injection nozzle made of the stainless steel |
-
1990
- 1990-01-31 JP JP2177690A patent/JPH03226548A/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5492573A (en) * | 1993-04-19 | 1996-02-20 | Hitachi Metals, Ltd. | High-strength stainless steel for use as material of fuel injection nozzle or needle for internal combustion engine, fuel injection nozzle made of the stainless steel |
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