JPH03223380A - Anisotropic conductive adhesive - Google Patents

Anisotropic conductive adhesive

Info

Publication number
JPH03223380A
JPH03223380A JP2029190A JP2029190A JPH03223380A JP H03223380 A JPH03223380 A JP H03223380A JP 2029190 A JP2029190 A JP 2029190A JP 2029190 A JP2029190 A JP 2029190A JP H03223380 A JPH03223380 A JP H03223380A
Authority
JP
Japan
Prior art keywords
conductive filler
adhesive
anisotropic conductive
conductive adhesive
semiconductor element
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2029190A
Other languages
Japanese (ja)
Inventor
Yoshiro Takahashi
高橋 良郎
Toshimitsu Yamashita
山下 俊光
Kazuo Tokura
戸倉 和男
Yoshinori Arao
荒尾 義範
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Oki Electric Industry Co Ltd
Original Assignee
Oki Electric Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Oki Electric Industry Co Ltd filed Critical Oki Electric Industry Co Ltd
Priority to JP2029190A priority Critical patent/JPH03223380A/en
Publication of JPH03223380A publication Critical patent/JPH03223380A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00Apparatus or processes for manufacturing printed circuits
    • H05K3/30Assembling printed circuits with electric components, e.g. with resistor
    • H05K3/32Assembling printed circuits with electric components, e.g. with resistor electrically connecting electric components or wires to printed circuits
    • H05K3/321Assembling printed circuits with electric components, e.g. with resistor electrically connecting electric components or wires to printed circuits by conductive adhesives

Landscapes

  • Adhesives Or Adhesive Processes (AREA)
  • Conductive Materials (AREA)

Abstract

PURPOSE:To obtain the title adhesive which is used for bonding a semiconductor element to a circuit board and can improve the heat dissipation characteristics of the semiconductor element by mixing an adhesive resin, a specified electrically conductive filler, and a specified thermally conductive filler. CONSTITUTION:The title adhesive is formed by mixing an adhesive resin (e.g. epoxy resin), an electrically conductive filler (e.g. an Ni powder) having an almost uniform particle diameter, and a thermally conductive filler (e.g. an Al2O3 powder) having electrical insulating properties, a thermal conductivity higher than that of the adhesive resin, and a particle diameter smaller than that of the electrically conductive filler.

Description

【発明の詳細な説明】 〈産業上の利用分野〉 本発明は、発熱量が大きい半導体素子等を実装するのに
用いる異方性導電接着剤に関する。
DETAILED DESCRIPTION OF THE INVENTION <Industrial Application Field> The present invention relates to an anisotropic conductive adhesive used for mounting semiconductor elements and the like that generate a large amount of heat.

〈従来の技術〉 従来の異方性導電接着剤は、電気絶縁性を有する接着樹
脂と、電気伝導性を有する金属で形成した導電フィラー
とを混合して成る。
<Prior Art> Conventional anisotropic conductive adhesives are made by mixing an adhesive resin with electrical insulation properties and a conductive filler made of a metal with electrical conductivity.

次に第2図に示す実装構造の断面図により、上記従来の
異方性導電接着剤を用いて回路基板上に半導体素子を実
装した実装構造を説明する。
Next, a mounting structure in which a semiconductor element is mounted on a circuit board using the conventional anisotropic conductive adhesive described above will be described with reference to a cross-sectional view of the mounting structure shown in FIG.

図に示す如く、従来の実装構造は、回路基板21と半導
体素子23とを前記従来の異方性導電接着剤25を介し
て接着する。
As shown in the figure, in the conventional mounting structure, a circuit board 21 and a semiconductor element 23 are bonded together via the conventional anisotropic conductive adhesive 25.

回路基板21と半導体素子23との電気的接続は、回路
基板2】に設けた基板電極22と半導体素子23の接続
端子部23aに設けた/<ンプ電極24との間に挾まれ
た前記従来の異方性導電接着剤25中の導電フィラー2
8aを介して成される。この導電フィラー26aは接着
時に押圧されて押しつぶされる。
The electrical connection between the circuit board 21 and the semiconductor element 23 is made using the conventional method which is sandwiched between the board electrode 22 provided on the circuit board 2 and the /< pump electrode 24 provided on the connection terminal portion 23a of the semiconductor element 23. Conductive filler 2 in anisotropic conductive adhesive 25 of
8a. This conductive filler 26a is pressed and crushed during adhesion.

よって基板電極22とバンプ電極24との接続が確かな
ものになる。
Therefore, the connection between the substrate electrode 22 and the bump electrode 24 becomes reliable.

更に前記従来の異方性導電接着剤25は硬化される。Furthermore, the conventional anisotropic conductive adhesive 25 is cured.

又基板電極22とバンプ電極24との間以外の導電フィ
ラー2Eibは、異方性導電接着剤25中に浮遊した状
態で固定される。
Further, the conductive filler 2Eib other than between the substrate electrode 22 and the bump electrode 24 is fixed in a floating state in the anisotropic conductive adhesive 25.

よって基板電極22とバンプ電極24との接続部以外で
は、電気的導通が生じない。
Therefore, no electrical continuity occurs except at the connection portion between the substrate electrode 22 and the bump electrode 24.

又前記バンプ電極24を設けないで、前記接続端子部2
3aと前記基板電極22とを異方性導電接着剤で上記同
様に接続してもよい。
Moreover, the connection terminal portion 2 is not provided with the bump electrode 24.
3a and the substrate electrode 22 may be connected in the same manner as described above using an anisotropic conductive adhesive.

〈発明が解決しようとする課題〉 しかしながら、上記した従来の異方性導電接着剤を用い
た実装構造によれば、消費電力が大きい半導体素子を実
装した場合に、半導体素子内で発生した熱の放熱手段は
、熱伝導性の悪い樹脂を通した回路基板への熱伝導と、
半導体素子表面よりの熱放射とによる。よって半導体素
子の放熱が十分性われないために、半導体素子の温度が
上昇し過ぎて、回路の動作不良を生じてしまう、又半導
体素子の発熱によって樹脂が熱膨張を起こし、接続不良
を発生してしまう、これらの不良は接着樹脂が熱可塑性
樹脂の場合、特に顕著に現れる。
<Problems to be Solved by the Invention> However, according to the above-mentioned conventional mounting structure using an anisotropic conductive adhesive, when a semiconductor element with large power consumption is mounted, the heat generated within the semiconductor element is Heat dissipation means include heat conduction to the circuit board through resin with poor thermal conductivity,
This is due to heat radiation from the surface of the semiconductor element. As a result, heat dissipation from the semiconductor element is not sufficient, causing the temperature of the semiconductor element to rise too much, resulting in malfunction of the circuit.Also, the heat generated by the semiconductor element causes thermal expansion of the resin, resulting in poor connection. These defects appear particularly when the adhesive resin is a thermoplastic resin.

又半導体素子の高集積化にともなって消費電力が大きく
なるので、発熱量が大きい超LSI等の半導体素子の実
装に対して大きな障害になっていた。
Furthermore, as semiconductor devices become more highly integrated, their power consumption increases, which poses a major obstacle to the mounting of semiconductor devices such as ultra-LSIs that generate a large amount of heat.

〈課題を解決するための手段〉 本発明は、上記した課題を解決する為に成されたもので
、半導体素子の放熱特性に優れた異方性導電接着剤を提
供することを目的とする。
<Means for Solving the Problems> The present invention was made in order to solve the above problems, and an object of the present invention is to provide an anisotropic conductive adhesive having excellent heat dissipation properties for semiconductor devices.

即ち、接着樹脂と、電気伝導性を有するとともに略均一
な粒子径を有する導電フィラーと、電気絶縁性を有する
とともに熱伝導率が前記接着樹脂より高いものであって
、前記導電フィラーの粒子径より小さい粒子径を有する
熱伝導フィラーとを混合して成るものである。
That is, an adhesive resin, a conductive filler having electrical conductivity and a substantially uniform particle size, and a material having electrical insulation properties and a thermal conductivity higher than that of the adhesive resin, which has a particle size larger than that of the conductive filler. It is made by mixing a thermally conductive filler with a small particle size.

更には前記異方性導電接着剤の熱膨張率と被接着体の熱
膨張率とが略一致する量の前記熱伝導フィラーを前記異
方性導電接着剤に混合したものである。
Furthermore, the anisotropic conductive adhesive is mixed with the thermally conductive filler in an amount such that the coefficient of thermal expansion of the anisotropic conductive adhesive and the coefficient of thermal expansion of the adherend substantially match.

〈作用〉 上記構成の異方性導電接着剤は、電気絶縁性を右すると
ともに、熱伝導率が接着樹脂よりも高くかつ導電フィラ
ーの粒子径より小さい粒子径を有する熱伝導フィラーを
混合したことにより、異方性導電接着剤を用いて接着し
た半導体素子より発生した熱を伝導して、半導体素子の
温度上昇を防止する。
<Function> The anisotropic conductive adhesive having the above structure has a thermally conductive filler mixed therein which not only improves electrical insulation but also has a thermal conductivity higher than that of the adhesive resin and a particle size smaller than that of the conductive filler. This conducts the heat generated by the semiconductor element bonded using the anisotropic conductive adhesive, thereby preventing the temperature of the semiconductor element from rising.

又熱伝導フィラーの混合量を調節して異方性導電接着剤
の熱膨張率を被接着体の熱膨張率に略−致させたことに
より、異方性導電接着剤と被接着体との熱膨張差により
異方性導電接着剤と被接着体との剥離を防止する。
In addition, by adjusting the mixing amount of the thermally conductive filler to approximately match the thermal expansion coefficient of the anisotropic conductive adhesive to the thermal expansion coefficient of the adherend, the relationship between the anisotropic conductive adhesive and the adherend is improved. The difference in thermal expansion prevents separation between the anisotropic conductive adhesive and the object to be adhered.

更に接着樹脂が被接着体どうしを接着するとともに導電
フィラーが電極どうしを電気的に接続する。
Further, the adhesive resin adheres the objects to be adhered to each other, and the conductive filler electrically connects the electrodes to each other.

〈実施例〉 本発明の実施例を以下に説明する。<Example> Examples of the present invention will be described below.

異方性導電接着剤は、接着に寄与する接着樹脂、例えば
電気絶縁性を有するエポキシ樹脂やシリコン樹脂が用い
られる。前記接着樹脂は導電フィラーと熱伝導フィラー
とが混合される。
As the anisotropic conductive adhesive, an adhesive resin that contributes to adhesion, such as an epoxy resin or silicone resin having electrical insulation properties, is used. The adhesive resin is a mixture of a conductive filler and a thermally conductive filler.

前記導電フィラーは、電気伝導性を有するとともに略均
一な粒子径を有する金属粒子が用いられる。この金属に
は粒−子径が30JLm前後のニー2ケルや半田等が用
いられる。当然のことながらこれらに限定されることは
ない。
As the conductive filler, metal particles having electrical conductivity and a substantially uniform particle size are used. As this metal, a needle, solder, or the like having a particle size of about 30 JLm is used. Naturally, it is not limited to these.

前記熱伝導フィラーは、電気絶縁性を有するとともに、
前記接着樹脂よりも熱伝導性に優れていてかつ前記導電
フィラーの粒子径より小さい粒子径を有する粒子が用い
られる。この粒子には酸化アルミニウム(Al103)
や窒化アルミニウム(A立N)等が用いられる。
The thermally conductive filler has electrical insulation properties, and
Particles are used that have better thermal conductivity than the adhesive resin and have a particle size smaller than the particle size of the conductive filler. This particle contains aluminum oxide (Al103)
or aluminum nitride (A-N).

次に第1図に示す実装構造の断面図より、異方性導電接
着剤の接着構造を説明する。
Next, the bonding structure of the anisotropic conductive adhesive will be explained with reference to the cross-sectional view of the mounting structure shown in FIG.

回路基板11には電気伝導性の銅や金等の基板電極12
を配設する。−男手導体素子13には接続端子部13a
に金や銅等の金属よりなるバンプ電極14を配設する。
The circuit board 11 has an electrically conductive board electrode 12 made of copper, gold, etc.
Place. - The male hand conductor element 13 has a connecting terminal portion 13a.
A bump electrode 14 made of metal such as gold or copper is provided on the surface.

前記回路基板(被接着体)11と前記半導体素子(被接
着体)13とは上記した異方性導電接着剤15を介して
圧着される。又圧着時には、前記パンプ゛心棒14は所
定の前記基板電極12に対して前記異方性導電接着剤1
5中の導電フィラーleaを介して電気的に接続される
。この時、導電フィラー16は基板電極12とバンプ電
極14との間に挾まれて押しつぶされる。よって基板電
極12とバンプ電極14との′I扛気気的接続確かなも
のになる。
The circuit board (object to be bonded) 11 and the semiconductor element (object to be bonded) 13 are pressure bonded via the above-described anisotropic conductive adhesive 15. Further, during crimping, the pump shaft 14 is pressed against the anisotropic conductive adhesive 1 to the predetermined substrate electrode 12.
It is electrically connected through the conductive filler lea in 5. At this time, the conductive filler 16 is sandwiched between the substrate electrode 12 and the bump electrode 14 and crushed. Therefore, the pneumatic connection between the substrate electrode 12 and the bump electrode 14 is ensured.

又、電気的接続に関与した導電フィラーleaを除く他
の導電フィラー16bは、接着樹脂18中に浮遊した状
態で固定される。よって隣接する導電フィラー18b間
の導電性はない。
Further, the conductive filler 16b other than the conductive filler lea involved in electrical connection is fixed in a floating state in the adhesive resin 18. Therefore, there is no conductivity between adjacent conductive fillers 18b.

一方、前記異方性導電接着剤15中の熱伝導フィラー1
7は、前記導電フィラーIEia、16bより小さい粒
7−径を有しているので、圧着による変形を受けること
なく、接着樹脂18中に浮遊した状態で固定される。
On the other hand, the thermally conductive filler 1 in the anisotropic conductive adhesive 15
Since the particles 7 have a smaller diameter than the conductive fillers IEia and 16b, they are fixed in a floating state in the adhesive resin 18 without being deformed by pressure bonding.

更に前記接着樹脂18は硬化される。Further, the adhesive resin 18 is cured.

上記した接着構造では、半導体素子13で発生した熱を
、熱伝導フィラー17と導電フィラー16a。
In the adhesive structure described above, heat generated in the semiconductor element 13 is transferred to the thermally conductive filler 17 and the conductive filler 16a.

16bとの双方により回路基板llに対して熱伝導によ
り放熱する。
16b and radiates heat to the circuit board 11 by thermal conduction.

上記説明では、バンプ電極14を設けて基板電極12と
電気的に接続したが、前記接a1fi子部13aと基板
電極12とを異方性導電接着剤15で上記同様に接続し
てもよい。
In the above description, the bump electrode 14 is provided and electrically connected to the substrate electrode 12, but the contact portion 13a and the substrate electrode 12 may be connected using the anisotropic conductive adhesive 15 in the same manner as described above.

又前記接着樹脂18による接着力を維持するとともに、
前記導電フィラーIEiaによる電気的接続性能を確保
する範囲内で、前記熱伝導フィラー17の混合率は変え
られる。
In addition, while maintaining the adhesive force due to the adhesive resin 18,
The mixing ratio of the thermally conductive filler 17 can be varied within a range that ensures electrical connection performance by the conductive filler IEia.

よって、前記熱伝導フィラー17の混合率を変えること
によって、半導体素子13の熱伝導率や回路基板11の
熱伝導率に近い熱伝導率を有する異方性導電接着剤15
を得る。
Therefore, by changing the mixing ratio of the thermally conductive filler 17, an anisotropic conductive adhesive 15 having a thermal conductivity close to that of the semiconductor element 13 or the circuit board 11 can be obtained.
get.

例えば、酸化アルミニウム製の回路基板11とシリコン
基板を用いた半導体素子11とを、接着樹脂18にエポ
キシ樹脂を用いた異方性導電接着剤15で接着する場合
には、10Bm乃至20井■の粒子径を有する酸化アル
ミニウム粒子より成る熱伝導フィラー17を20%(体
積比)R合する。当然のことながら、上記数値的等の条
件はそれに限定されないこと明らかである。
For example, when bonding a circuit board 11 made of aluminum oxide and a semiconductor element 11 made of a silicon substrate with an anisotropic conductive adhesive 15 using an epoxy resin as the adhesive resin 18, 20% (volume ratio) of thermally conductive filler 17 made of aluminum oxide particles having a particle size is combined. Naturally, it is clear that the above numerical conditions are not limited thereto.

従って、半導体素子−13で温度上昇が生じても、導’
11i、フィラーleaを介して接続した基板電極12
やパップ電極14に生じる応力が大幅に低減される。
Therefore, even if the temperature rises in the semiconductor element-13, the conduction
11i, substrate electrode 12 connected via filler lea
The stress generated in the pad electrode 14 is significantly reduced.

〈発明の効果〉 以L、説明したように本発明によれば、異方性導電接着
剤に熱伝導フィラーを混入したので、異方性導電接着剤
の熱伝導率を高めることができる。よって発熱ψが大き
い半導体素子を接着によって回路基板に接続することが
できるとともに、完熟による半導体素子の動作不良を防
止できる。
<Effects of the Invention> As explained below, according to the present invention, since the thermally conductive filler is mixed into the anisotropic conductive adhesive, the thermal conductivity of the anisotropic conductive adhesive can be increased. Therefore, a semiconductor element that generates a large amount of heat ψ can be connected to a circuit board by adhesion, and malfunction of the semiconductor element due to overripe can be prevented.

又熱伝導フィラーの混合率をかえて異方性導電接着剤の
熱伝導率を半導体素子等の被接着体の熱伝導率に近づけ
たので、被接着体の温度が上昇して熱膨張を起こした場
合の電極接続部の応力を小さくできる。
In addition, by changing the mixing ratio of the thermally conductive filler, the thermal conductivity of the anisotropic conductive adhesive was brought close to that of the adhered object such as a semiconductor element, which caused the temperature of the adhered object to rise and cause thermal expansion. It is possible to reduce the stress at the electrode connection part when the electrode is connected.

よって電気的接続不良が防止できる。Therefore, electrical connection failures can be prevented.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は、実施例の実装構造の断面図、第2図は、従来
の実装構造の断面図である。 15・・・異方性導電接着剤。 IEi、lea、IEib・・・導電フィラー17・・
・熱伝導フィラー、18・・・接着樹脂。
FIG. 1 is a sectional view of a mounting structure of an embodiment, and FIG. 2 is a sectional view of a conventional mounting structure. 15...Anisotropic conductive adhesive. IEi, lea, IEib...conductive filler 17...
- Thermal conductive filler, 18...Adhesive resin.

Claims (2)

【特許請求の範囲】[Claims] (1)接着樹脂と、 電気伝導性を有するとともに略均一な粒子型を有する導
電フィラーと、 電気絶縁性を有するとともに熱伝導率が前記接着樹脂よ
り高いものであって、前記導電フィラーの粒子径より小
さい粒子径を有する熱伝導フィラーとを混合して成るこ
とを特徴とする異方性導電接着剤。
(1) an adhesive resin; a conductive filler that has electrical conductivity and a substantially uniform particle shape; and a conductive filler that has electrical insulation and a higher thermal conductivity than the adhesive resin, and a particle size of the conductive filler. An anisotropic conductive adhesive characterized by being mixed with a thermally conductive filler having a smaller particle size.
(2)前記異方性導電接着剤の熱膨張率と被接着体の熱
膨張率とが略一致する量の前記熱伝導フィラーを前記異
方性導電接着剤に混合したことを特徴とする請求項1記
載の異方性導電接着剤。
(2) A claim characterized in that the thermally conductive filler is mixed into the anisotropic conductive adhesive in an amount such that the coefficient of thermal expansion of the anisotropic conductive adhesive and the coefficient of thermal expansion of the adhered object substantially match each other. Item 1. Anisotropic conductive adhesive according to item 1.
JP2029190A 1990-01-30 1990-01-30 Anisotropic conductive adhesive Pending JPH03223380A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2029190A JPH03223380A (en) 1990-01-30 1990-01-30 Anisotropic conductive adhesive

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2029190A JPH03223380A (en) 1990-01-30 1990-01-30 Anisotropic conductive adhesive

Publications (1)

Publication Number Publication Date
JPH03223380A true JPH03223380A (en) 1991-10-02

Family

ID=12023064

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2029190A Pending JPH03223380A (en) 1990-01-30 1990-01-30 Anisotropic conductive adhesive

Country Status (1)

Country Link
JP (1) JPH03223380A (en)

Cited By (19)

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US5410806A (en) * 1993-09-15 1995-05-02 Lsi Logic Corporation Method for fabricating conductive epoxy grid array semiconductors packages
US5686703A (en) * 1994-12-16 1997-11-11 Minnesota Mining And Manufacturing Company Anisotropic, electrically conductive adhesive film
WO2000048206A1 (en) * 1999-02-09 2000-08-17 Do-Coop Technologies Ltd. Materials and composites activable into a state of enhanced conductivity
KR100305750B1 (en) * 1999-03-10 2001-09-24 윤덕용 Manufacturing Method for Anisotropic Conductive Adhesive for Flip Chip Interconnection on an Organic Substrate
WO2003000816A1 (en) * 2001-06-25 2003-01-03 Telephus, Inc. Anisotropic conductive adhesives having enhanced viscosity and bonding methods and integrated circuit packages using the same
WO2004055126A1 (en) * 2002-12-13 2004-07-01 Ls Cable Ltd. Anisotropic-electroconductive adhesive, circuit connection method and structure using the same
US6884833B2 (en) 2001-06-29 2005-04-26 3M Innovative Properties Company Devices, compositions, and methods incorporating adhesives whose performance is enhanced by organophilic clay constituents
KR100710957B1 (en) * 2006-01-03 2007-04-24 엘에스전선 주식회사 Anisotropic-electroconductive adhesive, circuit connection using the same, and circuit connection structure
JP2007107008A (en) * 2006-11-13 2007-04-26 Hitachi Chem Co Ltd Film-shaped adhesive and method for producing laminate
JP2007113012A (en) * 2006-11-13 2007-05-10 Hitachi Chem Co Ltd Adhesive for connecting circuit part
JP2007335889A (en) * 2007-08-06 2007-12-27 Hitachi Chem Co Ltd Adhesive for circuit member connection
JP2008123851A (en) * 2006-11-13 2008-05-29 Kitagawa Ind Co Ltd Contact
WO2009133901A1 (en) * 2008-04-28 2009-11-05 日立化成工業株式会社 Circuit connecting material, film-like adhesive, adhesive reel, and circuit connecting structural body
JP2009289729A (en) * 2008-04-28 2009-12-10 Hitachi Chem Co Ltd Anisotropic conductive film
JP2010157753A (en) * 1997-02-14 2010-07-15 Hitachi Chem Co Ltd Adhesive for connecting circuit member
US7879445B2 (en) 1998-08-13 2011-02-01 Hitachi Chemical Company, Ltd. Adhesive for bonding circuit members, circuit board and process for its production
JP2012178400A (en) * 2011-02-25 2012-09-13 Toyoda Gosei Co Ltd Led lamp
CN102883519A (en) * 2011-07-15 2013-01-16 昆山雅森电子材料科技有限公司 Blind-hole type two-sided thermal-conduction circuit board and manufacturing process thereof
JP2016029740A (en) * 2010-11-08 2016-03-03 株式会社東芝 Led-based light source using asymmetrical conductor

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US5410806A (en) * 1993-09-15 1995-05-02 Lsi Logic Corporation Method for fabricating conductive epoxy grid array semiconductors packages
US5686703A (en) * 1994-12-16 1997-11-11 Minnesota Mining And Manufacturing Company Anisotropic, electrically conductive adhesive film
JP2010157753A (en) * 1997-02-14 2010-07-15 Hitachi Chem Co Ltd Adhesive for connecting circuit member
US8273458B2 (en) 1997-02-14 2012-09-25 Hitachi Chemical Company, Ltd. Adhesive for bonding circuit members, circuit board and process for its production
US8273457B2 (en) 1998-08-13 2012-09-25 Hitachi Chemical Company, Ltd. Adhesive for bonding circuit members, circuit board and process for its production
US8252419B2 (en) 1998-08-13 2012-08-28 Hitachi Chemical Company, Ltd. Adhesive for bonding circuit members, circuit board and process for its production
US7879445B2 (en) 1998-08-13 2011-02-01 Hitachi Chemical Company, Ltd. Adhesive for bonding circuit members, circuit board and process for its production
WO2000048206A1 (en) * 1999-02-09 2000-08-17 Do-Coop Technologies Ltd. Materials and composites activable into a state of enhanced conductivity
KR100305750B1 (en) * 1999-03-10 2001-09-24 윤덕용 Manufacturing Method for Anisotropic Conductive Adhesive for Flip Chip Interconnection on an Organic Substrate
WO2003000816A1 (en) * 2001-06-25 2003-01-03 Telephus, Inc. Anisotropic conductive adhesives having enhanced viscosity and bonding methods and integrated circuit packages using the same
US6884833B2 (en) 2001-06-29 2005-04-26 3M Innovative Properties Company Devices, compositions, and methods incorporating adhesives whose performance is enhanced by organophilic clay constituents
WO2004055126A1 (en) * 2002-12-13 2004-07-01 Ls Cable Ltd. Anisotropic-electroconductive adhesive, circuit connection method and structure using the same
KR100710957B1 (en) * 2006-01-03 2007-04-24 엘에스전선 주식회사 Anisotropic-electroconductive adhesive, circuit connection using the same, and circuit connection structure
JP4679492B2 (en) * 2006-11-13 2011-04-27 北川工業株式会社 contact
JP2007113012A (en) * 2006-11-13 2007-05-10 Hitachi Chem Co Ltd Adhesive for connecting circuit part
JP2008123851A (en) * 2006-11-13 2008-05-29 Kitagawa Ind Co Ltd Contact
JP2007107008A (en) * 2006-11-13 2007-04-26 Hitachi Chem Co Ltd Film-shaped adhesive and method for producing laminate
JP2007335889A (en) * 2007-08-06 2007-12-27 Hitachi Chem Co Ltd Adhesive for circuit member connection
JP2010183049A (en) * 2008-04-28 2010-08-19 Hitachi Chem Co Ltd Circuit connecting material, film-like adhesive, adhesive reel, and circuit connection structure
JP2009289729A (en) * 2008-04-28 2009-12-10 Hitachi Chem Co Ltd Anisotropic conductive film
WO2009133901A1 (en) * 2008-04-28 2009-11-05 日立化成工業株式会社 Circuit connecting material, film-like adhesive, adhesive reel, and circuit connecting structural body
JP2016029740A (en) * 2010-11-08 2016-03-03 株式会社東芝 Led-based light source using asymmetrical conductor
JP2012178400A (en) * 2011-02-25 2012-09-13 Toyoda Gosei Co Ltd Led lamp
CN102883519A (en) * 2011-07-15 2013-01-16 昆山雅森电子材料科技有限公司 Blind-hole type two-sided thermal-conduction circuit board and manufacturing process thereof

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