JPH0321600B2 - - Google Patents
Info
- Publication number
- JPH0321600B2 JPH0321600B2 JP59221109A JP22110984A JPH0321600B2 JP H0321600 B2 JPH0321600 B2 JP H0321600B2 JP 59221109 A JP59221109 A JP 59221109A JP 22110984 A JP22110984 A JP 22110984A JP H0321600 B2 JPH0321600 B2 JP H0321600B2
- Authority
- JP
- Japan
- Prior art keywords
- rinse
- layered clay
- dishes
- water
- cycle
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000004927 clay Substances 0.000 claims abstract description 19
- 239000000203 mixture Substances 0.000 claims abstract description 9
- AZJYLVAUMGUUBL-UHFFFAOYSA-A u1qj22mc8e Chemical compound [F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].O=[Si]=O.O=[Si]=O.O=[Si]=O.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3 AZJYLVAUMGUUBL-UHFFFAOYSA-A 0.000 claims abstract description 3
- 238000004851 dishwashing Methods 0.000 claims abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 11
- 238000005406 washing Methods 0.000 claims description 4
- 235000012211 aluminium silicate Nutrition 0.000 claims description 3
- 229910000278 bentonite Inorganic materials 0.000 claims description 3
- 239000000440 bentonite Substances 0.000 claims description 3
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 3
- QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical compound OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 claims description 3
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 3
- 229910000271 hectorite Inorganic materials 0.000 claims description 3
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 claims description 3
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 3
- 150000001298 alcohols Chemical class 0.000 claims description 2
- 238000005260 corrosion Methods 0.000 claims description 2
- 230000007797 corrosion Effects 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 claims description 2
- 239000003205 fragrance Substances 0.000 claims description 2
- 239000003752 hydrotrope Substances 0.000 claims description 2
- 239000003112 inhibitor Substances 0.000 claims description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 2
- 150000007524 organic acids Chemical class 0.000 claims description 2
- 235000005985 organic acids Nutrition 0.000 claims description 2
- 239000000080 wetting agent Substances 0.000 claims description 2
- 239000005995 Aluminium silicate Substances 0.000 claims 1
- 230000000844 anti-bacterial effect Effects 0.000 claims 1
- 239000003899 bactericide agent Substances 0.000 claims 1
- 229910001919 chlorite Inorganic materials 0.000 claims 1
- 229910052619 chlorite group Inorganic materials 0.000 claims 1
- 229910052900 illite Inorganic materials 0.000 claims 1
- VGIBGUSAECPPNB-UHFFFAOYSA-L nonaaluminum;magnesium;tripotassium;1,3-dioxido-2,4,5-trioxa-1,3-disilabicyclo[1.1.1]pentane;iron(2+);oxygen(2-);fluoride;hydroxide Chemical compound [OH-].[O-2].[O-2].[O-2].[O-2].[O-2].[F-].[Mg+2].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[K+].[K+].[K+].[Fe+2].O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2 VGIBGUSAECPPNB-UHFFFAOYSA-L 0.000 claims 1
- 229910021647 smectite Inorganic materials 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 229940094522 laponite Drugs 0.000 description 8
- XCOBTUNSZUJCDH-UHFFFAOYSA-B lithium magnesium sodium silicate Chemical compound [Li+].[Li+].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Na+].[Na+].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3 XCOBTUNSZUJCDH-UHFFFAOYSA-B 0.000 description 8
- 238000004140 cleaning Methods 0.000 description 5
- -1 volkonscoreite Substances 0.000 description 3
- 229910052626 biotite Inorganic materials 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 229910052902 vermiculite Inorganic materials 0.000 description 2
- 239000010455 vermiculite Substances 0.000 description 2
- 235000019354 vermiculite Nutrition 0.000 description 2
- 229910018068 Li 2 O Inorganic materials 0.000 description 1
- 239000004113 Sepiolite Substances 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 description 1
- 229910052898 antigorite Inorganic materials 0.000 description 1
- VNSBYDPZHCQWNB-UHFFFAOYSA-N calcium;aluminum;dioxido(oxo)silane;sodium;hydrate Chemical compound O.[Na].[Al].[Ca+2].[O-][Si]([O-])=O VNSBYDPZHCQWNB-UHFFFAOYSA-N 0.000 description 1
- 229910052620 chrysotile Inorganic materials 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- YGANSGVIUGARFR-UHFFFAOYSA-N dipotassium dioxosilane oxo(oxoalumanyloxy)alumane oxygen(2-) Chemical compound [O--].[K+].[K+].O=[Si]=O.O=[Al]O[Al]=O YGANSGVIUGARFR-UHFFFAOYSA-N 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 229910052621 halloysite Inorganic materials 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052622 kaolinite Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 229910052627 muscovite Inorganic materials 0.000 description 1
- 229910000273 nontronite Inorganic materials 0.000 description 1
- 229910052628 phlogopite Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229910052903 pyrophyllite Inorganic materials 0.000 description 1
- 229910000275 saponite Inorganic materials 0.000 description 1
- 229910000276 sauconite Inorganic materials 0.000 description 1
- 229910052624 sepiolite Inorganic materials 0.000 description 1
- 235000019355 sepiolite Nutrition 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000003826 tablet Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- CWBIFDGMOSWLRQ-UHFFFAOYSA-N trimagnesium;hydroxy(trioxido)silane;hydrate Chemical compound O.[Mg+2].[Mg+2].[Mg+2].O[Si]([O-])([O-])[O-].O[Si]([O-])([O-])[O-] CWBIFDGMOSWLRQ-UHFFFAOYSA-N 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
- C11D3/126—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in solid compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Abstract
Description
本発明は、皿洗い機にて皿を洗浄する方法のす
すぎサイクルにおける改善に関する。
皿洗い機にて皿を洗浄する一般的な方法では、
洗浄しようとする物品を先ず主洗浄サイクルで洗
浄し、次いで数回すすいで付着している洗浄剤及
び残りの汚れをすすぎ落す。すすぎ水には、通
常、物品を更に均一に乾燥させ且つ乾燥後の物品
の視覚的外観を改善するすすぎ助剤が添加され
る。このようなすすぎ助剤を添加したすすぎ液で
すすいだ物品の外観は、すすぎ助剤を添加しない
すすぎ液ですすいだ物品と比較して改善される
が、すすぎ助剤を使用しても、依然としてフイル
ムやスポツトが若干形成されることがある。
皿洗い機にて皿を洗浄する方法のすすぎサイク
ルで有効量の層状クレイを使用すると、乾燥後の
物品上にスポツトが殆んど形成されないことが知
見された。
従つて、本発明は皿洗い機にて皿を洗浄する方
法のすすぎサイクルにおける改善に関し、すすぎ
水に有効量の層状クレイを添加することを特徴と
する。
本発明で使用するに適する層状クレイは、スメ
クタイト、カオリン、イライト、クロライト、ア
タパルジヤイト及び混合層状クレイの地質学的群
に属する。これらの群に属する特定なクレイの代
表的なものを以下に例示する：
スメクタイト類；モンモリロナイト、ベントナイ
ト、パイロフイライト、ヘクトライト、サポ
ナイト、ソーコナイト、ノントロナイト、タ
ルク、バイデライト、ボルコンスコアイト、
バーミキユライト
カオリン類；カオリナイト、デイツカイト、ナク
ライト、アンチゴライト、アナウキサイト、
ハロイサイト、インデライト（indellite）、
クリソタイル
イライト類；ブラベサイト、白雲母、ソーダ雲
母、金雲母、黒雲母
クロライト類；コーレンサイト、ペンナンタイ
ト、ドンバスサイト、スドイト（sudoite）、
ペンニン、クリノクロア
アタパルジヤイト類；セピオライト、ポリゴルス
キイト（polygorskyte）
混合層状クレイ類；アレバルダイト、バーミキユ
ライトバイオタイト
層状クレイは、天然に存在するものでも合成の
ものでもよい。本発明で使用するのに好適なクレ
イ鉱物は天然又は合成のヘクトライト、モンモリ
ロナイト及びベントナイトであり、これらの中で
ヘクトライトが特に好適である。前記クレイの多
くは市販されており、市販ヘクトライトの代表的
なものとして、英国のLaporte Industries Ltdか
ら市販されているラポナイト（Laponites）、米
国のR.T.Vanderbietから市販されているビーガ
ム（Veegum）Pro及びビーガムＦ、米国の
Baroid Division Mational Read Comp.から市
販されているバラサイムス（Barasyms）、マカ
ロイド（Maca−Ioids）及びプロパロイド
（Propaloids）が挙げられる。
特に好適な市販ヘクトライトはラポナイトＳ、
ラポナイトXLS、ラポナイトRD及びラポナイト
RDSであり、これらの中でラポナイトXLSが特
に好ましい。ラポナイトXLSは次の特徴を有す
る合成ヘクトライトである；分析値（乾燥基
準）：SiO259.8％、MgO27.2％、Ma2O4.4％、
Li2O0.8％、構造水7.7％、ピロリン酸四ナトリウ
ム（６％）添加物；比重：2.53；カサ密度：1.0
層状クレイをそのまますすぎ水に添加してもよ
いが、層状クレイを水に分散させた分散液の形
で、又はクレイと少量の適当なもしくは望ましい
任意成分を含有する適当な形態の組成物の形で、
すすぎ水に添加することもできる。前記した成分
としては、湿潤剤（洗浄表面活性剤）、有機酸、
ハイドロトロープ、アルコール、香料、殺菌剤、
腐食防止剤等が挙げられる。組成物の適当な形態
は、粉末、液体、錠剤、ブロツク、顆粒等であ
る。
層状クレイの量は、すすぎ水が１当り0.001
〜１ｇを含有するような量であるべきである。層
状クレイを添加したすすぎ水はすすぎ水の温度が
高温でも低温でも有効である。
本発明を以下の実施例により更に説明する。
実施例 １
標準汚れで汚したタンブラーを、西独の
MieleAG製皿洗い機（Miele Ｇ 550）で洗浄し
た。洗浄を通常のプログラムに従つて65℃の温度
で実施した。9゜ドイツ硬度の水を使用した。市販
の皿洗い機用洗剤を３ｇ／の量使用した。
１つの実験ではラポナイトXLSを0.05ｇ／最
終すすぎ水に添加し、別の実験では最終すすぎ水
にクレイを添加しなかつた。
乾燥後のタンブラー上のスポツトの有無を、下
記の尺度により目視で評価した。
１＝スポツトなし
２＝１〜５個のスポツト
３＝６〜10個のスポツト
４＝11〜20個のスポツト
５＝20個より多いスポツト
下記の結果が得られた。
The present invention relates to improvements in the rinse cycle of a method of cleaning dishes in a dishwasher. The general method of cleaning dishes in a dishwasher is as follows:
The item to be cleaned is first cleaned in the main wash cycle and then rinsed several times to rinse off any adhering cleaning agent and remaining dirt. Rinse aids are typically added to the rinse water to dry the article more evenly and improve the visual appearance of the article after drying. Although the appearance of articles rinsed with rinse aids to which such rinse aids have been added is improved compared to articles rinsed with rinse aids to which no rinse aid has been added, the use of rinse aids still A slight film or spot may form. It has been found that when an effective amount of layered clay is used in the rinse cycle of a method of cleaning dishes in a dishwasher, fewer spots form on the dried items. The invention therefore relates to an improvement in the rinse cycle of a method for cleaning dishes in a dishwasher, characterized by the addition of an effective amount of layered clay to the rinse water. Layered clays suitable for use in the present invention belong to the geological group of smectites, kaolins, illites, chlorites, attapulgiaites and mixed layered clays. Representative examples of specific clays belonging to these groups include: Smectites; montmorillonite, bentonite, pyrophyllite, hectorite, saponite, sauconite, nontronite, talc, beidellite, volkonscoreite,
Vermiculite kaolins; kaolinite, dateskite, nacrite, antigorite, anauxite,
halloysite, indellite,
Chrysotile illites; brabesite, muscovite, soda mica, phlogopite, biotite chlorites; corensite, pennantite, donbassite, sudoite,
pennins, clinochlorite attapulgiites; sepiolite, polygorskyte; mixed layered clays; arevaldite, vermiculite biotite. Layered clays may be naturally occurring or synthetic. Clay minerals suitable for use in the present invention are natural or synthetic hectorite, montmorillonite and bentonite, of which hectorite is particularly preferred. Many of the above clays are commercially available, and typical examples of commercially available hectorites include Laponites, commercially available from Laporte Industries Ltd, UK, Veegum Pro, and Veegum, commercially available from RTVanderbiet, USA. F. of the United States
Examples include Barasyms, Maca-Ioids and Propaloids commercially available from Baroid Division Mational Read Comp. Particularly suitable commercially available hectorites include Laponite S,
Laponite XLS, Laponite RD and Laponite
RDS, and among these, Laponite XLS is particularly preferred. Laponite _
Li 2 O 0.8%, structured water 7.7%, tetrasodium pyrophosphate (6%) additives; Specific gravity: 2.53; Bulk density: 1.0 Layered clay may be added to the rinse water as is, but layered clay may be added to the water as is. in the form of a dispersed dispersion or in the form of a composition in a suitable form containing the clay and small amounts of suitable or desired optional ingredients;
It can also be added to the rinse water. The above-mentioned components include wetting agents (cleaning surfactants), organic acids,
hydrotropes, alcohols, fragrances, disinfectants,
Examples include corrosion inhibitors. Suitable forms of the composition are powders, liquids, tablets, blocks, granules and the like. The amount of layered clay is 0.001 per 1 rinse water.
The amount should be such that it contains ~1 g. Rinse water containing layered clay is effective regardless of whether the temperature of the rinse water is high or low. The invention is further illustrated by the following examples. Example 1 A tumbler soiled with standard dirt was
Washed in a Miele AG dishwasher (Miele G 550). Washing was carried out according to the usual program at a temperature of 65°C. Water with a German hardness of 9° was used. A commercially available dishwasher detergent was used in an amount of 3 g/ml. In one experiment, 0.05 g of Laponite XLS was added to the final rinse water, and in another experiment, no clay was added to the final rinse water. The presence or absence of spots on the tumbler after drying was visually evaluated using the following scale. 1 = No spots 2 = 1-5 spots 3 = 6-10 spots 4 = 11-20 spots 5 = More than 20 spots The following results were obtained.
【表】
実施例 ２
主洗浄サイクルで別の皿洗い機用洗剤を使用
し、すすぎサイクルにおいてすすぎ助剤を全く添
加しないか、又は市販のすすぎ助剤を添加する
か、又は下記組成を有する本発明のすすぎ助剤組
成物を使用して、実施例１を繰返した。
重量％
ラポナイトXLS 6.0
イソプロピルアルコール 2.0
低発泡性非イオン性表面活性剤 1.0
クエン酸３ナトリウム２水和物 2.5
水 88.5
すすぎ助剤は2.5ml（ラポナイトXLS0.015ｇ／
に相当する）使用した。
下記の結果が得られた。Table Example 2 The invention using a separate dishwasher detergent in the main wash cycle and adding no rinse aid or adding a commercially available rinse aid in the rinse cycle or having the following composition: Example 1 was repeated using the rinse aid composition. Weight% LAPONITE
) was used. The following results were obtained.
【表】
実施例 ３
本発明の適当なすすぎ助剤組成物の組成（重量
％）を下記に示す。Table: Example 3 The composition (% by weight) of a suitable rinse aid composition of the present invention is shown below.
【表】
実施例 ４
実施例１と同じ方法で、200mg／10のクレイ
を最終すすぎ水に添加して試験した。
下記の結果が得られた。Table: Example 4 Tested in the same manner as Example 1 with 200 mg/10 clay added to the final rinse water. The following results were obtained.
Claims (1)
サイクルで皿をすすぐことからなる皿洗い機にて
皿を洗浄する方法であつて、すすぎサイクルにお
いてすすぎ水１当り0.001〜１ｇの量の層状ク
レイをすすぎ水に添加することを特徴とする方
法。 ２ 層状クレイがスメクタイト、カオリン、イラ
イト、クロライト、アタパルジヤイト及び混合層
状クレイよりなる群から選択されることを特徴と
する特許請求の範囲第１項に記載の方法。 ３ 層状クレイがヘクトライト、モンモリロナイ
ト及びベントナイトよりなる群から選択されるこ
とを特徴とする特許請求の範囲第２項に記載の方
法。 ４ 層状クレイが合成ヘクトライトであることを
特徴とする特許請求の範囲第３項に記載の方法。 ５ 層状クレイをクレイ及び水を含む分散液の形
態で添加することを特徴とする特許請求の範囲第
１項〜第４項のいずれかに記載の方法。 ６ 皿洗い機のすすぎサイクル添加用すすぎ助剤
組成物であつて、水及び任意成分として湿潤剤、
有機酸、ハイドロトロープ、アルコール、香料、
殺菌剤及び／又は腐食防止剤を含有し、更に層状
クレイを、すすぎ水が１当り0.001〜１ｇの量
の層状クレイを含むような量含有することを特徴
とするすすぎ助剤組成物。[Scope of Claims] 1. A method for washing dishes in a dishwasher comprising washing the dishes in a main wash cycle and then rinsing the dishes in a rinse cycle, the method comprising: washing the dishes in a main wash cycle, and then rinsing the dishes in a rinse cycle, the method comprising: washing the dishes in a main wash cycle; A method characterized in that an amount of layered clay is added to the rinse water. 2. A method according to claim 1, characterized in that the layered clay is selected from the group consisting of smectite, kaolin, illite, chlorite, attapulgiaite and mixed layered clay. 3. Process according to claim 2, characterized in that the layered clay is selected from the group consisting of hectorite, montmorillonite and bentonite. 4. The method according to claim 3, characterized in that the layered clay is synthetic hectorite. 5. The method according to any one of claims 1 to 4, characterized in that the layered clay is added in the form of a dispersion containing clay and water. 6. A rinse aid composition for adding to the rinse cycle of a dishwasher, comprising water and optionally a wetting agent,
organic acids, hydrotropes, alcohols, fragrances,
1. A rinse aid composition, characterized in that it contains a bactericide and/or a corrosion inhibitor and further contains layered clay in an amount such that each rinse water contains layered clay in an amount of 0.001 to 1 g.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB838328077A GB8328077D0 (en) | 1983-10-20 | 1983-10-20 | Rinse aid |
| GB8328077 | 1983-10-20 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60110792A JPS60110792A (en) | 1985-06-17 |
| JPH0321600B2 true JPH0321600B2 (en) | 1991-03-25 |
Family
ID=10550501
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59221109A Granted JPS60110792A (en) | 1983-10-20 | 1984-10-20 | Rinsing aid |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP0139330B1 (en) |
| JP (1) | JPS60110792A (en) |
| AT (1) | ATE54326T1 (en) |
| AU (1) | AU566578B2 (en) |
| DE (1) | DE3482635D1 (en) |
| GB (1) | GB8328077D0 (en) |
| NO (1) | NO163963C (en) |
| PT (1) | PT79379B (en) |
| ZA (1) | ZA848108B (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8616615D0 (en) * | 1986-07-08 | 1986-08-13 | Unilever Plc | Rinse aid |
| ZA885894B (en) * | 1987-08-21 | 1990-04-25 | Colgate Palmolive Co | Thixotropic clay aqueous suspensions containing polycarboxylic acids and metal salts thereof stabilizers |
| US4828750A (en) * | 1987-12-02 | 1989-05-09 | Colgate-Polmolive Company | Fabric rinse composition to remove surfactant residues |
| DE3934675C1 (en) * | 1989-10-18 | 1991-05-23 | Joh. A. Benckiser Gmbh, 6700 Ludwigshafen, De | |
| AU2002230983A1 (en) * | 2001-01-30 | 2002-08-12 | The Procter And Gamble Company | Rinse aid surface coating compositions for modifying dishware surfaces |
| US8316684B2 (en) | 2003-08-28 | 2012-11-27 | Timberline Tool, L.L.C. | Clamp and repair tool |
| US8689599B2 (en) | 2003-08-28 | 2014-04-08 | Timberline Tool, L.L.C. | Clamp and repair tool |
| BRPI0413983A (en) * | 2003-08-28 | 2006-11-07 | Timberline Tool & Casting Inc | tool |
| US9109740B2 (en) | 2005-01-31 | 2015-08-18 | Timberline Tool, L.L.C. | Multi-layered patch system and method |
| CN105002000B (en) * | 2015-07-03 | 2018-02-02 | 承德人和矿业有限责任公司 | A kind of cleanser and its production and use |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5070411A (en) * | 1973-07-10 | 1975-06-11 | ||
| JPS5176685A (en) * | 1974-09-09 | 1976-07-02 | Procter & Gamble | KENMA SEIMIGAKIZAISOSEIBUTSU |
| JPS5311480A (en) * | 1976-07-15 | 1978-02-01 | Ishikawajima Harima Heavy Ind Co Ltd | Sea freight transporting process |
| JPS606794A (en) * | 1983-06-27 | 1985-01-14 | ライオン株式会社 | Detergent composition for hard surface |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1303810A (en) * | 1969-05-02 | 1973-01-24 | ||
| DE3138425A1 (en) * | 1981-09-26 | 1983-04-14 | Henkel KGaA, 4000 Düsseldorf | "USE OF A PASTOESE CLEANER IN DISHWASHER" |
| GB8328076D0 (en) * | 1983-10-20 | 1983-11-23 | Unilever Plc | Dishwashing compositions |
-
1983
- 1983-10-20 GB GB838328077A patent/GB8328077D0/en active Pending
-
1984
- 1984-10-10 EP EP84201449A patent/EP0139330B1/en not_active Expired - Lifetime
- 1984-10-10 AT AT84201449T patent/ATE54326T1/en not_active IP Right Cessation
- 1984-10-10 DE DE8484201449T patent/DE3482635D1/en not_active Expired - Fee Related
- 1984-10-17 AU AU34428/84A patent/AU566578B2/en not_active Ceased
- 1984-10-17 ZA ZA848108A patent/ZA848108B/en unknown
- 1984-10-18 NO NO844170A patent/NO163963C/en unknown
- 1984-10-19 PT PT79379A patent/PT79379B/en unknown
- 1984-10-20 JP JP59221109A patent/JPS60110792A/en active Granted
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5070411A (en) * | 1973-07-10 | 1975-06-11 | ||
| JPS5176685A (en) * | 1974-09-09 | 1976-07-02 | Procter & Gamble | KENMA SEIMIGAKIZAISOSEIBUTSU |
| JPS5311480A (en) * | 1976-07-15 | 1978-02-01 | Ishikawajima Harima Heavy Ind Co Ltd | Sea freight transporting process |
| JPS606794A (en) * | 1983-06-27 | 1985-01-14 | ライオン株式会社 | Detergent composition for hard surface |
Also Published As
| Publication number | Publication date |
|---|---|
| ATE54326T1 (en) | 1990-07-15 |
| PT79379A (en) | 1984-11-01 |
| NO163963B (en) | 1990-05-07 |
| ZA848108B (en) | 1986-06-25 |
| PT79379B (en) | 1987-02-09 |
| EP0139330A3 (en) | 1987-08-05 |
| EP0139330A2 (en) | 1985-05-02 |
| EP0139330B1 (en) | 1990-07-04 |
| JPS60110792A (en) | 1985-06-17 |
| NO163963C (en) | 1990-08-15 |
| DE3482635D1 (en) | 1990-08-09 |
| AU3442884A (en) | 1985-04-26 |
| GB8328077D0 (en) | 1983-11-23 |
| AU566578B2 (en) | 1987-10-22 |
| NO844170L (en) | 1985-04-22 |
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