JPH03209792A - Both-side metal-cladded flexible printed circuit board and manufacture thereof - Google Patents

Both-side metal-cladded flexible printed circuit board and manufacture thereof

Info

Publication number
JPH03209792A
JPH03209792A JP424590A JP424590A JPH03209792A JP H03209792 A JPH03209792 A JP H03209792A JP 424590 A JP424590 A JP 424590A JP 424590 A JP424590 A JP 424590A JP H03209792 A JPH03209792 A JP H03209792A
Authority
JP
Japan
Prior art keywords
adhesive
flexible printed
polyimide film
printed wiring
metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP424590A
Other languages
Japanese (ja)
Inventor
Moriji Gonda
盛二 権田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nikkan Industries Co Ltd
Original Assignee
Nikkan Industries Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nikkan Industries Co Ltd filed Critical Nikkan Industries Co Ltd
Priority to JP424590A priority Critical patent/JPH03209792A/en
Publication of JPH03209792A publication Critical patent/JPH03209792A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To simplify and improve a manufacturing method by forming a 5-layer structure of a metal foil-polyimide film-adhesive-polyimide film-metal foil. CONSTITUTION:2-layer structure piece metal-cladded flexible printed circuit boards 4, 5 in which metal foils 1 and polyimide films 2 are integrated without adhesive are opposed at the film 2 side and adhered through adhesive 3. In a manufacturing method of a circuit board, the polyimide films of the two 2-layer structure piece metal-cladded flexible printed circuit boards adhered with the metal foils to the films are adhered with the adhesive. The adhesive is not particularly limited if organic polymer adhesive is employed. That is, the structure is formed of a 5-layer structure of the metal foil-the polyimide film-the adhesive-the polyimide film-the metal foil.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明はフレキシブル印刷配線基板に利用され、特に、
両面金属張りフレキシブル印刷配線基板に関する。
[Detailed Description of the Invention] [Industrial Application Field] The present invention is utilized for flexible printed wiring boards, and in particular,
This invention relates to a double-sided metal-clad flexible printed wiring board.

〔概要〕〔overview〕

本発明は、両面金属張りフレキシブル印刷配線基板にお
いて、 構造を無接着剤の2層構造片面金属張りフ1/キシプル
印刷配線基板−接着剤−2層構造片面金属張りフレキシ
ブル印刷配線基板とすることにより、製造方法の簡単化
と特性の向上を図ったものである。
The present invention provides a double-sided metal-clad flexible printed circuit board having the following structure: an adhesive-free, two-layer structure, one-sided metal-clad flexible printed wiring board-adhesive-two-layer structure. , which aims to simplify the manufacturing method and improve the characteristics.

〔従来の技術〕[Conventional technology]

従来の両面金属張りフレキシブル印刷配線基板は、第2
図の模式的断面図にその一例を示すように、構造が、金
属箔1−接着剤3−ポリイミドフィルム2−接着剤3−
金属箔1の5層構造となっている。
Conventional double-sided metal-clad flexible printed wiring boards
As shown in the schematic cross-sectional view of the figure, the structure is: metal foil 1-adhesive 3-polyimide film 2-adhesive 3-
It has a five-layer structure of metal foil 1.

通常、この従来の両面金属張りフレキシブル印刷配線基
板の製造方法は、例えば、プラスチックフィルムどして
ポリイミドフィルムを用い、ポリイミドフィルムまたは
金属箔に接着剤を塗布乾燥後貼り合わせ、片面金属張り
フレキシブル印刷配線基板を製造した後、さらに次の工
程で、再度ポリイミドフィルムの他の面に接着剤を塗布
し乾燥後貼り合わせて製造される。
Normally, this conventional method for manufacturing double-sided metal-clad flexible printed circuit boards involves, for example, using a polyimide film instead of a plastic film, applying an adhesive to the polyimide film or metal foil, drying, and then bonding the single-sided metal-clad flexible printed wiring board. After manufacturing the substrate, the next step is to apply an adhesive again to the other side of the polyimide film, dry it, and then bond it together.

〔発明が解決しようとする問題点〕[Problem that the invention seeks to solve]

ところで、最近、フレキシブル印刷配線基板は、通信機
器、民生機器および産業機器等に極めて広範囲にわたり
使用され、これら機器における実装方法の簡略化、小型
化、高信頼性化および高機能化が進むにつれて、フレキ
シブル印刷配線基板に対する要求は極めて厳しいものが
ある。これに対して従来の両面金属張りフレキシブル印
刷配線基板は、前述のように接着剤を介して金属箔とポ
リイミドフィルムとを一体化しであるために、使用する
際、金属箔を取り除いたエツチング面には、接着剤が露
出し、ポリイミドの特徴よりも接着剤の特徴が出やすく
なり、耐熱性、電気的特性、耐溶剤性および難燃性等が
低下する欠点がある。また、両面金属張りフレキシブル
印刷配線基板の製造にあたっては、その製造工程が複雑
化する欠点がある。
Incidentally, recently, flexible printed wiring boards have been used in a wide range of communication equipment, consumer equipment, industrial equipment, etc., and as the mounting methods of these equipment have become simpler, smaller, more reliable, and more sophisticated, There are extremely strict requirements for flexible printed wiring boards. On the other hand, conventional double-sided metal-clad flexible printed wiring boards integrate metal foil and polyimide film through an adhesive as described above, so when used, the etched surface with the metal foil removed is This has the disadvantage that the adhesive is exposed, the characteristics of the adhesive are more likely to be exhibited than those of polyimide, and the heat resistance, electrical properties, solvent resistance, flame retardance, etc. are deteriorated. Further, in manufacturing a double-sided metal-clad flexible printed wiring board, there is a drawback that the manufacturing process becomes complicated.

また接着剤を用いずに両面板の長尺品を作成することは
、イミド樹脂生成時に縮合反応により水が発生し、ふ(
れやはがれが生じて、両面銅張り板の製造はきわめて困
難である欠点がある。
In addition, creating long double-sided boards without using adhesives is a problem because water is generated due to condensation reaction during the production of imide resin.
It has the disadvantage that it is extremely difficult to manufacture double-sided copper-clad plates due to the occurrence of cracking and peeling.

本発明の目的は、前記の欠点を除去することにより、特
性を向上させかつ製造工程を簡単にできる両面金属張り
フレキシブル印刷配線基板およびその製造方法を提供す
ることにある。
An object of the present invention is to provide a double-sided metal-clad flexible printed wiring board and a method for manufacturing the same, which can improve characteristics and simplify the manufacturing process by eliminating the above-mentioned drawbacks.

〔問題点を解決するための手段〕[Means for solving problems]

本発明は、前述の問題点を解決するために鋭意研究を行
い、第1図の模式的断面図にその一例を示すように、金
属箔1とポリイミドフィルム2とが接着剤を介さずに一
体化されている2層構造片面金属張りフレキシブル印刷
配線基板4および5を用いて、ポリイミドフィルム2の
面を相対して有機高分子からなる接着剤3を介して貼り
合わせることにより目的とする両面金属張りフレキシブ
ル印刷配線基板が製造できることを見出した。このよう
にして製造された両面金属張りフレキシブル印刷配線基
板は、耐熱性、電気的特性、耐溶剤性および難燃性にす
ぐれ、フレキシブル印刷配線基板として要求される緒特
性は全て満足する。また、製造工程も一工程のワニス塗
布乾燥貼り合わせて製造でき、非常に簡便である。
In order to solve the above-mentioned problems, the present invention has been made through intensive research, and as shown in the schematic cross-sectional view of FIG. By using two-layer structure single-sided metal-clad flexible printed circuit boards 4 and 5, which have been developed in the industry, the surfaces of the polyimide film 2 are bonded together via an adhesive 3 made of an organic polymer to form the desired double-sided metal. It has been discovered that a stretched flexible printed wiring board can be manufactured. The double-sided metal-clad flexible printed wiring board produced in this manner has excellent heat resistance, electrical properties, solvent resistance, and flame retardancy, and satisfies all the mechanical properties required for a flexible printed wiring board. Furthermore, the manufacturing process is very simple, as it can be manufactured by applying varnish, drying, and bonding in one step.

すなわち、本発明の両面金属張りフレキシブル印刷配線
基板は、両面に金属箔を有する両面金属張りフレキシブ
ル印刷配線基板において、構造が、金属箔−ポリイミド
フィルム−接着剤−ポリイミドフィルム−金属箔の5層
構造であることを特徴とする。
That is, the double-sided metal-clad flexible printed wiring board of the present invention is a double-sided metal-clad flexible printed wiring board having metal foil on both sides, and has a five-layer structure of metal foil-polyimide film-adhesive-polyimide film-metal foil. It is characterized by

また、本発明の両面金属張りフレキシブル印刷配線基板
の製造方法は、ポリイミドフィルムに金属箔が接着され
た2層構造片面金属張りフレキシブル印刷配線基板2枚
の前記ポリイミドフィルムどうしを接着剤を用いて接着
することを特徴とする。
Further, the method for manufacturing a double-sided metal-clad flexible printed wiring board of the present invention includes bonding two polyimide films of two-layer single-sided metal-clad flexible printed wiring boards each having a metal foil adhered to a polyimide film using an adhesive. It is characterized by

本発明におけるポリイミドフィルムの接着方法には、接
着剤の無い2層構造片面金属張りフレキシブル印刷配線
基板のポリイミドフィルム面の接着力を増加するために
、ポリイミドフィルム面をアルカリエツチングのように
処理されであるもの、またはプラズマ処理、マット処理
さらには、1〜7μ口のアンカーコート処理しであるも
のなどについても有効である。
The method for adhering polyimide films in the present invention includes treating the polyimide film surface with alkali etching in order to increase the adhesive strength of the polyimide film surface of the two-layer structure single-sided metal-clad flexible printed circuit board without an adhesive. It is also effective for those that have been subjected to plasma treatment, matte treatment, and even anchor coat treatment of 1 to 7 μm.

本発明に用いられる接着剤は、カルボキシル基含有アク
リルニトリル共重合体−エポキシ樹脂系、カルボキシル
基含有エチレンアクリル共重合体−エポキシ樹脂系、ポ
リアミド−エポキシ樹脂系、ポリエステル−エポキシ樹
脂系、アクリルニトリルブタジェンゴム系、ブチラール
樹脂系、フッソ樹脂系およびシリコーン樹脂系等、なら
びにこれらの樹脂と硬化剤とを含む組成物からなるもの
であり、これらの接着剤組成物には、必要に応じて、充
填剤、難燃剤および添加剤等を配合することができる。
The adhesive used in the present invention is a carboxyl group-containing acrylonitrile copolymer-epoxy resin system, a carboxyl group-containing ethylene acrylic copolymer-epoxy resin system, a polyamide-epoxy resin system, a polyester-epoxy resin system, an acrylonitrile but These adhesive compositions are made of adhesives such as Gen rubber, butyral resin, fluorocarbon resin, silicone resin, etc., as well as compositions containing these resins and curing agents. additives, flame retardants, additives, etc. can be blended.

以上のように本発明に用いられる接着剤は、有機高分子
接着剤であれば特に制限のあるものではない。
As described above, the adhesive used in the present invention is not particularly limited as long as it is an organic polymer adhesive.

〔作用〕[Effect]

本発明の構造をもつ両面金属張りフレキシブル印刷配線
基板は、中間層である例えばポリイミドフィルムとポリ
イミドフィルムとが接着剤を介して一体化されており、
金属箔とポリイミドフィルム間には接着剤が無いために
、接着剤の影響は受けずにポリイミドフィルムの特徴が
そのままフレキシブル印刷配線基板の特徴となる。すな
わち、耐熱性、特に熱時気中におけるビール強度の劣化
が著しく少ない。またマイグレーション等の電気的特性
に非常に優れ、さらに、ハンダ性および難燃性にも優れ
た両面金属張りフレキシブル印刷配線基板を製造するこ
とが可能となる。さらに、この製造方法は、2枚の2層
構造片面金属張りフレキシブル印刷配線基板を接着剤で
接着するだけでよいので、製造工程を簡単化することが
可能となる。
The double-sided metal-clad flexible printed wiring board having the structure of the present invention has an intermediate layer, for example, a polyimide film and a polyimide film, which are integrated through an adhesive.
Since there is no adhesive between the metal foil and the polyimide film, the characteristics of the polyimide film become the characteristics of the flexible printed wiring board without being affected by the adhesive. That is, heat resistance, especially beer strength in hot air, deteriorates significantly less. Furthermore, it is possible to produce a double-sided metal-clad flexible printed wiring board that has excellent electrical properties such as migration, and also has excellent solderability and flame retardancy. Furthermore, this manufacturing method simplifies the manufacturing process because it is only necessary to bond two two-layered single-sided metal-clad flexible printed circuit boards with an adhesive.

〔実施例〕〔Example〕

以下、本発明の実施例について説明するが、本発明はこ
れらに限定されるものではない。
Examples of the present invention will be described below, but the present invention is not limited thereto.

実施例1 カルボキシル基含有エチレンアクリル共重合体−エポキ
シ樹脂系樹脂および硬化剤からなる接着剤を、濃度40
%の接着剤溶液に調整した。次に、この接着剤溶液を、
塗布乾燥後の厚さが15μ0になるように、接着剤の無
いポリイミドフィルムと銅箔とからなる2層構造片面金
属張りフレキシブル印刷配線基板に塗布し、120℃で
10分間乾燥した。
Example 1 An adhesive consisting of a carboxyl group-containing ethylene acrylic copolymer-epoxy resin and a curing agent was prepared at a concentration of 40
% adhesive solution. Next, add this adhesive solution to
The coating was applied to a two-layer structure single-sided metal-clad flexible printed wiring board consisting of an adhesive-free polyimide film and copper foil so that the thickness after coating and drying was 15μ0, and the coating was dried at 120° C. for 10 minutes.

その後、この2層構造片面金属張りフレキシブル印刷配
線基板のポリイミドフィルム面が接1側になるように積
層し、160℃、60分、40kg/cr++”の条件
でプレス接着し、加熱アフターキュアーさせ、両面金属
張りフレキシブル印刷配線基板を作成した。
After that, the polyimide film side of this two-layer structure single-sided metal-clad flexible printed wiring board is laminated so that the first side is the contact side, press bonded at 160 ° C. for 60 minutes, 40 kg/cr++'', and heated after-cured. A double-sided metal-clad flexible printed wiring board was created.

実施例2 カルボキシル基含有アクリルニトリルブタジェン共重合
体−エポキシ樹脂系樹脂、硬化剤および充填剤からなる
接着剤を、固型分15%になるようにメチルエチルケト
ン:キシレン=1:1溶液に混合溶解して接着剤溶液を
調整した。そして、この接着剤溶液を用い、実施例1と
同様にして両面金属張りフレキシブル印刷配線基板を作
成した。
Example 2 An adhesive consisting of a carboxyl group-containing acrylonitrile butadiene copolymer-epoxy resin, a curing agent, and a filler was mixed and dissolved in a 1:1 solution of methyl ethyl ketone and xylene so that the solid content was 15%. The adhesive solution was prepared by Then, using this adhesive solution, a double-sided metal-clad flexible printed wiring board was created in the same manner as in Example 1.

実施例3 ポリアミド−エポキシ樹脂および硬化剤からなる接着剤
を固型分20%になるように、メタノールベンジルアル
コール溶液に混合溶解して接着剤溶液を調整した。そし
て、この接着剤溶液を用い、実施例1と同様にして両面
金属張りフレキシブル印刷配線基板を作成した。
Example 3 An adhesive solution was prepared by mixing and dissolving an adhesive consisting of a polyamide-epoxy resin and a curing agent in a methanol-benzyl alcohol solution so that the solid content was 20%. Then, using this adhesive solution, a double-sided metal-clad flexible printed wiring board was created in the same manner as in Example 1.

比較例1.2.3 実施例1.2および3の接着剤をそれぞれ厚さ25μl
のポリイミドフィルムの表裏両面に塗布し、120℃で
10分間乾燥した。その後、厚さ35μmの電解銅箔を
、ポリイミドフィルムの両面に積層し、160℃、60
分、40kg/Cm2の条件でプレス接着し、その後加
熱アフターキュアーさせ、両面金属張りフレキシブル印
刷配線基板を作成した。
Comparative Example 1.2.3 Adhesives from Examples 1.2 and 3 were each used at a thickness of 25 μl.
It was applied to both the front and back sides of a polyimide film and dried at 120°C for 10 minutes. After that, electrolytic copper foil with a thickness of 35 μm was laminated on both sides of the polyimide film, and
Press bonding was carried out under the conditions of 40 kg/cm2 for 30 minutes, followed by heat after-curing to produce a double-sided metal-clad flexible printed wiring board.

前記のようにして得られた各試料について、銅箔引き剥
がし強度、熱時気中銅箔引き剥がし強度、はんだ耐熱性
、マイグレーションおよび難燃性について試験を行った
。結果は第2表に示すとおりで、実施例は比較例に比べ
て、特に、熱時気中引き剥がし強度が強く、さらに、マ
イグレーションおよび難燃性はすべて合格で、極めてよ
い特性を示した。なお、第1表は接着剤の配合の詳細を
示したものである。
Each sample obtained as described above was tested for copper foil peel strength, hot air copper foil peel strength, solder heat resistance, migration, and flame retardancy. The results are shown in Table 2, and the examples showed particularly high peel strength in hot air compared to the comparative examples, and also passed the migration and flame retardance tests, showing extremely good properties. Note that Table 1 shows details of the formulation of the adhesive.

(以下本頁余白) 〔発明の効果〕 以上説明したように、本発明によれば、接着剤の無い2
層構造片面金属張りフレキシブル印刷配線基板を、接着
剤を用いてポリイミドフィルム面を相対して接着するこ
とにより、熱時気中での銅箔引き剥がし強度の低下が著
しく小さく、マイグレーションおよび難燃性にも優れた
両面金属張りフレキシブル印刷配線基板を簡単に得るこ
とができ、その効果は大である。
(Hereinafter, the margin of this page) [Effects of the invention] As explained above, according to the present invention, two
By bonding the polyimide film side of the layered single-sided metal-clad flexible printed wiring board with adhesive, the drop in peel strength of the copper foil in hot air is extremely small, and migration and flame retardant properties are achieved. It is possible to easily obtain an excellent double-sided metal-clad flexible printed wiring board, and its effects are great.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明の両面金属張りフレキシブル印刷配線基
板の一例の構造を示す模式的断面図。 第2図は従来の両面金属張りフレキシブル印刷配線基板
の一例の構造を示す模式的断面図。 1・・・金属箔、2・・・ポリイミドフィルム、3・・
・接着剤、4.5・・・2層構造片面金属張りフレキシ
ブル印刷配線基板。
FIG. 1 is a schematic cross-sectional view showing the structure of an example of the double-sided metal-clad flexible printed wiring board of the present invention. FIG. 2 is a schematic cross-sectional view showing the structure of an example of a conventional double-sided metal-clad flexible printed wiring board. 1... Metal foil, 2... Polyimide film, 3...
・Adhesive, 4.5...Two-layer structure single-sided metal-clad flexible printed wiring board.

Claims (3)

【特許請求の範囲】[Claims] 1.両面に金属箔を有する両面金属張りフレキシブル印
刷配線基板において、 構造が金属箔−ポリイミドフィルム−接着剤−ポリイミ
ドフィルム−金属箔の5層構造であることを特徴とする
両面金属張りフレキシブル印刷配線基板。
1. A double-sided metal-clad flexible printed wiring board having metal foil on both sides, characterized in that the structure is a five-layer structure of metal foil, polyimide film, adhesive, polyimide film, and metal foil.
2.接着剤が、熱硬化型アクリル系接着剤、熱硬化型ナ
イロン系接着剤、熱硬化型カルボキシル基含有アクリル
ニトリル共重合体、熱硬化型エポキシ樹脂系接着剤、フ
ッ素樹脂、あるいはシリコーン樹脂を含む有機高分子接
着剤である請求項1記載の両面金属張りフレキシブル印
刷配線基板。
2. The adhesive is a thermosetting acrylic adhesive, a thermosetting nylon adhesive, a thermosetting carboxyl group-containing acrylonitrile copolymer, a thermosetting epoxy resin adhesive, a fluororesin, or an organic resin containing a silicone resin. The double-sided metal-clad flexible printed wiring board according to claim 1, which is a polymer adhesive.
3.ポリイミドフィルムに金属箔が接着された2層構造
片面金属張りフレキシブル印刷配線基板2枚の前記ポリ
イミドフィルムどうしを接着剤を用いて接着する両面金
属張りフレキシブル印刷配線基板の製造方法。
3. A method for manufacturing a double-sided metal-clad flexible printed wiring board, which comprises bonding two polyimide films of two layers, each having a metal foil adhered to a polyimide film, to each other using an adhesive.
JP424590A 1990-01-11 1990-01-11 Both-side metal-cladded flexible printed circuit board and manufacture thereof Pending JPH03209792A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP424590A JPH03209792A (en) 1990-01-11 1990-01-11 Both-side metal-cladded flexible printed circuit board and manufacture thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP424590A JPH03209792A (en) 1990-01-11 1990-01-11 Both-side metal-cladded flexible printed circuit board and manufacture thereof

Publications (1)

Publication Number Publication Date
JPH03209792A true JPH03209792A (en) 1991-09-12

Family

ID=11579159

Family Applications (1)

Application Number Title Priority Date Filing Date
JP424590A Pending JPH03209792A (en) 1990-01-11 1990-01-11 Both-side metal-cladded flexible printed circuit board and manufacture thereof

Country Status (1)

Country Link
JP (1) JPH03209792A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1667501A1 (en) * 2003-09-10 2006-06-07 Unitika Ltd. Substrate for flexible printed wiring board and method for manufacturing same
JP2011014727A (en) * 2009-07-02 2011-01-20 Mitsui Mining & Smelting Co Ltd Copper foil with composite resin layer, method of manufacturing the same, and method of manufacturing flexible double-sided copper clad laminate and solid molding printed wiring board
JP2012106491A (en) * 2010-10-25 2012-06-07 Daikin Industries Ltd Metal-clad laminate, method of manufacturing the same, and flexible printed circuit board
KR20150003243A (en) * 2012-04-10 2015-01-08 랜 테크니컬 서비스 가부시키가이샤 Method for bonding polymer film and polymer film, method for bonding polymer film and inorganic material substrate, polymer film laminate, and laminate of polymer film and inorganic material substrate
JP2022041804A (en) * 2020-09-01 2022-03-11 佳勝科技股▲ふん▼有限公司 Composite substrate method for manufacturing the same

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5683098A (en) * 1979-12-11 1981-07-07 Matsushita Electric Ind Co Ltd Bothhside metallic foil stretcher for printed circuit
JPS6265394A (en) * 1985-09-17 1987-03-24 旭化成株式会社 Flexible circuit board
JPS62208690A (en) * 1985-10-31 1987-09-12 三井東圧化学株式会社 Flexible printed circuit and manufacture of the same

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5683098A (en) * 1979-12-11 1981-07-07 Matsushita Electric Ind Co Ltd Bothhside metallic foil stretcher for printed circuit
JPS6265394A (en) * 1985-09-17 1987-03-24 旭化成株式会社 Flexible circuit board
JPS62208690A (en) * 1985-10-31 1987-09-12 三井東圧化学株式会社 Flexible printed circuit and manufacture of the same

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1667501A1 (en) * 2003-09-10 2006-06-07 Unitika Ltd. Substrate for flexible printed wiring board and method for manufacturing same
EP1667501A4 (en) * 2003-09-10 2010-01-06 Unitika Ltd Substrate for flexible printed wiring board and method for manufacturing same
JP2011014727A (en) * 2009-07-02 2011-01-20 Mitsui Mining & Smelting Co Ltd Copper foil with composite resin layer, method of manufacturing the same, and method of manufacturing flexible double-sided copper clad laminate and solid molding printed wiring board
JP2012106491A (en) * 2010-10-25 2012-06-07 Daikin Industries Ltd Metal-clad laminate, method of manufacturing the same, and flexible printed circuit board
KR20150003243A (en) * 2012-04-10 2015-01-08 랜 테크니컬 서비스 가부시키가이샤 Method for bonding polymer film and polymer film, method for bonding polymer film and inorganic material substrate, polymer film laminate, and laminate of polymer film and inorganic material substrate
JP2022041804A (en) * 2020-09-01 2022-03-11 佳勝科技股▲ふん▼有限公司 Composite substrate method for manufacturing the same

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