JPH03197344A - Production of carbon fiber-reinforced dry mortar and mortar coating material - Google Patents

Production of carbon fiber-reinforced dry mortar and mortar coating material

Info

Publication number
JPH03197344A
JPH03197344A JP33634789A JP33634789A JPH03197344A JP H03197344 A JPH03197344 A JP H03197344A JP 33634789 A JP33634789 A JP 33634789A JP 33634789 A JP33634789 A JP 33634789A JP H03197344 A JPH03197344 A JP H03197344A
Authority
JP
Japan
Prior art keywords
carbon fiber
mortar
weight
coating material
produced
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP33634789A
Other languages
Japanese (ja)
Inventor
Teruaki Oki
大木 照章
Takashi Nakamura
孝 中村
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Showa Shell Sekiyu KK
Original Assignee
Showa Shell Sekiyu KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Showa Shell Sekiyu KK filed Critical Showa Shell Sekiyu KK
Priority to JP33634789A priority Critical patent/JPH03197344A/en
Publication of JPH03197344A publication Critical patent/JPH03197344A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

PURPOSE:To improve the dispersibility of carbon fiber by mixing white cement to a dried slurry produced by drying a kneaded mixture of carbon short fibers, calcium oxide and carbonated water or an aqueous solution of a surfactant. CONSTITUTION:A dried slurry is produced by successively adding 1-5wt.% of pitch-based carbon short fibers, 50-70wt.% of calcium oxide such as CaO3 and 30-45wt.% of a dispersing agent consisting of carbonated water or an aqueous solution of a surfactant having a concentration of 0.01-1wt.%, kneading the mixture, drying the obtained slurry under specific condition and crushing the product. The objective carbon fiber-reinforced dry mortar can be produced by mixing 25-50wt.% of the dried slurry and 50-75wt.% of white cement.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は炭素繊維補強モルタルの製造法および炭素繊維
補強モルタルを使用した建築土木構造物のモルタル塗装
材に関する。
DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a method for producing carbon fiber-reinforced mortar and a mortar coating material for architectural and civil engineering structures using carbon fiber-reinforced mortar.

(従来の技術) 従来の繊維補強モルタルの製造法は繊維を直接にセメン
トに混合する方法であるが、繊維の分散性が悪い欠点が
あった。さらに、繊維をシリカを主成分とした混和材、
例えばシリカヒユームを使用してセメントに混合する方
法があるが、塗装した場合にグレーに着色し、白色に仕
上らない欠点がある。
(Prior Art) The conventional method for manufacturing fiber-reinforced mortar is to mix fibers directly into cement, but this method has the drawback of poor fiber dispersibility. In addition, fibers can be mixed with silica-based admixtures,
For example, there is a method of using silica fume and mixing it with cement, but it has the disadvantage that when painted, it is colored gray and the finish is not white.

(発明が解決しようとする課題) 本発明者は、塗装した場合に炭素繊維の分散性が良く、
かつ白色に仕上る炭素繊維補強乾燥モルタルについて研
究し、本発明に到達した。
(Problems to be Solved by the Invention) The present inventor has discovered that carbon fibers have good dispersibility when painted;
The present invention was achieved through research on carbon fiber-reinforced dry mortar that has a white finish.

(課題を解決するための手段) 本発明は短繊維の炭素繊維1〜5重量%、カルシウム酸
化物50〜70重量%および分散剤として炭酸水又は界
面活性剤の0.01〜1重量%濃度の水溶液30〜45
重量%を混練した後乾燥してなる乾燥スラリー25〜5
0重量%および白セメント50〜75重量%を混合する
ことを特徴とする炭素繊維補強乾燥モルタルの製造法で
ある。
(Means for Solving the Problems) The present invention has a concentration of 1 to 5% by weight of short carbon fibers, 50 to 70% by weight of calcium oxide, and 0.01 to 1% by weight of carbonated water or a surfactant as a dispersant. Aqueous solution of 30-45
Dry slurry obtained by kneading and drying 25 to 5% by weight
This is a method for producing carbon fiber reinforced dry mortar characterized by mixing 0% by weight and 50 to 75% by weight of white cement.

また、本発明の製造法で製造した炭素繊維補強乾燥モル
タルから成り、炭素繊維の分散が良く、かつ白色に仕上
る建築土木構造物のモルタル塗装材である。
It is also a mortar coating material for architectural and civil engineering structures, which is made of carbon fiber-reinforced dry mortar produced by the production method of the present invention, has good dispersion of carbon fibers, and has a white finish.

本発明に使用する炭素繊維は、ピッチ系炭素繊維で短繊
維のものであれば、何でも使用できる。
The carbon fiber used in the present invention can be any pitch-based carbon fiber as long as it is short fiber.

カルシウム酸化物としてはCaO1Cab、またはCa
Osが使用できるが、好ましいのはCaO3である。
Calcium oxide is CaO1Cab or Ca
Although Os can be used, CaO3 is preferred.

スラリー中、カルシウム酸化物が50重量%より少い場
合は炭素繊維の分散性が悪くなる。カルシウム酸化物が
70重量%を超えると仕上げたモルタル表面に粉を生じ
、またモルタルがもろくなる。
If the calcium oxide content in the slurry is less than 50% by weight, the dispersibility of carbon fibers will be poor. If the calcium oxide content exceeds 70% by weight, powder will form on the surface of the finished mortar, and the mortar will become brittle.

分散剤としては炭酸水または界面活性剤のいずれでもよ
いが、炭酸水のほうが、モルタル塗装材中に気泡が残ら
ず好ましい、界面活性剤としては通常のカチオン系界面
活性剤、アニオン系界面活性荊あるいは非イオン界面活
性剤のいずれでもよい。スラリー中、分散剤が30重量
%より少いと混合が不充分になり易く、分散剤が45重
量%より多いと乾燥に時間を要し、熱損失が大きい。
The dispersant may be carbonated water or a surfactant, but carbonated water is preferable because it does not leave bubbles in the mortar coating material.As the surfactant, ordinary cationic surfactants and anionic surfactants can be used. Alternatively, any nonionic surfactant may be used. If the amount of dispersant in the slurry is less than 30% by weight, mixing tends to be insufficient, and if the amount of dispersant is more than 45% by weight, drying takes time and heat loss is large.

白セメントは市販の通常の白セメントを使用することが
できる。
Commercially available normal white cement can be used as the white cement.

(実施例) 以下、本発明を実施例によって説明する。これらは本発
明を何ら限定するものではない。
(Examples) Hereinafter, the present invention will be explained by examples. These do not limit the present invention in any way.

大胤皿上 ピッチ系炭素繊維10g、カルシウム酸化物としてCa
O3(ニスカロン100.三井精粉(株)製)200g
および分散剤としてアルキルベンゼンスルフオン酸ナト
リウム高縮合物塩(ハイ・ベック。
10g of pitch-based carbon fiber on a large plate, Ca as calcium oxide
O3 (Niscaron 100.Mitsui Seifun Co., Ltd.) 200g
and sodium alkylbenzenesulfonate high condensate salt (Hy Beck) as a dispersant.

サンワード(株)製)の0.5%水溶液IQOgをこの
順に加え、撹拌してスラリーを得た。
A 0.5% aqueous solution IQOg (manufactured by Sunward Co., Ltd.) was added in this order and stirred to obtain a slurry.

このスラリーを20℃、72時間で乾燥した後粉砕し、
乾燥スラリーを得た。
This slurry was dried at 20°C for 72 hours and then ground.
A dried slurry was obtained.

乾燥スラリー150gと白色セメント(粉末)150g
を混合し、ミキシングして、炭素繊維補強乾燥モルタル
を得た。
150g dry slurry and 150g white cement (powder)
were mixed and mixed to obtain a carbon fiber reinforced dry mortar.

大嵐班1 実施例1で得られた炭素繊維補強乾燥モルタル200g
に水80gを加え混練した後、ブロック塀、家屋の外壁
および発泡スチロール板上に塗った。
Daiarashi Group 1 200g of carbon fiber reinforced dry mortar obtained in Example 1
After adding 80 g of water and kneading, the mixture was applied to block walls, the exterior walls of houses, and polystyrene foam boards.

仕上りは、白色で繊維のランダム配向模様が見られた。The finish was white with a randomly oriented pattern of fibers.

(発明の効果) 本発明の製造法によって得られる炭素繊維補強乾燥モル
タルは、 (1)  水を加えて混練するだけで手軽に使用でき、
特にブロック塀、壁等の上塗、下塗に好適である。
(Effects of the invention) The carbon fiber-reinforced dry mortar obtained by the production method of the present invention is: (1) Easy to use by simply adding water and kneading;
It is particularly suitable for top coating and undercoating of block walls, walls, etc.

(2)仕上りは白色で明るく、短繊維のランダム模様も
あり・、優雅な怒じを与える。
(2) The finish is white and bright, with a random pattern of short fibers, giving it an elegant look.

Claims (1)

【特許請求の範囲】 1、短繊維の炭素繊維1〜5重量%、カルシウム酸化物
50〜70重量%および分散剤として炭酸水又は界面活
性剤の0.01〜1重量%濃度の水溶液30〜45重量
%を混練した後乾燥してなる乾燥スラリー25〜50重
量%および白セメント50〜75重量%を混合すること
を特徴とする炭素繊維補強乾燥モルタルの製造法。 2、請求項第1項の製造法で製造した炭素繊維補強乾燥
モルタルを含有するモルタル塗装材。
[Claims] 1. An aqueous solution of 1 to 5% by weight of short carbon fibers, 50 to 70% by weight of calcium oxide, and 0.01 to 1% by weight of carbonated water or a surfactant as a dispersant. A method for producing a carbon fiber reinforced dry mortar, which comprises mixing 25 to 50% by weight of a dry slurry obtained by kneading and drying 45% by weight and 50 to 75% by weight of white cement. 2. A mortar coating material containing carbon fiber-reinforced dry mortar produced by the production method according to claim 1.
JP33634789A 1989-12-27 1989-12-27 Production of carbon fiber-reinforced dry mortar and mortar coating material Pending JPH03197344A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP33634789A JPH03197344A (en) 1989-12-27 1989-12-27 Production of carbon fiber-reinforced dry mortar and mortar coating material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP33634789A JPH03197344A (en) 1989-12-27 1989-12-27 Production of carbon fiber-reinforced dry mortar and mortar coating material

Publications (1)

Publication Number Publication Date
JPH03197344A true JPH03197344A (en) 1991-08-28

Family

ID=18298187

Family Applications (1)

Application Number Title Priority Date Filing Date
JP33634789A Pending JPH03197344A (en) 1989-12-27 1989-12-27 Production of carbon fiber-reinforced dry mortar and mortar coating material

Country Status (1)

Country Link
JP (1) JPH03197344A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0776153A3 (en) * 1995-11-24 1997-06-18 Knauf Westdeutsche Gips
CN105884305A (en) * 2016-04-18 2016-08-24 西安建筑科技大学 Method for preparing carbon fiber cement based composite through dry mixing and dry pressing

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0776153A3 (en) * 1995-11-24 1997-06-18 Knauf Westdeutsche Gips
CN105884305A (en) * 2016-04-18 2016-08-24 西安建筑科技大学 Method for preparing carbon fiber cement based composite through dry mixing and dry pressing

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