CN110423137A - A kind of novel environment friendly ardealite high-strength light walling product and preparation method thereof - Google Patents
A kind of novel environment friendly ardealite high-strength light walling product and preparation method thereof Download PDFInfo
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- CN110423137A CN110423137A CN201910674057.2A CN201910674057A CN110423137A CN 110423137 A CN110423137 A CN 110423137A CN 201910674057 A CN201910674057 A CN 201910674057A CN 110423137 A CN110423137 A CN 110423137A
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/14—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
- C04B28/142—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements containing synthetic or waste calcium sulfate cements
- C04B28/143—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements containing synthetic or waste calcium sulfate cements the synthetic calcium sulfate being phosphogypsum
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/40—Porous or lightweight materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/52—Sound-insulating materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The present invention discloses a kind of novel environment friendly ardealite high-strength light walling product, it is prepared by the raw material of following parts by weight: 5~20 parts of composite granule, 30~80 parts of phosphorus building gypsum, 10~50 parts of haydite, 0.05~0.3 part of retarder, 0.3~1.5 part of water-reducing agent, it is 0.1~1.0 part of waterproofing agent, 1~5 part of exciting agent, anti-to creep 0.05~0.3 part of agent, 0.01~0.5 part of binder, 40~60 parts of water.The present invention prepares wallboard, building block and brick as primary raw material using phosphorus building gypsum, provides solution for the comprehensive utilization of ardealite Industrial Solid Waste industrial by-product ardealite, to protection environment, realizes that sustainable development is of great significance；And the novel environment friendly ardealite high strength light wall board/building block/brick prepared has the advantages that lightweight, compression strength height, High anti bending strength, water absorption rate are low etc., can be widely applied to interior/exterior decoration material.
Description
Technical field
The invention belongs to wallboard production technical fields, and in particular to a kind of novel environment friendly ardealite high-strength light walling product
And preparation method thereof.
Background technique
Industrial by-product ardealite is the industrial solid castoff of generation during Wet-process phosphoric acid (WPPA), 1 ton of phosphoric acid of every production
About 4-5 tons of ardealite can be discharged.The a large amount of main processing mode of ardealite is still simple stacking, not only land occupation area,
And it can be polluted to surrounding enviroment.Therefore, the resource utilization of industrial by-product ardealite is always country, industry and society
Focus.
Currently, the most frequently used have backfill pit the method that handles industrial by-product ardealite, production Flocculated Cement agent, prepare sulphur
Ammonium and calcium carbonate, improvement basic soil.These methods have pushed the technology of China's ardealite recycling to develop, but there is safety
And pollution hidden trouble, long flow path invest the disadvantages of big, can not fundamentally solve the Environmental security hidden danger of industrial by-product ardealite
The relatively low status with utilization rate.Meanwhile publication No. is that CN102180700A Chinese patent application is disclosed and a kind of used ardealite
Method to prepare light cellular partition board and building block, product has many advantages, such as lightweight, sound insulation and heat preservation, and produces easy, cost
It is low, pollution-free, but plastering the problems such as that there are intensity is low, poor water resistance, thus limit gypsum partition board, building block and brick
Application and development.
Summary of the invention
In view of the above technical problems, the present invention provides a kind of novel environment friendly ardealite high-strength light walling product and its preparation
Method, the present invention prepare wallboard, building block and brick as primary raw material using phosphorus building gypsum, utilize and mention for ardealite Industrial Solid Waste
Solution has been supplied, to protection environment, has realized that sustainable development is of great significance；And the environment-friendly novel high strength gypsum prepared
Light-weight aggregate brick, building block, plate etc. have the advantages that lightweight, compression strength height, High anti bending strength, water absorption rate are low etc., can be widely applied to
Interior/exterior decoration material.
To achieve the above object, the technical solution adopted by the present invention is that: a kind of novel environment friendly ardealite high-strength light walling
Product is prepared by the raw material of following parts by weight: 5~20 parts of composite granule, 30~80 parts of phosphorus building gypsum, and haydite 10~50
Part, 0.05~0.3 part of retarder, 0.3~1.5 part of water-reducing agent, 0.1~1.0 part of waterproofing agent, 1~5 part of exciting agent, anti-agent of creeping
0.05~0.3 part, 0.01~0.5 part of binder, 40~60 parts of water.
Further technical solution is prepared by the raw material of following parts by weight: 5~20 parts of composite granule, phosphorus building
50~80 parts of gypsum, 20~40 parts of haydite, 0.05~0.15 part of retarder, 0.9 part of water-reducing agent, 0.2~1.0 part of waterproofing agent, swash
1~5 part of agent of hair, anti-to creep 0.05~0.3 part of agent, binder 0.01~0.5,40~55 parts of water.
Further technical solution is that the composite granule is the powder binding material being mixed in a certain ratio.
Further technical solution is that the phosphorus building gypsum is modified self-control ardealite.
Specific modification mode: first passing through neutralisation treatment about 48h, then is dried (105~170 DEG C of temperature) processing, then
Grinding to certain fineness (meets 0.2mm square hole screen and tails over≤10%).
Further technical solution is that the retarder is any one in animal protein class, borax and Citric Acid Mono
Kind.
Further technical solution is that the water-reducing agent is that melamine compounds water-reducing agent with naphthalene system, compounds buck agent
Solid content 15%, water-reducing rate is greater than 25%, to not influence gypsum color, can obviously increase the mobility of gypsum, reduce stone
The viscosity of cream slurry.
Further technical solution is that the waterproofing agent is dissolubility organosilicon or hydrophober such as calcium stearate class.
Further technical solution is that the haydite is self-control haydite, and self-control haydite is using municipal sludge and building slag
Soil, engineering spoir, building micro mist etc. are fired through treatment process, environmental protection and energy saving.
Further technical solution is that the exciting agent is quick lime, for exciting the activity of gypsum mixing material, improves stone
Cream hardenite intensity.
Further technical solution is that the anti-agent of creeping is boric acid or trimethyl sodium phosphate.
Further technical solution is that the binder is latex powder, improves workability, improves mobile performance, is increased
Bend resistance intensity.The exciting agent is quick lime.
A kind of preparation method of novel environment friendly ardealite high-strength light walling product, comprising the following steps:
A, it is uniformly mixed obtained mixture 1 in advance after weighing phosphorus building gypsum, composite granule and haydite；
B, Jiang Shui, water-reducing agent, retarder, waterproofing agent, exciting agent, anti-agent of creeping, binder are added mixture 1 and stir equal
Even obtained mixture 2；
C, wallboard, building block and brick is made by moulding by casting, heating curing, demoulding, machine-shaping in mixture 2.
The water consumption that melamine compounds water-reducing agent with naphthalene system when can reduce gypsum mix in the present invention, improves gypsum
The crystal form of crystal, node increases between crystal and contact point physically well develops, and mutual collocation more closely, is formed more complete
Crystalline network system is improved its intensity so as to improve the mechanical property of gypsum hardenite；Retarder is that one kind can prolong
The additive of long setting time, enables newly to mix gypsum slurry and keeps plasticity in a longer period of time, operates convenient for formed product；
Haydite is fired as the precision processing technique such as mud and engineering spoir, building micro mist, can make that product weight is light, heat insulating ability
Energy is good, heat loss is small；In gypsum substrate hydration reaction occurs for composite granule, generates the hydrated products such as hydrated calcium aluminate sulfate,
It can be improved the water resistance of product.
The invention has the following advantages that
1, the present invention prepares high strength gypsum product as primary raw material using phosphorus building gypsum, solid for industrial by-product ardealite
Useless utilization provides scheme, to protection environment, realizes that sustainable development is of great significance.
2, the present invention is fired using haydite as the precision processing technique such as mud and architecture sediment, engineering spoir, building micro mist
It forms, can make that product weight is light, good heat insulating, be city solid waste using scheme is provided, to environment is protected, realization can be held
Supervention exhibition is of great significance；
3, the present invention, which uses to resist, creeps agent as boric acid, and boric acid can promote the generation of the dihydrate gypsum crystal of large area, reduce
The production quantity of acicular crystal improves the rigidity of plasterboard, overcomes plasterboard to bend in wet environment phenomenon, avoids being self-possessed
Effect is lower, and deformation occurs.
4, into scientific research is carried out to raw material proportioning excessively, the environment-friendly novel high strength gypsum thistle board of preparation has light the present invention
The advantages that matter, compression strength height, High anti bending strength, water absorption rate are low, heat preservation and heat resistance are good, can be widely applied to indoor exterior
Exterior material, and produce easy, at low cost, pollution-free.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to embodiments, to the present invention
It is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to
Limit the present invention.
Embodiment 1
A kind of novel environment friendly ardealite high-strength light walling product, is prepared: composite powder by the raw material of following parts by weight
10 parts of body, 70 parts of phosphorus building gypsum, 20 parts of haydite, 0.15 part of retarder, 0.9 part of water-reducing agent, 0.8 part of waterproofing agent, exciting agent 1
Part, anti-creep 0.05 part of agent, 0.01 part of binder, 45 parts of water.
Wherein water-reducing agent is that melamine compounds water-reducing agent, solid content 15%, water-reducing rate 28%, phosphorus building gypsum with naphthalene system
Ardealite is made by oneself to be modified, and retarder is protein retarder, and waterproofing agent is dissolubility organosilicon.
Embodiment 2
A kind of novel environment friendly ardealite high-strength light walling product, is prepared: composite powder by the raw material of following parts by weight
10 parts of body, 80 parts of phosphorus building gypsum, 20 parts of haydite, 0.1 part of retarder, 0.6 part of water-reducing agent, 0.7 part of waterproofing agent, 5 parts of exciting agent,
Anti- creep 0.3 part of agent, 0.5 part of binder, 45 parts of water.
Wherein water-reducing agent is that melamine compounds water-reducing agent, solid content 15%, water-reducing rate 28%, phosphorus building gypsum with naphthalene system
Ardealite is made by oneself to be modified, and retarder is protein retarder, and waterproofing agent is dissolubility organosilicon.
Embodiment 3
A kind of novel environment friendly ardealite high-strength light walling product, is prepared: composite powder by the raw material of following parts by weight
5 parts of body, 65 parts of phosphorus building gypsum, 30 parts of haydite, 0.2 part of retarder, 0.12 part of water-reducing agent, 0.6 part of waterproofing agent, 5 parts of exciting agent,
Anti- creep 0.3 part of agent, 0.5 part of binder, 50 parts of water.
Wherein water-reducing agent is that melamine compounds water-reducing agent, solid content 15%, water-reducing rate 28%, phosphorus building gypsum with naphthalene system
Ardealite is made by oneself to be modified, and retarder is protein retarder, and waterproofing agent is dissolubility organosilicon.
Embodiment 4
A kind of environment-friendly novel high strength gypsum light block and brick, are prepared: composite granule 5 by the raw material of following parts by weight
Part, resists 55 parts of phosphorus building gypsum, 40 parts of haydite, 0.25 part of retarder, 0.15 part of water-reducing agent, 0.5 part of waterproofing agent, 1 part of exciting agent
It creeps 0.05 part of agent, 0.01 part of binder, 55 parts of water.
Wherein water-reducing agent is that melamine compounds water-reducing agent, solid content 15%, water-reducing rate 28%, phosphorus building gypsum with naphthalene system
Ardealite is made by oneself to be modified, and retarder is protein retarder, and waterproofing agent is dissolubility organosilicon.
Above-described embodiment 1 to embodiment 4 wallboard all through the following steps that being prepared:
1) it is uniformly mixed obtained mixture 1 in advance after weighing phosphorus building gypsum, composite granule and haydite；
2) mixture 1 is added in water, water-reducing agent, retarder, waterproofing agent, exciting agent, binder, anti-agent of creeping and stirred equal
Even obtained mixture 2；
3) wallboard is made by moulding by casting, heating curing, demoulding, machine-shaping in mixture 2.
The compression strength of environment-friendly novel high strength gypsum light-weight wall material product prepared by detection above-described embodiment 1 to embodiment 4,
Flexural strength and water absorption rate.As a result as follows:
1 embodiment 1 of table to example 4 prepares environment-friendly novel high strength gypsum light-weight wall material product properties parameter
It is available from table 1, the compression strength of novel environment friendly ardealite high-strength light walling product prepared by the present invention and
High anti bending strength, water absorption rate are low, sound insulation value is good, contraction is small.
In conclusion the present invention prepares walling product with lightweight, pressure resistance as primary raw material using phosphorus building gypsum
The advantages such as height, High anti bending strength, water absorption rate be low are spent, can be widely applied to interior/exterior decoration material.
The above is not intended to limit the present invention in any form, although the present invention takes off through the foregoing embodiment
Show, however, it is not intended to limit the invention, any person skilled in the art, is not departing from technical solution of the present invention range
It is interior, made when the technology contents using the disclosure above and change or be modified to the equivalent embodiments of equivalent variations a bit, but it is all not
Be detached from technical solution of the present invention content, according to the technical essence of the invention it is to the above embodiments it is any it is simple modification,
Equivalent variations and modification, still fall within the range of technical solution of the present invention.
Claims (10)
1. a kind of novel environment friendly ardealite high-strength light walling product, which is characterized in that by the raw material preparation of following parts by weight
At: 5~20 parts of composite granule, 30~80 parts of phosphorus building gypsum, 10~50 parts of haydite, 0.05~0.3 part of retarder, water-reducing agent
It is 0.3~1.5 part, 0.1~1.0 part of waterproofing agent, 1~5 part of exciting agent, anti-to creep 0.05~0.3 part of agent, binder 0.01~0.5
Part, 40~60 parts of water.
2. a kind of novel environment friendly ardealite high-strength light walling product according to claim 1, which is characterized in that by following
The raw material of parts by weight is prepared: 5~20 parts of composite granule, 50~80 parts of phosphorus building gypsum, and 20~40 parts of haydite, retarder
It is 0.05~0.15 part, 0.9 part of water-reducing agent, 0.2~1.0 part of waterproofing agent, 1~5 part of exciting agent, anti-to creep 0.05~0.3 part of agent, it glues
Knot agent 0.01~0.5,40~60 parts of water.
3. a kind of novel environment friendly ardealite high-strength light walling product according to claim 1 or 2, which is characterized in that institute
Stating composite granule is powder binding material.
4. a kind of novel environment friendly ardealite high-strength light walling product according to claim 1 or 2, which is characterized in that institute
Phosphorus building gypsum is stated as modified self-control ardealite.
5. a kind of novel environment friendly ardealite high-strength light walling product according to claim 1 or 2, which is characterized in that institute
Stating retarder is any one in animal protein class, borax and Citric Acid Mono.
6. a kind of novel environment friendly ardealite high-strength light walling product according to claim 1 or 2, which is characterized in that institute
Stating water-reducing agent is that melamine compounds water-reducing agent, solid content 15% with naphthalene system, and water-reducing rate is greater than 25%.
7. a kind of novel environment friendly ardealite high-strength light walling product according to claim 1 or 2, which is characterized in that institute
Stating waterproofing agent is dissolubility organosilicon or hydrophober such as calcium stearate class.
8. a kind of novel environment friendly ardealite high-strength light walling product according to claim 1 or 2, which is characterized in that institute
Stating exciting agent is quick lime.
9. a kind of novel environment friendly ardealite high-strength light walling product according to claim 1 or 2, which is characterized in that institute
Stating anti-agent of creeping is boric acid or trimethyl sodium phosphate, and the binder is latex powder.
10. a kind of preparation method of novel environment friendly ardealite high-strength light walling product, which comprises the following steps:
A, it is uniformly mixed obtained mixture 1 in advance after weighing phosphorus building gypsum, composite granule and haydite；
B, mixture 1 and the system of stirring evenly is added in Jiang Shui, water-reducing agent, retarder, waterproofing agent, exciting agent, anti-agent of creeping, binder
Obtain mixture 2；
C, wallboard, building block and brick is made by moulding by casting, heating curing, demoulding, machine-shaping in mixture 2.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111792902A (en) * | 2020-06-11 | 2020-10-20 | 中建西部建设建材科学研究院有限公司 | High-strength water-resistant phosphogypsum composite cementing material and preparation method thereof |
| CN112759420A (en) * | 2021-03-09 | 2021-05-07 | 扈士凯 | Building gypsum foam concrete and preparation method thereof |
| CN113860837A (en) * | 2021-10-15 | 2021-12-31 | 钟祥绿景环保科技有限公司 | Phosphogypsum production method and calcination-free phosphogypsum |
| CN114166604A (en) * | 2021-12-08 | 2022-03-11 | 重庆重通成飞新材料有限公司 | Testing method for recycled fiber reinforced pouring type gypsum wallboard of wind power blade |
| CN114804803A (en) * | 2022-04-29 | 2022-07-29 | 贵州开磷磷石膏综合利用有限公司 | High-strength moisture-proof gypsum block for wall and preparation method thereof |
| CN115417612A (en) * | 2022-08-30 | 2022-12-02 | 华新水泥股份有限公司 | High-flow-state early-strength geopolymer material and preparation method thereof |
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| CN103539419A (en) * | 2013-08-29 | 2014-01-29 | 武汉理工大学 | Phosphogypsum-base wall material for cast-in-place wall |
| CN105174890A (en) * | 2015-09-09 | 2015-12-23 | 济南大学 | Composite light partition board and manufacturing method thereof |
| CN108997023A (en) * | 2018-09-29 | 2018-12-14 | 常州工程职业技术学院 | A kind of fluorgypsum Quito member composite light high-strength wall material and preparation method thereof |
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| CN103539419A (en) * | 2013-08-29 | 2014-01-29 | 武汉理工大学 | Phosphogypsum-base wall material for cast-in-place wall |
| CN105174890A (en) * | 2015-09-09 | 2015-12-23 | 济南大学 | Composite light partition board and manufacturing method thereof |
| CN108997023A (en) * | 2018-09-29 | 2018-12-14 | 常州工程职业技术学院 | A kind of fluorgypsum Quito member composite light high-strength wall material and preparation method thereof |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111792902A (en) * | 2020-06-11 | 2020-10-20 | 中建西部建设建材科学研究院有限公司 | High-strength water-resistant phosphogypsum composite cementing material and preparation method thereof |
| CN112759420A (en) * | 2021-03-09 | 2021-05-07 | 扈士凯 | Building gypsum foam concrete and preparation method thereof |
| CN113860837A (en) * | 2021-10-15 | 2021-12-31 | 钟祥绿景环保科技有限公司 | Phosphogypsum production method and calcination-free phosphogypsum |
| CN114166604A (en) * | 2021-12-08 | 2022-03-11 | 重庆重通成飞新材料有限公司 | Testing method for recycled fiber reinforced pouring type gypsum wallboard of wind power blade |
| CN114804803A (en) * | 2022-04-29 | 2022-07-29 | 贵州开磷磷石膏综合利用有限公司 | High-strength moisture-proof gypsum block for wall and preparation method thereof |
| CN115417612A (en) * | 2022-08-30 | 2022-12-02 | 华新水泥股份有限公司 | High-flow-state early-strength geopolymer material and preparation method thereof |
| CN115417612B (en) * | 2022-08-30 | 2023-09-26 | 华新水泥股份有限公司 | High-flow-state early-strength geopolymer material and preparation method thereof |
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Application publication date: 20191108 |